JAI GURU DEV

Unit 1 2 3 4

Weightage marks 25 20 20 25 25 25 15 25 30 20 230

Part - I 1 marks MCQ 4 1 2 4 4 4 2 4 3 2 30

5X1=5

Part - II 3 marks VSA 2 3 1 2 2 2 1 2 4 1 20

5 X 3 = 15

Part - III 5 marks SA 1 2 1 1 1 1 2 1 1 1 12 3 X 5 = 15

Part - IV 10 marks LA 1 0 1 1 1 1 0 1 1 1 8

SGK Study Material

+2 Chemistry (6th Edition) +2 Physics (4th Edition)
2010-2011
To Download the E-B ook version of this material, visit: http://www.froomple.com (No Charges will be taken for d ownloading. Its completely free.)

5 6 7 8 9 10 Total

Maximum no of problems

Numerical problems total marks: 5 + 15+ 15 = 35

Note: Only some important 1, 3, 5 & 10 mark questions given from all units in this material.

One mark questions

Unit-1. ELECTRO STATICS
Total no of one mark questions from this chapter- 4 Hint Normally March question papers 2 question from Text book self evaluation only.

Sl. No
1 2 3 4 5 6 7 8 9 10

UNITS
ELECTROSTATICS CURRENT ELECTRICITY EFFECTS OF ELECTRICITY CURRENT ELECTRO MAGNETIC INDUCTION AND A/C ELECTRO MAGNETIC WAVES AND WAVE OPTICS ATOMIC PHYSICS DUAL NATURE NUCLEAR PHYSICS SEMI CONDUCTOR DEVICES COMMUNICATION SYSTEMS

No. of Qus. 30 4 1 2 4 4 4 2 4 3 2

Q.No 1, 2, 3, 4 5 6, 7

1.Book Questions: (Refer Page No.40-42)

1. 2. A glass rod rubbed with silk acquires a charge of +8 10-12 C. The number of electrons it has gained or lost 5 x 10 7 lost The electro static force between two point charges kept at distance d apart, in a medium r = 6, is 0.3 N. The force between them at the same separation in vacuum is 1.8 N Electric field intensity is 400 Vm-1 at a distance of 2m from a point charge. It will be 100 Vm-1 at a distance 4 m (Mar 07) Two point charges +4q and +q are placed 30cm apart. At what point on the line joining them the electric field is zero? 20 cm from the charge 4q A dipole is placed in a uniform electric field with its axis parallel to the field. It experiences neither a net force nor a torque
(Mar 06, 07 & 08, Oct 07)

3.
8, 9, 10, 11

4.
12, 13, 14, 15 16, 17, 18, 19 20, 21 22, 23, 24, 25 26, 27, 28 29, 30

5.

6. 7.

A If a point lies at a distance x from the midpoint of the dipole, the electric potential at this point is proportional to Four charges +q, +q, -q and q respectively are placed at the corners A, B, C and D of a square of side a. the electric potential at the centre O of the square is zero (Oct 06)

8. 9.

Electric potential energy (U) of two point charges is

June 10)

(Mar 09,

3. 4. 5. 6.

The work done in moving 500c charge between two points on equipotential surface is zero (June 07,10, Mar 08,10) 10. Which of the following quantities is scalar? Electric potential 11. The unit of permittivity is C2 N -1 12. The number of electric lines of force originating from a charge of 1micro coulomb is 1.129 x 10 11 13. The electric field outside the plates of two oppositely charged plane sheets of charge density is zero (Mar 06, Oct 09) 14. The capacitance of a parallel plate capacitor increase from 5F to 60F when a dielectric is filled between the plates. The dielectric constant of the dielectric is 12 (June 08, Oct 10) 15. A hollow metal ball carrying an electric charge produced no electric field at inside the sphere points. (June 06, Mar 10)
(June 06 & 08, Mar 09) -2 m (Oct 06, 08)

7. 8. 9.

The relative permittivity of air is 1 The particle which cannot be accelerated by van- de- Graaff generator is electron An electric dipole is kept in a non-uniform electric field it experiences a force and a torque (Mar 08) The work done in moving 4c charge from one point to another in an electric field is 0.012J. The potential difference between them is 3000 V (Mar 06, Oct 09) Torque on a dipole in a uniform electric field is maximum when angle between P vector and E vector is 90 (June 06,Oct 09) Potential energy of 2 equal negative point charges of magnitude 2c placed 1 m apart in air is 0.036J (June 06) The value of permittivity of free space is
(Oct 06)

10. The principle used in lightning conductors is corona discharge

(Oct 06)

11. Unit of electric dipole moment is Coulomb / metre (c /m)

(Mar 07)

2. Additional Questions:
Note: Prepare one marks from frictional electricity, coulombs law,

electric field, electric lines of force, electric field intensity, dipole in uniform electric field, electric potential energy and equipotential surface, gauss law and its applications, dielectric and polarization effect, capacitor in series and parallel and Van De Graff generator and Prepare unit based questions for Electric field intensity, electric fluc, permittivity, capacitance, electric dipole moment etc. 1. The unit of electric field intensity is NC-1 (or) VM -1 2. The unit of electric flux is
(Oct-06, June-08, Mar 09) Nm2 C-1 (Mar 06, June 09)

12. Which is not a dielectric Gold (June 07) 13. The electric potential energy of an electric dipole in an electric field is PE cos. (Mar 07) 14. The direction of electric field at a point on the equatorial line due to an electric dipole is Parallel to the axis of the dipole and opposite to the direction of dipole moment (June 07) 15. When an electric dipole of dipole moment P is aligned parallel to the electric field E then the potential energy of the dipole is given as -PE (June 08) 16. A capacitor of capacitance 6F is connected to a 100 V battery. The energy stored in the capacitor is 0.03J (Mar 08)

17. The equivalent capacitance of 2 capacitors in series is 1.5. The capacitance of one of them is 4. The value of capacitance of the other is 2.4 (Oct 07 & 09) 18. The law that governs the force between electric chargers is Coulombs law (Oct 07) 19. Quantization of electric charge is given by q = ne (Oct 08) 20. An example of conductor is human body (Oct 08) 21. The magnitude of the force acting on a charge of 2 x 10 -10C placed in a uniform electric field of 10 Vm-1 is 2x10-9N (Mar 09) 22. The torque ( ) experienced by an electric dipole placed in a uniform electric field (E) at an angle () with the field is PE sin
(June 09)

field. The direction of the torque is Perpendicular to the plane containing Vector p and E. (Mar 10) 31. Electric field intensity at a distance r due to a infinitely long straight charged wire is directly proportional to 1/r. (June 10) 32. The ratio of electric potential at point 10cm and 20cm from the centre of an electric dipole along its axial line is 4:1. (June 10) 33. Capacitance of a capacitor is directly proportional to charge and inversely proportional to potential (Oct 10)

Unit-2. CURRENT ELECTRICITY

Total of one mark questions from this chapter -1 Hint Normally less chance from Text book self evaluation.

23. The negative gradient of potential is electric field intensity

(June 09, Oct 10)

24. When a point charge of 6C is moved between 2 points in an electric field, the work done is 1.8 x 10 -5J. the potential difference between the 2 points is 3V (Oct 09) 25. Van de Graaff generator is used to accelerate both protons and deuterons. 26. If the total charged bodies of charge +3q and -9q are brought in contact, the total charge of the system is -6q (Oct 07) 27. The number of electric lines of force originating from a charge of 1micro coulomb is 1.129 x 105 (Oct 07) 28. The capacitance of a parallel plate capacitor increases from 5F and 50F, when the dielectric is filled between the plates, the dielectric constant of the dielectric is 10. (June 09) 29. 3 Capacitor of capacitance, 1F, 2f, 3F, are connected in series. The effective capacitance of a capacitor is 6/11F. (Mar 10) 30. An electric dipole of moment vector p is placed in a uniform electric field of intensity vector E at an angle with respect to the

1. Book Questions: (Refer Page No.74-75)

1. 2. 3. 4. 5. A charge of 60 C passes through an electric lamp in 2 minutes. Then the current in the lamp is 0.5 A The material through which electric charge can flow easily is Copper (Oct 07) The current flowing in a conductor is proportional to drift velocity A toaster operating at 240V has a resistance of 120. The power is480 W (June 10) If the length of a copper wire has a certain resistance R, then on doubling the length is specific resistance will remain the same
(Oct 06, June 08, Oct 09, Mar 10) When two 2 resistances are in parallel, the effective is 1 (Oct-08)

6. 7.

In the case of insulators, as the temperature decreases, resistivity increases (Mar 08 & 09)

8.

If the resistance of a coil is 2 at 0C C, then its resistance at 100C is 2.8 9. According to Faradays law of electrolysis, when a current is passed, the moss of ions deposited at the cathode is independent of resistance 10. When n resistors of equal resistance (R) are connected in series, the effective resistance is nR.

2. Additional Questions:
Note: Prepare one mark from Drift velocity, current density, super conductivity, combination of resistors, temperature dependence of a resistance, internal resistance of a cell, Wheatstone bridge, metrebridge, potentiometer, Faradays law, electric cell, and prepare unit based questions for current, mobility, current density, resistance, conductance, specific resistance, electric energy, electrochemical equivalence etc.. 1. 2. 3. 4. 5. Expression for current density is J = 1/ A The unit of conductance is mho Which of the following is conducting current? Tungsten. Transition temperature of mercury is 4.2 K. (June 09) In carbon resistors, silver rings indicates 10% variation of resistance 6. Example for secondary cell is Lead Acid accumulator 7. The unit of conductivity is mho m -1 (June 07) 8. Resistance of metal wire of length 10cm is 2. If the wire is stretched uniformly to 50cm the resistance is 50 (Mar 06) 9. The colour code on a carbon resister is red red black. The resistance of the resistor is 22 (June 06) 10. The brown ring at one end of a carbon resistor indicates a tolerance of 1% (Mar 07)

11. Drift Velocity in metals is the order of 0.1 cms-1 12. Drift Velocity is directly proportional to electric field intensity. 13. Unit of current density is Am-2 . 14. Unit of resistivity is ohm m. 15. The resistance of mercury at 4.2K is zero 16. The cell which supplies intermittent current is Leclanche cell. 17. The e.m.f of Leclanche cell is 1.5 V 18. The e.m.f of freshly charged lead acid accumulator is 2.2 V 19. The internal resistance of a secondary cell is low. 20. Ohms law is true for Conductors only. 21. The relation between current and drift velocity is I=nAV de (O 10) 22. Unit of mobility is m2V-1s-1 23. Unit of electrochemical equivalent is Kgc-1

Unit-3. EFFECTS OF ELECTRIC CURRENT

Total of one mark questions from this chapter -2

1. Book Questions: (Refer Page No.117-119)

1. 2. 3. Joules law of heating is H = VIt (Mar 08) Nichrome is used as heat element because it has high specific resistance. (June 06 & 08) Peltier coefficient at a junction of thermocouple depends on the temperature of the junction. (June 09, Oct 10)

4.

In a thermo couple, the temperature of the cold junctions 20C. The neutral temperature is 270C. The temperature of inversion is 520C. (Mar 10, June 08, Oct 08) What is the equation of Biot-Savart law? .(M10)

of galvanometer and prepare unit based question for (Peltier effect, Pettier coefficient, Thomson Coefficient, magnetic induction, reduction factor of T.G.. etc. ) 1. A fuse wire having high resistance, low melting point. 2. Unit of Thomson coefficient volt / C. 3. To convert a galvanometer in to a voltmeter by connecting a high resistance in series. (Mar 06) 4. In a TG 6A current produce a deflection of 60. Find the current required to produce a deflection of 30 is 2A. (Oct 06) 5. Thermopile works on the principle of See back effect. (Oct 07) 6. The direction of magnetic field due to solenoid is given by Right hand palm rule. 7. The converse of see back effect is Peltier effect. (Mar 07) 8. Cyclotron cannot accelerate electrons. 9. Melting point of tungsten is 3380C. 10. Work done by a Lorentz force is always zero. 11. Unit of reduction factor of tangent galvanometer is ampere. (Mar-06) 12. In a Thermo couple, the temperature of cold junction is 20C; the inversion temperature is 600c. then neutral temperature is 310C. (Oct 06 ) 13. The torque experienced by a rectangular current loop placed perpendicular to a uniform magnetic field is zero. (Mar 07) 14. Sb - Bi pairs of metals thermo couple the e.m.f is maximum. (June
-07)

5. 6. 7.

8. 9. 10. 11. 12.

13.

Magnetic Induction due to an infinitely long straight conductor placed in a medium of permeability is I/2a. In a tangent galvanometer, for a constant current, the deflection is 30. The plane of the coil is rotated through 90. Now, for the same constant current, the deflection will be 0. (June 07) The period of revolution of a charged particle inside a cyclotron does not depend on the velocity of the particle. The torque on a rectangular coil placed on a uniform magnetic field is large when the number of turns is large. Phosphor bronze wire is used for suspension in a moving coil galvanometer because it has small couple per unit twist. (Oct 09) Of the following devices, which has small resistance? ammeter of range (0 10)A. (June 06, Mar 09) A galvanometer of resistance G ohm is shunted with S ohm. The effective resistance of the combination is Ra then which of the following statements is true? Ra is less than both G and S. An ideal voltmeter has infinite resistance. (June 10, Oct 07)

2. Additional Questions:
Hint: Prepare one marks from Joules law, seebeck effect, peltier effect, Thermopile, Tangent Galvanometer, Lorentz force, Cyclotron, Torque experienced by a current loop, Galvanometer, Sensitivity and conversion

15. Fuse wire is an alloy of lead and tin. (Mar 08) 16. Thermo pile is used to detect thermal radiation (Oct 08)

17. The resistance of the filament of a 110W, 220V electric bulb is 440 ohm (Mar 09) 18. The magnitude and direction of the magnetic Lorentz force is given by
(June 09)

Hint: Normally in march question papers, 2 questions are asked from self evaluation.

1. Book Questions: (Refer Page No.156-157)

1. 2. Electromagnetic induction is not used in room heater
(Mar 06 & 08, June 07, 08 & 09,)

19. Unit of Peltier coefficient is volt (Oct 09) 20. In a TG a current 1A produces a deflection of 30 the current required to produce a deflection of 60 is 3A. (Oct 06) 21. The unit of magnetic induction is Tesla and W b/m2 22. Positive Thomson effect is observed in Ag, Sn, Cu, Zn, Cd, Sb, and Au. 23. Thomson effect for lead is zero 24. Gyro magnetic ratio of an electron is 8.8 x 1010 C Kg-1. 25. For a given thermocouple, the neutral temperature is a constant (June 10) 26. When the number of turns (n) in a galvanometer is doubled, current sensitivity increases twice (Oct 10) 27. Cyclotron is used to accelerate protons, deuterons and particles. 28. Negative Thompson effect is observed in Fe, Bi, Ni, Pt, Co, Hg. 29. Tangent Galvanometer works on the principle of Tangent law. 30. Tangent Galvanometer and Moving Coil Galvanometer is a device for measuring current.

3. 4. 5. 6. 7. 8. 9.

A coil of area of cross section 0.5m2 with 10 turns is in a plane which is perpendicular to as uniform Magnetic field of 0.2 Wb/m2. The flux through the coil is 1Wb (June 09, Mar 10) Lenzs law is in accordance with the law of conservation of energy (Mar 07 & 08) The self induction of a straight conductor is zero (June 10, Mar 07
& 09)

The unit Henry can also be written as VSA -1, WbA -1, s (June 06 An e.m.f of 12V is induced when the current in the coil changes at the rate of 40A s1 the coefficient of the coil is 0.3H (Oct 09,10) A DC of 5A produces the same heating effect as an AC of 5A rms current (Oct 08, Mar 09) Transformer works on AC only (June 10, Mar 07, Oct 07) The part of the AC generator that passes the current from the coil to the external circuit is Brushes. lags behind the

10. In an AC circuit, the current I = Isin e.m.f e = E sin by .

(Oct 06)

Unit- 4. ELECTRO MAGNETIC INDUCTION AND AC

Total of one mark questions from this chapter 4.

11. Which is the following cannot be stepped up in a transformer? Input power (June 08, Oct 09)

12. The power loss is less in transmission lines when voltage is more but current are less (Oct 06) 13. Which of the following devices does not allow D.C to pass through capacitor (Jun 09, Mar10, Oct 10) 14. In an A.C circuit the average value of current is zero.
(Mar 09)

6.

Q factor on A.C circuit contains a resistance R. inductance L and capacitor C is

(June 08, Mar 09)

7.

In a 3 phase AC generator the 3 coils are fastened rigidly together and are displaced from each other by an angle 120
(Oct 08)

Hint Prepare one marks from Electromagnetic induction, magnetic flux, Lenzs law, generator rule, self inductance, mutual induction, method of producing induced e.m.f, A.C Generator (Single & Three Phase), Eddy currents, Transformers, r.m.s value of A.C, L.C.R in series, Power in a A.C Circuit, Choke Coil. Prepare unit based questions for Henry, Inductive reactance, Self inductance, Coefficient of mutual inductance, inductive reactance, capacitive reactance, Magnetic flux, Inductance. Etc. 1. 2. 3. 4. 5. For a D.C circuit the value of capacitive reactance (X C) is Infinity
(June 08)

2. Additional Questions:

8. Generator rule is Fleming is right hand rule. (June 07,Oct 06) 9. Unit of inductive reactance is ohm 10. Reverse effect of Oersted experiment was demonstrated by Faraday. 11. Induction motors are used in Fans. 12. Choke coils are commonly seen in fluorescent tubes. 13. The angle between the area vector A and plane of area A is
June 09)
.

(Mar 06,

14. If flux associated with a coil varies at the rate of 1 wb/min then the induced e.m.f is
.

(Mar 06)

In a transformer eddy current loss is minimised by using laminated core made of Stelloy. (Mar 08) The reactance offered by 300 mH inductor to an AC supply of frequency 50Hz is 94.2 (Oct 07) The rms value of an A.C voltage with a peak value of 311V is 220v. (Oct 07) The core used in audio frequency chokes is iron. (Oct 07 & 09)

15. In an A.C circuit with an inductor current lags voltage by

(June 06)

16. In LCR circuit when X L = X C, the current is in phase with the voltage (Mar 07) 17. In step up transformer the input voltage is 220V and output voltage is 11KV. The ratio of number of turns primary to secondary is 1:50. (Oct 06) 18. In LCR series circuit at resonance Impedance is equal to R. (Oct 09)

19. The average power consumed over one cycle in an A.C circuit is E rms I rms cos (Mar 06) 20. In LCR circuit, phase difference between current and voltage is 30. The reactance of the circuit is 17.32 . The value of resistance is 30 (June 06) 21. In a A.C circuit with capacitor only if the frequency of the signal is zero, then the capacitive reactance is infinity. (June 07) 22. A power of 11,000 W is transmitted at 220 V. the current through line wire is 50 A (Mar 08) 23. The average value of A.C current over one complete cycle is zero. 24. The rms value of an A.C is 70.7% of the peak value. (Mar 10) 25. The resistance offered by a pure inductor to D.C is zero 26. The resistance offered by a capacitor to D.C is infinite. 27. The value of Q-factor for normal frequency is 10 -100. 28. The domestic power in India is supplied at 50Hz. 29. An emf of 12V is introduced when the current in the coil changes from 2A to 6A in 0.5s. The coefficient of self inductance of a coil is 1.5H. (June 06) 30. In step up transformer the input voltage is 220V and output voltage is 11KV. The ratio of number of turns secondary to primary is 50:1. (June 07) 31. In R.L.C Circuit, at resonance current is in phase with voltage. (Oct 08) 32. In an A.C. circuit, average power consumed is 200W and the apparent power is 300W. The power factor is 0.66. (June 10) 33. In an R.L.C circuit, at resonance XL = XC. (Oct 10) 34. The effective value of alternating current is Io/2 (June 10)

35. Electromagnetic induction is not used in Filament Bulb and Room Heater. (Oct 08)

Unit-5. ELECTROMAGNETIC WAVES & WAVE OPTICS

Total of one mark questions from this chapter -4 Hint Normally March question papers 2 question from Text book self evaluation.

