AuChem10142C Quiz#7- Ch8

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Question 1.
A solution contains 0.36 M HA (Ka = 2.0 10-7) and 0.24 M NaA. Calculate the pH after 0.04 mol of NaOH is added to 1.00 L of this solution. A) 6.76 B) 6.52 C) 6.64 D) 6.40 E) 6.70

Required. a b c d e

Question 2.
Consider a solution of 2.0 M HCN and 1.0 M NaCN (Ka for HCN = 6.2 1010). Which of the following statements is true? A) The solution is not a buffer because [HCN] is not equal to [CN ]. B) The pH will be below 7.00 because the concentration of the acid is greater than that of the base. C) [OH] > [H+] D) The buffer will be more resistant to pH changes from addition of strong acid than to pH changes from addition of strong base. E) All of these statements are false. Required. a b c d e

Question 3.

A 50.00-mL sample of 0.100 M KOH is titrated with 0.100 M HNO3. Calculate the pH of the solution after the 52.00 mL of HNO3 is added. A) 6.50 B) 3.01 C) 2.71 D) 2.41 E) none of these Required. a b c d e

Question 4.
After adding 25.0 mL of 0.100 M NaOH to 100.0 mL of 0.100 M weak acid (HA), the pH is found to be 5.90. Determine the value of Ka for the acid HA. A) 1.6 10-11 B) 4.2 10-7 C) 2.1 10-5 D) 3.5 10-9 E) none of these

Required. a b c d e

Question 5.
The solubility of AgCl in water is _____ the solubility of AgCl in strong acid at the same temperature. A) greater than B) less than C) about the same as D) cannot be determined Required.

A B C D E

Question 6.
The solubility of Fe(OH)2 in water is 7.9 106 mol/L at 25 C. What is Ksp for Fe(OH)2 at 25 C? A) 4.9 1016 B) 2.0 1015 C) 6.2 1011 D) 2.5 1010 E) none of these Required. A B C D E

Question 7.
How many moles of CaF2 will dissolve in 3.0 L of 0.050 M NaF solution? (Ksp for CaF2 = 4.0 10 11 ) A) 8.9 109 mol B) 8.0 108 mol C) 4.8 108 mol D) 2.7 108 mol E) none of these Required. A B C D E Ch. 6 1. The equilibrium constant for A + 2B equilibrium constant for 4A + 8B 2.

For the reaction 2NCl3(g) N2(g) + 3Cl2(g), the equilibrium pressures are P(NCl3) = 0.160 atm, P(N2) = 2.31 atm, P(Cl2) = 0.0565 atm. Determine Kp for this reaction. (Ans. 0.0163) 3. The reaction H2(g) + I2(g) 2HI(g) has Kp = 45.9 at 763 K. A particular equilibrium mixture at that temperature contains gaseous HI at a partial pressure of 3.50 atm and hydrogen gas at a partial pressure of 0.230 atm. What is the partial pressure of I2? (Ans 1.16 atm) 4. For the reaction, CaCO3(s) CaO(s) + CO2(g), Kp = 1.16 at 800.C. If a 25.0-g sample of CaCO3 is put into a 10.2-L container and heated to 800.C, what percent of the CaCO3 will react to reach equilibrium? (ans. 53.8%) 5. Consider the reaction 2NOBr(g) 2NO(g) + Br2(g). A 1.0-L vessel was initially filled with pure NOBr at a pressure of 3.8 atm and 300 K. At equilibrium, the partial pressure of NOBr was 2.0 atm. Determine the value of Kp for the reaction. (Ans. 0.73) 6. Consider the decomposition of hydrazine: N2H4(g) 2H2(g) + N2(g) At a certain temperature, Kp = 2.5 103. When pure hydrazine is placed in an otherwise empty vessel at this temperature, equilibrium is reached after 30.0% of the hydrazine has decomposed. Calculate the partial pressure of hydrogen gas at equilibrium. (Ans. 76 atm) 7. A sample of solid NH4NO3 was placed in an evacuated container and then heated so that it decomposed explosively according to the following reaction: NH4NO3(s) N2O(g) + 2H2O(g) At equilibrium, the total pressure in the container was found to be 2.03 atm at a temperature of 500C. Calculate Kp. (Ans. 1.24) 8. Consider the following reaction: 2NOCl(g) 2NO(g) + Cl2(g). Initially pure NOCl(g) is placed in a vessel at 3.00 atm. At equilibrium, 0.416% of the NOCl has decomposed. Determine the value for Kp. (Ans. 1.09 107) 9.

