Ionic equilibrium DPP 4 (1)

Ionic Equilibrium
DPPs By Sanjay Arya TG : Sanjay Arya Chemistry
LEVEL-1
Q1. Addition of HCl will not suppress the ionization of:
A) Acetic acid
B) Benzoic acid
C) H2S
D) Sulphuric acid
Q2. The following equilibrium exists in aqueous solution CH3COOH ⇌ CH3COO⁻ + H⁺. If dilute HCl is
added:
A) Acetate ion concentration will increase
B) Acetate ion concentration will decrease
C) The equilibrium constant will decrease
D) The equilibrium constant will increase
-5
Q3. Find the concentration of acetate ions in 0.1M acetic acid (Ka = 2 x 10 ) solution added with 0.1 M
HCl:
-5
A) 10 M
-1
B) 10 M
-2
C) 10 M
-4
D) 10 M
Q4. Calculate pH of solution obtained by mixing equal vol. of 0.02 M HOCl & 0.2 M CH₃COOH:
A) 2.7
B) 2.3
C) 3.3
D) 5.7
-10 -4
Q5. Values of dissociation constant Ka are given as follows: HCN - 6.2 × 10 , HF - 7.2 × 10 , HNO2 -
-4
4.0 × 10 . Correct order of increasing base strength of the base CN⁻, F⁻, and NO₂⁻ will be:
A) F⁻ < CN⁻ < NO₂⁻
B) NO₂⁻ < CN⁻ < F⁻
C) F⁻ < NO₂⁻ < CN⁻
D) NO₂⁻ < F⁻ < CN⁻
Q6. Which of the following is an acidic salt?

A) NH₄Cl
B) NaCl
C) NaHSO₄
D) NH₄NO₃
Q7. Which of the following salts is the most basic in aqueous solution?
A) FeCl₃
B) Pb(CH₃COO)₂
C) Al(CN)₃
D) CH₃COOK
Q8. Cationic hydrolysis will take place in case of:

A) Salts of strong acid and strong base
B) Salts of strong acid and weak base
C) Salts of weak acid and strong base
D) Salts of weak acid and weak base
Q9. The pH of ammonium phosphate solution, if pKa of phosphoric acid and pKb of ammonium
hydroxide are 5.23 and 4.75 respectively, is:
A) 6.0
B) 7.0
C) 8.0
D) 6.5
Q10. pKa of a weak acid (HA) and pKb of a weak base (BOH) are 3.2 and 3.4, respectively. The pH of
their salt (AB) solution is:
A) 6.9
B) 7.0
C) 1.0
D) 7.2
Q11. Calculate the pH of a solution containing equal molar amounts of acetic acid (CH3COOH) and
sodium acetate (CH3COONa):
A) 4.75
B) 3.75
C) 2.75
D) 6.75
-10
Q12. The solubility product of BaSO₄ is 1.1 × 10 . What is the concentration of SO₄²⁻ in a saturated
BaSO₄ solution?
-5
A) 1.05 × 10 M
-5
B) 2.10 × 10 M
-6
C) 1.1 × 10 M
-10
D) 1.1 × 10 M
Q13. What is the pH of a buffer solution that is 0.1 M in acetic acid and 0.1 M in sodium acetate? (Ka
-5
of CH₃COOH = 1.8 × 10 ):
A) 4.74
B) 5.74
C) 3.74
D) 6.74 (Answer: A)
Q14. A solution of NH₄OH and NH₄Cl has a pH of 9.25. What is the pOH of the solution?
A) 4.75
B) 5.75
C) 6.75
D) 7.75
-4
Q15. The dissociation constant (Ka) of formic acid is 1.8 × 10 . Calculate the degree of dissociation in
a 0.1 M solution of formic acid:
-2
A) 4.24 × 10
-2
B) 1.34 × 10
-2
C) 2.24 × 10
-2
D) 3.24 × 10
Q16. In a solution of 0.1 M acetic acid (Ka = 1.8 × 10^-5), the degree of dissociation is approximately:
-2
A) 1.34 × 10
-2
B) 2.4 × 10
-2
C) 3.2 × 10
-2
D) 4.2 × 10
Q17. The pH of a 0.1 M NaOH solution is:

