S E C T I O N

P H Y S I C A L
M

III

P R O P E R T I E S
S

O
V

F
T

P h y s i c a l

P r o p e r t i e s

o f

M o n o m e r s

D a n i e l R. B l o c h
Lakeshore Research, 5536 W. Branch Trail, Racine, Wl 53402, USA

A. Introduction
B. Tables of Physical Properties
Table 1. Acetylenes
Table 2. Acid Dichlorides
Table 3. Acroleins
Table 4. Acrylamides/Methacrylamides
4.1. Acrylamides
4.2. Methacrylamide
Table 5. Acrylates/Methacrylates
5.1. Acrylate, Acids/Esters
5.2. Methacrylate, Acids/Esters
Table 6. Alcohols
6.1. Alkanediols
6.2. Ether Diols
Table 7. AIIyI Functional
Table 8. Amines, Difunctional
Table 9. Anhydrides
9.1. Monoanhydrides
9.2. Dianhydrides
Table 10. Butadienes
10.1. 1,2-Butadienes
10.2. 1,3-Butadienes
Table 11. Butenes
11.1. 1-Butenes
11.2. 2-Butenes
Table 12. Epoxides
12.1. Monoepoxides
12.2. Diepoxides
Table 13. Ethylene Halides
Table 14. Fumaric, Acids/Esters
Table 15. lsocyanates
Table 16. Lactams
Table 17. Lactones
Table 18. Maleic, Acids/Esters
Table 19. Propenes
Table 20. Styrenes
Table 21. Vinyl Functional
21.1. Aryl
21.2. Esters
21.3. Ethers

111-1
ill-4
III-4
III-4
III-4
III-4
III-4
III-6
III-8
III-8
111-12
111-16
111-16
111-18
111-18
III-20
III-20
III-20
III-24
III-24
III-24
III-24
III-26
III-26
III-26
III-26
III-26
III-28
III-28
III-30
III-30
III-32
IM-32
III-32
III-32
III-34
III-36
III-36
III-36
III-38

21.4. /V-substituted
21.5. Sulfonates

A.

III-38
III-40

INTRODUCTION

This chapter contains some of the principal properties of the

more common monomers. The monomers are arranged
alphabetically, in groups, with derivatives listed alphabetically within the groups. Compounds are listed under their
most commonly used names in polymer chemistry. Therefore, some names are not in agreement with the nomenclature rules of the International Union of Pure and Applied
Chemistry.
Data are taken from a variety of published literature,
including the 3rd edition of the "Polymer Handbook",
"The Brandon Worldwide Monomer Reference Guide and
Sourcebook", the "Aldrich Catalog Handbook of Fine
Chemicals", and "Polysciences Monomers/Polymers,
Scientific Polymer Products", "TCI America", "Lancaster
and Janssen Chemica" catalogs. Where a range is reported
in the literature, the average value is used here for melting
points and boiling points. No attempt was made to verify
the reported values experimentally.
Linear structures are given for most monomers. Molecular formulas are provided when linear structures cannot
be unambiguously drawn.
Molecular weight is calculated based on the International
Atomic Weight values.
Boiling point is given in degrees Celsius (0C), at
760mmHg, unless indicated otherwise by the value in
mmHg following a slash (/).
Melting point is given in degrees Celsius (0C), at
760 mmHg, unless indicated otherwise by the value in
mmHg following a slash (/).
Refractive index is given at 200C, unless indicated
otherwise by the temperature in Celsius following a slash
(/).
Density is relative to water at 4C and measured at 200C,
unless otherwise indicated by the value following a slash
(/).
Flash point was determined by the closed-cup method,
using a Setaflash apparatus.

RTECS# is the reference to the Registry of Toxic Effects

of Chemical Substances.
R&S is the reference found in the "Sigma-Aldrich
Library of Regulatory & Safety Data", available from
Aldrich Chemical Company.
FT-NMR is the reference to spectra in the "Aldrich
Library of 13C and 1H FT-NMR Spectra", available from
the Aldrich Chemical Company.
FT-IR is the reference to spectra in the "Aldrich Library
of FT-IR Spectra", available from the Aldrich Chemical
Company.

Merck Index is the reference to "The Merck Index",

Merck & Co., Inc., Whitehouse Station, NJ.
Beilstein is the reference to "Beilsteins Handbuch
der Organischen Chemie", Springer-Verlag, New York,
NY.
Fieser is the reference to L. F. Fieser and M. Fieser,
"Reagents for Organic Synthesis", John Wiley, New York,
NY.
Abbreviations: (d) decomposes; (s) sublimes; (aq)
aqueous.

B. TABLES OF PHYSICAL PROPERTIES

TABLE 1. ACETYLENES
Formula RC = CR'
Name
Acetylene
- , Chloro
- , Dichloro- , Diphenyl- , Phenyl-

CAS
Registry
Number

R'

-H
-Cl
-Cl
-C 6 H 5
-C 6 H 5

-H
-H
-Cl
-C 6 H 5
-H

74-86-2
501-65-5

MoL wt.
26.04
60.48
94.93
178.23
102.14

Boiling
point (0C)
-82
-32
60
143

Melting
point (0C)
- 84(s)
-126
-66
170/19

TABLE 2. ACID DICHLORIDES

Formula ClC(O)RC(O)Cl
Name
Adipoyl
Azelaoyl
Diethylmanoyl
Dodecanedioyl
Glutaryl
Isophthaloyl
Malonyl
Methylpimeloyl
Oxalyl
Phthaloyl
Pimeloyl
Sebacoyl
Suberoyl
Succinyl
Terephthaloyl
Thionyl

CAS
Registry
Number

R
-(CH 2 ) 4 -(CH 2 ) 7 -C(CH 2 CH 3 ) 2 -(CH 2 ) 1 0 -(CH 2 ) 3 -C6H4-CH2-(CH 2 ) 2 CH(CH 3 )(CH 2 ) 2 -CO-CO-C6H4-(CH 2 ) 5 -(CH 2 ) 8 -(CH 2 ) 6 -(CH 2 ) 2 -C6H4ClC(S)Cl

111-50-2
123-98-8
54505-72-5
4834-98-4
2873-74-7
99-63-8
1663-67-8
44987-62-4
79-37-8
88-95-9
142-79-0
111-19-3
10027-07-3
543-20-4
100-20-9
7719-09-7

MoI. wt.

Boiling
point (0C)

183.03
255.12
197.06
267.20
169.01
203.02
140.95
197.06
126.93
203.02
197.06
239.14
211.09
154.98
203.02
118.97

106/2
166/18
198
140/0.5
217
276
54/19
118/10
61
270
113/5
168/12
162/15
190
266
79

MoI. wt.

Boiling
point (0C)

Melting
point (0C)

43
-8
12
-2.5
16
80
-105

TABLE 3. ACROLEINS
Formula HC(O)CR = CHR'
Name
Acrolein
-, 2-Chloro- , 2-Methyl- , 3-Methyl-,
fra/w-(Crotonaldehyde)
- , 2-Chloro-3-methyl-

CAS
Registry
Number

R'

-H
-Cl
-CH 3

-H
-H
-H

107-02-8

-H
-Cl

-CH 3
-CH 3

123-73-9

78-85-3

56.06
90.51
70.09

53
40/30
68

70.09
104.54

148

Melting
point (0C)
-87
-81
104

TABLE 4. ACRYLAMIDES/METHACRYLAMIDES
Name

4.1. ACRYLAMIDES H2C=CHC(O)NRR'

Acrylamide
-H
-, Acetyl-, N-C(O)CH3
- , Adamantyl-, N-Ci 0 H 5
-,AlIyI-, N-CH2CH=CH2
- , Benzyl-, N-CH 2 C 6 H 5
- , Butoxymethyl-, N-CH2O(CH2)3CH3
- , terf-Butyl-, N-C(CH 3 ) 3
- , Cyclohexyl-, N-C 6 Hn
- , Cystamine-bis-, NJf'-CH 2 CH 2 SSCH 2 CH 2 - , Diacetone-, N-C(CH3)2CH2C(O)CH3
- , Diallyl-, N,N-CH2CH=CH2
- , Di-n-butyl-, N9N-(CH 2 ) 3 CH 3

R'
-H
-H
-H
-H
-H
-H
-H
-H
-H
-H
-CH2CH=CH2
-(CH 2 ) 3 CH 3

CAS Registry
Number

MoI. wt.

79-06-1
1432-45-7
19026-83-6
2555-13-7
13304-62-6
1852-16-0
107-58-4
3066-72-6
60984-57-8
2873-97-4
3085-68-5
2274-13-7

71.08
113.12
205.30
111.14
161.20
157.21
127.19
153.23
260.38
169.23
151.21
183.29

Boiling
point (C)

Melting
point (0C)

125/25
129
155
120/19
125/0.3

93/0.1
108/3
97/1

70
-9
128
113
123
55

Density
(at 200C)

Refractive
index (at 200C)

Flash
point (C)

1.000
0.990
0.929

Density
(at 200C)
1.259
1.143
1.145
1.069
1.324

R and S

FT-NMR

FT-IR

Fieser
1,11

1(2),2711I

Refractive
index (at 200C)
1.4700
1.4680
1.4590
1.4680
1.4720

1.631

1.5190

1(3), 533A

1(2),946B

Refractive
index (at 200C)

Flash
point (0C)
>110
>110
74
>110
107
180
47
>110
None
>110
>110
>110
>110
77
180
None

RTECS
Number

R and S

WN4900000
WZ1797000
XM515OOOO

1(1), 867J
1(1),869C
1(1),867G
1(1),869E
1(1),867I
1(2),1981H
1(1),867F
1(1),867K
1(1),867D
1(2),1981G
1(1),869A
1(1),869D
1(1),869B
1(1),867H
1(2),1981I
1(2),3197F

Flash
point (C)

RTECS
Number

R and S

NT2625000
KI2950000

FT-NMR

FT-IR

11,9428

1(1),1211B
1(1)1212C
1(1),1212A

5,656

1,335

Beilstein

Fieser

1(1),1211A
1(1),1212B

1(1),1211C

FT-NMR

l(l),740D
1(2),352A
l(l),740A
1(1),741B
1(1),739C
1(2),351D
1(1),741C
1(1),742B
1(1),741D
l(l),740C
1(2),352B
1(2),1227B

FT-IR

-19

AS105000

1(1),515A

1(1),733B

l(l),470D

-16

OZ2625000

1(1),515B

1(1),733C

1(1),471A

0.846
1.478

1.4365

GP9625000

1(1),515G

RTECS
Number

R and S

AS3325000

1(1),877K

Flash
point (C)

1.122

1.4620

> 110

>110

1(1),472C

FT-NMR
1(1),1221A

2,653
2,709
2,687
2(4),2127
2,634
9,834
2(1),252

l(l),740B

1.4025
1.463
1.4160

Refractive
index (at 200C)

Merck

1(1),741A

0.839
1.199
0.847

0.9790

Beilstein

1.548

1.4650
1.4720
1.4290
1.5684
1.4690
1.4680
1.4680
1.4680

Density
(at 200C)

Merck

AO9600000

1.449
1.217
1.455
1.409
1.205
1.121
1.172
1.407

Density
(at 200C)

RTECS
Number

FT-IR
1(1),749B

11,6867
11,7439

11,8844
11,9278

Merck
11,122

13,297

Beilstein

Fieser

1,725

10,2

11,2599

Merck
11,123

1,728

Beilstein
2,400

4(4),664
1(1),887I

1(1),1236A

l(l),750C

17,241
14,263

1(3),2981

AS3450000
AS3460000
AS3475000

2,542
9,805
2,671
2,719
2,694
2,613
9,844

12,291

11,2943

Fieser

TABLE 4.

cont'd

- , Diethyl-, N9N- , 1,2-Dihydroxyethylenebis-,N,N'

- , Diisopropyl-, N,N- , 4,4-Dimethoxybutyl-, N- , Dimethyl-, N9N- , 3-(Dimethylamino)propyl-, N-, l,l-Dimethyl-2sulfoethyl-, N-(AMPS)
- , Diphenylmethyl-,7V- , Ethylenebis-,WV'- , Ethylhexyl-,iV- , 2-Glycolic acid, N- , 2-Glycolic acid
methyl ester, N- , Hexamethylenebis-, N,Nf
- , tert-Hexyl-, N- , Hydroxymethyl-,
N- (solution)
- , Isobornyl-, N-, Isobutoxymethyl-, N-, Isopropyl-, N-, Isopropylidenebis-,
N9N1- , 3-Methoxypropyl-, N- , Methyl-, N- , Methylenebis-, N,Nf- , (1-Methoxy)
- , (Methoxy)acetoxymethyl-, N- , Morpholinoethyl-, N- , 1-Naphthyl-, N- , Octadecyl-, N- , Octamethylenebis-,
NJ*'- , tert-Octyl-, N- , Phthalamidomethyl-, N- , 2,2,2-Trichloro-lhydroxyethyl-, N- , Tri(hydroxymethyl)methyl-, N
-, 1,1,3-Trimethylbutyl-, N- , Trimethylenebis-, N,N'- , Triphenylmethyl-, N4.2.

R;

Name

Boiling
point (0C)

CAS Registry
Number

MoI. wt.

2675-94-7
868-63-3

127.19
200.19

93/19
54/0.4
135/0.7
82/21
117/2

Melting
point (0C)

-CH 2 CH 3
-CH(OH)CH(OH)-

-CH 2 CH 3
-H

-CH(CHs) 2
-(CH 2 ) 3 CH(OCH 3 ) 2
-CH3
-(CH 2 ) 3 N(CH 3 ) 2

-CH(CH 3 ),
-H
-CH3
-H

44975-46-4
38486-53-2
2680-03-7
3845-76-9

155.24
187.24
99.13
156.23

-C(CH 3 ) 2 CH 2 SO 3 H

-H

15214-89-8

207.25

-CH(C 6 H 5 ),
-CH2CH2-CH 2 CH(CH 2 CH 3 )
(CH 2 ) 3 CH 3
-CH(OH)C(O)OH
-CH(OH)C(O)OCH3

-H
-H
-H

10254-08-7
2956-58-3
91625-16-0

237.30
168.20
183.30

-H
-H

6737-24-2
77402-03-0

163.13
173.17

-(CH2)6-

-H

7150-41-6

224.28

135

-CH 2 CH 2 C(CH 3 ),
-CH 2 OH

-H
-H

51330-07-5
924-42-5

155.24
101.11

100

- C H)H 17

-CH 2 OCH 2 CH(CH 3 ) 2

-CH(CH 3 ),
-C(CH3)2-

-H
-H
-H
-H

17159-04-5
16669-59-3
2210-25-5

207.31
157.21
113.16
182.22

-(CH 2 ) 3 OCH 3
-CH3
-CH2-

-H
-H
-H

107374-86-7
1187-59-3
110-26-9

143.19
85.11
154.17

-C(OCH 3 )C(O)OCH 3

-H

77402-03-0

173.17

-CH 2 CH 2 NC 4 H 8 O
-Ci0H7
-(CH 2 ) 17 CH 3
-(CH2)8-

-H
-H
-H
-H

5117-12-4
22302-62-1
1506-54-3
2945-02-0

141.17
197.24
323.56
252.35

-(CH 2 ) 4 C(CH 3 ) 3
-CH 2 NC 8 H 4 O 2
-CH(OH)CCl 3

-H
-H
-H

4223-03-4
80500-94-3

183.29
230.22
218.47

58
190
170

-C(CH 2 OH) 3

-H

13880-05-2

175.18

139

-C(CH 3 ) 2 CH 2 CH(CH 3 ) 2
-(CH2),-C(C 6 H 5 ),

-H
-H
-H

25269-93-6
4887-13-2
102548-89-0

169.27
182.22
313.40

156(d)

18

195(d)

178
140

123/0.5
95
74

135

108
90/2

61
210

99/0.3
106/4
>300
73

158/50

125/25

>110
138
75
138

55
112
204

METHACRYLAMIDES H2C=C(CH3)C(O)NRR'

215
76/1.2

Methacrylamide
- , Acetyl-, N- , Acetylphenyl-, N- , AlIyI-, N- , 3-Aminopropyl-, N-,
hydrochloride
- , Benzyl-, N-, Bis(diethylaminoethyl)-,
N9N- , Butoxymethyl-, N-

-H
-C(O)CH 3
-C 6 H 4 C(O)CH 3
-CH 2 CH=CH 2
-(CH 2 ) 3 NH 2 HC1

-H
-H
-H
-H
-H

79-39-0
44810-87-9
58813-69-7
2186-33-6
72607-53-5

85.11
127.14
203.24
125.17
178.66

-CH 2 C 6 H 5
-CH 2 CH 2 N(CH 2 CH 3 ) 2

3219-55-4
76392-05-7

175.23
183.28

122/0.4

-CH 2 O(CH 2 ) 3 CH 3

-H
-CH 2 CH 2 N(CH 2 CH 3 ),
-H

171.24

105/0.3

-, ^rr-Butyl-, N- , 2-Cyanoethyl-, N- , 2-Cyanoethyl-, N-,

methyl-, N

-C(CH 3 ),
-CH 2 CH 2 CN
-CH 2 CH 2 CN

-H
-H
-CH3

5153-77-5
28384-61-4
6554-73-0
24854-94-2

142.20
138.17
152.20

163

109
138
138

90/2.2
124
82

113/1

60
46
46

Density
(at 200C)

0.962
0.949

Refractive
index (at 200C)

1.4730
1.4820

Flash
point (0C)

71
> 110

RTECS
Number

AU3230000

160

R and S

FT-NMR

1(1),885K

1(1),1233C

1(1),893I

1(1),1244C

l(l),1065K

1(1),1438C

FT-IR

1(3),784B

1(1),915E
1(1),913D

1(1),885J

1.074

1.4130

None

AS3600000

0.970

1.4610

79

AS3630000
AS3675000

1.122

1.5120

Beilstein

4(3),130
4(4), 1268

4(3),526

1(1),883K

AI8967330

Merck

1(1),1276B
1(1),1272B

1(1),781A

l(l),750A

2(4), 1472

4(4),517

AS3678000

1(1),883J

l(l),1230C

AI8967330

1(1),913D

1(1),1272B

> 110

1(1),749D

1.10

UC6475000

1(1),883M

1(1),1231B

1(1),877L

1(1),1221B

27(4),278

2(2),399
1.4702
0.96

1.46

1.4755

122

1(1),749C

Fieser

TABLE 4.

cont'd
R

Name
-,
-,
-,
-,
-,
-,
-,
-,
-,
-,
-,
-,

Cyclohexyl-, NDiallyl-, N,NDibenzyl-, N,NDibutyl-, NJf3-Di(butyl)aminopropyl-, NDiethyl-, NJf3-(Diethylamino)propyl-, NDiisopropyl-, NJf2,2-Dimethoxyethyl-, NDimethyl-, NJf2-(Dimethylamino)ethyl-, N3-(Dimethylamino)propyl-,
N- , Dodecyl-, N-, Ethylenebis-, NJf'- , 2-Ethylhexyl-, N-, 2-Hydroxyethyl-, N- , Hydroxymethyl-, N- , 4-Hydroxyphenyl-, N- , Isobutoxymethyl-, Af- , Isopropyl-, N-, Methoxymethyl-, N- , Methyl-, N- , Methylenebis-, NJf'- , Methyl-, N-, Phenyl-, N-, Methyl-, N-, 2,2-dimethoxyethyl-, N-, 3-(Af-morpholino)propyl-, A^- , 2-(2-Oxo-l-imidazolidinyl)ethyl-, N- , Phenyl-, N- , Phenyl-, N-, Phenylethyl-, N-, 3-(Trifluoromethyl)phenyl-,
A^- , 3-(Trimethylammonium)propyl-, chloride,
N- (eq. solution)

TABLE 5.