1. Book Questions: (Refer Page No.206-208)

1. 2. 3. 4. 5. 6. In an electromagnetic wave power is transmitted in direction perpendicular to both fields (June 09) Electromagnetic waves are transverse. (Oct 09, 10) Refractive index of glass is 1.5 Time taken for light to pass through a glass plate of thickness 10cm is 5 X 10-10 sec
In an Electromagnetic wave the phase difference between electric field E and magnetic field B is zero (June 06,10 & 08, Oct 08, Mar 09) Atomic spectrum should be pure line spectrum (Mar07)

7.

8.

When a drop of water is introduced between the glass plate and plane convex lens in Newtons ring system, the ring system contracts. (Mar 06,08, June 10,07) A beam of mono chromatic light enters from vacuum into a medium of refractive index . The ratio of the wavelengths of the incident and refracted waves is :1 If the wavelength of the light is reduced to on fourth, then the amount of scattering is increase by 256 times (June 09, Mar10)

10

9.

In Newtons ring experiment the radii of mth and (m+4) th dark rings are respectively 5mm and 7mm. what is the value of m? 10 (Oct 09)

2. 3. 4. 5. 6. 7.

10. The path difference between two monochromatic light waves of wavelength 4000A is 2x10 -7m. The phase difference between them is . 11. In youngs double slit experiment the third bright band for wavelength of light 6000A coincides with the fourth bright band for another source in the same arrangement. The wavelength of the source is 4500A. (Oct 10) 12. A light of wavelength 6000A is incident normally on a grating
0.005m wide with 2500 lines. Then the maximum order is 3. (Mar 08)

In case of Fraunhofer diffraction, the wave front undergoing diffraction is plane wave front. (Oct 08) The phenomenon of light used in the formation of Newtons rings is interference. (Oct 07)
An example for uniaxial crystal is tourmaline (or) Quartz. (Mar 07 , Oct 07)

In Raman Effect, the spectral line with lower frequency than the incident frequency is stokes line. (Oct 07) The optical rotation does not depend on intensity of light-used
(Oct 07)

13. A diffraction pattern is obtained using a beam of red light. What happens if the red light is replaced by blue light? diffraction pattern become narrower and crowded together (June-07 &08) 14. The refractive index of the medium for the polarising angle 60 is 1.732 or 5
(Mar 10, Oct 08)

2. Additional Questions:
Hint: Prepare one marks from Electromagnetic waves, electromagnetic spectrum and its uses, types of spectra, theories of light, scattering of light, Raman effect, Huygens principle, total internal reflection, phase difference and path difference, Youngs double slit, Newtons ring, Diffraction grating, Polarization, Double refraction, optical activity. Prepare unit based questions for Grating element, Specific rotation, Refractive index... Etc. 1. In Raman effect if the scattered photon gains energy. It gives rise to anti stokes line. (Oct 07)

The transverse nature of light waves is demonstrated only by the phenomenon of polarization. (June 10, Mar 08) 8. Velocity of light in a medium is 2.25 x108 Ms-1 the refractive index of the medium will be 1.33. (June 08) 9. The polarizing angle for water is 53 4. If the light is incident at this angle on the surface of water the angle of refraction is water is 36 56. (June 08) 10. Spectral lines emitted by sun line absorption spectra. 11. The rays used to study the molecular structure are IR rays. 12. Wavelengths of sodium D1, D2 lines of lines 5896A, 5890A. (Mar 06) 13. Raman Effect supports quantum theory. 14. Electromagnetic waves used to study structure of nucleus gamma rays. 15. Radiations used in detection of forged documents are uv rays. 16. Double refraction was discovered by Bartholinus. 17. New types of Polaroid are prepared in which thin films of polyvinyl alcohol are used. 18. IR lamps used in physiotherapy. (Mar 07) 19. Spectrum used for making dye is band absorption. 20. Unit grating element is metre. (June 06)

11

21. The existence of electromagnetic waves was confirmed experimentally by Hertz (Mar 06) 22. When a ray of light is incident on a glass surface at polarizing angle of 57 5. The angle between the incident ray and the reflected ray is 115. (June 06, Mar 06 & 08) 23. Electric filament lamp gives rise to continuous spectrum. (June 07 Mar 08) 24. A ray of light is incident on a glass surface such that the reflected ray is completely plane polarised. The angle between the reflected ray and refracted ray is 90 (Mar 09) 25. Soap bubbles exhibit brilliant colour in sunlight due to interference of light (Mar 09) 26. The radii of Newtons dark rings are in the ratio 1 : 2 : 3. (Mar
09)

34. If C is the velocity of light in vacuum, the velocity of light in a medium with refraction index is . 35. 36. 37. 38. 39. 40. 41. 42. 43.
(Oct 06)

27. In the grating formula sin = Nm, the unit of N is metre -1

(June 09,10 )

Gamma rays are not an electromagnetic wave. (Oct 06) In radar M icro wave is used. X-rays are used as diagnostic tool in medicine. Continuous spectrum depends only on temperature of the source. Molecule produce Band spectrum and atoms produces line spectrum. The central core of the sun is called photo sphere. In Fraunhofer diffraction the wave front undergoing diffraction is plane. (Oct 08) Polarising angle for glass is 57.5 The refractive index of extraordinary light is 1.486.

28. The ratio of the radii of the 4th and 9th dark rings in Newtons ring experiment is 2:3 (June 09) 29. Calcium chloride is not an optically active material (Oct 09) 30. Unpolarised light passes through a tourmaline crystal. The emergent light is analyzed by an analyzer when the analyzer is rotated through 90the intensity of light varies between maximum and zero. (Mar 06) 31. Velocity of the electromagnetic waves is given by c =

44. In Raman Effect, the incident photon makes collision with an excited molecule of the substance. The scattered photons give rise to Anti Stokes Lines. (Mar 10) 45. Refractive index of glass is 1.5. The velocity of light in glass is 2 x 108 m/s. (Mar 10) 46. The dark lines found in the solar spectrum are called Fraunhofer lines. (Oct 10) 47. A ray of light travelling in a rarer medium and reflected at the surface of a denser medium automatically undergoes a path difference of /2. (Oct 10).

(June 06)

32. In Youngs double slit experiment, the separation between the slits is halved and the distance between the slits and the screen is doubled. Then the fringe width is quadrapled. (June 07) 33. Nicol prism is based on the principle of double refraction.

12

9.

Unit-6. ATOMIC PHYSICS

Total of one mark questions from this chapter - 4 Hint Normally March question papers 1 question from Text book self evaluation.

10. 11. 12. 13. 14. 15.

1. Book Questions: (Refer Page No.46-48) Vol.II

1. 2. The cathode rays are a stream of electrons. A narrow electron beam passes undeviated through an electric field E = 3x10 V/m and an overlapping magnetic field B = 2x10-3 Wb/m2. The electron motion, electric field and magnetic field are mutually perpendicular. The speed of the electron is 1.5 x 10 -7 ms -1. According to Bohrs postulates, which of the following quantities take discrete values? angular momentum (Mar 07, June 07,
Oct 07, 08 & 09)

X-ray is phenomenon of conversion of kinetic energy into radiation (Mar 07,10, June 09) In an X-ray tube, the intensity of the emitted X-ray beam is increased by Increasing the filament current (June 06) The energy of photon of characteristic X-ray from a Coolidge tube comes from an atomic transition in the target. (June 08) A Coolidge tube operates at 24800V. The maximum frequency radiation emitted from Coolidge tube is 6x10 18 HZ (Oct 10) In hydrogen atom, which of the following transitions produces spectral line of maximum wavelength 65 (Oct 06 & 09, Mar 08) In hydrogen atom, which of the following transitions produces spectral line of maximum frequency 2 1 (June 06) After pumping process in laser the number of atoms in the excited
state is greater than the no of atoms in the ground state.

16. The chromium ions doped in the ruby rod absorbs green lights.
(Mar 06, 09, 10, Oct 08, June 06, 08, 10)

3.

4. 5.

The ratio of the radii of the first three Bohr orbit is 1:4:9.(Mar 10,
08, June 07)

The first excitation potential energy or the minimum energy required to excite the atom from ground state of hydrogen atom is 10.2eV.
(Oct 10, Mar 08)

6. 7. 8.

According to Rutherford atom model, he spectral lines emitted by an atom is Continuous spectrum Refer Textbook Page No.47 in Vol.II. The elliptical orbits of electron in the atom were proposed by Sommerfeld. (Oct 10)

Hint: Prepare one marks from cathode rays, Canal rays, Thomson and Millikens Experiment, Bohrs Atom Model, Spectral series of Hydrogen Atom, Somerfield atom model, X-Rays production, Diffraction of X-Rays, X-Ray spectra, Ruby laser, He-Ne laser, Application of laser and maser. Prepare unit based questions for (Rydbergs constant, wave numbers etc.) 1. Number waves per unit length is known as wave number (Oct 08) 2. Three dimensional image of an object can form by holography.
(Oct 08)

3.

Unit of Rydbergs constant is m-1 (Value 1.094x10-7 m-1) (O 07,J 09)

13

4. 5. 6. 7. 8. 9. 10. 11. 12. 13.

For the 1storder x ray diffraction, the wave length of x ray is equal to lattice spacing at glancing angle of 30 (Oct 07) A Coolidge tube operates at 18600.V the maximum frequency of x radiation emitted from it is 4.5 x 1018 Hz (Oct 07)] Maser materials are paramagnetic ion and ammonia gas. (J 08) Pressure inside the Coolidge tube is 10-6mm mercuric pressure. Wave length of laser beam emitted from ruby laser is 6943A. Fine holes are drilled in diamonds using laser beam. Wave number is defined as the number of waves in a distance one metre. (Mar 06, Oct 08) The energy electron in the first orbit of hydrogen atom is -13.6 eV. Its potential energy is -27.2 eV. (Jun 06) Somerfield model for a given value of n the number of values can take is n. (Oct 06) Ratio of areas enclosed by 1st 3 Bohr orbits of H atom is 1:16:81.
(Oct 06)

20. Ionization potential energy of hydrogen atom is 13.6 eV (Mar 09) 21. When an electric field is applied to an atom each of the spectral lines split into several lines. This effect is known as stark effect
(June 09)

22. In holography, which of the following is recorded on the photography film phase and amplitude (Oct 06 & 09, June 07) 23. The direction of viscous force in Millikans oil drop experiment is opposite to the direction of motion of the oil drop(Mar 09) 24. Canal rays were discovered by Goldstein. 25. The value of e/m is 1.7592 x 1011C Kg-1 26. 1eV = 1.602 x 10 -19 J. 27. The device used to determine the wavelength of X-rays is Braggs X-ray spectrometer. 28. Roentgen discovered X-rays 29. The ratio of Ne and He gases used in He-Ne laser is 4:1. 30. Wavelength of D1 and D2 lines emitted by Sodium Vapour lamp is 589.6 nm, 580nm (Mar 06) 31. In Somerfield atom model, for principle quantum number, n=3, the subshell represents circular orbit is 3d.(Mar 10) 32. A Coolidge tube operates at 24800V, the maximum wavelength of X-Ray radiation emitted from the Coolidge tube is 0.5 x 10 10 m

14. Crystal diffracts monochromatic x-rays, angle of diffraction for 2nd order is 90,1st order 30 (Mar 07) 15. If R is Rydbergs constant, the minimum wavelength of hydrogen spectrum is . (June 07)

16. The spectral series of hydrogen atom in UV-region are called Lyman series. (June 08) 17. If the minimum wavelength of X-rays produced in a Coolidge tube is 0.62 . the operating potential is 20Kv. (Mar 06,08) 18. In a discharge tube, the source of positive rays (canal rays) is gas atoms present in the discharge tube. (Mar 09) 19. The minimum wavelength of X-rays tube at 1000 Kv is 0.0124
(Mar 09)

(June 09)

33. If c is the velocity, is the frequency and is the wavelength of radiation, then its frequency is defined as the number of waves produced in a period of T second. (Oct 10)

14

34. e/m ratio of Cathode ray particles is independent of nature of electrodes and gas used. (June 10) 35. If R is Rydbergs constant, the shortest wavelength of paschen series is 1/R.(June 10) 36. In Millikens experiment, the plates are kept at a distance of 16mm and are maintained at a potential difference of 10000V. The electric field is 6.25 x 10 5 V/m. (June 10) 37. Principle of Maser action is population inversion followed by stimulated emission. 38. Unit of wave number is metre-1 .

5. The photo electric effect can be explained on the basis of Quantum theory of light (Mar 10,June10) 6. The wavelength of the matter wave is independent of Charge (June 08, Oct 09) 7. If the kinetic energy of the moving particle is E, then the De Broglie wavelength is =h/2mE 8. The moment of electron having wavelength 2Ao is 3.3 x 10 -24 Kgms-1 (June 07) 9. According to relativity, the length of a rod in motion is less than its rest length. (June 06,07,09,10) 10. If 1 Kg of substance id fully converted into energy , then the energy produced is 9 x 1016 J(Oct 10) Prepare one marks from photoelectric effect, stopping potential, threshold frequency, laws of photoelectric emission, Einsteins photoelectric equation, photoelectric cells and applications, matter waves, electron microscope, relativity, special theory of relativity, Einsteins mass- energy equivalence.

UNIT-7. DUAL NATURE OF RADIATION, MATTER AND RELATIVITY

Total of one mark questions from this chapter -2 Hint- Normally, in March question papers, 1 question from Text book self evaluation.

1. The work function of a metal is 6.626 x 10-19 J. Threshold frequency is 1 x 1015 Hz (Mar 07) 2. If the radius of third Bohr orbit in hydrogen atom is r, then the de Broglie wavelength of electron in this orbit is
(Mar 06) 3. An electron of mass m and charge e accelerated from rest

1. Book Questions: (Refer Page No.72, 73) Vol.II

1. A photon of frequency v is incident on a metal surface of threshold frequency v o. The kinetic energy of the emitted photo electron is h(v-vo) (Oct 07,08) 2. The work function of a photo electric material is 3.3 eV. The threshold frequency will be equal to 8 x 1014 Hz (Mar 08) 3. The stopping potential of a metal surface is independent of intensity of incident radiation. 4. At the threshold frequency, the velocity of electron is Zero. (Oct 06,07,08,09, M 06,09)

through a potential of V volt, then its final velocity is 2Ve/m

(Oct 08) 4. When a material particle of rest mass mo attains the velocity of light its mass become infinity (Oct 07)

5. Photo electric emission is an instantaneous process. 6. Concept of matter waves was proposed by de Broglie. 7. Particle that has energy with zero rest mass is photon.

(Mar08)

15

8. An un-accelerated frame of reference is called inertial frame. 9. According to Special theory of relativity the only constant in all frames is Velocity of light. (Oct 06, Mar 07,09) 10. Electron microscope is operated in high vacuum. 11. The value of stopping potential when the frequency of light is equal to the threshold frequency is Zero. (Mar 06) 12. Two photons, each of energy 2.5 eV are simultaneously incident on metal surface. Work function of metal is 4.5 eV. Then from the surface of the metal not a single electron will be emitted.
(June 06) 13. Photon has energy but zero mass . (June 08) 14. Photoelectric effect was first observed by Heinrich Hertz.

27. Stopping potential is same for different intensities. 28. The cut off potential is dependent on the frequency of the incident radiation. 29. Photoelectric effect is based on Conservation of energy. 30. Application of photoelectric cells is used in temperature sensor, cinematography, measure light intensity. 31. The material having low function is Caesium oxide. 32. Photoelectric cell is used in opening and closing of door automatically. 33. The operating potential in an electron microscope is about 60,000 V. 34. The mass of body in motion Increases.

15. Einsteins photoelectric equation is W+ hv= mv2 max (June 09) 16. The wave particle duality was extended to particles as matter waves by De Broglie. 17. The highest magnification of the best optical microscope is 2000. 18. Minimum amount of energy required to liberate on electron from the metal is called photoelectric work function. 19. De Broglies concept confirms Bohrs postulates. 20. X-rays cannot be focused by lenses. 21. The rest mass of photon is Zero. 22. An energetic photon can create an electron- positron pair. 23. Magnetic lenses can focus a beam of electrons. 24. The mass of an electron accelerated by a cyclotron is Increases at high velocity. 25. Electron microscope works on the principle of wave nature of moving electron. (Mar 10) 26. The de Broglie wavelength of electron accelerated with a potential V is =h/2Vem(Oct 10)

Total of one mark questions from this chapter - 4 Hint- Normally March question papers 2 question from text book self evaluation.

1. Book Questions: (Refer Vol.II Page No. 116-118)

1. The nuclear radius of 4Be8 nucleus is 2.6 x 10-15 m 2. The nuclei 13Al27 and 14Si28 are example of isotones. (Mar 07,10,June 07,09) 3. The mass defect of certain nucleus is found to be 0.03 amu. Its binding energy is 27.93 MeV. 4. Nuclear fission can be explained by Liquid drop model. 5. The nucleons in a nucleus are attracted by nuclear force. 6. The ionization power is maximum for -particles. 7. The half life period of a certain radio active element with disintegration constant 0.0693 per day is 10 days. (Oct 08,07) 8. The radio isotope used in agriculture is 15P32 . (June 06,08,Oct 08,09) 9. The average energy released per fission is 200 MeV.

16

10. Explosion of atom bomb is based on the principle of uncontrolled fission reaction. (June 09,10,Mar 10) 11. Anaemia can be diagnosed by 26Fe59. (Mar 07,10,June 07,09) 12. In the nuclear reaction 80Hg198 + X79Au198 + 1H1, X stands for Neutron (June 08, Mar 09) 13. In -decay neutron number decreases by one. (Mar 09,Oct 09) 14. Isotopes have same proton number but different neutron number. 15. The time taken by a radioactive element to reduce to 1 times its original amount is its mean life. (Mar 06) 13is 10.1 minute. Its life time is infinity. 16. The half life period of N 17. Positive rays of the same element produce two different traces in a Bainbridge mass spectrometer. The positive ions have different mass with same velocity. 18. The binding energy of 26Fe56 nucleus is 493 MeV. (June 10, Oct 07) 19. The ratio of nuclear density to the density of mercury is about 1.3 x 1013

Prepare one marks from classification of nuclei, properties of nucleus, Brainbridge mass spectrometer, nuclear force, radioactivity, radioactive displacement law and disintegration, neutron, artificial radioactivity, G.M. counter, nuclear fission, nuclear reactor, nuclear fusion, cosmic rays, elementary particle and prepare unit based questions for activity, radiation exposure, electron volt, etc. 1. Safety amount of radiation exposure on human body is 250 milliroentgen per week. 2. Fast breeder reactors, the neutrons reflectors used are Th232 3. Energy radiated from surface of the sun is 3.8 x 1026 J/S 4. Energy of fast neutrons is between 0.5 MeV to 10 MeV 5. Rays having high penetrating power is gamma rays. (Oct 06)

6. Boiling point of liquid sodium used is 1000o C 7. Only operating reactor in the world using 92U233 as fuel is Kamini. (Oct 07,09) 8. In nuclear reactor, moderator is Heavy water. (Mar 07) 9. Which of the following particle is a leptons electron. (Mar 06) 10. Nuclear force is due to the continuous exchange of particles called mesons (Mar 06,09, Oct 09) 11. The particles which exchange between the nucleons and responsible for the origin of the nuclear force are mesons (June 07) 12. In the nuclear reaction 7N14 + 0n1 X + 1H1 the element x is 6 C14 (Mar 06) 13. One amu is equal to 1.66 x 10-27 Kg (or) 1.66 x 10-24 g (or) 931 MeV. (June 06,09,Oct 06) 14. In the following nuclear reaction 13Al27 +2He4 X + on1. The element X is 15P30 (Oct 06) 15. The numbers and particles emitted when isotope 92U238 undergoes and decays to form 82Pb206 are respectively 8,6 (Mar 07) 16. Liquid sodium is not a moderator. (June 07) 17. 11 Na24 is used to defect the presence of block in blood vessels. (Mar 08) 18. If the nuclear radius is 2.6 x 10 -15 m then mass number will be 8 (June 08) 19. Slow neutrons are neutrons having energies between 0 eV to 1000 eV. (June 08) 20. The half life of a radioactive element is 300 days. The disintegration constant of the radioactive element is 0.00231/day. (Mar 09) 21. The mean life of Radon is 5.5 days. Its half life is 3.8 days (June 09)

17

22. The rest mass of a proton is about 1836 times the mass of an electron. 23. The phenomenon of radioactivity was discovered by Henry Becquerel. 24. The reciprocal of decay constant is 1.44 times its half life period. 25. To determine the age of a wooden sample C14 is used. 26. The unit of radiation exposure is Roentgen. 27. Half life period of C14 is 5570 years. 28. The energy produced in proton-proton cycle is 26.7 MeV. 29. The name of cosmic ray was given by Millikan. 30. Neutrino and antineutrino are associated with -emission. 31. The name of meson was given by Yukawa. 32. An element zXA undergoes three -decays and four -decays and gets converted to an element Y. The mass number and atomic number of the element Y are respectively A-12,Z-2 (June 07, Mar 08) 33. The mean life and half life T1/2 of a radioactive element are related as = T1/2 /0.6931 (Mar 08) 34. The time taken by a radioactive element , its reduce to e -1/2 times its original amount is its mean life period (June 06) 35. Find the emitted particle in the nuclear reactions 4Be9 + 2He4 6C12 + X. X stands for neutrons. (Mar 10) 36. In the fast breeder reactor the chain reactor is sustained by Fast neutrons. 37. The particle which has zero mass but has energy is Photon (Mar 08) 38. Particle that has no charge and no mass and travels with the velocity of light is Photons (Oct 08) 39. Which of the following particle belongs to Baryon group Proton (Mar 10) 40. Based on quark model a neutron is represented as udd (June 06, Oct 06) 41. Ionization power is maximum for - particles (June 10, Oct 10)

42. According to the law of disintegration N=No e-t the number of radioactive atoms that have been decayed during a time of t is No-N (June 10) 43. Isotopes have same proton number but different neutron number. (Oct 10) 44. The coolant used in fast breeder reactor is liquid sodium (Oct 10) 45. The half life period of N 13 is 10.1 minute. Its life time is Infinity. (Oct 10) 46. 1 Fermi is 10-15 m. 47. 1 eV is 1.6 x 10 -19 Joule. 48. Unit of activity is becquerel. 49. 1 curie is the activity of one gram of Radium. 50. Chadwick discovered neutrons. 51. A particle accelerator accelerates charged particles. 52. Geiger- Muller counter is a particle detector.

