Atomic Structure Part 6
Atomic Structure Part 6
Atomic Structure Part 6
Q1.
(a) The electronic structure of a sodium atom can be written 2,8,1.
Write the electronic structure of a potassium atom in the same way.
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(1)
(b) The electronic structure of a sodium atom can also be represented as in the
diagram below.
(ii) Draw similar diagrams to show the electronic structure of the particles in
sodium fluoride.
(4)
(Total 5 marks)
Q2.
(a) Why do the elements in Group 1 of the Periodic Table have similar chemical
properties?
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(1)
(b) Explain why the reactivity of the elements in Group 1 increases down the group.
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(2)
(Total 3 marks)
Q3.
The following passage was taken from a chemistry textbook.
Germanium is a white, shiny, brittle element. It is used in the electronics industry because
it is able to conduct a small amount of electricity.
It is made from germanium oxide obtained from flue dusts of zinc and lead smelters.
The impure germanium oxide from the flue dusts is changed into germanium by the
process outlined below.
(a) Balance the equation below which represents the reaction in step 1.
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(1)
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(1)
(d) The equation which represents the reaction in step 4 is shown below.
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(1)
(ii) Calculate the mass of germanium which could be made from 525 g of
germanium oxide. (Relative atomic masses: Ge = 73; O = 16).
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Mass _____________________ g
(3)
(i) Give as much evidence as you can from the information in this question to
support the view that germanium is a metal. Explain your answer as fully as
you can.
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(3)
(ii) Give as much evidence as you can from the information in this question to
support the view that germanium is a non-metal. Explain your answer as fully
as you can.
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(3)
(Total 13 marks)
Q4.
(a) The list below gives six substances.
• aluminium
• beer
• copper
• milk
• pure water
• sodium chloride
(3)
(b) Elements can be divided into two groups, metals and non-metals.
• brittle
• dull
• shiny
(3)
(Total 6 marks)
Q5.
Sando-K is a medicine. It is given to people whose bodies contain too little of a particular
element.
Sando-K is a mixture of two compounds. The formulae of the two compounds are given
below.
KHCO3 KCl
(a) Use the Data Sheet to help you to name all the elements in these compounds.
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(3)
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(1)
(Total 4 marks)
Q6.
The table shows the % composition by mass of modern British coins.
% COMPOSITION BY MASS
COIN
copper nickel tin zinc
70 5.5 – 24.5
£1
84 16 – –
20p
97 – 0.5 2.5
1p &2p (until 1991)
(a) Use the Data Sheet to help you to complete the table by filling in the information
about 5p, 10p and 50p coins which are made of cupronickel.
(1)
(1)
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(1)
______________________________________________________________
(1)
• bends easily
• hard
• unreactive
From this list, choose two properties which coinage metals should have. For each
property, give a reason for your answer.
Property 1 __________________________________________________________
Reason ____________________________________________________________
Property 2 __________________________________________________________
Reason ____________________________________________________________
(2)
(Total 6 marks)
Q7.
Sando-K is a medicine. It is given to people whose bodies contain too little of a particular
element.
Sando-K is a mixture of two compounds. The formulae of the two compounds are given
below.
KHCO3 KC1
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(1)
(b) Sando-K contains the ion, CO32–. Which gas would be produced if a dilute acid was
added to Sando-K? (The Data Sheet may help you to answer this question.)
___________________________________________________________________
(1)
_______________________________ .
more __________________________ .
(4)
(d) Electricity can be used to show that an aqueous solution of Sando-K contains ions.
(i) Draw a diagram of an apparatus that you could use to prove that Sando-K
contains ions.
(4)
(ii) Explain, as fully as you can, what would happen when the electricity is
switched on.
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(3)
(Total 13 marks)
Q8.
Calcium and magnesium are elements. They are found in the Earth’s crust as
compounds, often carbonates and sulphates. Magnesium is also found as its chloride.
(a) Calcium and magnesium are in the same Group in the Periodic Table.
State which Group this is.
___________________________________________________________________
(1)
(b) Use the Data Sheet to help you to answer this question.
______________________________________________________________
(1)
Q9.