-C6Hn
-CH2CH=CH2
-CH 2 C 6 H 5
-(CH 2 ) 3 CH 3
-(CH2)3N((CH2)3CH3)2
-CH 2 CH 3
-(CH 2 ) 3 N(CH 2 CH 3 ) 2
-CH(CH 3 ) 2
-CH2CH(OCH3)2
-CH 3
-CH 2 CH 2 N(CH 3 ) 2
-(CH 2 ) 3 N(CH 3 ) 2

-H
-CH2CH=CH2
-CH 2 C 6 H 5
-(CH 2 ) 3 CH 3
-H
-CH 2 CH 3
-H
-CH(CH 3 ) 2
-H
-CH 3
-H
-H

-(CH 2 )nCH 3
-CH 2 CH 2 -CH2CH(CH2CH3)(CH2)3CH3
-CH2CH2OH
-CH 2 OH
-C 6 H 4 OH
-CH2OCH(CH3)2
-CH(CH 3 ),
-CH 2 OCH 3
-CH 3
-CH2-CH 3
-CH 3

-H
-H
-H
-H
-H
-H
-H
-H
-H
-H
-H
-C 6 H 5
-CH2CH(OCH3)2

-(CH 2 ) 3 NC 4 H 4 O
-CH 2 CH 2 C 3 H 5 N 2 O

CAS Registry
Number
2918-67-4
13169-99-8
57625-30-6
22240-86-4
76392-03-5
5441-99-6
51745-62-1
95984-11-5
6976-91-6
13081-44-2
5205-93-6

MoL wt.
167.25
197.32
265.36
197.32
253.41
141.21
197.30
169.27
173.21
113.16
156.34
170.26

Boiling
point (0C)

Melting
point (C)
102

50/1.1
41
81/0.8
125/0.13
82/7
134/10
47
27
66/10
87/1.8
134/2

1191-39-5
6117-25-5
5238-56-2
923-02-4
19243-95-9
4548-27-0
13749-61-6
3644-12-0
3887-02-3
2359-15-1
2918-73-2
95984-81-9

253.43
196.25
197.32
129.16
115.13
177.20
171.24
127.19
129.16
99.13
182.22
238.31
187.24

110/0.3
147/1.2
ca. 100
127/5
112/115
80.03
88/3.5

-H
-H

55937-58-1
3089-19-8

212.30
197.24

150/0.08
100

-C 6 H 5
-C 6 H 5
-C 6 H 4 CF 3

-H
-CH 2 CH 2 C 6 H 5
-H

1611-83-2
76392-02-4
783-05-1

161.20
266.37
229.20

84
63
95

-(CH 2 ) 3 N(CH 3 ) 3 HC1

-H

51410-72-1

220.74

-22.5

CAS Registry
Number

MoL wt.

-H
-CH2CH=CH2
-C(O)CH=CH2
-CH 2 C 6 H 5
-C 6 H 4 C 6 H 5
(-(CH2CH2OC6H4)2C(CH3)2
(-CH2CH(OH)CH2OC6H4)2C(CH3)2

79-10-7
999-55-3
2051-76-5
2495-35-4
13026-23-8
64401-02-1
4687-94-9

72.06
112.13
126.11
162.19
226.27
424
484.55

H2C=CBrC(O)OH
BrCH=CHC(O)OH
H2C=CBrC(O)OCH2CH3
-CH 2 CH 2 Br
H2C=C(CH2Br)C(O)OH
H2C=C(CH2Br)C(O)OCH2CH3
H2C=C(CH2Br)C(O)OCH3
-CH 2 CH 2 CH(CH 3 )-(CH 2 ) 4 -CH 2 CH=CHCH 2 -

10443-65-9
1609-92-3
4519-46-4
4823-47-6
72707-66-5
17435-72-2
4224-69-5
19485-03-1
1070-70-8

150.97
150.96
164.99
179.03
164.99
193.05
179.02
198.22
198.22
127.16

145/0.08

88/2
72/2

170
-37
154
90
164
50

ACRYLATES/METHACRYLATES

Name
5.1.

R'

Boiling
point (0C)

Melting
point (0C)

139
123
97/35
110/8

13

ACRYLATE, ACIDS/ESIPERS H2C = CHC(O)OR

Acid
Allyl ester
Anhydride
Benzyl ester
4-Biphenylyl ester
Bisphenol A ethoxylate diester
Bisphenol A diglycidyl
ether diester
2-Bromo3-Bromo-, cis2-Bromo-, ethyl ester
2-Bromoethyl ester
2-Bromomethyl2-Bromomethyl-, ethyl ester
2-Bromomethyl-, methyl ester
1,3-Butylene diester
1,4-Butylene diester
2-Butylene-l,4 diester

224

63
63
72/78
52/5
70
86/20
36/1.3
73/0.1
83/0.3
60/23

Density
(at 200C)

Refractive
index (at 200C)

Flash
point (0C)

RTECS
Number

R and S

FT-NMR

FT-IR

Merck

Beilstein

Fieser

1.4731

0.940

1.4600
1.4744
1.4790

140

1.5002
1.100
0.97

1.4300
1.46

>110

UC6380000

107
4(3),276

SI1225000
1.4707
1.4740
0.97

1.4560

>110

1.110

1.427
1.053

Density
(at 200C)

1.051
0.880

Refractive
index (at 20C)

Flash
point (0C)

54
8

1.0573

1.4202
1.4320
1.4487
1.5143

101

1.146
1.180

1.5450
1.5570

> 110
> 110

RTECS
Number

R and S

AS4375000

1(1),547A

FT-NMR

1(1),776A

FT-IR

1(1),498B

1.4770

1.388
1.489
1.030
1.051
0.9344

1.478
1.490
1.4500
1.4560
1.4422

78
93
>110

AS4900000
AS5250000
UD3130000

11,124
2,400

Beilstein

2,397

2,402
2(4), 1486

1(1),563H
1(1),563I
1.4774

Merck

1(1),563K

l(l),806C

1(1),516C

1(1),745J

l(l),1031C

1(3),696D
2(4), 170

Fieser

TABLE 5.

Name

cont'd

2-(2-Butoxyethoxy)ethyl ester
-CH2CH2OCH2CH2O(CH2)3CH3
2-Butoxyethyl ester
-CH2CH2O(CH2)SCH3
w-Butyl ester
-(CH 2 ) 3 CH 3
s-Butyl ester
-CH(CH3)CH2CH3
f-Butyl ester
-C(CH 3 ) 3
2-ChloroH2C=CClC(O)OH
2-Chloro-, butyl ester
H2C=CC1(O)O(CH2)3CH3
2-Chloro-, ethyl ester
H2C=CClC(O)OCH2CH3
2-Chloro-, methyl ester
H2C=CClC(O)OCH3
3-Chloro-, cisClCH=CHC(O)OH
3-Chloro-, transClCH=CHC(O)OH
2-Chloroethyl ester
-CH2CH2Cl
Cinnamyl ester
-CH2CH=CHC6H5
Crotyl ester
-CH2CH=CHCH3
2-Cyano-, butyl ester
H2C=C(CN)C(O)O(CH2)3CH3
2-Cyano-, ethyl ester
H2C=C(CN)C(O)OCH2CH3
2-Cyano, isobutyl ester
H2C=C(CN)C(O)OCH2CH(CH3)2
2-Cyanoethyl ester
-CH2CH2CN
Cyclohexyl ester
-C 6 H 1 1
Cyclopentyl ester
-C 5 H 9
rc-Decyl ester
-(CH 2 ) 9 CH 3
2,3-Dibromopropyl ester
-CH2CHBrCH2Br
2,3-Dichloropropyl ester
-CH2CHCICH2Cl
Dicyclopentenyl ester
-C1OH13
Dicyclopentenyloxyethyl ester -CH2CH2OC 10H 13
2-(Diethylamino)ethyl ester
-CH2CH2N(CH2CH3)2
3-(Diethylamino)propyl ester
-(CH 2 ) 3 N(CH 2 CH 3 ) 2
Di(ethylene glycol) diester
-CH 2 CH 2 OCH 2 CH 2 Dihydrodicyclopentadienyl estei -C1OH15
2,3-Dihydroxypropyl ester
-CH2CH(OH)CH2OH
2-(Dimethylamino) ethyl ester -CH 2 CH 2 N(CH 3 ) 2
3-(Dimethylamino) neopentyl - CH2C(CH3)2CH2N(CH3)2
ester
3-(Dimethylamino) propyl ester -(CH 2 ) 3 N(CH 3 ) 2
Dipentaerythritol pentaester
(-CH2)3CCH2OCH2C(CH2OH)(CH2-)2
Di(propylene glycol) diester
-CH2CH(CH3)OCH2CH(CH3)Di(trimethylolpropane) tetraester ((-CH2)2C(CH2CH3)CH2)2O
Dodecyl ester
-(CH 2 ) n CH 3
1H,1H,1 lH-Eicosafluoro-CH 2 (CF 2 ) 9 CHF 2
undecylester
2-(2-Ethoxyethoxy)ethyl ester
-(CH2CH2O)2CH2CH3
2-Ethoxyethyl ester
-CH2CH2OCH2CH3
Ethyl ester
-CH 2 CH 3
Ethylene diester
-CH 2 CH 2 2-Ethylhexyl ester
-CH2CH(CH2CH3)(CH2)3CH3
Furfuryl ester
-CH 2 C 4 H 3 O
Glycidyl ester
-CH 2 CH(-O-)CH 2
Glycerol propoxylate triester
-CH(CH3)CH2OCH(CH2OCH2CH(CH3)-)2
1H,1H,2H,2H-Heptadecafluoro- -CH 2 CH 2 (CF 2 ) 7 CF 3
decyl ester
1H, 1 H-Heptafluorobutyl ester -CH 2 CF 2 CF 2 CF 3
Heptyl ester
-(CH 2 ) 6 CH 3
Hexadecyl ester
-(CH 2 ) 15CH3
2,2,3,4,4,4-Hexafluorobutyl este:r -CH2CF2CHFCF3
lH-Hexafluoroisoporpyl ester
-CH(CF 3 ),
Hexanediol diester
-(CHa) 6 n-Hexyl ester
-(CH 2 ) 5 CH 3
4-Hydroxybutyl ester
-(CH 2 ) 4 OH
2-Hydroxyethyl ester
-CH2CH2OH
2-Hydroxy-3-phenoxypropyl
-CH2CH(OH)CH2OC6H5
ester
2-Hydroxypropyl ester
-CH2CH(OH)CH3
Isobornyl ester
-C 10 H 18
Isobutyl ester
-CH2CH(CH3)2

CAS Registry
Number

MoI. wt.

Boiling
point (0C)

Melting
point (0C)

4074-88-8
12542-30-2
10095-20-2
2439-35-2
20166-73-8

232.28
172.22
128.17
128.17
128.17
106.51
162.62
134.56
120.54
106.51
106.51
134.57
188.23
126.16
153.18
125.13
153.18
125.13
154.21
282.38
212.34
271.94
183.04
202.25
248.32
171.27
185.27
214.22
204.27
146.15
143.19
181.24

18526-07-3
60506-81-2
85136-76-1
94108-97-1
2156-97-0
4998-38-3

157.22
524.53
242.27
466.53
240.39
586.17

7328-17-8
106-74-1
140-88-5
2274-11-5
103-11-7
10525-17-4
106-90-1
52408-84-1
27905-45-9

188.23
144.17
100.12
170.16
184.28
152.15
128.13
428
518.10

250
65/16
99
67/2
217
92/16
115/78

424-64-6
2499-58-3
13402-02-3
54052-90-3
2160-89-6
13048-33-4
2499-95-8
2478-10-6
818-61-1
16969-10-1

254.11
170.25
296.50
236.11
222.09
226.28
156.23
144.17
116.11
222.24

121/743
56/1
170/15
48/12
84
295
190
95/0.1
90/12

-101

999-61-1
5888-33-5
106-63-8

130.15
208.30
128.19

77/15
275
132

-92
-15
-61

7251-90-3
141-32-2
2998-08-5
1663-39-4
26952-44-3
13401-85-9
687-46-7
80-63-7
1609-93-4
2345-61-1
2206-89-5
23916-33-8
6606-65-1
7085-85-0
1069-55-2
106-71-8
3066-71-5
16868-13-6
2156-96-9
19660-16-3
24910-84-7
33791-58-1
65983-31-5
2426-54-2

103/23
63/2
145
59/25
30/25
176(d)
100/42
41/20
52/50

-64
60

61
84
64/20
105/2
38/10
92/6
90/5
81/4
103/8
183
145/0.08
185/50
105/6
58/0.5
105/4
100/0.5
171.27
44/0.1
162
119/5
115/0.1
64/12
53/1.4

-17
-17

<-60
-40
<-60

167
95/0.5
120/1
115/1

49

-72
-90

100/4

-45

Density
(at 200C)
0.9821
0.9497
0.894
0.8114
0.8850

Refractive
index (at 200C)
1.4394
1.4323
1.4180
1.4140
1.4108

Flash
point (0C)
90
39

RTECS
Number

R and S

UD3150000

1(1),719E

1(1),974A

1(1),642A

1(1),719F

1(1),974B

1(3),674D

2(3),1228

1(1),563F
1(1),563G

l(l),805C
l(l),806A

1(1),516A
1(1),516B

2,400
2,400

FT-NMR

FT-IR

Merck

11,1539

Beilstein

Fieser

2(2),388

17
1.1404
1.189

1.4384
1.4420
33

AS5960000

1.1404
1.0495

1.4384
1.5660

0.986
1.069

1.4420

99
108

1.0690
0.975

1.4433
1.4673

124
29

0.8781
1.7803
1.2603

1.440
1.5520
1.4765

227

1.085
0.9250
0.9180
1.118
1.08

1.5010
1.443
1.441
1.4630
1.509

99
68

AS8225000

> 110

AS9450000

0.943
0.90

1.4380
1.439

58
75

AS8578000

0.928
1.1915

1.4400

68
115

1.101
0.884

1.4488
1.4790
1.4450

3(3),543

AT1500000
AS7350000

1(1),771G

l(l),1073C

1(3),734A

4(3),649

> 110
> 110

2(3), 1230

1.016
0.9819
0.924
1.090
0.8859
1.1125
1.099
1.064

1.4390
1.4282
1.4060
1.4610
1.4360
1.4800
1.4490
1.4610
1.3380

102
65
15
100
79

AS9800000
AT0700000
AT0350000
AT0855000

76

AS9275000

1.418
0.8846
0.8620
1.398
1.330
1.010
0.8882
1.039
1.011
1.160

1.3301
1.4311
1.4470
1.352
1.3190
1.4562
1.4280
1.4520
1.4502
1.5280

31
59
10
> 110
68
> 110
98
89

1.05
0.986
0.8896

1.4448
1.4760
1.4140

65
93
33

1(1),719D
1(1),727M
1(1),719G

1(1),973C
1(1),974C

1(1),638C
1(3),675B
1(3),675A

11,3715

2(3),1232
2(3), 1232
2,399
2(4), 1496
2(3),1229

1(1),1O88C
17(3), 1005

2(4), 1464

AT1430000
AT1450000

1(1),745C
1(1),729E

l(l),1029B

1(1),753L
1(1),753J

l(l),1044C
l(l),1044A

1(1),639B
l(3),720C
l(3),720B

2(3), 1228
2(4), 1470
2(4), 1496

AT1750000
1(1),719H
2(3),1227
AT2100000

6,251

TABLE 5.

cont'd

Name

Isodecyl ester
-(CH 2 )7CH(CH 3 ) 2
Isooctyl ester
-(CH 2 )5CH(CH 3 )2
Isopropoxyethyl ester
-CH 2 CH 2 OCH(CH 3 )S
Isopropyl ester
-CH(CH 3 ) 2
Methallyl ester
-CH 2 C(CH 3 )=CH 2
2-(2-Methoxyethoxy) ethyl ester - C H 2 C H 2 O C H 2 C H 2 O C H 3
2-Methoxyethyl ester
-CH 2 CH 2 OCH 3
Methyl ester
-CH3
2-Methylbutyl ester
-CH 2 CH(CH 3 )CH 2 CH 3
2-(A^Morpholino)ethyl ester
-CH 2 CH 2 NC 4 H 8 O
1-Naphthyl ester
-Ci0H7
2-Naphthyl ester
-Ci0H7
Neopentyl ester
-CH 2 C(CH 3 ) 3
Neopentyl glycol diester
-CH 2 C(CH 3 ) 2 CH 2 Nonyl ester
-(CH 2 ) 8 CH 3
Octadecyl ester
-(CH 2 ) I 7 CH 3
1H,1H,5H-Octafluoropentyl ester -CH 2 (CF 2 ) 3 CF 2 H
rc-Octyl ester
-(CH 2 ) 7 CH 3
1H,1H-Pentadecafluorooctyl ester-CH 2 (CF 2 ) 6 CF 3
Pentaerythritol tetraester
(-CH 2 ) 4 C
Penterythritol triester
(-CH 2 ) 3 CCH 2 OH
Pentaerythritol stearate diester
(-CH 2 ) 2 C(CH 2 OH)CH 2 OC(O)(CH 2 )I 6 CH 3
2,2,3,3,3-Pentafluoropropyl e s t e r -CH 2 CF 2 CF 3
1,5-Pentanediol diester
-(CH2)5w-Pentyl ester
-(CH 2 ) 4 CH 3
2-Phenoxyethyl ester
-CH 2 CH 2 OC 6 H 5
Phenyl ester
-C6H5
1,4-Phenylene diester
-C6H41,4-Phenylene di(acrylic acid)
C 6 H 4 (CH=CHC(O)OH) 2
2-Phenylethyl ester
-CH 2 CH 2 C 6 H 5
Trimethyl 2-phosphonoacrylate (CH 3 O) 2 P(O)C(C(O)OCH 3 )=CH 2
Propargyl ester
- C H 2 C = CH
w-Propyl ester
-CH 2 CH 2 CH 3
1,2-Propylene glycol diester
-CH 2 CH(CH 3 )1,3-Propylene glycol diester
-(CH2)3Tetradecyl ester
-(CH 2 )I 3 CH 3
Tetra(ethylene glycol) diester
-(CH 2 CH 2 O) 3 CH 2 CH 2 2,2,3,3-Tetrafluoropropyl ester
-CH 2 CF 2 CF 2 H
Tetrahydrofurfuryl ester
-C5H^
S,S'-Thiodi-l,4-phenylene dithiol - S C 6 H 4 S S C 6 H 4 S diester
2,3,3-TrichloroClCH 2 =CC1C(O)OH
Tridecyl ester
-(CH 2 ) I 2 CH 3
Tri(ethylene glycol) diester
-(CH 2 CH 2 O) 2 CH 2 CH 2 2,2,2-Trifluoroethyl ester
-CH2CF3
l,l,l-Tri(2-hydroxyethoxy(-CH 2 CH 2 OCH 2 ) 3 CCH 2 CH 3
methyl)propane triester
Tri(2-hydroxyethyl) isocyanurate (-CH 2 CH 2 ) 3 C 3 N 3 O 3
triester
3,5,5-Trimethylcyclohexyl ester -C 6 H 8 (CH 3 ) 3
3,5,5-Trimethylhexyl ester
-(CH 2 ) 2 CH(CH 3 )CH 2 C(CH 3 ) 3
Trimethylolpropane triester
(-CH 2 ) 3 CCH 2 CH 3
Trimethylolpropane ethoxylate
((-CH 2 CH 2 O) X CH 2 ) 3 CCH 2 CH 3
triester
Tri(propylene glycol) diester
(-CH2(CH3)CH2O)2CH2CH(CH3)Vinyl ester
-CH=CH 2

5.2.

