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    KJB Test - 2 Electrochemistry

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    Lalita
    This document provides a chemistry practice test on electrochemistry with 23 multiple choice questions. Some of the questions ask students to: 1) Calculate standard reduction potentials, electrode potentials, and cell potentials from half reactions. 2) Determine the spontaneity and cell reactions from standard potentials. 3) Use the Nernst equation to calculate cell potentials with non-standard concentrations. The test covers concepts related to galvanic cells, concentration cells, the Nernst equation, standard reduction potentials, cell notation, and thermodynamics of cell reactions.

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    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd

    KJB Test - 2 Electrochemistry

    Uploaded by

    Lalita
    38 views2 pages
    This document provides a chemistry practice test on electrochemistry with 23 multiple choice questions. Some of the questions ask students to: 1) Calculate standard reduction potentials, electrode potentials, and cell potentials from half reactions. 2) Determine the spontaneity and cell reactions from standard potentials. 3) Use the Nernst equation to calculate cell potentials with non-standard concentrations. The test covers concepts related to galvanic cells, concentration cells, the Nernst equation, standard reduction potentials, cell notation, and thermodynamics of cell reactions.

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    Practice sheet

    Original Title

    KJB TEST -2 ELECTROCHEMISTRY

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    This document provides a chemistry practice test on electrochemistry with 23 multiple choice questions. Some of the questions ask students to: 1) Calculate standard reduction potentials, electrode potentials, and cell potentials from half reactions. 2) Determine the spontaneity and cell reactions from standard potentials. 3) Use the Nernst equation to calculate cell potentials with non-standard concentrations. The test covers concepts related to galvanic cells, concentration cells, the Nernst equation, standard reduction potentials, cell notation, and thermodynamics of cell reactions.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    38 views2 pages

    KJB Test - 2 Electrochemistry

    Uploaded by

    Lalita
    This document provides a chemistry practice test on electrochemistry with 23 multiple choice questions. Some of the questions ask students to: 1) Calculate standard reduction potentials, electrode potentials, and cell potentials from half reactions. 2) Determine the spontaneity and cell reactions from standard potentials. 3) Use the Nernst equation to calculate cell potentials with non-standard concentrations. The test covers concepts related to galvanic cells, concentration cells, the Nernst equation, standard reduction potentials, cell notation, and thermodynamics of cell reactions.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 2

    REVISION TEST -2 CLASS – XII [CHEMISTRY] CHAPTER –ELECTROCHEMISTRY

    VINAY GUPTA –B1 JANAKPURI SHAHGANJ AGRA - 7302699469 , 9412161447,8958541623

    MAXIMUM MARKS 41


    Q.1 Give Nernst equation to calculate electrode potential for any concentration of ions for the
    following electrochemical cell. [1]
    Ni(s) | Ni2+ (aq) | Ag+(aq) | Ag
    Q.2 Give the relation between equilibrium constant of the reaction and standard potential of the cell.[1]
    Q.3 Give relation between standard Gibbs energy of the reaction (ΔrG°) and standard potential of the
    cell. [1]
    Q.4 Consider the following half cell reactions:
    Mn2+ + 2e– → Mn E° = – 1.18V
    Mn2+ → Mn3+ + e– Eo = – 1.51V
    The Eo for the reaction 3Mn2+ → Mn+2Mn3+, and the possibility of the forward reaction are
    respectively. [2]
    (a) 2.69V and spontaneous (b) – 2.69 and non spontaneous
    (c) 0.33V and Spontaneous (d) 4.18V and non spontaneous
    Q.5 In the electrochemical cell: Zn|ZnSO4 (0.01M)||CuSO4 (1.0M)|Cu , the emf of this Daniel cell is E1.
    When the concentration of ZnSO4 is changed to 1.0 M and that CuSO4 changed to 0.0 1M, the emf
    changes to E2. From the followings, which one is the relationship between E1 and E2? [2]
    (a) E1 < E2 (b) E1 > E2 (c) E1 = E2 (d) none
    Q.6 Calculate ΔrG° for the reaction Fe2+(aq) + Ag+(aq) Fe3+(aq) + Ag(s) (E°cell = 1.57V). [2]
    Q.7 {JARA KARKE TO DEKHO OR KARKE DIKHAO … EASY HAI BUT NAYA HAI }
    Cell equation: A2+ + 2B– → A2+ + 2B
    A2+ + 2e– → A E° = + 0.34V and log10 K = 15.6 at 300K for cell reactions find E° for
    B+ + e– → B [2]
    (a) 0.80 (b) 1.26 (c) – 0.54 (d) – 10.94
    Q.8 Calculate the standard emf of the cell: Cd | Cd2+|| Cu2+ | Cu and determine the cell reaction. The
    standard reduction potentials of Cu2+ | Cu and Cd2+ | Cd are 0.34V and – 0.40 volts respectively.
    Predict the feasibility of the cell reaction. [2]
    Q.9 For the cell Mg(s) | Mg2+(aq) || Ag+ (aq) | Ag (s), calculate the equilibrium constant at 25°C and
    maximum work that can be obtained during operation of cell. Given: [3]