Sulphur hexafluoride is a colourless, odourless, non-flammable gas, which is insoluble in
water and extremely unreactive. It is used as an insulator in high voltage transformers
and switchgear.
(a) What type of chemical bond holds the sulphur and fluorine atoms together in
sulphur hexafluoride molecules?
___________________________________________________________________
(1)
___________________________________________________________________
___________________________________________________________________
(2)
(c) Explain how three of the properties of sulphur hexafluoride make it suitable for use
as an insulator inside electrical transformers.
Property 1: _________________________________________________________
Explanation: ________________________________________________________
__________________________________________________________________
Property 2: _________________________________________________________
Explanation: ________________________________________________________
__________________________________________________________________
Property 3: _________________________________________________________
Explanation: ________________________________________________________
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(3)
(Total 6 marks)
Q10.
The diagram represents an atom. Choose words from the list to label the diagram.
electron ion neutron nucleus
(Total 3 marks)
Q11.
Use these relative atomic masses: H = 1; O = 16; Ca = 40
to calculate the relative formula mass (Mr ) of
Q12.
One definition of an element is:
“A substance that cannot be broken down into simpler substances by chemical methods”
The table below shows some of the ‘substances’ which Antoine Lavoisier thought were
elements. He divided the ‘substances’ into four groups. He published these groups in
1789.
magnesia
phosphorus caloric copper nickel (magnesium oxide)
(heat)
barytes
oxygen gold platina (barium sulphate)
charcoal (platinum)
(carbon) argilla
(aluminium oxide)
azote iron silver
(nitrogen)
silex
hydrogen (silicon dioxide)
lead tin
magnese tungsten
zinc
(a) Name one ‘substance’ in the list which is not a chemical element or compound.
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(1)
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(1)
(ii) Suggest why Lavoisier thought that this substance was an element.
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(1)
(Total 3 marks)
Q13.
X is an element with the following properties:
• forms ionic salts with metals in which its ion has a 1–charge.
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(1)
(b) Predict the formula of the product formed when X reacts with aluminium.
(The aluminium ion is Al3+ and the X ion is X–.)
Select your answer from the list below.
AlX AlX2 AlX3 Al3X Al2X3
(c) To which Group of the Periodic Table does the element X belong?
___________________________________________________________________
(1)
(Total 3 marks)
Q14.
Sodium and potassium are both in Group 1 of the Periodic Table.
(a) Explain, by reference to their electronic structures, why both elements are placed in
Group 1.
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___________________________________________________________________
(1)
(b) Use the Data Sheet to help you to answer this question.
The diagrams below represent the electronic structures of some atoms and ions.
(i) The word equation represents the reaction of sodium with water.
sodium + water → sodium hydroxide + hydrogen
(ii) How does the reactivity of potassium with water differ from that of sodium
with water?
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(4)
(Total 9 marks)
Q15.
One definition of an element is:
“A substance that cannot be broken down into simpler substances by chemical methods”
The table below shows some of the ‘substances’ which Antoine Lavoisier thought were
elements. He divided the ‘substances’ into four groups. He published these groups in
1789.
magnesia
phosphorus caloric copper nickel (magnesium oxide)
(heat)
barytes
oxygen gold platina (barium sulphate)
charcoal (platinum)
(carbon) argilla
iron silver (aluminium oxide)
azote
(nitrogen) silex
lead tin (silicon dioxide)
hydrogen
magnese tungsten
zinc
Dmitri Mendeleev devised a Periodic Table of the elements in 1869. A modern version of
this table is shown on the Data Sheet.
Give two ways in which Mendeleev’s table is more useful than Lavoisier’s.
1. _____________________________________________________________________
_______________________________________________________________________
2. _____________________________________________________________________
_______________________________________________________________________
(Total 2 marks)
Q16.
Ammonia is a very important chemical.
(a) The table shows the percentage of ammonia used to make different substances.
fertilisers 75
nitric acid 10
nylon 5
others 10
Shade on the pie chart the percentage of ammonia used to make nitric acid.
(1)
(b) Ammonia gas is made by the reaction between nitrogen gas and hydrogen gas.
Write a word equation to represent this reaction.
