FORM 3 SULPHUR AND ITS COMPOUNDS ANS Teacher - Co - .Ke

Sulphur and its compounds
1. (a) Frasch process

(b) Hot compressed air
(c) Monoclinic / prismatic sulphur /beta sulphurP
Rhombic/octahedral sulphur /alpha sulphur P
2. (a) RFM of H2SO3 = 98 (no units)
Number of moles of H2SO4 = 1.8
98
= 0.01837moles
Molarity of H2SO4 = 0.01837 x 1000
1
= 18.37M P½
(b) Apply formular; M conc. X Vol conc. = Mdil. x Vdil.

18.37 x V conc: = 0.2 x 500 Vconc. = 0.2 x 500
18.37
= 5.44cm of conc. H2SO4
3
3. (a) By dissolving in water

(b) – Manufacture of fertilizers
- Manufacture of detergents
- Cleaning of metal surfaces
- As an electrolyte in car batteries
- In refining of petroleum
- Manufacture of synthetic fibre (e.g. rayon)
- Manufactures of paints, dyes and explosives (award 1mk any one)
4. Chlorine bleaches permanently by oxidation p1 while sulphur (IV) oxide bleaches

temporary by eduction. p1
5. (i) Weak acid p1

(ii) Has few free H+ (Hydrogen) ions
6. a) Vanadium (v) oxide V2OS Ö ½
b) 2SO2 (g) + O2 (g) ________ 2SO3 (g) Ö ½
c) SO3 (g) + H2 SO4 (l) _____ H2S2O7 (l)
H2S2O7(L) + H2 O (L) _________ H2SO4(l)

Student must explain Explanation 1 mark
7. – Concentrated sulphuric acid oxidizes copper turnings to copper(II) oxide black solid,SO2
gas and water. ½ mk
- Then copper (II) oxide reacts excess conc. sulphuric acid to produce copper (II) sulphate mk
- Which is dehydrated by conc. Sulphuric acid to an hydrous copper (II) sulphate white solid 1½
Which dissolves in water to produce blue solution
8. a) Method of collection is wrong. √½ Should be collected by downward delivery/upward

displacement of air √½ since the gas is denser than air.
b) Na2SO3(s) + H2SO4(aq) Na2SO4(aq) + SO2(g) + H2O(l) √1
c) By passing it through calcium hydroxide in which the gas dissolves. √1
9. a) Dirty grey solids are formed. √1

b) FeS(s) + 2HCl (aq) FeCl2(aq) √1 + H2S(g)
c) Iron powder has high surface area hence the reaction is none vigorous than iron fillings
with low surface area.
10. a)a sulphate e.g. sodium sulphate√1

b)moist blue litmus paper turns to red√ ½ then after some minutes to white√ ½ .it is bleached by
sulphur(iv)oxide
SO2(g) + H2O(l) +Dye H2SO4(aq) + (Dye-o)√1
(litmus) (white)
11. (a) – FlexibleP/elastic

1
- Strong and
P 1tough
P1
- Non-sticky (any two)
P½ P½
(b) Molten sulphur would have lost heat to the surrounding hence solidify/ in the middle pipe
P ½ cannot solidify since hot air in the inner pipe and hot water in the outer pipe
sulphur
mountains high temperature.
12. (a) It dissolves in water releasing √1 a lot of heat which boils the acid which
can easily be spilt to the body. √1 (2 mks)
(b) - It is used in manufacture √1 of batteries/acid accumulators. Any 3
- Manufacture of soap, plastics, detergents. one
13. (a) Deposits of a yellow solid; and droplets of colourless liquid;

(b) 2H2S(aq) + SO(g) 2H2O(l) + 3S(s)
(c) Oxidizing agent
14. (a) A – takes in hot compressed air to force out molten sulphur to the surface.
B - takes out molten sulphur.
C – takes in super heated water to melt the sulphur.
(b) Rhombic, Monoclinic
(c) S(s) + O2(g) SO2(g)
(d) Iron (II) sulphide.
(e) – Vulcanization of rubber.

- Making chemicals
- Manufacture of matches and fire works.
(f) (i) 2SO2(g) + O2(g) 2SO3(g)

(ii) 24 dm3 of SO2 = 1 mole
6.0 dm3 1 mol x 6 dm3 p ½ = 0.25 mole p ½

24 dm3
From the equation :-
Moles of O2 used = 0.25 p½ = 0.125 moles p½
2
(iii) 1 mole of O2 = 0.125
0.25 mole = 24 dm3 x 0.125 mol p1

1 mol
= 3. dm3 p1
15. i) X – Rhombic √½
Y – Monoclinic √½
ii) I) Mg has a higher √1 √1 affinity for combined oxygen than S.
II) Add √1 dilute nitric acid to the mixture. It reacts with MgO√1 to form Mg (NO3)2
Filter √1 to obtain S as residue.
16. (a) (i) – Rhombic sulphur (½ mk)

(ii) Sulphur is heated until it boils. The boiling liquid sulphur is then poured into a beaker
containing water to form plastic sulphur ( ½ mk)
(a)
() – sulphur (½ mk)
- Iron (II) Sulphide (Iron pyrites)
- Zinc sulphide (Zinc blend)
- Dust or Arsenic compounds (½ mk)
(c) – Avoid poisoning of the catalyst (Avoid destruction of catalytic properties by impurities)
(d) 25O2(g) + O2(g) 2SO3(g)
(e) (I) – Vanadinim (V) Oxide ( ½ mk)

