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International University, Vietnam National University - HCMC 1

CHEMISTRY LABORATORY

qREPORT
EXPERIMENT 5: FACTORS AFFECTING REACTION RATE

Group: _____1________ Section: ______5________ Date: _30/03/2022______

Group members:

Seq. Full name Student ID % contribution Signature Score


(total = 100%)
1 Phạm Đức Đạt ITITIU20184 25%

2 Huỳnh Lam Đạt ITITIU20364 25%

3 Nguyễn Văn Đạt ITITIU19100 25%

4 Mai Nguyễn An IEIEIU20120 25%

Total score: ________/15__

Present well: + 1 point

Clear picture: + 1 point

Total = 15 points

The report must be typed and handed in together with the signed data sheet by the deadline
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CHEMISTRY LABORATORY

I. Introduction (1 pt)
(Introduce what experiments you do in this report)
The speed of a chemical reaction is reflected in its rate. The type of the reactant, the
temperature, the surface of the reactants, the concentration, the catalyst, and the reaction
pressure are all elements that might impact the pace of the reaction. The faster the reaction, the
bigger the rate of reaction. is a response. To ascertain the quantity of reactants used up or the
products created, we may calculate the amount of reactants used up or the amount of products
formed. The rate at which something happens The purpose of every experiment we conduct is
to investigate the effects of concentration, temperature, and catalysts. on the pace of response

II. Experimental (1 pt)


(Describe what experiments you did in this report, write down each step of your experiments)
1. Equipment
Name Number

stirring rod 1

test tubes 12

test tube rack 1

a stopwatch 1

medicine dropper 1

Water bath 1

Ice bath 1

Beaker 150 mL 1
2. chemicals
0.5M K2CrO4
Concentrated HCl
6M NaOH
Methyl violet
0.1M FeCl3
0.1M KSCN
0.1M CaCl2
6M HCl
0.1M Na2C2O4
0.1M H2C2O4
6M NH4OH
0.1M AgNO3
0.1M CaCl2
Distilled water

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III. Results and discussion

1. EFFECT OF CONCENTRATION ON REACTION TIME (5 pts)

Reaction 1:

2I- + S2O8- 2 + 2SO42-

Reaction 2:

I2 + 2S2O32- -
+ S4O62-

Calculate the initial concentrations of I- and S2O82- ions:

Mixture # 5:

[I-] = (4.0 mL x 0.2 mL) / 29.0 mL = 0.027 (mol/L)

[S2O82-] = (10.0 mL x 0,1 mL) / 29.0 mL = 0.034 (mol/L)

Mixture Iodide ion Peroxydisulfate Time in seconds

1 0.069 0.034 107.8

2 0.058 0.034 207.6

3 0.048 0.034 179.8

4 0.037 0.034 193.1

5 0.027 0.034 260.3

6 0.017 0.034 301.5

Mixture Iodide ion Peroxydisulfate Time in seconds

7 0.068 0.029 169.7

8 0.068 0.024 226.6

9 0.068 0.019 321.6

10 0.068 0.014 330.7

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11 0.068 0.008 378.9

Plotting the concentration of iodide ion versus time: [Note: X – axis: time; Y – axis:
concentrations].

- Mixtures # 1-6: Graph (1 pt)

The order of reaction with respect to iodide ion: (1) > (2) > (3) > (4) > (5) > (6)

Comments: (0.5 pts)

As the volume of iodine decreases, so does its concentration, resulting in slower reaction rates
and longer durations. The higher the concentration of reactant atoms and molecules, the more
likely they will collide. More collisions result in faster reaction rates. As a result, lower Iodine
concentrations in these reactions result in slower reaction rates and longer reaction times.

Adding starch at a high temperature speeds up the reaction, resulting in more accurate results.
We can conclude that the temperature of the starch can influence the reaction rate.

- Mixtures # 1, 7, 8, 9, 10, and 11: Graph (1 pt)

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The order of reaction with respect ro peroxydisulfate ion: (1) > (7) > (8) > (9) > (10) > (11)

Comments: (0.5 pts)

Peroxydisulfate concentration decreases as volume decreases, resulting in slower reaction rates


and longer durations. The higher the concentration of atoms and molecules in the reactant, the
more likely a combination will occur. More collisions result in faster reaction rates. As a
result, decreasing the concentration of peroxydisulfate in this reaction results in a slower
reaction rate and a longer reaction time.

