2.2 Bonding and Structure QP
2.2 Bonding and Structure QP
2.2 Bonding and Structure QP
com
Q1.
This question is about Group 1 elements.
(a) Give two observations you could make when a small piece of potassium is
added to water.
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2 _________________________________________________________
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(2)
(b) Complete the equation for the reaction of potassium with water.
K + H 2O → +
(2)
(c) Explain why the reactivity of elements changes going down Group 1.
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(4)
Sodium reacts with oxygen to produce the ionic compound sodium oxide.
(d) Draw a dot and cross diagram to show what happens when atoms of
sodium and oxygen react to produce sodium oxide.
Diagram
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(4)
(e) Why is oxygen described as being reduced in the reaction between sodium
and oxygen?
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(3)
(Total 16 marks)
Q2.
This question is about metals.
A –117 79 No No
D 1610 2230 No No
A B C D
(1)
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(3)
(c) A student wants to compare the reactivity of an unknown metal, Q, with that
of zinc.
Describe a method the student could use to compare the reactivity of metal
Q with that of zinc.
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(4)
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(Total 8 marks)
Q3.
This question is about substances used to make windows and window frames.
Figure 1
Clay
Graphite
Limestone
Sodium carbonate
Sodium hydroxide
(2)
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The polymers poly(chloroethene) and HDPE are used to make window frames.
Table 1
Relative strength 72 25
Use Table 1.
Advantage __________________________________________________
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Reason ____________________________________________________
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(2)
Use Table 1.
Advantage __________________________________________________
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Reason ____________________________________________________
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(2)
Figure 2
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(1)
Test _______________________________________________________
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Result _____________________________________________________
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(2)
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Advantage of
polymers ________________________________________________
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Advantage of
wood ___________________________________________________
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(2)
Table 2
Element Mass in kg
Aluminium 5.94
Magnesium 0.04
Silicon 0.02
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(h) Why is an alloy used instead of pure aluminium to make window frames?
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(1)
(Total 14 marks)
Q4.
This question is about the elements in Group 7 of the periodic table.
Table 1 shows the melting points and boiling points of some of the elements.
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Table 1
Bromine –7 59
Use Table 1.
Gas
Liquid
Solid
(1)
Use Table 1.
Temperature = _______________ °C
(1)
_______________ .
(2)
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(1)
What happened to the mass of the glass tube and contents during the
reaction?
Reason
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(2)
The teacher repeated the investigation with bromine gas and with iodine gas.
Table 2
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Element Observation
Predict what you would observe when fluorine gas reacts with iron.
Use Table 2.
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(1)
(g) Balance the equation for the reaction between iron and bromine.
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Q5.
This question is about aluminium.
Draw one line from each property of aluminium to the correct reason for
that property.
Property Reason
Conducts
Aluminium has layers of atoms which can slide
electricity
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High melting
Aluminium has weak intermolecular forces
point
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(1)
How does this show that bauxite is a mixture and not a compound?
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(1)
(d) The waste material from the bauxite is stored in lakes of mud.
Suggest two possible problems with storing the waste material in lakes of
mud.
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2 _________________________________________________________
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(2)
(f) What is the reason for adding cryolite to the aluminium oxide?
(1)
When the molten aluminium oxide and cryolite mixture is electrolysed the
product at
This product reacts with the positive electrode because the positive
electrode is
made of _______________.
(2)
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Calculate the maximum mass of aluminium that can be extracted from 300
000 kg of the sample of bauxite.
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Q6.
This question is about structure and bonding.
Diamond
Magnesium
Poly(ethene)
Sodium chloride
Water
(2)
Compound Structure
Carbon dioxide
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Magnesium
oxide
Silicon dioxide
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(6)
(Total 8 marks)
Q7.
This question is about the halogens.
Table 1 shows the melting points and boiling points of some halogens.
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Table 1
Bromine –7 59
Gas Gas
Gas Liquid
Liquid Gas
Liquid Liquid
Solid Gas
Solid Liquid
(1)
(b) Explain the trend in boiling points of the halogens shown in Table 1.
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(4)
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(c) Why is it not correct to say that the boiling point of a single bromine
molecule is 59 °C?
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(1)
(d) Give one reason why this experiment should be done in a fume cupboard.
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(1)
(e) Explain why the reactivity of the halogens decreases going down the
group.
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(3)
(f) A teacher investigated the reaction of iron with chlorine using the apparatus
in the above diagram.
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Table 2
Mass in g
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Q8.
This question is about alloys.
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Aluminium
Tin
Zinc
(1)
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(1)
The table below shows information about two gold rings, A and B.
A 7 7
B 18 9
(2)
(d) Suggest two reasons why alloys of gold are used instead of pure gold to
make jewellery.
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2 _________________________________________________________
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(2)
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Spoons:
• are washed after use
• must not wear away quickly.
Suggest one reason why stainless steel is suitable for making spoons.
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(1)
Stainless steel
(1)
(Total 8 marks)
Q9.
This question is about materials used to make plates.