(II) - Heat incoming air (SO2 & Air)
- Cools the SO3
(III) - The reaction between SO2 and water is highly exothermic which makes the solution boil
to form a mist of dilute sulphuric (VI) acid which pollutes the environment
(g) I. – SO2
II- Un reacted SO2 is recycled
o Absorbed by Ca(OH)2 in tall chimneys
- Passed over hot carbon (IV) Oxide and sulphur which is recycled and Carbon (IV) Oxide
released to the environment
(h) Manufacture of fertilizers
17. a) (i)
(ii) I ion II sulphide or copper II Sulphur

II anhydrous Calcium Chloride (zero of Calcium chloride)
III Fe s(l) + Hcl(aq) Fecl2(aq) + H2s
b) Fe3+ is reduced or Fe2+ or Fe2+(aq) ions and formed
H2S is oxidized to sulphur on sulphur is formed.
c) (i) Vanadium V oxide or platinised asbestos
(ii) I. The yield of SO3 increase because increase in pressure favour the forward reaction
since less number of SO3
II. The yield of SO3 is the same because catalyst only speeds the rate at which equibrium.
(iii) Exothermic reaction occurs. When dissolved in water produce acid spray (fumes) cause
pollution.
18 (a) (i) Red-brown fumes

(ii) It is not an oxidizing agent
(iii) S(s) + 6HNO3(l) 2H2O(l) + 6NO2(g) + H2SO4(l)
(iv) Neutralization
(v) Sulphuric acid
(vi) Forms acid rain / plant + yellowing corrodes metallic and stone works
19. a) i) They are different physical/ structural forms of an element
ii) Trausition temperature

b) i) X - Diluter
Y- Heat exchanger
Z- Roaster/ Burner
ii) Catalyst- Vanadium (v) Oxide, V2O5

Temperature – 450C
Pressure – 1 atmosphere
iii) I - They are purified not to poison the catalyst

II - The reaction in the convertor/ production of sulphur (vi) Oxide is exothermic/
heat is produced. Chamber Y is used to ensure temperature does not rise above 450oC
iv) Step 2: 2502(g) +O2(g) ____________2503(g) Ö 1 mark

Step 3: 503(g) + H2SO4(L) __________ H252O7(l Ö 1 mark
Step 4: H2S2O7(L) + H2O(L) _________ 2H2SO4(L) Ö 1 mark
20. - Test tube L- Acidified KMnO4 changed from purple to colourless (it is decolourized) – SO2 is a
P1
reducing agent. P1 P1
- Test tube K Hal+/KMnO4 was not decoloured – SO2 was absorbed by ash solution hence did not
reach the H+/KMnO4.
21. a) Metal sulphide

b) Hydrogen sulphide is less soluble in warm water compared to cold water
22. SO2 form acidic when it dissolves in atmospheric moisture. The acidic rain lowers soil PH/
corrodes stone building
No – disrupts the Ozone cycle hence causing depletion of Ozone layer which react with
oxygen in the atmosphere to form NO2 gas
23. a) The solution changed from brown/yellow p½ to light/pale green p½

b) 2FeCl(aq) + H2S(g) 2FeCl2(aq) + 2HCl(aq) + S(s) p1 mk
c) Oxidation. p1 mk
24. Barium carbonate reacts with dilute sulphuric (VI) acid to form the insoluble Barium
sulphate (BaSO4) which coversPthe reactant. Barium Carbonate preventing any contact
between the acid and the Carbonate salt.
Hence, the reaction is slow and stops after a very short time.
BaCO3(s) = H2SO4(aq) BaSO4(s) + CO2(g) + H2O(l)

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Sulphur and its compounds

1. (a) Frasch process

(b) Apply formular; M conc. X Vol conc. = Mdil. x Vdil.

3. (a) By dissolving in water

4. Chlorine bleaches permanently by oxidation p1 while sulphur (IV) oxide bleaches

5. (i) Weak acid p1

6. a) Vanadium (v) oxide V2OS Ö ½

b) 2SO2 (g) + O2 (g) ________ 2SO3 (g) Ö ½

c) SO3 (g) + H2 SO4 (l) _____ H2S2O7 (l)

H2S2O7(L) + H2 O (L) _________ H2SO4(l)

8. a) Method of collection is wrong. √½ Should be collected by downward delivery/upward

9. a) Dirty grey solids are formed. √1

10. a)a sulphate e.g. sodium sulphate√1

11. (a) – FlexibleP/elastic

13. (a) Deposits of a yellow solid; and droplets of colourless liquid;

(b) Rhombic, Monoclinic

(c) S(s) + O2(g) SO2(g)

(d) Iron (II) sulphide.

(e) – Vulcanization of rubber.

(f) (i) 2SO2(g) + O2(g) 2SO3(g)

6.0 dm3 1 mol x 6 dm3 p ½ = 0.25 mole p ½

(iii) 1 mole of O2 = 0.125

0.25 mole = 24 dm3 x 0.125 mol p1

16. (a) (i) – Rhombic sulphur (½ mk)

(e) (I) – Vanadinim (V) Oxide ( ½ mk)

(ii) I ion II sulphide or copper II Sulphur

18 (a) (i) Red-brown fumes

19. a) i) They are different physical/ structural forms of an element

ii) Trausition temperature

ii) Catalyst- Vanadium (v) Oxide, V2O5

iii) I - They are purified not to poison the catalyst

iv) Step 2: 2502(g) +O2(g) ____________2503(g) Ö 1 mark

21. a) Metal sulphide

23. a) The solution changed from brown/yellow p½ to light/pale green p½

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