Examen de Admision Mas Dificil Del Mundo 6

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, FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26515949, 26569493, Fax 26513942
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FIITJEE Solutions to
IIT JEE - 2009
(PAPER 2, CODE 1)

Time: 3 Hours Maximum Marks: 240

A. Question paper format:

1. The question paper consists of 3 parts (Chemistry, Mathematics and Physics). Each part has 4 sections.

2. Section I contains 4 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its answer,
out of which only one is correct.

3. Section II contains 5 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its
answer, out of which one or more is/are correct.

4. Section III contains 2 questions. Each question has four statements (A, B, C and D) given in column I and five
statements (p, q, r, s and t) in Column II. Any given statement in Column I can have correct matching with one
or more statement(s) given in Column II. For example, if for a given question, statement B matches with the
statements given in q and r, then for that particular question, against statement B, darken the bubbles
corresponding to q and r in the ORS.

5. Section IV contains 8 questions. The answer to each of the questions is a single digit integer, ranging from 0
to 9. The answer will have to be appropriately bubbled in the ORS as per the instructions given at the beginning
of the section.

B. Marking scheme:

6. For each question in Section I you will be awarded 3 marks if you darken the bubble corresponding to the
correct answer and zero mark if no bubbles is darkened. In case of bubbling of incorrect answer, minus one
(-1) mark will be awarded.

7. For each question in Section II, you will be awarded 4 marks if you darken the bubble(s) corresponding to the
correct choice(s) for the answer, and zero mark if no bubble is darkened. In all other cases, Minus one (-1)
mark will be awarded.

8. For each question in Section III, you will be awarded 2 marks for each row in which you have darkened the
bubble(s) corresponding to the correct answer. Thus, each question in this section carries a maximum of 8
marks. There is no negative marking for incorrect answer(s) for this section.

9. For each question in Section IV, you will be awarded 4 marks if you darken the bubble corresponding to the
correct answer and zero mark if no bubble is darkened. In all other cases, minus one (-1) mark will be
awarded.
IITJEE2009-Paper 2-CMP-2

FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26515949, 26569493, Fax 26513942
IITJEE 2009 (PAPER-2, CODE-1)

SECTION-I

Single Correct Choice Type

This section contains 4 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its answer,
out which ONLY ONE is correct.
1. In the following carbocation. H/CH
3
that is most likely to migrate to the positively charged carbon is

C H
3
C
H
OH
C
H
C
CH
3
H
CH
3
1 2
3
4 5

(A) CH
3
at C-4 (B) H at C-4
(C) CH
3
at C-2 (D) H at C-2

Sol. (D)

C H
3
C
OH
H
C
H
C
H
CH
3
CH
3
1
2
3
4
5
C H
3
C
OH
CH
2
CH
CH
3
CH
3
1
2
4
3
(driving force is conjugation from oxygen)
2 3
H shift from C to C

2. The correct stability order of the following resonance structures is

( ) ( ) ( ) ( )
2 2 2 2
I II III IV
H C N N H C N N H C N N H C N N
+ + + +
= = = =
(A) (I) > (II) > (IV) > (III) (B) (I) > (III) > (II) > (IV)
(C) (II) > (I) > (III) > (IV) (D) (III) > (I) > (IV) > (II)

Sol. (B )
On the basis of stability of resonating structures.

3. The spin only magnetic moment value (in Bohr magneton units) of Cr(CO)
6
is
(A) 0 (B) 2.84
(C) 4.90 (D) 5.92

Sol. (A)
[Cr(CO)
6
]
Cr(24) = [Ar]3d
5
4s
1

Since (CO) is strong ligand, in Cr(CO)
6
no unpaired electron is present. So spin only magnetic moment is
zero.

4. For a first order reaction A P, the temperature (T) dependent rate constant (k) was found to follow the
equation log k ( )
1
2000 6.0
T
= + . The pre-exponential factor A and the activation energy E
a
, respectively,
are
(A) 1.0 10
6
s
1
and 9.2 kJmol
1
(B) 6.0 s
1
and 16.6 kJmol
1

(C) 1.0 10
6
s
1
and 16.6 kJmol
1
(D) 1.0 10
6
s
1
and 38.3 kJmol
1

PART I: CHEMISTRY


Sol. (D)
Given, log K = 6
2000
T

Since, log K = log A
Ea
2.303RT
So, A = 10
6
sec
-1
and Ea = 38.3 kJ/mole

SECTION-II

Multiple Correct Choice Type

out which ONE OR MORE is/are correct.
5. The nitrogen oxide(s) that contain(s) NN bond(s) is(are)
(A) N
2
O (B) N
2
O
3

(C) N
2
O
4
(D) N
2
O
5

Sol. (A, B, C )
2
N O N N O
2 3
N O N O
O
N
O
, O N N
O
O

2 4
N O
2 5
N O
N O
O
N
O
O O
,
N N
O
O O
O

6. In the reaction
( ) | |
2 6 2 4
2
2 B H BH BH
+

( +

X X
the amine(s) X is(are)
(A) NH
3
(B) CH
3
NH
2

(C) (CH
3
)
2
NH (D) (CH
3
)
3
N

Sol. (A, B, C)
Due to bulkiness of trimethylamine, it does not react.