(1)
(i) Use the Data Sheet to help you answer this question.
Name the elements in the compound NH4NO3.
1. ____________________________________________________________
2. ____________________________________________________________
3. ____________________________________________________________
(2)
(ii) Use the Data Sheet to help you answer this question.
Name the compound KCl.
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(1)
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(1)
(ii) Use your answer to part (f)(i) to help you calculate the percentage by mass of
nitrogen present in ammonium nitrate NH4NO3.
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(2)
(Total 9 marks)
Q17.
Use the Data Sheet to help you answer this question.
Q18.
Part of the Periodic Table which Mendeleev published in 1869 is shown below.
Use the Data Sheet to help you to answer this question.
(a) (i) Give the symbols of two elements in Group 1 of Mendeleev’s Periodic Table
which are not found in Group 1 of the modern Periodic Table.
(b) Which group of elements in the modern Periodic Table is missing on Mendeleev’s
table?
___________________________________________________________________
(1)
(c) Mendeleev left several gaps in his Periodic Table. These gaps are shown as
asterisks(*) on the table above.
Suggest why Mendeleev left these gaps.
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___________________________________________________________________
___________________________________________________________________
(1)
In the modern Periodic Table the elements are arranged in the order of their
____________________ numbers.
(1)
(e) Mendeleev placed lithium, sodium and potassium in Group 1 of his Periodic Table.
This was because they have similar properties.
Some properties of elements are given in the table.
Four of them are properties of lithium, sodium and potassium. One of these
properties has been ticked for you. Place a tick next to the other three properties.
PROPERTY
(f) What happens when a small piece of sodium reacts with water?
You should describe what you would see and state what substances are formed.
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(3)
(Total 12 marks)
Q19.
Part of the Periodic Table which Mendeleev published in 1869 is shown below.
(b) Which group of elements in the modern Periodic Table is missing on Mendeleev’s
table?
___________________________________________________________________
(1)
(c) Mendeleev left several gaps in his Periodic Table. These gaps are shown as
asterisks(*) on the table above.
Suggest why Mendeleev left these gaps.
___________________________________________________________________
___________________________________________________________________
___________________________________________________________________
(1)
In the modern Periodic Table the elements are arranged in the order of their
____________________ numbers.
(1)
(Total 5 marks)
Q20.
(a) What is the name given to the block of elements in the middle of the Periodic Table
which includes vanadium?
___________________________________________________________________
(1)
• It is a conductor of electricity.
Select two properties, from the list above, which are not typical of a Group 1 metal.
1. _________________________________________________________________
2. _________________________________________________________________
(2)
(Total 3 marks)
Q21.
In sea water the bromine is present as bromide ions (Br–). The equation below shows how
chlorine can be used to displace bromine from sea water.
Explain, as fully as you can, why chlorine can displace bromine from sea water.
To obtain full marks your answer should refer to electronic structure.
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(Total 3 marks)
Q22.
The graph shows the melting point of four elements in Group 7 of the periodic table.
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(1)
Using data from the graph, describe the trend of melting points of the elements in
Group 7.
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(2)
(2)
(Total 6 marks)
Q23.
The periodic table on the Data Sheet might help you to answer this question.
Complete the table to give the name and the formula of each of the molecules A – D.
The first one has been done for you.
A Hydrogen H2
D
(Total 6 marks)
Q24.
The elements in Group 1 are known as the alkali metals.
Low density
Used as catalysts
(Total 3 marks)
Q25.
Use the periodic table on the Data Sheet to answer these questions.
The table below gives the electronic structures of four elements, W, X, Y and Z.
W 2,5
X 2,7
Y 2,8,8
Z 2,8,8,1
(b) Which two Groups of the periodic table do not contain any non-metals?
___________________________________________________________________
(1)
(Total 4 marks)
Q26.
(a) You may find the Data Sheet helpful to complete the word equation.
2H2 + O2 → 2H2O
(b) Complete this sentence by crossing out the two words in the box that are wrong.
Q27.
Beryllium and calcium are metals in Group 2 of the periodic table.
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(1)
Suggest an explanation for this in terms of the electronic structure of the two
elements.
