Natural Gas Condensate MSDS
Natural Gas Condensate MSDS
Natural Gas Condensate MSDS
419-421-3070 877-627-5463
2. COMPOSITION/INFORMATION ON INGREDIENTS
Natural Gas Condensate is a complex combination of hydrocarbons (predominantly C2 through C8) separated and/or condensed from natural gas during transportation, wellhead collection and/or from the production, gathering, transmission and distribution pipelines in drips, scrubbers, etc. Product information:
Name CAS Number Weight % ACGIH Exposure Limits: OSHA - Vacated PELs - Time Weighted Ave Other:
68919-39-1
100
Component Information:
Name CAS Number Weight % ACGIH Exposure Limits: OSHA - Vacated PELs - Time Weighted Ave Other:
C7-C8 Hydrocarbons
Mixture
40-90
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Name
CAS Number
Weight %
Other:
600 ppm TWA 600 ppm TWA = 1800 mg/m3 TWA = 600 ppm TWA = 2250 mg/m3 STEL = 750 ppm STEL = 1900 mg/m3 TWA = 800 ppm TWA
1000 ppm TWA 1000 ppm TWA Skin - potential significant contribution to overall exposure by the cutaneous route 0.5 ppm TWA 2.5 ppm STEL
OSHA Exposure Limit as specified in 1910.1028: =1.0 ppm TWA = 5 ppm STEL = 0.5 ppm Action Level
Notes:
The manufacturer has voluntarily elected to reflect exposure limits contained in OSHA's 1989 air contaminants standard in its MSDS's, even though certain of those exposure limits were vacated in 1992.
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Inhalation: Breathing high concentrations may be harmful. May cause central nervous system depression or effects. Symptoms may include headache, excitation, euphoria, dizziness, incoordination, drowsiness, light-headedness, blurred vision, fatigue, tremors, convulsions, loss of consciousness, coma, respiratory arrest and death, depending on the concentration and duration of exposure. Breathing high concentrations of this material, for example, in a confined space or by intentional abuse, can cause irregular heartbeats which can cause death. See Toxicological Effects (Section 11) for more information. Ingestion: Swallowing this material may be harmful. May cause irritation of the mouth, throat and gastrointestinal tract. May cause central nervous system depression or effects. Symptoms may include salivation, pain, nausea, vomiting and diarrhea. Exposure may also cause central nervous system symptoms similar to those listed under "Inhalation" (see Inhalation section). Skin contact: Contact may cause reddening, itching and inflammation. Skin contact may cause harmful effects in other parts of the body. Eye contact: Contact may cause pain and severe reddening and inflammation of the conjunctiva. Effects may become more serious with repeated or prolonged contact. Carcinogenic Evaluation: Product information:
Name Marathon Natural Gas - Condensate C2-C8 68919-39-1 IARC Carcinogens: NE NTP Carcinogens: ACGIH Carcinogens: OSHA - Select Carcinogens:
Notes:
The International Agency for Research on Cancer (IARC) has determined that there is limited evidence for the carcinogenicity of naphtha (light straight run and light catalytic cracked) in experimental animals.
Component Information:
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NTP Carcinogens: Known Human Carcinogen male rat-clear evidence; female rat-clear evidence; male mice-clear evidence; female mice-clear evidence
Notes:
The International Agency for Research on Cancer (IARC), the National Toxicology Program (NTP), and OSHA have determined that there is sufficient evidence for the carcinogenicity of benzene in humans (Group 1A).