7. The correct statement(s) about the following sugars X and Y is(are)

O
H
O H
H
OH
CH
2
OH
H
H
O
HOH
2
C
O
CH
2
OH
H
OH
H
H
O H H
OH
X
O
OH
H
CH
2
OH
H
H
OH
O
H
O H
H
OH
CH
2
OH
H
O
H
H
H
OH
OH
H
Y

(A) X is a reducing sugar and Y is a non-reducing sugar
(B) X is a non-reducing sugar and Y is a reducing sugar
(C) The glucosidic linkages in X and Y are and , respectively
(D) The glucosidic linkages in X and Y are and , respectively


Sol. (B, C)

8. Among the following, the state function(s) is(are)
(A) Internal energy (B) Irreversible expansion work
(C) Reversible expansion work (D) Molar enthalpy

Sol. (A, D)

9. For the reduction of
3
NO
ion in an aqueous solution, E

0
is +0.96 V. Values of E
0
for some metal ions are
given below
( )
2 0
V aq 2e V E 1.19 V
+
+ =
( )
3 0
Fe aq 3e Fe E 0.04 V
+
+ =
( )
3 0
Au aq 3e Au E 1.40 V
+
+ = +
( )
2 0
Hg aq 2e Hg E 0.86 V
+
+ = +
The pair(s) of metals that is(are) oxidized by
3
NO
in aqueous solution is(are)

(A) V and Hg (B) Hg and Fe
(C) Fe and Au (D) Fe and V

Sol. (A, B, D)

( )
( )
3
o
NO aq
SRP
E 0.96 V
= All V, Fe, Hg have less SRP w.r.t.

3
NO .

So, V, Fe, Hg can be oxidized by
3
NO
in aqueous solution.

SECTION III

Matrix Match Type

This section contains 2 questions. Each question contains statements given in two columns, which have to be
matched. The statements in Column I are labelled A, B, C and D, while the statements in Column II are labelled p,
q, r, s and t. Any given statement in Column I can have correct matching with ONE OR MORE statement(s) in
Column II. The appropriate bubbles corresponding to the answers to these questions have to be darkened as
illustrated in the following example:
If the correct matches are A p, s and t; B q and r; C p and q; and D s and t; then the correct darkening of
bubbles will look like the following:
p q r s
p q r s
p q r s
p q r s
p q r s
D
C
B
A
t
t
t
t
t

10. Match each of the compounds given in Column I with the reaction(s), that they can undergo given in
Column II.
Column I Column II
(A)
O
Br

(p) Nucleophilic substitution

(B)
OH

(q) Elimination
(C)
CHO
OH

(r) Nucleophilic addition
(D)
Br
NO
2

(s) Esterification with acetic anhydride
(t) Dehydrogenation

Sol. ((A p, q, t) (B p, s, t) (C r, s) (D p))

11. Match each of the reactions given in Column I with the corresponding product(s) given in Column II.
Column I Column II
(A) Cu + dil HNO
3
(p) NO
(B) Cu + conc HNO
3
(q) NO
2
(C) Zn + dil HNO
3
(r) N
2
O
(D) Zn + conc HNO
3
(s) Cu(NO
3
)
2
(t) Zn(NO
3
)
2

Sol. ((A p, s) (B q, s) (C r, t) (D q, t))
( )
3 3 2
2
3Cu dil.8HNO 3Cu NO 4H O 2NO + + +
( )
3 3 2 2
2
Cu conc. 4HNO Cu NO 2H O 2NO + + +
( )
3 3 2 2
2
4Zn dil. 10HNO 4Zn NO 5H O N O + + +
( )
3 3 2 2
2
Zn conc. 4HNO Zn NO 2H O 2NO + + +


SECTION IV

Integer Answer Type

This section contains 8 questions. The answer to each of the questions is a single digit integer, ranging from 0 to 9.
The appropriate bubbles below the respective question numbers in the ORS have to be darkened. For example, if the
correct answers to question numbers X, Y, Z and W (say) are 6, 0, 9 and 2, respectively, then the correct darkening
of bubbles will look like the following:

0 0 0 0
1 1 1 1
2 2 2 2
3 3 3 3
4 4 4 4
5 5 5 5
7 7 7 7
8 8 8 8
9 9 9 9
6 6 6 6
X Y Z W

12. The oxidation number of Mn in the product of alkaline oxidative fusion of MnO
2
is

Sol. 6

( )
2 2 2 4 2
Potassium manganate
2MnO 4KOH O 2K MnO 2H O + + + O. S. of Mn = +6 in K
2
MnO
4

13. The number of water molecule(s) directly bonded to the metal centre in
4 2
CuSO 5H O is

Sol. 4
( )
4 2 2 4 2
4
CuSO 5H O Cu H O SO H O (

So, water molecules directly attached to Cu are 4.

14. The coordination number of Al in the crystalline state of AlCl
3
is

Sol. 6
Coordination number of Al is 6. It exists in ccp lattice with 6 coordinate layer structure.

