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NEET JEE AIIMS- Chemical Kinetics

KEY CONCEPTS INVOLVED

By arvind Arora
NEET JEE AIIMS- Chemical Kinetics

● Units of Rate Constant

By arvind Arora
NEET JEE AIIMS- Chemical Kinetics

By arvind Arora
NEET JEE AIIMS- Chemical Kinetics

Question: If 50 % of a reaction occurs in 100 second and 75 % of the reaction occurs in 200
second, the order of this reaction is :

A. 2 B. 3

By arvind Arora
C. Zero D. 1
NEET JEE AIIMS- Chemical Kinetics

Question: If 50 % of a reaction occurs in 100 second and 75 % of the reaction occurs in 200
second, the order of this reaction is :

A. 2 B. 3

By arvind Arora
C. Zero D. 1
Solution

By arvind Arora
NEET JEE AIIMS- Chemical Kinetics

Question: The rate of a reaction quadruples when the temperature changes from 300 to 310
K. The activation energy of this reaction is :

(Assume activation energy and pre-exponential factor are independent of temperature;

ln2 = 0.693; R = 8.314 J mol–1K–1)
 
A. 107.2 kJ mol–1 B. 53.6 kJ mol–1

By arvind Arora

C. 26.8 kJ mol–1 D. 214.4 kJ mol–1

NEET JEE AIIMS- Chemical Kinetics

Question: The rate of a reaction quadruples when the temperature changes from 300 to 310
K. The activation energy of this reaction is :

(Assume activation energy and pre-exponential factor are independent of temperature;

ln2 = 0.693; R = 8.314 J mol–1K–1)
 
A. 107.2 kJ mol–1 B. 53.6 kJ mol–1

By arvind Arora

C. 26.8 kJ mol–1 D. 214.4 kJ mol–1

Solution

By arvind Arora
NEET JEE AIIMS- Chemical Kinetics

Question: Two reactions, R1 and R2 have identical pre-exponential factors. Activation energy of
R1 exceeds that of R2 by 10 kJ mol–1. If k1 and k2 are rate constants for reactions R1 and R2
respectively at 300 K, then ln(k2/k1) is equal to

A. 12 B. 6

By arvind Arora
C. 4 D. 8
NEET JEE AIIMS- Chemical Kinetics

Question: Two reactions, R1 and R2 have identical pre-exponential factors. Activation energy of
R1 exceeds that of R2 by 10 kJ mol–1. If k1 and k2 are rate constants for reactions R1 and R2
respectively at 300 K, then ln(k2/k1) is equal to

A. 12 B. 6

By arvind Arora
C. 4 D. 8
Solution

By arvind Arora
NEET JEE AIIMS- Chemical Kinetics

Question: N2O5 decomposes to NO2 and O2 and follows first order kinetics. After 50 minutes,
the pressure inside the vessel increases from 50 mm Hg to 87.5 mm Hg. The pressure of the
gaseous mixture after 100 min at constant temperature will be:

A. 136.25 mm Hg B. 106.25 mm Hg

By arvind Arora
C. 175.0 mm Hg D. 116.25 mm Hg
NEET JEE AIIMS- Chemical Kinetics

Question: N2O5 decomposes to NO2 and O2 and follows first order kinetics. After 50 minutes,
the pressure inside the vessel increases from 50 mm Hg to 87.5 mm Hg. The pressure of the
gaseous mixture after 100 min at constant temperature will be:

A. 136.25 mm Hg B. 106.25 mm Hg

By arvind Arora
C. 175.0 mm Hg D. 116.25 mm Hg
Solution

By arvind Arora
NEET JEE AIIMS- Chemical Kinetics

Question: Higher order (>3) reactions are rare due to

A. Low probability of simultaneous collision of all the reacting species.

B. Increase in entropy and activation energy as more molecules are involved.

C. Shifting of equilibrium towardsBy arvinddue

reactants Arora
to elastic collisions.

D. Loss of active species on collision.

NEET JEE AIIMS- Chemical Kinetics

Question: Higher order (>3) reactions are rare due to

A. Low probability of simultaneous collision of all the reacting species.

B. Increase in entropy and activation energy as more molecules are involved.

C. Shifting of equilibrium towardsBy arvinddue

reactants Arora
to elastic collisions.

