Page: 1 of 12

Revision Date: 08/21/2012

SAFETY DATA SHEET Print Date: 02/07/2013
Derakane Momentum™ 470-300 EPOXY VINYL MSDS Number: R0402387
ESTER RESIN Version: 1.1
™ Trademark, Ashland or its subsidiaries, registered
in various countries
40212

1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

Product name : Derakane Momentum™ 470-300 EPOXY VINYL ESTER RESIN

™ Trademark, Ashland or its subsidiaries, registered in various
countries

Product code : 40212

Company : Ashland (China) Holdings Co., Ltd

China
Shanghai
1089 Zhongshan No.2 rd(s.)18th Floor Xuhuiyuan Building
Zip Code:200030

制造商或供应商名称 : 亚什兰（中国）投资有限公司
中国
上海
中山南二路1089号 徐汇苑大厦18层
邮政编码：200030

E-mail address : [email protected]

Telephone : 021 2402 4883

Telefax : 86 21 24024999

Emergency telephone number : 0532 8388 9090

Use of the Substance/Mixture : Industrial chemical

 Page: 2 of 12
Revision Date: 08/21/2012
SAFETY DATA SHEET Print Date: 02/07/2013
Derakane Momentum™ 470-300 EPOXY VINYL MSDS Number: R0402387
ESTER RESIN Version: 1.1
™ Trademark, Ashland or its subsidiaries, registered
in various countries
40212

2. HAZARDS IDENTIFICATION

GHS-Classification
Hazardous classification : Flammable liquids, Category 3
Acute toxicity, Category 5, Inhalation
Skin irritation, Category 2
Eye irritation, Category 2A
Aspiration hazard, Category 1

GHS-Labelling
Symbol(s) :

Signal word : Danger

Hazard statements : H226 Flammable liquid and vapour.

H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H333 May be harmful if inhaled.

Precautionary statements : Prevention:

P210 Keep away from heat/sparks/open flames/hot
surfaces. - No smoking.
P233 Keep container tightly closed.
P280 Wear protective gloves/ protective clothing/ eye
protection/ face protection.
Response:
P301 + P310 IF SWALLOWED: Immediately call a POISON
CENTER or doctor/ physician.
P304 + P312 IF INHALED: Call a POISON CENTER or doctor/
physician if you feel unwell.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water
for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P331 Do NOT induce vomiting.
Disposal:
P501 Dispose of contents/ container to an approved
waste disposal plant.
 Page: 3 of 12
Revision Date: 08/21/2012
SAFETY DATA SHEET Print Date: 02/07/2013
Derakane Momentum™ 470-300 EPOXY VINYL MSDS Number: R0402387
ESTER RESIN Version: 1.1
™ Trademark, Ashland or its subsidiaries, registered
in various countries
40212

3. COMPOSITION/INFORMATION ON INGREDIENTS

Pure substance/mixture : mixture

Chemical nature : Static Accumulator

Hazardous components
Chemical Name CAS-No. Concentration
STYRENE 100-42-5 >=30 - <50 %
METHACRYLIC ACID 79-41-4 >=1 - <3 %

4. FIRST AID MEASURES

General advice : Consult a physician.

Show this safety data sheet to the doctor in attendance.

If inhaled : Move to fresh air.

Consult a physician after significant exposure.
If symptoms persist, call a physician.
In case of shortness of breath, give oxygen.

In case of skin contact : Take off contaminated clothing and shoes immediately.
Wash off immediately with plenty of water.
If skin irritation persists, call a physician.

In case of eye contact : Hold eyelids apart and flush eyes with plenty of water for at least
15 minutes. Get medical attention.
Remove contact lenses.

If swallowed : Do not induce vomiting without medical advice.

Never give anything by mouth to an unconscious person.
Consult a physician if necessary.

Notes to physician
Symptoms : Signs and symptoms of exposure to this material through
breathing, swallowing, and/or passage of the material through
the skin may include:
stomach or intestinal upset (nausea, vomiting, diarrhea)
irritation (nose, throat, airways)
central nervous system depression (dizziness, drowsiness,
weakness, fatigue, nausea, headache, unconsciousness) and
other central nervous system effects
Lack of coordination
 Page: 4 of 12
Revision Date: 08/21/2012
SAFETY DATA SHEET Print Date: 02/07/2013
Derakane Momentum™ 470-300 EPOXY VINYL MSDS Number: R0402387
ESTER RESIN Version: 1.1
™ Trademark, Ashland or its subsidiaries, registered
in various countries
40212

confusion
liver damage

5. FIREFIGHTING MEASURES

Suitable extinguishing media : Dry chemical

Carbon dioxide (CO2)
Foam
Water spray

Unsuitable extinguishing media : Halons

High volume water jet

Specific hazards during : Do not use a solid water stream as it may scatter and spread
firefighting fire.
Do not allow run-off from fire fighting to enter drains or water
courses.

