Chemistry

Chemistry-I 7
 2
Classification of elements and
Periodicity in Properties
Very Short Answer Type Questions (2 Marks)
1. What are the representative elements? Give their valence shell configuration.
2.
B IE
Ans. S and P block elements excluding O group are called representative elements.
The valence shell configuration is ns1-2 np0-5
What factors impart characteristic properties to the transition elements?
Ans. The Vacant or partially filled d- orbital of penultimate shell small size, high nuclear charge
3.
T S
impart characteristic properties to the transition elements.
IE of O is less than that of N - explain.
Ans. Nitrogen has stable half filled P configuration. So more amount of energy is required to
4.
remove an electron from nitrogen than in oxygen. So IE of nitrogen is greater than that of
oxygen.
What is screening effect? How is it related to IE?
Ans. The inner shell electrons screen the outer shell electrons from the attractions of the nucleus.
This is called screening effect of shielding effect.
1
IE 
screeing effect
5. Why the Zero group elements are called noble gases or inert gases?
Ans. These contain stable octet configuration. So they are chemically inactive due to completely
filled orbitals in the outer shell ns2np6 (He-1s2). Hence these are called noble gases.
6. Na+ has higher value of ionization energy than Ne, though both have same electronic
configuration - explain.
Ans: Effective nuclear charge is more in Na+ than in Ne. So ionization energy of Na+ is more
than Ne.
8 Basic Learning Material
7. Electron affinity of chlorine is more than that of fluorine - explain

Ans: Fluorine has small size. More electronic repulsions exist in Fluorine. So electron affinity
of chlorine is more than that of Fluorine.
8. What are rare earths and transuranic elements?
Ans: The elements in which differentiating electrons enter into 4f orbitals are called rare earths
or lanthanoids. The elements after Uranium are called Transuranic elements and these
elements are man made. All are radio active elements.
Short Answer Type Questions (4 Marks)
1. Give any characteristic properties of transition elements.
Ans: a) They are hard and heavy metals.
b) They have high melting points, boiling points and densities.
c) They are good conductors of heat and electricity
d) They are good catalysts.
2.
e)
f)
They form alloys.
They exhibit variable oxidation states.
IE
What is diagonal relationship? Give a pair of elements having diagonal relationship.
Why do they show relation?
B
S
Ans: In the periodic table, an element of a group in the second period is similar in properties
with second element of next group in the third period. This type of relationship is called
T
diagonal relationship.
eg: (a) Li-Mg (b) Be-Al (c) B -Si
Group IA IIA IIIA IVA
2nd Period Li Be B C
3rd Period Na Mg Al Si
The diagonal relationship is due to
(a) Similar size of atoms or ions
(b) Similar Electro negativity
(c) Same polarizing power,
Where
Ionic charge
Polarising power 
Ionic radius
3. What is lanthanide contraction? What are its consequences?

Ans: Lanthanide Contraction : The steady decrease of atomic or ionic radii from left to right
in lanthanides is called lanthanide contraction.
It is due to poor shielding effect and peculiar shapes of f-orbitals.
Chemistry-I 9
Consequences:
(1) The properties of elements are similar. Therefore it is difficult to separate them from the
mixture.
(2) The atomic radii of 5d and 4d transition elements are very close to each other when compared
to those of 3d and 4d transition elements.
Long Answer Type Questions (8 Marks)
1. Write an essay on S, P, D and F block elements.
Ans: Based on electronic configuration, elements are classified into four blocks.
s-block p-block
d-block
B
f-block
IE
S
They are
s-Block elements
T
(a) The elements in which the differentiating electron enters into outer most 's' sub shell is
called S block elements.
(b) The position of 's' block elements is on the left side of the periodic table.
(c) 's' block contains two groups IA and IIA. These elements are called alkali metals alkaline
earth metals.
(d) The general electronic configuration of IA group of elements is ns1 and IIA group elements
is ns2.
(e) These are highly reactive elements and strongly electropositive in nature due to low
ionization enthalpy
(f) They do not occur free in state in nature, but occur as their compounds.
(g) They form +1 (IA) and +2 (IIA) oxidation states. These are metallic in nature.
p-block elements
(a) The elements in which the differentiating electron enters into 'p' sub shell are called 'p'
block elements.
(b) The position of 'p' block elements is on the right hand side of the periodic table
(c) 'p' block elements contain IIIA to VIIA and O groups.

(d) The general electronic configuration is ns2np1-6.
(e) p-block elements contain non metals, metalloids and metals.
d-block elements
(a) The elements in which differentiating electron enters into penultimate (n-1)d sub shell are
called d-block elements.
(b) The Position of d-block elements is in between s-block elements and p-block elements.
They are known as transition elements.
(c) The elements of IIIB to VIIB, VII, IB, IIB are d-block elements.
(d) The general configuration of these elements is (n–1)d1-10ns1-2.
(e) Based on the filling of the differentiating electron d Block is divided into 3d, 4d, 5d series
contains 10 elements and 6d series is incomplete.
E
f-block elements
I
(a) The elements in which differentiating electron enters into anti penultimate (n-2)f sub shell
are called f block elements.
S B
(b) The f block elements are placed in the bottom of the periodic table.
(c) f block elements contain two series 4f and 5f. Each series contains 14 elements.
(d) The general electronic configuration is (n–2)f1-14 (n–1)d0-1 ns2.
2.
(a) Atomic radiusT

(e) These are known as inner transition elements. They are radio active in nature.
What is a periodic property? How the following properties vary in a group and in a
period? Explain :
(c) Electron gain enthalpy

(b) ionisation enthalpy
(d) Electro negativity
Ans: The repetition of properties of elements at regular intervals in the periodic table are called
as periodic properties and the phenomenon is called periodicity.
(a) Atomic radius: The distance between the centre of the nucleus and the outermost shell of
an atom is called its atomic radius.
In a group: Atomic radius in a group from top to bottom increases, because in every
group, the differentiating electron enters into a new shell.
In a period: Atomic size decreases from left to right in a period, because the effective
nuclear charge increases as the differentiating electron enters into the same shell.
(b) Ionisation enthalpy: The energy required to remove an electron from an isolated gaseous
atom in its ground state is called ionisation enthalpy.
In a group: As atomic size increases in a group from top to bottom, the screening effect
Chemistry-I 11
increases. The nuclear attraction over valency electrons decreases and as a result IE decreases
down the group.
In a period: The atomic size decreases from left to right in a period, so the effective
nuclear charge increases and nuclear attraction on valence electrons increases as a result
I.E increases.
(C) Electron gain Enthalpy: The amount of energy released when an electron is added to the
valence shell of neutral gaseous atom is called electron gain enthalpy.
In a group: As we go down the group atomic size increases as a result the attraction
between added electron and nucleus decreases. Hence Electron gain Enthalpy decreases in
a group.
In a period: As we go from left to right in a period atomic size decreases. As a result, the
attraction between the added electron and nucleus increases. Hence electron gain enthalpy
increases in a period.
E
(D) Electro negativity: the tendency of an atom to attract the shared pair of electrons towards
I
itself is called electronegativity.
In a group: As we go down top to bottom in a group atomic size increases as a result of
decreases in a group.
S B
which the tendency of attraction of nucleus on shared pair decreases. Hence electro negativity
In a period: As we go from left to right in a period, atomic size decreases as a result of
T
which the tendency of attraction of nucleus on shared pair increases. Hence electro negativity
increases in a period.
3. Define IE1 and IE2. Why is IE2 is greater than IE1 for a given atom. Discuss the
factors that effect the IE of an element.
Ans. IE1: The minimum energy required to remove the most loosely bounded electron from an
isolated gaseous atom is called as first Ionisation Enthalpy.
M(g) + IE1  M+(g) + e–
IE2: The energy required to remove an electron from uni positive gaseous ion is called as
second Ionisation Enthlapy IE2.
M+(g) + IE2  M+2(g) + e–
IE2 > IE1: The second Ionization enthalpy is greater than first ionization enthalpy on
removing the electron from an atom. The unipositive ion is formed in that ion effective
nuclear charge increases ie the nuclear attraction increases on the remaining electrons.
Therefore more energy is required to remove an electron from uni positive ion.
IE1 < IE2 < IE3
Factors influencing the ionization enthalpy:

1. Atomic radius: As the atomic radius increases, the nuclear force of attraction over the
valence electrons decreases so IE is less.
1
IE 
Atomic radius
2. Nuclear charge: As the nuclear charge increases the force of attraction on the valence
electrons increases. Hence IE is more.
IE  Nuclear charge
3. Screening effect or shielding effect: The electrons present in inner orbitals decreases the
nuclear attraction on the valence electrons. This is called screening or shielding effect. As
the number of electrons in the inner shells increases, shielding effect increases. So IE is
less.
E
Ionisation enthalpy  1
I
screeing effect
4. Extent of penetration of orbitals of valence electrons:
S B
(a) Penetration Power of orbitals depends on the shape of the orbitals.
(b) Penetration power of orbitals is in the order : s > p > d > f
5. Half filled or completely filled sub shells: Atoms with half filled or completely filled sub
T
shells are more stable. So IE values of these atoms are high.
Chemistry-I 13
Unit 3
Chemical Bonding and Molecular Structure
1. What is Octet rule?
Ans. Atoms prefer to have eight electrons in their outermost orbits by losing, gaining or sharing
electrons, in order to have an Octet in their valence shell. This is known as Octet rule.
2. Write Lewi's dot structures for S and S-2.
Ans. The Lewis dot structure are:
S
-2
- S
S
–2
1s22s22p63s23p4
2 2 6 2 6
B IE
S
S - 1s 2s 2p 3s 3p
3. Predict the change if any, in hybridization of Al atom in the following reaction:
T
AlCl3 + Cl–  AlCl4–
Ans. In AlCl3, Al undergoes sp2 hybridization and the shape of the molecule is trigonal planar.
In AlCl4– & Al undergoes sp3 hybridization and the shape of the ion is tetrahedral.
4. Which of the two ions Ca+2 or Zn+2 in more table and why?
Ans. Ca+2 is more stable than Zn+2 because Ca+2 has Octet configuration in valence shell, where
as Zn+2 has pseudo Octet configuration in valence shell.
Ca+2 - 3s2p6 configuration having 8 electros in valence shell.
Zn+2 - 3s23p63d10 configuration having 18 electrons in valence shell.
5. Cl- ion is more stable than Cl atom. Why?
Ans: Cl- - possess 3s23p6 stable Octet configuration.
Cl - possess 3s23p5 does not have Octet configuration.
6. Why argon does not form Ar2 molecule?
Ans: Argon is monoatomic gas as it possess stable Octet configuration in its valence shell.
3s23p6. It cannot share its electron with another Ar atom and does not form diatomic
molecule.
7. How many Sigma and Pi bonds are present in (a) C 2H2, (b) C2H4 ?
Ans: In C2H2 [H – C  C – H] 3 Sigma bonds and 2 Pi bonds are present.
H H
In C2H4  [H - C| = C| - H] 5 Sigma bonds and 1 Pi bond is present.
8. Is there any change in the hubridization of Boron and Nitrogen atom as a result of
the following reaction: BF3 + NH3  F3BNH3
Ans: Before the reaction in the hybridization of Boson is sp2 and after the reaction it is sp3. But
for Nitrogen it is sp3 before and after the reaction.
..
BF3 + NH3  [H3 N  BF3]
sp2 sp3 sp3 sp3
E
9. Write the possible resonance structures for SO3?
I
O O O
Ans: S S S
B
O O O O O O
S
1. Define Dipole moment. Write its applications?
T
Ans: Dipile moment can be defined as the product of the magnitude of the change and the
distance between the charges. It is denoted by μ
=Q  l
 = Charge  distance between the charges
It is expressed in Debye units or coulomb meter
Q = Charge on dipole
l = distance between the dipoles.
Debye unit = 3.33  10-30 cm