15. In a constant volume calorimeter, 3.5 g of a gas with molecular weight 28 was burnt in excess oxygen at
298.0 K. The temperature of the calorimeter was found to increase from 298.0 K to 298.45 K due to the
combustion process. Given that the heat capacity of the calorimeter is 2.5 kJ K
1
, the numerical value for
the enthalpy of combustion of the gas in kJmol
1
is

Sol. 9
Energy release at constant volume due to combustion of 3.5 gm of a gas = 2.5 0.45
Hence energy released due to the combustion of 28 gm (i.e., 1 mole) of a gas
1
28
2.5 0.45 9 kJmol
3.5

= =

16. The dissociation constant of a substituted benzoic acid at 25
o
C is 1.0 10
4
. The pH of a 0.01 M solution of
its sodium salt is


Sol. 8
K
a
(C
6
H
5
COOH) = 1 10
4

pH of 0.01 M C
6
H
5
COONa

( )
1
6 5 2 6 5
0.01 h 0.01 1 h 0.01 h
C H COO H O C H COOH OH

+ +

2
w
h
a
K 0.01 h
K
K 1 h
= =

( )
14 2 2
4
10 10 h
1 h 1
1 h 10

[OH
] = 0.01 h = 0.01 10
4
= 10
6

[H
+
] = 10
8

pH = 8

17. The total number of cyclic structural as well as stereo isomers possible for a compound with the molecular
formula C
5
H
10
is

Sol. 7
Cyclic C
5
H
10

1 2 3 4 5

For 3
rd
structure 2 cis-trans and 1 optical isomer are possible.
Total 7 isomers.

18. The total number of and particles emitted in the nuclear reaction
238 214
92 82
U Pb is

Sol. 8

238 6 214 2 214
80 82
92
U X Pb

(6, 2), total 8 paritcles.

19. At 400 K, the root mean square (rms) speed of a gas X (molecular weight = 40) is equal to the most
probable speed of gas Y at 60 K. The molecular weight of the gas Y is

Sol. 4

( )( ) ( )( ) X gas 400 K Ygas 60 K
rms mp
V V =
M.W. (X gas) = 40; M.W. (Y gas) = x

1 2
1 2
3RT 2RT
M M
=

400 3 2 60
40 x

=

120
30
x
=
x = 4


SECTIONI


out of which ONLY ONE is correct.

20. The normal at a point P on the ellipse x
2
+ 4y
2
= 16 meets the x-axis at Q. If M is the mid point of the line
segment PQ, then the locus of M intersects the latus rectums of the given ellipse at the points
(A)
3 5 2
,
2 7
| |

|
\ .
(B)
3 5 19
,
2 4
| |

|
\ .

(C)
1
2 3,
7
| |

|
\ .
(D)
4 3
2 3,
7
| |

|
\ .

Sol. (C)
Normal is 4x sec 2y cosec = 12
Q (3 cos, 0)
M (, )
=
3cos 4cos 7
cos
2 2
+
=
cos =
2
7

= sin
cos
2
+ sin
2
= 1

2 2
4
1
49
+ =
2 2
4
x y 1
49
+ =
latus rectum x = 2 3

P (4cos, 2sin )
M
Q(3cos, 0)

48
49
+ y
2
= 1 y =
1
7

( 2 3 , 1/7).

21. The locus of the orthocentre of the triangle formed by the lines (1 + p)x py + p(1 + p) = 0, (1 + q)x qy +
q(1 + q) = 0 and y = 0, where p q, is
(A) a hyperbola (B) a parabola
(C) an ellipse (D) a straight line

Sol. (D)
Intersection point of y = 0 with first line is B(p, 0)
Intersection point of y = 0 with second line is A(q, 0)
Intersection point of the two lines is C(pq, (p + 1)(q + 1))
Altitude from C to AB is x = pq
Altitude from B to AC is y = ( )
q
x p
1 q
+
+

Solving these two we get x = pq and y = pq
locus of orthocentre is x + y = 0.

PART II: MATHEMATICS

22. A line with positive direction cosines passes through the point P(2, 1, 2) and makes equal angles with the
coordinate axes. The line meets the plane 2x + y + z = 9 at point Q. The length of the line segment PQ
equals
(A) 1 (B) 2
(C) 3 (D) 2

Sol. (C)
D.C of the line are
1 1 1
, ,
3 3 3
.
Any point on the line at a distance t from P(2, 1, 2) is
t t t
2 , 1 , 2
3 3 3
| |
+ + +
|
\ .

which lies on 2x + y + z = 9 t = 3 .

23. If the sum of first n terms of an A.P. is cn
2
, then the sum of squares of these n terms is
(A)
( )
2 2
n 4n 1 c
6
(B)
( )
2 2
n 4n 1 c
3
+

(C)
( )
2 2
n 4n 1 c
3
(D)
( )
2 2
n 4n 1 c
6
+

Sol. (C)
t
n
= c {n
2
(n 1)
2
}
= c (2n 1)

( )
2 2 2
n
t c 4n 4n 1 = +

( )( ) ( )
n
2 2
n
n 1
4n n 1 2n 1 4n n 1
t c n
6 2
=
+ + +
= + `
)

= { }
2
c n
4(n 1)(2n 1) 12(n 1) 6
6
+ + + +
=
{ } ( )
2 2
2 2
c n c
4n 6n 2 6n 6 3 n 4n 1
3 3
+ + + = .