Special protective equipment for : In the event of fire, wear self-contained breathing apparatus.
firefighters Use personal protective equipment.

Hazardous combustion products : carbon dioxide and carbon monoxide

Hydrocarbons

Further information : Keep containers and surroundings cool with water spray.
Prevent fire extinguishing water from contaminating surface
water or the ground water system.
Fire residues and contaminated fire extinguishing water must be
disposed of in accordance with local regulations.
For safety reasons in case of fire, cans should be stored
separately in closed containments.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions : Persons not wearing protective equipment should be excluded

from area of spill until clean-up has been completed.
Ensure adequate ventilation.
Pay attention to the spreading of gases especially at ground
level (heavier than air) and to the direction of the wind.

Environmental precautions : Prevent further leakage or spillage if safe to do so.

Methods for cleaning up : Contain spillage, and then collect with non-combustible
absorbent material, (e.g. sand, earth, diatomaceous earth,
 Page: 5 of 12
Revision Date: 08/21/2012
SAFETY DATA SHEET Print Date: 02/07/2013
Derakane Momentum™ 470-300 EPOXY VINYL MSDS Number: R0402387
ESTER RESIN Version: 1.1
™ Trademark, Ashland or its subsidiaries, registered
in various countries
40212

vermiculite) and place in container for disposal according to local

/ national regulations (see section 13).
Keep in suitable, closed containers for disposal.

Additional advice : Comply with all applicable federal, state, and local regulations.

7. HANDLING AND STORAGE

Handling
Advice on safe handling : Avoid formation of aerosol.
Do not breathe vapours or spray mist.
Avoid contact with skin and eyes.
For personal protection see section 8.
Provide sufficient air exchange and/or exhaust in work rooms.
Avoid exceeding of the given occupational exposure limits (see
section 8).
Smoking, eating and drinking should be prohibited in the
application area.
Ensure all equipment is electrically grounded and bonded before
beginning transfer operations.

Advice on protection against fire : Take measures to prevent the build up of electrostatic charge.
and explosion Mixture may charge electrostatically: always use earthing leads
when transferring from one container to another.
Keep product and empty container away from heat and sources
of ignition.
No sparking tools should be used.

Storage
Requirements for storage areas : Store in original container.
and containers Keep containers tightly closed in a dry, cool and well-ventilated
place.
Containers which are opened must be carefully resealed and
kept upright to prevent leakage.

Materials to avoid : Acids, aluminum, aluminum chloride, Amines, Bases, Copper,

Copper alloys, halogens, iron chloride, metal salts, Oxidizing
agents, Peroxides

Other data : Stable under recommended storage conditions.

 Page: 6 of 12
Revision Date: 08/21/2012
SAFETY DATA SHEET Print Date: 02/07/2013
Derakane Momentum™ 470-300 EPOXY VINYL MSDS Number: R0402387
ESTER RESIN Version: 1.1
™ Trademark, Ashland or its subsidiaries, registered
in various countries
40212

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Components with workplace control parameters

Components CAS-No. Value Control Update Basis

parameters
STYRENE 100-42-5 TWA 50 mg/m3 2002 CN OEL

STEL 100 mg/m3 2002 CN OEL

METHACRYLIC 79-41-4 TWA 70 mg/m3 2002 CN OEL

ACID

Engineering measures
Provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below
level of overexposure (from known, suspected or apparent adverse effects).

Personal protective equipment

Respiratory protection : In the case of vapour formation use a respirator with an
approved filter.
When workers are facing concentrations above the exposure
limit they must use appropriate certified respirators.