Applications:
1. It is used to decide the polarity of the molecules. Molecules with zero dipole moment are
non-polar and those with dipole moment are polar.
2. It is used to fixed geometry of molecule.
2. What are  and bonds ? Specify the difference between them?
Ans: Sigma Bond (): A covalent bond formed by the end to end (head on) overlap of bonding
orbitals along with internuclear axis. This is called as head on overlap or axial overlap.
Pi Bond (): A covalent bond formed by a sidewise overlap or lateral overlap is called Pi
bond.
Chemistry-I 15
Differences between Sigma bond and Pi bond

Sigma Bond () Pi Bond ()
1. Sigma bond is formed by end to end 1. Pi bond is formed by parallel or lateral
(head on) overlap of bonding orbitals overlap of a bonding orbitals perpendicular
along the internucleus axis. to the internucleus axis.
2. It is a strong bond. 2. It is a weak bond.
3. It allows free rotation of atoms or 3. Pi bond restricts free rotation.
grops about the bond.
4. It can exist independently. 4. it is formed only after the '' bond is formed.
5. Hybrid orbitals forms only bonds. 5. Hybrid Orbitals cannot form bonds.
3. Explain the hybridization involved in PCl 5 molecule?
Ans: PCl5 - Phosphorous Pentachloride
P -15 3s23p3
3s 3p 3d
B IE Ground State configuration
First exicted State configuration
S
3s 3p 3d
1. Phosphorous is PCl5 molecule undergoes sp3d hybridisation.
Cl
T
Cl
2. One 's'and three 'p'and one 'd'orbitals of phosphorous atom undergo sp3d
hybridization gives 5 sp3d hybrid orbitals of equal energy. Cl P
3. These hybrid orbitals overlap with singly occupied p-orbitals of chlorine
Cl Cl
atoms to form 5 P–Cl sigma bonds.
4. PCl5 is having trigonal bipyramidal shape with bond angles 900 to 1200.
4. Explain the hybridization involved in SF6 molecule.
Ans: SF6 - Sulphur hexafluoride
S - 16
Ground State Configuration

3s 3p 3d
First exicted State configuration

3s 3p 3d
Second excited state configuration

3s 3p 3d
1. Sulphur in SF6 molecule undergoes sp3d2 hybridization. F

2. One 's'and three 'p'and two 'd'orbitals of Sulphur atom undergoes sp3d2 F F
hybridization. S
3. These 6 hybrid sp3d2 orbitals overlap with 6 singly occupied p - orbitals F F
of fluorine atoms to form 6sp3d2 - p sigma bonds. F
4. SF6 is having regular Octahedral shape.
5. Bond angle is 900 , 1800.
5. Explain the formation of coordinate covalent bond with one example.
Ans: 1) The covalent bond formed in which the shared pair of electrons is contributed by one
atom only.
2) The atom which denotes the shared pair of electrons is called as donor and that which
accepts the electrons is called as acceptor.
3) The bond between two atoms in which one donated a pair of electrons and other
eg: Formation of NH 4 +


H 

B IE
accepts a pair of electrons is called as coordinate covalent bond or dative bond.
S
 | 
H - N  H 
+
H3N: + H+    NH 4  or  
T
 | 
 H 
donor acceptor ammonium ion

Coordinate covalent bond is shown by arrow which is directed from donor to acceptor.
6. What is Hydrogen bond? Explain the different types of Hydrogen bonds with example.
Ans: Hydrogen bond is defined as the electrostatic forces of attraction between a partially
positively changed hydrogen atom in the molecule and negatively charged electronegative
atom of the same molecule or another molecule.
There are two types of hydrogen bond. They are:
1) Inter molecular Hydrogen bond
2) Intra molecular Hydrogen bond.
1. Intermolecular Hydrogen bond: It is formed between two different molecules of the
same or different compounds.
Example: H - F molecule.
Chemistry-I 17
   
H –– O H –– O H –– O
1.H2O
H H H
    
2.HF H –– F H –– F H –– F HF molecule
2. Intramolecular Hydrogen bond: It is formed when hydrogen atom is in between the two
highly electronegative (F, O, N) atoms present within the same molecule.
Examples: O - nitrophenol the hydrogen is in between the two oxygen atoms.
–
O
H +
N O –
O
O - nitrophenol
Long Answer Type Questions (8 Marks)
1.
IE
Give an account of VSEPR Theory and its applications?
Ans. VSEPR Theory: In order to predict the shapes of covalent molecules a simple theory
B
based on the repulsive interactions of the electron pairs in the valence shell of the atoms
was developed Nyholm and Gillespie.
S
1) The shape of a molecule depends on the number of pairs in the valence shell around the
central atom.
T
2) Pairs of electrons in the valence shell repel one another since their electron clouds are
negatively charged.
3) These pairs of electrons occupy such positions in space that minimise repulsion and thus
maximum separation between them.
4) The order of the repulsions between the electron pair is
lone pair - lone pair > lone pair - bond pair > bond pair - bond pair
No. of electron No. of Bond No. of lone Shape of the Examples
pairs pairs pairs
2 2 0 Linear BeCl2
3 3 0 Trigonal planar BCl3
4 4 0 Tetrahedral CH4
3 1 Pyramidal NH3
2 2 Angular H2O
1 3 Linear HOCl
5 5 0 Trigonal bipyramidal PCl5
6 6 0 Octahedral SF6
Eg: 1. NH3 Molecule Shape 1. Total No. of electron pairs = 4

2. No. of Bond Pairs = 3
N
H H 3. No. of Lone Pairs = 1
H
4. Shape - Pyramidal
2. H2O Molecule Structure 1. Total No. of electron pairs = 4
2. No. of Bond Pairs = 2
O
H H 3. No. of Lone Pairs = 2
4. Shape - Angular
2. What do you understand by Hybridization ? Explain different types of hybridization
involving s and p orbitals?
Ans: Hybridization: Intermixing of atomic orbitals of almost equal energies of an atom and
their redistribution into an equal number of identical orbitals is called Hybridization.
E
1. sp Hybridization: The phenomenon of intermixing of one 's' orbital and one 'p' orbital of
I
an atom forming two 'sp' hybrid orbitals is called sp hybridization.
1 1
B
Each of the sp hybrid orbitals possesses s - character and p - character..
2 2
The bond angle in between two hybrid orbitals is 1800.
s - Orbital
+
T S
The shape of the molecule is linear.
p - Orbital
Eg: Beryllium Chloride BeCl2
sp - Linear
1. In the formation of BeCl2 molecule the central 'Be' atom undergoes sp hybridization.
2. Be - 4 - 1s22s22p0
1s22s22p1
Ground State Configuration 

2s 2p
Excited State Configuration 

2s 2p
3. One s - orbital and one p - orbital of Be undergoes sp hybridization and forms two sp
hybrid orbitals.
4. The two sp hybrid orbitals overlap with the 3p- orbital of chlorione axially and form two
Be - Cl sigma bonds.
5. The shape of the molecule is linear and the bond angle is 1800.
Chemistry-I 19
180º
+ ; Cl – Be – Cl
p p
sp sp
Linear Shape bond angle 1800
2) sp2 Hybridization: The phenomenon of intermixing of one 's'orbital and two 'p'orbitals
forming three 'sp2' hybrid orbitals is called sp2 hybridization. Each of the sp2 hybrid orbitals
1 2
possess s - character and p - character..
3 3
The bond angle is between any two sp2 hybrid orbitals is 1200.
The shape of the molecule is planar triangular.
s-orbital p
B IE sp
S
Example: Formation of Boson trichloride (BCl3) molecule
1. In the formation of BCl3 molecule the central atom 'B' undergoes sp2 hybridization.
2. B - 5
T
Ground State Configuration
Excited State Configuration

:
:
2s
2s
2p
2p
1s22s22p1
1s22s12p1
3. One s- orbital and two p - orbitals of 'B' undergoes sp2 hybridization and forms three sp2
hybrid orbitals.
4. The three sp2 hybrid orbitals of 'B' overlap with singly occupied 3p orbitals of three chlorine
atoms forms three B - Cl sigma bonds.
5. The shape of the molecule is plane triangular with the bond angle 1200.
p
sp2 Cl
sp2 120º
+ 3 sp2 B
d p p Cl Cl
2
sp
(b) Plane - triangular shape (b) Bond angle 1200
3) sp3 hybridization:
The phenomenon of intermixing of one 's' orbitals and three 'p' orbitals forming four sp3
hybrid orbitals is called sp3 hybridization.
1 3
Each of the sp3 hybrid orbitals posses of s - character and of p - character..
4 4
E
The bond angle between any two sp3 hybrid orbitals is 109028''.
I
The shape of the molecule in which the central atom undergoes sp 3 hybridization is
tetrahedral.
S B
T
+
s sp3
p
Example: Formation of Methane (CH4 ) Molecule:
1. In the formation of CH4 molecule the central atom 'c' undergoes sp3 hybridization.
2. C - 6 1s22s22p2 Ground State Configuration

2s 2p
1s22s12p3 First Excited State Configuration

2s 2p
3. One s - orbital and 3 - p - orbitals of 'c' undergoes sp3 hybridization and forms four sp3
hybridization.
4. The sp3 hybrid orbitals overlap with the s - orbital of three hydrogen atoms and form 4 C -
H sigma bonds.
5. The shape of the molecule is tetrahedral and the bond angle is 109028''.
Chemistry-I 21
+ 4 C
H H
sp3 H
3. Give the Molecular Orbital Energy diagram of (a) N 2 and (b) O 2. Calculate the
respective bond order. Write the magnetic nature of N2 and O2 Molecule.
Ans. Molecular Orbital Energy diagram of N2
*2px
2p
B E
*2px *2py
I
2pz
2p
2s
T S 2px 2py
*2s
2s
2s
*1s
1s 1s
1s
The electronic configuration of N2 in terms of MO is given as
(1s)2(*1s)2(2s)2(*2s)2(2px)2(2py)2(2pz)2
bonding electrons - antibonding electrons
Bond Order =
2
1 1
BO  (Nb  N a )   (10  4)  3 ( N  N)
2 2
No unpaired electrons so it in diamagnetic in nature.
b) Molecular Orbital Energy diagram of O2:
*2pz
*2px *2py
2p 2p
2px 2py
E
2pz
B I
*2s
2s
T S 2s
*1s
2s
1s 1s
1s
The electronic configuration of O2 in terms of MO is given as
(1s)2(*1s)2(2s)2(*2s)2(2pz)2(2px)2(2py)2(*2px)1(*2py)1
1
Bond Order  (N b  N a )
2
1
  2 (10  6)  2 ( O  O)
Oxygen is having unpaired electrons so it shows paramagnetic nature.