Total number of one mark questions from this chapter is - 3 Hint Normally March question paper chance 1 question from Text book self evaluation.

1. Book Questions: (Refer Page No. 175-177 in Vol.II)

1. The electrons in the atom of an element which determine its chemical and electrical properties are called Valence electrons 2. In a N-type semiconductor there are immobile positive ions

18

3. The reverse saturation current in a PN junction diode is only due to minority carriers (June 09) 4. In the forward bias characteristic curve, a diode appears as an ON switch 5. A avalanche break down is primarily dependent on the phenomenon of Collision (Oct 2007) 6. Colour of light emitted by a LED depends on types of Semiconductor material (June 06,10 & Oct 08,10) 7. The Emitter base junction of a given transistor is forward biased and its collector base junction is reverse biased. If the base current is increased then its IC will increase. 8. Improper biasing of a transistor circuit products distortion in the output signal. 9. An oscillator is an amplifier with feed back (Mar 08 &
June 09,10, Oct 10)

15.

The Boolean expression

can be simplified as -

(Jun 10, Mar 06)

2. 3. 4. 5. 6. 7. 8. 9. 10.

10.

Colpitts oscillator circuit Capacitive feedback is used

(June 06)

11. Since the input impedance of an ideal operational amplifier is infinite its input current is zero. 12. The following arrangement performs the logic function of AND gate (Book back refer text book Vol.II, P.No 176) (Oct 06&08,
June 08, Mar 10)

13. If the output Y of the following circuit is 1 the input ABC must be 101 (Refer text book Vol.II, P.No 176) (June 09) 14. According the laws of Boolean algebra, the expression (A+AB) is equal to A. (Mar 07, Mar 09)

Hint: Prepare one marks from Insulators, Semi-conductors, Conductors, PN Junction diode, L.E.D, Junction transistor, Transistor amplifier, Feedback in amplifier, Logic Gates, DeMorgans theorem, OP-AMP circuit, Electronic measuring instrument. Also refer example problems in Page No. 173 175 (9.3, 9.4, 9.5(June 08), 9.6) and Book back problems in Page no. 178-179. (9.51, 9.52, 9.55, 9.56) 1. In CE amplifiers, the phase reversal between input and output voltages is 180 (June 2008) In junction the emitter region is heavily doped since emitter has to supply to the base majority carriers. (Oct 2007) A logic gate which has on output I when the inputs are complement to each other is EXOR. (Oct 2007) The potential barrier of germanium PN junction is 0.3V. (June 06) Condition for an amplifier to become an oscillator is A=1/ (M 06) Thickness of the base in transistor is 25 microns. Output impedance of CE mode transistor is low. Zener diode working in the breakdown region can act as voltage regulators. OP Amp consists of 20 transistor 11 resistors, 1 capacitor Boolean expression for NAND gate is Y = (Oct 09 & June 06)

11. In CE configuration output terminal is Collector 12. In tank circuit the energy in the inductance coil is stored as magnetic energy and it produces wave forms

19

13. CRO works on the principle that the beam of electron can be deflected both in electric and magnetic field 14. Forbidden energy gap for germanium is of order 0.7eV (Mar 06 &
Oct 06)

15. Forbidden energy gap for silicon is of order 1.1eV (Oct 06,10, Jun
06 & Mar 08, 09)

Total number of one mark questions from this chapter is - 2 Hint Normally March question paper chance 1 question from self evaluation so see all 8 questions given in text book page-215,216(vol-2) 1. 2. 3. 4. 5. 6. 7. High frequency waved follows ionospheric propagation
2006, June 2006) (March

16. Barkhausen condition for maintenance of oscillation is =

(Mar 07 & Oct 09)

17. A logic gate for which there is low output only when both the inputs are high is NAND. (June 2007) 18. In CE single stage amplifier, the voltage gain at mid-frequency is 10. The voltage gain at upper cut-off frequency is 7.07 (Oct06&09) 19. An example for non-sinusoidal oscillator is multi vibrator (Mar 09) 20. LED is a forward biased PN junction diode which emits visible light when energized. 21. The commonly used transistor is CE Circuits. 22. The forbidden energy gap for conductor is zero. (Mar 10) 23. Bi and As are examples for donor atom. (Mar 08) 24. In CE Transistor circuit, the base current of the transistor is 50micro Ampere. And the collector current is 25 micro Ampere. Then the current gain is 500.(Oct 08) 25. In the PIN configuration IC 741, PIN 3 represents Non Inverting Input. 26. Potential Barrier for a silicon PN junction is 0.7V. 27. PN Junction diode does not obey Ohms law. 28. The unit of output Impedance is .

Main propose of modulation is to transmit low frequency information over long distance efficiently The amplitude modulation the amplitude of the carrier wave
varies in accordance with the amplitude of the modulating signal

8.

In amplitude modulation, the bandwidth is twice the signal frequency (June 2007) In phase modulation both the phase and the frequency of the carrier wave varies. R/F channel in a radio transmitter produces high frequency carrier waves (Mar 2007, 10 & Mar 2009) Purpose of dividing each frame into 2 fields so as to transmit 50 views of picture per second is to avoid flicker in the picture (June 2008) Printed documents to be transmitted by fax are converted into electrical signals by the process of Scanning
(Mar, June & Oct 08 & june-2009)

Hint: Prepare one mark from Propagation of Electromagnetic waves, AM modulation, FM Modulation, Radio transmission and reception,

20

Television, Monochrome Picture tube, Modem, Fax, Wire and Cable, Fibre Optic & Satellite communication. 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13. Skip distance is the shortest distance between a point of transmission and the point of reception. (Oct 2008) Audio frequency range is 20 Hz to 20000 Hz (Mar 2008) The first man made satellite Sputnik (Oct-07) An analog signal is a continuous varying voltage (or) current. Twisted pair cable the wire is twisted to minimize external noise Modem device convert digital signals into analog signal (M7, O9) Scanning high negative potential is used as Blanking pulse Cu is an inexpensive metal easily made into wire. Working principle of Radar is radio echoes In TV, blanking pulse is applied to control grid (Mar 06, Oct 09) In AM super heterodyne, the local oscillator frequency is 1.245 MHZ. the turned station frequency is 790 KHz (June 2006) Radio waves after refraction from different parts of ionospheres on reaching the earth are called as sky waves. (Oct 2006) Principle used for transmission of light signals through optical fiber is total internal reflection (Oct 2006)

19. In India the frame repetition rate is at 25 frames per second. 20. Voice signal is an analog signal. 21. The long distance radio communication is possible through sky waves propagation.

Sl. No
1 2 3 4 5 6 7 8 9 10

UNITS
ELECTROSTATICS CURRENT ELECTRICITY EFFECTS OF ELECTRICITY CURRENT ELECTRO MAGNETIC INDUCTION AND A/C ELECTRO MAGNETIC WAVES AND WAVE OPTICS ATOMIC PHYSICS DUAL NATURE NUCLEAR PHYSICS SEMI CONDUCTOR DEVICES COMMUNICATION SYSTEMS

No. of Qus. 20 2 3 1 2 2 2 1 2 4 1

Q.No 31, 32 33, 34, 35 36 37, 38 39, 40 41, 42 43 44, 45 46, 47, 48,49 50

14. In interlaced scanning time taken to scan one line is 64 s (June 07) 15. In Vidicon camera tube, the front face of the target plate or image plate facing the light is coated in tin oxide 16. Function of modem is modulation and demodulation 17. In FM super heterodyne receiver, the intermediate frequency is 10.7 M Hz. (Oct 10) 18. In radar to locate the direction of the target directional antennas are used.

21

12. What is meant by electrostatic shielding? Where it is used. To Write 31 and 32 Total questions: 27
No.21 (Mar 08)

Page

One question can be asked from the textbook self evaluation. Refer Page No. 42, 43. 1. 2. 3. 4. 5. 6. 7. 8. 9. Define electric potential at a point. example. Page No.3
(Mar 07 & June 09 ) Page No.12

13. Define electric flux. Give its unit. Page No.17

(June 08) (June 08)

14. Define Potential difference? Give its unit. Page No.12 15. Explain the working of microwave oven. Page No.12 its advantages? Page No.30 (June 07, Oct 08) 17. Difference between polar and non-polar molecules. Page No.24 18. Write the application of capacitor. Page No.27 (Oct 07) 19. Distinguish between electric potential and potential difference.
Page No.12

What do you mean by Additive nature of charge? Give an

(Oct 07) (Mar 07)

16. What is meant by corona discharge (or) action of points? What are

What is a polar molecule? Page No.24

06,Mar,09)

State Gauss Law in electrostatics Page No.17,18 (June & Oct What is meant by Dielectric Polarization? Page No.25(Oct 06, 09) Why it is safer to be inside a car than standing under a tree during lightning. Page No.21 (Mar 06,10,June 06 & 09) Define coulomb on the basis of coulombs law, explain it in vector form? Page No.3,4
Page No.4 (Mar 10, June 07,10)

20. What is Gaussian surface and equipotential surface? Page No.16 21. What is an electric dipole? Define electric dipole moment. Page
No.8 (Oct 09)

22. Define electric field intensity at a point in an electric field. What is its unit? Page No.6 23. Define coulomb. (Mar 06, Oct 10) Page No.4 24. What is a non-polar molecule? Give example ( Oct 06) Page No.24 25. What is electric potential energy? Page No.11 26. Problems: from text book example, page no 37, 38.
1.8, 1.11, 1.12, 1.13, 1.14, 1.15

Define relative permittivity and permittivity. How they are related. What is the unit of capacitances? Define it .What is capacitor?
Page No.22 (Mar 09)

10. What are conductors and Insulators? Give example Page No.2 11. Give any three properties of electric line of force? (June 07) Page
No.7

27. Problems: from book back, page no 43 to 45.

1.46, 1.50, 1.55, 1.58, 1.59 (Mar 08)

22

To Write 33, 34 and 35

Total questions: 29

17. The colour of a carbon resistor is yellow, violet and orange. What is the value of resistance resistor? 18. What is the difference between primary cells and secondary cells?
Page No.66.67

Note: One Question chance from book back and one Problem. Refer Page No. 75-76. 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. State Ohms law. Page No.48 (Mar 10,06, Oct 07 & 09) Mention any 3 application of super conductor? Page No.51 (Oct 06
& 07,June 06 & 07)

19. Distinguish between electric power and electric energy. Page No.62
(June 08 & 09)

20. State Kirchhoffs second law for electric network. Page No.56 (Mar
09)

Distinguish between electromotive force and potential difference .

Page No.62 (June 07,Oct 08)

State Kirchhoffs voltage law and current law? Page No.55,56 (June
06, Mar 07 & 08)

21. Define electro chemical equivalent of a substance. Page No.63 22. What are the changes observed at transition temperature when the conductor becomes a super conductor? (June 2010) Page
No.51

Define drift velocity. Page No.47

09)

(Mar 10,07, Oct 08 & 09, June

Define mobility of electrons. Give its units. Page No.47 (Oct 06,10,
Mar 08 & 09)

State Faradays laws of electrolysis. Page No.63 (Mar 06, Jun 10) Define temperature co-efficient of resistance. Page No.54(June 08) What are the advantages of secondary cells? Page No.68 (Oct 08) State Kirchhoffs laws and mention the sign convention. Page
No.55,56

23. What is called primary cells? Page No.66 24. How does e.m.f differ from potential difference? Page No.62 25. List the changes that occur at transition temperature. Page No.51. 26. Differentiate current from current density. Page No.46, 47. 27. Define Transition temperature. Page No.51 28. Problems: from text book example, Page No.69 - 74
2.1(Mar 10), 2.2, 2.3, 2.4, 2.5 (June 07 & 09, Oct 07,10, Mar 08) 2.6 (Mar 07), 2.8, 2-9 (June 08) 2-10 (Oct 06) 2-13. 29. Problems: from Book Back, page no 76 to 78. 2.31, 2.32(Jun 06), 2.34 (Oct 09), 2.38 (M 07, J 10) 2.39, 2.40. 2.41

11. What is called current density? Is it scalar or vector? What is its unit? Page No.47 12. What is called super conductivity? Page No.50 13. Define electric resistance? Page No.48 (June 08) 14. Define electric resistivity of a material. Page No.49 15. Why is copper wire not suitable for potentiometer? 16. Why automobile batteries have low internal resistance?

To Write 36 Problems also possible.

Total questions: 29

23

1. 2.

Why is nichrome used as a heating element? Page No.81(June 07) In a Galvanometer, increasing the current sensitivity does not necessarily increase the voltage sensitivity. Explain . Page No.106
(Mar 07)

3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13. 14. 15.

Mention the limitations of Cyclotron. Page No.99 (Oct 06) Define Peltier co-efficient and write its unit. Page No.84 (June 06) Define Thomson co-efficient. What is its unit? Page No.85 Define seebeck effect. Page No.82 Define Ampere in terms of force. Page No.102 (Mar & June 08) Difference between Peltier effect and Joule heating effect? Page
No.82,84 (Mar06)

22. State principle of a cyclotron Page No.97 23. State the principle of moving coil galvanometer. Page No.10. 24. Why do we connect ammeter in series with the circuits and Voltmeter in parallel with the circuit? Page No.108. 25. Define Thermo emf and Thermo electric current. Page No.52. 26. State end rule. Page No.95 27. What is magnetic Lorentz force? Page No.95 28. Problems: from text book example, page no 112 to 115.
3.2 (Oct 07), 3.3, 3.4, 3.7, 3.9, 3.9, 3.11, 3.12, 3.13 29. Problems from book back : Page No.120-121 3.28, 3.32, 3.38 and 3.39.

State Joules law? Page No.79 State Biot - savart law? Page No.87,88 What is meant by fuse wire? State its function? Page No.81 Define temperature of inversion. Page No.83 State Maxwells right hand corkscrew rule. Page No.87 What is Amperes circuital law? Page No.92(Mar 09 ) What is neutral temperature of a thermocouple? Page No.83 (Oct
08)

To Write 37 and 38

Total questions: 27.

16. How is the galvanometer converted into: (a) ammeter (b) voltmeter Page No.106,108 (June 09) 17. How can we increase the current sensitivity of a galvanometer?
Page No.106 (Oct 09)

Normally one question from Book back. Page No: 157 and 158 and one problem. In Oct 06, 08, Mar 07 and 10, problems were not given from either example or book back. So problems may come from outside the textbook. Refer guides. 1. 2. 3. 4. State Faradays laws of electromagnetic induction?
No.124 Oct 09) (June 06 & 07, Oct 07) 07, Page

18. What is mean positive Thomson effect? In which elements it can be observed? Page No.85 19. What are the characteristics of heating elements used in electric heating device? (Mar 10) Page No.81 20. State Flemmings left hand rule (Oct 10) Page No.100 21. What is right hand palm rule? Page No.93

Define r.m.s value of alternating current? Page No.141 (June

State Flemings right hand rule .Page No.125 (Mar 10,07 & 09, June
09, Oct 09)

Define quality factor.(or) q- factor. Page No.148

(Oct 06)

24

5. 6. 7. 8. 9.

Mention the methods of producing induced e.m.f. Page No.131 (Oct

10, Mar 06)

A capacitor blocks D.C but allows A.C explain. Page No.145,146 Define power factor? Page No.150 Compare step up and step down transformer. Page No.138 Give difference between AF choke and RF choke. Page No.151(June
08)

24. Define resonant frequency. Page No.148 25. Define efficiency of a transformer. Page No.138,139 26. Problems: from text book example, page no: 151 to 153.
4.1, 4.2 (June 06, Mar 08) 4.4 (Mar 06 & 09) 4.5, 4.7 (June 08 & 09) 4.3 4.6,

27. Problems: from book back, page no 159-160.

4-54, 4-56, 4-63,

10. State Lenzs law in electromagnetic induction. Page No.124 (June

10, Oct 07)

11. 12. 13. 14.

Why a D.C ammeter not read A.C? Page No.141 (Oct 07) What is electromagnetic induction? Page No.122 (Mar 08) Define coefficient of self induction of a coil. Page No.126 (June 09) Define coefficient of mutual induction, Mention its unit. Page
No.129

To Write 39 and 40

Total questions: 31

15. Difference between Self induction and mutual inductance. Page

No.125,128

Note: Normally one question from book back, Page No.208 (chance) and
one problem from either example or book back problems.

1. 2. 3. 4. 5. 6. 7. 8. 9.

Define optic axis of a crystal? What is meant by optical rotation?

Page No.199 (June 07,10)

16. If the rate of charge of current of 2As-1. Induces an e.m.f of 10mv in a solenoid. What is the self inductance of the solenoid? Answer: =-L x di/dt. (Formula). =5mH.(repeated) 17. What is eddy current? Page No.136 18. Define instantaneous power of an AC circuit. Page No.144 19. What is inductive and capacitive resistance? Page No.144,145 20. What are the advantages of ac over dc? Page No.145,146 21. What are the factors on which the mutual inductance depends on? Page No.129 22. What do you mean by resonance? What is the use of resonance?
Page No.148,149

What is Tyndall scattering? Page No.173(Mar 07, June 10,09, Oct 10) What is band emission spectrum? Give an example. Page No.168 Why does the sky appear blue in colour? Page No.173 (June 06) What are emission and absorption spectra? Page No.168,169 (Mar
& Oct 06)

Distinguish between interference and diffraction fringes. Page

No.194 (Oct 07)

What is meant by specific rotation? Page No.202 (Mar 08) The sun appears reddish during sunrise and sunset. Why? Page
No.173

23. What is magnetic flux? Give its unit. Page No.122

State Rayleigh scattering law. Page No.175

25

10. Difference between fluorescence and phosphorescence. Page

No.170 11. What are factors on which optical rotation depends upon ? Page No.202 (June08)

30. Difference between line spectrum and continuous spectrum. Page

No.169

31. What are stokes and anti-stokes lines? Page No.173 32. What are uniaxial and biaxial crystals? Give examples Page
No.199

12. What are the conditions for total internal reflection to take place? Page No.180 (Oct 08) 13. What are the characteristics of electromagnetic waves? Page
No.163

14. State Huygens Principle. Page No.176 (Oct 09) 15. Write any three uses of infrared radiation. Page No.167 (Oct 08) 16. Why is the centre of the Newtons ring dark? Page No.187 (Mar
09)

33. 34. 35. 36. 37. 38.

