Assessment of Pretreatment Methods and Osmotic Dehydration For Cranberries
Assessment of Pretreatment Methods and Osmotic Dehydration For Cranberries
Assessment of Pretreatment Methods and Osmotic Dehydration For Cranberries
Department of Bioresource Engineering, McGill University, Ste. Anne de Bellevue, Quebec, Canada H9X 3V9
Sunjka, P.S. and Raghavan, G.S.V. 2004. Assessment of dipping of a product into a chemical solution (normally alkaline
pretreatment methods and osmotic dehydration for cranberries. or acid solution of oleate esters) of a specific concentration for
Canadian Biosystems Engineering/Le génie des biosystèmes au a specific amount of time. Mechanical pretreatment consists of
Canada 46: 3.35-3.40. In this research, different drying pretreatment skin abrasion, puncturing, or cutting the product into smaller
methods were tested on cranberry fruit (Vaccinium macrocarpon). pieces.
Mechanical and chemical pretreatments were examined, as well as
osmotic dehydration. Two types of assessed mechanical pretreatments One of the most useful pretreatments for drying of fruit is
were cutting the berries in halves and into quarters and chemical osmotic dehydration (Beaudry 2001). Osmotic dehydration is
pretreatment consisted of testing different temperatures of chemical the incomplete removal of water from a food product by means
agent and dipping times for cranberries. Osmotic dehydration involved of an osmotic agent (usually either sugar or salt solution). The
evaluation of different osmotic agents, their concentrations, and main advantage of this process is its influence on the principal
different times of osmotic dehydration. There were three observed drying method, shortening of the drying process, resulting in
parameters: mass gain, solids gain, and moisture loss. The mechanical lower energy requirements. Considering that heat is not applied
pretreatment that showed the best results for observed parameters was in this stage, osmotic dehydration offers higher retention of
cutting the berries into quarters, but chemical pretreatment showed no initial food characteristics, such as colour, aroma, nutritional
significant difference. Time and concentration of osmotic agent
constituents, and flavour compounds (Beaudry 2001).
significantly promoted the moisture removal and sugar uptake.
Keywords: cranberry, drying pretreatment, moisture loss, osmotic Skin pretreatment
dehydration.
Chemical pretreatment involves immersion of the product in
Dans cette étude, différentes méthodes de prétraitement pour le alkaline or acid solutions of oleate esters prior to drying.
séchage de la canneberge (Vaccinium macrocarpon) ont été évaluées. Alkaline dipping facilitates drying by forming fine cracks on
À savoir, la méthode mécanique, la méthode chimique et la méthode fruit surface (Salunkhe et al. 1991), and dipping in oleate esters
de déshydratation osmotique. En ce qui concerne la méthode causes wax platelets on the fruit skin to dissociate, helping the
mécanique, deux types de prétraitements ont été utilisés : le découpage removal of moisture (Venkatachalapathy 1998).
en deux ou en quatre des canneberges. La méthode chimique consistait
à optimiser température des agents chimiques et la durée d’immersion It was determined by Ponting and McBean (1970) that, for
des canneberges. La méthode de déshydratation osmotique impliquait fruits with a waxy surface layer, the most effective treatment is
l’évaluation des différents agents osmotiques, des concentrations, ainsi with ethyl esters of fatty acids, especially oleic acid. Saravacos
que des durées du prétraitement. Les paramètres utilisés pour comparer et al. (1988) and Tulasidas et al. (1994) used ethyl oleate (EO)
les méthodes étaient: le gain de masse du fruit, le gain des solides as a pretreatment, and found that it can improve the drying rate
solubles, et la perte d’eau. Les meilleurs résultats ont été obtenus avec with only a minor effect on product quality. Venkatachalapathy
le prétraitement mécanique avec découpage des baies en quatre (1998) used an alkaline solution of 2% EO and 0.5% sodium
quartiers. Le prétraitement chimique n’a montré aucune avantage sur hydroxide (NaOH) as a pretreatment for strawberries and
les baies non traitées. Le temps et la concentration de l’agent blueberries. Beaudry (2001) tested different concentrations and
osmotique avaient accentué l’élimination d’eau et d’accumulation de time periods of dipping for cranberries and concluded that these
sucre dans les baies. have no significant influence on subsequent osmotic
dehydration.