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(2)
(Total 3 marks)
Q28.
(a) Helium is used to fill party balloons.
Which two of the following are properties that make helium suitable for filling party
balloons?
Coloured
Very unreactive
(2)
Use the correct formulae from the box to complete the table. The first one has been
done for you.
Gas Formula
Oxygen O2
Carbon dioxide
Hydrogen chloride
Ammonia
(3)
(Total 5 marks)
Q29.
Use the Periodic Table of Elements on the Data Sheet to help you to answer this
question.
(a) Describe, in as much detail as you can, the structure of a fluorine atom.
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(3)
(b) Complete the diagram to show the electronic structure of a magnesium atom.
(1)
(Total 4 marks)
Q30.
Use the Periodic Table of Elements on the Data Sheet to help you to answer this
question.
Francium (Fr) is a very rare element. It is estimated that there is only 25 g of francium in
the Earth’s crust. Francium is radioactive and has a half-life of only a few minutes.
Mendeleev predicted the existence of francium in the 1870s but the element was not
discovered
until 1939.
(a) Explain why Mendeleev was able to predict the existence of francium in the 1870s.
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(2)
(b) Suggest why there is not much experimental evidence for the properties of
francium.
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(1)
(c) (i) If you could react francium with water, how would the reaction compare with
that of sodium with water?
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(1)
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(2)
(Total 6 marks)
Q31.
Use the periodic table on the Data Sheet to help you to answer these questions.
___________________________________________________________________
(1)
___________________________________________________________________
(1)
(c) Write the name of the element which has a relative atomic mass of 64.
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(1)
(d) Write the name of the element with the next highest atomic number after Te
(tellurium) in the periodic table.
___________________________________________________________________
(1)
(Total 4 marks)
Q32.
The diagram shows an atom.
(b) To which Group of the periodic table does this atom belong?
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___________________________________________________________________
___________________________________________________________________
(2)
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(1)
(Total 7 marks)
Q33.
The table shows some properties of four Group 7 elements.
Explosive
Hydrogen
Chlorine – 34 – 101 gas reaction in
chloride
sunlight
___________________________________________________________________
(1)
(c) Name the compound formed when hydrogen reacts with bromine.
___________________________________________________________________
(1)
(Total 4 marks)
Q34.
Ammonium chloride, NH4Cl, is made up of nitrogen, hydrogen and chlorine atoms.
(i) Complete the table to show the number of atoms of each element present in NH4Cl.
Number of atoms in
Element
NH4Cl
nitrogen 1
hydrogen
chlorine
(1)
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Relative formula mass = _________________________
(2)
(Total 3 marks)
Q35.
The table shows how Group 7 elements react with hydrogen.
Explosive reaction in
Fluorine Hydrogen fluoride
dim light
Explosive reaction in
Chlorine Hydrogen chloride
sunlight
Reacts if heated
Iodine Hydrogen iodine
strongly
Explain the difference in the rates of the reaction of fluorine with hydrogen and of iodine
with hydrogen.
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(Total 2 marks)
Q36.
John Newland produced a periodic table in 1866. The first 21 elements in his table are
shown in the diagram.
Column
1 2 3 4 5 6 7
H Li Be B C N O
F Na Mg Al Si P S
Cl K Ca Cr Ti Mn Fe
Use the periodic table on the Data Sheet to help you to answer these questions.
(a) In which two columns of Newland’s periodic table do all the elements have similar
properties?
___________________________________________________________________
(1)
(b) The modern periodic table is arranged in a different order to Newland’s table.
______________________________________________________________
(1)
(ii) Argon has a higher relative atomic mass than potassium. Explain why.
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______________________________________________________________
(1)
(iii) Describe the changes in the number of electrons in the atoms of elements in
the period which begins with potassium and ends with krypton.
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______________________________________________________________
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(2)
(Total 5 marks)
Q37.
The table gives some properties of the element silicon.
(a) Give two ways in which silicon is similar to the alkali metals.
1. _________________________________________________________________
___________________________________________________________________
2. _________________________________________________________________
___________________________________________________________________
(2)
(b) Give two ways in which the properties of silicon are different from those of the alkali
metals.