SECTIONII


out of which ONE OR MORE is/are correct.

24. The tangent PT and the normal PN to the parabola y
2
= 4ax at a point P on it meet its axis at points T and
N, respectively. The locus of the centroid of the triangle PTN is a parabola whose
(A) vertex is
2a
, 0
3
| |
|
\ .
(B) directrix is x = 0
(C) latus rectum is
2a
3
(D) focus is (a, 0)


Sol. (A, D)
G (h, k)
h =
2
2a at
3
+
, k =
2at
3

2
2
3h 2a 9k
a 4a
| |
=
|
\ .

required parabola is

2
2
9y (3x 2a) 3 2a
x
a a 3 4a
| |
= =
|
\ .

y
2
=
4a 2a
x
3 3
| |
|
\ .

P (at
2
, 2at)
N (2a, at
2
, 0) T (at
2
, 0)

Vertex
2a
, 0
3
| |
|
\ .
; Focus (a, 0)
25. For function f(x) = x cos
1
x
, x 1,
(A) for atleast one x in interval [1, ), f(x + 2) f(x) < 2
(B)
( )
x
lim f x 1
=
(C) for all x in the interval [1, ), f(x + 2) f(x) > 2
(D) f(x) is strictly decreasing in the interval [1, )

Sol. (B, C, D)
For f(x) =
1
x cos
x
| |
|
\ .
, x 1
f(x) =
1 1 1
cos sin
x x x
| | | |
+
| |
\ . \ .
1 for x
also f(x) =
2 2 3
1 1 1 1 1 1
sin sin cos
x x x x x x
| | | | | |

| | |
\ . \ . \ .

=
3
1 1
cos
x x
| |
|
\ .
< 0 for x 1
f(x) is decreasing for [1, )
f(x + 2) < f(x) . Also, ( ) ( ) ( )
x x
1 1
limf x 2 f x lim x 2 cos x cos 2
x 2 x

(
+ = + =
(
+

( ) ( ) f x 2 f x 2 x 1 + >

26. For 0 < <
2
, the solution(s) of
( )
6
m 1
m 1 m
cos ec cos ec 4 2
4 4
=
| | | |
+ + =
| |
\ . \ .
is(are)
(A)
4
(B)
6

(C)
12
(D)
5
12

Sol. (C, D)
Given solutions

( )
( )
( )
( ) ( )
( ) ( )
( ) ( ) ( )
( ) ( )
1 sin / 4 sin / 2 / 4 sin 3 / 2 5 / 4
...
sin / 4 sin sin / 4 sin / 4 sin / 2 sin 3 / 2 sin 5 / 4
( + + + + +
+ + +
(
+ + + + +
= 4 2

( ) ( ) ( ) ( ) ( ) | | 2 cot cot / 4 cot / 4 cot / 2 ... cot 5 / 4 cot 3 / 2 + + + + + + + + = 4 2

tan + cot = 4 tan = 2 3
=
12
or
5
12
.
27. An ellipse intersects the hyperbola 2x
2
2y
2
= 1 orthogonally. The eccentricity of the ellipse is reciprocal
of that of the hyperbola. If the axes of the ellipse are along the coordinates axes, then
(A) equation of ellipse is x
2
+ 2y
2
= 2 (B) the foci of ellipse are ( 1, 0)
(C) equation of ellipse is x
2
+ 2y
2
= 4 (D) the foci of ellipse are ( 2 , 0)

Sol. (A, B)
Ellipse and hyperbola will be confocal
( ae, 0) ( 1, 0)

1
a , 0
2
| |

|
\ .
( 1, 0)
a = 2 and e =
1
2

b
2
= a
2
(1 e
2
) b
2
= 1
Equation of ellipse
2 2
x y
1
2 1
+ = .

28. If I
n
=
( )
x
sin nx
dx
1 sin x
, n = 0, 1, 2, , then
(A) I
n
= I
n + 2
(B)
10
2m 1
m 1
I 10
+
=
=

(C)
10
2m
m 1
I 0
=
=
(D) I
n
= I
n + 1

Sol. (A, B, C)
I
n
=
( )
x
sin nx
dx
1 sin x

=
x
x x
0
sin nx sin nx
(1 ) sin x (1 ) sin x
| |
+
|
|
+ +
\ .
dx =
0
sin nx
sin x

Now, I
n+2
I
n
=
( )
0
sin n 2 x sin nx
dx
sin x

=
( )
0
2cos n 1 x sin x
dx
sin x
= 0
I
1
= , I
2
=
0
2cos x dx 0


SECTION III

Matrix Match Type

matched. The statement in Column I are labelled A, B, C and D, while the statements in Column II are labelled p,
q, r, s and t. Any given statement in Column I can have correct matching with ONE OR MORE statement (s) in
If the correct matches are A p, s and t; B q and r; C p and q; and D s and t; then the correct darkening of
bubbles will look like the following.
p q r s
p q r s
p q r s
p q r s
p q r s
D
C
B
A
t
t
t
t
t

29. Match the statements/expressions in Column I with the values given in Column II.
Column I Column II
(A) The number of solutions of the equation xe
sinx
cosx = 0 in the
interval 0,
2
| |
|
\ .

