Aiits 1416 PT III Jeem Jeea Advanced Paper 2 Questions Paper
Aiits 1416 PT III Jeem Jeea Advanced Paper 2 Questions Paper
Aiits 1416 PT III Jeem Jeea Advanced Paper 2 Questions Paper
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FIITJEE
Paper 2
Time Allotted: 3 Hours
Pl ea s e r ea d t h e i n s t r u c t i o n s c a r ef u l l y. Yo u a r e a l l o t t ed 5 m i n ut es
s p ec i f i c a ll y f o r t h i s p u r p o s e.
Yo u a r e n o t a l l o wed t o l ea v e t h e E xa m i n at i o n Ha l l b ef o r e t h e en d o f
t h e t es t .
INSTRUCTIONS
A. General Instructions
1.
2.
3.
4.
5.
Attempt ALL the questions. Answers have to be marked on the OMR sheets.
This question paper contains Three Parts.
Part-I is Physics, Part-II is Chemistry and Part-III is Mathematics.
Each part has only one section: Section-A.
Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic
devices, in any form, are not allowed.
Section-A (01 to 10) contains 10 multiple choice questions which have one correct answer.
Each question carries +3 marks for correct answer and 1 mark for wrong answer.
Section-A (11 to 16) contains 3 paragraphs with each having 2 questions. Each question carries
+3 marks for correct answer and 1 mark for wrong answer.
Section-A (17 20) contains 4 Matching Lists Type questions: Each question has four
statements in LIST I & 4 statements in LIST II. The codes for lists have choices (A), (B), (C), (D)
out of which only one is correct. Each question carries +3 marks for correct answer and
1 mark for wrong answer.
Enrolment No.
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AIITS-PT-III (Paper-2)-PCM-JEE(Advanced)/16
Useful Data
PHYSICS
Acceleration due to gravity
g = 10 m/s2
Planck constant
Charge of electron
e = 1.6 1019 C
Mass of electron
me = 9.1 1031 kg
Density of water
Atmospheric pressure
Pa = 105 N/m2
Gas constant
R = 8.314 J K1 mol1
CHEMISTRY
Gas Constant
Avogadro's Number Na
Plancks constant h
1 Faraday
1 calorie
1 amu
1 eV
=
=
=
=
=
=
=
=
=
=
8.314 J K1 mol1
0.0821 Lit atm K1 mol1
1.987 2 Cal K1 mol1
6.023 1023
6.625 1034 Js
6.625 1027 ergs
96500 coulomb
4.2 joule
1.66 1027 kg
1.6 1019 J
Atomic No:
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Physics
PART I
SECTION - A
Straight Objective Type
This section contains 10 multiple choice questions numbered 1 to 10. Each question has 4 choices (A),
(B), (C) and (D), out of which ONLY ONE is correct.
1.
F
A
2.
3.
c
2R
x
x=0
(D) kI
Space for rough work
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AIITS-PT-III (Paper-2)-PCM-JEE(Advanced)/16
4.
3 1
(B)
C
4
5 1
(C)
C
4
5.
2F
4F
10 V
for y
Bo i
2
b
b
zero for 2 y 2
y
(0, b)
x
0
(a, 0)
(0, -b/2)
(0, -b)
2Bo a
k
o
(B)
2B oa
k
o
(C)
2Bob
k
o
(D)
2B ob
k
o
(0, b/2)
(A)
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AIITS-PT-III (Paper-2)-PCM-JEE(Advanced)/16
7.
8.
B
v0
9.
A parallel plate capacitor is connected across a source of constant potential difference. When a
dielectric plate is introduced between the two plates, then
(A) Potential difference between two plates increases
(B) Potential difference between two plates decreases
(C) Potential difference between two plates remains same
(D) Charge on the plates decreases
10.
5
+
17V
G
19V
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Comprehension Type
This section contains 3 groups of questions. Each group has 2 multiple choice question based on a
paragraph. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of which ONLY ONE is
correct
Paragraph for Question Nos. 11 to 12
In a region, charge density is
x
o sin for 0 x L
L
12.
(A) o i
2
(C) o
i
2L
Equipotential surface will be
(A) Planes parallel to x-y plane
(C) Planes parallel to x-z plane
(B) o
i
22
(D) zero
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Ex(N/c)
20
5 6 7 8 x(m)
20
13.
14.
(B) 20 V
(D) 40 V
The greatest positive value of electric potential for points of the x-axis for which 0 x 6m is :
(A) 10 V
(B) 20 V
(C) 30 V
(D) 40 V
Paragraph for Question Nos. 15 to 16
2V
16.