D. Loss of active species on collision.

Solution

By arvind Arora
NEET JEE AIIMS- Chemical Kinetics

Question: Decomposition of H2O2 follows a first order reaction. In fifty minutes, the
concentration of H2O2 decreases from 0.5 to 0.125 M in one such decomposition. When the
concentration of H2O2 reaches 0.05 M, the rate of formation of O2 will be :

A. 6.93 × 10-2 mol min -1 B. 6.93 × 10-4 mol min -1

By arvind Arora
C. 2.66 L min -1 at STP D. 1.34 × 10-2 mol min -1
NEET JEE AIIMS- Chemical Kinetics

Question: Decomposition of H2O2 follows a first order reaction. In fifty minutes, the
concentration of H2O2 decreases from 0.5 to 0.125 M in one such decomposition. When the
concentration of H2O2 reaches 0.05 M, the rate of formation of O2 will be :

-2 -1 B. 6.93 × 10-4 mol min

A. 6.93 × 10 mol min -1

By arvind Arora
C. 2.66 L min -1 at STP D. 1.34 × 10-2 mol min -1
Solution

By arvind Arora
NEET JEE AIIMS- Chemical Kinetics

Question: For the non-stoichiometric reaction, 2A + B ⟶C + D, the following kinetic data were
obtained in three separate experiments, all at 298 K.

By arvind Arora
A. B.

C. D.
NEET JEE AIIMS- Chemical Kinetics

Question: For the non-stoichiometric reaction, 2A + B ⟶C + D, the following kinetic data were
obtained in three separate experiments, all at 298 K.

By arvind Arora
A. B.

C. D.
NEET JEE AIIMS- Chemical Kinetics

Question: For a first order reaction, A → P, the temperature (T) dependent rate constant (k)
was found to follow the equation:

the pre-exponential factor A and the activation energy Ea, respectively, are

A. 1.0 × 106s–1 and 9.2 kJ mol–1 B. 6.0 s–1 and 16.6 kJ mol–1

By arvind Arora

C. 1.0 × 106s–1 and 16.6 kJ mol–1 D. 1.0 × 106s–1 and 38.3 kJ mol–1
NEET JEE AIIMS- Chemical Kinetics

Question: For a first order reaction, A → P, the temperature (T) dependent rate constant (k)
was found to follow the equation:
-
the pre-exponential factor A and the activation energy Ea, respectively, are

A. 1.0 × 106s–1 and 9.2 kJ mol–1 B. 6.0 s–1 and 16.6 kJ mol–1

By arvind Arora

C. 1.0 × 106s–1 and 16.6 kJ mol–1 D. 1.0 × 106s–1 and 38.3 kJ mol–1
Solution

By arvind Arora
NEET JEE AIIMS- Chemical Kinetics

Question: Under the same reaction conditions, initial concentration of 1.386 mol d-3 of a
substance becomes half in 40 s and 20 s through first order and zero order kinetics respectively.
Ratio of the rate constants for first order (k1) and zero order (ko) of the reaction is

A. 0.5 mol–1 dm3 B. 1.0 mol dm –3

By arvind Arora
C. 1.5 mol dm –3 D. 2.0 mol–1 dm3
NEET JEE AIIMS- Chemical Kinetics

Question: Under the same reaction conditions, initial concentration of 1.386 mol d-3 of a
substance becomes half in 40 s and 20 s through first order and zero order kinetics respectively.
Ratio of the rate constants for first order (k1) and zero order (ko) of the reaction is

A. 0.5 mol–1 dm3 B. 1.0 mol dm –3

By arvind Arora
C. 1.5 mol dm –3 D. 2.0 mol–1 dm3
Solution

By arvind Arora
NEET JEE AIIMS- Chemical Kinetics

Question: Consider a reaction, aG + bH → products. When concentration of both the reactants

G and H is doubled, the rate increases by eight times. However, when concentration of G is
doubled keeping the concentration of H fixed, the rate is doubled. The overall order of the
reaction is

A. 0 B. 1

By arvind Arora
C. 2 D. 3
NEET JEE AIIMS- Chemical Kinetics

Question: Consider a reaction, aG + bH → products. When concentration of both the reactants

G and H is doubled, the rate increases by eight times. However, when concentration of G is
doubled keeping the concentration of H fixed, the rate is doubled. The overall order of the
reaction is

A. 0 B. 1

By arvind Arora
C. 2 D. 3
Solution

By arvind Arora
NEET JEE AIIMS- Chemical Kinetics

Question: Which one of the following statement(s) is incorrect about order of reaction?