1. _________________________________________________________________
___________________________________________________________________
2. _________________________________________________________________
___________________________________________________________________
(2)
(Total 4 marks)
Q38.
Use the periodic table on the Data Sheet to help you to answer these questions.
___________________________________________________________________
(1)
___________________________________________________________________
(1)
(c) Write the name of the element which has a relative atomic mass of 64.
___________________________________________________________________
(1)
(d) Write the name of the element with the next highest atomic number after Te
(tellurium) in the periodic table.
___________________________________________________________________
(1)
(Total 4 marks)
Q39.
(a) The table shows how Group 7 elements react with hydrogen.
Description Product
Explosive reaction in
Fluorine Hydrogen fluoride
dim light
Explosive reaction in
Chlorine Hydrogen chloride
sunlight
(i) Explain why all the Group 7 elements react in a similar way with hydrogen.
______________________________________________________________
______________________________________________________________
______________________________________________________________
______________________________________________________________
(2)
(ii) Explain the difference in the rates of the reaction of fluorine with hydrogen,
and of iodine with hydrogen.
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______________________________________________________________
______________________________________________________________
(2)
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(2)
(Total 6 marks)
Q40.
Part of the Periodic Table is shown. It includes the symbols for six elements.
(b) (i) Put the symbol Cl, for chlorine, into its correct position in the Table.
(1)
(ii) Bromine, chlorine, fluorine and iodine are halogens. Which one of these
halogens is least reactive?
______________________________________________________________
(1)
(c) The alkali metals form Group 1 in the Periodic Table. Write the symbol of the most
reactive alkali metal shown in the Table above.
___________________________________________________________________
(1)
(d) Write the symbol for an element which is in the same Group as sodium.
___________________________________________________________________
(1)
(Total 5 marks)
Q41.
Electrons, neutrons and protons are sub-atomic particles.
____________________ 1 ____________________
____________________ ____________________ 0
____________________ _____________________
(3)
(b) An aluminium atom has 13 electrons. How are these arranged in shells around the
nucleus?
___________________________________________________________________
(1)
(i) How many electrons does each neutral chromium atom have?
______________________________________________________________
(1)
______________________________________________________________
(1)
(d) What change occurs to an atom which undergoes the process of reduction in a
chemical reaction?
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(1)
(e) The diagram shows part of the ionic lattice of a sodium chloride crystal.
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(3)
(Total 10 marks)
Q42.
(a) Choose from the names of elements in the box the answers to the questions which
follow.
______________________________________________________________
(1)
(ii) a halogen
______________________________________________________________
(1)
(iii) a noble gas
______________________________________________________________
(1)
(b) The alkali metals are in Group 1 of the Periodic Table. The elements in Group 1
have a number of similar properties.
______________________________________________________________
(1)
______________________________________________________________
(1)
(Total 5 marks)
Q43.
(a) Atoms are made of sub-atomic particles. Complete the six spaces in the table.
_________________ ___________
_________________ 1 ____________
(3)
(ii) The mass number of an atom is the total number of _________________ and
(c) The table gives information about the atoms of three elements.
Neon Ne 2 8 0
Sodium Na 2 8 1
______________________________________________________________
(1)
(iii) Explain, in terms of electron transfer, how the bonding occurs in this
compound.
______________________________________________________________
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______________________________________________________________
(2)
(Total 10 marks)
Q44.
Part of the Periodic Table is shown below. Use the information to help you answer the
questions which follow.
(b) (i) What is the symbol of the element which is in Group 2 and Period 3?
____________
______________________________________________________________
(2)
___________________________________________________________________
(1)
(e) What is the name of the uncharged particle in the nucleus of an atom?
___________________________________________________________________
(1)
(Total 8 marks)
Q45.
The word box contains the names of some metals.
(i) The drawing shows the view from a window. Choose from the names of metals in
the box to complete the three spaces.
(3)
(ii) What is the name of the metal in the word box which has the chemical symbol Fe?
___________________________________________________________________
(1)
(iii) What is the name of one metal in the word box which often has coloured
compounds?
___________________________________________________________________
(1)
(Total 5 marks)