Chemistry Class 12 Boards Electrochemistry Pyq
Chemistry Class 12 Boards Electrochemistry Pyq
Chemistry Class 12 Boards Electrochemistry Pyq
(2020)
SA (2 marks)
(2/5, 2020)
VSA (1 mark)
reaction
Zn(s) + Cu2+
(aq) → Zn2+
SA (2 marks)
MnO–
4(aq) + 8H+
(aq) + 4H2O(l),
E° = + 1.51V
Sn2+
(aq) → Sn4+
LA I (3 marks)
(Delhi 2011C)
SA (2 marks)
Mg(s) + Cu2+
(aq) Mg2+
(aq) + Cu(s)
Given E°
(2/3,AI 2014)
A(s) + B2+
(aq) A2+
(aq) + B(s)
(2/3,Foreign 2014)
the reaction.
Zn(s) + Cu2+
(aq) → Zn2+
(aq) + Cu(s)
potential.
Ni(s) + 2Ag+
(aq) → Ni2+
(1 F = 96500 C mol–1)
LA I (3 marks)
Zn(s) + Cu2+
(aq) Zn2+
(aq) + Cu(s)
Given : E° for Zn2+/Zn = –0.76 V and
(3/5, 2020)
Ni(s) + 2Ag+
(aq) Ni2+
(aq) + 2Ag(s)
Given :
E°
Ni2+/Ni = –0.25 V, E°
Ag+/Ag = + 0.80 V
Given : E°
Zn2+/Zn = –0.76 V, E°
Ag+
/Ag = + 0.80 V
reaction.
Cd2+
(aq) + Cd(s)
(AI 2019)
+ 2Cl–(0.1 M)
Given : E°
(Cr3+|Cr) = –0.74 V, E°
(Fe2+|Fe) = –0.44 V
(Delhi 2016)
298 K.
(Delhi 2015)
25°C.
E E Zn Zn H H 2 V V
2 + + 0 76 0 00 ° ° = − =
/(/) .,.
(Foreign 2015)
24. For the cell reaction,
Ni(s) |Ni2+
(aq)||Ag+
(aq)|Ag(s)
E E ( / ) / . . Ni Ni Ag Ag 2+ + 0 25 0 V and V 80 ° ° = − =
takes place :
Fe2+
(aq) + Ag+
(aq) → Fe3+
(aq) + Ag(s)
of the reaction.
EE
Ag Ag Fe Fe + + V V + ° ° = = ( ) / / 0 8. ; 0 0 3 2 .77
[Given : E°
reaction,
2
3
298 K :
25°C :
(AI 2013)
(aq) + 2Ag(s)
+ 2OH–
(aq)
occurs :
2Fe3+
(aq) + 2I–
(aq) → 2Fe2+
(aq) + I2(s)
; of 8.0
= 10 × 108
(Delhi 2012C)
(aq) and
1.0 × 10–4 M H+
Cr2O2–
7(aq) + 14H+
(aq) + 7H2O(l)
EE
Zn Zn Cu Cu 2 2 + + 0 76 0 V V 34 ° ° =− =+
//.;.
(Delhi 2011C)
reaction at 298 K,
Zn(s) + Cu2+
(aq) Zn2+
(aq) + Cu(s)
E E Zn Zn Cu Cu 2 2 + + 0 76 0 V V 34 ° ° =− =+ / / . ; .
(AI 2011C)
LA II (5 marks)
Mg Cu M Mg M Cu () () s s + → ( . ) ( . )+
22++
0 01 0 001
Mg(s)
EE
( / ) ( / ) , . Mg Mg Cu Cu 2 2 2 37 0 V V 34 + +
°°=−⋅=+
(AI 2015)
VSA (1 mark)
increases on dilution.
Assertion (A).
Assertion (A).
is incorrect statement.
(Delhi 2011)
SA (2 marks)
electrodes.
(Given : E°
Cu2+/Cu = + 0.34 V,
E°
(1/2Cl2/Cl–) = + 1.36 V
E°
H+
/H2
(g), Pt = 0.00 V, E°
(1/2 O2
/H2
O) = + 1.23 V)
(2/5, 2020)
B.
39.05 S cm2
mol–1.
mol–1 and
mol–1)
(Delhi 2017)
degree of dissociation.
(2/5, AI 2015C)
(AI 2014)
(2/3, AI 2014C)
390 S cm2
LA I (3 marks)
electricity.
CH3COOH solution.
is 5 × 103
ohm.
of dissociation (a).
mol–1 and
mol–1]
(3/5, AI 2016)
mol–1 and
while l° SO2–
4 is 160 S cm2
mol–1, calculate
(AI 2013C)
50 cm is 5.55 × 103
ohm. Calculate
(AI 2012C)
mol–1
mol–1
LA II (5 marks)
68. (a) Define molar conductivity of a solution
electrolyte.
Electrolysis
VSA (1 mark)
(1/5, 2018)
solution : Ag+
H+
(aq) + e– 1
H2( ) g , E° = 0.00 V
(Delhi 2015)
chloride solution :
Cu2+
H+
(aq) + e– 1
H2( ) g ; E° = 0.00 V
(Delhi 2015C)
SA (2 marks)
(2/5, 2020)
15 minutes.
the following :
platinum electrodes.
by
(2/3, AI 2013C)
1 mole Cr2O7
2– to Cr3+?
(2/3, Delhi 2012C)
(2/5, AI 2011)
LA I (3 marks)
1 F = 96500 C mol–1]
(AI 2019)
occurs :
2Fe3+
(aq) + 2I–
(aq) → 2Fe2+
(aq) + I2(s)
has E°
(AI 2017)
3.6 Batteries
VSA (1 mark)
SA (2 marks)
Dry cell
Programme?
inverters?
(Delhi 2016)
(2/5, AI 2015)
(Delhi 2011C)
VSA (1 mark)
(2/5, 2018)
(AI 2011C)
3.8 Corrosion
VSA (1 mark)
E(Fe /Fe) 2+ 0 4. 4 ° = −
E E ( / A A) B B
. V; . V
(/)
2 2 + 2 37 0 14 + ° = − ° =
(AI 2016)
SA (2 marks)
(Delhi 2011)
LA I (3 marks)
105. What is corrosion? Explain the electrochemical theory of rusting of iron and write the
(Delhi 2012C