2V 2
2V
15.
8V
W
(B) 1 A
(D) 3 A
(B) 1 A
2
(D)
A
3
Space for rough work
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AIITS-PT-III (Paper-2)-PCM-JEE(Advanced)/16
17.
Read the following statements and match the following and write the correct pairs.
Three wires are carrying same constant current in different
directions. Four loops enclosing the wires in different manners
Loop 1
i
i
Loop 2
i
Loop 3
Loop 4
(P)
List - I
Along closed loop 1
(1)
List - II
(Q)
(2)
(R)
(3)
(S)
(4)
B.d
oi
oi
B.d
3 oi
B.d
B.d 3oi
Codes:
(A)
(B)
(C)
(D)
P
2
1
4
2
Q
1
4
3
3
R
2
2
1
4
S
1
3
2
1
Space for rough work
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AIITS-PT-III (Paper-2)-PCM-JEE(Advanced)/16
18.
2Q
List - I
List - II
(P)
(1)
Q/2
(Q)
(2)
(R)
(3)
(S)
(4)
3Q/2
Codes:
(A)
(B)
(C)
(D)
19.
P
2
1
4
2
Q
3
4
3
1
R
1
2
1
4
S
4
3
2
3
List I
List - II
(P)
(1)
Maximum
(Q)
(2)
Minimum
(R)
Intensity of B1
(3)
Same
(S)
Current drawn by B2
(4)
Different
Codes:
(A)
(B)
(C)
(D)
P
2
1
4
2
Q
1
4
3
3
R
2
1
1
4
S
1
2
2
1
Space for rough work
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20.
List I
List - II
(Q)
B at A is
B at B is
(R)
B at C is
(3)
(S)
B at D is
(4)
(P)
(1)
Zero
(2)
0 JR
3
5 0 JR
3
15 0 JR
32
Codes:
(A)
(B)
(C)
(D)
P
2
1
1
2
Q
1
4
1
3
R
2
2
2
4
S
1
3
4
1
Space for rough work
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AIITS-PT-III (Paper-2)-PCM-JEE(Advanced)/16
Chemistry
PART II
SECTION - A
Straight Objective Type
This section contains 10 multiple choice questions numbered 1 to 10. Each question has 4 choices (A),
(B), (C) and (D), out of which ONLY ONE is correct.
1.
(B)
CH3
CH3
(C)
CH3
(D)
2.
1(A)
(B)
(C)
(D)
3.
Bromination of aniline gives 2, 4, 6 tribromoaniline where as the nitration of aniline with mixed
acids gives m nitroaniline. In this case nitration, the m derivative is formed because
(A)
(B)
(C)
(D)
4.
In the presence of strong acids the amino group is protonated to NH3 which is m orienting
m nitro aniline is thermodynamically more stable than the ortho and para-isomers
nitro groups can not enter ortho and para-positions due to steric factor
the mechanism of bromination and nitration are different
The major product formed by the reaction of a anisole with tert-butyl alcohol is
(A) 1- methoxycyclohexa 1,4 diene
(B) 2 methoxycyclohexa -1,3 diene
(C) 1- methoxycyclohexa 1,3 diene
(D) 3- methoxycyclohexa 1,4 diene
Space for rough work
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COCH3
5.
NaOBr
Pr oduct
OH
The product is
COOH
O
(A)
(B)
OH
O
COCH2Br
(C)
(D)
OH
Br
OH
6.
(i) LiAlH4
A
(ii) H O
3
RC N
(i) CH3MgBr
B
(ii) H O
3
A and B are
(A)
O
R
O
H
and
(B)
and
R
CH3
CH3
(C)
R
NH2
and
(D)
NH
CH3
CH3 and
R
R
H
CH3
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7.
O
II
(i) CH3MgBr
C6H5 CH = CH - C -CH3
[X] (major product)
(ii)H2O / H
X will be
H3 C
CH3
H5 C6
CH3
(A)
(B)
C 6H 5
CH3
OH
H3C
OH
CH3
CH3
OH
(C)
(D)
C6 H5
H3C
CH3
C6 H 5
8.
H
H3C
H / DMSO
Major product;
Ph
(B)
Ph
H 2C
NH
H3C
NH2
Ph
NH2
(C)
OH
(D)
H3C
H3C
N
Ph
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C2H5
9.
acetone
NaSCH3
A
SN2
Br
The compound A is
C2H5
(A)
C2H5
(B)
SCH3
(C)
C2 H5
(D)
H5 C2
SCH3
SCH3
SCH3
10.