Eye protection : Safety glasses with side-shields

Skin and body protection : Wear as appropriate:

Safety shoes
Flame-resistant clothing
Wear resistant gloves such as:
polyvinyl alcohol

Hygiene measures : Keep away from food, drink and animal feedingstuffs.
When using do not eat, drink or smoke.
Ensure that eyewash stations and safety showers are close to
the workstation location.
 Page: 7 of 12
Revision Date: 08/21/2012
SAFETY DATA SHEET Print Date: 02/07/2013
Derakane Momentum™ 470-300 EPOXY VINYL MSDS Number: R0402387
ESTER RESIN Version: 1.1
™ Trademark, Ashland or its subsidiaries, registered
in various countries
40212

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance
Physical state : liquid
Colour : no data available
Odour : pungent
Odour Threshold : no data available

Safety data
Flash point : 29.4 °C Method: Seta closed cup
Ignition temperature : no data available
Lower explosion limit : 0.9 %(V)
Upper explosion limit : 6.8 %(V)
Flammability (solid, gas) : no data available
Oxidizing properties : no data available
Auto-ignition temperature : 490 °C
Decomposition temperature : no data available
Molecular Weight : no data available
pH : not applicable
Melting point/freezing point : no data available
Boiling point : 145 °C Calculated Phase Transition Liquid/Gas
Sublimation point : no data available
Vapour pressure : 8.53248 hPa at 25 °C Calculated Vapor Pressure
Density : 1.078 g/cm3 at 20 °C
Bulk density : no data available
Water solubility : Note: insoluble
Partition coefficient: n- : no data available
octanol/water
Solubility in other solvents : no data available
Viscosity, dynamic : no data available
Viscosity, kinematic : > 20.5 mm2/s at 40 °C
Flow time : no data available
Impact Sensitivity : no data available
Relative vapor density : (>)1 AIR=1
Surface tension : no data available
Evaporation rate : no data available

10. STABILITY AND REACTIVITY

Conditions to avoid : Heat, flames and sparks.

Exposure to sunlight.
Exposure to air.
 Page: 8 of 12
Revision Date: 08/21/2012
SAFETY DATA SHEET Print Date: 02/07/2013
Derakane Momentum™ 470-300 EPOXY VINYL MSDS Number: R0402387
ESTER RESIN Version: 1.1
™ Trademark, Ashland or its subsidiaries, registered
in various countries
40212

Materials to avoid : Acids

aluminum
aluminum chloride
Amines
Bases
Copper
Copper alloys
halogens
iron chloride
metal salts
Oxidizing agents
Peroxides

Hazardous decomposition : carbon dioxide and carbon monoxide

products Hydrocarbons

Hazardous reactions : Stable under recommended storage conditions.

Hazardous polymerisation may occur.Vapours may form
explosive mixture with air.

11. TOXICOLOGICAL INFORMATION

Acute toxicity

Acute oral toxicity - Product : no data available

Acute oral toxicity - Components

STYRENE : LD 50: 2,650 mg/kg Species: Rat
METHACRYLIC ACID : LD 50: 1,320 mg/kg Species: Rat Method: OECD Test Guideline
401

Acute inhalation toxicity - : no data available

Product

Acute inhalation toxicity - Components

STYRENE : LC 50: 2800 ppm Exposure time: 4 h Species: Rat
METHACRYLIC ACID : LD 50: 7.1 mg/l Exposure time: 4 h Species: Rat Remarks:
Aerosol

Acute dermal toxicity - : no data available

Product

Acute dermal toxicity - Components

METHACRYLIC ACID : LD 50: 500 mg/kg Species: Rabbit

Skin corrosion/irritation
 Page: 9 of 12
Revision Date: 08/21/2012
SAFETY DATA SHEET Print Date: 02/07/2013
Derakane Momentum™ 470-300 EPOXY VINYL MSDS Number: R0402387
ESTER RESIN Version: 1.1
™ Trademark, Ashland or its subsidiaries, registered
in various countries
40212

Skin irritation - Product : no data available

Serious eye damage/eye irritation

Eye irritation - Product : no data available

Reproductive toxicity

Target Organ Systemic Toxicant - Single exposure - Components

STYRENE : Remarks: May cause respiratory irritation.

Target Organ Systemic : Target Organs: Overexposure to this material (or its components)
Toxicant - Repeated has been suggested as a cause of the following effects in
exposure - Product humans:, mild effects on color vision, effects on hearing,
respiratory tract damage (nose, throat, and airways), central
nervous system effects

Aspiration hazard

Aspiration toxicity - Product : The substance or mixture is known to cause human aspiration
toxicity hazards or has to be regarded as if it causes a human
aspiration toxicity hazard.