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Specific hazards:
Flash point: Autoignition temperature: Flammable limits in air - lower (%): Flammable limits in air - upper (%): NFPA rating: Health: 2 Flammability: 3 Instability: 1 Other: -
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Colorless Liquified Gas Liquid Mixture Clear Hydrocarbon Not determined. Neutral -127 to 257 F Not determined. Not applicable. 0.3-0.7 Liquid 2.5-5.8 lbs/gal No data available. 1.0-3.9 Not determined. No data available. Soluble
Product name: Marathon Natural Gas Condensate C2-C8 Page 6 of 15
Toxicology Information:
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NAPHTHAS: In a large epidemiological study on over 15,000 employees at several petroleum refineries and amongst residents located near these refineries, no increased ricks of kidney cancer was observed in association with gasoline exposures (a similar material). In another similar study, no increased risk of kidney cancers among service station employees, especially after a 30-year latency period. BENZENE: Studies of Workers Overexposed to Benzene: Studies of workers exposed to benzene show clear evidence that overexposure can cause cancer and other diseases of the blood forming organs including Acute Myelogenous Leukemia (AML), and Aplastic Anemia (AA), an often fatal disease. Some studies suggest overexposure to benzene may also be associated with Myelodysplastic Syndrome (MDS). Findings from a Case-Control study of workers exposed to benzene was reported during the 2009 Benzene Symposium in Munich included an increase in Acute Myeloid Leukemias and Non-Hodgkins Lymphoid Neoplasms (NHLN) of the subtype follicular lymphoma (FL) in some occupational categories. Some studies of workers exposed to benzene have shown an association with increased rates of chromosome aberrations in circulating lymphocytes. One study of women workers exposed to benzene suggested a weak association with irregular menstruation. However, other studies of workers exposed to benzene have not demonstrated clear evidence of an effect on fertility or reproductive outcome in humans. Benzene can cross the placenta and affect the developing fetus. Cases of AA have been reported in the offspring of persons severely overexposed to benzene. Studies in laboratory animals indicate that prolonged, repeated exposure to high levels of benzene vapor can cause bone marrow suppression and cancer in multiple organ systems. Studies in laboratory animals show evidence of adverse effects on male reproductive organs following high levels of exposure but no significant effects on reproduction have been observed. Embryotoxicity has been reported in studies of laboratory animals but effects were limited to reduced fetal weight and minor skeletal variations. Benzene has been classified as a proven human carcinogen by OSHA and a Group 1 (Carcinogenic to Humans) material by IARC. The current proposed IARC classification for benzene is summarized as follows: Sufficient evidence for Acute Myeloid Leukemia; limited evidence for Acute Lymphatic Leukemia, Chronic Lymphatic Leukemia, Non-Hodgkin Lymphoma, and Multiple Myeloma. PENTANES: Studies of pentane isomers in laboratory animals indicate exposure to extremely high levels (roughly 10 vol.%) may induce cardiac arrhythmias (irregular heartbeats) which may be serious or fatal. BUTANES: Studies in laboratory animals indicate exposure to extremely high levels of butanes (1-10 or higher vol.% in air) may cause cardiac arrhythmias (irregular heartbeats) which may be serious or fatal. PROPANE: Studies in laboratory animals indicate exposure to extremely high levels of propane (1 to 10 vol.% in air) may cause cardiac arrhythmias (irregular heartbeats) which may be serious or fatal. Altered mental state, drowsiness, peripheral motor neuropathy, irreversible brain damage (so-called Petrol Sniffers Encephalopathy), delirium, seizures, and sudden death have been reported from repeated overexposure to some hydrocarbon solvents, naphthas, and gasoline. TARGET ORGANS: central nervous system, heart, eyes, skin, liver, kidney, blood bone marrow,
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EPA Superfund Amendment & Reauthorization Act (SARA): SARA Section 302:
Name C7-C8 Hydrocarbons C9 Hydrocarbons C6 Hydrocarbons Iso-Pentane C10 Hydrocarbons Normal Pentane Normal Butane Iso-Butane C1-C3 Hydrocarbons Benzene
This product contains the following component(s) that have been listed on EPA's Extremely Hazardous Substance (EHS) List:
CERCLA/SARA - Section 302 Extremely Hazardous Substances and TPQs NA NA NA NA NA NA NA NA NA NA
This product contains the following component(s) identified either as an EHS or a CERCLA Hazardous substance which in case of a spill or release may be subject to SARA reporting requirements:
CERCLA/SARA - Hazardous Substances and their Reportable Quantities NA NA NA NA NA NA NA NA NA = 10 lb final RQ = 4.54 kg final RQ
Name C7-C8 Hydrocarbons C9 Hydrocarbons C6 Hydrocarbons Iso-Pentane C10 Hydrocarbons Normal Pentane Normal Butane Iso-Butane C1-C3 Hydrocarbons Benzene
The following EPA hazard categories apply to this product: Acute Health Hazard Chronic Health Hazard Fire Hazard Sudden Release Of Pressure
This product contains the following component(s) that may be subject to reporting on the Toxic Release Inventory (TRI) From R:
CERCLA/SARA 313 Emission reporting: None None None Product name: Marathon Natural Gas Condensate C2-C8 Page 10 of 15
Name Iso-Pentane C10 Hydrocarbons Normal Pentane Normal Butane Iso-Butane C1-C3 Hydrocarbons Benzene
CERCLA/SARA 313 Emission reporting: None None None None None None = 0.1 % de minimis concentration
