Environmental-protection type gypsum-

based putty powder for building

CN1454945A
China

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Other languages: Chinese

Inventor: 彭家惠, 陈明凤, 张建新, 彭志辉, 万体智, 瞿⾦东

Worldwide applications

2003 CN

Application CN 03117999 events

2003-05-30 Application filed by 重庆⼤学

2003-05-30 Priority to CN 03117999

2003-11-12 Publication of CN1454945A

2005-11-09 Application granted

2005-11-09 Publication of CN1226357C

Info: Cited by (22), Legal events, Similar documents,

Priority and Related Applications

External links: Espacenet, Global Dossier, Discuss

Abstract

The present invention relates to an environment-

protecting gypsum base building putty powder,
which uses building gupsum as main setting
hardening component, and utilizes the
composite retarding agent to resolve the
problems of that the building gupsum can be
quickly set and hardened and single retarding
agent can be resulted into large strength loss.
Said invention adopts inorganic mineral powder
and cellulose ether composition to reduce
material cost and improve water-holding property
of putty, and adopts water-soluble adhesive
powder to raise cohesional strength of building
putty, and said environment-protecting type
gypsum base building putty powder is a single
component solid powder, has no harmful
substance, and has good construction property,
and said putty surface is fine and smooth

Claims (10) Hide Dependent

1. environment-friendly type gypsum-based

construction putty powder is characterized in that this
environment-friendly type gypsum-based construction
putty powder comprises following component and
weight percent:

Plaster of Paris 60-85

Compound retarder 0.15-0.5

Compound water retaining agent 3.05-10.2

Water-soluble gelatin powder 0.1-3

Filler 5-30

Wherein, plaster of Paris is a kind of in the following

plaster of Paris: the plaster of Paris of the plaster of
Paris of plaster of paris preparation, phosphogypsum
preparation, the plaster of Paris of desulfurated plaster
preparation; Compound retarder is citric acid and
gelatine; Compound water retaining agent is a kind of
and wilkinite in methyl cellulose ether, TYLOSE 30000,
the hydroxypropyl methyl cellulose ether; Water-soluble
gelatin powder is a kind of in the following water-soluble
gelatin powder: modified tapioca starch, ethene-vinyl
acetate emulsion copolymer powder, polyvinyl alcohol
rubber powder, polyacrylic ester latex powder; Filler is a
kind of in the following filler: talcum powder, dry powder.

2. environment-friendly type gypsum-based

construction putty powder as claimed in claim 1
is characterized in that the component and the
weight percent of compound retarder:

Citric acid 0.05-0.2

Gelatine 0.1-0.3.
3. environment-friendly type gypsum-based
construction putty powder as claimed in claim 1
is characterized in that the component and the
weight percent of compound water retaining
agent: methyl cellulose ether or TYLOSE 30000
or hydroxypropyl methyl cellulose ether 0.05-0.2

Wilkinite 3-10.

4. as claim 1 or claim 2 or the described

environment-friendly type gypsum-based
construction of claim 3 putty powder, it is
characterized in that the concrete component
and the weight percent of this environment-
friendly type gypsum-based construction putty
powder:

Plaster of Paris 68.96

Citric acid 0.1

Gelatine 0.2

Methyl cellulose ether 0.1

Wilkinite 4

Ethene-vinyl acetate emulsion copolymer powder

0.25

Dry powder 26.39.

5. as claim 1 or claim 2 or the described

environment-friendly type gypsum-based
construction of claim 3 putty powder, it is
characterized in that the concrete component
and the weight percent of this environment-
friendly type gypsum-based construction putty
powder:

Plaster of Paris 77.3

Citric acid 0.15

Gelatine 0.1

Hydroxypropyl methyl cellulose ether 0.2

Wilkinite 5.7

Polyvinyl alcohol rubber powder 0.85

Talcum powder 15.7.

6. as claim 1 or claim 2 or the described
environment-friendly type gypsum-based
construction of claim 3 putty powder, it is
characterized in that the concrete component
and the weight percent of this environment-
friendly type gypsum-based construction putty
powder:

Plaster of Paris 85

Citric acid 0.1

Gelatine 0.2

TYLOSE 30000 0.1

Wilkinite 6.25

Ethene-vinyl acetate emulsion copolymer powder

0.25

Dry powder 8.1.