(p) 1
(B) Value(s) of k for which the planes kx + 4y + z = 0, 4x + ky + 2z = 0
and 2x + 2y + z = 0 intersect in a straight line
(q) 2
(C) Value(s) of k for which |x 1| + |x 2| + |x + 1| + |x + 2| = 4k has
integer solution(s)
(r) 3
(D) If y = y + 1 and y(0) = 1 then value(s) of y(ln2) (s) 4
(t) 5
Sol. (A) (p) (B) (q, s) (C) (q, r, s, t) (D) (r)
(A). f(x) > 0, x (0, /2)
f(0) < 0 and f(/2) > 0
so one solution.
(B). Let (a, b, c) is direction ratio of the intersected line, then
ak + 4b + c = 0
4a + kb + 2c = 0

2
a b c
8 k 4 2k k 16
= =

We must have 2 (8 k) + 2 (4 2k) + (k
2
16) = 0
k = 2, 4.

(C). Let f(x) = |x + 2| + |x + 1| + |x 1| + |x 2|
k can take value 2, 3, 4, 5.
2x 4 4 2x
4x
4x
2 1 1
2
6


(D).
dy
dx
y 1
=
+

f(x) = 2e
x
1
f(ln 2) = 3

30. Match the statements/expressions in Column I with the values given in Column II.
Column I Column II
(A) Root(s) of the expression 2sin
2
+ sin
2
2 = 2
(p)
6

(B) Points of discontinuity of the function f(x) =
6x 3x
cos
( (
( (

,
where [y] denotes the largest integer less than or equal to y
(q)
4

(C) Volume of the parallelopiped with its edges represented by
the vectors

i j, i 2j and i j k + + + +
(r)
3

(D) Angle between vectors a and b
where a, b and c

are unit
vectors satisfying a b 3c 0 + + =

(s)
2

(t)
Sol. (A) (q, s) (B) (p, r, s, t) (C) (t) (D) (r)
(A). 2sin
2
+ 4sin
2
cos
2
= 2
sin
2
+ 2sin
2
(1 sin
2
) = 1
3sin
2
2sin
4
1 = 0 sin =
1
2
, 1
= ,
4 2

.
(B). Let y =
3x

1
y 3
2
x ,
6
(
(

Now f(y) = [2y] cos[y]
Critical points are y =
1
2
, y = 1, y =
3
2
, y = 3
points of discontinuity
{ }
, , ,
6 3 2

.

(C).
1 1 0
1 2 0
1 1
= volume of parallelopiped =

(D). a b 3 + =

2 2cos 3 + =
2 + 2 cos = 3
=
3
.


SECTION IV

Integer Answer Type

This section contains 8 questions. The answer to each of the questions is a single digit integer, ranging from 0 to 9.
of bubbles will look like the following:

0 0 0 0
1 1 1 1
2 2 2 2
3 3 3 3
4 4 4 4
5 5 5 5
7 7 7 7
8 8 8 8
9 9 9 9
6 6 6 6
X Y Z W

31. Let f: R R be a continuous function which satisfies f(x) =
( )
x
0
f t dt
. Then the value of f(ln5) is

Sol. 0
f(x) =
( )
x
0
f t dt
f(0) = 0
also, f(x) = f(x), x > 0
f(x) = ke
x
, x > 0
f(0) = 0 and f(x) is continuous f(x) = 0 x > 0
f(ln5) = 0.

32. The centres of two circles C
1
and C
2
each of unit radius are at a distance of 6 units from each other. Let P
be the mid point of the line segment joining the centres of C
1
and C
2
and C be a circle touching circles C
1

and C
2
externally. If a common tangent to C
1
and C passing through P is also a common tangent to C
2
and
C, then the radius of the circle C is

Sol. 8
cos =
2 2
3

sin =
1
3

tan =
2 2
R

R =
2 2
tan
= 8 units.

A
B
C1
C2
R

C
3
2 2

1
P


Alternate:
(R + 1)
2
= (R 1)
2
+
( )
2
4 2
R = 8.

33. The smallest value of k, for which both the roots of the equation x
2
8kx + 16(k
2

k + 1 ) = 0 are real,
distinct and have values at least 4, is

Sol. 2
x
2
8kx + 16 (k
2
k + 1) = 0
D > 0 k > 1 (1)

b
4
2a
>
8k
4
2
>
k > 1 (2)
f (4) 0 16 32 k + 16 (k
2
k + 1) 0
k
2
3k + 2 0
k 1 k 2 (3)
Using (1), (2) and (3)
k
min
= 2.

4

34. The maximum value of the function f(x) = 2x
3
15 x
2
+ 36x 48 on the set A = {x|x
2
+ 20 9x|} is

Sol. 7
f(x) = 6(x 2)(x 3)
so f (x) is increasing in (3, )
Also, A = {4 x 5}
f
max
= f(5) = 7.