Chemistry-I 23
Unit 4
States of Matter

1. State Boyle's Law. Give its mathematical expression.
Ans. At constant temperature, the pressure of a fixed amount of gas varies inversely with its
E
volume. This is known as Boyle's Law.
Mathematically, it can be written as
V
1
P
B I
at constant T, n)
S
1
p = K1  K = Proportionality constant
v 1
2.
T
State Charle's Law. Give its mathematical expression.
Ans. A constant pressure, the volume of a fixed mass of a gas is directly proportional to its
absolute temperature.
V  T at constant P, n)
V = K 2  T K2 = Proportionality constant
3. State Avogadro's Law ?
Ans. It states that equal volume of all gases under the same conditions of temperature and
pressure contain equal number of molecules.
V  n Where n is the number of moles of the gas)
V = K3n K3 = Proportionality constant
4. State Graham's Law of diffusion?
Ans. The rate of diffusion of given mass of a gas is inversely proportional to the square root of
its density.
1
It may be mathematically written as  r 
d
Volume of the gas diffused (v)

rate of diffusion of a gas r =
Time of diffusion (t)
r = rate of diffusion of the gas d = density of the gas.
5. State Dalton's Law of Partial Pressures?
Ans. It states that the total pressure exerted by the mixture of non-reactive gases is equal to the
sum of the partial presures of individual gases.
PTotal= P1 + P2 + P3 + ....... at constant T, V)
6. What is Absolute Temperature?
Ans. The lowest hypothetical temperature of which gases are supposed to occupy zero volume
is called Absolute Temperature which is -273.150C or OK.
7. What is Gram Molar Volume?
Ans. One mole of any gas at STP conditions occupies 22.70198 litres. It is called Gram Molar
8.
Volume.
What is an Ideal gas?
B IE
Ans. The gas which obeys all gas laws at all temperature and pressures is caleld an Ideal gas.
9. Which of the gases diffuses faster among N 2, O2 and CH4? Why?
S
Ans. CH4 gas diffuse faster amohng N2, O2 anc CH4.
Reason: CH4(16) has how molecular weight than N2(28) and O2(32).
10.
rCH 4
rSO2

MSO2
M CH 4
T
How many times methane diffuses faster than Sulphur dioxide?
Ans. According to Graham's law of diffusion,

64
14

4
1
2
Hence Methane gas diffuses 2 times faster than SO2.

11. Give the relation between the partial pressure of a gas and its molefraction.
Ans. Partial Pressure of a gas = Molefraction  total pressure.
P = x  pTotal
12. Why Ideal gas equation is called Equation of State?
Ans. Ideal gas equation is a relation between four variables (P, V, n, T) and it describes the state
of any gas. Hence it is called equation of state.
13. Give the Kinetic gas equation and write the terms in it.
1
Ans. Kinetic gas equation is PV  mnu rms
2
3
where
Chemistry-I 25
P = Pressure of the gas V = Volume of the gas

m = mass of one molecule of the gas n = No. of molecules of the gas
urms = RMS speed of the gas molecules.
1. Derive Ideal gas equation.
Ans. By combining Boyle's Law, Charle's Law and Avogadro's Law we get an equation which
relates to volume, pressure, absolute temperature and number of moles. This equation is
known as Ideal gas equation.
1
At Constant T and n V Boyle's Law
P
At Constant P and n VT Charle's Law
At Constant P and T Vn Avogadro's Law
E
1
V   T n
I
Thus,
P
nT
VR
B
P
 P V  n RT
2.
T S
V = Volume of the gas
P = Pressure of the gas
n = Number of Moles of Gas
T = Absolute temperature
R = Universal gas constant
Deduce (a) Boyle's Law and (b) Charle's Law from Kinetic gas equation.
Ans. (a) Boyle's Law: According to Kinetic gas equation
1
PV  mnu rms
2
3
2 1
PV   mnu rms
2
3 2
1
The Kinetic energy of 'n' molecules in the gas is  KE  mnurms
2
2
According to the Kinetic molecular theory. Kinetic energy is directly proportional to the
temperature on Kelvin Scale.
1 2
mnurms αT
2
or
1 2
mnu rms = K  T where K = Constant by substituting this in Kinetic gas equation we get
2
2
PV  K × T
3
PV = Constant
At Constant temperature PV = Constant. This is Boyle's Law.
b) Charle's Law
According to Kinetic gas equation
1
PV  mnu rms
2
3
2 1
PV   mnu rms
2
3 2
E
The Kinetic energy of 'n' molecule in the gas is K.E. 
I
1
2
2
mnu rms
According to Kinetic molecular theory, Kinetic energy is directly proportional to the

temperature on Kelvin Scale.
B
S
1 2
mnurms αT
2
T
1
or
2
mnu rms =K T where K = constant
2
by substituting this in Kinetic gas equation, we get
2
PV  K × T
3
2  KT 
or V =
3  P 
At Constant Pressure (P)
V = Constant × T
or V T (P, n are Constant)
This is Charle's Law
3. Dedude (a) Graham's Law (b) Dalton's Law from Kinetic Gas Equation.
Ans. (a) Graham's Law of Diffusion:
According to Kinetic Gas Equation,
1
PV  mnu rms
2
3
'mn' represents mass of the gas.
Chemistry-I 27
If the gas contains Avogadro's number of molecules, then 'mn' becomes equal to gram
molecular mass 'M' of the gas.
1
 PV  M urms
2
or
3
3PV 3PV
 urms
2
  urms 
M M
V Gram under Volume
Since,
M
 =
Molar Mass
= d(density)\
3P
 urms 
d
Constant
At Constant Pressure urms 
d
 urms 
Rate of diffusion, r 
1
d
1
d
 r  urms 
B IE
S
This shows that the RMS speed or the rate of diffusion of gas is inversely proportional to
the square root of its density.
4.
1.
2.
T
This is Graham's Law of diffusion.
Write the postulates of Kinetic Molecular Theory of gases?
Ans. Kinetic Molecular Theory of gases postulates:
Gases contain large number of tiny particles called molecules. The molecules of gas
are identical and moves with different velocities in random directions.
As the gas molecules are separated from each other by large distances, the volume of
the molecules is negligible when compared to the volume of the gas.
3. There are no attractive or repulsive forces between the gas molecules.
4. Molecules of a gas are always in a state of random motion in all directions and in
straight lines collecting with each other and with the walls of container.
5. The pressure of the gas is due to collision of gas molecules on the walls of the container.
6. The molecular collisions oare perfectly elastic in there is no loss of total kinetic energy
as a result of such collisions. But there may be exchange of energy among collecting
molecules.
7. There is no gravitational force of attraction on the motion of gas molecules.
8. The average kinetic energy of gas molecules is directly proportional to absolute

temperature. (E k )  T .
5. State and explain Graham's law of diffusion.
Ans. At constant temperature and pressure, the rate of diffusion of a gas is inversely proportional
to the square root of its density or molecular weight or vapour density
1 1 1
r ; r ; r
d M D
If the times of diffusion are equal i.e. t1 = t2 then we can write
r1 V d2 VD2 M2
= 1   
r2 V2 d1 VD1 M1
If the volumes of the two gases are same is V1 = V2 then
r1
r2
t
= 1 
t2
d2
d1

VD 2
VD1

M2
M1
B IE
r1 & r2 are the rates of diffusion of two gases.
d1 & d2 are the densities of two gases.
S
VD1, VD2 are the vapour densities of two gases.
T
M1 & M2 are the Molecular weights of two gases.
V1 & V2 are the Volumes of two gases.
t1 & t2 are the times of two gases.
Chemistry-I 29
Unit 5
Stoichiometry

1. How many number of moles of glucose are present in 540 gms of Glucose?
E
Ans. Weight of glucose = 540 g.
I
Molecular Weight of Glucose = (C6H12O6) = 180.
Weight of the Substance 540
B
Number of Moles = = =3
G.W.M of the Substance 180
S
2. Calculate the weight of 0.1 Mole of Sodium Carbonate?
Ans. Number of Moles of (Na2CO3) (n) = 0.1
T
G.M.W. of Na2CO3 = 106
Weight 'W' = n  GMW = 0.1  106 = 10.6 g.
3. The empirical formula of a compound is CH2O. Its Molecular Weight is 90. Calcu-
late the Molecular formula of the compound?
Ans. Empirical formula (CH2O) Weight = 12 + 2 + 16 = 30
Molecular Weight = 90
Molecular Weight 90
n= = =3
Empirical Formula Weight 30
Molecular Formule = [Empirical Formula]n = [CH2O]n
= (CH2O)3 = C3H6O3
 Molecular Formula = [C3H6O3]

4. Chemical analysis of a Carbon Compound gave the following percentage composi-
tion by weight of the elements present, Carbon = 10.06%, hydrogen = 0.84%, Chlo-
rine = 89.10%. Calculate the Empirical Formula of the Compound?
Ans. Element Percentage Atomic Weight Atomic Ratio Simple Ratio
10.06 0.84
C 10.06 12  0.84 1
12 0.84
0.84 0.84
H 0.84 01  0.84 1
1 0.84
89.10 2.51
Cl 89.10 35.5  2.51 3
35.5 0.84
E
 C : H : Cl = 1 : 1 : 3
I
 Hence, Empirical Formula of the Compound is CHCl3.
5. A Carbon Compound on analysis gave the following percentage composition, Car-
B
bon 14.5%, Hydrogen 1.8%, Chlorine 64.46%, Oxygen 19.24%. Calculate the Em-
pirical Formula of the Compound?
Ans. Element Percentage
H T
14.5
1.8
S Atomic Weight
12
1
Atomic Ratio
14.5
12
1.8
1
 1.21
 1.8
1.2
1.8
1.2
Simple Ratio
1.21
 1 2  2
 1.5 2  3
64.46 1.81
Cl 64.46 35.5  1.81  1.5 2  3
35.5 1.2
19.24 1.2
O 19.24 16  1.2  1 2  2
16 1.2
 C : H : Cl : O = 2 : 3 : 3 : 2
 Hence, Empirical Formula of the Compound is C2H3Cl3O2.
6. A Carbon Compound contains 12.8% Carbon, 2.1% Hydrogen, 85.1% Bromine. The
Molecular Weight of the Compound in 187.9. Calculate the Molecular Formula.
Ans. Element Percentage Atomic Weight Atomic Ratio Simple Ratio
12.8 1.067
C 12.8 12  1.067 1
12 1.067
Chemistry-I 31
2.1 2.1
H 2.1 1  2.1 2
1 1.067
85.1 1.067
Br 85.1 80  1.067 1
80 1.067
 C : H : Br = 1 : 2 : 1
 Hence, Empirical Formula of the Compound is CH2Br.
Empirical Formula Weight= 12 + 2 + 80 = 94
But given Molecular Weight = 187.9 (or) 188.
Molecular Weight 188

But, n =  2
Empirical Formula Weight 94
Molecular formula = Empirical Formulan
E
= (CH2Br) × 2 = C2H4Br2.