State Brewsters law. Page No.197 What do you mean by polarizer and analyzer? Page No.196 What is Raman Effect? Page No.173 State the defects of corpuscular theory. Page No.171 Compare polarized and unpolarised light. Page No.195 Problems: from text book example, Page No.203-205
5.2, (June 06) 5.6 (Mar 08) 5.4(Oct 10), 5.7,

17. State the conditions for obtaining clear and broad interference bands. Page No.185 18. What is total internal reflection? Page No.179 19. What are Polaroids? Mention any three uses of Polaroids. Page
No.200

5.5 (Mar & June 07) 5.8 (Mar 06 & 09) 39. Problems: from book back, page no 209. 5.41, 5.44, 5.45 (Oct 06 June08 & 09), 5.49 (Oct 09) 5.50,

&

07,

20. 21. 22. 23. 24. 25. 26. 27.

What are Newtons rings? Page No.187 What are electromagnetic waves? Page No.163 What is the principle of super position of waves? Page No.180 Compare ordinary and extraordinary light. Page No.199 Distinguish the corpuscle and photon. Give the conditions for sustained interference. Page No.182 What are coherent sources? Page No.181 Distinguish between Fresnel and Fraunhofer diffraction. (Mar10)
Page No.190,191

To Write 41 and 42 Note: One problem and one question (chance) 1. 2. 3. 4.

Total questions: 27

28. What are called corresponding points? Page No.191 29. What is polarizing angle? Page No.197

Who is hologram? Page No.46 (Oct 07) Write down the 2 important facts at the Laue experiment on X-ray diffraction. Page No.29 (Oct 07, June 08) State Moseleys law, write its equation. Page No.33(Mar 07, 08 & 09) What are the characteristics of laser? Page No.35 (Oct 06, June
09,10, Mar 10)

26

5. 6.

Write the principle of Millikans oil drop experiment. Page No.5

(June 06)

27. What is meant by energy level diagram? Page No.18 28. Problems: from text book example, (Vol-2) page no: 41 to 45.
6.1 6.7, (Oct 06) Oct 10, 08, Mar 09) 6.46(June 07) , 6.50(June 07), 6.3 6.8, 6-10. 6.4, 6.9 (June 10, 06,

Write the conditions to achieve laser action. Page No.36 (Mar 06,

June 07) 7. Explain any one of the drawbacks of Rutherford atom model. Page No.12 (Oct -08) 8. Give 3 industrial uses of laser. Page No.39(June 08) 9. Give 3 properties of cathode rays. Page No.2 10. State any 3 postulates of Bohr atom model. Page No.21 11. Give drawback of Thomsons atom model? Page No.9 12. Compare spontaneous emission and stimulated emissions. Page No.35 13. What is meant by normal population? Page No.35 14. What meant by population inversion. Page No.35,39 15. Write any 3 applications of laser in medical field? Page No.39 (Mar 08, Oct 09) 16. What are hard x-rays and soft x-rays? Page No.26 17. State Braggs law. Page No.29 18. What are continuous x-rays? Page No.31 19. Define Ionisation potential Energy? Page No.20,21(Mar 07, June 09, Oct 10) 20. Write any 3 industrial uses of X-Rays. Page No.34 21. What are the short-comings of Somerfields atom model? Page No.21,22 22. Write short notes on MASER. Page No.40 23. Define excitation potential energy. Page No.20,21 24. State the applications of Moseleys law. Page No.33 25. State Rutherfords atom model. Page No.11,12 26. How does laser light differ from ordinary light? Page No.34

29. Problems: from book-back, page no 49-50.

6.49(Mar 06),

6.52(Mar 10)

To Write 43 Note: Chance for problem (or) question. 1. 2. 3. 4. 5. 6. 7. 8. 9. 10.

Total questions: 15

Give limitations of electron microscope? Page No.62 (Mar 09,06) What are inertial and non inertial frames of reference? Page No.63
(Oct 06, Mar 08)

Define threshold frequency? Page No.54 State the postulates of special theory of relativity ? Page No.64 (Oct
07, June 09)

What are matter waves? Page No.58 Define stopping potential (or) cut-off potential? Page No.53
09)

(Oct

Define frame of reference? Page No.63 Define photoelectric work function? Page No.56 What is photoelectric effect? Page No.51 Calculate the threshold wavelength of certain metal of work function 1.8 eV. (Oct 08) 11. What are photo cells? What are the 3 types of photo cells? Page
No.57

27

12. Mention the uses of Electron microscope (Mar 07) Page No.62 13. According to classical mechanics, what is the concept of time? (June 10) Page No.63 14. Mention any 3 applications of Photoelectric cells. Page No.57,58 15. X-ray cannot be used in electron microscope, why? Page No.60, 61. 16. What are the concept of space and mass in classical mechanics? Page
No.63

17. Problems: from text book example, (Vol-2) Page No.68-71

7-1, 7-4, 7-5 (June 07, 08) 7-7, 7-8, 7-9. 18. Problems from Book-back, Refer Page No.74. 7.34, 7.40, 7.41, 7.42

9. 10. 11. 12. 13. 14. 15. 16.

What is radio carbon dating? Page No.91 What are breeder reactors? Page No.101 (Mar 09) State the laws of radioactive disintegration? Page No.86 Write any three properties of neutrons (June 06, Mar 08) Page No.89 What is mass defect? (Oct 10) Page No.79 Define binding energy of nucleus? Page No.79 (Oct 09) State radioactive displacement law? Page No.85 Define critical mass or critical size of nuclear reactor? Page No.97
(Oct 08)

To Write 44 and 45 Note: One problem and one question (Chance) 1. 2. 3. 4. 5. 6. 7. 8.

Total questions: 31

What is the use of a control rod in the nuclear reactor? Mention any two control rods? Page No.100 (Oct 07) Define roentgen? Page No.92 (June 07, Oct 08) What is meant by pair production and annihilation of matter?
Page No.107 Page No.80 (Mar 06 & 07, June 06) (Oct 06)

17. What are cosmic rays? At what latitude and altitude the cosmic rays intensity is maximum? Page No.105 (June 10,08) 18. Compare nuclear fission and fusion? Page No.95,103 19. What are nuclear forces? How do they arise? Page No.82 20. Write any three properties of nuclear force.Page No.82 (Mar 09) 21. Define radioactivity. Page No.83 22. Write a note on leptons. Page No.107 (June 07) 23. What are isotones? Page No.77 24. How do you classify the neutrons in the terms of K.E Page No.89
(June 09)

25. Write the equation proton-proton cycle can account for steller energy. Page No.104 26. What is called activity of a radioactive substance? Give its units.
Page No.88

Write any three conclusions obtain from Binding energy curve? Define curie. Page No.88 (June & Oct 06, Mar 08) What is -decay? Give an example. Page No.85 (Mar 06) Define half life period and mean life? Page No.87,88 What are primary and secondary cosmic rays? Page No.105

27. Explain the experiment conducted by Bothe and Becker. Page

No.89,90

28. What are thermonuclear reactions? Page No.103 29. State the principle of G.M counter. 94 30. What is a nuclear reactor? What are the uses? Page No.98,101

28

31. What are the precautions to be taken by those who are working in radiation laboratory? Page No.93 32. What do you mean by gamma decay? Give an example. Page
No.85,86

6. 7. 8. 9.

Draw the circuit configuration of NPN transistor in common collector (C.C) mode. Page No.139 (Mar 06 & 08, Oct 06)

Draw the circuit diagram for OR gate-using diodes. Give its truth
table Page No.159 (June 06) Define input impedance of a transistor connected in common emitter mode Page No.141 (June 06 & repeated) What is an intrinsic semiconductor? Give two examples. Page
No.125 (Mar-06)

33. Define amu. Page No.78 34. How are elementary particles classified? Page No.107 35. Problems: from text book example, (Vol-2) page no: 109.
8-1, 8.47, (Oct 07) 8.57(J 09) 8-2. 8.49, 8.52 (Mar 20), 8.58 (Mar 07, Oct09, June10), 8.59, 8.56, 8.60,

36. Problems: from Book back, page no 119-120.

10. State De - Morgan theorem. Page No.161(Mar 08 & 09,June 10) 11. Compare linear ICs and digital ICs 12. Define lower cut off frequency and upper cut off frequency? Page
No.147

To Write 46, 47, 48 and 49

Total questions: 41

Note: Chance one question from Book back and one problem from example (or) self evaluation. Problems may also come from inside the book, based on Logic gates. Difficult to write all four question from this chapter, so prepare well. 1. 2. 3. 4. 5. What are the advantages of negative feedback? Page No.150 (June
07&08, Oct 08, 07)

13. 14. 15. 16. 17.

Define output impedance of a transistor in? Page No.142 (O 08,09) Common emitter mode is widely used. Why? Page No.143 Define input impedance mention its uses. Page No.141 What is an extrinsic semiconductor Page No.126 (June 06, 08, O10) What is an integrated circuit, what are the types? Page No.154
(June 08 & 09)

18. What is Meant by doping Page No.125,126 (Oct 08) 19. Draw the circuit for summing amplifier Page No.167 (Mar

09)

Give the important parameter of an operational amplifier? Page

No.143
(Oct 07)

20. Give the Barkhausen conditions for oscillator Page No.150 (Oct
07,08, June 09, Mar 10)

Draw the circuit diagram of AND gate using diodes and resistor.
(June 07) Page No.157

21. Mention any three uses of Cathode Ray Oscillator (CRO) Page
No.170 (June 09)

Define bandwidth of an amplifier. Page No.147 (Mar 07) What is a light emitting diode? Give any one of its uses. Page
No.136 (Mar 07)

22. Write the different methods of doping a semiconductor Page

No.126 (Oct 09)

23. What is Zener diode? Draw its symbol. Page No.135 (Oct 09, 10).

29

24. Mention any 3 advantages of integrated circuit. Page No.154 (Mar

& Oct 06, June 10)

25. Define rectifier efficiency. Page No.133 26. What are universal logic gates? Why are they called so? Page
No.161

44. Compare analog and digital signal. Page No.155 45. Define current gain of CE mode. Page No.140 46. Problems: from text book example, (Vol-2) page no: 172 to 175.
9-2 (Mar 08), 9-5 (Oct 07), 9-3 (June 06, Oct 09, 10, Mar 10) 9-4, 9-8 (June 08) 9.9(Model in J 07)

27. 28. 29. 30.

Compare N-type and P-type semiconductor. Page No.126,127 What is an Ex OR gate? Give its truth table. Page No.159 What is avalanche breakdown? Page No.134 Draw the block diagram of an oscillator and mention the components. Page No.152,153 31. What is called feed back? State two types of feedback. Page
No.148

47. Problems: from Book-back, page no 178 to 179.

9.50 (June 10), 9.51, 9.52(Mar 07), 9-55, 9.57, 9.58, 9-60(June 09) 9.56(Model in Mar 09)

32. Construct AND gate using NOR gate. Page No.157,160 33. The gain of a amplifier without feedback is 100 and gain with positive 34. 35.
feedback is 200, Calculate the feedback fraction (Mar 06) What is Zener breakdown? Page No.135 (Oct 06, June 07, Mar 08) The voltage gain of an amplifier without feedback is 100, If feedback is supplied with a feedback fraction =0.1, Calculate the voltage gain after feedback. (Oct 06) What is rectification? Page No.132 (Mar 07,09) Draw the energy band diagram of N-type and P-type Semi-conductors. Page No.127,128 (Mar 10) Draw NOT gate using transistor. Page No.158 (June 10) What are the essential components of a LC oscillator? Page No.152 (Oct 10) What is the principle involved in the method of biasing a transistor? Page No.145. Write a note on OP-AMP. Page No.164. Derive the relation between the and of a transistor. Page No.140 Define forbidden energy gap. Page No.123

To Write 50

Total questions: 19

Note: Normally less chance for problem from this chapter. Chance from book-back question, Page No. 216, 217. 1. 2. 3. 4. 5. 6. 7. 8. 9. What is the necessity of modulation? Page No.185 (Oct 07) What is meant by skip distance? Page No.184 (June 07 &09, Mar
08, Oct 10)

36. 37. 38. 39. 40. 41. 42. 43.

What are the advantages of digital communication? Page No.209

(Mar 07, June 10)

What is fax? Give its uses? Page No.210 (Oct 06) Three applications of radar? Page No.207 (June 06) Define modulation factor in Amplitude modulation. Page No.186
(Mar 06, 10, June 08, Oct 09)

What is called phase modulation? Page No.191 What is optical fiber? Page No.211 Explain geo stationary satellite? Page No.212

30

10. What

are

the

advantages

of

frequency

modulation?

Page No. of Qus. 12 1 2 1 1 1 1 2 1 1 1

No.190(Mar 09)

11. Mention any three advantages of fiber optic communication system Page No.212 (Oct 08) 12. What are the different types of wire and cable used for communication system? Page No.210 13. What is meant by scanning? Page No.198 14. What are called blanking pulses? Page No.199 15. What is an antenna and antennae gain? Page No.191 16. What are the De-merits of satellite communications? Page No.214 17. What is meant by Skip zone? Page No.185 18. What is modulation? What are the different types of modulation? Page 19. 20. 21. 22. 23. 24. 25. 26. 27.
No.185 Define bandwidth and carrier swing. Page No.188,190 What do you mean by Sky wave (or) ionospheric propagation? Page No.183 What are the advantages and disadvantages of digital communications? Page No.209 What are the advantage and disadvantages of AM? Page No.189 Merits and De-merits of satellite communications. Page No.213-214 Disadvantages of FM. Page No.191 State the principle of radar. Page No.206 Problems: from text book example, (Vol-2) page no: 214. 10-2. Problem : From book-back: Page No: 217, 10.33 (Model)

Sl. No 1 2 3 4 5 6 7 8 9 10

UNITS ELECTROSTATICS CURRENT ELECTRICITY EFFECTS OF ELECTRICITY CURRENT ELECTRO MAGNETIC INDUCTION AND A/C ELECTRO MAGNETIC WAVES AND WAVE OPTICS ATOMIC PHYSICS DUAL NATURE NUCLEAR PHYSICS SEMI CONDUCTOR DEVICES COMMUNICATION SYSTEMS

Q.No 51 52, 53 54 55 56 57 58, 59 60 61 62

To write 51

Total Questions: 8

Note: Normally problems more chance, from this chapter. (Text book examples or self evaluation). If problem is not given, chance from text

31

book back Question. Refer March 09 and October 09 question papers.

Page No.42,43 For book-back questions.

15. Problems from text book examples. (Vol.I) - Page No.33-40.

1.4(C.P), 1.5(C.P), 1.9(C.P), 1.13(Mar 06), 1.16(June 09). 16. Problems from book-back problems, Page No.43-45 1.42, 1.45, 1.46, 1.47 1.49(C.P, Model Paper & June 08), 1.53(Oct 08) 1.54 (C.P in June 07), 1.55, 1.56, 1.58, 1.59(June 06, Oct 06).

1. Write the properties of electric lines of forces. Page No.7 (Mar 07 &
08, Oct -07, Mar 10)

2. Define electric potential at a point. Obtain an expression for electric potential due to a point charges. Page No.12,13 (Mar 09) 3. What is electrostatic potential energy of a system of two point charges? Deduce an expression for it. Page No.15,16 (Oct 09) 4. Prove that the energy stored in a parallel plate capacitors e is
Page No.28

To write 52 and 53

Total Questions: 19

5. Explain working method of Van-de-Graaff generator. Page No.30,31 6. Deduce an expression for the capacitance of the parallel plate capacitor. Page No.26 (June 10) 7. Derive an expression for the torque acting on the electric dipole when placed in a uniform electric field. (Oct 10) Page No.11 8. Find the effective capacitance of capacitors connected in parallel. Page
No.28 9. Find an expression for the field due to an Infinitely long straight charged wire. Page No.18 10. Find an expression for the electric field due to an infinitely charged plane sheet. Page No.19 11. State coulombs law and derive its vector equations. Page No.3, 4, 5. 12. Explain the principle of capacitor. Page No.22 13. Explain the electric potential energy of an electrical dipole in an electrical field. Page No.14

Note: Chance for one question and one problem. Compulsory problems is given in (Mar 07, June 10 and Oct 10) 3 Times, from this chapter. 1. Explain the working of a Leclanche cell with a diagram. Page
No.66-67 (June 07)

2. 3. 4. 5. 6.
7. 8.

How will you compare the e.m.f.s of 2 cells using potentiometer?

Page No.61,62 (Mar 07, Oct 08)

Obtain the condition for bridge balance in wheat stones bridge

Page No.57-58 (Mar 06 & 08, June 06 & 09, Oct 06, Mar 10)

If two or more resistors are connected in parallel derive an expression for the effective resistance. Page No.53 (Oct 06) Write any five applications of super conductors. Page No.51 (Oct
08, Mar 09)

14. Using Gauss Theorem, Determine the field due to an infinite long straight wire. Page No.17,18

9.

Explain how Metre Bridge is used to find the resistance of the wire . Page No.59 Define mobility. Establish a relation between drift velocity and current. Page No.47-48 (Mar 06) State and verify Faradays second law of electrolysis.How is it verified experimentally? Page No.63,64 (June 06, Mar 08) State and explain Kirchhoffs second law for electrical network
Page No.56 (June 07)

32

10. Explain the principle of potentiometer. Page No.60,61 (Oct 07) 11. Explain the action of lead acid accumulator. Page No.68 (Oct 07) 12. Explain the determination of the internal resistance of a cell using voltmeter. Page No.54-55 (June 08, Oct 09) 13. State the Faradays first law of electrolysis and describe the experimental verification. Page No.63(June 08, Oct 09) 14. Explain the construction and working of Daniel cell. Page No.66
(Oct 08, June 09, 10)

3. 4. 5. 6. 7.

Explain in detail the principle and construction of a Tangent galvanometer. Page No.91(Diagram, theory not necessary)(Oct 08) State and explain Biot-Savart law. Page No.87,88 (June 09) Show that the force acting on a current carrying conductor placed in a magnetic field is Page No.98-99 Deduce an expression for the force on a current carrying conductor placed in a magnetic field. Page No.98-99 Explain how a galvanometer is converted into a voltmeter. Page

15. State Ohms law. Derive the relation between the current and potential difference. Page No.48-49 16. Find the effective resistance of the resistors connected in parallel and series. Page No.53 17. Define the term specific resistance. How will you find this using metre bridge? Page No.59-60 18. Derive the relation between current and drift velocity. Page No.48 19. Problems from Textbook examples: Page No.69-74
2.2 (Mar 09), 2.6, 2.7, 2.9, 2.10 (C.P in June 10), 2.11(C.P in Oct 10), 2.12 (C.P in Mar 07).

20. Problems from Book-back: Page No: 76-78. 2.30 (Compulsory Problems), 2.33(Mar 10, C.P in Mar07), 2.36, 2.42, 2.44 (C.P in Oct 10), 2.45 To write 54 1. 2. Total Questions: 10

No.108 (repeated) 8. Find an expression for the force between two long current carrying conductors. Page No.101 9. Write a note on Thermopile. Page No.85, 86. 10. Problems from textbook examples Page No.112-117 3.3(C.P in Model Paper 5), 3.4(Oct 07), 3.5(Repeated in Model Paper), 3.6(C.O in model Paper), 3.11(Repeated problems in model paper), 3.13(June 10, C.P in Oct 09), 3.16 (Mar 07 & C.P in Mar 09), 3.18 (June 08). 11. Problems from Book-back. Page No.120-121. 12. 3.30 (Mar 06, Oct 06 and C.P in Mar 09), 3.32 (C.P in Model Papers), 3.34, 3.35 (June 06 & C.P in Oct 09), 3.37, 3.39(Oct 10 and C.P in Model Papers), 3.40.