CAS Registry
Number

MoI. wt.

Boiling
point ( 0 C)

25151-33-1
21643-42-5
17831-71-9
7383-71-3
2399-48-6
129283-82-5

212.34
184.25
159.21
114.14
126.16
174.20
130.14
86.09
142.20
185.2
198.22
198.22
142.24
212.25
198.31
324.55
286.12
184.28
454.13
352.34
298.30
510.72
204.10
212.25
142.20
192.21
148.16
218.21
218.21
176.22
194.13
110.11
114.14
184.19
184.19
268.44
302.33
186.11
156.18
386.56

2257-35-4
3076-04-8
1680-21-3
407-47-6
28961-43-5

175.40
254.41
258.30
154.09
428.48

40220-08-4

423.38

86178-38-3
2664-55-3
15625-89-5
28961-43-5

196.29
198.31
296.32
ca. 428

42978-66-5
2177-18-6

300
98.10

>120/l
91

79-41-4
21282-97-3
96-05-9
760-93-0
6498-81-3

86.09
214.22
126.16
154.17
155.20

163
274
60/43
200
190

1330-61-6
29590-42-9
689-12-3
818-67-7
7328-18-9
3121-61-7
96-33-3
19727-38-9
20069-66-3
52684-34-1
4513-36-4
2223-82-7
4813-57-4
376-84-1
2499-59-4
307-98-2
4986-89-4
3524-68-3
92092-01-8
356-86-5
36840-85-4
2998-23-4
48145-04-6
937-41-7
6729-79-9
16323-43-6
3530-36-7
55168-74-6
10477-47-1
925-60-0

121/10
125/20
82/19
51/103
70/50
86/4.6
56/12
80
63/27
67/0.2
212/1
138/0.4
31/3
105/5
76/0.2
160/3
88/41
57/0.05
65/5
>315

Melting
point (0C)
-100

-75

32

18
15
30

50/100
94/0.3
47/7
103/0.6
87/12
88
>300
104/5
91/0.1
138
43/40
63/0.3
122/0.5
138/0.4
>120/0.3
132
87/9

<-60
64
72

150/10
125/0.2
92
157
97
40/0.1
58/0.8
316
157

-34

<-20

METHACRYLATE, ACIDS/ESTERS (H 2 C=C(CH 3 )C(O)OR)

Acid
2-(Acetoacetoxy)ethyl ester
AUyI ester
Anhydride
2-(l-Aziridinyl)ethyl ester

-H
-CH 2 CH 2 C(O)OCH 2 C(O)CH 3
-CH 2 CH=CH 2
-C(O)C(CH 3 )=CH 2
-CH 2 CH(-NH-)CH 2

16

-20

Density
(at 200C)

Refractive
index (at 200C)

0.875
0.880
0.9549
0.8932
0.9285
1.0421
1.012
0.956
0.8883
1.0711

1.4420
1.4370
1.4258
1.4060
1.4372
1.4392
1.4272
1.4020
1.4800
1.4728

0.859
1.030
0.875
0.800

1.4530
1.4375

0.8810
1.63
1.190
1.180
1.018
1.32
0.8920
1.104

Flash
point (0C)

RTECS
Number

106
80

AT2190000
UD3391000

60
7

KL6000000
AT2800000

>37
123

AS8925000

R and S

1(1),719C

FT-NMR

1(1),973B

FT-IR

1(1),638B

Merck

11,5935

190
70

Beilstein

2(3),1232
3,638B

2(4), 1468

1.3467
1.4350
1.3279
1.4870
1.4840

170
> 110

UD3370000

1.3363
1.4551
1.4240
1.5180

> 110

KM0700000

6(3),572

1(2),1775F

1(2), 1050A

l(l),1109B

1(1),1489B

1(1),759E
1(1),745A

l(l),1053B

1(1),743M

l(l),1028C
1(1),999C

1.249

1.4540

105

0.9078

0.8700
1.110
1.317
1.063

1.4130
1.4470
1.4529
1.4468
1.4638
1.3629
1.4580

>110
45
>110

1.099
1.216
1.110

1.4609
1.3506
1.4710

63
12
>110

KM2890000

0.9292
0.875
1.100
1.110

1.455
1.4370
1.4736
1.4720

88
89
>110
86

UD3643625
AT4810000
KM2890000

1(1),729F

1.030
0.942

1.4500
1.4320

AT4690000

1(1),729A

1.015
1.122
0.934
1.035

1.432
1.4560
1.4360
1.454

76
106
34
83

OZ2975000

1(1),547B
1(1),791E
1(1),721E
1(1),831C

AS8100000

UD3483000
OZ5700000

1(1),639C

1(1),753I

9,914

1(2),179B

4(4),3638

1(1),639A
17(3),1104
17(3),1104

2(4), 1462

1(3),696C

2(3),1230
l(l),640A
1(1),999C
1(1),638D

1(1),776B
l(l),1107C
1(1),977A
l(l),1170C

1(1),499C
1(1),641B

11,5849

2,421
2(3), 1290
2(3),1293
6(3),1481

Fieser

17,183

TABLE 5.

cont'd

Benzyl ester
Bisphenol A diester
Bisphenol A tetraethoxylate
diester
2-Bromoethyl ester
1,3-Butylene diester
1,4-Butylene diester
2-Butoxyethyl ester
-Butyl ester
s-Butyl ester
tert-Butyl ester
7V-te/?-Butyl-2-aminoethyl ester
2-Chloro-2-hydroxypropyl ester
2-Chloroethyl ester
Chloromethyl ester
Cinnamyl ester
Chloride
2-Cyanoethyl ester
1,4-Cyclohexanediol diester
Cyclohexyl ester
Decanediol diester
Decyl ester
2,3-Dibromopropyl ester
2-(Dibutylamino)ethyl ester
Dicyclopentenyl ester
Dicyclopentenyloxyethyl ester
2-(Diethylamino) ethyl ester
3-(Dimethylamino) propyl ester
Di(ethylene glycol) diester
3,4-Dihydroxybutyl ester
2,3-Dihydroxypropyl ester
2-(Dimethylamino) ethyl ester
Diurethane diester (isomers)
IH, 1H,7H-Dodecafluoroheptyl
ester
Dodecanediol diester
Dodecyl ester
2,3-Epithiopropyl ester
2,3-Epoxybutyl ester
3,4-Epoxybutyl ester
2,3-Epoxyopropyl ester
4-Ethoxybutyl ester
2-Ethoxyethyl ester
Ethyl ester
Ethyl 2-bromomethyl- ester
2-Ethylbutyl ester
1,2-Ethylene diester
2-Ethylhexyl ester
2-(Ethylthio)ethyl ester
Ethyl 2-(trimethoxysilylmethyl-)
ester
Furfuryl ester
Glycerol diester
Glycerol triester
Glycidyl ester
1H,1H,2H,2H-Heptadecafluorodecyl ester
1H, 1 H-Heptafluorobutyl ester
Heptyl ester
1,6-Hexanediol diester
2,2,3,4,4,4-Hexafluorobutyl ester
lH-Hexafluoroisopropyl ester
Hexyl ester

Boiling
point ( 0 C)

CAS Registry
Number

MoI. wt.

-CH2C6H5
C 6 H 4 C(CH 3 ) 2 C 6 H 4
((-CH 2 CH 2 O) 2 C 6 H 4 )SC(CHs) 2

2495-37-6
3253-39-2
41637-38-1

176.22
364.44
452.55

-CH 2 CH 2 Br
-CH 2 CH 2 CH(CH 3 )-(CHz)4-CH 2 CH 2 O(CH 2 ) 3 CH 3
-(CH 2 ) 3 CH 3
-CH(CH 3 )CH 2 CH 3
-C(CH 3 ) 3
-CH 2 CH 2 NHC(CH 3 ) 3
-CH 2 C(OH)ClCH 3
-CH 2 CH 2 Cl
-CH 2 Cl
-CH 2 CH=CHC 6 H 5
CH 2 =C(CH 3 )C(O)Cl
-CH 2 CH 2 CN
-C6HiO-

4513-56-8
1189-08-8
2082-81-7
13532-94-0
97-88-1
2998-18-7
585-07-9
3775-90-4
13159-52-9
1888-94-4
27550-73-8
31736-34-2
920-46-7
4513-53-5
38479-34-4
101-43-9
6701-13-9
3179-47-3
3066-70-4
2397-75-3
31621-69-9
68586-19-6
105-16-8
17577-32-1
2358-84-1
62180-57-8
5919.74.4
2867-47-2
72869-86-4
2261-99-6

193.05
226.28
226.28
186.25
142.20
142.20
142.20
185.27
178.62
148.60
146.57
202.25
104.54
139.16
252.31
168.24
310.44
226.36
285.96
241.38
218.30
262.35
185.28
199.30
242.27
174.20
160.17
157.22
470.57
400.17

69/4
170/2
327
72/0.03
100/1
137/13
150/10
80/10
105/1.5
134/2
110/0.25
140/0.6
187
200
107/23

-CH2CH2-CH 2 CH(CH 2 CH 3 )(CH 2 ) 3 CH 3

-CH 2 CH 2 SCH 2 CH 3
CH 2 =C(CH 2 Si(OCH 3 ) 3 )C(O)OCH 2 CH 3

72829-09-5
142-90-5
3139-91-1
68212-07-7
55750-22-6
106-91-2
76392-24-0
2370-63-0
97-63-2
17435-72-2
5138-86-3
97-90-5
688-84-6
14216-25-2
74976-84-4

338.49
252.42
158.22
156.18
156.18
142.16
186.25
158.20
114.15
193.05
170.25
198.22
198.31
174.26
186.33

142/4
59/1.4
45/0.25
55/0.8
189
85/23
92/35
118
38/0.8
74/16
240
218
102/15
71/10

-CH2C4H3O
-CH 2 CH(OH)CH 2 -CH(CH2-),
-CH(-O-)CH2
-(CH 2 ) 2 (CF 2 ) 7 CF 3

3454-28-2
1830-78-0
52408-84-1
106-91-2
1996-88-9

166.18
228.25
296.3
142.16
532.20

81/5
120/1
150/0.1
189
120/4

-CH 2 (CF 2 ) 2 CF 3
-(CH 2 ) 6 CH 3
-(CH2)6-CH 2 CF 2 CHFCF 3
-CH(CF 3 ),
-(CH 2 ) 5 CH 3

13695-31-3
5459-37-0
6606-59-3
36405-47-7
3063-94-3
142-09-6

268.13
184.28
254.33
250.14
236.11
170.25

Name

-C 6 Hn
-(CH 2 )IO-(CH 2 ) 9 CH 3
-CH 2 CHBrCH 2 Br
-(CH 2 ) 2 N(CH 2 CH 2 CH 2 CH 3 ) 2
-C10H13
-C12HnO
-(CH 2 ) 2 N(CH 2 CH 3 ) 2
-(CH 2 ) 3 N(CH 3 ) 2
-CH2CH2OCH2CH2-CH2CH2CH(OH)CH2OH

-CH 2 CH(OH)CH 2 OH
-CH 2 CH 2 N(CH 3 ) 2
C23H38N2O8
-CH 2 (CF 2 ) 5 CF 2 H
-(CHz)12-(CH 2 )IiCH 3
-CH2CH(-S-)CH2
-CH 2 CH(-O-)CHCH 3
-CH 2 CH 2 CH(-O-)CH 2
-CH2CH(-O-)CH2
-(CH 2 ) 4 OCH 2 CH 3
-CH 2 CH 2 OCH 2 CH 3
-CH 2 CH 3
CH 2 =C(CH 2 Br)C(O)OCH 2 CH 3
-CH2CH(CH2CH3)CH2CH3

Melting
point (0C)

232
73
ca. 540
47/2.7
290
133/4
90/3
161
146
132
100/12
95/2
59/7.5
54/20
141/3
95
99/2
50

134
104/14
>315
158
99
88/14

-44

<-60

-30

0.95
-7

<-75
-40

<-18

Density
0

Refractive
index (at 20C)

Flash
point (0C)

RTECS
Number

R and S

FT-NMR

FT-IR

Merck

Beilstein

(at 20 C)
1.5120

107

1.5320

> 110

1.4520
1.4565
1.4335
1.4230
1.4195
1.4150
1.4420
1.4750

130
113
93
50

1.040

1(2),1931F

1(2),1296C

1(2),316B

1(1),729D

1(1),999A

1(1),639D

1(1),721A

1(1),975C

1(1),641A

1.120
1.010
1.023
0.939
0.894
0.875
0.914
1.190

OZ3675000

50
71
150

OZ3675500
OZ3500000

OZ5791000

2(4),1534
2(3),1292
2(3),1286
2(4),1582
4(4),1509
2(4),1533

1.4434
1.070

1.4420
1.4459

0.9626
0.875

1.459
1.4577
1.443

101

1.050
1.064
0.922

1.4474
1.4990
1.4970
1.4442

>110
> 110
85

1.082

1.4580

66

0.933
1.110

1.4400
1.485

70
>150

OZ4200000

1.46
0.868

1.4450

>110

OZ4300000

1(1),732C

82
82

2(3), 1293

6(3),25

6(3), 1942
4(3),676
2(3),1292

1(1),771H

l(l),1074A

1(1),675C
4(3),649

1(1),721D

1(1),976C

1(3),678B
2(3), 1290

0.964
0.917
1.398

1.4422
1.4472
1.4490
1.4223
1.4290
1.4130
1.4790

1.051
0.885

1.4540
1.4380

86
92

0.897

1.4380

59

1.078
1.120

1.4820
1.4720

90
> 115

1.042

1.4490

76

1.345

1.3410

37

0.995
1.348
1.302
0.885

1.4580
1.3610
1.3310
1.432

150
57
14
63

1.038
1.042

1(1),857B

76

OZ4375000

1(1),781F

l(l),1089A

1(1),668D

71
15
87

OZ4550000

1(1),759C
1(1),719J

l(l),1052C
1(1),975B

1(3),723C
l(l),640D

OZ4400000
OZ4630000

1(1),729B
1(1),721C

1(1),998B
1(1),976B

2(3),1291
2,423

2(3), 1292
2(3),1289
1(1),642D

1(2),2985A

1(3),686B

1(1),781F

l(l),1089A

17(3), 1248

OZ4375000

1(1),668D
1(1),745F
1(1),745E

l(l),1030B
l(l),1030A

Fieser

TABLE 5.

cont'd

Name

-(CH 2 ) 4 OH
4-Hydroxybutyl ester
2-Hydroxyethyl ester
-CH 2 CH 2 OH
3-(5-Hydroxypentyloxy)-CH 2 CH 2 C(O)O(CH 2 ) 5 OH
3-oxopropyl ester
3-Hydroxypropyl ester
-(CH 2 ) 3 OH
Isobornyl ester
-CioHg
Isobutyl ester
-CH 2 CH(CHs) 2
2-Isocyanatoethyl ester
-CH 2 CH 2 NCO
Isodecyl ester
-(CH 2 ) 7 CH(CH 3 ) 2
Isopropyl ester
-CH(CHs) 2
Methallyl ester
-CH 2 C(CH 3 )=CH 2
2-(2-Methoxyethoxy) ethyl ester -(CH 2 CH 2 O) 2 CH 3
2-Methoxyethyl ester
-CH 2 CH 2 OCH 3
Methyl ester
-CH3
2-Methyl-2-nitropropyl ester
-CH 2 C(CH 3 )(NO 2 )CH 3
2-(Methylthio) ethyl ester
-CH 2 CH 2 SCH 3
Methyl 2-bromomethyl ester
CH 2 =C(CH 2 Br)C(O)OCH 3
Methyl 2-(l-hydroxyethyl-)ester CH 2 =C(CH(OH)CH 3 )C(O)OCH 3
2-Af-Morpholinoethyl ester
-CH 2 CH 2 NC 4 H 8 O
Neopentylglycol diester
-CH2C(CH3)2CH2Nona(ethylene glycol) diester
-(CH 2 CH 2 O) 8 CH 2 CH 2 Nona(propylene glycol) diester - ( C H ( C H 3 ) C H 2 O ) 8 C H ( C H 3 ) C H 2 Nonyl ester
-(CH 2 ) 8 CH 3
4-Nonylphenyl ester
-C 6 H 4 (CH 2 ) 8 CH 3
Octadecyl ester
-(CH 2 ) 17 CH 3
-Octyl ester
-(CH 2 ) 7 CH 3
Pentabromophenyl ester
-C6Br5
Pentachlorophenyl ester
-C6Cl5
1H, 1 H-Pentafluorooctyl ester
-CH 2 (CF 2 ) 6 CF 3
Pentaerythritol tetraester
C(CH2-),
2,2,3,3,3-Pentafloropropyl ester -CH 2 CF 2 CF 3
Pentyl ester
-(CH 2 ) 4 CH 3
2-Phenoxyethyl ester
-CH 2 CH 2 OC 6 H 5
Phenyl ester
-C6H5
2-Phenylethyl ester
-CH 2 CH 2 C 6 H 5
rc-Propyl ester
-CH 2 CH 2 CH 3
1,2-Propylene diester
-CH 2 CH(CH 3 )1,3-Propylene diester
-(CH2),2-Sulfoethyl ester
-CH 2 CH 2 SO 3 H
3-Sulfopropyl ester, potassium
-(CH 2 ) 3 SO 3 K
salt
Tetra(ethylene glycol) diester
-CH 2 CH 2 (OCH 2 CH 2 ) 3 2,2,3,3-Tetrafluoropropyl ester
-CH 2 CF 2 CF 2 H
Trimethylsilyl ester
-Si(CH 3 ),
2-(Trimethylsilyloxy)ethyl ester
-CH 2 CH 2 OSi(CHs) 3
3-(Trimethylsilyloxy)propyl ester
-(CH 2 ) 3 OSi(CH 3 ) 3
3-(Tris(trimethylsiryloxy)silyl)
-(CH 2 ) 3 Si(OSi(CH 3 ) 3 ) 3
propyl ester
Vinyl ester
-CH=CH 2

TABLE 6.