7. as claim 1 or claim 2 or the described

environment-friendly type gypsum-based
construction of claim 3 putty powder, it is
characterized in that the concrete component
and the weight percent of this environment-
friendly type gypsum-based construction putty
powder:

Plaster of Paris 60

Citric acid 0.05

Gelatine 0.25

Wilkinite 8

Methyl cellulose ether 0.05

Modified tapioca starch 2.5

Talcum powder 29.15.

8. as claim 1 or claim 2 or the described

environment-friendly type gypsum-based
construction of claim 3 putty powder, it is
characterized in that the concrete component
and the weight percent of this environment-
friendly type gypsum-based construction putty
powder:

Plaster of Paris 81.5

Citric acid 0.2

Gelatine 0.1

Hydroxypropyl methyl cellulose ether 0.2

Wilkinite 3

Modified tapioca starch 2.5

Dry powder 12.5.

9. as claim 1 or claim 2 or the described

environment-friendly type gypsum-based
construction of claim 3 putty powder, it is
characterized in that the concrete component
and the weight percent of this environment-
friendly type gypsum-based construction putty
powder:

Plaster of Paris 65

Citric acid 0.1

Gelatine 0.1

Methyl cellulose ether 0.05

Wilkinite 10

Polyvinyl alcohol rubber powder 1

Talcum powder 23.75.

10. as claim 1 or claim 2 or the described

environment-friendly type gypsum-based
construction of claim 3 putty powder, it is
characterized in that the concrete component
and the weight percent of this environment-
friendly type gypsum-based construction putty
powder:

Plaster of Paris 71.39

Citric acid 0.05

Gelatine 0.25

TYLOSE 30000 0.2

Wilkinite 7.45

Ethene-vinyl acetate latex powder 0.1

Talcum powder 20.56.

Description

Environment-friendly type gypsum-based

construction putty powder

Technical field:

The invention belongs to material of

construction, it is as inner wall of building putty.

Background technology:

Traditional architecture putty is filler with

inorganic inert mineral mainly, is filmogen with
the organic polymer material, and the putty
completion of cure relies on polymer film
forming.Such building putties cohesive strength
is lower, shrinks greatlyyer, generally only is
suitable for constructing on more smooth
metope, if thickness is excessive, then easy to
crack; Operating efficiency is low, and is dry slow,
long construction period; Preparation is at the
construction field (site) used inconvenient;
Construction of the putty that has and toxic
substance such as release formaldehyde
between the usage period, construction
environment is abominable, and environmental
pollution is big.And traditional architecture putty
usually adopts single water-holding agent
technology, i.e. ether of cellulose water
conservation, and its cost is higher.Consider that
plaster of Paris has hydration activity, fast
solidifying, cohesive strength height, good, the
exquisite in texture of volume stability, satisfy the
basic demand of building putties to wood
property, and it is affine harmless to human body,
be green building material, the contriver is under
the subsidy of National Natural Science
Foundation of China and Chongqing City Science
﹠. Technology Commision (subsidize item
number is respectively 50078055,2000-6375),
with the plaster of Paris is main raw material, is
that research emphasis has been carried out
experimental study with putty workability, water-
retentivity, cohesiveness.Adopt the main setting
and harden component of plaster of Paris as
building putty powder, break through traditional
architecture putty and relied on the technology
mode that adds inorganic inert filler in the
organic polymer filmogen, and on " New Building
Materials " the 1st phase in 2002, delivered paper
" prescription and the performance study of putty
built in phosphogypsum capital construction ",
this article has highlighted the part achievement
of this research.

The production technique that the present

invention adopts is a common process.

Summary of the invention:

The objective of the invention is to avoid above-

mentioned the deficiencies in the prior art part
and provide a kind of and do not contain Toxic
matter, have good workability, short construction
period, cohesive strength height, water-
retentivity, the fine and smooth slick
environment-friendly type gypsum-based
construction putty powder in putty surface.

