Determination of The Differential Heat of Solution
Determination of The Differential Heat of Solution
Determination of The Differential Heat of Solution
The change in K with temperature at constant pressure reflects a change in mi,s , and also
the change in i,s, which is affected by both the variation s in temperature and
concentration of the solution.
ln K
T
H
R T 2
(eq.3)
, where H= standard enthalpy change for solution process. This quantity should not be
confused with any actual experimentally measurable heat of solution: it can be
determined indirectly, however.
It is obtained:
ln
x 2(T2 )
x
(T1 )
2
d H sat
1 1
T
1 T2
x2(T2 ) c1(T2 )
x2(T1 ) c2(T1 )
(eq.4)
(eq.5)
c 2(T2 ) d H sat
ln (T1 )
R
c2
1 1
T
1 T2
T
1 T2
(eq.6),
(eq.7)
from glass wool into a rubber tube is wrapped around the tip of the pipette. The filter is
removed before draining the pipette. In the first Erlenmayer flask introduce 50 ml of
benzoic acid solution at room temperature and in the other flask introduce 10 ml of the
solution of benzoic acid which was maintained in the thermostat. Each solution in titrated
with 0.1NaOH solution, in the presence of phenolphthalein as pH indicator.