In the reaction P4(g) 2P2(g) Kp = 0.500 atm at 1052C. In an experiment, P4(g) is initially placed into a container at 1052C. The total pressure of the equilibrium mixture of P4(g) and P2(g) is 6.00 atm. Calculate the equilibrium pressures of P4(g) and P2(g). Calculate the fraction (by moles) of P4(g) that has dissociated to reach equilibrium (Ans: Pressure of P4 = 4.50 atm; Pressure of P2 = 1.50 atm; 14.3% has dissociated). 3C is 1.0 10-6. Determine the 12C. (Ans. 1.0 10-24) Ch. 7 10. Which of the following is a conjugate acid-base pair? a) HCl/OCl3 b) H3PO4/PO43 c) NH4+/NH3 (Ans.: c) 11. Which of the following represents a conjugate acid-base pair? a)H2PO4 and PO43b)HSO4 and SO32 c)HNO3 and NO3 (Ans.: c) 12. The hydrogen sulfate or bisulfate ion HSO4 can act as either an acid or a base in water solution. In which of the following equations does HSO4 act as an acid? a)HSO4 + H2O H2SO4 + OH b) HSO4 + H3O+ SO3 + 2H2O c)HSO4 + H2O SO42 + H3O+ (Ans: c) 13. The strong acid HA is added to water. Which of the following is the strongest base in the system? a)HA b)H2O c) A (Ans: b) 14. Given that the Ka for HOCl is 3.5 10-8, calculate the K value for the reaction of HOCl with OH. (Ans. 3.5 106) Find the pH of a solution at 25C in which [OH] = 4.3 108 M. (Ans.: 6.63) 15. 16. Calculate the pH of a 1.9 M solution of HNO3. (Ans: 0.28 ) 17. Calculate the pH of a 0.040 M perchloric acid (HClO4) solution. (Ans: 1.40) 18. Calculate the pH of a solution made by mixing equal volumes of a solution of HCl with a pH of 1.44 and a solution of HNO3 with a pH of 2.74. (Assume the volumes are additive.) (Ans: 1.72) 19. The pH of a 0.6 M solution of a weak acid is 4.0. What percent of the acid has ionized? (Ans. 0.02%) 20. For nitrous acid, HNO2, Ka = 4.0 104. Calculate the pH of 0.33 M HNO2. (Ans. 1.94)

21. A monoprotic weak acid, when dissolved in water, is 0.92% dissociated and produces a solution with pH = 3.42. Calculate Ka for the acid. (Ans: 3.5 106) 22. The pH of a 0.025 M weak acid solution is 5.29. Calculate Ka for this acid. (Ans. 1.0 109) 23. The pKa of HOCl is 7.5. Calculate the pH of a 0.5 M solution of HOCl. (Ans.: 3.9) 24. A 0.240 M solution of the salt NaA has pH = 8.40. Calculate Ka for the acid HA. (Ans.: 3.80 104 ) 25. Calculate the pH of a 0.02 M solution of KOH. (Ans: 12.3) 26. Calculate the pOH of a 0.10 M solution of Ba(OH)2 (Ans.: 0.70) 27. Calculate the pH of a 5.0 M solution of aniline (C6H5NH2; Kb = 3.8 1010). (Ans.: 9.64) 28. Calculate the pH of a solution made by mixing equal volumes of a solution of NaOH with a pH of 11.40 and a solution of KOH with a pH of 10.30. (Assume the volumes are additive.) (Ans.: 11.13) 29. The pH of a 2.1 103 M solution of a weak base is 9.87. Calculate Kb for this base. (Ans.: 2.6 106 ) 30. A 0.10-mol sample of a diprotic acid, H2A, is dissolved in 250 mL of water. Ka1 for this acid is 1.0 105 and Ka2 is 1.0 1010. Calculate the concentration of A2 in this solution. (Ans.: 1.0 1010 M) 31. What is the pH in a solution of 1.0 M H2A (Ka1 = 1.0 104; Ka2 = 1.0 1014)? (Ans. 2.00) 32. Calculate [H+] in a 1.0 M solution of Na2CO3 (for H2CO3, Ka1 = 4.3 107 and Ka2 = 5.6 1011). (Ans.: 7.5 1013 M) 33. What is the pH of a 0.2 M solution of NH4Cl? Kb for NH3 is 1.8 105. (Ans.: 5.0) 34. Calculate the [H+] in a 0.2 M solution of NaC2H3O2.(Ka for HC2H3O2 = 1.8 105) (Ans.: 10-9 M) 35. Calculate the pH of a 1.5 10-7 M solution of HCl. (Ans.: 6.70) 36. Calculate [OH] in a 4.0 10-8 M solution of NaOH. (Ans.: 1.2 10-7 M) Ch. 8 37. A solution contains 0.36 M HA (Ka = 2.0 10-7) and 0.24 M NaA. Calculate the pH after 0.04 mol of NaOH is added to 1.00 L of this solution. (Ans.: 6.64) 38. How many moles of HCl need to be added to 150.0 mL of 0.50 M NaZ to have a solution with a pH of 6.50? (Ka of HZ is 2.3 10-5.) Assume negligible volume of the HCl.mol (Ans: 1.0 10-3 mol) 39. Calculate the pH of a solution made by mixing 33.0 mL of 0.340 M NaA (Ka for HA = 1.0 10-8) with 26.4 mL of 0.100 M HCl. (Ans: 8.51)

