WS Grade 10 IG Chemistry 23-24 - Revision For UT1

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NPS International School

Name: ________________ Subject: Chemistry


Date: _________________ Grade: X IGCSE
Revision - Chemical Energetics, Speed of Reaction & Stoichiometry
1 40 cm3 of ammonia gas was burnt in 50 cm3 of oxygen to produce nitrogen and
water, according to the equation 4NH3 + 3O2 → 2N2 + 6H2O. A catalyst is normally
used for this reaction.
(a) Calculate the total volume of gases, after the reaction chamber is cooled to
room temperature.

[1]

(b) The reaction releases 1286 kJ of energy. Use the data in the table below to
calculate the O−H bond energy.

Bond N−H O−O O=O N-N N=N N≡N


Bond Energy ( kJ/mol ) 390 140 498 160 418 946

[3]

(c) On the same axes, draw a labelled diagram of the energy profiles of both
the catalysed and uncatalysed reaction of ammonia and oxygen. Indicate the
energy change and activation energy on your diagram.

[4]

NPSI/ Version1.0/23-24/Chem./10IG/03 Page No:1


NPS International School
(d) Explain how the use of a catalyst affects the rate of the reaction.

[3]

2 A series of experiments were carried out at room temperature to measure the rate of
production of carbon dioxide from the reaction of calcium carbonate powder with
hydrochloric acid solution. The experimental data is shown in the table below.

Volume of Volume of Concentration


Mass of CaCO3
Expt HCl used / water used / of acid used /
used / g
cm3 cm3 moldm-3
1 1.6 10 40 1.0
2 1.1 20 30 0.5
3 1.6 50 0 0.3

The results obtained for Experiment 2 are shown in the graph below.

Vol of CO2
in cm3
_

Time
(a) Calculate the number of moles of hydrochloric acid present in the acid used in
Experiments 1, 2 and 3. [1]

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NPS International School
(b) Calculate the number of moles of calcium carbonate used in Experiments 1
and 2. [1]

(c) Calculate the maximum volume of carbon dioxide, at room temperature and [1]
pressure, produced in each of the Experiments 1, 2 and 3.

(d) On the axes given in the previous page, draw and label the graph you would
expect for Experiments 1 & 3. [2]

(e) Explain the effect of using lumps of calcium carbonate, on the rate of reaction?

[3]

3 Two experiments were carried out using excess magnesium ribbon and a dilute acid.
In each case, the same mass of magnesium ribbon and the same volume of acid of
the same concentration was used. The acids were 1 mol/dm3 hydrochloric acid and
1 mol/dm3 ethanoic acid.

(a) Name three key apparatus that is needed to measure the speed of the reaction
between magnesium and hydrochloric acid.

[1]

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NPS International School
(b) Sketch and label, on the same axes, the two curves you would expect, that show
the rate of reaction of magnesium ribbon with the two different acids. [2]

(c) Account for and explain the differences between the two curves you have
drawn.

[3]

(d) Besides changing the concentration of the acid and the surface area of the
ribbons, suggest another change that can be made by which the rate of this
reaction between magnesium ribbon and acid could be increased. Use the
collision theory to explain how this factor would help to increase the rate of
the reaction.

[4]

(e) In another experiment, the same mass of magnesium was used to react with
the same volume of a strong acid, H2A. What concentration of acid H2A would
be required in order to obtain a similar curve to that given by magnesium
ribbon and 1 mol/dm3 hydrochloric acid?

[1]

NPSI/ Version1.0/23-24/Chem./10IG/03 Page No:4

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