Ans.
 Molecular formula of Compound = C2H4Br2.
CaCO3(s) CaO(s) + CO2(g)
B I
What Volume of CO2 is obtained at STP by heating 4g. of CaCO3?
100g
S
(1 Mole of Co2 = 22.4 lits)
T
100g of CaCO3 on heating gives 22.4 litres of CO2.
4g of CaCO3 on heating gives ..................?

4
100
 22.4  0.896 Litres
8. What are disportionation reactions? Give Example?

Ans. The redox reaction, in which an element undergoes both Oxidation and reduction simulta-
neously is known as disproportionation reaction.
–1 –2 0
Ex: 2 H2O2 2 H2O + O2
  
 
Reduction

Oxidation
9. Assign Oxidation number to the underlines elements in each of the following species?
(a) NaH2PO4 (b) NaHSO4 (c) H4P2O7 (d) K2MnO4 (e) CaO2
(f) NaBH4 (g) H2S2O7
 (a) N aH 2PO4
1(+1) + 2(+1) + x + 4(–2) = 0

1+2+x–8=0
x–5=0
 x = +5.
(b) NaHSO4
1(+1) + 1(+1) + x + 4(–2) = 0
1+1+x–8=0
2+x–8=0x–6=0
x = +6.
(c) H4P2O7
4(+1) + 2x + 7(–2) = 0
4 +2x – 14 = 0
2x – 10 = 0
 x = +10/2.
 x = +5.
B IE
S
(d) K2MnO4
2(+1) + x + 4(–2) = 0
2 +x – 8 = 0
x–6=0
 x = +6.
(e) CaO2
T
1(+2) + 2 (x) = 0  2x = – 2
 x = –2/2.
 x = –1.
(f) NaBH4
1(+1) + x + 4(–1) = 0
1+x –4=0x–3=0
 x = +3.
(g) H2S2O7
2(+1) + 2(x) + 7(–2) = 0
2 + 2x – 14 = 0 2x – 12 = 0
 x = 12/2.
 x = +6.
Chemistry-I 33
10. Balance the following redox reaction by ion- electron method?

MnO4 –(aq) + I-(aq)  MnO2(s) + I2(s) [in Basic Medium]
Ans. Oxidation: I-  I2
2I-  I2
Balance electrically
2I-  I2 + 2e- .........................(1)
Reduction: MnO4-  MnO2
Balance 'O' by adding H2O
MnO4-  MnO2 + 2H2O
Balance 'H' by adding H2O on the side deficient in H and in adding same number of OH-
on the opposite side.
MnO4- + 4H2O  MnO2 + 2H2O + 4OH-
E
Balance electrically by adding electrons
I
MnO4- + 2H2O + 3e-  MnO2 + 4OH-
Multiply eqn. (1) by 3 & eqn. (2) by (2) to equalise electrons and add
B
6I-  3I2 + 6e-
2MnO4- + 4H2O + 6e-  2MnO2 + 8OH-
S
2MnO4- + 6e- + 4H2O  3I2 + 2MnO2 + 8OH-
11. Balance the following redox reaction by ion electron method:
T
MnO4 –(aq) + SO2(aq)  Mn+2(aq) + HSO4-(aq) [in acidic Medium]
Ans. Oxidation Half Reaction Reduction Half Reaction
SO2  HSO4– MnO4–  Mn+2
SO2  HSO4– MnO4–  Mn+2
SO2 + 2 H2O  HSO4– MnO4–  Mn+2 + 4 H2O
SO2 + 2 H2O  HSO4– + 3 H+ MnO4– + 8 H+  Mn+2 + 4 H2O
(0) (0) (-1) (+3) (-1) (8) (+2) (0)
 2 Electrons are to be substracted  5 electrons are to be added.
(SO2 + 2 H2O  HSO4– + 3H+ + 2e–) × 5 (MnO4– + 8 H+ + 5e–  Mn+2 + 4 H2O) × 2
5SO2 + 10H2O  5HSO4– + 15H+ + 10e– 2MnO4– + 16H+ + 10e–  2Mn+2 + 8 H2O
OHR × 5 = 5SO2 + 10H2O  5HSO4– + 15H+ + 10e–
RHR × 2 = 2MnO4– + 16H+ + 10e–  2Mn+2 + 8 H2O
5SO2 + 10H2O  5HSO4– + 15H+ + 10e–
______________________________________________________________________
2MnO4– + 5SO2 + 10H2O + 16H+  2Mn+2 + 5HSO4– + 8 H2O + 15H+

2MnO4– + 5SO2 + 10H2O - 8 H2O + 16H+ - 15H+  2Mn+2 + 5HSO4–

 2MnO4– + 5SO2 + 2H2O + H+  5HSO4– + 2Mn+2
12. Balance the following redox reaction by Ion Electron Method":
H2O2(aq) + Fe+2(aq)  Fe+1(aq) + H2O(l) [In acidic medium]
Ans. O.H.R R.H.R
Fe+2  Fe+3 H2O2  H2O
Fe+2  Fe+3 + Ie- H2O2  H2O + H2O
H2O2 + 2H+  2H2O
(0) (+2) (0)
+2+x=0
x = -2
Hence, two electrons are to be added.
E
OHR × 2 : 2Fe+2  2Fe+3 + 2e-
RHR × 1 : H2O2 + 2H+ + 2e-  2H2O
B I
2Fe+2 + H2O2 + 2H+  2Fe+3 2H2O
 2Fe+2 + H2O2 + 2H+  2Fe+3 2H2O
13.
Ans. OHR
SO2  SO4–2
SO2  SO4–2
SO2 + 2 H2O  SO4–2
T S
Balance the following redox reaction by Ion electron Method:
Cr2O72–(aq) + SO2(g)  Cr+3(aq) + SO4 2–(aq)
RHR
[in acidic solution]
Cr2O72–  Cr+3
Cr2O72–  2 Cr+3
Cr2O72–  2 Cr+3 + 7 H2O
SO2 + 2 H2O  SO4–2 + 4 H+ Cr2O72– + 14 H+  2 Cr+3 + 7 H2O
(0) (0) (-2) (+4) (-2) (+14) (+6) (0)
Hence, 2 electrons are to be substracted 12 + x = +6
SO2 + 2 H2O  SO4–2 + 4 H+ + 2e– Hence, six electrons are to be added
Cr2O72– + 14 H+ + 6e–  2 Cr+3 + 7 H2O
OHR × 3: 3SO2 + 6 H2O  3 SO4–2 + 12 H+ + 6e–
RHR × 1 : Cr2O72– + 14 H+ + 6e–  2 Cr+3 + 7 H2O
Cr2O72– + 3SO2 + 14 H+ + 6 H2O  2 Cr+3 + 3 SO4–2 + 7 H2O + 12 H+
 Cr2O72– + 3SO2 + 14 H+ - + 12 H+  2 Cr+3 + 3 SO4–2 + 7 H2O - 6 H2O
 Cr2O72– + 3SO2 + 2 H+  2 Cr+3 + 3 SO4–2 + H2O
Chemistry-I 35
Unit 6
Thermo Dynamics

1. Define a System. Give an example?
Ans. A small part of Universe that is choosen for thermodynamics study is called System.
E
Eg: Water in beaker.
I
2. State the 1st Law of Thermodynamics?
Ans. Energy can neither be created nor be destroyed.
3.
S
Ans. For Exothermic Reaction,H = –ve
For Endothermic Reaction, H = +ve
B
What are the 'H' sign convention for Exothermic and Endothermic Reactions?
4.
(i)
Properties.
T
What are the Extensive and Intensive Properties?
Ans. Measurable properties of a system may be classified into two types (i) Extensive (ii) Intensive
Extensive Properties: The properties of a system which depend on the total amount of the
material present the system are called Extensive Properties.
Ex: Mass (m), Volume (v), Internal Energy (E), Heat Energy (or) Heat Content (H) etc.
(ii) Intensive Properties: The properties of a system which are independent of amount of
material in the system are called Intensive Properties.
Ex: Density, Surface tension (s), Specific Heat, Pressure etc.
5. Give the equation that gives the relationship between U and H.
Ans. H = U + nRT
H = Enthalpy change,
n =Change in No. of Moles
U = Change in Internal Energy
R =Universal gas Constant
T =Temperature
6. State the 3rd Law of Thermodynamics?