CH3
(C)
CH3
(D)
NHCH3
NCH3
CH3
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Comprehension Type
This section contains 3 groups of questions. Each group has 2 multiple choice question based on a
paragraph. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of which ONLY ONE is
correct.
Paragraph for Question Nos. 11 to 12
Aldehydes without - hydrogen undergoes Cannizzaro reaction in the presence of conc. Alkali. Two
molecule undergoes self oxidation and reduction to yield a mixture of alcohol and salt of carboxylic acid.
Two different aldehydes without hydrogen undergoes crossed Cannizzaro reaction. The rate of reaction
is decided by the ease with which H is transferred.
11.
50% NaOH
HCHO PhCHO
P Q
P and Q are
(A) HCOOH and PhCOONa
(C) CH3OH and PhCOONa
12.
(H3C)3C
conc. NaOH
H
Pr oduct s
CH2OH
OH O
(B) Product is (H3C)3C
OH O
(C) Product is (H3C)3C
(D) Product are (H3C)3C
CH and (H3C)3C
CH2OH
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05 C
CH2NH2
(A)
(B)
OH
(C)
OH
(D)
CH2
CH3
14.
OH
Which of the following product(s) will be obtained when n-propyl amine is treated with NaNO2 and
HCl?
(A) H3C CH CH3
(B) H3C CH CH2
(C)
H3C
OH
CH
CH3
(D)
All of these
Cl
Space for rough work
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Polyhydric
Acetyl derivative
alcohol
(ii) Total number of OH groups in vicinal position can be calculated by oxidation with periodic acid or
lead tetra acetate.
C
OH
HIO4
or Pb(OCOCH3 )4
OH
15.
0.436 g of acetyl derivative of a polyhydric alcohol (molecular mass = 92) require 0.336 g KOH for
hydrolysis. The total numbers of hydroxyl group(s) in the alcohol are
(A) 1
(B) 2
(C) 3
(D) 4
16.
The product formed by the reaction of ethylene glycol and periodic acid (HIO4) is
(A) acetic acid
(B) formic acid
(C) formaldehyde
(D) glyoxal
Space for rough work
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CH3CH2CH2Cl
(1)
Column - II
(Major product)
CH3CH2CH=CH2
CH3
C H5ONa
CH3CCH3 2
(2)
CH3CH=CHCH3
(3)
CH3CH=CH2
(4)
CH3C=CH2
C2H5ONa
C2H5OH
(Q)
C2H5OH
Cl
(R)
Cl
tBuOK
(S)
Cl
2 H 5 ONa
CH 3 CH 2 CH CH 3 C
CH3
C2H 5OH
Codes:
(A)
(B)
(C)
(D)
P
3
1
3
4
Q
4
4
2
3
R
1
3
1
2
S
2
2
4
1
Space for rough work
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2.
3.
H C C CH
3
ii H2O2 / OH
Column II
Preparation of amines
Preparation of hydroxy ester
halogenation of carboxylic acid
Preparation of keto ester
(1)
(2)
(3)
(4)
(1)
Column II
CH3 CH2 CH = CH2
(2)
CH3 CH = CH CH3
CH3
(Q)
H3C
i Hg OAc
/HOH
CH2
ii NaBH4
C
CH3
(R)
Cl
H3C
CH2
(3)
CH3 ONa
CH3
CH
Cl
(S)
H3C
CH2
CH
CH3
H3C
(4)
CH3 3 CONa
CH3
CH
CH2
OH
OH
H3C
CH3
CH3
Codes:
(A)
(B)
(C)
(D)
P
4
3
3
3
Q
1
4
2
2
R
2
2
1
4
S
3
1
4
1
Space for rough work
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4.
(1)
Column II
Curtius rearrangement
(Q)
N3H
RCOOH
R NH2
H2SO4
(2)
Lossen rearrangement
(R)
NaN3
RCOCl
R NH2
(3)
Schmidt rearrangement
(4)
Hoffmann rearrangement
(S)
O
||
2
R C Cl
OH /
i NH OH
Codes:
(A)
(B)
(C)
(D)
P
4
1
3
4
Q
1
4
2
3
R
2
3
1
1
S
3
2
4
2
Space for rough work
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Mathematics
PART III
SECTION - A
Straight Objective Type
This section contains 10 multiple choice questions numbered 1 to 10. Each question has 4 choices (A),
(B), (C) and (D), out of which ONLY ONE is correct.
1.
2.
3.
4.