A. Order of reaction is determined experimentally

B. Order of reaction is equal to sum of the power of cementation terms in differential rate law

By arvind
C. It is not affected with stoichiometric coefficient Arora
of the reactants

D. Order cannot be fractional

NEET JEE AIIMS- Chemical Kinetics

Question: Which one of the following statement(s) is incorrect about order of reaction?

A. Order of reaction is determined experimentally

B. Order of reaction is equal to sum of the power of cementation terms in differential rate law

By arvind
C. It is not affected with stoichiometric coefficient Arora
of the reactants

D. Order cannot be fractional

NEET JEE AIIMS- Chemical Kinetics

Question: (A) follows first order reaction, (A) → product. Concentration of A, changes from 0.1
M to 0.025 M in 40 min. Find the rate of reaction of A when concentration of A is 0.01 M.

A. 3.47 × 10–4 M min–1 B. 3.47 × 10–5 M min–1

By arvind Arora
C. 1.73 × 10–4 M min–1 D. 1.73 × 10–5 M min–1
NEET JEE AIIMS- Chemical Kinetics

Question: (A) follows first order reaction, (A) → product. Concentration of A, changes from 0.1
M to 0.025 M in 40 min. Find the rate of reaction of A when concentration of A is 0.01 M.

A. 3.47 × 10–4 M min–1 B. 3.47 × 10–5 M min–1

By arvind Arora
C. 1.73 × 10–4 M min–1 D. 1.73 × 10–5 M min–1
Solution

By arvind Arora
NEET JEE AIIMS- Chemical Kinetics

Question: In a first order reaction, the concentration of reactant decreases from 800 mol/dm3
to 50 mol/dm3 in 2 × 104 s. The rate constant of reaction in s-1 is

A. 2 × 104 B. 3.45 × 10–5

By arvind Arora
C. 1.386 × 10–4 D. 2 × 10–4
NEET JEE AIIMS- Chemical Kinetics

Question: In a first order reaction, the concentration of reactant decreases from 800 mol/dm3
to 50 mol/dm3 in 2 × 104 s. The rate constant of reaction in s-1 is

A. 2 × 104 B. 3.45 × 10–5

By arvind Arora
C. 1.386 × 10–4 D. 2 × 10–4
Solution

By arvind Arora
NEET JEE AIIMS- Chemical Kinetics

Question: Consider the chemical reaction, N2(g )+ 3H2(g) → 2NH3(g). The rate of this reaction
can be expressed in terms of time derivatives of concentration of N2(g), H2(g) or NH3,(g ).
Identify the correct relationship amongst the rate expressions

A.

B.
By arvind Arora

C.

D.
NEET JEE AIIMS- Chemical Kinetics

Question: Consider the chemical reaction, N2(g )+ 3H2(g) → 2NH3(g). The rate of this reaction
can be expressed in terms of time derivatives of concentration of N2(g), H2(g) or NH3,(g ).
Identify the correct relationship amongst the rate expressions

A.

B.
By arvind Arora

C.

D.
NEET JEE AIIMS- Chemical Kinetics

Question: The rate constant for the reaction, 2N2O5 ⟶ 4NO2 + O2 is 3.0 ×10-5 s-1 . If the rate is
2.40 × 10-5 mol L-1 s-1 then the concentration of N2O5 (in mol L-1) is

A. 1.4 B. 1.2

By arvind Arora
C. 0.04 D. 0.8
NEET JEE AIIMS- Chemical Kinetics

Question: The rate constant for the reaction, 2N2O5 ⟶ 4NO2 + O2 is 3.0 ×10-5 s-1 . If the rate is
2.40 × 10-5 mol L-1 s-1 then the concentration of N2O5 (in mol L-1) is

A. 1.4 B. 1.2

By arvind Arora
C. 0.04 D. 0.8
Solution

By arvind Arora
 Arvind Arora

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