Ce - 5

CHEMICAL EQUILIBRIUM - SHEET -5
(Physical Equilibrium And Its Applications Heterogeneous Equilibrium)

LEVEL -1
1. The partial pressure of CO, in reaction CaCO3(s) CaO(s) + COz(g)is 0.773 mmHg at 500°C.
Calculate the degree of dissociation at 600°C, if reaction is started with 100g CaCO, and volume
reaction vessel is 1L. AH for the reaction is 43.2 kcal/mole.
2. A liquid is in equilibrium with its vapour in a sealed container at a fixed temperature. The volume of
the container is suddenly increased
(a) What is the initial effect of the change on vapour pressure?
(b) How do rates of evaporation and condensation change initially?
(c) What happens when equilibrium is restored finally and what will be the final vapour pressure?
3. Solid NH l on rapid heating in a closed vessel at 357°C develops a constant pressure of 275 mm Hg
owing to partial decomposition of NH4I into NH, and Hl but the pressure gradually increases further
(when the excess solid residue remains in the vessel) owing to the dissociation of HI. Calculate the
final pressure developed at equilibrium.
NH,I(S) NH, (9) + HI(g)
2HI(g) H2(g) + 12(g). K =0.065 at 357°C
4. The following data for the equilibrium composition of the reaction2Na(g) Na(g)at 1.013 MPa
pressure and 1482.53 K have been obtained.mass % Na (monomer gas) is 71.3 and mass % Na2
(dimer gas) is 28.7. Calculate the partial pressures of Na and Na,: also calculate the equilibrium
constant Kp.
5 At 90°C, the following equilibrium is established :Hz(g) + S(s) H,S(g) Kp = 6.8 x 10".If 0.2 mol
of hydrogen and 1.0 mol of sulphur are heated to 90°C in a 1.0 litre vessel,what will be the partial
pressure of H2S at equilibrium?
6 Anhydrous calcium chloride is often used as a dessicant. In the presence of excess of CaClz, the
amount of the water taken up is governed by Kp = 6.4 x 1085 for the following reaction at room
temperature, CaClz6) + 6H,O CaCl, .6H,O9. What is the equilibrium vapour pressure of
water ina closed vessel that contains CaClzs)?
7 20.0 grams of CaCOse) Were placed in a closed vessel, heated & maintained at 727° C under
equilibrium CaCO,(9) CaO() + COx@) and it is found that 75 % of CaCO, was decomposed. What is
the value of K,? The volume of the container was 15 litres.
8 Following equilibria are established on mixing two gases Az and C
3Az(g) As(g) Kpt = 1.6 atm?
A(g) + C(g) AzC(g) Kpz =?
If A, andC are mixed in 2:1 pressure ratio then calculate Kpz if total pressure after establishment of
equilibrium is 1.4 atm and partial pressure of As is 0.2atm at equilibrium. Express your answer after
multiplying with 6.
The equlibrium constant for the following reaction at 1395 K.

2H,0 2H, + O; K, =2.1 x 10-13
2C0, 2C0 + O2 K = 1.4x 10-12
Calculate the value of Kfor the reaction: H, + CO, C0 + H,0
10 (a) The equilibrium Hzg) + CO29) H,Oa + COa is established in an evacuated vessel at 723K
starting with 0.1 mole of H2 & 0.2 mole of CO2. If the equilibrium mixture contains 10 mole
percent of water vapour, calculate K, given that the equilibrium pressure is 0.5 atm. Calculate
the partial pressures of the component species &the volume of the container.
(b) Ifnow, into the flask (mentioned in the preceding problem), solid CoO &solid Co are introduced
two new equilibria are established.
CoO(s) +Hg) Co(s) +H,0(g) ; CoO(s) +CO(g) Co(s) +CO-(9)
The new equilibrium mixture contains 30 mole percent of water vapour. Calculate the equilibrium
constants for the new equilitbria.
LEVEL - 2
11 For following equilibrium A B C

first equilibrium constant is k; and second equilibrium constant is ka
For above equililbrium which of the following is/are correct.
(A) k, will always be greater than k, (B).(1-x)
K,
(C) k,4l-x)y (D) None of these
(x-y)
12. Two systems PCls(g) PClH(g) + Chg) and COClh(g) CO(g) + Ch(g) are simultaneously in
equilibrium in a vessel of fixed volume. If some CO is introduce into the vessel, then at the new equilibrium the
concentration of
(a) PCls is greater (b) PCI, remain unchanged

(c) PCls is decreasing (d) Clh is greater
13 CuSO. . 5H,0(s) CuSO 3H,0(s) + 2H,0(v) K, for this reaction is 10 atm. Vapour
pressure of water at 25 °C is 30.4 mm at 25 °C is 30.4 mm at 25 °C. At what relative humidities will
CuSO, . 5H,0(s) be efflorescent when exposed to air at 25 °C?
(A) Below 25% (B) Above 25%
(C) At 25% (D) Any
4 The value of AG, of gaseous mercury is 31 kJ/mole. At what total external pressure mercury
startboiling at 25°C. (R= 8.3] (B) 10125
(A) 10
(C) 10$52 (D) 10312
15. When pressure is applied to the ice water equilibrium, which of the following phenomenon will
happen?
(A) More ice wil be formed (B) Water will evaporate
(C) More water will be formed (D) lce sublimes
ANSWERS KEY - CHEMICAL EQUILIBRIUM - SHEET-5
1. 2.21 x 10-4
3 314.1 atm
4 PNa =0.843 M Pa; PNa2=0.170M Pa:
Kp =0.239
5 0.379 atm
6 PH20 =5 x 101 atm
7 0.821 atm
8 9
9 K= 2.58
10 (a) K = 7.563 x 10, v = 35.62, p(H,0) = p(CO) = 0.05atm, p(H) = 0.1167atm, p(CO,) =
0.2833atm
(b) K, =9, K, = 119
11 C
12
13 A
14 A
15

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CHEMICAL EQUILIBRIUM - SHEET -5

(Physical Equilibrium And Its Applications Heterogeneous Equilibrium)

The equlibrium constant for the following reaction at 1395 K.

11 For following equilibrium A B C

(a) PCls is greater (b) PCI, remain unchanged

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