MoI. wt.

997-46-6
868-77-9
85099-10-1

158.20
130.14
244.29

105/0.01
250

276-09-3
7534-94-3
97-86-9
30674-80-7
29964-84-9
4655-34-9
816-74-0
45103-58-0
6976-93-8
80-62-6
2177-42-6
14216-23-0
4224-69-5
18020-65-0
2997-88-8
1985-51-9
25852-47-5
25852-49-7
2696-43-7
76391-98-5
32360-05-7
2157-01-9
18967-31-2
16184-61-5
3934-23-4
3253-41-6
45115-53-5
2849-98-1
10595-06-9
2177-70-0
3683-12-3
2210-28-8
1188-09-6

90/9
245
155
211
126/10
125
157
67/1
66/16
100
102/4
38/0.06
36/1.3
91/20
80/0.08
112/1.2

10595-80-9
31098-21-2

144.17
222.33
142.20
155.17
226.36
128.17
140.18
188.22
144.17
100.12
187.20
160.24
179.02
130.14
199.25
240.30
550
560
212.33
288.43
338.58
198.31
556.69
334.41
468.16
408.45
218.12
156.23
206.24
162.19
190.24
128.17
212.25
212.25
194.21
246.33

109-17-1
45102-52-1
13688-56-7
17407-09-9
2530-85-0
17096-07-0

300.37
200.14
158.28
202.33
248.35
422.82

220
124
51/20
65/0.9
190
113/0.2

4245-37-8

112.13

111

Melting
point ( 0 C)

-12
-48

-51
-45
-41

-48

>200/l
125/0.03
195/6
105/4

19
132
87

67/5
55/110
73/17
183
115/10
119/11
140
68/1
68/1
(d)

66

295(d)

ALCOHOLS
Formula HOROH
R

Name
6.1.

Boiling
point ( 0 C)

CAS Registry
Number

CAS
Registry
Number

MoI. wt.

Boiling
point ( 0 C)

Melting
point (0C)

ALKANEDIOLS

1,2-Butane
1,3-Butane
1,4-Butane
1,10-Decane
1,12-Dodecane
1,2-Ethylene

-CH(C2H5)CH2-CH(CH 3 )CH 2 CH 2 -(CH2),-(CHa)10-(CH2)I2-(CH2)2-

584-03-2
107-88-0
110-63-4
112-47-0
5675-51-4
107-21-1

90.12
90.12
90.12
174.28
202.34
62.07

191/747
203
230
170/8
189/12
197

16
73
82
-13

Density
(at 200C)

Refractive
index (at 200C)

Flash
point (0C)

1.073
1.080

1.4520
1.4360

97
>110

1.066
0.9830
0.886
1.096
0.878
0.8847

1.4470
1.4770
1.420

96
107
41
97
>110

1.020
0.993
0.936
1.087
1.040
1.489
1.071

1.4397
1.4310
1.4140
1.450
1.4800
1.4900
1.4520

> 110
65
10
> 110
88
78
43

1.003
1.099
1.010
1.099

1.4530
1.4660
1.4520
1.4660
1.5020
1.4510
1.4373

117
>110
>110
> 110
> 110
196

0.864

1.4430
1.4122

1.5732

1.3482

1.0687

1.5130
1.5184
1.508
1.4450
1.4450

0.98
0.9022

1.3245

1(1),753M

l(l),1045A

OZ4900000

1(1),721B

1(1),976A

FT-IR

Merck

Beilstein

Fieser

1(1),665B

2(3),1287
1(3),677C

OZ5000000

OZ5075000

1(1),719I

11,5849

1(1),975A
1(1),64OC

AS4900000

1(1),745J

2(2),398
2(3),1288

l(l),1031C

2(4),1535

2(3),1290

122

1.4772

82
50
32
76
92
> 110

0.933

1.4360

13

1.113

OZ4725000

FT-NMR

100

1.4630
1.3730
1.4147
1.4280
1.4310
1.4190

1.006
1.005
1.017

Rand S

96
>100
6

1.080
1.250
0.890
0.928
1.045
0.918

Density
(at 2O0C)

RTECS
Number

Refractive
index (at 200C)

1.4380
1.4400
1.4450

1.4310

Flash
point (0C)

93
121
>110

>110

l(l),1065F

1(1),1438B

1(1),745B
1(2),2985B
1(2),2985C
1(2),2985D

l(l),1029A
1(3),686C
1(3),687A
1(3),687B

l(l),890D
2(4),1531

OZ4000000

UC0230000

1(2),1116C

2(3),1290

RTECS
Number

EK0380000
EK0440000
EK0525000
HD8433713
KW2975000

R and S

1(1),141A
1(1),139L
1(1),139K
1(1),143N
1(1),145A
1(1),139A

FT-NMR

1(1),196C
1(1),195C
1(1),195B
l(l),205C
l(l),206B

FT-IR

1(1), 130B
1(1), 130D
l(l),130A
1(1),136D
1(1),137A
1(1),127D

Merck

11,1566
11,2842
11,3755

Beilstein

1,477
1,477
1,478
l(2),560
1(2),562
1,465

Fieser

15,156

TABLE 6.

cont'd
Formula HOROH
R

Name
1,7-Heptane
1,16-Hexadiene
1,6-Hexane
1,7-Heptane
1,16-Hexadiene
1,9-Nonane
1,8-Octane
1,5-Pentane
1,2-Propane
1,3-Propane
1,14-Tetradecane
6.2.

ETHERDIOLS

Di(ethylene glycol)
Di(propylene glycol)
Hexa(ethylene glycol)
Penta(ethylene glycol)
Tetra(ethylene glycol)
Tri(ethylene glycol)
Tri(propylene glycol)

TABLE 7.

CAS
Registry
Number

MoL wt.

Boiling
point ( 0 C)

Melting
point (0C)

-(CHa)7-(CH2)I6-(CH2)6-(CHa)7-(CH 2 ) 1 6 -(CH2)9-(CH2)S-(CH2)S-CH(CH 3 )CH 2 -(CH2)S-(CH 2 ) 1 4 -CH2CH 2 OCH2CH2-

629-30-1
23079-20-1
629-11-8
629-30-1
23079-20-1
3937-56-2
629-41-4
111-29-5
57-55-6
504-63-2
19812-64-7

132.20
258.45
118.18
132.20
258.45
160.26
146.23
104.15
76.10
76.10
230.39

259
198/3
250
259
198/3
177/15
172/20
242
187
214

-CH(CH3)CH2OCH(CH3)CH2-

111-46-6
110-98-5
2615-15-8
4792-15-8
112-60-7
112-27-6
24800-44-0

106.12
134.18
282.34
238.28
194.23
150.17
192.26

245

-10

217/4
184/2
314
285
273

MoL wt.

Boiling
point ( 0 C)

-CH 2 CH 2 (OCH 2 CH 2 )S-CH 2 CH 2 (OCH 2 CH 2 ) 4 -CH 2 CH 2 (OCH 2 CH 2 ) 3 -CH 2 CH 2 (OCH 2 CH 2 ) 2 -CH(CH 3 )CH 2 (OCH(CH 3 )CH 2 ) 2 -

18
92
42
18
92
48
60
-60
-27
88

-6
-7

ALLYL FUNCTIONAL
Formula CH 2 =CHCH 2 R

Name
Acetate
-Acetic acid
Acetoacetate
Alcohol
- , 2-Bromo- , 2-Chloro- , 3-Methyl(crotyl alcohol;)
-Amine
-AT-Aniline
-4-Anisole
-Benzene
Benzyl ether
Bromide
Butyl ether
Butyrate
Chloride
Chloroacetate
Chloroformate
Cyanide
Cyanoacetate
Diallyl amine
2,3-Dibromide
2,3-Dichloride
Ether
Ethyl ether
Fluoride
Formate
Glycidyl ether
Iodide
Isocyanate
Isopropyl ether
4-(2-Methoxyphenol)
Methyl ether
-2-Phenol

R
-OC(O)CH 3
-CH 2 C(O)OH
-OC(O)CH 2 C(O)CH 3
-OH
H 2 C=CBrCH 2 OH
H 2 C=CClCH 2 OH
CH 3 CH=CHCH 2 OH
-NH2
-NC6H5
-C 6 H 4 OCH 3
-C6H5
-OCH 2 C 6 H 5
-Br
-O(CH 2 ) 3 CH 3
-OC(O)CH 2 CH 2 CH 3
-Cl
-OC(O)CH 2 Cl
-OC(O)Cl
-CN
-OC(O)CH 2 CN
-NHH 2 =CBrCH 2 Br
H 2 C=CClCH 2 Cl
-O-OCH 2 CH 3
-F
-OC(O)H
-O-CH2CH(-O-)CH2
-I
-NCO
-OCH(CH 3 ) 2
-C 6 H 4 (OCH 3 )OH
-OCH3
-C6H4OH

CAS
Registry
Number
591-87-7
591-80-0
1118-84-9
107-18-6
5976-47-6
6117-91-5
107-11-9
589-09-3
140-67-0
300-57-2
14593-43-2
106-95-6
3739-64-8
2051-78-7
107-05-1
2916-14-5
2937-50-0
109-75-1
13361-32-5
124-02-7
513-31-5
557-40-4
557-31-3
818-92-8
106-92-3
556-569
1476-23-9
97-53-0
627-40-7
1745-81-9

100.12
100.12
142.16
58.08
136.98
92.53
72.12
57.10
133.19
148.21
118.18
148.21
120.98
114.19
128.17
76.09
134.56
120.54
67.09
125.13
97.16
199.88
110.97
98.15
86.13
60.07
86.09
114.14
167.98
83.09
100.16
164.20
72.11
134.18

104
84/12
194/737
97
152
134
122
53
219
215
156
204
70
44/15
45
164/265
109
118
110/20
112
141
94
95
66
-10
84
154
103
88
84
154
46
220

Melting
point (0C)

-22
-129

-88

-119

-134

-88

-11

Density
(at 20 0 C)

Refractive
index (at 20C)

Flash
point (0C)

RTECS
Number

0.951

1.4550

>110

MI9804000

0.951

1.4550

102
> 110

MO2100000
MI9804000

1.4500
1.4320
1.4400

129
107
79

1.118
1.023
1.127
1.126
1.125
1.125
1.021

1.4460
1.4410
1.4640
1.4620
1.4590
1.4550
1.4440

143
138
>110
>110
177
166
>110

Density
(at 20 0 C)

Refractive
index (at 200 C)

0.928
0.981
1.037
0.854
1.6
1.162
0.845
0.761
0.982
0.965
0.892
0.959
1.398
0.783
0.902
0.939
1.159
1.136
0.834
1.065
0.787
1.934
1.211
0.803
0.760

1.4040
1.4283
1.4390
1.4120
1.5
1.4590
1.4270
1.4205
1.5630
1.5210
1.5100
1.5070
1.4690
1.4060
1.4140
1.4135
1.4460
1.4220
1.4050
1.4430
1.4405
1.5470
1.4603
1.4160
1.3880

0.9460
0.962
1.837
0.940
0.7764
1.066
0.978
1.028

1.4330
1.5540
1.4170
1.3946
1.5410
1.5200
1.5450

Flash
point (0C)

FT-NMR
l(l),204B

1(1),143J
1(1),145E
1(1),143D
1(1),143J
1(1),145E
1(1),143M
1(1),143K
1(1),141I
1(1),139C
1(1),139B
1(1),145C

l(l),205B
l(l),204C
1(1),199A
1(1),192C
1(1),192B
l(l),207A

ID5950000
UB8785000
MM3670000
RZ2670000
XC2100000
YE4550000
YK6825000

1(1),225D
1(1),225E
1(1),229B
1(1),227K
1(1),227H
1(1),227D
1(1),227F

1(1),341B
1(1),341C
1(1),347A
1(1),346B
1(1),346A
1(1),345A
1(1),345B

RTECS
Number

Rand S

>110
0.994
1.036
1.053

R and S

SA0480000
TY2000000
TY2010000

7
89
75
22

AFl760000
SB2800000

54
37
-29
89
81
33
76
-2
14
41
-29
61
31
23
>110
16
81

UD4725000
EM9275000
BA5425000

l(l),202B
l(l),204B

FT-NMR

FT-IR
1(1),135C
1(1),137D
1(1),134B
1(1),135C
1(1),137D
1(1),136B
1(1),135D
1(1),132B
1(1),128B
1(1),128A

1(1),223B
1(1),226A
1(1),227A
1(1),226D
1(1),226C
1(1),226B

Merck

Beilstein
1,489

11,4610

11,7073
11,7868
11,9629
1(2),564

11,3109

1,484
1,489
1,489
1,493
1,490
1,481
1,472
1,475

1,468
1(2),537
1,468
1,468
1,468
1,468

11,9585

FT-IR

Merck

Beilstein

1(1),715C
1(1),547H
1(1),787A
1(1),147A

1(1),963C
1(1),778A
1(1),687C
l(l),207B

1(1),633B
1(1),499B
l(l),1098A
1(1),138B

1(1),183D
1(1),147C
1(1),347A
1(1),1383K
1(1),1243C
1(1),1139E

l(l),208A
1(1),518C
1(2),454B
l(2),208B
1(2),24B

1(1),138C
1(1),322B
1(1),1191A
l(l),1053B
1(1),946B

1(1),135A
1(1),333B
l(l),970B
1(1),133C

1(1),93D

ES5775000
UC7350000

1(1),95I
1(1),219G
1(1),717N
1(1),95E

LQ5775000
EM8050000
AG3690000
UC6650000
UC8200000

1(1),863B
1(1),991F
l(l),1013F
1(1),347K
l(l),101K

l(l),1206B
1(1),1358C
1(1),1391B
l(l),520A

1(1),737A
1(1),843A
1(1),322C
1(1),99C

11,2951
11,3009

4,208
1,201

-7
-21

KN7525000

1(1),219H
1(1),219E

1(1),333C
1(1),332C

1(1),212D
1(1),212C

11,290
11,291

1,438
1,438

57
18
43

RR0875000
VD0450000
NQ8175000

1(1),251C
1(1),95J
l(l),1023E

1(1),374A

11,292

1,202

l(l),1404A

1(1),233D
1(1),94A
1(1),872A

SJ4375000

1(1),1283E

1(2),278A

l(l),1091A

11,3855

SJ3850000

1(1),1265H

1(2),245B

l(l),1070D

>110
63
88

BA5075000

BZ8225000
CY2275000
UC7090000

Fieser

1(1),637B
1(1),93C

1(1),687C
11,284

11,2604
11,285
11,3657

11,286

11,287

11,288

Fieser

2,136
2,425
19(3), 1203
1,436
1,439
1,442
4,205
12,170
6,751
5,484
6(3),1459
1,201
1(3),1882
2,272
1,198
2,198
3,12
2,408

4,214
6,961
6,572

13,2

TABLE 7.

cont'd
Formula CH 2 =CHCH 2 R

Name

Phenyl ether
4-Chloro2,4,6-TribromoPhenyl sulfone
Propyl
-Succinic anhydride
Sulfide
2-Tolyl ether
3-Tolyl ether
4-Tolyl ether
-Urea

TABLE 8.

-OC6H5
-OC 6 H 4 Cl
-OC 6 H 2 Br 3
-S(O)(O)C 6 H 5
-CH 2 CH 2 CH 3
-C4H3O3
-S-OC 6 H 4 CH 3
-OC 6 H 4 CH 3
-OC 6 H 4 CH 3
-NHC(O)NH 2

Name

Butane DecaneDodecaneEthyleneHeptaneHexaneNonaneOctanePentane1,2-Phenylene1,3-Phenylene1,4-PhenylenePropane-

3278-89-5
16212-05-8
1471-03-0
7539-12-0
592-88-1

557-11-9

134.18
168.63
370.88
182.24
100.16
140.1
114.21
148.21
148.21
148.21
100.12

Boiling
point (0C)

Melting
point (0C)

192
107/12
75
111/0.5
91
260
138
81/2
213
91/10

85

CAS
Registry
Number

MoL wt.

110-60-1
646-25-3
2783-17-7
107-15-3
646-19-5
124-09-4
646-24-2
373-44-4
462-94-2
95-54-5
108-45-2
106-50-3
109-76-2

88.15
172.32
200.37
60.10
130.24
116.21
158.29
144.26
102.18
108.14
108.14
108.14
74.13

CAS Registry
Number

MoL wt.

C6H6O5
C6H6O4S
C6H4O5

79814-40-7
6953-60-2
6318-55-4

158.11
174.18
156.10

C7H8O3
C 1 2 H 7 NO 3
C9H4O5

7539-12-0
6492-86-0
552-30-7

140.1
213.20
192.13

C10H10O3

24327-08-0

178.19

C 4 HBrO 3
C 1 2 H 5 BrO 3
C 11 H 20 O 4 Si

5926-51-2
21563-29-1
91424-40-7

176.96
277.08
244.37

C12H12O3
C 1 2 H 1 1 NO 5
C10H12O4
C 8 H 4 ClNO 3
C 1 2 H 5 ClO 3
C5H4O3
C8H10O3

32703-79-0
4515-23-5
56-25-7
4743-17-3
4053-08-1
616-02-4
13149-00-3

204.23
249.23
196.20
197.58
232.63
112.08
154.17

-(CHz)4-(CHz)10-(CHz)12-(CHz)2-(CHz)7-(CHz)6-(CHz)9-(CHz)8-(CH2)S-C6H4-C6H4-C6H4-(CHz)3-

Boiling
Point(C)
159
140/12
118
224
204
258/756
225
179
257
283
267
140

Melting
Point(C)
27
62
70
8.5
28
43
37
51
104
65
144
-12

ANHYDRIDES

Name
9.1.

1746-13-0

MoL wt.

AMINES, DIFUNCTIONAL
Formula H 2 NRNH 2

TABLE 9.

