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    Emmanuel Plaza
    This document contains information about 5 different chemical reactions and kinetics problems. It provides rate expressions, experimental data on reaction times and conversions, temperature and pressure data to determine rate constants and reaction orders. Specifically, it discusses: 1) The kinetics of a gas-phase reaction in a batch reactor to determine time for 50% and 90% conversion. 2) Equilibrium conversions of propane to propylene via two different reaction routes at various temperatures. 3) Experimental data to evaluate the rate constant for a Diels-Alder reaction. 4) Kinetic data to determine the complete rate equation for the decomposition of hydrogen iodide. 5) Pressure and half-life data

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    T 2

    Uploaded by

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    208 views1 page
    This document contains information about 5 different chemical reactions and kinetics problems. It provides rate expressions, experimental data on reaction times and conversions, temperature and pressure data to determine rate constants and reaction orders. Specifically, it discusses: 1) The kinetics of a gas-phase reaction in a batch reactor to determine time for 50% and 90% conversion. 2) Equilibrium conversions of propane to propylene via two different reaction routes at various temperatures. 3) Experimental data to evaluate the rate constant for a Diels-Alder reaction. 4) Kinetic data to determine the complete rate equation for the decomposition of hydrogen iodide. 5) Pressure and half-life data

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    This document contains information about 5 different chemical reactions and kinetics problems. It provides rate expressions, experimental data on reaction times and conversions, temperature and pressure data to determine rate constants and reaction orders. Specifically, it discusses: 1) The kinetics of a gas-phase reaction in a batch reactor to determine time for 50% and 90% conversion. 2) Equilibrium conversions of propane to propylene via two different reaction routes at various temperatures. 3) Experimental data to evaluate the rate constant for a Diels-Alder reaction. 4) Kinetic data to determine the complete rate equation for the decomposition of hydrogen iodide. 5) Pressure and half-life data

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    Download as doc, pdf, or txt
    208 views1 page

    T 2

    Uploaded by

    Emmanuel Plaza
    This document contains information about 5 different chemical reactions and kinetics problems. It provides rate expressions, experimental data on reaction times and conversions, temperature and pressure data to determine rate constants and reaction orders. Specifically, it discusses: 1) The kinetics of a gas-phase reaction in a batch reactor to determine time for 50% and 90% conversion. 2) Equilibrium conversions of propane to propylene via two different reaction routes at various temperatures. 3) Experimental data to evaluate the rate constant for a Diels-Alder reaction. 4) Kinetic data to determine the complete rate equation for the decomposition of hydrogen iodide. 5) Pressure and half-life data

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    of 1

    CL605: Advanced Reaction Engineering

    Tutorial # 1

    Date: 11 Aug 2006 Concepts: Kinetics, Rate, Batch Reactors, Conversion


    1. The gas-phase reaction C 2 H 2 2 H 2 C 2 H 6 occurs in a batch reactor at 1000K. The rate expression
    valid at these conditions is found to be rC2 H 2 10 5 C H2 2 C C2 H 2 gmol / l / min . The reactor has a volume of 1
    liter which is maintained during the course of the reaction. The initial composition is 75% H 2, rest C2H2. 0.001
    gmol of C2H2 is initially in the reactor.
    (a) What is the time taken for 50% conversion of H 2? (b) For 90% conversion of H2?

    2 (Davis). Propylene can be produced from propane through the oxydehydrogenation reaction: Propane +
    1/2O2 => Propylene + H2O. At atmospheric pressure, what is the fraction of propane converted to propylene at
    400, 500 & 600 C if equilibrium is reached at each temperature?
    Temp (0C) 400 500 600
    Ka 1.16 x 1026 5.34 x 1023 8.31x 1021
    The other possible route is the thermal one: Propane => Propylene + H 2. What is the fraction of propane
    converted to propylene by this route at the three temperatures, assuming equilibrium is reached at each
    temperature? Which route is better for propylene production? (Assume ideal behaviour)
    Temp (0C) 400 500 600
    Ka 0.000521 0.0104 0.104

    3 (Davis). The Diels-Alder reaction of 2,3-dimethyl-1,3-butadiene (DMB) and acrolein produces 3,4-dimethyl-
    3-tetrahydro-benzaldehyde. This overall second order reaction was performed in methanol solvent with
    equimolar amounts of reactants. Use the data below to evaluate the rate constant.
    Temperature (K) Reaction time (hours) [DMB] (mol/L)
    323 0 0.097
    323 20 0.079
    323 40 0.069
    323 45 0.068
    298 0 0.098
    298 74 0.081
    298 98 0.078
    298 125 0.074
    298 170 0.066
    278 0 0.093
    278 75 0.091
    278 110 0.090
    278 176 0.088
    278 230 0.087

    4. The thermal decomposition of hydrogen iodide to hydrogen and iodine is conducted in a batch reactor. The
    following data are given
    T, 0C 508 427 393 356 283
    k, cm3/mol/s 0.1059 0.00310 0.000588 80.9 x 10-6 0.942 x 10-6
    Find the complete rate equation, using linear and non-linear data fits.

    5 (Levenspiel). Find the overall order of the irreversible reaction 2 H 2 2 NO N 2 2 H 2 O from the
    following constant-volume batch reactor data using equimolar quantities of hydrogen and nitric oxide:
    Total pressure, mmHg 200 240 280 320 360
    Half life, seconds 265 186 115 104 67

    **************END**************

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