Ans. At absolute zero the entropy of any pure crystalline substance approached zero.
7. Explain the state function 'Enthalpy', 'H'. What is the relationship between U and
U?
Ans. The heat absorbed at a constant volume is equal to change in the internal energyU = qv.
But in the heat absorbed at constant presure, apart of it increases the internal energy U
and the remaining part is used in the expansion work done by the system. If the initial state
is represented with a subscript 1 and the final state with a subscript 2. The the above
equation written as
U2 - U1 = qp - P(V2 - V1)
(or)
E
qp = (U2 + PV2) - (U1 + PV1)
I
The value of U + PV is called Enthalpy and represented by H.
So, Enthalpy.
B
H U + PV
qp = H2 - H1 = H
8.
T S
Though 'q' is path function, H is a state function because it depends on U, P and V, all of
which are state functions.
Therefore, H = is dependent of path.
The relation between U and  is
H = U + PV (  PU = W)
Show that H = U + n(g)RT
Ans. In the reaction involving gaseous substances there is significant different in H and U.
If VA is the total volume of the gaseous reactions VB is the total volume of the gaseous
products, nA is the number of moles of gaseous reactions and nB is the number of moles of
gaseous products, all at constant pressure and temperature, then using ideal gaseous.
PVA = nART
PVB = nBRT
Thus, PVB – PVA= nBRT – nART
(or)
 P(VB – VA) = (nB – nA)RT
(or)
 PV = n(g)RT.
Here, n(g) is number of moles of gaseous products - number of moles of gaseous reactants.
Substituting the value of PV in
Chemistry-I 37
H = U + PV
We get, H = U + n(g)RT
9. Define and explain the standard enthalpy of formation fH
Ans. The Enthalpy of formation is the heat change accompanying the formation of one mole of
a compound from its constituent elements. It is generally denoted by fH. For example
the Enthalpy of formation of Carbondioxide can be represented as
C(graphite)+ O2(g) CO2(g); fH= –393.5 kJ
When all the species of chemical reactions are in their standard states, the Enthalpy of
formation is called Standard heat of formation. It is denoted by H
10. State and Explain Hess's Law of Constant heat summation?
Ans. Hess's Law: Energy changes remains constant whether the reactions takes place in single
step or in several steps.
Formation of CO2: CO2 can be formed either in one step or in two steps.
E
(a) C(graphite)+ O2(g) CO2(g) H= –393.5 kJ
I
1
(b) C(graphite)+ O2(g) CO2(g) H= –110.5 kJ
2
CO(g)+ ½O2(g) CO2(g); H= –283.0 kJ
Total
S B
H= –393.5 kJ
Reaction 'a' is completed in single step and reaction 'b' is completed in two steps. But in
both the cases energy changes remain constant, which proves Hess's Law.
T
11. Define and explain the Enthalpy of combustion (cH).
Ans. It is the enthalpy change accompanying the complete combusion of one mole of a substance
in excess of oxygen or air.
For example, the enthalpy of combustion of carbon is represented as
C(s) + O2(g)  CO2(g); H = -393.5 KJ
Combustion reactions are always accompained by the evolution of heat, therefore the value
of cH is always negative.
3
12. Calculate nG for conversion of Oxygen to Ozone O2(g)  O3(g) at 298k. kp the
2
reaction is 2.43 x 10-29.
Ans. nG= 2.30RT Log kp
kp = 2.43 x 10-29
nG = -2.303 8.314 298 (log 2.43 10-24)
nG = 163 kJ.
13. State the second law of thermodynamics and explain it?
Ans. Second law of thermodynamics may be stated as Heat can't flow from a colder body to a
hotter body on its own.
(or)
Heat cannot be converted into work completely without causing some permanant changes
in the system involved or in the surroundings.
Second Law of thermodynamics is useful in predicting
(1) Whether a process occurs in a specified direction or not on its own without the intervention
of any external agency i.e., whether a process is spontaneous or not in specified direction.
(2) The transformation or a process occurs what fraction of one form of energy is converted
into another form of energy in this transformation or process.
(3) A machine which transfers heat from lower temperature to higher temperature on its own
is called perpetual motion machine of second kind. Second law of thermodynamics predicts
that perpentual motion machine is not possible.
14. What is Entropy? Explain with examples?
Ans. Entropy: Entropy means randomness. it is denoted by 's'. Entropy is a measure of disorder
or randomness in a system. The greater the disorder in a system the higher is the Entropy.
Entropy is a state function. Entropy change (S) between any two states is therefore given
by the equation.
 S  rev
q
T
IE
qrcv is heat absorbed by the system isothermally and reversibly at 'T' during the state change.
B
A substance in solid state have lowest entropy because the particles are orderly arranged.
S
The gaseous state of the same substance have highest entropy because the partic;es are
moving most disorderly. The liquid state of the same substance have entropy in between
T
the value for solid and the gaseous state.
For a spontaneous process is an isolated system the change in entropy (S) is positive.
15. State the first law of thermodynamics. Explain its mathematical notation.
Ans. Energy can neither be created nor be destroyed but energy in a process may be converted
from one form to another form. First law of thermodynamics is also known as law of
Conservation of energy.
Mathematically, first law of thermodynamics can be represented as
Q = E + W
Where, Q = Amount of heat absorbed by the system
E = Increase in internal energy of the system
W = Work done on a system.
For infinitesimally small changes q = dE + W
According to first law of thermodynamics a part of amount of heat (Q) absorbed by the
system is used for increasing the internal energy (E) of the system and the remaining part
is used for doing work (W).
Heat absorbed by the system is given + sign,
Heat given out by the system is given – sign.
Work done by a system is given – sign and work done on a system is given + sign.
Chemistry-I 39
Unit 7
Chemical Equilibrium and Acids - Bases

1. State law of Chemical Equilibrium.
E
Ans. At a given temperature, the product of concentration of the reaction product raised to the
I
respective stiochiometric coefficients in the balanced chemical equation divided by the
product of concentrations of the reactants raised to their individual stochiometric coefficients
B
has a constant value. This is known as the Equilibrium Law (or) Law of Chemical
Equilibrium.
S
2. What is Homogenous Equilibrium? Write two Homogeneous reactions?
Ans. The Equilibrium in which all the substances are present in the same phase is known as
3.
Ex: 1.
2.
T
Homogeneous Equilibrium.
N2(g) + 3 H2(g)  2 NH3(g)
CH3COOH(l)+ C2H5OH(l)  CH3COOC2H5(l) + H2O(l)
What is Heterogeneous Equilibrium? Write two Heterogeneous reactions?
Ans. The Equilibrium in which the substances involved are present in different phases is called
Heterogenous Equilibrium.
Ex: 1. CaCO3(s)  CaO(s) + Co2(g)

2. H2O(l)  H2O(g)
4. Define the Equilibrium Constant?
Ans. The ratio of product of molar concentration of products to product of molar concentration
of reactants at a given temperature is called Equilibrium Constant.
5. Write the relation betweem KP and KC ?
Ans. KP = KC(RT)n
n = [Number of moles of gaseous products - Number of moles of gaseous reactants]
6. Can Catalyst disturb the state of Equilibrium?

Ans. No, but equilibrium is attained quickly because the Catalyst increases both the rate of
forward and backward reactions.
7. What is the effect of temperature on a system at Equilibrium?
Ans. Increase in temperature favours Endothermic Reactions,
Decrease in temperature favours Exothermic Reactions.
8. What is a Bronsted Base? Give One Example.
Ans. Proton acceptor is called "Bronsted Base".

 N H 4  Cl
NH 3  HCl 
In the above reaction, NH3 accepts a proton H+ from HCl, so NH3, is a Bronsted Base.
9. What is Lewis acid? Give an example.
Ans. Lewis acid is the substance which can accept a pair of electrons.
10.
Ex: BF3.
IE
All Bronsted bases are Lewis bases. Explain?
B
Ans. Bronsted base is a proton acceptor Lewis base is an electron pair donor. In order to accept
a proton, bronsted base must donate an eletron pair.
S
Hence, All Bronsted bases are Lewis bases.
Ex: H3N: + H+  [H3N  H]+
11.
T
All Lewis acids are not Bronsted acids. Why?
Ans. Substances which accept electron pair are Lewis acids.
Ex: BF3 can accept pair of electrons. Hence, it is an Lewis acid.
Substances which donate proton are Bronsted Base.
Ex: HCl.
Though BF3 is an Lewis acid, it does not have a proton, so it is not a Bronsted Base. Hence,
Lewis acids are not Bronsted acids.
12. Ice melts slowly at high attitudes. Explain why?
Ans. Ice has more volume than water. When pressure is increased Ice converts into water. When
Pressure is decreased the above reaction occurs slowly. Since, at high attitudes pressure is
low, Ice melts slowly.
1. Derive the relation between Kp and Kc for the equilibrium reaction.
N2(g) + 3 H2(g)  2 NH3(g)
Ans. N2(g) + 3 H2(g)  2 NH3(g)
Chemistry-I 41
2
 NH3 
2
PNH
KC  , KP  3
PN2  PH
3
[N 2 ][H 2 ]3
2
n
PV  nRT  P  RT
v
 P  cRT ( n/v = con = C)
 PNH3  [NH 3 ]RT
PN 2  [N 2 ]RT
PH 2  [H 2 ]RT
[NH3 ]RT
2
KP 
[N 2 ]RT[H 2 ]RT
3
[NH3 ]2
E
KP  3
(RT) 24  K C (RT)2
[N 2 ][H 2 ]
K P  K C (RT)2
KP 
KC
(RT) 2
B I
2.
T S
K P (RT) 2  K C  K C  K P (or) K P  K C
Explain the Arrhenius concept of acids and bases.
Ans. 1. Acids are substances that dissociate into water to give hydrogen ions H+(aq) and bases
are substances that produce hydroxyl ions OH–(aq)
HX(aq)  H+(aq) + X–(aq)
MOH(aq)  M+(aq) + OH–(aq)
2. Acids such as HCl, HNO3 undergo almost complete ionization. These are strong ac-
ids. Acids such as acetic acid (CH3COOH) undergoes partial ionization. Hence it is a
weak acid. In the same manner bases which undergo complete ionization are strong
bases the ones which undergo partial ionization are weak bases.
3. According to this theory neutralization reaction is formation of water by the combina-
tion of H+, OH- ions.
H+(l) + OH–(l)  H2O(l)
3. What is the conjugate acid base pair? Illustrate with an examples.
Ans. A pair of acid and base that differ by 'One Proton' is called as Conjugate acid base pair.

H
Ex: 1. HCl 
 
 Cl–
 H
(acid) (Conjugate base)

H
2. CH3 – COOH 
  CH3COO–
 
H
(acid) (Conjugate base)
4. The Species H2O, HCO3–, HSO4– and NH3 can act both as Bronsted acids and bases.
Give the corresponding conjugate acid and base for each of them.
Ans. (1) H3O+ –––––– H2O –––––– OH–
Conjugate acid Conjugate base
(2) H2CO3 –––––– HCO3– –––––– CO3–2
(3) H2SO4 –––––– HSO4– –––––– SO4–2
5.
(4) NH4+ –––––– NH3 –––––– NH2–
IE
Write the Conjugate acid and Conjugate base of each of following:
(a) OH– (b) H2O
B
(c) HCO3– (d) H2O2
S
Ans. (a) H2O –––––– OH– –––––– O2–
(b)
(c)
(d)
Conjugate acid
Conjugate acid
T
H3O+ –––––– H2O –––––– OH–
Conjugate base
H2CO3 –––––– HCO3– –––––– CO3–2
Conjugate base
H3O2+ –––––– H2O2 –––––– HO2–
6. Discuss the Application of Lechatlier's Principle for the Industrial Synthesis of
Ammonia.
Ans. Lechatlien's Principle: When a system at Equilibrium is subjected to stress (like change
in pressure, temperature and concentration) the equilibrium position shifts in the directions
where the stress is reduced (or) nullified.
Applying Lechatlien's principle to synthesis of NH3 by Haber's Process:
N2(g) + 3H2(g)  2 NH3(g) G Temperature (H = –92kJ)
Effect of Concentration: According to Lechatlier's Principle increase in the concentration
of N2 and H2 favours the forward reaction there by increases the formation of NH3.
Chemistry-I 43
Effect of Temperature: Formation of NH3 is a Exothermic Reaction. According to