INTRODUCTION Mechanical pretreatment might replace or complement
chemical pretreatment, mainly because consumers hesitate to
Drying of fruits and vegetables is one of the most time and
buy chemically treated fruits, and it has a profound effect on the
energy consuming processes in the modern food industry. To
later drying process. Mechanical pretreatment consists of
reduce the processing time, thus facilitating and accelerating the peeling, surface abrasion, and cutting in various shapes, such as
dehydration process, a number of obstacles must be overcome. halves, cylinders, and cubes. A number of researchers (Shi and
The main problem in this food preservation method is the outer Maupoey 1993; Jia et al. 1993; Kiranoudis et al. 1997) used
layer of a particular commodity, the skin. The skin impedes some kind of mechanical treatment to accelerate mass transfer
water transport from the interior of a food product to its surface, in subsequent processing. There are several methods that can be
slowing the drying process. applied (Beaudry 2001), puncture the skin by a needle, cut the
There are two main methods to reduce the effects of skin berry in halves or quarters, and abrade the skin surface. All
resistance and promote water transport, chemical and these mechanical pretreatments are used to increase the "active"
mechanical pretreatments. Chemical pretreatment involves skin surface where water can penetrate.
Standard
6.0 52.3 a,b 77.0 66.4 d,c 88.0 43.5c
(no chemical pretreatment)
Duncan groupings: Means with the same letters are not significantly different.
Mass loss, solids gain, and moisture loss were calculated RESULTS and DISCUSSION
using Eqs. 1 to 3, respectively (Beaudry 2001):
Chemical and mechanical pre-treatment
m fin − mini Chemical pre-treatment Chemically pretreated cranberries
m gain = × 100 (1)
mini showed similar results to the standard sample (no chemical
pretreatment) for the majority of observed parameters. There
was some significance for some of the parameters, but the
msfin − msin standard gave better results in solids gain and moisture loss
s gain = × 100 (2) values. Thus, it can be concluded that chemical pretreatment has
mini no significant influence on improving water transfer during
osmotic dehydration of cranberries.
In Table 1, average soluble sugar contents in ºBrix of HFCS
M ini − M fin and cranberries at the start and at the end of experiment, as well
Wloss = × 100 (3) as the initial and final moisture contents of cranberries for each
M ini
method are presented. It can be observed from Table 1, that it is
where: possible to obtain with appropriate osmotic dehydration
mgain = mass gain (%), treatment almost 50% of moisture loss from 88% of initial
mfin = total mass after osmosis (g), moisture to 44.7% of final moisture in the method with 65°C
mini = initial mass before osmosis (g), and 180 s. But, the most important parameters for determination
sgain = solids gain (%), of effectiveness for the aforementioned methods are the three
msfin = mass solids after osmosis (g), parameters: mass gain, solids gain, and moisture loss. Their
msin = mass solids before osmosis (g), change can be seen in Table 2.
Wloss = moisture loss (%), Higher moisture loss for standard (50.6%) than for any of
Mini = initial moisture content (%, wb), and the chemically treated samples was not statistically significant,
Mfin = final moisture content (%, wb). and this study confirmed the results from similar experiments by
Beaudry (2001); chemical pretreatment has no significant
Equations 1 to 3 provide a quantitative description of influence on quantitative parameters that describe water
component transfer under osmotic dehydration. exchange between osmotic agent and fruit. The majority of
parameters had similar results as the standard sample (no
Experimental design chemical pretreatment). Therefore, in further experiments within
All experiments were performed in four replicates in order to this study, chemical treatment was not used.
assure better analysis of the statistical data. The data were Mechanical pretreatment The purpose of this method was to
subjected to the analysis of variance (ANOVA) and to Duncan's increase the available surface for water to depart from a
multiple range tests for pairwise comparison of each variable. produce. There are several methods of mechanical pretreatment,
Differences were determined as significant or non-significant at but only two were tested here, cutting into halves and cutting
a significance level of 0.05 in all cases. into quarters with a stainless steel knife. These methods were
compared with the standard (whole berries, with intact skin).
Duncan groupings: Means with the same letters are not significantly different. Osmotic dehydration time Time of
osmotic dehydration had a significant
effect on observed parameters
(Table 5 and Fig. 1).
The reason why only two methods were tested here is Time has a significant effect on solids gain (sugar uptake)
because a similar study was performed by Beaudry (2001), and and moisture loss; while for the mass gain, time has no effect.
it was determined that cutting into halves has significant However, considering that moisture loss is the most significant
difference compared to skin surface abrasion and puncturing the parameter of these three, and that osmotic dehydration for 24
skin with a needle. Therefore, cutting of the berry into halves hours had the highest percentage of moisture loss, this time of
was tested against cutting into quarters, for the same observed 24 hours is recommended for subsequent experiments.