40. Calculate [H+] in a solution that is 0.34 M in NaF and 0.58 M in HF. (Ka = 7.2 10 4 ) (Ans: 1.2 103 M) 41. For ammonia, Kb is 1.8 10-5 . What the ratio of NH4Cl to NH3 must be to make a buffered solution with pH 10.0, (Ans: 0.18 : 1.) 42. Calculate the pH of a solution prepared by mixing 50 mL of a 0.10 M solution of HF with 25 mL of a 0.20 M solution of NaF. pKa of HF is 3.14. (Ans.: 3.14) 43. For 105.0 mL of a buffer that is 0.40 M in HOCl and 0.36 M in NaOCl, what is the pH after 13.4 mL of 1.5 M NaOH is added? Ka for HOCl = 3.5 108. (Assume the volumes are additive.) (Ans: 7.88) 44. What is the pH of a solution that results when 0.010 mol HNO3 is added to 655.0 mL of a solution that is 0.22 M in aqueous ammonia and 0.50 M in ammonium nitrate. Assume no volume change. (Kb for NH3 = 1.8 105.) (Ans.: 8.85) 45. How many mmoles of HCl must be added to 160.0 mL of a 0.24 M solution of methylamine (pKb = 3.36) to give a buffer having a pH of 11.37? (Ans: 6.0 mmol) 46. A 74.0-mL sample of 0.13 M HNO2 (Ka = 4.0 104) is titrated with 0.14 M NaOH. What is the pH after 25.8 mL of NaOH has been added? (Ans.: 3.18) 47. A 100.-mL sample of 0.10 M HCl is mixed with 50. mL of 0.10 M NH3. What is the resulting pH? (Kb for NH3 = 1.8 105) (Ans.: 1.48) 48. Consider the titration of 100.0 mL of 0.250 M aniline (Kb = 3.8 1010) with 0.500 M HCl. Calculate the pH of the solution at the stoichiometric point. (Ans.: 2.68) Silver chromate, Ag2CrO4, has a Ksp of 9.0 1012. Calculate the solubility, in 49. moles per liter, of silver chromate. (Ans.: 50. The solubility of La(IO3)3 in a 0.10 M KIO3 solution is 1.0 107 mol/L. Calculate Ksp for La(IO3)3. (Ans.: 1.0 1010 ) 51. How many moles of Fe(OH)2 [Ksp = 1.8 1015] will dissolve in 1 L of water buffered at pH = 12.00? (Ans.: 1.8 1011 mol) 52. The value of Ksp for AgI is 1.5 1016. Calculate the solubility, in moles per liter, of AgI in a 0.50 M NaI solution. (Ans.: 3.0 1016 mol/L 53. Calculate the solubility of Ca3(PO4)2(s) (Ksp = 1.3 1032) in a 1.0 102 M Ca(NO3)2 solution. (Ans.: 5.7 1014 mol/L) 54. If 30 mL of 5.0 102 M Ca(NO3)2 is added to 70 mL of 2.0 102 M NaF, will a precipitate form? (Ksp of CaF2 = 4.0 1011). What are the concentrations of all ions remaining in the solution? (Ans.: Yes. [Ca2+] = 8 x 103 M, [F] = 7.1 x 105 M, + [NO3] = 0.03M, [Na ] = 0.014M.)

55. How many moles of Ca(NO3)2 must be added to 1.0 L of a 0.11 M HF solution to begin precipitation of CaF2(s)? For CaF2, Ksp = 4.0 1011. (Ans.: 3.3 109 mol) 56. One liter of a 1M solution of AgNO3 is mixed with one liter of a 2M solution of KBr. What is the final concentration of all the ions in the solution? The solubility product for AgBr is K sp = 5 "10#13 . (Ans: [K ] = 1M, [Ag ] = 1012M, [Br] = 0.5M, [NO3 ] = 0.5M). 1.3 104 M) + + !