Lechatlier's principle low temperature favours the forward reaction. But at low temperature
reaction is very slow. Hence optimum temperature (725k - 775k) is used in Haber's Process.
Effect of Pressure: The formation of ammonia is accompanied with decrease in number
of moles (4  2). So, high pressure is required for the better yield of ammonia. Hence 200
at m pressure is used in Haber's Process.
Optimum Condition:
Pressure : 200 at m
Temperature : 725l - 775k
Catalyst : Iron (Fe)
7. Discuss the application of Lechatlier's principle for the industrial synthesis of sulphur
E
trioxide.
I
Ans: Lechatlien's Principle: When a system at equilibrium is subjected to stress (like change
of pressure, temperature and concentration) the equilibrium position shifts in the direction
B
where the stress is reduced (or) nullified.
S
Properties of SO3
2 SO2(g) + O2(g)  2 SO3(g) + Temperature (H = –189kJ)
T
Effect of Concentration: According to Lechatlien's Principle increase in the concentration
of reactants favours the forward reaction. Hence high concentration of SO2 and O2 are
required for better yield of SO3.
Effect of Temperature: Formation of SO 3 is a Exothermic Reaction. According to
Lechatlien's Principle low temperature favours the forward reaction. Hence, Temperature
673k is used.
Effect of Pressure: The formation of SO3 is accompained with decrease in number of
moles (3  2). So, high pressure is required for the better yield of SO3. Hence, to get better
yield of SO3 2 atm pressure is used.
Optimum Condition:
Temperature : 675k
Pressure : 2 atm
Catalyst : V2O5
Unit 8
Hydrogen and its Compounds

1. Define the term Hydride. How many categories of hydrides are known? Name them.
E
Ans. Dihydrogen, under certain reaction conditions, combines with almost all elements, except
I
Noble gases, to form binary compounds called 'Hydrides'.
Hydrides are classified into three categories:
B
(i) Ionic or Saline or Salt like hydrides.
(ii) Covalent or molecular hydrides.
2.
T S
(iii) Metalic or non-stoichiometric hydrides.
What do you mean by autoprotolysis? Give the equation to represent the autoprotolysis
of water.
Ans. Water has the ability to behave as an acid as well as base. It behaves as an amphoteric
substance. The self-ionising property of water is caleld autoprotolysis. The auto protolysis
of water is represented by equation
H2O(l) + H2O(l)   H3O+(aq) + OH–(aq)
Acid Base Conjugate Acid Conjugate Base
3. Water behaves as an amphoteric substance in the Bronsted sense. How do you ex-
plain?
Ans. Water has the ability to act as an acid as well as a basic i.e. It behagves as an amphoteric
substance. In the Bronsted sense it acts as an acid with NH3 and a base with H2S.

  OH–
H2O(l) + NH3(aq) 
 + NH4+(aq)
(aq)

  H O+
H2O(l) + H2S(aq) 
 + HS–(aq)
3 (aq)
Chemistry-I 45

4. Discuss the position of Hydrogen in the periodic table on the basis of its electronic
configuration.
Ans. Hydrogen is the first element of the Periodic Table with atomic number 1 and electronic
configuration is 1S1. It acts as both Alkali metals (Group IA) and halogen (Group VIIA)
and can be placed along with them.
Reasons for position of Hydrogen in Group IA:
(i) The outer electronic configuration of 'H' and Group IA are same i.e., 1s1.
(ii) Similar to Alkali metals, hydrogen also forms oxides, halides and sulphides.
Eg: NaCl, HCl; Na2S, H2S; Na2O, H2O
(iii) Like Alkali metals, hydrogen loose one electron to form unipositive ion.
Reasons for position of hydrogen in VIIA
E
(i) Like halogens, hydrogen also requires one electron to achieve the Noble gas configuration
I
(1s2 = Helium).
(ii) Similar to halogens, hydrogen also forms diatomic molecule.
5. Write a note on Heavy Water.
B
(iii) Like halogens, hydrogen gain one electron to form uninegative ion.
S
Ans. (i) It can be prepared by exhaustic electrolysis of water or as a by product of some fertilizer
T
industries.
(ii) It is used for the preportion of other deuterium compounds. For example:
CaC2 + 2D2O  C2D2 + Ca(OD)2
SO3 + D2O  D2SO4
Al4C3 + 12D2O  3CD4 + 4Al(OD)31
(iii) It is used as a moderate in nuclear reactors and in exchange reactions for the study of
reaction mechanism.
6. Name the isolopes of hydrogen. What is the ratio of the masses of these isotopes?
Ans. Hydrogen has three isotopes namely Protium (11H), Deuterium (12H or 12D) and Tritium
(13H or 13H). These isotopes differ from each other in the presence of Neutrons. Protium
has no neutrons, Deuterium has one neutron and Tritium has two neutrons in their nuclear
respectively.
Of these isotopes, only tritium is radio active and emits low energy  particles.
Relative ratio of the masses of isotopes are
Protium : Deuterium : Tritium = 1008 : 2014 : 3016
Protium : Deuterium : Tritium = 1 : 2 : 3
7. Discuss the principle and the method of softening of hard water by synthetic, ion -
exchange resins.
Ans. Principle: In synthetic resins method, the cations and anions present in water are ex-
changed by H+, OH- ions for removing permanent hardness of water.
Cation exchange Resins:
The REesins contain -OH, -COOH (or) -SO3H group. When hard water is passed through
these Resins, Na+, Ca2+, Mg2+ and other cations present in water are exchanges to H+.
2 R – COOH + Ca2+  (RCOO)2Ca + 2H+
2 RCOOH + Mg2+ (RCOO)2 Mg + 2H+
Anion Exchange Resin:
These Resins contain R - NH2 groups. When hard water is passed through these Resins,
Cl–, HCO3–, SO42– and other 
anions present in water are exchanged by OH-.
R  N H OH  X  R  N H X  OH
3 3
Where X = Cl- , HCO 3- , SO 2-4
8.
IE
H  + OH   H 2O
Thus ion exchange metjhod removes dissolved salt from water and produces soft water.
Write a few lines on the utility of Hydrogen.
B
Ans. 1. The combustion of hydrogen produces large amount of heat energy when compared
with other fuels like Petrol, LPG etc.
9.
T S
2. Hydrogen fuel is used for generating electrical energy.
3. Hydrogen is used as Rocket fuel.
4. Atomic and Oxyhydrogen torches are used for welding and cutting of Metal.
5. The combustion of fuel will give less pollutants than in Petrol.
Explain with suitable examples, the following:
(i) Electron deficient (ii) Electron Precise (iii) Electron rich hydrides.
Ans. (i) Electron deficient: An electron deficient hydride, as the name suggests, has too few
electrons for writing its conventional Lewis structure. Diborance (B2H6) is an ex-
ample. Infact, all the elements of Group 13 will form electron deficient compounds
and they act as Lewis Acids.
(ii) Electron Precise: These compounds have the required number of electrons to write
their convensional lewis structures. All elements of Group 14 form such compound
(Eg. CH4) which are tetrahedral in geometry.
(iii) Electron - Rich hydrides: Electron rich hydrides have excess electrons which are
present as lone pairs. Elements of group 15 - 17 form such compounds. (NH3 - One
lone pair) H2O - 2 and HF - 3 lone pairs). They behave as lewis bases i.e. electron
donors. The presence of lone pairs on highly electronegative atoms like N, O and 'F'
in hydrides results in hydrogen bond formation between the molecules. This will lead
to association of molecules.
Chemistry-I 47
Unit 9
s-Block Elements

1. Give reasons for the diagonal rotationship observed in the Periodic Table.
E
Ans. The diagonal relationship is observed in the Periodic Table due to
I
(i) Similar sizes of atoms or ions.
(ii) Similar electronegativities of the respective elements.
B
(iii) Diagonally similar elements possess same polarising power.
Ionic Charge
S
Polarising Power =
(Ionic Radius)2
T
2. Write completely the electronic configuration of K and Rb.
Ans. Potassium (K) : 19 – 1s22s22p63s23p64s1
Rubedium (Rb) : 37 – 1s22s22p63s23p64s23d104p65s1
3. Lithium Salts are mostly hydrated. Why?
Ans. Lithium salts are mostly hydrated due to
(a) Smaller size (ii) High hydration energy
Eg: LiCl. 2H2O
4. Which of the alkali metals shows abnormal density? What is the order of the variation
of density among the IA group elements?
Ans. K+ (Potassium) shares abnormal density to release in atomic size and presents of valant '3d'
orbital. The order of variation of density is
Li < Na > K < Rb < Cs
5. Lithium reacts with water less vigorously than Sodium. Give your reasons.
Ans. Lithium reacts with water less vigourously than Na7 (Sodium) as it has high small size and
high hydration energy when compared to Sodium.
6. Write the complete eletronic configuration of any two alkaline earth methods.
Ans. Berylliym (Be = 4) - 1s22s2
Magnesium (Mg = 12) - 1s22s22p63s2
Calcium (Ca = 20) - 1s22s22p63s23p64s2
7. What are the characteristic colours imparted by the IIA elements?
Ans. 'Be' and 'Mg' doesnot impart any colour because the electrons in 'Be' and 'Mg' are strongly
bounded.
When exposed to bunsen burner, other elements impart characteristic colour.
Calcium (Ca) : Brick Red
Strontrium (Sr) : Crimson
Barium (Ba) : Apple Green
8.
E
What happens when Magnesium metal is burnt in air?
I
Ans. When Magnesium burnt in air, it results in the formation of MgO and Mg3N2 and burns
with dazzling brilliant white light in air.
2 Mg + O2  2 MgO
B
9.
T S
3 Mg + N2  Mg3N2
Write a balance equation for the formation of ammoniated IIA metal ions from the
metals in liquid ammonia.
Ans. The Alkaline earth metal dissolves liquid ammonia to form ammoniated ion giving deep
blue black solution.
The equation is: M + (x+y)NH3  [M(NH3)x]+2 + 2[e(NH3)y]–
10. Why are alkali metals not found in the free state in nature.
Ans. The alkali metals are highly reactive due to their large size and low Ionization enthalpy.
Hence do not occur in free state.
11. Write the uses of 'Mg' metal.
Ans. (i) Magnesium is used in the production alloys in combination with Aluminium, Zinc,
Magnesium and tin.
(ii) It is used in the construction of air crafts.
(iii) Milk of magnesia (a suspension of Mg(OH)2 in H2O) is medically liked as an antacid.
Chemistry-I 49