State and Community Right-To-Know Regulations: The following component(s) of this material are identified on the regulatory lists below: C7-C8 Hydrocarbons Louisiana Right-To-Know: California Proposition 65: New Jersey Right-To-Know: Pennsylvania Right-To-Know: Massachusetts Right-To Know: Florida substance List: Rhode Island Right-To-Know: Michigan critical materials register list: Massachusetts Extraordinarily Hazardous Substances: California - Regulated Carcinogens: Pennsylvania RTK - Special Hazardous Substances: New Jersey - Special Hazardous Substances: New Jersey - Environmental Hazardous Substances List: Illinois - Toxic Air Contaminants New York - Reporting of Releases Part 597 List of Hazardous Substances: C9 Hydrocarbons Louisiana Right-To-Know: California Proposition 65: New Jersey Right-To-Know: Pennsylvania Right-To-Know: Massachusetts Right-To Know: Florida substance List: Rhode Island Right-To-Know: Michigan critical materials register list: Massachusetts Extraordinarily Hazardous Substances: California - Regulated Carcinogens: Pennsylvania RTK - Special Hazardous Substances: New Jersey - Special Hazardous Substances: New Jersey - Environmental Hazardous Substances List: Illinois - Toxic Air Contaminants New York - Reporting of Releases Part 597 List of Hazardous Substances: C6 Hydrocarbons Louisiana Right-To-Know: California Proposition 65: New Jersey Right-To-Know:
MSDS ID NO.: 0197MAR001
Not Listed Not Listed Not Listed. Not Listed. Not Listed. Not Listed. Not Listed Not Listed. Not Listed Not Listed Not Listed Not Listed Not Listed Not Listed Not Listed
Not Listed Not Listed Not Listed. Not Listed. Not Listed. Not Listed. Not Listed Not Listed. Not Listed Not Listed Not Listed Not Listed Not Listed Not Listed Not Listed
C7-C8 Hydrocarbons Pennsylvania Right-To-Know: Massachusetts Right-To Know: Florida substance List: Rhode Island Right-To-Know: Michigan critical materials register list: Massachusetts Extraordinarily Hazardous Substances: California - Regulated Carcinogens: Pennsylvania RTK - Special Hazardous Substances: New Jersey - Special Hazardous Substances: New Jersey - Environmental Hazardous Substances List: Illinois - Toxic Air Contaminants New York - Reporting of Releases Part 597 List of Hazardous Substances: Iso-Pentane Louisiana Right-To-Know: California Proposition 65: New Jersey Right-To-Know: Pennsylvania Right-To-Know: Massachusetts Right-To Know: Florida substance List: Rhode Island Right-To-Know: Michigan critical materials register list: Massachusetts Extraordinarily Hazardous Substances: California - Regulated Carcinogens: Pennsylvania RTK - Special Hazardous Substances: New Jersey - Special Hazardous Substances: New Jersey - Environmental Hazardous Substances List: Illinois - Toxic Air Contaminants New York - Reporting of Releases Part 597 List of Hazardous Substances: C10 Hydrocarbons Louisiana Right-To-Know: California Proposition 65: New Jersey Right-To-Know: Pennsylvania Right-To-Know: Massachusetts Right-To Know: Florida substance List: Rhode Island Right-To-Know: Michigan critical materials register list: Massachusetts Extraordinarily Hazardous Substances: California - Regulated Carcinogens: Pennsylvania RTK - Special Hazardous Substances: New Jersey - Special Hazardous Substances: New Jersey - Environmental Hazardous Substances List:
MSDS ID NO.: 0197MAR001
Not Listed. Not Listed. Not Listed. Not Listed Not Listed. Not Listed Not Listed Not Listed Not Listed Not Listed Not Listed Not Listed
Not Listed Not Listed sn 1064 Present Present Not Listed. Not Listed Not Listed. Not Listed Not Listed Not Listed flammable - fourth degree SN 1064 TPQ 500 lb Not Listed Not Listed
Not Listed Not Listed Not Listed. Not Listed. Not Listed. Not Listed. Not Listed Not Listed. Not Listed Not Listed Not Listed Not Listed Not Listed
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C7-C8 Hydrocarbons Illinois - Toxic Air Contaminants New York - Reporting of Releases Part 597 List of Hazardous Substances: Normal Pentane Louisiana Right-To-Know: California Proposition 65: New Jersey Right-To-Know: Pennsylvania Right-To-Know: Massachusetts Right-To Know: Florida substance List: Rhode Island Right-To-Know: Michigan critical materials register list: Massachusetts Extraordinarily Hazardous Substances: California - Regulated Carcinogens: Pennsylvania RTK - Special Hazardous Substances: New Jersey - Special Hazardous Substances: New Jersey - Environmental Hazardous Substances List: Illinois - Toxic Air Contaminants New York - Reporting of Releases Part 597 List of Hazardous Substances: Normal Butane Louisiana Right-To-Know: California Proposition 65: New Jersey Right-To-Know: Pennsylvania Right-To-Know: Massachusetts Right-To Know: Florida substance List: Rhode Island Right-To-Know: Michigan critical materials register list: Massachusetts Extraordinarily Hazardous Substances: California - Regulated Carcinogens: Pennsylvania RTK - Special Hazardous Substances: New Jersey - Special Hazardous Substances: New Jersey - Environmental Hazardous Substances List: Illinois - Toxic Air Contaminants New York - Reporting of Releases Part 597 List of Hazardous Substances: Iso-Butane Louisiana Right-To-Know: California Proposition 65: New Jersey Right-To-Know: Pennsylvania Right-To-Know: Massachusetts Right-To Know: Florida substance List: Rhode Island Right-To-Know: Michigan critical materials register list:
Not Listed Not Listed sn 1476 Present Present Not Listed. Toxic; Flammable Not Listed. Not Listed Not Listed Not Listed flammable - fourth degree SN 1476 TPQ 500 lb Not Listed Not Listed
Not Listed Not Listed sn 0273 Present Present Not Listed. Toxic; Flammable Not Listed. Not Listed Not Listed Not Listed flammable - fourth degree SN 0273 TPQ 500 lb Not Listed Not Listed
Not Listed Not Listed sn 1040 Present Present Not Listed. Not Listed Not Listed.