In order to realize the foregoing invention

purpose, technical scheme of the present
invention is:

Prepared environment-friendly type gypsum-

based construction putty powder, it comprises
following component and weight percent:

Plaster of Paris 60-85

Compound retarder 0.15-0.5

Compound water retaining agent 3.05-10.2

Water-soluble gelatin powder 0.1-3

Filler 5-30

Wherein, plaster of Paris is a kind of in the

following plaster of Paris: the plaster of Paris of
the plaster of Paris of plaster of paris
preparation, phosphogypsum preparation, the
plaster of Paris of desulfurated plaster
preparation; Water-soluble gelatin powder is a
kind of in the following water-soluble gelatin
powder: modified tapioca starch, polyvinyl
alcohol rubber powder, ethene-vinyl acetate
emulsion copolymer powder, polyacrylic ester
latex powder; Filler is a kind of in the following
filler: dry powder, talcum powder.Plaster of Paris
has hydration activity, fast solidifying, cohesive
strength height, good, the exquisite in texture,
affine harmless to human body of volume
stability, be green building material, can be used
for preparing environment-friendly type building
putty, add plaster of Paris, to improve the
cohesive strength of this environment-friendly
type gypsum-based construction putty
powder.Add above-mentioned water-soluble
solid powder rubber powder, to improve the
cohesive strength of this building putty
powder.Ethene-vinyl acetate emulsion copolymer
powder, polyvinyl alcohol, modified tapioca
starch, polyacrylic ester latex powder can
effectively improve the cohesive strength of
〜
building putties.Mix 0.1% 0.5% ethene-vinyl
acetate emulsion copolymer powder or 0.6% 〜
1.0% polyvinyl alcohol rubber powder or 2% 3% 〜
modified tapioca starch glue, can satisfy of the
requirement of this environment-friendly type
gypsum-based construction putty powder
cohesive strength.Add above-mentioned filler, to
improve the application property of this
environment-friendly type gypsum-based
construction putty powder.In order to reduce the
retardant volume, improve the putty application
property, can mix a certain proportion of
inorganic inert filler, increase with the filler
volume, putty prolongs time of coagulation, and
draw-off property, grinability turn for the better,
but intensity, cohesiveness reduce.Talcum
powder, dry powder etc. can effectively improve
the workability of building putties.

Purpose of the present invention can reach by

following measure:

Adopt compound retarder, its component and

weight percent:

Citric acid 0.05-0.2

Gelatine 0.1-0.3

Add above-mentioned compound retarder, to

regulate the plaster of Paris setting and harden
time.Usually the plaster of Paris setting and
〜
harden is very fast, presetting period is 6 30
minutes, and operable time has only 4 10 〜
minutes, can not satisfy the construction
requirement of building putties, the working hour
of building putties generally could satisfied
construction requirement more than 2 hours,
must adopt the slow setting technology for this
reason.Retardant kind, volume difference are
different to the prolongation of presetting period
and final setting time.Common single slow
setting technology exists retardant large usage
quantity, defective that the hardenite loss of
strength is very big.This putty adopts citric acid
and the compound slow setting technology of
gelatine, can effectively improve the defective
that single slow setting technology exists.When
the citric acid volume be 0.1%, when the gelatine
volume is 0.2%, the presetting period of plaster
of Paris was 172 minutes, final setting time can
reach 213 minutes, and its folding strength can
reach 2.11MPa, ultimate compression strength
can reach 8.53MPa.

Adopt compound water retaining agent, its

component and weight percent:

Methyl cellulose ether or TYLOSE 30000 or

hydroxypropyl methyl cellulose ether 0.05-0.2

Wilkinite 3-10

Add above-mentioned compound water retaining

agent, to improve the water-retentivity of this
environment-friendly type gypsum-based
construction putty powder.Water-retentivity is the
important technology index of building putties,
and good water-retentivity can be avoided
building putties plastic cracking and surperficial
efflorescence.Building putties adopts single
water-holding agent technology usually, and
ether of cellulose is the commodity water-
holding agent of using always, different water-
holding agent kind and volume, improve the
water-retentivity difference of building putties,
wherein methyl cellulose ether water
conservation effect is best, but its volume is
bigger, and cost is higher.Initiate component
wilkinite has another name called otaylite or
amargosite, with the montmorillonite be the
essential mineral composition the particulate
clay, often contain feldspar, quartz, visit stone,
calcite and pyroclastics.Main chemical
compositions is: SiO 2, Al 2O 3And small amount
of Fe 2O 3, MgO, CaO, K 2O, Na 2O and TiO
2Deng.Generally be white in color, be pale green,
light greenish blue, greyish white, pink isochrome
when impure.Wilkinite has the intensive water-
absorbent, and suction back volume expands 10-
30 doubly, is to suspend and gelatinized in the
aqueous solution, has the characteristic of
cationic exchange, also has high cohesiveness
and resistivity against fire.Wilkinite is a laminate
structure, has water retention, can effectively
reduce latter's volume with the compound use of
methyl cellulose ether, reduces the material cost
of putty preparation.When the methyl cellulose
〜
ether volume be 0.2%, when wilkinite is 3% 10%,
the building putties percentage of water loss is
0.1042g/cm 2, over dry folding strength and
ultimate compression strength are respectively
2.60MPa and 9.70MPa.