(A)
2ln 2
(C)
2ln 2
(B)
(D)
2
.
ln2
y
y
2cos x sin x
dx A ln cos x sin x 2 Bx C then the ordered pair triplet A, B, C is
cos x sin x 2
1 3
3 1
(A) , , 1
(B) , , 1
2 2
2 2
3
1
1
3
(C) , 1,
(D) , 1, .
2
2
2
2
If
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1
5.
I1 e
cos xdx I2 e
x2
cos x dx I3 e
x2
2
1
2
cos x dx I4 e
x2
2 dx
then
6.
equals
(A) 1060
(C) 960
7.
8.
9.
If I
f k
k 1
(B) 1260
(D) 1224
dx
, then I equals
sin x cos x
3
Consider a function f defined on the set of all non-negative integers such that
f(0)=1,f(1)=0and f(n)+f(n-1)=n f(n-1)+(n-1)f(n-2)for n 2 . Then f(5) =
(A) 40
(B) 44
(C) 45
(D) 60
x y f x f y
Let f : R R be a function such that f
,f 0 0 and f 0 3, then
3
3
f x
(A) 2 is differentiable in R
x
(B) f x is continuous but not differentiable in R
tan x
, then log e lim f(x) x 2 f (x) is equal, (where [] denotes greatest integer
x 0
x
Let f(x)
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AIITS-PT-III (Paper-2)-PCM-JEE(Advanced)/16
Comprehension Type
This section contains 3 groups of questions. Each group has 2 multiple choice question based on a
paragraph. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of which ONLY ONE is
correct.
11.
The value of A cos ec 1x dx {where [.] denotes greatest integer function} is equal to
1
(A) cosec 1 1
(B) 1
(C) 1 sin 1
(D) none of these.
12.
The value of B
100
(A) sec 1
(C) 99 sec 1
Value of a is
(A) 4
(C)
2
(B) 2
(D) 1.
14.
f r n Cr
is
r 1
(A) n2n1
n1
n2
(C) n2 + n(n 1)2
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AIITS-PT-III (Paper-2)-PCM-JEE(Advanced)/16
0
h
h
16.
If f is even which of following is right hand derivative of f at x = a
f a f a h
f a f a h
(A) lim
(B) lim
h 0
h 0
h
h
f a f a h
f a f a h
(C) lim
(D) lim
h 0
h 0
h
h
(S)
dy
dx
If f be a differentiable function such that f(xy) = f(x) + f(y) x
R, y R then f(e) + f(1/e) =
If f be a twice differentiable function such that f(x) = f(x) and
f(x) = g(x) if h(x) = (f(x))2 + (g(x))2and h(5) = 9 then h(10) = A
find value of 3A
dy
y = tan1(cot x) + cot1(tan x) x then
2
dx
3
List II
1.
2.
3.
4.
27
Codes:
(A)
(B)
(C)
(D)
P
4
1
3
4
Q
3
2
2
1
R
2
3
4
3
S
1
4
1
2
Space for rough work
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AIITS-PT-III (Paper-2)-PCM-JEE(Advanced)/16
18.
List I
Number of points of discontinuity of f(x) = tan2 x sec2x in (0,
2) is
1
1
1
Number of points at which f(x) = sin x + tan x + cot x is non
differentiable
Number of points of discontinuity of y = [sin x], x [0, 2) is N
then value of |2N| where [.] represents greatest integer function
Number of points where y = |(x 1)3| + |(x 2)5| + |x 3| is non
differentiable
List II
1.
2.
3.
4.
Codes:
(A)
(B)
(C)
(D)
19.
P
4
1
4
3
Q
3
2
1
2
R
2
3
3
4
S
1
4
2
1
List I
Let f : R R be a differentiable function and f(1) = 1, f(1) = 3;
x2
x 1
f t t
x 12 dt
List II
1.
2.
3.
4.
(Q)
(R)
(S)
1 n 4
lim
is equal to
n
2
2x
If lim
tan1 nx ; x > 0 then lim f x 1 is {where [.]
n
x 0
represents greatest integer function.
n 1
lim r where [.] denotes greatest integer function
n
r 1 2
Codes:
(A)
(B)
(C)
(D)
P
4
1
2
4
Q
3
2
3
1
R
2
3
4
2
S
1
4
1
3
Space for rough work
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
26
AIITS-PT-III (Paper-2)-PCM-JEE(Advanced)/16
20.
List II
10
(P)
(Q)
(R)
(S)
5050 x 200 dx
lim
1
then =
1.
1
100
2.
3.
4.
1
200
Codes:
(A)
(B)
(C)
(D)
P
4
1
2
4
Q
3
2
3
1
R
2
3
4
2
S
1
4
1
3
Space for rough work
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com