35. Let ABC and ABC be two noncongruent triangles with sides AB = 4, AC = AC = 2 2 and angle B =
30. The absolute value of the difference between the areas of these triangles is

Sol. 4
cos =
2
a 16 8
2 a 4
+

2
3 a 8
2 8a
+
=
a
2
4 3 a + 8 = 0
a
1
+ a
2
= 4 3 , a
1
a
2
= 8
|a
1
a
2
| = 4
|
1

2
| =
1
4sin30 4 4
2
= .
A
30
B
C

36. If the function f(x) = x
3
+ e
x/2
and g(x) = f
1
(x), then the value of g(1) is

Sol. 2
f(0) = 1, f(x) =
2 x / 2
1
3x e
2
+
f(g(x)) g(x) = 1
Put x = 0 g(1) =
1
2
f (0)
=
.

37. Let p(x) be a polynomial of degree 4 having extremum at x = 1, 2 and
2
x 0
p(x)
lim 1 2
x
| |
+ =
|
\ .
. Then the value
of p(2) is

Sol. 0
Let P(x) = ax
4
+ bx
3
+ cx
2
+ dx + e
P(1) = P(2) = 0

2
2
x 0
x P(x)
lim 2
x
| |
+
=
|
\ .

P(0) = 0 e = 0

x 0
2x P (x)
lim 2
2x
+ | |
=
|
\ .

P(0) = 0 d = 0

x 0
2 P (x)
lim 2
2
+ | |
=
|
\ .

c = 1
On solving, a = 1/4, b = 1
So P(x) =
4
x
4
x
3
+ x
2
P(2) = 0.
38. Let (x, y, z) be points with integer coordinates satisfying the system of homogeneous equations:
3x y z = 0
3x + z = 0
3x + 2y +z = 0.
Then the number of such points for which x
2
+ y
2
+ z
2
100 is

Sol. 7
3x y z = 0
3x + z = 0
y = 0
and z = 3x
x
2
+ y
2
+ z
2
= x
2
+ z
2
= x
2
+ 9x
2
= 10x
2
100
x
2
10
x = 0, 1, 2, 3
There are such seven points.



SECTION-I


out which ONLY ONE is correct.

39. Photoelectric effect experiments are performed using three different metal plates p, q and r having work
functions
p
= 2.0 eV,
q
= 2.5 eV and
r
= 3.0 eV, respectively. A light beam containing wavelengths of
550 nm, 450 nm and 350 nm with equal intensities illuminates each of the plates. The correct I-V graph for
the experiment is (Take hc = 1240 eV nm)
(A)

p

q

r

I

V

(B)
p

q

r

I

V

(C)

r

q

P

I

V

(D)
r

q

p

I

V

Sol. (A)
V
B
= (1/e)[(hc/) ]
V
P
= (1/e)[(1240/550) 2]eV = 0.2545 V
V
q
= (1/e)[(1240/450) 2.5]eV = 0.255 V
V
r
= (1/e)[(1240/350) 3]eV = 0.5428 V
If n is the number of photons in unit time then nhc/ = I
i
P
: i
q
: i
r
= n
P
: n
q
: n
r
=
P
:
q
:
r

40. A uniform rod of length L and mass M is pivoted at the centre. Its two ends are
attached to two springs of equal spring constants k. The springs are fixed to rigid
supports as shown in the figure, and rod is free to oscillate in the horizontal plane.
The rod is gently pushed through a small angle in one direction and released.
The frequency of oscillation is
(A)
1 2k
2 M
(B)
1 k
2 M

(C)
1 6k
2 M
(D)
1 24k
2 M

Sol. (C)
Restoring torque = 2 k
2 2
| |
|
\ .

=
2
2
Id
dt

2
2
d
dt
=
2
2
k
( )
2
M
12

=
6k
M

PART III: PHYSICS


41. A piece of wire is bent in the shape of a parabola y = kx
2
(y-axis vertical) with a bead of mass m on it. The
bead can slide on the wire without friction. It stays at the lowest point of the parabola when the wire is at
rest. The wire is now accelerated parallel to the x-axis with a constant acceleration a. The distance of the
new equilibrium position of the bead, where the bead can stays at rest with respect to the wire, from the y-
axis is
(A)
a
gk
(B)
a
2gk

(C)
2a
gk
(D)
a
4gk

Sol. (B)
tan =
a
g

tan =
dy
2kx
dx
=
x =
a
2gk

mg
ma
N cos

N sin

N

x
y

42. The mass M shown in the figure oscillates in simple harmonic motion with
amplitude A. The amplitude of the point P is
(A)
1
2
k A
k
(B)
2
1
k A
k

(C)
1
1 2
k A
k k +
(D)
2
1 2
k A
k k +

k
1
k
2
P

M

Sol. (D)
x
1
+ x
2
= A
k
1
x
1
= k
2
x
2

Hence x
1
=
2
1 2
k A
k k +

SECTION -II


out of which ONE OR MORE is/are correct.