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C7-C8 Hydrocarbons Massachusetts Extraordinarily Hazardous Substances: California - Regulated Carcinogens: Pennsylvania RTK - Special Hazardous Substances: New Jersey - Special Hazardous Substances: New Jersey - Environmental Hazardous Substances List: Illinois - Toxic Air Contaminants New York - Reporting of Releases Part 597 List of Hazardous Substances: C1-C3 Hydrocarbons Louisiana Right-To-Know: California Proposition 65: New Jersey Right-To-Know: Pennsylvania Right-To-Know: Massachusetts Right-To Know: Florida substance List: Rhode Island Right-To-Know: Michigan critical materials register list: Massachusetts Extraordinarily Hazardous Substances: California - Regulated Carcinogens: Pennsylvania RTK - Special Hazardous Substances: New Jersey - Special Hazardous Substances: New Jersey - Environmental Hazardous Substances List: Illinois - Toxic Air Contaminants New York - Reporting of Releases Part 597 List of Hazardous Substances: Benzene Louisiana Right-To-Know: California Proposition 65:
Not Listed Not Listed Not Listed flammable - fourth degree SN 1040 TPQ 500 lb Not Listed Not Listed
Not Listed Not Listed Not Listed. Not Listed. Not Listed. Not Listed. Not Listed Not Listed. Not Listed Not Listed Not Listed Not Listed Not Listed Not Listed Not Listed
New Jersey Right-To-Know: Pennsylvania Right-To-Know: Massachusetts Right-To Know: Florida substance List: Rhode Island Right-To-Know: Michigan critical materials register list: Massachusetts Extraordinarily Hazardous Substances: California - Regulated Carcinogens: Pennsylvania RTK - Special Hazardous Substances: New Jersey - Special Hazardous Substances: New Jersey - Environmental Hazardous Substances List: Illinois - Toxic Air Contaminants New York - Reporting of Releases Part 597 List of Hazardous Substances: Canadian Regulatory Information:
MSDS ID NO.: 0197MAR001
Not Listed carcinogen, initial date 2/27/87 developmental toxicity, initial date 12/26/97 male reproductive toxicity, initial date 12/26/97 sn 0197 Environmental hazard; Special hazardous substance Carcinogen; Extraordinarily hazardous Not Listed. Toxic (skin); Flammable (skin); Carcinogen (skin) = 100 lb Annual usage threshold carcinogen; extraordinarily hazardous Not Listed Present carcinogen; flammable - third degree; mutagen; teratogen SN 0197 TPQ 500 lb Present = 1 lb RQ land/water = 10 lb RQ air
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This product and/or its components are listed either on the Domestic Substances List (DSL) or are exempt.
Canada - WHMIS: Classifications of Substances: B2 B2 A, B1 A, B1 B2, D2A, D2B Canada - WHMIS: Ingredient Disclosure: 1% 1% 0.1 %
NOTE:
Not Applicable.
The information and recommendations contained herein are based upon tests believed to be reliable. However, Marathon Oil Company (MOC) does not guarantee their accuracy or completeness nor shall any of this information constitute a warranty, whether expressed or implied, as to the safety of goods, the merchantability of the goods, or the fitness of the goods for a particular purpose. Adjustment to conform to actual conditions of usage maybe required. Marathon assumes no responsibility for results obtained or for incidental or consequential damages, including lost profits arising from the use of these data. No warranty against infringement of any patent, copyright or trademark is made or implied. End of Safety Data Sheet
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