12. Write a note on the anamalous behavious of Beryllium.
Ans. The properties exhibited by the 'Be' are different from other elements due to its small
atomic and ionic size and high Ionization enthalpy.
(i) Beryllium compounds are largely covalent.
(ii) It is amphoteric in nature.
(iii) It doesnot respond to the flame test where as remaining elements impart colour.
(iv) It cannot decompose water at normal temperature.
(v) It can form many complexes where as other elements of the group cannot form complexes.
13. 'Be' shows diagonal relationship with 'Al'. Discuss.
Ans. 'Be' resembles 'Al' due to its similar charge to radius ratio.
The similar properties are:
(i)
(ii)
E
Both have same electronegativity value (i.e. 1.50).
I
Compounds of both 'Be' and 'Al' undergo hydrolysis.
(iii) Both Be and Al are amphoteric in nature.
B
(iv) Both Be and Al are not attacked by acids due to the presence of oxide film on the surface
S
of these metals.
(v) Salts of both Be and Al are extensively hydrolysed.
T
Unit 10
p-Block Elements - Group 13

1. How do you explain higher stability of TlCl?
Ans. TlCl exhibits +1 and +3 oxidation states. But the +1 oxidation state of Thallium is most
2.
important than +3 due to inert pair effect.
Why does Bf3 behave as a Lewis Acid.
B IE
Ans. BF3 is an electron deficient compound. There are only 6 electrons around Boron in BF3.
So, it has a tendency to accept 2 electrons to complete its octet configuration. According
S
to Lewis Theory, an electron pair acceptor is an acid. Hence, BF3 is a Lewis Acid.
3. Describe the shapes of BF3 and BH4-. Assign the hybridization of Boron in these
species.
T
Ans. The Hybridization of B in BF3 is sp2. Hence the geometry of BF3
molecule is triangular planar.
2
This shape is obtained by the overlap of these sp hybridised orbitals
of Boron with the 'p' orbitals of flourine atoms.
F
F
H
F
H
BH4–: In BH4– the hybridisation of Boron is sp3. Hence the shape of
B
Tetrahedral. H H
4. Explain inert pair effect.
Ans. The reluctance of 'ns' electrons to participate in the bond formation is known as Inert Pair
effect.
Eg: In Group 13, Tl should be stable + 1 state than + 3 oxidation state due to inert pair
effect.
5. Write the structure of AlCl3 as a dimer.
Ans. AlCl3 becomes stable by forming a dimer. The shape of AlCl3 is tetrahedral.
Chemistry-I 51
Cl Cl Cl
Al Al
Cl Cl Cl
1. What are electron deficient compounds? Is BCl3 an electron deficient species? Explain.
Ans. The compounds in which there are insufficient number of electrons to complete the octet
of central atom are called as electron deficient compounds.
Example is BCl3. In this molecule (BCl3) the central atom 'B' accepts electrons from NH3
and forms BCl3NH3.
NH3
Cl Cl
B –– Cl + NH3 B
Cl Cl
Cl
E
(Tetrahedral shape)
I
2. B-Cl bond has a bond moment. Explain why BCl 3 molecule has zero dipole moment.
Ans. There are two factors that govern the bond moments of a molecule. they are electronegativity
B
values and the geometry or the molecular arrangement in a compound.
S
(1) B – Cl has a dipole due to the difference in the electronegativity of Boron and Chlorine
atoms.
T
–
Cl + –
– B –– Cl
Cl
(2) BCl3 molecule is symmetrical in structure with trigonal planar in shape and with a bond
angle of 1200.
(3) In BCl3 molecule, the resultant of two B – Cl bonds is cancelled by the third B – Cl Bond.
(4) Hence BCl3 molecule has zero dipole moment.
Unit 11
p-Block Elements - Group 14

1. Give the Hybridisation of Carbon in
(a) CO32- (b) Diamond (c) Graphite (d) Fullerene.
Ans. (a) In Co32-, Carbon shows sp3 hybridisation.
IE
(b) In Diamond, Carbon shows sp3 hybridization.
B
(c) In graphite, Carbon shows sp2 hybridization.
(d) In fullerence, Carbon shows sp2 hybridization.
2.
3.
S
Why is CO poisonous?
T
Ans. Carbon monoxide (CO) has the capacity to mix with haemoglobin molecules in blood and
froms a complex with haemoglobin which is 300 times more stable than the oxygen =
Haemoglobin complex. This prevents haemoglobin from carrying O2 to different parts of
the body and results in death. Hence, CO is highly poisonous in nature.
What is allotrophy? Give the Crystalline allotropes of Carbon.
Ans. The tendency of an element to exist in two or more forms with same chemical properties is
called as allotropy.
Crystalline allotropes of Carbon:
(1) Diamond (2) Graphite (3) Fullerence.
4. Write the outer electronic configuration of group-14 elements.
Ans. The outer electronic configuration of group 14 elements in ns2np2.
Carbon - [He] 2s2sp2
Silicon - [Ne]3s2sp2
Germanium - [Ar] 3d104s24p2
Tin - [Kr] 4d105s25p2
Lead - [Xe] 4f145d106s26p2
Chemistry-I 53
5. How does graphite function as a lubricant?

Ans. Graphite has layer like structure. These layers can slide easily one over the other due to
weak vander woods forces. Hence graphite is very soft and slippery in nature and used as
a dry lubricant in machines which run at high temperature.
6. Graphite is good conductor. Why?
Ans. In graphite each Carbon atom undergoes sp2 hybridization and has one free p - electron.
Due to the presence of these free electrons, graphite behaves as a good conductor or
electricity.
7. C - C bond length in graphite is shorter than C - C bond length in Diamond. Explain.
Ans. In Graphite Carbon undergoes sp2 hybridisation where as in diamond it undergoes sp3
hybridisation. So, the C - C bond length is 141.5 pm in graphite and 154 pm in Diamond.
E
Hence, the C - C bond length in graphite is shorter than the C - C bond length in Diamond.
I
8. Explain the difference in properties of Diamond and Graphite on the basis of their
B
structure.
Ans. Diamond Graphite
1.
2.
3.
4.
5.
T S
Carbon undergoes sp3 hybridization
It has three dimensional structure.
It is a bad conductor of electricity.
The C - C bond length of 1.54A0 and
bond angle is 109028'
Its density is more.
1. Carbon undergoes sp2 hybridization
2. It has two dimensional structure/
3. It is a good conductor of electricity.
4. The C - C bond length is 1.42A0 and
bond angle is 1200
5. Its density is less.
9. What do you understand by (a) Allotropy (b) Inert Pair effect (c) Catenation.
Ans. (a) Allotropy: The ability of a compound to exist in two or more states with different
physical but same chemical properties is termed as Allotrophy.
Crystalline Allotropes: Diamond, Graphite and fullerence.
Amorphous Allotropes: Coal, Coke, Wood charcoal, Gas Carbon, Lamp Black.
(b) Inert Pair effect: "The reluctance of 'ns' electrons to participate in bond formation" is
known as Inert Pair effect.
Eg: In Group-14, Pb shows +2 stable oxidation state instead of +4 oxidation states due to
inert pair effect.
(c) Catenation: The ability of an atom of the same element to form a long chain or group is
known as Catenation. The order of Catenation of Group-14 is
C >> Si > Ge = Sn
Pb = No Catenation
Carbon has highest catenation ability due to its high bond energy.
10. Why Diamond is hard?
Ans. Diamond is a Crystalline lattice and forms a three dimensional structure with carbon atoms.
Each Carbon atom is linked to four other carbon atoms in a tetrahedral fashion and undergoes
sp3 hybridisation. The C - C bonds are very strong and form directional covalent bonds. To
break these bonds, large amount of energy is required. Hence, diamond is hard and can be
used as abrasive.
Carbon atoms
'C' atom
IE
(Anyone figrare)
B
*****
T S
Chemistry-I 55
Unit 13
Organic Chemistry - Hydrocarbon
and Aromatic Hydrocarbon
1. Write the reagents required for conversion of Benzene to Methyl Benzene.
E
Ans. When Benzene is treated with Methyl Chloride in presence of Anh. AlCl3, Methyl Benzene
I
is obtained.
CH3
2.
+ CH3 –– Cl
S
Anh. AlCl3
How is Nitro Benzene prepared? B + HCl
T
Ans. When Benzene reacts with nitration mixture (Conc. HNO3 + Conc. H2So4) at <600C. Nitro
Benzene is obtained.
+ conc.HNO3
conc. H2SO4
< 60ºC
NO2
+ H2O
3. Write the confirmations of Ethane.

Ans. There are two confirmations for Ethane. These can be represented by saw-horse or Neoman
projection.
H H
H H
H H
H H H H
H H H
H H H
H H H H
H H H
H
Sawhorse Newman Sawhorse Newman
Projection Projection Projection Projection
4. How do you prepare Ethyl Chloride from Ethylene.

Ans. Ethylene reacts with HCl- in presence of Anh.AlCl3, Ethyl Chloride is obtained.
CH2 = CH2 + HCl 
Anh.AlCl3
 CH3 - CH2 - Cl
5. Write the IUPAC names of
O
(a) CH3 - CH2 - CH2 - CH = CH2 (b)
O
CHO CHO
(c) (d)
NO2
NO2
Ans. (a) CH3 – CH2 – CH2 – CH = CH2  Pent-1-ene
(b)
O
IE
 Pent-2-one (or) 2-Pentanone
B
 Pent-3-one (or) 3-Pentanone
S
O
CHO
(c)
(d)
CHO
NO2
T  Meta-nitro benzaldehyde (or) Nitro Benzene Carbaldehyde
 Para-nitro Benzaldehyde (or) 3-Nitro Benzene Carbaldehyde

NO2

6. Complete the following reactions and the products A, B and C.
CaC2   A   B  C
H2O hot metal table Anh. AlCl3 + CH3 Cl
Ans. Step-1: CaC2 + 2H2O  Ca(OH)2 + C2H2

A = C2H2 = Acetylene
Step-2: 3C2H2 
hot metal table
 C6H6
B = Benzene = C6H6
Chemistry-I 57
CH3
Step-3: ACl3 + CH3Cl