43. Under the influence of the coulomb field of charge +Q, a charge q is moving around it in an elliptical
orbit. Find out the correct statement(s).
(A) The angular momentum of the charge q is constant
(B) The linear momentum of the charge q is constant
(C) The angular velocity of the charge q is constant
(D) The linear speed of the charge q is constant
Sol. (A)


44. The figure shows the P-V plot of an ideal gas taken through a cycle ABCDA.
The part ABC is a semi-circle and CDA is half of an ellipse. Then,
(A) the process during the path A B is isothermal
(B) heat flows out of the gas during the path B C D
(C) work done during the path A B C is zero
(D) positive work is done by the gas in the cycle ABCDA

D

1

2

3

1

2

3

0

A

B

C

P

V

Sol. (B) & (D)
Q = U + W
For process B C D
U is negative as well as W is also negative

45. A sphere is rolling without slipping on a fixed horizontal plane surface. In the
figure, A is the point of contact, B is the centre of the sphere and C is its topmost
point. Then,
(A)
( )
C A B C
V V 2 V V =

(B)
C B B A
V V V V =

(C)
C A B C
V V 2 V V =

(D)
C A B
V V 4 V =

C
B
A

Sol. (B) & (C)

46. A student performed the experiment to measure the speed of sound in air using resonance air-column
method. Two resonances in the air-column were obtained by lowering the water level. The resonance with
the shorter air-column is the first resonance and that with the longer air column is the second resonance.
Then,
(A) the intensity of the sound heard at the first resonance was more than that at the second resonance
(B) the prongs of the tuning fork were kept in a horizontal plane above the resonance tube
(C) the amplitude of vibration of the ends of the prongs is typically around 1 cm
(D) the length of the air-column at the first resonance was somewhat shorter than 1/4th of the wavelength
of the sound in air
Sol. (A) & (D)
Larger the length of air column, feebler is the intensity

47. Two metallic rings A and B, identical in shape and size but having different resistivities
A
and
B
, are kept
on top of two identical solenoids as shown in the figure. When current I is switched on in both the
solenoids in identical manner, the rings A and B jump to heights h
A
and h
B
, respectively, with h
A
> h
B
. The
possible relation(s) between their resistivities and their masses m
A
and m
B
is(are)

A
B

(A)
A
>
B
and m
A
= m
B
(B)
A
<
B
and m
A
= m
B

(C)
A
>
B
and m
A
> m
B
(D)
A
<
B
and m
A
< m
B

Sol. (B) & (D)
As
d
dt
= emf is same, the current induced in the ring will depend upon resistance of the ring. Larger the
resistivity smaller the current.


SECTION III

Matrix-Match Type

matched. The statements in Column I are labelled A, B, C and D, while the statements in Column II are labelled p,
q, r, s and t. Any given statement in Column I can have correct matching with ONE OR MORE statement(s) in
If the correct matches are A-p, s and t; B-q and r; C-p and q; and D-s and t; then the correct darkening of bubbles
will look like the following.

p q r s
p q r s
p q r s
p q r s
p q r s
D
C
B
A
t
t
t
t
t

48. Column I shows four situations of standard Youngs double slit arrangement with the screen placed far
away from the slits S
1
and S
2
. In each of these cases S
1
P
0
= S
2
P
0
, S
1
P
1
S
2
P
1
= /4 and S
1
P
2
S
2
P
2
= /3,
where is the wavelength of the light used. In the cases B, C and D, a transparent sheet of refractive index
and thickness t is pasted on slit S
2
. The thicknesses of the sheets are different in different cases. The
phase difference between the light waves reaching a point P on the screen from the two slits is denoted by
(P) and the intensity by I(P). Match each situation given in Column I with the statement(s) in Column II
valid for that situation.
Column I Column II
(A)

P2
P1
P0
S2
S1

(B) ( 1)t = /4

P2
P1
P0
S2
S1

(C) ( 1)t = /2

P2
P1
P0
S2
S1

(D) ( 1)t = 3/4
P2
P1
P0
S2
S1

(p) (P
0
) = 0

(q) (P
1
) = 0

(r) I(P
1
) = 0

(s) I (P
0
) > I(P
1
)

(t) I (P
2
) > I (P
1
)


Sol. A (p, s); B (q); C (t); D (r, s, t)

49. Column II gives certain systems undergoing a process. Column I suggests changes in some of the
parameters related to the system. Match the statements in Column I to the appropriate process(es) from
Column II.

Column I Column II
(p)

System: A capacitor, initially uncharged
Process : It is connected to a battery

(q)

System: A gas in an adiabatic container
fitted with an adiabatic piston

Process: The gas is compressed by
pushing the piston

(r)

System: A gas in a rigid container

Process: The gas gets cooled due to
colder atmosphere surrounding it

(s)

System : A heavy nucleus, initially at rest

Process: The nucleus fissions into two
fragments of nearly equal masses
and some neutrons are emitted
(A) The energy of the system is increased

(B) Mechanical energy is provided to the
system, which is converted into energy of
random motion of its parts

(C) Internal energy of the system is
converted in to its mechanical energy

(D) Mass of the system is decreased

(t)

System: A resistive wire loop

Process: The loop is placed in a time
varying magnetic field
perpendicular to its plane

Sol. A (p, q, t); B (q); C (s); D (s)


SECTION IV

Integer Answer Type

This section contains 8 questions. The answer to each of the questions is a single-digit integer, ranging from 0 to 9.
of bubbles will look like the following
0 0 0 0
1 1 1 1
2 2 2 2
3 3 3 3
4 4 4 4
5 5 5 5
7 7 7 7
8 8 8 8
9 9 9 9
6 6 6 6
X Y Z W