    Q.10 The emf of the following cell at 25°C is equal to 0.34v. Calculate the reduction potential of copper
    electrode. [1]
    Pt(s) | H2(g,1atm) | H+ (aq,1M) || Cu2+(aq,1M) | Cu(s)
    Q.11 The net redox reaction of a galvanic cell is given below
    2 Cr (s) + 3Cu2+(aq) → 2Cr3+(aq) + 3Cu(s)
    Write the half reactions and describe the cell using cell notation. [2]
    Q.12 Let us calculate the emf of the following cell at 25°C using Nernst equation.
    Cu (s) | Cu2+(0.25 aq, M) || Fe3+(0.05 aq M) | Fe2+(0.1 aq M) | pt(s) [3]
    Q.13 Consider the following statements.
    (i) Energy can neither be created nor be destroyed but one form of energy can be converted to
    another form
    (ii) In batteries, electrical energy is converted to chemical energy.
    (iii) Electrochemjcal reactions are redox reactions.
    Which of the above statement is / are not correct? [1]
    (a) i & ii only (b) ii only (c) i only (d) iii only
    Q.14 Consider the following statements:
    (i) In Galvanic cell, Zinc is oxidised to Zn2+ ions and Cu2+ ions are reduced to copper
    (ii) In Galvanic cell, Zn2+ ions are reduced to Zinc and copper is oxidised to Cu2+ ions
    (iii) In Galvanic cell, Zn and copper both get oxidised.
    REVISION TEST -2 CLASS – XII [CHEMISTRY] CHAPTER –ELECTROCHEMISTRY
    VINAY GUPTA –B1 JANAKPURI SHAHGANJ AGRA - 7302699469 , 9412161447,8958541623

    Which of the above statement is / are correct? [1]


    (a) (i) only (b) (ii) & (iii) (c) (ii) only (d) (iii) only
    Q.15 The salt bridge used in Daniel cell contains [1]
    (a) Na2SO4 + NaCl (b) Agar-Agar gel + Na2SO4
    (c) Silica gel + CuSO4 (d) ZnSO4 + CuSO4
    Q.16 Consider the following statements.
    (i) In Daniel cell, when the switch (k) closes the circuit, the electrons flow from Zinc strip to copper
    strip.
    (ii) In Daniel cell, when the switch (k) closes the circuit, the electrons flow from copper strip to Zinc
    strip
    (iii) In Daniel cell, when the Switch (k) opens the circuit, the electrons flow from Zinc to copper.
    Which of the above statement is / are correct? [1]
    (a) (i) only (b) (ii) & (iii) (c) (ii) only (d) (iii) only
    Q.17 The electrode used in SHE is made of …………. [1]
    (a) graphite (b) copper (c) platinum (d) iron
    Q.18 Gibbs free energy can be related to cell emf as follows. [1]
    (a) ΔG° = – nFEcell (b) ΔG° = – nFE°cell (c) ΔG = nFEcell (d) ΔG° = nFE°cell
    Q.19 The standard reduction potential for the half reactions are as ………..
    Zn → Zn2+ + 2e– E° = +0.76V
    Fe → Fe2+ + 2e–E° = + 0.41 V.
    Find EMF for cell reaction Fe2+ + Zn → Zn2+ + Fe . [2]
    Q.20 The standard emf for the given cell reaction Zn + Cu2+ → Cu + Zn2+ is 1.10V at 25°C. Find the emf
    for the cell reaction when 0.1 M Cu2+ and 0.1 M Zn2+ solutions are used at 25°C . [2]
    Q.21 Calculate the emf of the cell in which the following reaction takes place
    Ni(s) + 2Ag+(0.002 M) —> Ni2+(0.160 M) + 2 Ag(s)
    Given that E°cell = 1.05 V {log 4 =0.6020} [3]
    Q.22 Calculate emf of the following cell of 25°C.
    Fe | Fe2+(0.001M) || H+(0.01M) | H2(g) (1 bar) pt
    E0(Fe2+/Fe) = – 0.44V E0(H+/H2) = 0.00V [3]
    Q.23 The cell in which the following reaction occurs:
    2Fe3 +(aq) + 2I- (aq) → 2Fe2+(aq) + I2(s)
    has E°cell = 0.236 V at 298 K.
    Calculate the standard Gibbs energy and the equilibrium constant of the cell reaction.
    (Antilog 7.983 = 9.62 x 10 7 Antilog 9.346 = 4.5 x 10 7) [3]

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