CAS
Registry
Number

Formula

Boiling
point ( 0 C)

Melting
point ( 0 C)

MONOANHYDRIDES

Acetoxysuccinic
5-Acetylmercaptosuccinic
Aconitic, cisAcrylic (see Acrylates)
Allylsuccinic
4-Amino-1,8-naphthalic
1,2,4-Benzenetricarboxylic
(trimellitic)
Bicyclo[2.2.2.]oct-5-ene2,3-dicarboxylic, endoBromomaleic
4-Bromo, 1,8-naphthalic
3-(tert-Butyldimethylsilyloxy)glutaric
4-tert-Butylphthalic
N-Carboxybenzyloxy-L-aspartic
Cantharidin
5-Chloroisotoic
4-Chloro-1,8-naphthalic
Citraconic
Cyclohexane-1,2-dicarboxylic,
cis-

56
83
75
260

6
167
145

215
218
80

213
158/17

73
123
216
300(d)
208
7
33

Density
(at 20 0 C)

Refractive
index (at 20 0 C)

Flash
point (0C)

RTECS
Number

R and S

FT-NMR

0.978

1.5200
1.5348

63

DA8575000

1(1),1241M

l(2),207A

1.189
0.767

1.5480
1.3990

>110
_5

WR2400000

1(2),2185B
1(1),219F

1(2), 1580A
1(1),333A

0.887
0.950
0.9564
0.970

1.4889
1.5179
1.5179
1.5168

46

BC4900000

Refractive
Index*At 200 C)

0.877

1.4569

0.899

1.4565

0.873

1.4582

Flash
Point(C)
52
155
34
88
81
>110
165
63
>110

0.888

Density
(at 200C)

1.4565

Refractive
index (at 20 0 C)

34

Flash
point (0C)

RTECS
Number
EJ6800000
HD7175000
JR2200000
KH8575000

1(1),287J

1(1),432C

1(1),939M

l(l),1308B

Rand S

RG8841500
SA0200000
SS7875000
SS7700000
SS8050000
TX6825000

RTECS
Number

R and S

FT-NMR
1(1),465A
1(1),469B
1(1),469C
1(1),463B
1(1),468A
1(1),467A
1(1),469A
1(1),468B
1(2),536B
1(2),539A
1(2),542C
1(1),464A

FT-NMR

Merck

Beilstein

6,144

11,14

11,295
1,440
11,296
4,209

FT-IR
1(1),291D
1(1),293D
1(1),294A
1(1),289C
1(1),293A
1(1),292C
1(1),293C
1(1),293B
1(1,292B
1(1),1235C
1(1),1239A
1(1),1242B
l(l),290A

FT-IR

Merck
11,7964

11,3752
11,4614

11,1608
11,7255
11,7254
11,7256

Merck

Beilstein
4,264
4,273
4,273
4,230
4,271
4,269
4,272
4,271
4,266
13,6
3,33
13,61
4,261

Beilstein

18(2), 1128
1(1),837E
1(1),837D

1(1),1179B

1QV715C
18,463

1.163
DC2050000

1(2),336A

1(2),1961B
1(2),1959G

1(2),1329C

1(1),835N

1(1),1178B

1(1),839A
1(2),1961A
1(2),2987F

1(1),1182B
1(2), 133OB
1(3),692A

11,9617

18(2),469
18,468

1,(2),334A
1(1),717D
1.905

>110

1(1),719C

RN8575000

1.247

1.4710

101
>110

QL6127295
GE6825000

1(2),1957H
1(2),1959N
1(1),837J
1(1),835G

1(1),1181A
1(1),1175C

Fieser

6,205
6,299
1,438

l(3),2780

l(l),800D

l(l),309G
1(1)3111
1(1),31U
l(l),309A
1(1),3HE
1(1),311B
1(1),3HH
1(1),3HF
l(l,309K
1(1),1429A
1(1),1431C
1(1),1433D
l(l),309D

MOl 180000

l(l),1052B

1(1),269C

YR7875000

Density
(at 20 0 C)

FT-IR

1(2),332C
1(2),335D
1(1),718D
1(1),715D

17,435
17,523

19,161
27,265
17,522
17,440

Fieser

4,231

8,393

Fieser

TABLE 9.

cont'd

Name
Cyclohexane-1,2-dicarboxylic,
transDiacetyl-L-tartaric
3,5-Diacetyltetrahydropyran2,4,6-trione
Dichloromaleic
3,6-Dichlorophthalic
4,5-Dichlorophthalic
3,6-Difluorophthalic
Diglycolic
2,2-Dimethylglutaric
3,3-Dimethylglutaric
2,3-Dimethylmaleic
2,2-Dimethylsuccinic
Diphenic
2,3-Diphenylmaleic
2-Dodecen-1 -ylsuccinic
3,6-Epoxy-l,2,3,6-tetrahydrophthalic, exo3-Ethyl-3-methylglutaric
3-Fluorophthalic
4-Fluorophthalic
2-Foraiamidosuccinic
Glutaric
l,4,5,6,7,7-Hexachloro-5norbornene2,3-dicarboxylic
Hexafluoroglutaric
Hexahydro-4-methylphthalic
Homophthalic
3 -Hy droxy phthalic
Isatoic
Isobutenylsuccinic
Itaconic
Maleic
3-Methylglutaric
Af-Methylisatoic
Methyl-5-norbornene2,3-dicarboxylic
4-Methylphthalic
Methylsuccinic
1,8-Naphthalic
3-Nitro-1,8-naphthalic
4-Nitro-1,8-naphthalic
3-Nitrophthalic
4-Nitrophthalic
5 -Norbornene- endo2,3-dicarboxylic,

Boiling
point ( 0 C)

Melting
point ( 0 C)

CAS Registry
Number

MoI. wt.

C8H10O3

14166-21-3

154.17

146

C8H8O7
C9H8O6

6283-74-5
33524-89-9

216.15
212.16

131
154

C 4 Cl 2 O 3
C 8 H 2 Cl 2 O 3
C 8 H 2 Cl 2 O 3
C8H2F2O3
C4H4O4
C7H10O3
C6H6O3
C6H8O3
Ci 4 H 8 O 3
C 1 6 Hi 0 O 3
C16H26O3
C8H6O4

1122-17-4
4466-59-5
942-06-3
652-40-4
4480-83-5
2938-48-9
4160-82-1
766-39-2
17347-61-4
6050-13-1
4808-48-4
19780-11-1
6118-51-0

166.95
217.01
217.01
184.10
116.07
142.16
142.16
126.11
128.13
224.22
250.26
266.38
166.13

188
186
219
92
36
124
94
30
225
160
42
118(d)

C8H12O3
C 8 H 3 FO 3
C 8 H 3 FO 3
C 5 H 5 NO 4
C5H6C3
C 9 H 2 Cl 6 O 3

6970-57-6
652-39-1
319-03-9
33605-73-1
108-55-4
115-27-5

156.18
166.11
116.11
143.10
114.10
370.83

185/20

C5F6O3
C9H12O3
C9H6O3
C8H4O4
C 8 H 5 NO 3
C8H10O3
C5H4O3
C4H2O3
C6H8O3
C 9 H 7 NO 3
C10H10O3

376-68-1
19438-60-9
703-59-3
37418-88-5
118-48-9
18908-20-8
2170-03-8
108-31-6
4166-53-4
10328-92-4
25134-21-8

222.04
168.19
162.14
164.12
163.13
157.17
112.09
98.06
128.13
117.16
178.19

72

C9H6O3
C5H6O3
Ci 2 H 6 O 3
Ci 2 H 5 NO 5
C 1 2 H 5 NO 5
C 8 H 3 NO 5
C 8 H 3 NO 5
C9H8O3

19438-61-0
4100-80-5
81-84-5
3027-38-1
34087-02-0
641-70-3
5466-84-2
129-64-6

162.14
114.10
198.18
243.17
343.17
193.11
193.11
164.16

295
239

C22H38O3
C12H18O3
C5H4O3

26680-54-6
5617-74-3

350.55
210.27
112.08

251/4
168/10
100/5

C 3 H 3 NO 3
C11H10O3
C10H6O3
C18H10O3

2185-00-4
2959-96-8
36122-35-7
1985-37-1

101.06
190.20
176.16
247.28

C10H8O3
C8H4O3
C 1 3 H 9 NO 5
C7H10O4
C6H2N2O3

1131-15-3
85-44-9
3343-28-0
130221-78-2
4744-5O-7

176.17
148.12
259.22
158.16
150.09

Formula

CVHK)O3

240
175/60
181/25
223
219

180/5

159
79
145
56
237

146/14
114/12
202
181/25

141
200
233(d)
64
71
52
45

91
34
268
248(d)
228
164
118
166

CJS-

Octadecylsuccinic
2-Octen-1 -ylsuccinic
3-Oxabicyclo[3.1.0] hexane2,4-dione
2,5-Oxazolidenedione
2-Phenylglutaric
Phenylmaleic
1 -Phenyl-2,3-naphthalenedicarboxylic
Phenylsuccinic
Phthalic
N-Phthaloylglutamic
1 -Propenyloxymethylmaleic
Pyrazinedicarboxylic

218/13

191/12
284

62
10
60
120(d)
97
121
259
54
132
199

251
210(d)

Density
(at 20 0 C)

Refractive
index (at 2O0C)

Flash
point (0C)

RTECS
Number

ON4025000
1.135

108

177

Rand S

1.654
1.162

1.3240
1.4770

MA3850000
RB9080000

None
>110
TI3300000
DM3100000

103
>110

ON3675000
DM3140000

1.232

1.5060

1.220

>110

>110

RB9100000

QK5350000
QK5370000

TI3328000
DT5600000

1.055
1.000

FT-IR

Merck

1(1),1176A

1(1),716A

17,452

1(1),837F
1(1),839L

1(1),1179C
1(1),1174A

1(1),457D

18,162
17(4),6841

1(1),839B
1(2),1959B
1(2),1959C
1(2),1959A
1(1),841C
1(1),839G
1(1),839H
1(1),837K
1(1),835C
1(2),1959L
1(2),1957C
1(1),835K
1(1),837B

1(1),1183C
1(1),1184A
1(1),1181B
1(1),1175A

1(1),722A
l(l),720D
1(1),721A
1(1),719A
1(2),335B

1(1),1177A
1(1),1179A

1(1),717A

1(1),1184B

1(1),721B

19(2),181

1(1),839E
1(1),839C

1(1),1183A
1(1),1182C

l(l),720B
l(l),720A

1(1),839K
1(1),835I
1(2),1957E
1(2),1959F
1(2),1957F
1(1),835E
1(1),835J
1(1),837I
1(1),839F
1(2),1957G
l(l),835O

1(1),1184C
1(1),1176B

1(1),716B

1(2),1957M
1(1),835B
1(2),1959M
1(2),1961C
1(2),1961D
1(2),1959H
1(2),1959I
1(1),835M

1(2),1329B

17(1),231
17(5),11,259
18(11),5,548
17,411
11,2084

17(4),5814
1(2),331D
1(2),332A

1(1),1175B
1(1),1176C
l(l),1180C
1(1),1183B
1(1),1178C
1(2),1327B
1(1),1174C

1(1),716D
1(1),718C
l(l),720C
1(2),332B
1(1),718C

11,5586

1(1),715B
1(2),335C

1(2), 1330C
l(2),1330A
1(1),1177C

Fieser

17,434
5,195
17,483
17,483
17(5), 11,259
19,153
17,418
17,419
17,445
17,417
17,526
17,532

1(1),719D
1(2),1328B
1(2),1328C
1(2),1328A

1(2),334B
1(2),334C
1(1),717C

11,1801

17,489
18,94
27,264
17(4),5927
17,442
17,432
17,415
27,265
17(2),461

11,254

5,422

17,492
17,414
17,521
17,523
17,524
17,486
17,486
17(2),461
1,713

1.4694

>110
17,442

1(1),835F
l(l),907M
1(2),1957D

TI3150000
MA3900000
1.100

Beilstein

1(1),835H

1(1),839I

>110

FT-NMR

1.4610

1(2), 1957 J
l(2),2017M

27,245
17,494
17,510

1(2),331C

1(2),1327A
1(2)1391A

1(2),332D

11,7346

17,492
17,469
21(3),5370

>110
27,681

1,882

TABLE 9.

cont'd

Name

2,3-Pyridenedicarboxylic
3,4-Pyridinedicarboxylic
Succinic
4-Sulfo-1,8-naphthalic
Tetrabromophthalic
Tetrachlorophthalic
Tetrafluorophthalic
1,2,3,6-Tetrahydrophthalic, cis3,4,5,6-Tetrahydrophthalic
3,3-Tetramethy leneglutaric
Tetrapropenylsuccinic (isomers)
Trimellitic
2-(Triphenylphosphoranylidene)succinic
9.2.

TABLE 10.

699-98-9
4664-08-8
108-30-5
71501-16-1
632-79-1
117-08-8
652-12-0
935-79-5
2426-02-0
5662-95-3
26544-38-7
1204-28-0
906-65-0

149.11
149.11
100.07
316.34
463.72
285.90
220.08
152.15
152.15
168.19
266.38
210.57
360.35

C10H2O6
C17H6O7

89-32-7
2421-28-5

218.12

C12H8O6

1719-83-1

C16H6O6

2420-87-3

C8H4O6
C9H6O6

4415-87-6
6053-68-5

196.11
210.14

>300
225(d)

23911-26-4
23911-25-3
1107-00-2

357.32
256.22
444.25

183
190(d)
244

C14H4O6

81-30-1

268.18

>300

C24H8O6
C8H4O7

128-69-8
25774-69-0

392.32
212.11

>300
223

CAS Registry
Number

MoI. wt.

C 7 H 3 NO 3
C 7 H 3 NO 3
C4H4O3
C12H6O6S
C 8 Br 4 O 3
C 8 Cl 4 O 3
C8F4O3
C8H8O3
C8H8O3
C9H12O3
C16H26O3
C 9 H 3 ClO 4
C22H17O3P

126

371

186/15
150/3

138
76
119
275
256
95
98
72
65
67
167(d)

C14H19N3O8
C10H12N2O6
C19H6F6O6

397

283
220

322.23
>300
248.19
300
294.22

BUTADIENES

Name

Formula

Boiling
point ( 0 C)

Melting
point (0C)

1,2-BUTADIENES

1,2-Butadiene
- , 4-Bromo- , 4-Chloro- , 4-Hydroxy- , 4-Iodo- , 3-Methyl10.2.

Melting
point ( 0 C)

MoI. wt.

DIANHYDRIDES

Benzene-1,2,4,5-tetracarboxylic
Benzophenone3 3 ',4,4'-tetracarboxylic
Bicyclo[2.2.2.]oct-7-ene2,3,5,6-tetracarboxylic
Biphenylene-3,3',4,4'tetracarboxylic
Cyclobutanetetracarboxylic
Cyclopentane-1,2,3,4tetracarboxylic, cis,cisDiethylenetriaminepentaacetic
Ethylenediaminetetraacetic
4,4'-(HeXaSuOrOiSOPrOPyUdBnC)
diphthalic
Naphthalene-1,4,5,8-tetracarboxylic
Pery lene-3,4,9,10-tetracarboxylic
Tetrahydrofuran-2,3,4,5-tetracarboxylic

10.1.

Boiling
point ( 0 C)

CAS Registry
Number

Formula

H 2 C=C=CHCH 3
H 2 C=C=CHCH 2 Br
H 2 C=C=CHCH 2 Cl
H 2 C=C=CHCH 2 OH
H 2 C=C=CHCH 2 I
H 2 C=C=C(CH 3 ),

590-19-2

H 2 C=CHCH=CH 2
H 2 C=CBrCH=CH 2
HCCl=CHCH=CH 2
HCCl=C(CH 3 )CH=CH 2
HCC1=CHC(CH 3 )=CH 2
H 2 C=CClCH=CH 2
H 2 C=CC1C(CH 3 )=CH 2

106-99-0

598-25-4

54.09
133.00
88.54
70.09
179.99
68.12

11
110
88
127
130
41

54.09
133.00
88.54
102.57
102.57
88.54
102.57
122.98
122.98

-4
42/165
68
107
100
59
93
63/105
98

-136

-148

1,3-BUTADIENES

1,3-Butadiene
- , 2-Bromo- , 1-Chloro- , l-Chloro-2-methyl- , l-Chloro-3-Methyl- , 2-Chloro- , 2-Chloro-3-methyl- , 1,2-Dichloro- , 2,3-Dichloro-

HCCI=CCICH=CH2

H 2 C=CClCCl = CH 2

126-99-8

-109

Density
(at 2O0C)

Refractive
index (at 200 C)

Flash
point (0C)

RTECS
Number

WN0875000
TI3350000
TI3450000
GW5775000
1.005

1.4790

>110

WN1300000

DB9300000
162

QK3695000

Density
(at 2O0C)

Refractive
index (at 20 0 C)

0.652
1.4255
0.9891
0.9164
1.7129
0.694

1.4205/1.3
1.5248
1.4775
1.4759
1.5709
1.4190

0.650/- 6
1.397
0.961
0.9710
0.9543
0.9583
0.9593
1.1991
1.1829

1.4292/ - 2 5
1.4988
1.4709
1.4792
1.4719
1.4583
1.4686
1.4960
1.4890

Flash
point (0C)

RTECS
Number

R and S
1(2),2547K
1(2),2547L
1(1),835A
l(2),2203F
1(2),1959E
1(2),1959D
1(1),835L
1(1),837M
1(1),839J
1(2),1981E

FT-NMR
1(3),336A
1(3),336B
1(1),1174B

1(2),1329A
1(1),1177B
1(1),1182A

1(2),1353B
l(2),1680C

1(2),1959K
1(21),1957L

FT-IR
1(2),795B
1(1),715A
l(2),501D
1(2),333D
1(2),333C

11,8841

l(l),1180B

1(1),837G

l(l),1180A

1(1),841B
1(1),841A
1(2),1957N

1(1),1185A
1(2),1327C

1(1),717B
1(1),719B
1(1),721C

Fieser

27,261
27,261
17,407

4,468

1(2),351B
l(2),550D

19,196

1(1),716C

1(2),1961F

1(2),336B

1(2),1961G

1(2),336C

FT-NMR

Beilstein

17,485
17,484
15,300
17(5),ll,260
17,462
17,461
17,237
17(5),ll,105

1(2),335A
1(2),333B

1(1),837H

Rand S

Merck

FT-IR

19,196

Merck

Beilstein

1(4),975

-23

EI9275000

EI9625000

1(1),27B

1(1),35C

1(1),27D

1(1),36B

1,252

l(l),30C

11,1500

1,249

Fieser

TABLE 10.

cont'd

Name
-,
-,
-,
-,
-,
-,

Formula

2,3-Dimethyl2-FluoroHexachloroHexafluoro2-Iodo2-Methyl-

TABLE 11.

CAS Registry
Number

MoI. wt.