50. A steady current I goes through a wire loop PQR having shape of a right angle triangle with PQ = 3x, PR =
4x and QR = 5x. If the magnitude of the magnetic field at P due to this loop is k
0
I
,
48 x
| |
|
\ .
find the value of
k.
Sol. 7
B =
| |
0
I
cos 53 cos 37
12x
4
5
=
0
I
7
48 x
| |
|
\ .

k = 7
3x
P
5x
37
53
4x
12x/5

51. A light inextensible string that goes over a smooth fixed pulley as shown in the figure connects two blocks
of masses 0.36 kg and 0.72 kg. Taking g = 10 m/s
2
, find the work done (in joules) by the string on the
block of mass 0.36 kg during the first second after the system is released from rest.

Sol. 8
2mg T = 2ma
T mg = ma
a = g/3
T = 4mg/3
W = T.s = T.
2
1
at
2
= 8 Joules

2m
m

52. A solid sphere of radius R has a charge Q distributed in its volume with a charge density = kr
a
, where k
and a are constants and r is the distance from its centre. If the electric field at r = R/2 is 1/8 times that at r =
R, find the value of a.

Sol. 2
= kr
a

E
( )
R 1
r E r R
2 8
| |
= = =
|
\ .

( )
enclosed
2 2
0
0
q 1 Q
8 4 R
4 R 2
=

32q
enclosed
= Q
R

q
enclosed
=
R 2
a 2
0
kr 4 r dr
=
( )
( ) a 3
4 k R
a 3 2
+
| |
|
+ \ .

Q =
( )
( ) a 3
4 k
R
a 3
+
+

a 3
enclosed
Q
2
q
+
=
2
a + 3

= 32
a = 2

53. A metal rod AB of length 10x has its one end A in ice at 0C and the other end B in water at 100C. If a
point P on the rod is maintained at 400C, then it is found that equal amounts of water and ice evaporate
and melt per unit time. The latent heat of evaporation of water is 540 cal/g and latent heat of melting of ice
is 80 cal/g. If the point P is at a distance of x from the ice end A, find the value of . [Neglect any heat
loss to the surrounding.]
Sol. 9

vapour
ice
dm
dm
dt dt
=

ice vapour
400kS 300kS
xL (100 )xL
=

= 9
x P

(10 )x

400C
0C (ice)

100C (steam)

54. Two soap bubbles A and B are kept in a closed chamber where the air is maintained at pressure 8 N/m
2
.
The radii of bubbles A and B are 2 cm and 4 cm, respectively. Surface tension of the soap-water used to
make bubbles is 0.04 N/m. Find the ratio n
B
/n
A
, where n
A
and n
B
are the number of moles of air in bubbles
A and B, respectively. [Neglect the effect of gravity.]
Sol. 6
P
A
= P
0
+
A
4T
R
= 16 N/m
2

P
B
= P
0
+
B
4T
R
= 12 N/m
2

3
B B B
A A A
n P R
6
n P R
| |
= =
|
\ .

A

B

8 N/m
2
R
A
R
B
2 cm
4 cm

55. A 20 cm long string, having a mass of 1.0 g, is fixed at both the ends. The tension in the string is 0.5 N. The
string is set into vibrations using an external vibrator of frequency 100 Hz. Find the separation (in cm)
between the successive nodes on the string.

Sol. 5
v =
T
= 10 m/s
20 cm


=
v 10
f 100
= = 10 cm
Distance between the successive nodes = /2 = 5 cm

56. Three objects A, B and C are kept in a straight line on a frictionless horizontal surface. These have masses
m, 2m and m, respectively. The object A moves towards B with a speed 9 m/s and makes an elastic
collision with it. Thereafter, B makes completely inelastic collision with C. All motions occur on the same
straight line. Find the final speed (in m/s) of the object C.

2m
m m
A B C

Sol. 4
After 1
st
collision
mv
A
=
A B
mv 2mv +
1 =
B A
A
v v
0 v

B
v = 6 m/s
After 2
nd
collision

( )
B C
2mv 2m m v = + v
C
=
B
2
v
3
v
C
= 4 m/s
9 m/s
m 2m m

A
B C

57. A cylindrical vessel of height 500 mm has an orifice (small hole) at its bottom. The orifice is initially
closed and water is filled in it upto height H. Now the top is completely sealed with a cap and the orifice at
the bottom is opened. Some water comes out from the orifice and the water level in the vessel becomes
steady with height of water column being 200 mm. Find the fall in height (in mm) of water level due to
opening of the orifice.
[Take atmospheric pressure = 1.0 10
5
N/m
2
, density of water = 1000 kg/m
3
and g = 10 m/s
2
. Neglect any
effect of surface tension.]
Sol. 6
P = P
0
gh = 98 10
3
N/m
2

P
0
V
0
= PV
10
5
[A(500 H)] = 98 10
3
[A(500 200)]
H = 206 mm
Level fall = 206 200 = 6 mm

H 500 mm

200 mm
500 mm

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ion in an aqueous solution, E

in aqueous solution is(are)

= All V, Fe, Hg have less SRP w.r.t.

. Then the value of f(ln5) is

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