To write 55

Total Questions: 14.

Note: Compulsory problem given from this chapter in Mar 09 and Oct 09 What are the special features of magnetic Lorentz force? Page No.95-96
(June 07)

Note:Normally Q.No 55 is from Unit 4, Chances for book-back questions. Page No.158-159. Till now, In all the previous board papers (Mar
06-Oct 10), Compulsory problem is not given from this chapter. So chances for problems for the next board exam. Problem was given only once in June 09 (Eg.4.5)

Explain the conversion of a galvanometer in to an ammeter. Page No.106 (Mar 07)

33

1.

2.

Define the Efficiency of a transformer. What are the reasons for various energy losses in a transformer? Explain how they can be minimized. Page No.138-139 (June & Oct 06) Obtain the phase relation between current and voltage in an a.c circuit with an inductor only (graph not necessary) Page No.143144 (Mar 06 & 08)

To write 56

Total Questions: 23

Note: More chance for book back questions. Compulsory problem is given only in (Oct 07, 08, Mar 10), 3 Times from this chapter. 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. Write a note on piles of plates. Page No.198 (Mar 06, June 09) Explain polarization by reflection. Page No.197 State and prove Brewster law. Page No.197 (June 06, 07 & 08, Oct
06, Mar 09, June 10)

3. 4. 5.

What are eddy currents? Give their application. How are they minimised? Page No.136 Explain how an e.m.f can be induced by charging the area enclosed by the coil. Page No.132 (June 07, Oct 07 & 08, Mar 09) Explain the mutual induction between two long solenoids. Obtain an expression for the mutual inductance of a long solenoid. Page
No.130 (June 08)

6. 7. 8. 9. 10. 11. 12. 13.

Derive the expression for the self inductance of a long solenoid.

Page No.126-127

Write a note on Nicol prism. Page No.199 (Mar 07, Oct 09) Explain the Phenomenon of total internal reflection by using wave theory. Page No.199 Explain Huygens principle. Page No.176 What are Fraunhofer lines? How is it useful to study the suns atmosphere? Page No.169,170 State any five characteristic of electromagnetic waves. Page
No.163-164

Explain A.C circuit with resistor only. Page No.142-143

(June 08)

Calculate the energy associated with an inductor. Page No.127128

Describe the principle, construction and working of a choke coil.

Page No.150-151 Give the application of eddy currents (Mar 07) Page No.134-137 Explain long distance power transmission Page No.139-140 Problems from textbook examples. Page No.151-155 4.3, 4.5(June 09), 4.7, 4.8, 4.9, 4.10. Problems from Book-back. Page No.159-160 4.54, 4.56, 4.57, 4.59, 4.60, 4.64

State and explain Raman Effect. Page No.173 Describe Rayleigh scattering in detail. Page No.173 Explain double refraction. Page No.198-199 Give the difference between interference and diffraction. Page
No.194 (Oct 10)

13. Bring out the differences between ordinary and extraordinary light. Page No.199 14. What are Newtons rings? Why the centre of the Newtons ring is dark? Page No.187 15. What is meant by optical rotation? On what factors does it depend? Page No.201-202 16. How are (i) wavelength of light and (ii) refractive index of a liquid determined using Newtons rings? 17. Derive an expression to the radius of Newtons nth dark ring and hence explain the applications of Newtons rings. Page No.189

34

Explain the types of emission spectra Page No.168 Describe reflection of plane wave front using wave theory. Page No.177 Describe the uses of Polaroids. Page No.200-201 Problems from textbook examples Page No.203-205 5.3(Model, Given as C.P in Oct 09, 08), 5.7(Mar 08, C.P in Mar 10) 22. Problems from Book-back Page No.209 5.40, 5.42 (C.P in Oct 08), 5.43 (C.P in Oct 07), 5.46, 5.47 (C.P in Mar 10), 5.48

18. 19. 20. 21.

11. Explain the working of He-Ne Laser with the help of energy level diagram. Page No.38 12. Probe the energy of an electron for Hydrogen Aton in nth orbit (Oct 07) Page No.15 13. Explain how Braggs X-Ray spectrometer is used to determine the
wavelength of X-Rays. Page No.30 14. Wavelength of Balmer Second line is 4861 A. Calculate the wavelength of the first line (Repeated Problem) Page No.13 15. Derive an expression to the radius of nth orbit of an electron based on Bohrs theory. Page No.14

To write 57

Total Questions: 18

Note: Normally Q.no 57 will come from Atomic physics. Chance for a question or problem. Till now (Mar 06- Oct 10), C.P is not given from this chapter. So chances for C.P for this March 11. 1. Mention the properties from x rays. Page No.27 2. 3. 4.
(June 06) Describe Lane experiment, which are the facts established by it. Page No.28 (Oct 06) Short comings of Bohrs Theory? Page No.21

16. Describe industrious applications and medical applications of Laser Light. Page No.39 17. Describe the scientific and engineering applications of X-Rays. Page 18. 19. 20.
21. No.34 Explain the properties of canal rays. Page No.3 Describe the defects of Rutherfords atom model. Page No.12 Problems from text book examples Page No.42-45 6.2, 6.4 (Mar 08), 6.5(Mar 07), 6.7(Oct 07), 6.8(June 07). Problems from Book-back questions. Page No.49-50 6.45 (Oct 10), 6.46, 6.47, 6.48.

Explain the spectral series of hydrogen atom without diagrams.

Page No.16 (Mar 06, Mar 10m June 10) 5. State and obtain Braggs law. Page No.29 (June 08, Oct 09) 6. Write any five properties of cathode rays. Page No.2(Oct 06, June09) 7. Explain the origin of characteristic x-rays. Page No.32 (Mar 09) 8. Explain the production of x-rays in Coolidge tube. Page No.25 9. Explain the origin of continuous x-ray spectra. Page No.32 10. Explain the production of canal rays. Page No.2,3

To write 58 and 59

Total Questions: 24

Note: Normally Q.no 58 and 59 will come from dual nature of radiation. One question and one problem may come from this chapter. Compulsory problem was given in June 2009 from this chapter.

35

1. 2. 3. 4. 5. 6. 7. 8. 9.

Explain the construction and working of a photo emissive cell with diagram. Page No.57 (Oct 08) Describe Hallwachs experiment for they study of photo electric effect? Page No.51 (repeated) Discuss the effect of frequency of incident radiation on stopping potential. Draw graph. Page No.53-54 Explain the wave mechanical concept of an Atom. Page No.60 (Oct
07)

Define work function state law of photo electric emission. Page

No.55 (Mar 07)

17. Explain the construction and working of electron microscope. Draw neat sketch. Page No.61 18. What is photoelectric effect? Explain With the help of a graph. Explain the effect of intensity if incident radiation on the photoelectric current. Page No.51 19. State the postulates of special Theory of relativity. Page No.64 20. Discuss the concept of space, time and mass. Page No.63 21. Explain the frame of reference. Page No.63 22. What is photoelectric effect? State the laws of photoelectric emission 23. 24. 25. 26.
(Mar 09) Derive an expression to the D-broglies wavelength associated with accelerated electrons. Page No.59 Describe photo emission cell. What are its applications. Page No.57-58 Problems from text book examples: Page No.68-67 7.2(Oct 09), 7.8(Oct 08), 7.9 Problems from Book-back Page No.74 7.33, 7.39 (As C.P in Model Papers), 7.48, 7.40 (C.P in June 09)

Explain Lorentz Fitzgerald contraction, with examples? Page

No.64 (Mar 06 & 08)

Obtain Einsteins photoelectric equation. Page No.55-56 (Mar 06

June 06, Oct 09)

Explain time dilation with an example. Page No.65

Mar 08)

(Mar 06 &

Write any five applications of photoelectric cell. Page No.57-58 (Oct

06, June 07, Mar 08, June 08 & 09)

10. Derive an expression for De Broglie wavelength of matter waves.

Page No.58 (Oct 06, Mar 07 & 09)

11. Obtain Einsteins Mass-energy equivalence. Page No.65-66(June 07) 12. Explain the variation of photoelectric current with applied voltage.
Page No.52-53

To write 60

Total Questions: 11

13. Explain Einsteins theory of photoelectric effect. 14. Explain length contraction on the basis of relativity 9Mar 10, Oct 10). Page No.64 15. Explain the effect of potential difference on current. Page No.52 16. What is photo electric cell? Explain its working.

Page No.55-56

special theory of the photoelectric

Page No.57

Note: Normally Q.No is 60 is from nuclear physics, nearly all examples and all book back problems were given as problems or Compulsory problems in board papers or model papers. Compulsory problems were given in (Mar 06, June 06, Oct 06, Mar 08, June 08), 5 times in board papers. 1. If the mass defect of the nucleus 6C-12 is 0.098 amu. Then calculate the binding energy per nucleon. (June 07)

36

2. 3. 4. 5. 6. 7. 8.

Write a note on the biological hazards of nuclear radiation . Page No.92

(Oct 08)

Explain how a cosmic ray shower is formed Page No.105 (Mar 07) Explain the latitude effect of cosmic rays. Page No.106 (June
09,Oct 07)

Explain the different characteristics of nuclear forces. Page No.82 Explain the variation of binding energy with mass number by a graph and discuss its features. Page No.79-80 Explain the construction and working of an atom bomb. Page
No.98-99

Explain how liquid drop model of the nucleus can account for nuclear fission. Page No.96 9. Explain how carbon nitrogen cycle can account for the production of stellar energy. Page No.104 10. Give an explanation for the binding energy curve (Graph not needed) (June 10) Page No.79-80 11. Write the properties of alpha rays (Oct 10) Page No.89 12. Derive the expression N=Noe -t for radioactive disintegration Page No.86 13. Explain the principle, Construction and working of a G.M Counter. 14. 15. 16. 17. 18. 19. 20. 21. 22. Problems: from text book example, (Vol-2) Page No.109-115.
Page No.94 State any 5 properties of neutrons. Page No.89 Describe the properties of beta rays. Page No.84 Write a note on elementary particles. Write a note on Atom Bomb. Page No.97-98 Describe Radioactive displacement law. Page No.86 What are the results obtained in binding energy curve? Page No.79-80 Describe application of radio isotopes. Page No.90 Describe the properties of nuclear force. Page No.82

8-1 (compulsory problem in model papers) 8-2 (Mar 09) 8-3, 8-4 (repeated in model papers) 8-5 (Mar 08) 86.8-7 & 8-10 (compulsory problem in Mar 06) 8-8 (repeated) 8.9 (compulsory problem in Oct-06, June-08, as well as in few model papers) 23. Problems: from solution book, page no 63. 8-47 (Oct 07) 8-49 (compulsory problem in June 06) 8-50 (compulsory problem in model papers) 8-51 (repeated) 8-53 (compulsory problem in Oct 06, Mar 08) 8-54 (compulsory problem in June 06 & 08, Oct 09) 8-55, 8-58 & 8-60 (both combined as compulsory problem in few model papers). 8-61 (compulsory problem in few model papers)

To write 61

Total Questions: 21.

Note: Normally Q.no 61 will come from Semi conductor devices. Question or problem has more chances. Only in June 10, Problem was given from this chapter. Till now, compulsory problem has not been asked from this chapter. 1. 2. Explain bridge rectifier with neat circuit diagram. Page No.133
(June 06)

With a circuit diagram, explain voltage divider biasing of a transistor. Page No.145 (Mar 07, June 09)

37

3. 4. 5. 6. 7. 8.

Draw the frequency response curve of single stage CE amplifier and discuss the result. Page No.146 (Mar 08) What is an AND gate? Explain the function of AND gate using electrical circuit and using diodes. Page No.157 (June 08) Explain the circuit symbol and pin out configuration of an operational amplifier. Page No.164 (Oct 08) Explain the forward biased characteristics of PN junction diode.
Page No.129

19. Describe the voltage divider bias of a NPN transistor. Page No.145-146 20. Problem from text book example Page No. 172-175
9.1, 9.2 (June 10), 9.6, 9.8, 9.9

21. Problem from Book back questions. : Page No.179, 179

9.53 (Model Paper)

State and prove De Morgans Theorems. Page No.161

Oct 06,10 & 09)

(Mar 10, 06,

To write 62

Total Questions: 22

Define current amplification factor and and obtain the relation between them. Page No.140 (June 07) 9. Explain the function of a transistor as a switch. Page No.143(Oct 07) 10. Explain the working of a half wave diode rectifier. Page No.132(Mar
09)

Note: Normally Q.No 60 will come from Communication systems. Till now (Mar 06- Oct 10), Problems were not given from this chapter. 1. 2. 3. 4. 5. 6. 7. 8. What are the advantages and disadvantages of digital

communication Page No.209

(Mar 06, June 06, 08 & 09)

Explain space wave propagation of radio waves. Page No.183 (Oct 06) Explain the function of a straight radio receiver. Page No.194 Explain the function of a FM super heterodyne receiver with a diagram.
Page No.196 (Oct 08, Mar 09)

11. Explain, how operational amplifier is used as summing Page

No.167

12. 13. 14. 15.

Explain the principle of feedback amplifier. Page No.148 Explain the transistor circuit configurations. Page No.139 Explain half wave rectification. Page No.132 Sketch a neat diagram of a full wave rectifier using diodes. Explain its working. Page No.133 16. Describe the construction of Zener diode and mention, how it used as a voltage regulator? Page No.135 17. Compare intrinsic and extrinsic semiconductor. Page No.125-126 18. What is an EXOR gate? Give the Boolean expression for the EXOR operation. Page No.159

Explain analog and digital communication. Page No.208 Write a note on wire and cable used for Telecommunication system. Page No.210, 211 What is an optical fibre? Mention the advantages of fibre optical communication system. Page No.211 dements. Page No.212-214
(Mar 08)

Write a note on satellite communications. Give its merits and

38

9.

Mention the principle of RADAR and write its applications. Page

No.206
(Mar 07, 10)

22. Write a short note on fibre optical communication and mention its advantage (June 07). Page No.211, 212

10. Draw the block diagram of AM radio transmitter and explain its function.
Page No.192 (Oct 07, 10)

11. Explain the function of FM transmitter, with a neat diagram. Page

No.193 (Oct 08, 09, June 10)

Sl. No
1 2 3 4 5 6 7 8

UNITS
ELECTROSTATICS EFFECTS OF ELECTRICITY CURRENT ELECTRO MAGNETIC INDUCTION AND A/C ELECTRO MAGNETIC WAVES AND WAVE OPTICS ATOMIC PHYSICS NUCLEAR PHYSICS SEMI CONDUCTOR DEVICES COMMUNICATION SYSTEMS

No. of Qus. 8
1 1 1 1 1 1 1 1

Q.No
63 64 65 66 67 68 69 70

12. Explain the merits and demerits of frequency modulation. Page

No.190-191

13. Explain super heterodyne receiver (AM) with block diagram. Page
No.194-195

14. Explain the working of simple radio receiver with a block diagram. What are its disadvantages? Page No.194 15. Explain frequency modulation transmitter with block diagram.
Page No.193

16. How is flicker effect removed during interlaced scanning? Page

No.200

17. Explain the function of various units in the monochrome television transmission. Page No.203 18. Explain the ground wave propagation. Page No.182 19. Explain amplitude modulation. Page No.186 20. Explain the operation of Facsimile. Page No.210 21. Explain the variation of motion of radio waves at different angles of incidence. Page No.184-185
(repeated)

Note: Normally no ten marks question from Dual nature and Current electricity.

39

point charge. Page No.12-13 To write 64 Note: Normally two marks combined as 10 marks from this chapter. To write 63 NOTE: Chance from book question for this march 2010. Refer text book page no: 42, 43 (vol-1) 1. 2. 3. 4. 5. 6. 7. 8. 9. What is an electric dipole? Derive an expression for the electric field due to an electric dipole at a point on its axial line. Page What is an electric dipole? Derive an expression for electric potential due at a point to an electric dipole discus the special cases. Page No.14-15 (Oct 06, Mar & June 08, repeated) Deduce an expression for equivalent capacitance of capacitors connected Page No.27-28 (i) parallel (ii) series. Principle, construction and working of Van de Graaff generator. Derive an expression for electric field due to an electric dipole at a point along the equatorial line. Page No.9-10 (Mar 07, June 09) Explain the principle of a capacitor. Deduce an expression for the capacitance of a parallel plate capacitor. What is capacitor? Page State Gausss law. Applying this calculate electric field due to (i) an infinitely long straight charged with uniform charge density (ii) an infinitely plane sheet of charge of q. Page No.17-19. What is dielectric? Explain the effect of introducing a dielectric slab between the plates of a parallel plate capacitor. Page No.24Define the electric potential at a point. Is it a scalar or vector quantity? Obtain an expression for electric potential due to a
26 No.22-26 Page No. 30-31(Oct 08 & 09) (June, Oct 07) No. 8-9 (Mar 06 & 09, June 06, June 10, Oct 10)

1. 2. 3. 4.

Discuss the motion of a charged particle in a uniform magnetic field. Define magnetic Lorentz force.(June 10) Page No.95-97 Explain the principle, construction and working and limitations of a cyclotron. Page No.97-99 (Mar 07, Oct 10) Obtain an expression for the torque experienced by a current loop in a uniform Magnetic field. Page No.14-15 Obtain expression for a magnetic induction due at a point to infinitely long straight conductor carrying current. Write expression for the magnetic induction when the conductor is place in a medium of permeability. Page No.88-89 (June 06, Oct 09,
Mar 10)

5.

6.

Apply Biot Savart law, obtain an expression for the magnetic induction at a point due to infinitely long straight conductor carrying current. Page No.87-89 (Mar 06, Oct 09, repeated) Define amperes circuit law. Applying it find the magnetic induction at a point due to solenoid carrying current. Page No.9295 (Oct 06, June 09)

7. 8.

State Joules law. Explain Joules calorimeter experiment to verity Joules law of heating. Page No.79-81 (June 07) Deduce the relation for the magnetic induction, at a point along the axis of a current coil carrying current. Page No.89-90 (Oct 07,
Mar 08)

9.

Explain in detail the principle, construction and theory of a tangent galvanometer. Page No.91-92 (June 08)

40

10. Deduce expression for the force on a current carrying conductor placed in a magnetic field. (Oct 08) Find the magnitude of the force. (Mar 09) Page No.99-100 11. Explain the principle, construction, theory of moving coil galvanometer. Page No.103-105 12. Deduce an expression for the magnetic dipole of moment of a revolving electron. Page No.110-111

Page No.150-151

7. 8.

Explain A.C current containing resistor, inductor and capacitor in series. Page No.146-147
In an ac circuit containing a capacitor, the instantaneous emf is e=Eosint. Obtain the expression for instantaneous current. Explain the phase relation between emf and current by graph. (Oct 06) Page No.144 State Lenzs law and illustrate through an experiment. Explain how is it in accordance with the law of conservation of energy? Page No.124-125 Explain the mutual induction between two long solenoids. Obtain an expression for the mutual inductance. Page No.128-129 Obtain an expression for the current flowing in a circuit containing resistance only to which alternating emf is applied. Find the phase relationship between voltage and current. Page No.142-143 Obtain an expression for the current flowing in a circuit containing resistance only to which alternating emf is applied. Find the phase relationship between current and voltage. Page No.144-145 Describe the principle, construction and working of three phase a.c generator. Page No.135-136

9. 10. 11.

To write 65 Note: Normally Questions will be twisted type. So prepare well. Chances for book-back. Refer Page No.158-159 1. Principle, construction, theory of a transformer. Define its efficiency mention the energy losses and working of transformer.
Page No.137-138 (Mar 06)

12.

13.

2. 3.

