IB Chemistry Definitions SL/HL
IB Chemistry Definitions SL/HL
IB Chemistry Definitions SL/HL
com
Relative
molecular
mass
(Mr)
-‐
The
relative
molecular
mass
of
a
substance
is
the
mass
of
one
molecule
of
that
substance
relative
to
1/12
of
the
mass
of
carbon
–
12
atom.
Mass Number -‐ The sum of the protons and neutrons in the nucleus of the atom or ion.
Atomic Number -‐ is equal to the number of protons in the nucleus of an atom.
Isotope -‐ are atoms of the same element with different numbers of neutrons.
1st
Ionisation
Energy
-‐
The minimum energy required to remove one mole of electrons from an
atom in its gaseous state.
Electronegativity
-‐
Electronegativity
is
a
measure
of
the
tendency
of
an
atom
in
a
molecule
to
attract
a
bonding
pair
of
electrons
towards
itself.
Ligand
-‐
An
atom,
ion
or
molecule
that can donate a pair of electrons to a central metal ion to
form a dative covalent (coordinate) bond. (Ligands are Lewis bases)
Exothermic
Reaction
-‐
An exothermic reaction is one that releases heat to the surroundings. (As
a result of forming products with stronger bonds than the reactants. Exothermic reactions have
negative ∆H values.)
Endothermic
Reaction
-‐
An
endothermic
reaction
is
one
that
absorbs
heat
from
its
surroundings.
(As a result of forming products with weaker bonds than the reactants.
Endothermic reactions have positive ∆H values.)
Standard state The standard state of an element or compound is its most stable state
under the specified conditions.
Standard Conditions -‐ Temperature = 298K, Pressure = 1atm & solutions 1 mol dm-‐3.
Standard
enthalpy
change
of
a
reaction
-‐
The standard enthalpy change (ΔH θ) is the heat
energy transferred under standard conditions (pressure 101.3 kPa, temperature 298 K) for a
reaction.
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Average
Bond
Enthalpy
-‐
This is the energy required to break one mole of the same type of
bond in the gaseous state averaged over a variety of similar compounds.
Standard
enthalpy
change
of
Formation
-‐
The
enthalpy
change
when
1
mole
of
a
substance
is
formed
from
its
elements
in
their
standard
states,
under
standard
conditions.
Standard
enthalpy
change
of
Combustion
-‐
the
enthalpy
change
when
1
mole
of
a
substance
in
its
standard
states
burns
completely
in
excess
oxygen
under
standard
conditions.
Lattice
Enthalpy
-‐
the amount of energy required to separate one mole of ionic compound into
isolated gaseous ions under standard conditions.
Electron
Affinity
-‐
the
energy
change
when
1
mole
of
gaseous
atom
gains
1
mole
of
electron
to
form
a
gaseous
ion,
under
standard
conditions
(technically,
this
should
be
called
the
1st
electron
affinity)
Rate
of
Reaction
-‐
The increase in concentration of products or the decrease in concentration of
reactants per unit time.
Activation Energy -‐ The minimum energy needed (by reactants) to start/initiate a reaction.
Bronsted Lowry Acid -‐ An acid is a proton (hydrogen ion) donor.
Bronsted Lowry Base -‐ A base is a proton (hydrogen ion) acceptor.
Lewis Acid -‐ An acid is an electron pair acceptor.
Oxidation -‐ The loss of electrons from a species during a chemical reaction.
Oxidising
Agent
-‐
A species that brings about oxidation by removing electrons from another
reactant. During the reaction the oxidizing agent gains electrons and so is reduced.
Reducing
Agent
-‐
A species that brings about reduction by giving electrons to another reactant.
During the reaction the reducing agent loses electrons and so is oxidized.
Standard
Electrode
Potential
-‐
This is the electrode potential of a half-cell relative to the
hydrogen half-cell, which is assigned a value of zero. It is measured at standard conditions. (Also
known as standard reduction potential)