H 2 C=CHCH 2 CH 3
H 2 C=CHCH 2 CH 2 Br
H 2 C=C(CH 3 )CH(CH 3 ),
H 2 C=CHC(CH 3 ) 2 CH 3
H 2 C=C(CH 3 )CH 2 CH 3
H 2 C=CHCH 2 (CH 3 ) 2

106-98-9
5162-44-7
563-78-0
558-37-2
563-46-2
563-45-1

56.11
135.01
84.16
84.16
70.14
70.14

-6
99
56
41
31
20

-158
-115
-137
-168

CH 3 CH=CHCH 3
CH 3 CH=CHCH 3
H 2 C(OH)CH = CHCH 2 (OH)
(CH 3 ) 2 C = C(CH 3 ) 2
(CH 3 ) 2 C=CHCH 3

590-18-1
624-64-6
6117-80-2
563-79-1
513-35-9

56.11
56.11
88.11
84.16
70.14

4
1
131/12
73
36

-139
-105
7
-75
-134

CAS Registry
Number

MoL wt.

106-92-3
7144-65-2
2426-08-6
7665-72-7
3101-60-8
2212-05-7
286-20-4
286-62-4
285-67-6
3132-64-7
106-89-8
503-09-3
21490-63-1
2404-44-6
2855-19-8
7320-37-8
1436-34-6
3146-39-2
7390-81-0
4436-24-2
5455-98-1
3234-28-4
75-21-8
2461-15-6
5380-87-0
556-52-5

114.14
266.28
130.19
130.19
206.29
184.62
98.15
126.20
84.12
136.98
92.53
76.07
72.11
156.27
184.32
240.43
100.16
110.16
268.49
134.18
203.20
212.38
44.05
186.30
154.17
74.08

CCI2=CCICCI = CCI2

87-68-3
685-63-2

68
12
215
7
112
34

-76
-20
-132
-146

Boiling
point ( 0 C)

Melting
point (C)

1-BUTENES
-185

2-BUTENES

TABLE 12.

12.1.

Melting
point (0C)

78-79-5

513-81-5

Formula

2-Butene, cis2-Butene, trans1,4-Dihydroxy-, cis2,3-Dimethyl2-Methyl-

Name

Boiling
point (0C)

82.15
72.08
260.76
162.03
179.99
68.12

H 2 C=C(CH 3 )C(CHs)=CH 2
H 2 C=CFCH=CH 2
CF 2 =CFCF=CF 2
H 2 C=CICH=CH 2
H 2 C=C(CH 3 )CH=CH 2

1-Butene
- , 4-Bromo- , 2,3-Dimethyl- , 3,3-Dimethyl- , 2-Methyl- , 3-Methyl11.2.

MoI. wt.

BUTENES

Name
11.1.

CAS Registry
Number

EPOXIDES

Formula

Boiling
point ( 0 C)

Melting
point (0C)

MONOEPOXIDES CH 2 (-O-)CHR

Allylglycidyl ether
2-Biphenylyl glycidyl ether
n-Butyl glycidyl ether
r-Butyl glycidyl ether
4-f-Butylphenyl glycidyl ether
4-Chlorophenyl glycidyl ether
Cyclohexene oxide
Cyclooctene oxide
Cyclopentene oxide
Epibromohydrin
Epichlorohydrin
Epifluorohydrin
1,2-Epoxybutane, trans1,2-Epoxydecane
1,2-Epoxydodecane
1,2-Epoxyhexadecane
1,2-Epoxyhexane
2,3-Epoxynorbornane, exo1,2-Epoxyoctadecane
2,3-Epoxypropyl benzene
iV-(2,3-Epoxypropyl)phthalimide
1,2-Epoxytetradecane
Ethylene oxide
2-Ethylhexyl glycidyl ether
Furfuryl glycidyl ether
Glycidol

-CH 2 OCH 2 CH=CH 2

-CH 2 OC 6 H 4 C 6 H 5
-CH 2 O(CH 2 ) 3 CH 3
-CH 2 OC(CH 3 ) 3
-CH 2 OC 6 H 4 C(CHs) 3
-CH 2 OC 6 H 4 Cl
C6H10O
C8H14O
C5H8O
-CH 2 Br
-CH 2 Cl
-CH2F
CH 3 CH(-O-)CHCH 3
-(CH 2 ) 7 CH 3
-(CH 2 ) 9 CH 3
-(CH 2 ) 13 CH 3
-(CH 2 ) 3 CH 3
C7H10O
-(CH 2 ) 1 5 CH 3
-CH2C6H5
-CH 2 NC 8 H 4 O 2
-(CH 2 ) n CH 3
-H
-CH 2 OCH 2 CH(CH 2 CH 3 )(CH 2 ) 3 CH 3
-CH 2 OCH 2 C 4 H 3 O
-CH 2 OH

154
120/0.1
165
151
166/4

31

32
129
55/5
102
135
116
85
54
94/15
124/15
176/12
119
137/0.5
99/17

54
-40
-57

21
123
34
99

95/10.4
10.7
61/0.3
103/11
61/15

-111

Density
(at 200C)
0.726
0.843
1.665
1.553/-20
1.4220

Density
(at 200C)

Refractive
index (at 200C)
1.4390
1.400
1.5550
1.378/-20
1.5616
1.4220

Refractive
index (at 200C)

1.330
0.684
0.653
0.650
0.627/0

1.3962
1.4625
1.3890
1.3760
1.3780
1.3640

1.070
0.708
0.662

1.3931/-25
1.3848/-25
1.4780
1.4120
1.3870

Density
(at 20C)

Refractive
index (at 200C)

Flash
point (0C)

RTECS
Number

-22

1(1),32A

l(l),150A

l(l),102A

-54

NT4037000

1(1),27E

1(1),36C

l(l),30D

RTECS
Number

Rand S

FT-NMR

Flash
point (0C)

1(1),15C
1(1),97E
1(1),23I
1(1),23B
1(1),23G
1(1),23A

9
-18
-29
<-35
-57

37
126
-17
-46

Flash
point (0C)

EM4970000

RTECS
Number

RR0875000

0.910
0.917
1.038
0.970

1.4190
1.4170
1.5150
1.5450
1.4520

TX4200000
RR0475000
TX4250000
TX5600000
RN7175000

0.964
1.601
1.183
1.067
0.804
0.840
0.844
0.846
0.831

1.4340
1.4820
1.4380
1.3680
1.3730
1.4290
1.4360
1.4460
1.4060

56
43
102
107
27
56
10
56
34
4
-27
78
105
93
16
10
>110
82

1.4408
1.3597/7
1.4340
1.4810
1.4330

1(1),37A

l(l),105H

57

0.845
0.891/4
0.891
1.122
1.117

1(1),27F

FT-IR

EJ0700000

1.4330

1.5230

FT-NMR

None

0.962

1.020

R and S

RN8935000
TX4115000
TX4900000
TZ3325000
EK3855000
JR2450000
ML9450000
MO3630000
RB7176000
DA0178000
TI4950000

>110
97
102
81

KX2450000
TZ33OOOOO
LU1423000
UB4375000

1(1),19A
1(1),19B
1(1),153A
1(1),25H
1(1),25D

Rand S

1(1),251C
1(1),1253D
1(1),249K
1(1),251A
1(1),1253A
1(1),1253B
1(1),251L
1(1),251M
1(1),251K
1(1),247L
1(1),247I
1(1),247H
1(1),245F
1(1),245J
1(1),245K
1(1),247A
1(1),245H
1(1),253D
1(1),247B
1(1),1251D
l(2),2083B
1(1),245L
1(1),245A
1(1), 251B
1 (2),2319J
1(1),249B

FT-IR

Merck
11,3228

11,5087

Merck

11,1513
1(1),136C
1(1),31B
1(1),29B
l(l),30C
1(1),29A

1(1),221A
1(1),35B
1(1),34A

FT-NMR

1(1),374A
1(2),225A
1(1),373A
1(1),373B
1(2),224A
1(2),224B
1(1),376C
1(1),377A
1(1),376B
l(l),370B
1(1),369B
1(1),369A
1(1),364C
1(1),365C
1(1),366A
1(1),366C
1(1),378B
1(1),367A
l(2),220C
1(2),1461C
1(1),366B
1(1),373C
1(3),17C
l(l),370C

Beilstein

Fieser

1(3),991

1,276

1,250

10,195

1,252

Beilstein

Fieser

1(1),94B
1(1),22A
1(1),25B
1(1),21B
1(1),21C

1,203
1(D,84
1(3),816
1,217
1,211
1,213

1,205
1,205

1(1),146C
1(1),25A
1(1),21D'

11,1514
11,1514
1(2),567
1,218
1,211

Beilstein

Fieser

FT-IR

11,644
11,644

Merck

1(1),233D
l(l),1065C
1(1),232C
l(l),1065B
l(l),1064E)
1(1),235A
1(1),235B
1(1),234D
1(1),232A
1(1),231D
11,3563
1(1),231C
1(1),229B
l(l),230A
l(l),230B
l(l),230D
1(1),229A
1(1),235D
1(1),231B
l(2),408A
l(2),230C

17(3),988
17(3),988

17,21
17,21
17,21
17,6
17(3),49
17,18
17(3),136
17,20
17,86
17(3), 140
17,51

11,3758

17(3), 139
17,4

11,4385

17(5),347
17,104

1(1),232D
1(1),232B

5,290

8,150

TABLE 12.

cont'd

Name

Formula

3-Glycidoxypropyl trimethoxy- -CH 2 O(CH 2 )SSi(OCHs) 3

silane
(R)-(-)-Glycidyl Butyrate
-CH 2 OC(O)CH 2 CH 2 CH 3
Glycidyl isopropyl ether
-CH 2 OCH(CH 3 ) 2
Glycidyl methacrylate (see Methacrylates)
GIy cidy ltrimethy lammonium
-CH 2 N(CH 3 ) 3 C1
chloride, (70% aq. solution)
Hexafluoropropylene oxide
F 2 C(-O-)CFCF 3
4-Methoxyphenyl glycidyl ether -CH 2 OC 6 H 4 OCH 3
a-Pinene oxide
CioH^O
Propylene oxide
-CH3
Styrene oxide
-C6Hs
Tetracyanoethylene oxide
(NC) 2 C(-O-)C(CN) 2
1,1,2,2-Tetrafluoroethyl glycidyl -CH 2 OCF 2 CHF 2
ether
Vinylethylene oxide
-CH=CH 2

CAS Registry
Number

MoI. wt.

Boiling
point (0C)

2530-83-8

236.34

120/2

60456-26-0
4016-14-2

144.17
116.16

90/19
131

3033-77-0

151.54

428-59-1
2211-94-1
1686-14-2
75-56-9
96-09-3
3189-43-3
85567-21-1

166.02
180.20
152.24
58.08
120.15
144.09
174.10

102/50
34
194

930-22-3

70.09

65

3130-19-6

366.46

1464-53-5
2425-79-8
27035-39-8
2426-07-5
2386-87-0

86.09
202.25
140.18
142.20
252.31

57/25
158/11
70/0.4
240

2224-15-9

174.20

112/4.5

CAS Registry
Number

MoI. wt.

Boiling
point ( 0 C)

28.05
106.96
62.50
84.48
116.47
185.86

-104
16/750
-13.4
-24
-29
92

Melting
point (0C)

-42
46
-112
-37

143

12.2. DIEPOXIDES CH2(-O-)CHRCH(-O-)CH2

Bis(3,4-epoxycyclohexylmethyl) C 6 H9(-O-)CH 2 OC(O)(CH 2 )4C(O)OCH 2 C 6 H9(-O-)
adipate
1,3-Butadiene diepoxide
CH 2 (-O-)CHCH(-O-)CH 2
1,4-Butanediol diglycidol ether -CH 2 O(CH 2 ) 4 OCH 2 1,2,5,6-Diepoxycyclooctane
CgHi 2 O 2
1,2,7,8-Diepoxyoctane
-(CH2)43,4-Epoxycyclohexylmethyl
C 6 H9(-O-)CH 2 OC(O)C 6 H 9 (-O-)
3,4-epoxycyclohexanecarboxylate
Ethylene glycol digycidyl ether -CH 2 O(CH 2 ) 2 OCH 2 -

TABLE 13.

-37

ETHYLENE HALIDES

Name
Ethylene
- , Bromo- (vinyl bromide)
- , Chloro- (vinyl chloride)
- , 1-Chloro-1-fluoro- , Chlorotrifluoro- , 1,1-Dibromo- (vinylidene
bromide)
- , 1,2-Dibromo-, cis1,2-Dibromo-, trans- , 1,1-Dichloro- (vinylidene
chloride)
- , 1,2-Dichloro-, cis- , 1,2-Dichloro-, trans- , Tetrabromo- , Tetrachloro- , Tetrafluoro- , Tetraiodo- , Tribromo- , Trichloro-

Formula
H 2 C=CH 2
BrCH=CH 2
ClCH=CH 2
ClCF=CH 2
ClCF=CF 2
Br 2 C=CH 2
BrCH=CHBr
BrCH=CHBr
Cl 2 C=CH 2
ClCH=CHCl
ClCH=CHCl
Br 2 C=CBr 2
Cl 2 C=CCl 2
F 2 C=CF 2
I 2 C=CI 2
Br 2 C=CHBr
Cl 2 C=CHCl

74-85-1
593-60-2
75-01-4
79-38-9

75-35-4
156-59-2
156-60-5
127-18-4
116-14-3
513-92-8
79-01-6

Melting
point (0C)
-169
-139
-154
-169
-157

185.86
185.86
96.94

112
108
31

-53
-6
-122

96.94
96.94
343.66
165.83
100.02
531.64
264.76
131.39

60
48
226
121
-76

-80
-50
56
-22
-142
192

163
87

-85

Density
(at 20 0 C)

Refractive
index (at 20 0 C)

Flash
point ( 0 C)

RTECS
Number

Rand S

FT-NMR

FT-IR

1.070

1.4290

>110

VV4025000

1(2),2973B

1(3),667C

1(2),1113D

1.018
0.924

1.4280
1.4100

85
33

TZ35OOOOO

1(1),781E
1(1),249J

l(l),1088B
1(1),372C

l(3),306A

1.129

1.4780

> 110

BQ3480000

0.964
0.830
1.054

1.4690
1.3660
1.5350

>110
66
-35
79

TZ3400000
DA0176000
TK4565000
TZ2975000
CZ9625000

1.380

1.3490

51

0.870

1.4170

-50

EM7350000

1.149

1.4930

> 110

MO 1880550

1.113
1.100
1.138
0.997
1.170

1.4340
1.4610
1.4690
1.4450
1.4980

46
>110
105
98
118

1.118

1.4630

> 110

Density
(at 20 0 C)

Refractive
index (at 20 0 C)

1.517
0.911

1.4350
1.3700

Flash
point ( 0 C)

None
- 61

Merck

Beilstein

Fieser

17(5),3,34
17(3),988
18,583

1(1),616B
1(1),249A
1(1),1253C
1(1),253B
1(1),245B
1(1),1251A
l(l),1003F

1(2),224C
1(1),377C
1(1),363B
1(2),219C
1(1),1376C

l(l),1065A
1(1),237A
1(1),228B
l(l),1063C

1(1),247D

1(1),367C

1(1),233A

EJ8400000
EJ5100000
GX9627000
RG9450000
RN7750000

1(1),251E
1(1),251I
1(1),253E
1(1),251F

1(1),374B
1(1),375C
1(1),378C
1(1),374C

1(1),234A
1(1),234C
1(1),235C
1(1),234B

KH5780000

1(1),251G

1(1),375A

RTECS
Number

Rand S

KU5340000
KU8400000
KU9625000

1(1),15A
1(1),95B
1(1),95A

KV0525000

l(l),103I

17(3),20

FT-NMR
1(3),17C
1(1),133A

11,7869

5,152
17,6
17,49

18(5),7,215

17(1),13

11,3621

4,53

19,14

17(3),997

FT-IR

Merck
11,3748

1(1),93A
11,9898

Beilstein
1,180
1,188
1,186

Fieser

1,1274

1(3),646

2.178
2.2464
2.2308
1.213

1.5428
1.550
1.4254

-9

KV9275000

l(l),101B

1(1),142B

1(1),98B

11,9900

1,186

1.284
1.257

1.4481
1.4456

6
6

KV9420000
KV9400000

l(l),101D
l(l),101E

1(1),143A
1(1),134B

1(1),98A
1(1),79D

11,86
11,86

1,188
1,188

1.623
1.1507/- 40
2.983
2.708
1.463

1.5060

KX3850000

l(l),103J

11,9126

1,187

11,9151

1,195

11,9552

1,187

None
1.6045/16
1.4760
None

KX4125000

l(l),103K

KX4550000

l(l),103G

l(l),101C
1(1),147C
l(l),101B

14,127
12,175

11,552

TABLE 14.

FUMARATE ACIDS/ESTERS
Formula ROC(O)CH=CHC(O)OR

Name

CAS Registry
Number

Acid
2-Bromo2-Chloro2-Chloro-, diethyl ester
2-Chloro-, dimethyl ester
Di-n-amyl ester
Diethyl ester
Diisoamyl ester
Diisobutyl ester
Diisopropyl ester
2,3-DimethylDimethyl ester
Dinitrile- (fumaronitrile)
Diphenyl ester
Di-/z-propyl ester
2-Methyl- (mesaconic acid)
2-Methyl-, diethyl ester

-H
HOC(O)CBr=CHC(O)OH
HOC(O)CCl=CHC(O)OH
CH3CH2OC(O)CCI=CHC(O)OCH2CH3
CH3OC(O)CCI=CHC(O)OCH3
-(CH 2 ) 4 CH 3
-CH 2 CH 3
-CH 2 CH 2 CH(CH 3 ) 2
-CH 2 CH(CH 3 ) 2
-CH(CH 3 ) 2
HOC(O)C(CH3)=C(CH3)C(O)OH
-CH 3
NCCH=CHCN
-C6H5
-CH 2 CH 2 CH 3
HOC(O)C(CH3) = CHC(O)OH
CH3CH2OC(O)C(CH3)=CHC(O)CH2CH3

2-Methyl-, dimethyl ester

CH3OC(O)C(CH3)=CHC(O)OCH3

TABLE 15.

623-91-6

624-49-7
764-42-1

498-24-8

116.07
194.98
150.52
206.63
178.57
256.33
172.18
256.33
228.29
200.24
144.13
144.13
78.07
268.27
200.24
130.10

Boiling
point (0C)

200(d)
136/19
224
162/7
217
166/11
170/160
226
192
186
219/14
110/5
205(d)
186.21
158.16

Melting
point (0C)
299(s)
186
193

241
103
96
162
204
229
204

ISOCYANATES
Formula OCNRNCO

Name

110-17-8

MoI. wt.

