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MATERIAL SAFETY DATA SHEET SECTION 1 Trade Name: Part Numbers: Product Use: Formula: Synonyms: Firm Name: Mailing Address: PRODUCT AND COMPANY IDENTIFICATION Cherne Smoke Fluid 065-808, 065-818, 065-828 Smoke fluid for use with Cherne smoke blowers for sewer testing. See Section 3. Highly refined petroleum hydrocarbon oil. Cherne Industries Incorporated 5700 Lincoln Drive Minneapolis, MN 55436 http://www.cherneind.com For chemical transportation emergencies ONLY, call CHEMTREC at (800)424-9300. Outside the U.S.(703)527-3887. (952) 933-5501 Corporate Director Environmental, Health, and Safety (216) 267-7100 May 18, 2009

Emergency Phone: Information Phone: Prepared By: Contact Phone: Preparation Date:

SECTION 2 HAZARDS IDENTIFICATION Emergency Overview: Water white liquid with a slight hydrocarbon odor. Ingestion may lead to an aspiration hazard. May cause mild irritation to the eye and skin. Potential Health Effects: Skin: Eyes: Inhalation: Ingestion:

May cause mild irritation to the skin, including redness and dryness. May cause irritation, redness, tearing and blurred vision. Long term inhalation may cause lung damage. Harmful or fatal if swallowed due to aspiration hazard if vomiting occurs. Not an OSHA hazard.

OSHA Hazard Classification:

SECTION 3 COMPOSITION/INFORMATION ON INGREDIENTS INGREDIENTS: % wt/wt: CAS NUMBER: Hydrotreated Middle Distillates 100% 64742-46-7 SECTION 4 Skin: Eyes: Inhalation: FIRST AID MEASURES CALL 1-877-740-5015 Remove contaminated clothing. Wash thoroughly with soap and water. Call a physician or poison control center if irritation develops. Remove contact lenses if any. Rinse eyes with water for 15 minutes. Get medical attention if irritation develops. This material has a low vapor pressure and is not expected to present an inhalation hazard at ambient conditions. Move victim to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Keep victim quiet and warm. Call a poison control center or physician if symptoms persist. NEVER give anything by mouth if victim is unconscious. Have victim rinse mouth thoroughly with water. DO NOT INDUCE VOMITING. If vomiting occurs naturally, have victim lean forward to reduce risk of aspiration. Call the Poison Control Center at 1-877-740-5015.

Ingestion:

MSDS No: Issue Date: Page: SECTION 5 Extinguishing Media: Special Fire Fighting Procedures:

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FIRE FIGHTING MEASURES Use dry chemical, CO2, water, or foam extinguisher. Firefighters should wear positive pressure self-contained breathing apparatus and full protective clothing for fires in areas where chemicals are used or stored. Water in a straight hose stream may cause fire to spread and should be used as a cooling medium only. Dense smoke may be generated while burning. ACCIDENTAL RELEASE MEASURES Contain spill immediately. Do not allow spill to enter sewers or water ways. Absorb with appropriate inert material, such as sand or clay. Pick up large spills with vacuum equipment. Appropriate personal protective equipment cited in Section 8 should be worn during all clean-up operations. HANDLING AND STORAGE Avoid contact with eyes, skin, or clothing. Do not take internally. Avoid breathing vapors or mist. Use only in well ventilated areas. Wash thoroughly after handling. Keep container closed when not in use. Handle with care. Keep out of reach of children. Store in a cool dry place away from heat, sparks, open flames or oxidizing agents. None. EXPOSURE CONTROLS/PERSONAL PROTECTION CAS NUMBER: ACGIH TLV TWA OSHA PEL TWA 3 3 5 mg/m 5 mg/m 64742-64-7 3 10 mg/m STEL Good general ventilation (equivalent to outdoors) should be adequate for normal use. For operations where the TLV may be exceeded, mechanical ventilation such as local exhaust may be needed to maintain exposure levels below applicable limits. For operations where the TLV may be exceeded, a NIOSH approved organic vapor respirator is recommended. Equipment selection depends on contaminant type and concentration, select in accordance with 29 CFR 1910.134 and good industrial hygiene practice. For firefighting, use self-contained breathing apparatus. Normally not needed. Launder soiled clothing before re-use. To prevent any contact, wear impervious protective clothing such as neoprene or butyl rubber gloves, apron, boots or whole bodysuit, as appropriate. Safety glasses with sideshields or safety goggles. Eye wash and safety shower should be available.