Describe principle, construction, and working of a single phase A.C generator. Page No.133-134 (Mar 07 & 08, June 07, Oct 08, 07) Discuss theory of inducing e.m.f in a coil by changing its orientation with respect to the direction of the magnetic field. Page
No. 132-133(June 08, Oct 09)

14. A source of alternating emf is connected to a series combination of a resistor R, L, C. Refer the page 159 (4.53) Page No.146-147
(June 06, 09)

4.

Obtain the phase relation between voltage and current in an A.C circuit containing a pure inductance. Draw the necessary graph.
Page No.143-144 (Oct 08)

To write 66 Note: Normally question from book back chance. Two 5 marks questions combine as 10 mark (chance) 1. Explain Raman scattering of light with the help of energy level

5. 6.

What are eddy current? Explain their applications. How are they minimized? Page No.136-137 (Mar 09) Describe principle, construction, and working of a choke coil.

41

2. 3. 4. 5. 6.

diagram. Page No.173-175 (Mar 07, Oct 07) Discuss an experiment to demonstrate the transverse nature of light. Page No.194-195 Obtain an expression for the radius of the n th dark ring in Newtons rings. Give its applications. Page No.189 Explain Polarisation by reflection. Derive Brewsters law and describe the working of pile of plates. Page No.197-198 Write a note on (i) Nicol Prism (ii) Polaroid. Page No.199-200 On the basis of wave theory, explain total internal reflection. Write the conditions for the total internal reflection to take place.
Page No. 179-180 (Mar 06, June 06, 10, Oct 10, Mar 10)

16. Explain reflection and refraction on the basis of wave theory of light.
Page No.177-178

To write 67 Note: Normally Questions will be twisted way. So prepare well. 1. 2. 3. 4. State Bohrs postulates. Obtain an expression for the radius of n th orbit of hydrogen atom. Page No.12-13 (Mar 06, June 09) Draw a neat diagram of the He-Ne laser and explain its working with the help of energy level diagram. Page No.38-39(June 06) Draw a neat sketch of ruby laser. Explain its working with the help of energy level diagram. Page No.36-37(Oct 06 & 07, Mar 09) How will you determine the wavelength of x-rays using Braggs spectrometer. Write any five properties of x-rays. Page No.2730(Mar 07)

7.

What is known as interference? Derive an expression for band with of interference fringes in Youngs double slit experiment.
Page No.181-183 (Oct 06, June 07, Mar 09) Explain emission and absorption spectra.PageNo.168-169(June 09)

8. 9. 10.

11. 12. 13. 14.

State Huygenss principle on the basis of wave theory. Prove the laws of reflection. Page No.176-177 (Oct 08) Explain theory of interference in thin transparent film due to reflected light and obtain the condition for the intensity to be maximum and minimum. Page No.181 (June 08, Oct 09) What are called Newtons rings? Explain the experiment and theory of forming the Newtons ring. Page No.182 Discuss the theory of transmission grating. Page No.191-192 Explain the refraction of a plane wave front at a plane surface and state laws of refraction. Page No.178-179 What is meant by optical rotation? On what factors does it depend? Page No.201-202
Page No.173-175

5.

Derive Braggs law. Explain how a Braggs spectrometer can be used to determine the wavelength of x-rays. Page No.29-30 (June
07)

6. 7. 8.

Obtain the expression for the radius of nth orbit of an electron based on Bohrs theory. Page No.13-14 (Mar 08) Describe the J.J Thomson method for determine the specific charge of an electron. Page No.3-4 (Oct 09, 10, Mar 10, June 10) Explain the method of calculating ratio of semi major and semi minor axes of elliptical orbit of Sommer field atom model. Page
No.21-24

15. What is Raman Effect? Explain Raman Spectrum with diagram (Mar 08)

9.

Explain the production of X-rays using Coolidge tube. Page No.2526

42

10. Give an account for principle of laser, laser action and characteristic laser. Page No.34-35 11. Millikans oil drop experiment to determine the charge of an electron. Page No.5-7 (June 08, Oct 08) 12. Refer book back questions: (Vol-2) page no 48, 49.
6-21, 6-24, 6-25.

7. 8. 9.

period and decay constant. (Oct-08). Write the radioactive law of disintegration. (Oct 09) Page No.86-87 Compare the properties of alpha, beta and gamma rays. Page
No.84-87

Draw a neat sketch; explain the working of a nuclear reactor.

Page No.9-101

13. Find an expression for the total energy of an electron.

To write 68 Note: Normally book back question Chance. Refer Page No.118-119 1. 2. Explain the stellar energy with proton-proton cycle and carbonnitrogen cycle? Page No.104 What is the nuclear reactor? Explain the function of (i) moderator (ii) control rods (iii) neutron reflector. Mention the uses of nuclear reactor. (diagram not necessary) Page No.98-101 (Mar
06)

Describe the cosmic rays showers. Explain quark model of elementary particles. Page No.106-108 10. What are the nuclear forces? Give important properties of nuclear forces. Page No.82 11. Explain mass defect. Draw the graph of binding energy. What are the inferences from the graph? Page No.79-80 12. Describe the properties of cosmic rays. Page No.105 13. Derive the relation N=Noe -t. Derive an expression for Half-life. Page
No.86-87

To write 69 Note: Normally book back question chance. Refer Page No.117-178. 1. 2. 3. 4. With the circuit diagram, explain the working of a Bridge rectifier. Draw its input and output signals. Page No.133-134 (June 07) Explain with neat circuit diagram, the working of single stage CE amplifier Page No.146-147 (June 08, Oct 08, repeated) What is the rectification? Explain the working of Bridge rectifier with necessary wave forms. Page No.132-133 (Mar 06) Sketch the circuit of a Colpitts oscillator and explain its working.

3.

Describe the principle and action of a Bainbridge spectrometer in determining the isotopic masses.
No.80-81 (June 06, 07 & 08, Oct 06, Mar 09) (Mar 07, Oct 07, June 09)

Mass
Page

4. 5. 6.

Explain the construction and working of a GM counter.

Page No.94

What are cosmic rays? Explain the latitude effect and Altitude effect, regarding cosmic rays. Page No.13-106 (Mar 08) Obtain an expression for the amount of the radioactive substance present at any moment. Obtain the relation between half life

43

Page No.153 (June 06, Oct 06, Mar 08, June 09)

17. Describe the construction and working of a multimeter with a neat

diagram. Explain how is it used as a voltmeter and ohm-meter. Page No.170-171

5. 6. 7.

With a circuit diagram, explain the working of an operational amplifier as a summing amplifier. Page No.167 (Mar 07) Explain the action of an operational amplifier as difference amplifier. Page No.168 (Oct 07) What meant by feed back? Derive an expression for voltage gain of an amplifier with negative feedback. Page No.148 (Mar 09.
repeated)

To write 70

Total questions: 15

8.

What is operational amplifier? Explain its action as (i) inverting amplifier (ii) non inverting amplifier. (Oct 09. repeated) Page No.164167

Note: Normally Book back question chance more. Book-back may also be asked in a twisted manner. 1. Make the analysis of amplitude modulated wave. Plot the frequency spectrum and band width. Page No. 187-188(June & Oct
06, Mar 08 & 09, Oct 10, June 10)

9. 10.

11. 12.

13.

Describe the energy band structure of insulator, semi conductor and conductor. Page No.123-124 Describe the construction of cathode ray oscilloscope (CRO) working; describe various compounds with neat diagram and how it used to determine frequency and voltage. Page No.169-170 What is called amplifier? With a circuit explain the working of transistor as amplifier. Page No.143-144 With the help of neat circuit diagram, explain the output characteristic of an NPN transistor in CE mode and methods of finding the parameters of the transistor. Page No.140-142 Describe the working of a transistor amplifier with graph. Page
No.143-144

2.

With the help of a functional block diagram. Explain the operation of a super heterodyne AM receiver. Page No.194195(June 07)

3. 4. 5. 6.

Explain the construction and working of Monochromic picture tube Page No.201-203 Write a note on fiber optic communication. Mention its advantages. Page No.211-212 Write a note on satellite communication. Give its merits and demerits. Page No.212-214 With the help of a functional block diagram, explain the function of a monochrome TV receiver. Page No.204-205 (Mar 06,Mar 07,
repeated)

14. Draw the logic diagram and write the truth table for the following logic gates. (i) OR gate (ii) AND gate (iii) NOR gate (iv) EXOR gate (v) NAND gate. Page No.156-160 15. What is an IC? Explain the classification of IC by its construction.
Page No.154

7.

With the help of block diagram, explain the function of various units in the monochrome television transmitter. Page No.203-204
(June 08, Oct 08 & 09)

8.

16. Explain the working of half wave diode rectifier. Page No.132

Explain the construction and working of a vidicon camera tube with neat diagram. Page No.197-198 (June 07)

44

9. 10. 11. 12.

13. 14. Write about radar. (Principle, Working and applications. Page No.206208 15. Explain analog and digital communication. Page No.208-209 16. Explain the working of a FM transmitter using block diagram. Page No.193 17. Explain the method of black and white TC telecast with the help of a block diagram.

With the help of block diagram, explain the transmission and reception of radar signals. Page No.206 (repeated) Describe scanning and synchronizing in television. What are different types of wire and cable used for telecommunication system? Page No.209-211 With the help of block diagram, explain the function of AM transmitter. Page No.192-193 Explain frequency modulation. Page No.189-190

1. Electric potential energy (u) of two point charges is

a) b) c) PE cos d) PE sin

2. A hollow metal ball carrying an electric charge produces no electric fields at points
a) Outside the Sphere b) On its surface c) Inside the Sphere d) At a distance more than twice.

3. The unit of electric field is

a) Volt/metre b)Volt x metre c) Volt/metre2 d) Coulomb/metre2

4. Which of the following quantities is scalar?

(For Practice)

Part I
Note: (i) Answer all the questions (ii) Choose and write the correct answer (iii) Each question carried one mark

a) Displacement b) Electric force c) Electric Field d) Electric potential

5. Ohms law is true for

a) Conductors only b) Semi conductors c)Both d)Neither a or b

45

and 550w refrigerator? 6. The current produced due to orbital motion of electron is
a) b) c) d) a) 55A b) 2.5A c) 0.4A d) 44A

11. Which of the following devices doesnt allow D.C current to pass through?
a) Resistor b) capacitor c) inductor d) all of the above

7. The number of turns of a coil of radius 20cm required to produces a magnetic field of 5 x 10 -4T.
a) 50 b) 25 c) 500 d) 100

12.Cores of chokes used in low frequency AC circuit is made of

a) Stelloy b) Mumetal c) Iron d) Aluminium

8. In a three phase AC generator, the three coils are inclined at angle of

a) 45 b) 90 c) 120 d) 90

13.Instrument used to determine the optical rotation produced by the substance is

a) Interferometer b) Photometer c) Polaris cope d) Polari meter

9. Flux loss can be minimized by using

a) Wires of low resistance b) Using laminated core made of mumetal c) shell type of core d) laminated core made of alloy.
14.

If the velocity of light in a medium is 2.25 x 108m/s, then the refractive index of the medium will be
a) 1.5 b) 0.5 c) 1.33 d) 1.73

10.How much current is drawn by the primary coil of a transformer connected to a 220V supply, when it delivers power to an 110V

46

a) 21 b) 65 c) 41 d) 52

15.In a Newtons ring experiment, the ratio of the radii of 4 th and 9th ring is
a) 4:9 b) 2:3 c) 16:81 d) 2: 3

20.

The wavelength of photon having an energy of 413eV is

a) 1018Hz b) 10 17Hz c) 10 17Hz d) 10 15Hz

16.When an electron jumps from M-shell to Vacant K-shell, it contributes

a) K-line b)K-line c) L-line d) L-line

21.Number of neutrons in 17Cl35 atom is?

a) 17 b) 18 c) 35 d) 19

22. 17.The size of an atom from Rutherford experiment is

a) 10-10m b) 10 -16m c) 10 -14m d) 10 -12m

The nucleons in a nucleus are attracted by

b)Nuclear Force d) Electrostatic Force.

a) Magnetic Force c) Gravitational Force

18.The charge of an oil drop is 12.82 x 10-19C, then the number of elementary charges are
a) 6 b) 2 c) 7 d) 8

23.

The wavelength of matter waves is independent of

a) Mass b) Velocity c) Momentum d) Charge

19.In Hydrogen atom, which of the following transition produces spectral line of maximum wavelength?

24.

Nuclear fission can be explained by

b) Liquid drop model d) Bohr-atom model

a) Shell model c) Quark model

47

a) 100A b) 1000mA c) 1mA d) 0.1mA 25. Electrons in the atom of an element which determines its

chemical and electrical properties are called

a) Valence Electron b) Revolving electron c) Excess electron d) Active electron

29.

The human voice (or) music contains waves with a frequency

b) 30- 300 Hz c) 3000- 30,000 Hz d) 300-3000 Hz

range of
a) 3- 30 Hz

26. The gain of the amplifier is constant at _______ range a) Low frequency c) High frequency b) mid-frequency d) both low and high frequency

30.

If 900 KHz station is turned, then the local oscillator will

b) 455KH c) 10.7mHz d) 1355 Hz

have to produce a frequency of

a) 600 KH

Part - II 27. An oscillator is

Note: Answer any fifteen questions. 31. What is a capacitor? Define its capacitance. 32. A sample of HCl gas is placed in an electric field of 2.5 x 10 4 NC-1. The dipole moment of each HCl molecule is 3.4 x 10 -30 cm, find the maximum torque that can act on a molecule. 33. Distinguish between electric power and electric energy. 34. Why is copper wire not suitable for a potentiometer? 35. What is meant by transition temperature in super conductors? 36. Define: Ampere. a) An amplifier with positive feedback b) Converter of a.c to d.c voltage c) An amplifier with negative feedback d) An amplifier without feedback

28.

In a transistor with =40, the base current is 25A. Then the

collector current (Ic) is

48

37. A capacitor blocks D.C but allows A.C why? 38. Write the equation of a 25 cycle current sine wave having rms value 30A. 39. Write the conditions for sustained interference. 40. In a Youngs experiment, the width of the fringes obtained with light of wavelength 600 is 2m.m. Calculate the fringe width if the entire apparatus is immersed in a liquid of refractive index 1.33. 41. State: Moseleys law. 42. What are hard and soft X-Rays? 43. At what speed is a particle moving if the mass is equal to three times its rest mass? 44. What is meant by breeder reactor? 45. What is meant by binding energy of a nucleus? 46. What is Zener breakdown? 47. Differentiate between Linear ICs and Digital ICs. 48. Give the Barkhausen criteria for oscillation. 49. When the negative feedback is applied to an amplifier of gain 50, the gain after feedback falls to 25. Calculate the feedback gain. 50. What is phase modulation?

(ii) Answer any six questions of the remaining 11 questions. (iv) Draw diagrams wherever necessary. 51. Two charges +q and -3q are separated by a distance of 1m. At what point on its axis is the potential zero? 52. Explain the principle of a potentiometer. 53. Explain the reactions at the electrodes of Lechlanche cell. 54. Deduce an expression for the force on a current carrying conductor placed in a magnetic field. 55. A coils is connected across 250V, 50Hz power supply and it draws a current of 2.5 A and consumes power of 400W. Find the self-inductance and power factor (or) A coil of 100 turns and resistance 100 is connected in series with a galvanometer of resistance 100 and the coil is placed in a magnetic field. If the magnetic flux linked with coil changes from 10-3 Wb to 2 x 10 -4 Wb in a time of 0.1s, calculate the induced e.m.f and current. 56. Explain Huygens principle. 57. Derive an expression for Rydbergs constant. 58. Explain length contraction. 59. A carbon specimen found in a cave contained a fraction of 1/8 of C14 to that present in a living system. Calculate the approximate

Part - III
Note: (i) Answer the question no. 55 compulsorily.

49

age of the specimen. Given T1/2 for 6C14 = 5560 years. 60. Explain the working of a half wave diode rectifier. 61. Describe the different types of wire and cable used in data communication. 62. Explain Einsteins theory of photoelectric effect.

moment. 69. Describe the energy band structure of insulator, semiconductor and conductor. 70. With the help of a block diagram, explain Monochrome TV Transmission.

Part IV
Note: (i) Answer any four questions in detail. (ii) Draw diagrams wherever necessary. 63. Explain the principle of a capacitor. Deduce an expression for the capacitance of a parallel plate capacitor. 64. Describe the principle, construction and working of a cyclotron. 65. Obtain an expression for the current flowing in the circuit containing capacitance only to which an alternating e.m.f is applied. Find the phase relationship between current and voltage. 66. Discuss the theory of interference in thin transparent film due to reflected light and obtain the condition for the intensity to be maximum and minimum. 67. Describe Millikans oil drop experiment to determine the charge of an electron. 68. State radioactive law of disintegration. Obtain an expression to deduce the amount of the radioactive substance present at any

50

10 11

Chemical Equilibrium II Chemical kinetics II Surface Chemistry Electro chemistry I Electro chemistry II Isomerism Hydroxy derivatives Ethers Carbonyl compounds Carboxylic acids Organic Nitrogen Compounds Biomolecules Chemistry in action

2 1 3 1 1 2 1 1 3 2 -

Volume I INORGANIC
S. No 1 2 3 4 5 6 7 8 9 Chapters Atomic structure II Periodic classification II P-block elements D-block elements F-block elements Co-ordination Chemistry Nuclear chemistry Solid state II Thermodynamics II Max .Questions 2 1 1 2 2 1 1 1 2

12 13 14 15 16 17 18 19 20 21 22

51

Total

30

10

July 2007, Mar-09, June 10.

Additional Questions: Total - 36

Note: There are no one Mark Questions from Electro Chemistry II, Isomerism and Chemistry in Action. Hint: Prepare one marks from the following topics: Verification of Wave and Particle character, Significance of De-Broglie equation, De-Broglie waves, Negative Electronic Energy, Shapes of Orbitals, Molecular Orbital Theory, Hybridization (Refer Pg. No.26-Examples), Hydrogen Bonding. 1. 2. 3. 4. 5. 6. 7. 8. 9. The wave associated with particles is called matter wave. Concept used in the construction of electron microscope is De Broglie. Molecular orbital with less energy is 1s. Circumference of the circular orbit of an electron should be an integral multiple of de Broglie wave length.(Oct-2006) The number of nodal planes of 5s orbital is four. Sicl4 is involved in Sp3 hybridisation. Type of hybridisation in NH 4+ ions is Sp3. The type of bond present between HF(or) H 2O molecule is intermolecular hydrogen bonding.(Oct-2008) Particle nature of electron can be proved by J. J. Thomsons e/m ratio experiment.

Chapter I ATOMIC STRUCTURE

Total of one mark questions from this chapter is 2. Note: Normally one question is from Book Back. (In all the previous March papers (Mar06, 07, 08, 09&10) Book Back is only being asked.) Book back questions are also asked in a twisted manner, options might be interchanged, so be careful while answering. Refer (Vol. - I) Page 29 & 30. Q. No 1 2 3 4 5 6 7 8 9 OPTIONS B C D A C B C D B June 2008 Oct-2007, 08, Mar 06, June-09, 10 June-06 & Oct-2009 Model Paper 2010 Mar 2007 Repeated in Model Papers Repeated in Model Papers. Oct 10 Mar 2008,10 YEAR

10. Uncertainty principle cannot be applied to Stationary Electron. 11. The Number of possible orientation of orbital when l=1 is three. 12. Bond order of Lithium molecule is one. 13. Stability of a molecule is directly proportional to bond order. 14. Sideway overlap of two dx2-y2 Orbitals produces delta bond. 15. The weakest bond is Hydrogen bond.

52

16. Momentum of particle which has de Broglie wavelength of 1A 0 is 6.6 x 10 -24 kg ms -1. (Mar-2006) 17. Bond order of N2 molecule is 3. (June-2006) 18. Nature of hybridisation in IF7 molecules is Sp3 d3.(Oct-2006,10) 19. In a molecule 8 electron present in molecular orbital 4 in anti bonding orbital bond order is 2. (Mar-2008) 20. Water exists in liquid state. This is due to hydrogen bond.( June08) 21. Energy level of molecular orbitals has been determined experimentally by Spectroscopic studies. (Oct-2007) 22. Hybridization involved in XeF6 is Sp3d3.
(June-2007)

34. Hydrogen Bonding exists in Skin, Blood and bones. 35. For s Orbital, how many m values are possible? One. 36. Energy of Hydrogen in the Second Orbit is 328 KJ mol-1.