1,3-Benzene diisocyanate
-C6H41,4-Benzene diisocyanate
-C6H41,3-Bis(isopropyl)benzene
-C(CH 3 ) 2 C 6 H 4 C(CH 3 ) 2 a,oc'-diisocyanate
1,4-Bis(isopropyl)benzene
-C(CH 3 ) 2 C 6 H 4 C(CH 3 ) 2 a,a'-diisocyanate
1,4-Butene diisocyanate
-(CH2)4a-Chlorotoluene
-C 6 H 3 (CH 2 Cl)2,4-diisocyanate
1,4-Cyclohexylene diisocyanate, - C 6 H 1 0 trans1,12-Dodecane diisocyanate
-(CH 2 ) 1 2 1,6-Hexane diisocyanate
-(CH 2 ) 6 Isopherone diisocyanate
-C 1 0 H 1 S(isomers)
4,4/-Methylenebis(cyclohexyl
-(C 6 H 1 0 )CH 2 (C 6 H 1 0 )isocyanate) (isomers)
4,4'-Methylenebis(2,6-di-C 6 H 2 (CH 2 CH 3 ) 2 CH 2 C 6 H 2 (CH 2 CH 3 ) 2 ethylphenyl
isocyanate)
4,4/-Methylenebis(phenyliso-C6H4CH2C6H4cyanate)
2-Methylpentane 1,5-diisocyanate-CH2CH(CH3)(CH2)3 1,8-Octane diisocyanate
-(CH 2 )g2,4-Toluene diisocyanate
-C 6 H 3 (CH 3 )-

CAS
Registry
Number

MoI. wt.

Boiling
point (0C)

Melting
point (0C)

123-61-5
104-49-4
2778-42-9

160.13
160.13
244.30

121/25
260
157/10

2778-41-8

244.30

150/3

4538-37-8
51979-57-8

140.14
208.60

102/14
153/11

72

7517-76-2

166.18

13879-35-1
822-06-0
4098-71-9

252.36
168.20
222.29

168/3
255
158/15

60

5124-30-1

262.35

105442-35-1

362.48

101-68-8

250.26

200/5

43

34813-62-2
10124-86-4
584-84-9

168.20
196.25
174.16

156/15
120/10

21

50
98
-10

56

Density
(at 20 0 C)

Refractive
index (at 20 0 C)

1.1880
1.290
0.9681
1.052
0.9655
0.9760

1.4571

0.9416

1.4349

1.0129
1.466

1.4439

Density
(at 20 0 C)

1.4496
1.4410
1.4479
1.4432

Flash
point ( 0 C)

94

1.0453

1.4488

1.0914

1.4512

Refractive
index (at 20 0 C)

Flash
point (0C)
>110
>110
153

1.05

RTECS
Number

R and S

LS9625000

1(1),553A

1(1),787B

l(l),502D

EM5950000

1(1),725M

1(1),993C

1(1),645A

2,742

EM6125000
LT2300000

1(1),725L
1(1),993A

1(1),993B
l(l),1360B

1(1),644D
1(1),844A

2,741
2(l),302

OX5075000

1(1),553C

1(1),788A

l(l),503B

RTECS
Number

Rand S

NR0150000
CZ6150000
CY8480000

FT-NMR

FT-NMR

FT-IR

FT-IR

Merck
11,4200

11,5806

Merck

Beilstein

Fieser

2,737

5,319

2,763

Beilstein

Fieser

13,50
13,105

1(2),2165G
1(2),2165H

>93
1.105
1.362

1.5960

106
>110

l(l),1023F
1(2),2169H

l(l),1404B
1(2),1572A

4(3),578
13(4),245

GU9642500

l(l),1025A

l(l),1406A

13(3),12

l(l),1405A
l(l),1404C
l(l),1405C

4(3),624
4(2),711

1(3),1432D

0.940
1.040
1.049

1.4590
1.4520
1.4840

>110
140
>110

MO1740000
NQ9370000

l(l),1023H
l(l),1023G
l(l),1023J

1.066

1.4970

>110

NQ9250000

l(l),1025B
1(2),2169K

1.180
1.049
1.007
1.214

>110
1.4550
1.4550
1.5680

>110
> 110
> 110

NQ9350000

1(2),1572C
1(1),871A

1(2),2163D
l(l),1023I

CZ630000

13(4),33

13(3),461

l(l),1405B

1(2),2169F

11,9456

1(2),478B

4(3),614
13,138

1,117

TABLE 16.

LACTAMS

Name

Formula

y-Butyrolactam (2-pyrrolidinone)
s-Caprolactam
12-Dodecanolactam
7-Heptanolactam
P-Propiolactam
5-Valerolactam

-C(O)(CH 2 ) 3 NH-C(O)(CH 2 ) 5 NH-C(O)(CH 2 ) n N H -C(O)(CH 2 ) 6 NH-C(O)CH 2 CH 2 NH-C(O)(CH 2 ) 4 NH-

TABLE 17.

Formula

y-Butyrolactone
8-Caprolactone
p-Propiolactone
5-Valerolactone

-C(O)(CH 2 )^O-C(O)(CH 2 ) 5 O-C(O)(CH 2 ) 2 O-C(O)(CH 2 ) 4 O-

616-45-5
105-60-2
947-04-6
673-66-5
930-21-2
675-20-7

85.11
113.16
197.32
127.19
71.08
99.13

CAS Registry
Number

MoI. wt.

Boiling
point (0C)

96-48-0
502-44-3
57-57-8
542-28-9

86.09
114.14
72.06
100.12

204
97/15
162
59/0.5

MoI. wt.

Boiling
point (C)

245
137/10
149/10
106/15
256

Melting
point (0C)
24
69
151
36
75
39

Melting
point (0C)
-45
-33

MALEATE ACIDS/ESTERS
Formula ROC(O)CH=CHC(O)OR

Name

Acid
2-Chloro2-Chloro-, diethyl ester
2-Chloro-, dimethyl ester
Diallyl ester
Di-n-amyl ester
Di--butyl ester
2,3-DichloroDiethyl ester
2,3-DihydroxyDiisoamyl ester
Dimethyl ester
Diphenyl ester
Di-n-propyl ester
2-Methyl-, cis- (citraconic acid)
2-Methyl-, diethyl ester, cis2-Methyl-, dimethyl ester, cis-

TABLE 19.

MoI. wt.

LACTONES

Name

TABLE 18.

Boiling
point (0C)

CAS Registry
Number

-H
HOC(O)CCl=CHC(O)OH
CH3CH2OC(O)CCI=CHC(O)OCH2CH3
CH3OC(O)CCI=CHC(O)OCH3
-CH 2 CH=CH 2
-(CH 2 ) 4 CH 3
-(CH 2 ) 3 CH 3
HOC(O)CC1=CC1C(O)OH
-CH 2 CH 3
HOC(O)C(OH)=C(OH)C(O)OH
-CH 2 CH 2 CH(CH 3 ) 2
-CH 3
-C6H5
-CH 2 CH 2 CH 3
HOC(O)C(CH3 )=CHC(O)OH
CH3CH2OC(O)C(CH3)=CHC(O)OCH2CH3
CH3OC(O)C(CH3)=CHC(O)OCH3

CAS
Registry
Number
110-16-7

999-21-3
105-76-0
141-05-9

624-48-6

498-23-7

116.07
150.52
206.63
178.57
196.20
256.33
228.29
184.97
172.18
148.07
156.33
144.13
268.27
200.24
130.10
186.21

Melting
point (0C)
141
110

235
107
110/4
161/10
281

-47

225

120
-10
155

157/13
204
226/15
126/12

93
90

230
158.16

211

PROPENES

Name
Propene
- , 1-Bromo-, cis- , 1-Bromo-, trans- , 2-Bromo- , 1-Chloro-, cis- , 1-Chloro-, trans- , 2-Chloro- , l-Chloro-2-methyl(isocrotyl chloride)
- , 3-Chloro-2-methyl(methallyl chloride)
- , 1,1-Dichloro-

Formula

CAS Registry
Number

MoI. wt.

Boiling
point (0C)

Melting
point (0C)

-48
58
64
48
33
37
22.5
68

-185

557-98-2
513-37-1

42.08
120.98
120.98
120.98
76.53
76.53
76.53
90.55

H 2 C=C(CH 3 )CH 2 Cl

563-47-3

90.55

71

-80

Cl 2 C=CHCH 3

563-58-6

110.97

76

H 2 C=CHCH 3
BrCH=CHCH3
BrCH=CHCH3
H 2 C=CBrCH 3
ClCH=CHCH3
ClCH=CHCH3
H 2 C=CClCH 3
C1CH=C(CH3)2

115-07-1
590-13-6
590-15-8
557-93-7

-125
-135
-99
-139

Density
(at 2O0C)
1.120

Density
(at 200C)
1.120
1.030
1.146
1.079

Density
(at 200C)

Refractive
index (at 2O0C)
1.4870

Refractive
index (at 200 C)
1.4360
1.4630
1.4120
1.4580

Refractive
index (at 2O0C)

Flash
point (0C)
>110

RTECS
Number

Rand S

>110

UY5715000
CM3675000
CL6940000
CN4810000

> 110

TO0110000

1(1),923B
1(1),927G
1(1),929A
1(1),927M
1(1),923A
1(1),927E

RTECS
Number

Rand S

Flash
point (0C)
98
109
70
100

Flash
point (0C)

1.590

LU3500000
MO8400000
RQ7350000

l(l),803J
1(1),819E
l(l),803A
1(1),815A

FT-NMR
1(1),1285B
1(1),1293B
1(1),1296A
1(1),1295B
1(1),1285A
1(1),1292C

FT-NMR

FT-IR
1(1),788D
1(1),792B
1(1),794A
1(1),793C

Merck
11,8027
11,1762

1(1),1127A
1(1),1161C

1(1),697D
1(1),699B

1(1),1152A

l(l),704D

Merck
11,1596
11,7832

RTECS
Number

Rand S

OM9625000

l(l),5510

1(1),787A

FT-NMR

FT-IR
l(l),503A

21,236
21(2),216

Merck
11,5585

Beilstein
17,234
17(2),290
17(l),130
17,235

Beilstein

Fieser
1,101
1,957

Fieser

2,748

1.1741
1.277
1.073
0.9741
0.988

1.4690
1.4475
1.4452

>110

ON0700000

1(1),725K

1(1),993A

2(3), 1926

>110

ON0875000

1(1),725J

1(1),992C

2(3),1925

1.064

1.4410

93

ON1225000

1(1),725I

1(1),992B

0.9714
1.152

1.4459
1.4410

1.0245

1.4433

1.0491

1.4468
1.9491

1(1),644C

Fieser

21,242
21(3),3141
21,238

1(1),791D

FT-IR

Beilstein

11,3113
2,751

91

EM6300000

1(1),725H

1(1),992A

1(1),644B
2,751

GE6650000

Density
(at 2O0C)

Refractive
index (at 2O0C)

1(1),553B

1(1),787C

l(l),503C

11,2323
2,768

1.4473

Flash
point (0C)

RTECS
Number

R and S

FT-NMR

FT-IR

Merck
11,7862

Beilstein
1,196
l(3),710
1(4),754
1,200

1(1),15B
1(1),95F
1(1),95C
1(1),95H

1(1),134C

1(1),96B

UC7200000
UC8045000

1(1),95D
1(1),97I

1(1),133B
1(1),137C

1(1),96A
1(1),97A

11,2147

1,198
1,209

-12

UC8050000

1(1),97J

1(1),138A

1(1),96D

11,2148

1,209

UC8290000

l(l),101G

1(1),144A

1(3),138D

1.423
1.408
1.362
0.9347
0.9351
0.899
0.920

1.4545
1.4530
1.436
1.4055
1.4054
1.3939
1.4225

-34
-15
4

-34
-1

0.917

1.4278

1.169

1.4450

UC6740000

UC7085000

1(1),134A

1,199

Fieser

4,236

TABLE 19.

cont'd

Name

Formula

-,
-,
-,
-,
-,
-,
-,

CICH=CClCH 3
F 2 C=CFCF 3
H 2 C=C(CH 3 ) 2
Cl 2 C=CClCH 3
Cl 2 C=CHCH 2 Cl

1,2-DichloroHexafluoro2-Methyl- (isobutylene)
1,1,2-Trichloro1,1,3-Trichloro1,2,3-Trichloro3,3,3-Trichloro-

TABLE 20.

CAS Registry
Number

116-15-4
115-11-7

CICH=CCICH2CI

H 2 C=CHCCl 3

MoI. wt.

Boiling
point (0C)

110.97
150.02
56.11
145.42
145.42
145.42
145.42

77
-28
-7
118
131
142
114

MoI. wt.

Boiling
point (0C)

Melting
point (0C)

-153
-140

STYRENES
Formula CH 2 =CHR

Name
Styrene
- , 4-Acetoxy- , 2-Amino- , 4-Amino- , 4-Benzyloxy-3-methoxy- , 3,5-Bis(trifluoromethyl)a-Bromop-Bromo- , 2-Bromo- , 3-Bromo- , 4-Bromo- , 4-terf-Butyl- , 4-Carboxya-Chloro(3-Chloro- , 2-Chloro- , 3-Chloro
- , 3-Chloromethyl
(3-vinylbenzyl chloride)
- , 4-Chloro- , 4-Chloromethyl- , 4-Chloro-a-Methyl- , 2-Cyano- , 3-Cyano
- , 4-Cyano- , 2,5-Dichloro- , 2,6-Dichloro- , 3,4-Dichloro- , a,p-Difluoro- , 1,2-Difluoro- , 2,6-Difluoro- , 1,3-Diisopropenyl benzene
- , 3,4-Dimethoxy- , a,2-dimethyl- , 2,4-Dimethyl- , 2,5-Dimethyl- , Divinyl-, (isomers)
- , 4-Ethoxy- , 2-Ethyl- , 4-Ethyl- , 3-Iodo- , 2-Fluoro- , 3-Fluoro- , 4-Fluoro- , 2-Hydroxy- , 3-Hydroxy- , 4-Hydroxy- , 4-Isopropyl-

R
-C6H5
-C 6 H 4 OC(O)CH 3
-C6H4NH2
-C6H4NH2
-C 6 H 3 (OCH 3 )OCH 2 C 6 H 5
-C 6 H 4 (CF 3 ) 2
H 2 C=CBrC 6 H 5
HCBr=CHC 6 H 5
-C 6 H 4 Br
-C 6 H 4 Br
-C6H4Br
-C 6 H 4 C(CH 3 ),
-C6H4CO2H
H 2 C=CClC 6 H 5
HCCl=CHC 6 H 5
-C 6 H 4 Cl
-C 6 H 4 Cl
-C 6 H 4 CH 2 Cl
-C 6 H 4 Cl
-C 6 H 4 CH 2 Cl
H 2 C=C(CH 3 )C 6 H 4 Cl
-C6H4CN
-C 6 H 4 CN
-C 6 H 4 CN
-C6H3Cl2
-C6H3Cl2
-C6H3Cl2
HCF=CFC 6 H 5
-C6H3F2
-C6H3F2
C 6 H 4 (C(CH 3 )=CH 2 ) 2
-C6H3(OCH3),
H 2 C=C(CH 3 )C 6 H 4 CH 3
-C6H3(CH3),
-C6H3(CH3),
C 6 H 4 (CH=CH 2 ) 2
-C 6 H 4 OCH 2 CH 3
-C 6 H 4 CH 2 CH 3
-C 6 H 4 CH 2 CH 3
-C6H4I
-C6H4F
-C6H4F
-C6H4F
-C6H4OH
-C6H4OH
-C 6 H 4 OH
-C 6 H 4 CH(CH 3 ),

CAS
Registry
Number
100-42-5
2628-16-2
3867-18-3
1520-21-4
55708-65-1
349-59-7
98-81-7
103-64-0
2039-88-5
2039-86-3
2039-82-9
1746-23-2
1075-49-6

2039-87-4
2039-85-2
57458-41-0
1073-67-2
1592-20-7
1712-70-5
5338-96-5
3435-51-6
1123-84-8
28469-92-3
2039-83-0
366-37-0
3748-13-8
6380-23-0
26444-18-8
2234-20-0
2039-89-6
1321-74-0
5459-40-5
7564-63-8
3454-07-7
394-46-7
350-51-6
405-99-2

2055-40-5

104.15
162.19
119.18
119.18
240.30
240.15
183.05
183.05
183.05
183.05
183.05
160.26
148.16
138.60
138.60
138.60
138.60
152.62

145
260
104/8
249
51
60/20
69/4
111/20
210
74/3
212
219

138.60
152.62
152.62
129.16
129.16
129.16
173.04
173.04
173.04
140.03
140.03
140.03
158.25
164.20
132.21
132.21
132.21
130.19
148.21
132.21
132.21
233.05
122.14
122.14
122.14
120.15
120.15
120.15
146.22

192
229

199
199
188
62/6
229

53/0.15
83/2.6
92/3
74/3
88/8
76/3
88/60
90/45
59/51
231
120/10
54/11
70/11
71/10
59/1
191
193
67/15
30/4
30/14
108/15
115
204

Melting
point (0C)
-30
7
23
7
-44
7
-53
4.5
-37
143
-23

-63

-16

-15

-64
-35

-127
-50
73

29
73.5
-45

Density
(at 20 0 C)
1.1818

1.382
1.403
1.414
1.369

Density
(at 20 0 C)
0.9059
1.060
1.608
1.014

Refractive
index (at 20 0 C)

1.4827
1.4950
1.5020
1.4827

Refractive
index (at 2O0C)
1.5470
1.5380

R and S

UD0350000
UD0890000

l(l),105A
1(1),23F

UD1928500

l(l),103H

RTECS
Number

R and S

WL3675000
SL3784000

1(1),1139A
1(2),1927F

1(2),23A
1(2),1287C

1(1),945B

1(1),1237M
1(1),1213A
l(l),1203F
l(l),1203H
l(l),1203L
l(l),1205D
l(l),1205H

1(2),197C
1(2),155A

l(l),1053A

1(2),136C
1(2),138A
1(2),139C
1(2),141A

l(l),1017B
l(l),1018A
1(3),195B
l(l),1019C

1(2),1789D

l(2),1076A

1(2),194D

l(l),1203K
l(l),1205C

1(2),137C
1(2),139B

l(l),1017D
l(l),1018C

l(l),1205F

1(2), 140B

l(l),1019B

l(l),1205G

1(2), 140C

l(l),1018D

l(l),1205J

1(2),141C

l(l),1019D

1(1X12051
1(1),1139L
1(1),1243D

1(2),141B
1(2),26B
l(2),208C

1(1),947C
l(l),1053D

1(1),1141D
1(1),1141E
1(1),1141B
1(1), 1243 A

1(2),27C
1(2),28A

l(l),1203J
l(l),1205B
l(l),1205E

1(2),137B
1(2), 139 A
1(2), 140A

FT-NMR

FT-IR

48

Flash
PQint ( 0 C)
31
87

1(3),143C
1(3),28B
1(1),148A

Merck

FT-NMR

1.1016/18
1.1095/15
1.080
1.090
1.074

1.5612
1.5648
1.5648
1.5613

1.155
1.083
1.065

1.5662
1.5740
1.5550
1.5756
1.5630
1.575
1.5740

11,5024

1(3),142A

FT-IR

Beilstein

l(3),707

Merck
11,8830

Beilstein
5,474
6(3),2387

>110
122
87
102
85
67
75
80

58
62
105

WL3840000
WL385OOOO

WL4160000

60
104
74

5(4), 1386
5,477
5,477
5(3X1176
5(3),1176
5(2),367
5(3X1254
9(3),2755

5(2),367

104

71

1.5061
1.130
0.925
1.109
0.894
0.906
0.904
0.914
0.990
0.8955
0.8925

Fieser

1(3),697
1,207

12,1187

1.6267
1.4250
1.5880
1.6070
1.5927
1.5891
1.5940
1.5260

1.267

RTECS
Number

1.4471

1.334
1.410
1.427
1.460
1.406
1.400
0.875

1.083

Flash
point ( 0 C)

1.025
1.025
1.024
1.0609/18
1.0468/35

1.4990
1.5570
1.5710
1.5150
1.5390
1.5391
1.5470
1.5498
1.5351
1.5376
1.6390
1.5200
1.5175
1.5156
1.5783/27
1.5804/31

0.885

1.5289

30
91
>110
43
60
63
64
87

35
29
26

CY8535OOO

WL4450000
WL4460000
CZ9370000

6,954
5,491
5,491

1(3),984B

l(l),1081B
l(l),1019A

6,561

5(3),1171
5(3),1171

Fieser

TABLE 20.

cont'd
Formula CH 2 =CHR
R

Name
- , 2-Methoxy- , 3-Methoxy- , 4-Methoxy- , 2-Methoxy-4-hydroxya-Methyl- , 2-Methyl- , 3-Methyl- , 4-Methyl- , P-Nitro- , 2-Nitro- , 3-Nitro- , 4-Nitro- , Pentabromo- , Pentafluoro- , 4-Phenoxy- , 4-Phenyl- , 4-Sulfonic acid, sodium salt
- , 2-Trifluoromethyl- , 3-Trifluoromethyl- , 4-Trifluoromethyl- , 2,4,6-Trimethyl-

TABLE 21.