Unusual Fire and Explosion Hazards: SECTION 6 Spill or Leak Procedures:

SECTION 7 Handling:

Storage: Other: SECTION 8 INGREDIENTS: Hydrotreated middle distillate* *As oil mist Ventilation:

Respiratory Protection:

Skin Protection:

Eye Protection: Other:

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES Flashpoint / Method: > 250F (> 121 C) Flammability: LEL = Not determined, UEL = Not determined Boiling Point: 490 to 680F (254 360C) Melting Point: Not determined Vapor Pressure: <0.1 mm Hg at (70F) Vapor Density: Not determined Volatile Components: Not determined Solubility In Water: Insoluble pH: Not determined Specific Gravity: 0.83 0.84 @ 20 Degrees C Evaporation Rate: Not determined Appearance: Clear liquid Odor: Slight hydrocarbon odor Will Dissolve In: Hydrocarbons Material Is: Liquid

MSDS No: Issue Date: Page: SECTION 10 Stability: Conditions To Avoid: Hazardous Decomposition Products: Incompatibility/ Materials To Avoid: Hazardous Polymerization: SECTION 11 Inhalation: STABILITY AND REACTIVITY Stable. Avoid flames or other sources of ignition. Hydrocarbons, aldehydes, smoke, carbon monoxide, carbon dioxide.

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Strong oxidizing agents. Will not occur. TOXICOLOGICAL INFORMATION Long term inhalation may be irritation to the respiratory tract. Overexposure may cause drowsiness, dullness, numbness, and headache followed by dizziness, weakness, and nausea. Contact may cause mild irritation. Prolonged or repeated contact may cause dermatitis. Individuals with preexisting skin conditions are more susceptible to skin irritation. Product may cause redness and irritation. May cause irritation. No data available. None of the components are known to cause sensitization. The International Agency for Research on Cancer (IARC) has concluded that light and intermediate middle distillates and Group 3 substances, not classifiable as to the carcinogenicity to humans, based on inadequate human and inadequate animal evidence. None of the components have been found to be mutagenic. None of the components are known to cause adverse reproductive effects. None known.

Skin:

Eye: Ingestion: Toxicity Data: Sensitization: Carcinogenicity:

Mutagenicity: Reproductive Toxicity: Medical Conditions Aggravated By Exposure:

SECTION 12 ECOLOGICAL INFORMATION Acute Aquatic Effects: No data available. SECTION 13 Waste Disposal: DISPOSAL CONSIDERATIONS Dispose of in accordance with federal, state, and local regulations. It is the responsibility of the end-user to determine at the time of disposal of the product. EPA Hazardous Waste Number: None. EPA Hazard Waste Class: None.

SECTION 14 TRANSPORT INFORMATION DOT Proper Shipping Name: Not regulated. Hazard Class/Packing Group: None. UN/NA Number: None. Hazard Labels: None. IMDG Proper Shipping Name: Hazard Class/Packing Group: UN/NA Number: Hazard Labels:

Not regulated. None. None. None.

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SECTION 15 REGULATORY INFORMATION Hazard Category for Section Not regulated. 311/312: Section 302 Extremely Hazardous This product does not contain chemicals regulated under SARA Title III, Substances (TPQ): Section 302. Section 313 Toxic Chemicals: This product does not contain any chemicals subject to SARA Title III Section 313 Reporting requirements. CERCLA 103 Reportable Quantity: This product does not contain chemicals regulated under CERCLA. Many states have more stringent release reporting requirements. Report spills required under federal, state and local regulations. This product does not contain chemicals regulated under California Proposition 65. All of the components of this product are listed on the TSCA inventory. Not a Controlled Product. This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR.

California Proposition 65: TSCA Inventory: Canadian WHMIS Classification:

SECTION 16 OTHER INFORMATION NFPA and HMIS: NFPA Hazard Signal Health: 0 Flammability: 1 HMIS Hazard Signal: Health: 0 Flammability: 1

Reactivity: 0 Reactivity: 0

Special: None PPE: X

Disclaimer:
The information in this MSDS was obtained from sources we believe to be reliable. However, the information is provided by Cherne Industries Incorporated without any warranty, express or implied, regarding its correctness. Some information presented and conclusions drawn herein are from sources other than direct test data on the substance itself. If the product is used as a component in another product other than listed in section 1, this MSDS information may not be applicable. Users should make their own investigations to determine the suitability of the information or products for their particular purpose. The conditions or methods of handling, storage, use, and disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, Cherne Industries Incorporated does not assume responsibility and expressly disclaims liability for loss, damage or expense arising out of or in any way connected with handling, storage, use, or disposal of the product.