Chapter 2 PERIODIC CLASSISICATION

Number of one mark questions from this chapter 1. (Chances of Book Back). Note: Out of the previous 15 Board exam papers (Mar 06- Oct-10), only in March 2008, 1 mark Question was not given from the Book Back, all other 14 papers had only Book Mark questions, So prepare one marks from Book Back itself. Refer Page No. 46 Vol. I for Book Back.
Q. No 1 2 3 4 5 6 7 8 9 10 11 12 OPTIONS C B A A A D B B A D C B Oct 2010 Mar 2006 Mar 2009,June 2010 Oct 2008 and Oct 2009 Mar 2007, Model Paper - 2010 Oct 2006, June 2009 June 2006 & June 08 YEAR

23. Intermolecular hydrogen bonding is present in HF, H2 O and Ethanol.(March 2007) 24. Among the halogen acid the weakest acid is HF.(Model Paper
2008)

25. The hybridisation in SO4 2- ion is Sp3. 26. Number of spherical nodes in 2S orbital is 1. 27. The hybridisation in Co3 2- ion is Sp2 .

(Mar 09) (June 09) (Oct 09)

28. The factor the decreases the boiling point of a compound is Chelation. 29. The energy of electron in an atom is given by En = 30. Wave character of photon can be explained by interference. 31. Particle character of photon can be explained by photo electric effect. 32. Carbohydrates and proteins have Hydrogen Bonding. 33. Elliptical orbits wave introduced by Sommer field.

53

13 14 15

B C C Model Paper - 2009 Oct 2007, June 2007, March 2010

Number of 1 mark questions from this chapter is 1. Only 50% chances for Book Back questions, so prepare one marks from inside the book, as it may come from any topic. Q. No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 OPTIONS C B C A B C A B A C D C D A A Oct 2007 Oct 2008 June 2009 Mar 2007, Mar 2009 YEAR

Additional Questions: Total 12

Hint: Prepare one mark from Atomic radius, ionic radii, Ionization Energy, Electron Affinity among elements, Electro Negativity and its applications. 1. As we move from left to right across a period, the atomic radius Decreases. 2. As we move from left to right across a period, the ionization energy and electron gain enthalpies Increases. 3. On Moving down the group, the ionization energy and electron gain enthalpies Decreases. (Oct 2008) 4. Metal having maximum electron affinity is Gold. (Mar 2008) 5. Covalent radius values can be used to calculate Bond Length. 6. Unit for Electro negativity is no unit. 7. First Electron Affinity of the Non-metals is positive and second Electron Affinity of the Non-metals is negative. 8. Formation of the Oxide (or) Sulphate ion has been found to be Endothermic. 9. Metals have Low electron affinity. 10. Inter-ionic distance is measured by X-Ray Diffraction. 11. Electron Affinity of Zinc is -87 KJ mol-1. 12. Effective Nuclear charge of Na+ is 6.48.

Additional Questions: Total 20

Hint: Prepare one mark from Group 13- Elements, Electronic Configuration, and Potash Alum. Group 14- Elements, Electronic

Chapter 3. p BLOCK ELEMENTS

54

configurations, Silicones, Lead. Group 15- Elements, Electronic Configurations. Compounds of phosphorus (structure, hybridisation, odour, taste and uses.). Group 17- Electronic Configurations, Chemical properties, Anomalous Nature of Fluorine, Uses of Fluorine, Structure of inter halogen compounds and hybridisation. Group 18 - Structures of xenon compounds, uses of noble gases etc. 1. 2. The Metalloid among Pb, P, Ge, Sn is GE. (June 2006) Which of the following does not belong to Group 14 - C, Si, Ga, Pb, - Ga. (June 2007) 3. Tetra Ethyl Lead (Pb (C2H5)4) is used as an additive to petrol to prevent knocking. 4. Potash alum is employed to arrest bleeding. (June-2008) th group elements (or) carbon family 5. Electronic configuration of 14 is ns2 np2 . (Mar-06) 6. He is used in the inflating aero plane tyres. 7. Souring agent in the preparation of soft drink is H3 PO4. 8. Compound with rotten fish odour is PH3. 9. H3PO3 has Garlic taste. 10. Oxygen-helium mixture is used in the treatment of Asthma.
(Model Paper 2008)

17. Radon element used in radiotherapy for treatment of cancer. 18. Toxic element of boron family is Thallium. 19. HF has property of etching on glass.
(Oct 2006)

(Mar 2008)

20. An element which belongs to group 14 is soft in nature does not react with pure water, but dissolves in water containing dissolved air. Then the element is Pb. (Oct-2009)

Chapters - 4 d BLOCK ELEMENTS

Number of one Mark Questions from this chapter is 2. Normally one question from Book Back, even in all previous March question papers (Mar06-10) only Book Back were asked. Refer Page No. 104-106 in Vol. I. Book back questions are also asked in a twisted manner, options might be interchanged, so be careful while answering.
Q. No 1 2 3 4 5 6 7 8 9 10 11 12 OPTIONS D B B A B C C A D D C B Oct 2010 Model Paper 2009 Oct 2008,July 2009,June 2010 Mar 2008 Oct 2009 YEAR

11. Mixture used by deep sea diver is He-O2. 12. Na F prevents dental cavities and Fermentation. 13. CaF2 used as flux in Metallurgy. 14. Shape of IF7 Pentagonal bi pyramidal. 15. Gas used in lamps of botanical gardens to stimulate the growth of the plants is Neon. 16. Water repellent property is possessed by Silicone.

55

13 14 15 16 17 18 19 20 21 22 23 24 25 26

D D B A D D C D D A B B A C

Mar 2006 Mar 2009,Model Paper 2010

6. 7. 8. 9. 10. 11. 12. 13. 14. 15. 16. 17. 18. 19. 20. 21. 22. 23. 24. 25. 26.

Purple of cassias is Au adsorbed in Sn (OH) 4. Catalyst used in the manufacture of polythene is TiCl4 (Oct-08) Bordeaux mixture is a mixture of Copper Sulphate and lime.
(Mar 2007)

June 2008

Mar 2007,Jube 2010 June 06, Model Paper 2008 Mar 06, June 07 June 06, Mar 10

Additional Questions: Total - 39

Hint: Prepare one mark questions from inside the book carefully, see topics like Salient Features of Oxidation State, Extraction , Properties and Uses of Cu, Cr, Zn, Ag, Au, Properties and uses of CuSO4 , AgNO3 , ZnCO3 , Purple of Cassius. 1. 2. 3. 4. 5. If the Magnetic moment value is 5.92 BM, The number of unpaired electrons is 5. The electrolyte used in chrome plating is Chromic acid and sulphuric acid. Philosophers wool is ZnO. Marking inks and hair dyes can be prepared from AgNO3 (Lunar caustic). Orange red vapour formed in chromyl chloride test is CrO2 Cl2.

4d series ends with Cd (cadmium). Number of unpaired electron in Fe+3 ion is 5. Role of aluminum in aluminothermy process is reducing agent. Silver coin contains Ag and Cu. Aquaregia is 3 parts of conc.HCL +1 part of conc.HNO 3. Colour of cuprous iodide is white. Compound used in ointment for Skin disease is ZnCo3 (Calamine). Zinc metal is used in galvanizing iron sheets. (Oct-2006) Silver amalgam is employed in dental filling. (Model Paper 08) Silver obtained from silver coins is purified by fusion with Borax. The number of unpaired electrons in Ti 3+ is 1. It magnetic moment in BM is 1.732. (June-2008) The colour of Purple of cassius is Purple. (Oct-2007) Ferrochrome is an alloy of Fe, Cr. (Oct-2007) K2Cr2O7 reacts with KI and dil. H 2 SO4 and 1iberates I2 . (July-07) A metal which precipitates gold from its auro-cyanide complex is Zinc (Mar-09) The reagent which is added first in the separation of silver from silver coin is conc. nitric acid. (July-2009) The substance used in malting ruby red glass and high class pottery is purple of cassius. (Oct -2009) Ti 3+ ions have purple colour.

56

27. On adding an alkali to a solution of potassium dichromate it is converted into potassium chromate. 28. The colour of copper ammonium sulphate is deep blue. 29. Spitting of silver can be prevented by coating the molten metal with a layer of charcoal. (Mar 2010) 30. In chrome plating, the articles are first plated with nickel. 31. The general electronic configuration of d-Block elements is (n-1) d1-10 ns1-2 . 32. The most malleable and ductile metal is Gold. 33. Ferrochrome is used in the manufacture of chrome steel, burglar proof safe. 34. Sodium Chromite can be converted into Cr2O3 to the treatment with H2O. 35. In the first transition series, which one exhibits maximum no. of oxidation states is M n. 36. Sc3+ is colorless due to the absence of d-electrons. 37. Zn-Cu couple when treated with steam gives ZnO+H2 . 38. Reason for complex formation in d-Block element is small size, high positive charge density, presence of vacant d-Orbitals. 39. Chromo Nickel Steel is used for armour plates.

2 3 4 5 6 7 8 9 10 11 12 13 14

D C C B D B C B A B B D C

June 2008 March 2006 Mar 2010. Model Paper 2010 June 2007, Mar 2007 & Oct 2010 June 08, Mar 2008, Oct 07, Oct 2009& Jun 2010 Model paper 2008 June 06, Oct 07 & Oct 2010 Oct 2008, March 2009 Model paper 2009

Additional Questions: Total 16

Hint: Prepare one marks from the topics: Electronic Configuration, Oxidation state, Cause and consequences of Lanthanides and Actinide series, Monazite sand, similarities and difference between Lanthanides and Actinides. Uses of Lanthanides and Actinides. 1. 2. 3. 4. 5. 6. The fuel in nuclear power plant is U-235. Pyrophoric alloy is used in cigarette lighters. Promethium element in lanthanides is radioactive.(Mar 07, June Pu-238 is used as a power source in long mission space probes. The colour of UO2 2+ is yellow. Among lanthanide elements, with the increase in atomic number the tendency to act as reducing agent decreases. (Oct -2006)
(Mar 2006,2010 & Oct 2006) 07,2006 & Mar 2009)

Chapter 5. f BLOCK ELEMENTS

Number of one mark from this chapter is 2. (Normally one question from Book Back has been asked in all previous March board question papers (Mar 06-10). Refer text book Page No.113-114 in Vol. I. Q. No 1 OPTIONS C YEAR

57

7. 8. 9. 10. 11. 12. 13. 14. 15. 16.

Cause of actinide concentration is imperfect shielding of 5f electron. Common oxidation state of actinides is +4. (Mar - 2008) Thoria (ThO2) is used in gas lamp materials. (Oct 2008) +6 is the oxidation state of U in UF6 (June 2009) 3+ ion Ln (OH)3 According to Fajans rule decrease in size of Ln increases the covalent character. (Oct 2009) 4+ is green The colour of U The colour of U3+ is red The isotope of which element is used in nuclear fission reaction? Uranium. (June 2010) Lutetium has no partly filled 4f subshell. 30% Mish metals + M g + 1%Zr are useful in making parts of jet engines.

11 12 13 14 15 16 17 18

B B A D A C D B

Jun 2007, Oct 2007 June 2009

Model Paper 2008

Additional Questions: Total 14

Hint: Prepare one marks from the topics: Types of Ligands, IUPAC rules, mentioning the name of a complex, IUPAC Name, Oxidation state, electronic configuration, coordination number, structure. Central metal ion for that complex. Types of Isomerism, VB Theory, Uses of Coordination compounds, Bio-coordination compounds. 1. 2. 3. 4. 5. 6. 7. 8. 9. The colour of the pigment copper pthalocyanine is blue. Iron porphyrin complex acts as an oxygen carrier. Anti tumor drug is Cis-pt (NH3)2 Cl2 Cis trans isomerism is possible in square planar complexes EDTA is example for masking agent in complex metric titration. The complex used for electron transfer is ferredoxin Transport and storage of oxygen is the function of Hemoglobin [Cu (NH3)4] Cl2 is cationic complex (Oct 2006, Mar 2009) The type of isomerism found in the complexes [Pt(NH3)4] (CuCl4) and [Cu(NH3)4 (PtCl4) is Co-ordination isomerism (Mar 2006)

Chapter 6 Co-Ordination Compounds

Number of one mark questions from this chapter 1 (Normally less chances for Book Back.) Book back questions are also asked in a twisted manner, options might be interchanged, so be careful while answering. Q. No 1 2 3 4 5 6 7 8 9 10 OPTIONS A D C D C C A B C A YEAR

Oct 2008,Mar 2007 Oct 2010

Oct 2009 June 2006 Mar 2008,Mar 2010, Model Paper 2010

58

10. Co-ordination number of CrIII in [Cr (H20)4 Cl2 ]Cl2 .2H2O is 6.

(June 2008)

11. The ligand No3- is named as nitrato. 12. An example of a bidentate ligand is en. (June 2010) 13. The magnetic moment of a complex is 3.87BM. Then the number of unpaired electrons present is 3. 14. The maximum number of Cis-position in a octahedral complex is 12.

Hint: Prepare one mark based on average life, Radioactive decay series, radiocarbon dating, uses of radioactive isotopes; complete the following nuclear reactions in Q. No: 20, 29, 33, 34 (refer text book page 149 and 150 in Vol.I). 1. 2. 3. 4. Uranium belongs to the series 4n+2. Hydrogen bomb is based on nuclear fusion. Age of animal fossils can be determined using 6C14. After 24 hrs, 0.125g of the initial quantity at 1g of a radio active isotope is left out. The half life period is 8 hrs. (Mar-2006) 5. P-32 used for detection of eye tumours. 6. Au- 198 used as curing cancer. 7. Fe- 59 used diagnosis of anaemia. 8. Atom bomb is based on nuclear fission. 9. Co-60 is used to the treatment of cancer. 10. Level of liquids in tanks can be known using Sr -90. 11. Principle used in nuclear reactor is nuclear fission. (Model Paper 12. In nuclear reaction atomic number and mass number is balanced on both sides. (Mar-2008) 13. When N-15 is bombarded with a proton it gives 6C12 and particle. (June07) 14. Half-Life period of a radioactive element is 1050 years. The value of disintegration constant in terms of seconds is 0.1465x10 -10 sec-1. (Oct 2008) 15. Half-Life period of a radioactive element is 100 seconds; its average life period is 144 seconds. (Mar 2010. 16. Half-Life period of U238 is 140 days; its average life is 202.02 days. 17. The average life of a particular decay is 144 hours, then its halflife period is 100 hours.
2008)

Chapter 7. Nuclear chemistry

Number of one marks from this chapter is 1. (Less chances for book back). Normally problems based questions has more chances to come, so see text book example problems for one marks. Q.No: 1,2,3,5,9,10 (Page No: 144-147 in Vol.I) Q. No 1 2 3 4 5 6 7 8 9 10 OPTIONS C C D A D C A A C D YEAR Oct 2009 Oct 2007, June 2006, Mar 2009,Oct 2010 June 2008 Mar 2007, June 2010, Model paper 2010.

Oct 2006, June 2009 Model Paper 2009

Additional Questions: Total 17

59

Chapter -8. SOLID STATE

Number of one mark from this chapter is 1 (Out of the previous 15 Board exam papers, Only in Mar 2007, 10 and June 2009 one mark questions were not given from book back self evaluation) Q. No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 OPTIONS C D B C D B B D D C C C B A D D YEAR

1.

An ion leaves its regular site and occupies a position in the space between the lattice sites. This defect is called Frenkel defect.
(Mar -2007)

Model Paper - 2008 Oct 2006 June 2006, Model Paper - 209 June 2008 Mar 2009 Mar 2006, July 2007,Oct 2010 Oct 2007, Oct 2009, June 2010

2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13.

Mar 2008, 0ct 2008

Additional Questions: Total 18

Hint: Prepare one mark from the topics: Types of cubic system, Laue experiment, Braggs equation & Spectrometer, Types of crystals & Point defect. Glasses problem based questions are also possible. Refer Vol.I Page no.: 163, solved problems 3&4 (Repeated in model papers)

14. 15. 16. 17. 18.

Crystal used in Laue experiment is ZnS. Diamond is an example for covalent crystal. Vanderwaals forces are present in molecular crystals. Lattice vacancies are called as unoccupied points in a crystal. Imperfection due to unoccupied lattice points in crystal is called Schottky defect. FeO and FeS show metal deficiency defect. Pure Si and Ge is insulator at room temperature. Glasses are considered as amorphous solids, super cooled liquid (or) pseudo solids Most common point defects are Schottky defect and Frenkel defect. Example for molecular crystal (or) dipole-dipole forces occur in water (ice). NaCl heated in sodium vapour acquires yellow colour due to metal excess defect. The size of the anion in Frenkels defect crystal is larger than the Cation. (June-2009) Total number of atoms per unit cell of Edge centered is 4. Number of ruling required for X-rays diffraction experiment is 40 million ruling per cm. The 8:8 type of packing is present in CsC. (Model Paper 2010) The co-ordination number of ZnS is 4. (March 2010) An example for Frenkel defect, Other than AgBr is AgCl.

60

Chapter 9. THERMO DYNAMICS

Number of one mark from this chapter is 2. In all March question papers (March 06 to March 10 one question was from book back only). Refer page no. 179, 180 in Vol. I Q. No 1 2 3 4 5 6 7 8 9 OPTIONS B D B A A A C B D
Mar 2007, June 2007 & June 2009 June-06, Oct-07, Mar-08, Oct-08 March2006,Mar 2010, Model Paper 2009 Oct 2009 Oct 2006, June 2008 & June 2009 Oct 2006 & Oct 2007

Prepare one marks from the topics: Efficiency, Entropy (Characteristics, Unit, And Standard Entropy), Gibbs free energy (Characteristics. Standard Free energy). 1. 2. 3. 4. 5. 6. Entropy of vaporization of a liquid is equal to 21 Cal deg-1 mol-1 . Liquid helium does not obey Troutons rule because its boiling point is little above zero Kelvin High H vap. of water is due to H-bonding SI unit of entropy is JK-1 mol-1 Enthalpy of Vap. of water is 40.85 Jk mol -1. Change in entropy of the process is 109.5 J mol-1 K-1 Change of increase in entropy for the process H 2O () H2O (vap.) involving H vap. = 40850 J mol -1 at 373 k is 109.52 J mol-1 K-1.
(Mar-06, Oct -08,10)

YEAR
March2007,June2006,Model paper 2008 March2009,Oct 2010

7. 8.

9. 10. 11. 12. 13. 14. 15. 16.

Additional Questions: Total 20

Hint: Problems based questions has more chances to come, so see text book example problems for one mark. Example 1 (Vol.I - Pg. No.170), Example 2 (Repeated), 3 (Repeated), 4, 7(Vol.I - Pg. No.: 172-174). Example 10, 11(Repeated) (Vol.I - Pg. No.:178). Exercise problems: Vol.I - Pg. No.: 180,182 Q.No. 18, 19(Repeated), 20, 21, 25, 27, 28(Repeated), 30.

Entropy (S) and entropy change (s) of a process are state function. (Mar-2008) The entropy change involved in the process of H2O (s) H2O () at 0C and 1 atom pressure involving H fusion = 6008J mol -1 is 22.007J mol k -1. (June-2007) Water steam. In this process the entropy is H2O () H2O (g) increases. (June-2008) The percentage efficiency of a heat engine that operates between 127C and 270C is 25%. (Mar-2009) The network obtained from a system is given by w-pv (Oct-2009) When a solid melts Entropy increases.(Model Paper 2008) By the second law of Thermodynamics the percentage efficiency of a machine (or) heat engine is always < 100 (or) less than 100. S universe = S system + S surroundings. H, the heat of combustion of a compound is negative. Thermodynamic condition for irreversible spontaneous process at constant T and P is G<0 . (March 2010)

61

17. S is a State function.(June 2010) 18. Standard free energies of formation of elements are taken as zero. (June 2010) 19. s=q is valid only for reversible process. 20. Natural process is called as spontaneous process.