A) 14
B) 12
C) 13
D) 11
-4
Q18. Calculate the pH of a mixture containing 0.02 M HOCl and 0.2 M NaOCl. (Ka of HOCl = 2 × 10 ):
A) 6.5
B) 7.7
C) 5.5
D) 4.7
Q19. A buffer solution is prepared by mixing 50 mL of 0.1 M NH₄OH with 50 mL of 0.1 M NH₄Cl.
-5
Calculate the pH. (Kb of NH₄OH = 1.8 × 10 ):
A) 9.26
B) 8.75
C) 7.8
D) 8.26
Q20. What will be the pH of a 0.05 M H₂SO₄ solution?
A) 1.3
B) 2.3
C) 0.7
D) 3.3
Answers LEVEL 1
Q1 Q2 Q3 Q4 Q5 Q6 Q7 Q8 Q9 Q10
D B A A C C D B B A
Q11 Q12 Q13 Q14 Q15 Q.16 Q.17 Q.18 Q.19 Q.20
A A A A A A C D A C
LEVEL-2
Q1. Calculate the pH of a solution containing 0.1 M NH₄Cl and 0.05 M NH₃ (K_b for NH₃ = 1.8 × 10⁻⁵).
A) 8.95
B) 8.50
C) 9.25
D) 9.50
Q2. Calculate the pH of a solution that contains 0.02 M CH₃COOH (Ka = 1.8 × 10⁻⁵) and 0.01 M HCOOH
(Ka = 1.77 × 10⁻⁴).
A) 2.87
B) 3.25
C) 3.15
D) 3.55
Q3. The Kb of a weak base BOH is 1.5 × 10⁻⁵. What is the K_a of its conjugate acid BH⁺?
A) 1.5 × 10⁻⁹
B) 6.7 × 10⁻¹⁰
C) 6.7 × 10⁻¹⁵
D) 6.67 × 10⁻⁵
Q4. Calculate the pH of a 0.01 M solution of sodium acetate (CH₃COONa) (Ka for CH₃COOH = 1.8 ×
10⁻⁵).
A) 9.12
B) 8.37
C) 9.45
D) 9.25
Q5. A solution contains 0.1 M CH₃COOH and 0.1 M HCOOH. If Ka(CH₃COOH) = 1.8 × 10⁻⁵ and
Ka(HCOOH) = 1.77 × 10⁻⁴, find the pH of the solution.
A) 2.5
B) 2.7
C) 2.2
D) 3.1
Q6. Calculate the pH of a 0.1 M NH₄OH solution to which 0.05 M NH₄Cl is added (K_b for NH₄OH = 1.8
× 10⁻⁵).
A) 8.94
B) 9.08
C) 9.22
D) 8.79
Q7. Find the pH of a solution containing 0.05 M CH₃COOH and 0.05 M HCOOH. The Ka values are
given as: Ka(CH₃COOH) = 1.8 × 10⁻⁵, Ka(HCOOH) = 1.77 × 10⁻⁴.
A) 2.67
B) 2.46
C) 3.12
D) 3.45
Q8. The pH of a 0.1 M solution of NH₄Cl is closest to:
A) 5.13
B) 5.64
C) 6.0
D) 4.85
Q9. If Ka of acetic acid is 1.8 × 10⁻⁵, calculate the Kb of acetate ion (CH₃COO⁻).
A) 5.56 × 10⁻¹⁰
B) 5.56 × 10⁻⁵
C) 1.8 × 10⁻⁹
D) 5.56 × 10⁻⁶
Q10. What is the pH of a 0.05 M solution of Na₂CO₃? (Ka1 for H₂CO₃ = 4.3 × 10⁻⁷, Ka2 = 5.6 × 10⁻¹¹).
A) 11.47
B) 10.92
C) 10.5
D) 11.25
Answers LEVEL 2
Q1 Q2 Q3 Q4 Q5 Q6 Q7 Q8 Q9 Q10
A A B B C B B A A A

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Ionic Equilibrium

DPPs By Sanjay Arya TG : Sanjay Arya Chemistry

Q6. Which of the following is an acidic salt?

Q8. Cationic hydrolysis will take place in case of:

Q17. The pH of a 0.1 M NaOH solution is:

Q8. The pH of a 0.1 M solution of NH₄Cl is closest to:

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