Boiling
point (0C)

Melting
point (0C)

61.3
144/2
204
224
167
171
170
172
250

29

586-39-0
100-13-0
53097-59-9
653-34-9
4973-29-9
2350-89-2
2695-37-6
395-45-9
402-24-4
402-50-6
769-25-5

134.18
134.18
134.18
150.18
118.18
118.18
118.18
118.18
149.15
149.15
149.15
149.15
498.66
194.10
196.25
180.25
206.20
172.15
172.15
172.15
146.24

Formula

CAS Registry
Number

MoI. wt.

Boiling
point (0C)

Melting
point (0C)

-CI4HQ

2444-68-0

204.27

62/10

65

-C10H7
-C5H4N
-C5H4N
-C5H4N
-C9H6N

827-54-3
100-69-6
1121-55-7
100-43-6
772-03-2

154.21
105.14
105.14
105.14
155.20

80/29
68/15
63/15
71/0.5

108-05-4

86.09

72

56860-96-9
769-78-8
5309-70-6
15484-80-7
123-20-6
872-36-6
2549-51-1
15721-27-4
5130-24-5
3098-92-8
14861-06-4
4704-31-8
2146-71-6
94-04-2
692-45-5
1917-10-8
693-38-9
3050-69-9

212.25
148.16
165.0
204.27
114.14
86.05
120.54
182.61
106.51
174.20
112.13
198.31
226.36
170.25
72.06
138.12
282.47
142.20
168.15

135/9
203
50/10
111/2
116
162
134

-C 6 H 4 OCH 3
-C 6 H 4 OCH 3
-C 6 H 4 OCH 3
-C 6 H 3 OCH 3 (OH)
H 2 C=C(CH 3 )C 6 H 5
-C6H4CH3
-C6H4CH3
-C6H4CH3
HC(NO 2 )=CHC 6 H 5
-C6H4NO2
-C6H4NO2
-C6H4NO2
-C6Br5
-C6F5
-C6H4OC6H5
-C6H4C6H5
-C 6 H 4 SO 3 Na
-C6H4CF3
-C6H4CF3
-C6H4CF3
-C6H2(CH3),

90/3.5
120/10

-24
-69
-82
-34
58
13
-5
25
188

139
71
120
225
61/40
55/12
65/40
209

ARYLH 2 C=CHR

9-Anthracene
Benzene (see Styrene)
2-Naphthalene
2-Pyridine
3-Pyridine
4-Pyridine
2-Quinoline
21.2.

612-15-7
626-20-0
637-69-4
7786-61-0
98-83-9
611-15-4
100-80-1
622-97-9

MoI. wt.

VINYLFUNCTIONAL

Name
21.1.

CAS
Registry
Number

61

ESTERS H 2 C=CHOC(O)R

Acetate
Acrylate (see Acrylates)
AUyI adipate
Benzoate
Bromoacetate
4-tert-Buty\ benzoate
Butyrate
Carbonate
Chloroacetate
2-Chlorobenzoate
Chloroformate
Cinnamate
Crotonate
Decanoate
Dodecanoate
2-Ethylhexanoate
Formate
2-Furoate
Hexadecanoate (palmitate)
Hexanoate (caproate)
Maleate

-CH3
-(CH 2 ) 4 C(O)OCH 2 CH=CH 2
-C6H5
-CH 2 Br
-C 6 H 4 C(CH 3 ) 3
-(CH 2 ) 2 CH 3
-OCH=CH 2
-CH 2 Cl
-C 6 H 4 Cl
-Cl
-CH=CHC 6 H 5
-CH 2 CH=CHCH 3
-(CH 2 ) 8 CH 3
-(CH 2 ) K)CH3
-CH(CH 2 CH 3 )(CH 2 ) 3 CH 3
-H
-C4H3O
-(CH 2 ) 14 CH 3
-(CH 2 ) 4 CH 3
-CH=CHC(O)OCH=CH 2

68/735
125/7
133
146/50
140/10
128/20
46
182/10
165/2
160/10
94/10

-93

22

-90
14
24

Density
(at 20 0 C)

Refractive
index (at 200 C)

Flash
point (0C)

1.0049
0.9999
0.994
1.110
0.909
0.917
0.890
0.897

1.5388
1.5540
1.5620
1.5820
1.5380
1.544
1.5408
1.5412

1.070

1.5840
1.6016

107

1.4455

34

72
>110
45
58
52
45

RTECS
Number

SL8205000
WL5075300
WL5075900
WL5075800
WL5076000

R and S

FT-NMR

FT-IR

Merck

Beilstein

l(l),1241O

l(2),207C

l(l),1052C

1(1),1139B
1(1),1139K
1(1),1139M
1(1),1139N

1(2),2437C

1(1),945C
1(1),947A
1(3),869B
1(1),947B

6,561
6(3),4981
5,484
5(1),233
5,485
5,485

1(1),1334D

5,478

1(2),26C

Fieser

1(2),27A

1.406

1.175
1.161
1.165
0.906

1.4700
1.4655
1.4660
1.5320

1(1),1555D
WL5470000

42

75

l(l),1205N
l(l),1205K

1(2),687C

1(1),1145G
l(2),2207I
l(l),1207C
l(l),1207K
l(l),1209F
1(1),1141G

1(2),142A
1(2),35B
1(2),1598C
1(2), 143 A
1(2),138C
1(2),148A

l(l),1020B
l(l),1020A

5(4), 1367
5(3),1197
5(4), 1369
5,500

1(1),951D

1(3),871A

Density
(at 20 0 C)

0.975
0.975
1.340

Refractive
index (at 20 0 C)

1.5490
1.5530
1.5500

Flash
point (0C)

RTECS
Number

47

UU1040000

52
128

UU1045000

R and S

1.3950

-6

1.5290

82

0.999
0.9022
1.355
1.19
1.22
1.253
1.07
0.940
0.886
0.8639
0.875
0.9651

1.5180
1.411
1.4210
1.4440

>110
20
72

1.4100

-4

1.4480
1.4350
1.4387
1.4256
1.4757

27
104
136
65

0.8602
0.8837

1.4444
1.4159

Merck

Beilstein

1(2),51A

1(1),963B

1(1),1151G
1(2),2495G

1(2),46A
1(3),242C

1(1),959C
1(2),734A

20,256

1(2),738D
1(2),853D

20(2),170
20,425

1(1),632D

11,9896

2(1),63

12,565

1(1),963A
9(1),65

DI1050000

9(4), 1885
2(4),792

l(2),1903L

1(2),1248C

1(1),697E

1(1),933A

1(1),644A

1(1),863A

l(l),1206A

1(1),736D

3(3),28

GQ5850000

1(1),721H

1(1),978C

1(1),642B

2(3),1263
2(3),843

MO7875000
LR0525000

1(1),719A

1(1),793A
l(l),1206A

1(1),637C
1(1),736C

2(4), 1005
3(3),28

FG3325000

Fieser

1(3),248B

AK0875000
1(1),715A

1.070

FT-IR

1(1),1153I

1(2),2499B
0.934

FT-NMR

13,342

8,530

8,530

TABLE 21.

cont'd

Name

Maleate, monoester
Methacrylate (see Methacrylates)
Neodecanoate
Nonate
Octadecanoate (stearate)
9-Octadecenoate (oleate)
Octanoate
Pentafluoropropionate
Pentanoate
Pivalate
Propionate
Sebacate
Succinate
Tetradecanoate (myristate)
Thioacetate
Trichloroacetate
Trifluoroacetate
1-Trifluoromethyl acetate
Trithiocarbonate
Undecanoate
Versatate
21.3.

MoI. wt.

Boiling
point (0C)

-CH=CHC(O)OH

19896-47-0

142.11

80/1

-C9H19
-(CH 2 ) 7 CH 3
-(CH 2 ) i 6 CH 3
-(CH2)7CH=CH(CH2)7CH3
-(CH 2 ) 6 CH 3
-CF2CF3
-(CH 2 ) 3 CH 3
-C(CH 3 ) 3
-CH 2 CH 3
-(CH 2 ) 8 C(O)OCH=CH 2
-CH 2 CH 2 C(O)OCH=CH 2
-(CH 2 ) I 2 CH 3
H 2 C=CHSC(O)CH 3
-CCl 3
-CF3
H 2 C=C(CF 3 )OC(O)CH 3
H 2 C=CHSC(S)SCH=CH 2
-(CH 2 ) 9 CH 3
-C(CH 3 ) 2 (CH 2 ) 5 CH 3

51000-52-3
6280-03-1
111-63-7
3896-58-0
818-44-0

198.31
184.28
310.51
308.49
170.25
190.08
128.17
128.17
100.12
254.33
170.16
254.41
102.15
189.43
140.06
154.09
134.24
212.33
198.31

216
133/50
181/2
145
79/7
58/560
132
112
95
142/3
50/3
152/3
115
38/5
42
86

109-53-5
37769-62-3
926-65-8
26256-87-1
1663-35-0
107-25-5
930-02-9
1623-05-8
766-94-9
6230-62-2
764-47-6

84.12
144.21
100.16
100.16
100.16
106.55
106.55
126.20
141.00
132.16
70.09
212.38
72.11
156.27
100.12
276.76
268.47
116.16
88.11
114.19
100.16
156.27
86.13
190.24
102.13
58.08
296.54
266.04
120.15
148.21
86.13

67
70/20
94
87
75
109
109
147
128
196
28
118
33
177
139
210
173/5
189
143
112
82
175
83
242
108
5
178/5
36
154
211
65

2235-00-9
1484-13-5
13162-05-5
3485-84-5
88-12-0
3195-78-6

139.20
193.25
71.08
173.17
1-11.14
99.10

128/21
154/3
210

36
65
-16
85

166

-36

5873-43-8
3377-92-2
105-38-4
10355-50-7
13416-90-5
5809-91-6
10340-63-3
7062-87-5
433-28-3
2247-91-8
930-35-8
49863-74-3

Melting
point (0C)

32
36

-81

15

48
125/8
60/1

ETHERS H 2 C=CHOR

Allyl
Butoxyethyl
/i-Butyl
2-Butyl
tert-Butyl
1 -Chloroethyl
2-Chloroethyl
Cyclohexyl
1,2-Dichloroethyl
Di(ethylene glycol)
Divinyl
Dodecyl
Ethyl
2-Ethylhexyl
Glycidyl
Hexachlorodivinyl
Hexadecyl
4-Hydroxybutyl
2-Hydroxyethyl
Isoamyl
Isobutyl
Isooctyl
Isopropyl
2-(2-Methoxyethoxy)ethyl
2-Methoxyethyl
Methyl
Octadecyl
Perfluoropropyl
Phenyl
1-Phenylethyl
Propyl
21.4.

CAS Registry
Number

Formula

-CH 2 CH=CH 2
-CH 2 CH 2 O(CH 2 ) 3 CH 3
-(CH 2 ) 3 CH 3
-CH(CH 2 CH 3 )CH 3
-C(CH 3 ) 3
-CHClCH 3
-CH 2 CH 2 Cl
-C6Hn
-CHClCH 2 Cl
-CH 2 CH 2 OCH 2 CH 2 OH
-CH=CH 2
-(CH 2 ) 11CH3
-CH 2 CH 3
-CH 2 CH(CH 2 CH 3 )(CH 2 ) 3 CH 3
-CH2CH(-O-)CH2
(Cl 2 C=CCl) 2 O
-(CH 2 )I 5 CH 3
-(CH 2 ) 4 OH
-CH 2 CH 2 OH
-CH 2 CH 2 CH(CH 3 ) 2
-CH 2 CH(CH 3 ) 2
-(CH 2 ) 5 CH(CH 3 ) 2
-CH(CH 3 ) 2
-(CH 2 CH 2 O) 2 CH 3
-CH 2 CH 2 OCH 3
-CH3
-(CH 2 )I 7 CH 3
F 2 C=CFOCF 2 CF 2 CF 3
-C6H5
-CH(C 6 H 5 )CH 3
-CH 2 CH 2 CH 3

3917-15-5
4223-11-4
111-34-2
4181-12-8
926-02-3
110-75-8
110-75-8
2182-55-0
929-37-3
109-93-3
765-14-0
109-92-2
103-44-6
3678-15-7
822-28-6
17832-28-9
764-48-7

-92

-70
-109

-101
-12
-116
-85

16
-33

-112
-140
-83
-123
27

-50

^-SUBSTITUTED H 2 C=CHR

-Caprolactam
-Carbazole
-Formamide
-Phthalimide
-Pyrolidone
-N-Methylacetamide

-NC 6 H10O
-NCi2H8
-NHC(O)H
-NC8H4O2
-NC4H6O
-N(CH 3 )C(O)CH 3

Density
(at 20 0 C)

Refractive
index (at 20 0 C)

Flash
point ( 0 C)

0.882
0.8689
0.904

1.4360
1.4291

0.8719

1.4256

0.866
0.9173

1.4050
1.4030

10
6

1.3170
1.3410

-31
2
> 110

RTECS
Number

83

R and S

FT-NMR

FT-IR

Merck

Beilstein

Fieser

2(3),1290
2(4),1045

1(1),719B

>110
>110

2(3),532

UF8575000

0.87

1.203
1.212

0.8
0.866
0.774
0.762
1.048
1.048
0.891
1.197
0.986
0.773
0.817
0.754
0.816
1.006
1.654

1.4109
1.4220
1.410
1.4558
1.3980
1.4380
1.4380
1.4540
1.4558/17
1.4480
1.3989
1.4382
1.3770
1.4280
1.4326

0.939
0.982
0.7826
0.7645

1.4440
1.4360
1.4072
1.3950

0.7534
0.990
0.8967
0.7511/0
0.821
1.53

1.3840
1.4390
1.4072
1.3730/0
1.440

<20
46
-9
-17
16
16
35
83
-30
>110
-45
52
35

1(1),745G

l(l),1030C

1(1),697F

1(1),933B

KH7175000
KN5950000

1(1),219C

1(1),332B

1(1),213D

KN6300000
KN6300000

1(1),221C
1(1),221C

1(1),336A
1(1),336A

1(1),213B
1(1),213B

1(1),219B

1(1),332A

1(1),212B

19(3),1598

1(4),2387

KM5495500

KO0710000
KO0175000

2(4),466

l(3),704B

11,2139
11,2139

1(3), 1863
1(2),473
1(2),473
6(3), 18
1(4),2398
1(4),2398

1,433
1(3),1864
17(5),8,12

85
48

KM5495000

-13

KO1300000

1(1),219D

1(3),278A

1(3),1862

KO2300000
RG0300000

1(1),219A

1(3),277C

1(3), 1857
l(4),2057

1(4),2518
l(2),520

-32
17
-56
177

1.5226
1.3908

1.029

11,235

-26

1(3),1859

101

1.014

1.4940

102

1.040
0.9600

1.5120
1.4835

94
60

FE6350000

1(2),2425E

1(3),161C

UY6107000
AC6475000

1(1),923K
1(1),891K

1(1),1288A
1(1),1242C

2(3),3207
20(2),282
21(1),363
l(l),790B
1(1),759C

4(3),442

1,697

TABLE 21.

cont'd

Name
21.5.

Formula

CAS Registry
Number

MoL wt.

Boiling
point (0C)

108.10
178.23
164.21
136.16
192.26
178.23
164.21
152.20
122.13
184.21
152.20

100/0.5
131/17
117/15
76/5
146/15
124/15
78/5
70/4
91/15
45/2
110/18

SULFONATES H 2 C=CHSO 3 R

Ethylene sulfonic acid

n-Amy\ ester
n-Butyl ester
Ethyl ester
n-Hexyl ester
Isoamyl ester
Isobutyl ester
Isopropyl ester
Methyl ester
Phenyl ester
rc-Propyl ester

-H
-(CH 2 ) 4 CH 3
-(CH 2 ) 3 CH 3
-CH 2 CH 3
-(CH 2 ) 5 CH 3
-(CH 2 ) 2 CH(CH 3 ) 2
-CH 2 CH(CH 3 ) 2
-CH(CH 3 ) 2
-CH3
-C6H5
-CH 2 CH 2 CH 3

1562-34-1

Melting
point (0C)

Density
(at 200C)

1.4003
1.087
1.122
1.183
1.050
1.082
1.190
1.132
1.248
1.165
1.156

Refractive
index (at 200C)

1.4493
1.4412
1.4416
1.431
1.4430
1.4415
1.426
1.4321
1.4316
1.426
1.4368

Flash
point (0C)

>110

RTECS
Number

Rand S

1(2),2219A

FT-NMR

l(2),1605A

FT-IR

1(3),1437A

Merck

Beilstein

6(3),651

Fieser

13,241