Test shows, when proportioning is: plaster of

Paris 68.96, citric acid 0.1, gelatine 0.2, methyl
cellulose ether 0.1, wilkinite 4.0, ethene-vinyl
acetate emulsion copolymer powder 0.25, dry
powder 26.39, the performance of this
environment-friendly type gypsum-based
construction putty powder is: standard
consistency 46%, surface drying time 2 hours 10
minutes, grinability 48%, whiteness 78, water
retention 96%, over dry folding strength 2.8MPa,
over dry ultimate compression strength 6.2MPa,
cohesive strength 0.72MPa.

The present invention has following advantage

compared to existing technology:

1. do not contain Toxic matter.

2. cohesive strength height, operating efficiency

height, short construction period.

3. adopt wilkinite and ether of cellulose

composite water conservation technology, not
only reduced the material cost of putty, and
improved water retention property.

4. have good workability, the putty surface is

moist.

5. the present invention is a single component

solid powdery product, need not on-the-spot
prepare, and is easy to use.
Embodiment:

Specific embodiments of the invention are as

follows, and each embodiment all represents
with weight percent.

Embodiment 1:

Plaster of Paris 68.96

Citric acid 0.1

Gelatine 0.2

Methyl cellulose ether 0.1

Wilkinite 4

Ethene-vinyl acetate emulsion copolymer powder

0.25

Dry powder 26.39.

Embodiment 2:

Plaster of Paris 77.3

Citric acid 0.15

Gelatine 0.1

Hydroxypropyl methyl cellulose ether 0.2

Wilkinite 5.7

Polyvinyl alcohol rubber powder 0.85

Talcum powder 15.7.

Embodiment 3:

Plaster of Paris 85

Citric acid 0.1

Gelatine 0.2

TYLOSE 30000 0.1

Wilkinite 6.25

Ethene-vinyl acetate emulsion copolymer powder

0.25

Dry powder 8.1.

Embodiment 4:
Plaster of Paris 60

Citric acid 0.05

Gelatine 0.25

Methyl cellulose ether 0.05

Wilkinite 8

Modified tapioca starch 2.5

Talcum powder 29.15.

Embodiment 5:

Plaster of Paris 81.5

Citric acid 0.2

Gelatine 0.1

Hydroxypropyl methyl cellulose ether 0.2

Wilkinite 3

Modified tapioca starch 2.5

Dry powder 12.5.

Embodiment 6:

Plaster of Paris 65

Citric acid 0.1

Gelatine 0.1

Methyl cellulose ether 0.05

Wilkinite 10

Polyvinyl alcohol rubber powder 1

Talcum powder 23.75.

Embodiment 7:

Plaster of Paris 71.39

Citric acid 0.05

Gelatine 0.25

TYLOSE 30000 0.2

Wilkinite 7.45

Ethene-vinyl acetate latex powder 0.1

Talcum powder 20.56.Above-mentioned gypsum-
based construction putty powder can once claim
foot stirring simultaneously to form required
starting material in proportion.

Cited By (22)

Publication number Priority date Publication da

CN100334177C * 2004-11-16 2007-08-29

CN100406405C * 2006-12-12 2008-07-30

CN101891980A * 2010-07-23 2010-11-24

CN102219466A * 2011-03-23 2011-10-19

CN101514267B * 2008-02-21 2012-04-18

CN101638530B * 2008-07-30 2012-09-26

CN103102727A * 2012-12-17 2013-05-15

CN103214225A * 2013-03-01 2013-07-24

CN103642297A * 2013-12-24 2014-03-19

CN103881462A * 2014-02-25 2014-06-25

CN103881463A * 2014-02-25 2014-06-25

CN104962124A * 2015-06-17 2015-10-07

CN105731971A * 2016-03-10 2016-07-06

CN105754395A * 2016-04-25 2016-07-13

CN105801065A * 2016-02-26 2016-07-27

CN105800987A * 2016-03-15 2016-07-27

CN105885509A * 2016-07-04 2016-08-24

CN106478035A * 2015-08-25 2017-03-08

 CN107722702A * 2017-09-28 2018-02-23

CN107722703A * 2017-09-28 2018-02-23

CN108191363A * 2017-02-18 2018-06-22

CN110204944A * 2019-06-11 2019-09-06

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* Cited by examiner, † Cited by third party, ‡ Family to family citation