+ HCl
CH3
C= = toluene.
7. Name the products A, B and C formed in the following reactions. Give the equations
for the reactions.
Ethylene 
Br2 /CCl 4
 A  
AlC.KOH
 B 
Br
C
Ans. Step-1: C2H4 + Br2  CH2 - CH2

| |
E
Br Br
|
Br
B I
A = 1, 2 - Dibromo Ethane = CH2 - CH2
|
Br
S
AlC KOH
Step-2: CH2 –– CH2 HC  CH
–2K Br
T
–2K H2O
Br Br
B = Acetylene = CH  CH
Step-3: HC  CH + 2 Br2 CH –– CH
Br2 Br2
C = 1,1,2,2-Tetrabromoethane = CH –– CH
Br2 Br2
8. How does Acetylene react with (a) Bromine (b) Hydrogen? Write the balanced
equations for the above reactions. Name the Products.
Ans. (a) Acetylene reacts with bromine in the presence of carbon tetrachloride and forms.
1,1,2,2-Tetrabromoethane as final product.
CCl4 Br2
H – C  C – H + Br2 HC  CH CH –– CH
CCl4
Br Br Br2 Br2
(b) Acetylene reacts with hydrogen in the presence of catalyst and forms Ethane.
H H
Ni/Pt
H – C  C – H + 2 H2 H – C– C – H
H H
9. What is substitution reaction? Explain any two substitution reactions of Benzene.
Ans. In a reaction, an atom or a group of atoms is replaced by another atom or group then the
reaction is known as Substitution reaction.
uv light
Example: CH 4  Cl 2   CH 3  Cl  HCl
Substitution reactions of Benzene
(i) Nitration: When Benzene is heated with Nitration mixture at <600, Nitro Benzane is
obtained.
H NO2
+ HO – NO2
< 60ºC
IE
conc. H2SO4
+ H2O
(ii) Halogenation: When Benzene is treated with Cl2 in presence of Anh.AlCl3 or Anh.FeCl3,
Chlorobenzene is obtained.
B
10.
H
T S
+ Cl – Cl
Anh. FeCl3
Cl
+ HCl
What is dehydro halogenation? Write the equation for the formation of Alkene from
Alkyl halide.
Ans. Dehydrohalogenation: The process of removing one hydrogen atom and one halogen
atom from adjacent carbon atoms of an Alkylhalide in the presence of a base to form an
Alkene is known as dehydrohalogenation.
H H
Alc. KOH H H
H – C– C – H C= C
H H
X X
Alc.KOH
Example: CH 3  CH 2  Cl   CH 2  CH 2  KCl  H 2 O
11. Give two examples each for position and functional Isomerism.
Ans. (1) Position Isomerism: Isomers which have the same molecular formula but differ in
the position of particular atom or a group or a multiple bond on the carbon chain; then
the isomers are called position isomers and the phenomenon position Isomerism
Chemistry-I 59
OH
|
CH3CH2CH2OH
CH3 - CH - CH3
1-Propanol 2-Propanol
CH3 - CH = CH - CH3 CH3 - CH2 - CH = CH2
2-Butene 1-Butene
(2) Functional Group Isomersim: Two isomers which have same molecular formula but
differ in the nature of fucntional group are known as functional isomers and the phenomenon
functional group Isomerism.
Example:
H O
| ||
E
CH3 - CH2 - C = O CH 3 - C - CH 3
Propanal
CH3 – CH3 – COOH
Propionic Acid
Propanone
I
CH3 – COO – CH3
B
Methyl Ethanoate
S
12. What is the product formed when Sodium propionate is heated with Soda lime.
Ans. When Sodium propionate is heated with Sodalime, it produces Ethane.
T
CH3 - Ch3 - COONa + NaOH 
Δ
Cao
CH3 - CH3 + Na2CO3
13. Write the IUPAC names of the following compounds.

(a) (b) CH2 = CH – C  C – CH3
(c) CH3 – CH = C(CH3)2 (d) – CH – CH – CH = CH
(e) CH3 – CH = CH – CH2 – CH = CH – CH – CH2 – CH = CH2
C2H5
Ans: (a)  1, 3 - Butadiene
(b) CH2 = CH – C C – CH3  Pent-1-ene-3-yne
(c) CH3 – CH = C(CH3)2  2-Methyl-2-Butene
(d) –CH – CH – CH = CH  4-Phenyl-1-Butene
(e) CH3 – CH = CH – CH2 – CH = CH – CH – CH2 – CH = CH2
C2H5
 4 - Ethyl - 1, 5, 8 - decatriene.
14. How does ethylene react with the following reagents? Give the chemical equation
and names of the products formed in the reactions.
(a) Hydrogenhalide (b) Hydrogen (c) Bromine (d) Water
Ans. (a) Hydrogehalide: Ethylene reacts with hydrogenhalides (HCl, HBr or HI) and gives
Ethylhalides
CH2 = CH2 + HX  CH3 - CH2 - X (X = Cl, Br, I)
(b) H2: Ethylene reacts with hydrogen in the presence of Nickel or Platinum or Palladium
Catalyst and gives Ethane.
CH2 = CH2 + H2 Ni or Pt or Pd CH3 - CH3
(b) Br2: Ethylene reacts with bromine in presence of CCl4 and gives 1, 2 - dibromoethane.
CH2 = CH2 + Br2 CH2 –– CH2
Br Br
(c) H2O: Ethylene reacts with water in presence of Conc.H2SO4 and gives ethanol or
E
Ethyl alcohol.
I
C2H4 + H2O    C2H5OH
Conc.H 2SO4
15. How do we get Benzene from Acetylene? Give the correcponding equation. Explain
B
the halogenations, Allkylation, Acetylation, Nitration and Sulphonation of Benzene.
Ans. Preparation of Benzene: Acetylene undergoes cyclic polymetisation when passed through
S
Red hot Iron tube at 873k. Three molecules of Acetylene Polymerise to form Benzene.
Red Rot 'Fe' tube
T
3 C2H2
873 K
Reactions of Benzene: (Electrophilic Substitution Reactions)
(1) Halogenation: The proces in which Benzene is treated with halogens producing
halobenzene in presence of Lewis Acid Anh.FeCl3, Anh.AlCl3
Cl
Anh. AlCl3
+ Cl2 + HCl
(2) Alkylation: It is also known as Friedel Crafts alkylation. Benzene reacts with alkyl halides
in the presence of Anhydrous AlCl3 and give Alkyl benzene or Toluene.
CH3
Anh. AlCl3
+ CH3Cl + HCl
(3) Acylation: It is also known as Friedel Crafts acylation. Benzene reacts with Acylhalides
in the presence of Lewis acid (And. AlCl3) and gives Acyl benzene (or) Acyl Arene.
CO – CH3
Anh. AlCl3
+ CH3COCl + HCl
Chemistry-I 61
(4) Reaction with Nitration mixture: The reaction is commonly called as nitration. Benzene
reacts with a mixture of Conc. HNO3 and Conc. H2SO4 and give Nitro benzene.
NO2
conc. H2SO4
+ HO – NO2 + H2O
< 60ºC
(5) Reaction with Sulphuric Acid: It is also known as Sulphanation. When Benzene is heated
with Oleum, Benzene sulphonic Acid is formed.
SO3H
(SO2)
+ H2SO4 + H2O

16. What do you understand about Geometrical Isomerism? Explain the geometrical
isomers of 2 - Butene.
E
Ans. The isomers which have the same structural formula but differ in spatial arrangement of
I
atoms or groups around the double bond are known as geometrical isomers and the
phenomenon is known as geometrical isomerism. It is also known as Cis-Trans Isomerism.
B
Eg: 2-Butene will exhibit two geometrical isomers.
S
CH3 CH3 H CH3
C= C C= C
T
H H H
CH3
Cis-2-Butene Trans-2-Butene
17. Discuss Markovnikov Rule and Kharash effect.
Ans. Markovnikov Rule: When unsymmetrical Alkene is treated with HX (X = Cl, Br, I), the
negative part of the reagent is added to Carbon having less number of 'H' atoms.
CH3 - CH = CH2 + H - Br  CH3 - CH2 - CH2

| |
Br H
Propene 2 - Bromopropane
Kharash Effect: When unsymmetrical Alkene (CH3 - CH = CH2) is treated with HX (X
= Cl, Br, I) in presence of Peroxide, the negative part of the reagent is added to the Carbon
having more number of hydrogen atoms.
CH3 - CH = CH2 + HBr   CH3 - CH2 - CH2 - Br
Peroxide
Propene 1- Bromopropane

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Chemistry-I 7

7. Electron affinity of chlorine is more than that of fluorine - explain

3. What is lanthanide contraction? What are its consequences?

(c) 'p' block elements contain IIIA to VIIA and O groups.

(a) Atomic radiusT

(c) Electron gain enthalpy

In a period: As we go from left to right in a period, atomic size decreases as a result of

Factors influencing the ionization enthalpy:

Debye unit = 3.33  10-30 cm

Differences between Sigma bond and Pi bond

B IE Ground State configuration

First exicted State configuration

Ground State Configuration

First exicted State configuration

Second excited state configuration

1. Sulphur in SF6 molecule undergoes sp3d2 hybridization. F

donor acceptor ammonium ion

Eg: 1. NH3 Molecule Shape 1. Total No. of electron pairs = 4

Ground State Configuration 

Excited State Configuration 

Excited State Configuration

2. C - 6 1s22s22p2 Ground State Configuration

1s22s12p3 First Excited State Configuration

Oxygen is having unpaired electrons so it shows paramagnetic nature.

Very Short Answer Type Questions (2 Marks)

Volume of the gas diffused (v)

Hence Methane gas diffuses 2 times faster than SO2.

P = Pressure of the gas V = Volume of the gas

According to Kinetic molecular theory, Kinetic energy is directly proportional to the

8. The average kinetic energy of gas molecules is directly proportional to absolute

If the volumes of the two gases are same is V1 = V2 then

Very Short Answer Type Questions (2 Marks)

Short Answer Type Questions (4 Marks)

Molecular Weight 188

CaCO3(s) CaO(s) + CO2(g)

8. What are disportionation reactions? Give Example?

1(+1) + 2(+1) + x + 4(–2) = 0

10. Balance the following redox reaction by ion- electron method?

2MnO4– + 5SO2 + 10H2O + 16H+  2Mn+2 + 5HSO4– + 8 H2O + 15H+

2MnO4– + 5SO2 + 10H2O - 8 H2O + 16H+ - 15H+  2Mn+2 + 5HSO4–

Very Short Answer Type Questions (2 Marks)

6. State the 3rd Law of Thermodynamics?

Very Short Answer Type Questions (2 Marks)

What is Heterogeneous Equilibrium? Write two Heterogeneous reactions?

Ex: 1. CaCO3(s)  CaO(s) + Co2(g)

6. Can Catalyst disturb the state of Equilibrium?

(acid) (Conjugate base)

Effect of Temperature: Formation of NH3 is a Exothermic Reaction. According to

Very Short Answer Type Questions (2 Marks)

Short Answer Type Questions (4 Marks)

5. Write a note on Heavy Water.

Very Short Answer Type Questions (2 Marks)

Short Answer Type Questions (4 Marks)

Very Short Answer Type Questions (2 Marks)

Very Short Answer Type Questions (2 Marks)

5. How does graphite function as a lubricant?

How is Nitro Benzene prepared? B + HCl

3. Write the confirmations of Ethane.

4. How do you prepare Ethyl Chloride from Ethylene.

Ans. (a) CH3 – CH2 – CH2 – CH = CH2  Pent-1-ene