Adding starch at high temperatures speeds up the reaction, resulting in more accurate results.
We can conclude that the temperature of the starch can influence the reaction rate.

2. EFFECT OF TEMPERATURE ON THE REACTION RATE (2 pts)

Reaction System:

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5H2C2O4 + 2KMnO4 + 3H2SO4 2MnSO 4 + K2SO4 + 10CO2 + 8H2O

Description of Predicted Observation Reaction Explanation


conditions outcome time

Room Colorless The purple 25.2s (0.5 pts)


temperature solution
The collision of atoms in solution
changes into
provided enough energy to break
colorless
the chemical bond and form new
slowly
substances (at a normal speed).

Colorless The purple 3.2s (0.5 pts)


solution
500C Atmospheric collisions between
changes into
atoms in solution produced the
colorless in a
energy needed to break the
short time
chemical bond and form new
substances. However, as the
temperature was raised, the atoms
moved quicker and more energy
was created, causing the reaction to
speed up.

900C Colorless The purple 0.5s (0.5 pts)


solution
The extremely high temperature
changes into
caused the atoms in substances to
colorless
travel at a breakneck pace, causing
immediately
the reaction to occur almost
(very fast)
instantly.

Comment: (1pt)

- The projected result is comparable to actual observation.

- The temperature is the most important element in determining how long a reaction takes.

- The reaction takes place under typical conditions at room temperature.

- As the temperature rises, more energy is delivered to the atoms and molecules of the
reactants, causing them to move faster and increase collisions. As a result, the reaction rate is
higher, and less time is spent. The reaction occurs more quickly as the temperature rises.

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- When compared to other groups and book theories, our report's reaction time was a few
seconds longer. Because we took the test tube of solution out of the water bath and poured it
for longer than 3 minutes, or we put the test tube in the water path for less than 3 minutes, it
wasn't hot enough to react quickly. As a result, we should heat the test tube thoroughly and not
rush the procedure in order to achieve the desired temperature and reaction time.

3. EFFECT OF A CATALYST ON THE REACTION RATE (3 pts)

Reaction System:

H2O2 ⇌ H2O + O2

Trial Description of Predicted Observation Explanation


conditions outcome (Reaction rate)

1 + MnCl2 Slow The reaction (0.25 pts)


was slow (12.4s)
*The reaction released air
bubbles, but just a few at a time.
As a result, MnCl2 proved
ineffective as a hydrogen
peroxide breakdown catalyst.

2 + MnO2 Very fast The reaction (0.25 pts)


was very fast
*A considerable number of air
(3.7s)
bubbles, as well as heat, were
created by the reaction. H2O2 is
broken down into H2O and O2 via
MnO2 catalysis.

3 + NaCl Very slow The reaction (0.25 pts)


was very slow
*NaCl was not an effective
(140.3s)
catalyst for this reaction since the
bubbles were slow and little

4 + CaCl2 Slow The reaction (0.25 pts)


was slow
*CaCl2 wasn't the best catalyst
(13.04s)
for this reaction, and it didn't
assist much with speeding it up.

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As a result, the reaction took a


long time to take place.

5 + Zn Very slow The reaction (0.25 pts)


was very slow
Because the bubbles were slow
(43.3s)
and little, Zn may not be a
catalyst for this reaction.

6 + KNO3 (0.25 pts)

7 + Fe(NO3)3 Fast The reaction (0.25 pts)


was fast (3.2s)
*The catalyst for this reaction was
Fe(NO3)3, which allowed the
reaction to proceed quickly.

The order of catalyst activity: (0.5 pts)

NaCl < Zn < CaCl2 < MnCl2 < Fe(NO3)3 < MnO2

Comments: (0.75 pts)

- A catalyst is a chemical that speeds up a reaction without being consumed in the process. The
mass of the catalyst at the end of the reaction is the same as it was at the start.

- The speed with which bubble air appears shows the effect of the catalyst on the reaction rate,
thus we need to carefully consider and select suitable catalysts before doing the experiment in
order to observe the phenomena and obtain the desired findings.

IV. Conclusions (1 pt)


(conclude all your performance in this report)

In response to the presence of components that affect reaction rate, the experiment modifies
the reaction rate. These factors just speed up the reaction and have no influence on the
chemical properties of the reactants and products.

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