Further information
STYRENE : Central Nervous System

12. ECOLOGICAL INFORMATION

Ecotoxicity effects

Toxicity to fish - Product : no data available

Toxicity to fish - Components

STYRENE : LC 50: 4.02 mg/l Exposure time: 96 h
Species: Pimephales promelas (fathead minnow)

Toxicity to daphnia and other : no data available

aquatic invertebrates -
Product

Toxicity to daphnia and other aquatic invertebrates - Components

STYRENE : EC 50: 4.7 mg/l Exposure time: 48 h Species: Water flea
(Daphnia magna)
 Page: 10 of 12
Revision Date: 08/21/2012
SAFETY DATA SHEET Print Date: 02/07/2013
Derakane Momentum™ 470-300 EPOXY VINYL MSDS Number: R0402387
ESTER RESIN Version: 1.1
™ Trademark, Ashland or its subsidiaries, registered
in various countries
40212

Toxicity to algae - Product : no data available

Toxicity to algae
STYRENE : EC 50: > 4.9 mg/l Exposure time: 72 h Species:
Pseudokirchneriella subcapitata (green algae)

Toxicity to bacteria - Components

STYRENE : EC 50: ca. 500 mg/l Exposure time: 0.5 h Species: activated
sludge
Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity)
STYRENE : NOEC: 1.01 mg/l Exposure time: 21 d Species: Water flea
(Daphnia magna)

Elimination information (persistence and degradability)

Bioaccumulation - Product : no data available

Biodegradability - Product : no data available

Biodegradability - Components
STYRENE : Remarks: Readily biodegradable

13. DISPOSAL CONSIDERATIONS

CN HW China. National : Hazardous waste

Catalogue of Hazardous Wastes
Product : Dispose of in accordance with the European Directives on waste
and hazardous waste.

: Do not contaminate ponds, waterways or ditches with chemical

or used container.
Container hazardous when empty.
Dispose of in accordance with local regulations.

Contaminated packaging : Empty remaining contents.

Dispose of as unused product.
Empty containers should be taken to an approved waste
handling site for recycling or disposal.
Do not re-use empty containers.
Do not burn, or use a cutting torch on, the empty drum.

Nature of the waste : Hazardous waste

 Page: 11 of 12
Revision Date: 08/21/2012
SAFETY DATA SHEET Print Date: 02/07/2013
Derakane Momentum™ 470-300 EPOXY VINYL MSDS Number: R0402387
ESTER RESIN Version: 1.1
™ Trademark, Ashland or its subsidiaries, registered
in various countries
40212

14. TRANSPORT INFORMATION

REGULATION
ID NUMBER PROPER SHIPPING NAME *HAZARD SUBSIDIARY PACKING MARINE
CLASS HAZARDS GROUP POLLUTANT /
LTD. QTY.

CHINA - ROAD
UN 1866 RESIN SOLUTION 3 III

CHINA - RAIL
UN 1866 RESIN SOLUTION 3 III

CHINA - INLAND WATERWAYS

UN 1866 RESIN SOLUTION 3 III

INTERNATIONAL MARITIME DANGEROUS GOODS

UN 1866 RESIN SOLUTION 3 III

INTERNATIONAL AIR TRANSPORT ASSOCIATION - CARGO

UN 1866 Resin solution 3 III

INTERNATIONAL AIR TRANSPORT ASSOCIATION - PASSENGER

UN 1866 Resin solution 3 III

CHINA AIR CARGO

UN 1866 Resin solution 3 III

CHINA PASSENGER AIR

UN 1866 Resin solution 3 III
*ORM = ORM-D, CBL = COMBUSTIBLE LIQUID

Marine Pollutant no

Dangerous goods descriptions (if indicated above) may not reflect quantity, end-use or region-specific
exceptions that can be applied. Consult shipping documents for descriptions that are specific to the
shipment.

15. REGULATORY INFORMATION

Further information Regulations on the Control over Safety of Dangerous Chemicals

(Decree No. 344 of the State Council of the People's Republic of
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Revision Date: 08/21/2012
SAFETY DATA SHEET Print Date: 02/07/2013
Derakane Momentum™ 470-300 EPOXY VINYL MSDS Number: R0402387
ESTER RESIN Version: 1.1
™ Trademark, Ashland or its subsidiaries, registered
in various countries
40212

China)

List of dangerous goods GB12268-2005

Classification and code of dangerous goods （GB6944-2005）
General rules for preparation of chemical safety data sheet
（GB16483-2008）
Classification and labels of dangerous chemical substances
commonly used （GB13690-2009）

16. OTHER INFORMATION

Further information - Company

The information accumulated herein is believed to be accurate but is not warranted to be whether
originating with the company or not. Recipients are advised to confirm in advance of need that the
information is current, applicable, and suitable to their circumstances. This MSDS has been
prepared by Ashland's Environmental Health and Safety Department.