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Priority And Related Applications

Priority Applications (1)

Application Priority date Filing date Title

CN 03117999 2003-05-30 2003-05-30 Environme

protection
gypsum-ba
putty powd
for building

Applications Claiming Priority (1)

 Application Filing date Title

CN 03117999 2003-05-30 Environmental-

protection type gypsum-
based putty powder for
building

Legal Events

Date Code Title

2003-11-12 C06 Publication

2003-11-12 PB01 Publication

2005-11-09 C14 Grant of patent or utility model

2005-11-09 GR01 Patent grant

2012-08-01 C17 Cessation of patent right

2012-08-01 CF01 Termination of patent right due to n

Concepts

machine-extracted Download Filter table

Name Image Sections

powders title,claims,

gypsum title,claims,

gypsum title,claims,

construction claims,abst

calcium sulfate claims,desc

calcium sulfate Ca+2 claims,desc

hemihydrate O
O-
S
O-
O
O
O-
H2O S Ca+2
O-
O
 gypsum plaster claims,desc

gelatin claims,desc

gelatine claims,desc

Bentoquatam claims,desc
O O
Al Al
O

H2O O Si O

diethyl ether claims,desc

ether claims,desc

Citric acid claims,desc

Gelatine claims,desc

citric acid claims,desc

citric acid group claims,desc

O O

HO OH OH

O OH

compounds claims,desc

(2R,3R,4S,5R,6S)-4,5- claims,desc
dimethoxy-2- O
O
O

(methoxymethyl)-3- O

O
O
O
O

O
O

[(2S,3R,4S,5R,6R)-3,4,5-
O O O

O
O O

trimethoxy-6-
(methoxymethyl)oxan-2-
yl]oxy-6-
[(2R,3R,4S,5R,6R)-4,5,6-
trimethoxy-2-
(methoxymethyl)oxan-3-
yl]oxyoxane

methyl cellulose claims,desc

methylcellulose claims,desc

methylcellulose claims,desc

fillers claims,desc

talc claims,desc
 talc claims,desc

talc claims,desc

chemical substances claims,desc

by application

ethene;ethenyl claims,desc
acetate O

water claims,desc

copolymers claims,desc

emulsions claims,desc

5-[5-[3,4-dihydroxy-6- HO

claims,desc
(hydroxymethyl)-5-
O

O OH

methoxyoxan-2-yl]oxy-6- HO OH O
OH

O
OH

[[3,4-dihydroxy-6-
HO O
O
O

HO
O

(hydroxymethyl)-5-
HO OH

methoxyoxan-2-
HO

yl]oxymethyl]-3,4-
dihydroxyoxan-2-yl]oxy-6-
(hydroxymethyl)-2-
methyloxane-3,4-diol

Polyvinyl alcohol claims,desc

elastomers claims,desc

polyvinyl alcohols claims,desc

preparation methods claims,desc

2-[6-[4,5-bis(2- claims,desc
hydroxypropoxy)-2-(2-
HO

hydroxypropoxymethyl)-6-
O

OH O
O

O
O
HO

methoxyoxan-3-yl]oxy-4,5-
O

O O

O OH

O O

OH

dimethoxy-2-
HO

(methoxymethyl)oxan-3-
yl]oxy-6-
(hydroxymethyl)-5-
methoxyoxane-3,4-diol

6-(hydroxymethyl)-5- claims,desc
methoxy-2-[4,5,6- O
OH

OH

trimethoxy-2-
O
O

(methoxymethyl)oxan-3-
O

O
O

yl]oxyoxane-3,4-diol
O OH

hydroxypropyl methyl claims,desc

cellulose
 hydroxypropyl methyl claims,desc
cellulose

hydroxypropyl methyl claims,desc

cellulose

Gelatin claims,desc

gelatin claims,desc

gelatine desserts claims,desc

Latex claims,desc

latex claims,desc

calcium sulfate O claims,desc

-
dihydrate O
S
-
O
O
+2
H2O H2O Ca

esters claims,desc

plaster claims,desc

mixtures abstract,de

materials abstract,de

inorganic minerals abstract,de

solids abstract,de

composite materials abstract,de

substances abstract,de

retarding agents abstract

adhesive abstract

adhesives abstract

cellulose ethers abstract

Show all concepts from

the description section

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