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(1)
Forming a composite
Heating in a furnace
(2)
(d) The alkene needed to make poly(propene) is produced from crude oil.
Which two processes are used to produce this alkene from crude oil?
Chromatography
Cracking
Fermentation
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Fractional distillation
Quarrying
(2)
Covalent
Ionic
Metallic
(1)
The table below shows information about two polymers used to make plates.
B melts at 50 °C
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(Total 10 marks)
Q10.
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(a) Complete the dot and cross diagram for the ammonia molecule shown in
Figure 1.
Figure 1
(2)
(b) Give one limitation of using a dot and cross diagram to represent an
ammonia molecule.
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(3)
(d) Which metal oxide is most likely to be a catalyst for this reaction?
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CaO
Cr2O3
MgO
Na2O
(1)
Figure 2
Bond
Bond energy in
391 498 945 464
kJ/mol
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(f) Explain why the reaction between ammonia and oxygen is exothermic.
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(2)
(g) Figure 3 shows the reaction profile for the reaction between ammonia and
oxygen.
• activation energy
• overall energy change.
Figure 3
(2)
(Total 14 marks)
Q11.
This question is about mixtures.
Draw one line from each substance and mixture to the best method of
separation.
Chromatography
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Fractional distillation
(3)
Figure 1
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Figure 2
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(d) Calculate the percentage of metal B atoms in the mixture of metals shown
in Figure 2.
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An alloy
A compound
A molecule
A polymer
(1)
(f) Why is the mixture of metals in Figure 2 harder than the pure metal?
(1)
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Figure 3
20 nm3
60 nm3
400 nm3
8000 nm3
(1)
(Total 11 marks)
Q12.
This question is about Group 7 elements.
(a) Name the products formed when chlorine solution reacts with potassium
iodide solution.
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(1)
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(3)
The diagram below shows the displayed formulae for the reaction of
bromine with methane.
The table below shows the bond energies and the overall energy change in
the reaction.
Overall
C—H Br—Br C—Br H—Br energy
change
Energy in
412 193 X 366 −51
kJ/mol
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Q13.
This question is about alloys of copper.
The table shows the percentage by mass of copper and zinc in two types of
brass.
Red brass 90 10
Yellow brass X 30
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Mass = ____________________ g
(2)
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(1)
(e) Brass contains layers of atoms which can slide over each other.
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9 18 22 24
(1)
(Total 8 marks)
Q14.
This question is about different substances and their structures.
(a) Draw one line from each statement to the diagram which shows the
structure.
Statement Structure
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(4)
Figure 1
Carbon
Chloride
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Nitrogen
Xenon
(1)
(1)
Figure 2
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Compound
Element
Mixture
(1)
(Total 11 marks)
Q15.
Figure 1 shows the outer electrons in an atom of the Group 1 element potassium
and in an atom of the Group 6 element sulfur.
Figure 1
Describe what happens when two atoms of potassium react with one atom
of sulfur.
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(5)
(b) The structure of potassium sulfide can be represented using the ball and
stick model in Figure 2.
Figure 2
The ball and stick model is not a true representation of the structure of
potassium sulfide.
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(1)
Complete the dot and cross diagram to show the covalent bonding in a
molecule of hydrogen sulfide.
(2)
(d) Calculate the relative formula mass (Mr) of aluminium sulfate Al2(SO4)3
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(e) Covalent compounds such as hydrogen sulfide have low melting points
and do not conduct electricity when molten.
Draw one line from each property to the explanation of the property.
Explanation
Property
of property
There are no
charged particles
free to move
Weak intermolecular
forces of attraction
(2)
(f) Ionic compounds such as potassium sulfide have high boiling points and
conduct electricity when dissolved in water.
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Draw one line from each property to the explanation of the property.
Explanation
Property
of property
There are no
charged particles
free to move
Weak intermolecular
forces of attraction
Conduct electricity
when molten
(2)
(Total 14 marks)
Q16.
This question is about substances containing carbon atoms.
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© Kershawj/iStock
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Use the correct answer from the box to complete the sentence.
Covalent
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Ionic
Metallic
(1)
(ii) How many carbon atoms does each carbon atom bond to in
graphite?
(1)
Dissolves in water
(1)
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are no _______________________ .
(1)
(ii) Use the correct answer from the box to complete the sentence.
_____________________ .
(1)
1.
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2.
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(2)
C4H
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CH4
C4H4
(1)
Charged ions
A giant lattice
Small molecules
(1)
(Total 11 marks)
Q17.
This question is about zinc.
(b) Zinc ions move towards the negative electrode where they gain electrons
to produce zinc.
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____________________________________
(1)
(ii) Explain why zinc ions move towards the negative electrode.
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(2)
(iii) What type of reaction occurs when the zinc ions gain electrons?
Neutralisation
Oxidation
Reduction
(1)
(i) Figure 2 shows the particles in the alloy and in pure zinc.
Use Figure 2 to explain why the alloy is harder than pure zinc.
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(2)
(ii) Alloys can be bent. Some alloys return to their original shape when
heated.
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(1)
(Total 8 marks)
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