3. 4.

Chapter- 10. CHEMICAL EQUILIBRIUM

Number of one mark from this chapter is 2. In all the previous March question papers (March 06 to March 10), one question was only from book back. Refer Page no.: 193-104 in Vol.I. Q. No 1 2 3 4 5 6 7 OPTIONS A B C D B A A YEAR
March 2008, June 2008, June 2010 Oct 2006, 10, Mar 09 Mar 07, Oct 08, June 09 Mar 10, Oct 09 Mar 2006, June 2006 & Mar 2009 Repeated in model papers June 2007, Model Paper 2009.

5. 6. 7. 8. 9. 10. 11. 12. 13. 14. 15.

For equilibrium 2H2O (g) + 2Cl2 (g) 4HCl (g) +5 O2 (g). the value of KP and K C are related as Kp > Kc. (Mar 2006) In equilibrium constant for the formation of a product is 25. The equilibrium constant for decomposition of the same product 1/25. (June 2006) In formation of HI. K C value is 16. K P value is also 16. (June 2008) Maximum yield of ammonia by Habers process is 37%. (June 07) In a reaction 2O3 3O2 KC value is [O2 ]3 / [O3]2 . (Oct 2007) Synthesis of NH3 between N2 and H2 reaction KP unit is atm-2
(Oct 2007)

Additional Questions: Total 17

Hint: Problem also possible, Refer Vol.I example problems in page no. 188 (HI), 190(PCl5 ) (Repeated in Model Papers). Prepare one mark questions from the topics: Relationship between Kp and Kc, formation of HI and Dissociation on PCL 5 , Habers and contact process. Pressure, optimum temperature, yield based questions 1. 2. When ng in a homogenous gaseous equilibrium is positive then Kp > Kc. (Oct 2006,10, June 2010) Optimum temp. range maintained in contact process is 400C to 450C. (Oct 2008)

16. 17.

The rate constant of the forward and reverse reaction are 8 x 10 -5 and 2 x 10-4 respectively. The value of K C is 0.4. (Oct 2009) The degree of dissociation of PCL5 at 1 atm and 298 k is 0.2. The value of KP is 0.042 atm. The initial concentration of H 2, I2, and HI are 0.1, 0.1, and 0.02 moles respectively. The value of Q is 0.04 The molar concentration of a gas at 300k is I mol dm-3 then its partial pressure is 24.63 atm. In Habers process, ng value is negative. (Mar 2008) In Habers process the yield of ammonia is greater at high pressure. (June 2009). Kc for the reaction 2AB is 25 mol-1 dm3 at 900K. What is the equilibrium constant for the reaction B2A in dm-3 mol at the same temperature? 0.04.(Mar 2010) When 4 is greater than Kc, the reaction will be forward reaction. (Model paper 2008) What is the pressure involved in the synthesis of ammonia by Habers process? 300-500 atm. Pressure (Model Paper 2010)

62

2. 3.

Chapter-11. CHEMICAL KINETICS

Number of one mark from this chapter is 1. Less chances for book back questions. Q. No 1 2 3 4 5 6 7 8 9 10 11 OPTIONS C B D C D B B C B C A YEAR June 2007,Mar 2010 Mar 2009,June 2010

4. 5. 6.

The minimum amount of Energy needed to make all the collision effective is Threshold energy. First order rate constant of a reaction is 0.0693 min -1. Then the time required for 50% completion of a reaction is 10 min. (Oct 06) Decomposition of N2 O5 in CCl4 is an example for 1st order reaction. (Oct 2008) Half - life period of a first order reaction is 20 min. the time taken for the completion of 99.9% of the reaction is 200 min. (Mar -08) In 1st order reaction the concentration of the reactant is increased by 2 times. The rate of the reaction is increased by 2 times.(June
2008)

7. Oct 2007, June 2009 Oct 2009,Model paper 2008 June 2006 Oct 2010 Mar 2006,Model paper 2009 8. 9. 10. 11. 12.

Additional Questions: Total 20

Hint: Problem based one mark Questions has more chances. Problems based on First order and Half life period. Refer Vol.II Example problem in page no.: 8,9,10 (Repeated questions). Prepare one marks from the topics: Rate, Order, Characteristics of order of a reaction, characteristics of first order reactions, Examples of first order reactions, Arrhenius equation, Activation energy, simple and complex reaction and types of complex reactions. 1. Unit for activation energy is J mol-1.

13. 14. 15.

50% of 1st order reaction completed in 20 min. the time required for 75% of completion is 40 min. (Mar 2007) If the rate of the reaction is independent of initial concentration of the reactant, then it is a zero order reaction. All radio active transformations follows first order kinetics. The rate constant for first order reaction is 200S -1. The half-life period of the reaction is 3.47 x 10 -3S. The time required for 75% completion of first order reaction is 9.hrs. The half-life period of the reaction is 4.5 hrs. The time required for 90% completion of first order reaction is 10.hrs. Then the time required for 99% completion of the reaction is 20 hrs. The half-life period of a first order reaction is 30 min. Then the time required for 99% completion of the reaction is 3.33 hrs. The half-life period of a first order reaction is 1 hrs. The time required for 75% completion of the reaction is 2 hrs. The conversion reaction of cyclopropane into propene is an example of opposing reactions.

63

16. Simple reaction occurs in single step. 17. Higher the value of Ea, slower is the rate of reaction. 18. Half life period of a first order reaction is independent of the initial concentration of the reactant and inversely proportional to the rate constant of the reaction. 19. Decomposition of Sulphuryl Chloride in the gas phase proceeds by first order kinetics. 20. Inversion of sucrose in acidic medium is an example for first order reaction.

Additional Questions: Total 42

Hint: Prepare one marks from Adsorption, Difference between Physical and chemical adsorption, Factors affecting adsorption, characteristics of catalytic reactions, types of catalytic reactions, types of catalysts, theories of catalysis, applications of catalysts, (Pg. No.:31), types of colloids (important) Refer Pg. No.:32 table, preparation of colloids, purification of sols, properties of colloids, application of colloids-1) Natural Applications, 2) Technical applications. 1. 2. 3. 4. 5. 6. 7. 8. 9. The Catalyst used for the decomposition of KCl03 MnO2 . Iron Catalyst used in Habers process is poisoned by H2 S. (Mar 06) Promoter used for the Boschs process is Cr2 O3. Bergius process is used for the Synthesis of petrol from coal. Haze is an example of solid dispensed in gas. An example of foams is froths of air. Sky looks like blue due to scattering of light. (June 2010) Gold chloride can converted into colloidal gold using tannic acid and formaldehyde. Sulphur in water is an example for Lyophobic colloid.(Model
Paper 2010)

Chapter12. SURFACE CHEMISTRY

Number of one mark from this chapter is 3. In all the previous March question papers (March 06 to March 10), one question was only from book back. Refer Pg. No.:43-44 in Vol.II. Q. No 1 2 3 4 5 6 7 8 9 10 11 12 OPTIONS D D B C B A D A C C B C YEAR
Oct 2010, Model Paper 2009

June2008 March2007 & Oct2008

June 2006, Oct 2007, June 2009 March2008,2010 Oct 2006&2010, Mar 2007, Mar 2009 June 2007, Oct 2006, June 2008

10. Delta is formed because of coagulation of colloid. 11. Cottrell precipitator is used for the precipitation of dust in smoke. 12. An example for (gel or liquid in solid) type of colloid is curd.
(June 2006 & Mar 2006 )

Mar 2006,June 2010, Model paper 2009 Mar 2007,2008&2010, Oct 2008& 2009

13. Argyrols is used as eye lotion. 14. Emulsion can be diluted using dispersion medium.

64

15. 16. 17. 18.

Cork is an example for solid form. Printing inks can be prepared by using colloidal mill. Smoke is a colloidal solution of solid in gas. (Oct - 2006) Catalytic activity of a powdered catalyst is high because it has large number of active sties. (Model Paper 2008) 19. An example of Lyophobic colloid is starch. (Oct - 2008) 20. Coconut charcoal has great capacity of the adsorption of gases.
(Oct -07)

33. Solute or gas which is held in the surface of the solid is known as adsorbate. 34. Excess of bleeding from a wound is stopped by forming a clot due to the styptic action of Alum and FeCl 3. 35. Arsenic Sulphide sol is prepared by Double Decomposition. 36. Ferric Oxide is used as a catalyst for both Boschs and Bergins process 37. Milk of M agnesia colloid is used for stomach disorder (Mar-2010) 38. Colloidal antimony is used in caring Kala azar. 39. Gold sol and Silver sol is obtained by reduction method 40. Oxidation of Sodium Sulphite by air is retarded by alcohol. 41. Ag, Pt, and Au metal sols can be prepared by Bredigs Arc method. 42. Reaction between Oxalic acid and Potassium Permanganate, in the presence of dil.H 2SO4 , MnSO4 acts as a auto catalyst (Mar2010,June-2010)

21. Emulsifying is used for stabilization of an emulsion. (Oct -2007) 22. De composition of hydrogen peroxide is retarded in the presence of glycerine. (June 2006, Oct -2009) 23. Sol comes under solid - liquid type of colloid. (June-2007,Oct
2010)

24. The Platinum catalyst used in the oxidation of SO2 by contact process is poisoned by AS2 O3. (June-2007) 25. The function FeCl3 in the conversion of Fe(OH)3 precipitate into a colloid is peptising agent. (June-2008) 26. The emulsifying agent used in O/W emulsion is protein. (Oct 2009)

Chapter 13. ELECTRO CHEMISTRY

Number of one mark from this chapter is 1. Less chances for book back questions. Q. No 1 2 3 4 5 OPTIONS C B C C B YEAR

27. Catalyst used in Deacons method of manufacture of chlorine is CuCl2. (June-2009) 28. 29. 30. 31. 32. Argyrols is a colloidal silver (or) silver sol. (June-2009) The blue colour of the sky is due to Tyndall effect. (Mar-2009) Fe(OH)3 colloidal particles absorb Fe3+ ions. In Habers process the promoter used is molybdenum. Chemical adsorption is irreversible in nature

Mar 2006, Oct 2007 Mar 2009 Repeated in Model Papers

65

6 7 8 9 10 11 12 13 14 15 16 17 18

B B B B A D A B C A A C B

June 200, Repeated in Model Papers Oct 2006, Oct 2009, June 2009

4. 5. 6.

Mar 2010 Oct 2008 Mar 2008, Oct 2010 June 2010

7. 8. 9. 10. 11. 12. 13. 14. 15. 16. 17. 18. 19. 20. 21. 22.

Model Paper 2010 June 2006

Additional Questions: Total 22

Hint: Problems are also possible, Refer example problems: 1(Page No.:55), 4(Pg. No.:56), Example 1 and 3 in Page No.:60, Example 4 (Page No.:62), Example 3 and 4 (Page No.:68), Example 1 & 2 in Page no.:72&73. Solved Problems 1, 2,3,6,7,8,10 in Page No.:80,83. (All the above mentioned problems are repeated questions in model papers.) Also prepare on mark from the topics: Semiconductors, Evidence of Arrhenius Theory, Ostwald Dilution law, electrochemical equivalent, electrical conductance (Unit). Calculate pH based problems, Henderson equation and selection of pH. 1. 2. 3. The Colour of nickel salts is green. pH of 0.05M KOH solution is 12 + log10 5. pH of 0.1M H2SO4 is 0.6990.

Quantity of Electricity carried by one mole of electrons is 96495c. The indicator used in the titration of NH4OH with HCl is methyl orange. (Mar 2007) If 0.2amp can deposit 0.1978g of cooper in 50min. How much of cu will be deposited by 600 coulombs 0.1978g. (June 2007) The PkW value at 298k is 14. The colour of sodium chromate is yellow. Unit of molar conductance is Ohm-1 m2 mol-1. Benzene and Carbon Tetra Chloride is an example of insulator. For 1:1 electrolyte like NaCl equivalent conductance is equal to molar conductance. Unit of self conductance is Ohm-1 m-1. Quantity of electricity = n x F. For strong electrolytes, Debye, Huckel-Onsager equation can be applied. Enthalpy of neutralization of strong acid by strong base is equal to -57.32 KJ mol-1. Charge of an electron is 1.602 x 10-19 coulomb. Semiconductor which exhibits conductivity due to the flow of excess of negative electrons is called as n-type semiconductors. For the titration of HCl Vs Na2CO3, the suitable indicator in Methyl orange NH4OH obeys Ostwald dilution law. pH of pure water at 25oC is 7. Ph range of phenolphthalein is 8.3-10. Unit of cell constant in m-1.

Note: There are no one mark questions from Chapter 14 and 15 according to Blue
Print.

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Chapter-16. HYDROXY DERIVATIVES

Number of one mark from this chapter is 1. Chance for Book back questions. Refer Page No.: 167-169 in Vol.II. Q. No OPTIONS YEAR 1 C 2 C 3 B Oct 2010 4 B 5 A 6 C 7 A 8 B June 2009 9 D Mar 2007, June 2007, Oct 2007,Mar 2010 10 C 11 D 12 C 13 B 14 A Model Paper- 2009 15 D Oct 2009 16 C Mar 2008 17 C 18 B June 2006 19 C Model Paper 2008 20 C 21 D 22 C 23 A Oct 2008,June 2010 24 B Mar 2009 25 B June 2008

Additional Questions: Total 29

Hint: Prepare one mark from Lucas test, oxidation, Chlorine water, Iodoform test, Victor Meyers test, Uses of ethanol, Propertius of glycerol (Dacron, Dioxan), Uses of glycol, Properties of glycerol (Dehydration, oxalic acid, oxidation), uses of glycerol and benzyl alcohol, classification of phenols, preparation of phenol, naming reactions, uses of phenol. 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13. 14. 15. Lucas regent is a mixture of conc. HCl + anhydrous Zncl2 Ethylene glycol reacts with conc. HNO 3 in the presence of conc. H2SO4 to give ethylene dinitrate Fentons reagent is FeSO4 + H2 O2 Dynamite is prepared from glycerol Common name for 4 Hydroxy toulene is P-cresol High boiling point of phenol due to inter molecular hydrogen bonding Victor Meyers test gives red colour with ethanol Tertiary alcohol do not undergo reaction with chlorine water because of absence of alpha-hydrogen Oxidation of glycerol using bismuth nitrate gives meso oxalic acid. (Mar 2006) Orcinol is an example for dihydric phenol Lederer manasse reaction phenol is converted into P-Hydroxy Phenyl methanol. Glycerose is a mixture of glyceraldehydes and di hydroxyl acetone Characteristic odour of lower phenols is carbolic acid (Oct 2006) The reagent used for causing Decarboxylation is soda lime Dacron is prepared by terephthalic acid + ethylene glycol

67

16. The product obtained when ethylene glycol reacts with conc. H2SO4 is dioxane 17. When glycerol is heated with KHSO 4 or P2O5 the product obtained is acrolein 18. Benzyl alcohol is used as local anesthetic and antiseptic. 19. Benzyl acetate has the fragrance of Jasmine 20. Phenol gives violet colour with neutral FeCl3 21. Phenolphthalein is prepared from Phenol + Phthalic anhydride 22. Dows process is used for the preparation of Phenol. 23. Glycerol reacts with oxalic acid at 533K to give Allyl Alcohol. 24. Propylene when treated with dil.H2SO4 gives Iso Proplyl Alcohol. 25. Na + C2 H5OH is a reducing agent used in Bouveault Blanc reduction. 26. Phenol with 5% water is known as carbolic acid. 27. Phenol is used as an antiseptic and germicide. 28. Cumene is 2-Phenyl Propane. 29. Iso Propyl alcohol gives blue colour in Victor Meyer test.

3 4 5 6 7 8 9 10

A D C B B D A B

March 2009 Oct 2006, June-08 Mar 06& 07, June 07, Oct 07& 10 Model Paper - 2009 Oct 2008, Oct 2009 June 2009 Mar 2008, June 06 Mar 2008, June 2010

Additional Questions: Total 29

Hint: Prepare one mark questions from preparation, properties and uses if diethyl ether. Anisole - properties & uses. Difference between anisole and diethyl ether. 1. 2. 3. 4. 5. Metamerism is exhibited by ethers. William sons synthesis involves healing alkyl halides with Sodium alkoxide. Ethers should never be evaporated to dryness because they form explosive peroxides. (June 2010) Ethers, when dissolved in conc.H 2 So4 gives oxonium salts (or) diethyl oxonium hydrogen sulphate. Reagent used to distinguish anisole and phenol is Bromine water. Ether do not react with CH3COOH, NaOH, Na. Diethyl ether is inflammable.

Chapter-17. ETHERS
Number of one mark from this chapter is 2. In all the previous March question papers (March 06 to March 10), one question was from book back. Book back questions are also asked in a twisted manner, options might be interchanged, so be careful while answering. Refer Page No.: 192-193 in Vol.II. .) Q. No 1 2 OPTIONS B C Mar 2010 YEAR

6. 7.

68

8.

Compound mixed with ethanol to serve as substitute for petrol is ethoxy ethane. (Mar 2006) 9. Isomerism exhibited by 1 propanol and methoxy ethane is functional. (June 2006) 10. Number of ether isomers possible for C 4 H10 o is 3. (June 2008) 11. Ether used in perfumery is methyl phenyl ether.
(June 2007 & Oct 2009)

Chapter-18. CARBONYL COMPOUNDS

Number of one mark from this chapter is 1. In all the previous March question papers (March 06 to March 10), question was asked only from book back. Refer page No.:232-234 in Vol.II. Q. No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 OPTIONS B B C B D B C A B B D C D C B Mar 2006 Mar 2009, June 2008 Oct 2006 Mar 2008 June 2007 June 2009 Model Paper 2010 Oct 2007, 2009, Mar 2007, June 2010 YEAR

12. CH3-O-C6H5 is example for unsymmetrical ether. (Oct 2007) 13. Diethyl ether react with excess of HI to from ethyl iodide + water. 14. Anisole on bromination gives O- and P- bromo anisole. (Mar-09) 15. Diethyl ether react with PCl 5 to from ethyl chloride + POCl3. 16. Diethyl ether cannot be prepared by reaction of halogenated ether with strong Grignard reagent. 17. In the formation of oxonium salt when ethereal oxygen reacts with strong mineral acid is called protonation. (June 2009) 18. IUPAC name of phenatole is Ethoxy Benzene. (Mar 10) 19. Higher ethers can be prepared from lower members by the action of Grignard reagent. (Oct 10) 20. Anisole and Phenatole is an example for mixed ethers. 21. IUPAC name for methyl isopropyl ether is 2-methoxy propane. 22. Lower members of ethers are gases. 23. Ethers are lighter than water. 24. Functional Isomerism of Ethyl Methyl Ether is Propyl Alcohol. 25. Zeisels method of detection and estimation of alkoxy group in alkaloides involves the reaction of ether with HI. (Mar 07)

69

16 17 18 19 20 21 22 23 24 25

C B A B C A D A C B Mar 2010 Oct 2010 June 2006 June 2008

2. 3. 4. 5. 6. 7. 8. 9.

hydrogen undergo Cannizaro reaction. Derivatives of ammonia acts as nucleophile. Oil of bitter almonds is Benzaldehyde. Formalin is 40% solution of HCHO in water.
Original pink colour of Schiffs reagent is made colour less using SO2

Fehlings solution is CUSO4 + sodium potassium tart rate. Knoevenagal reaction leads to the formation of cinnamic acid. Medicine for throat infection is tincture Benzoin.

10. Paraldehyde is used as hypnotic. 11. Benzaldehyde is used in the preparation of M alachite green. 12. Benzoin condensation is carried out in the presence of aqueous alcoholic KCN. 13. The compound used as hypnotic under the name hypnone is Acetophenone. 14. Acetone on treating with Lithium aluminum hydride gives iso propyl alcohol. 15. The intermediate formed in the Wolff Kishner reduction is Hydrazones. 16. Stephens reaction of methyl cyanide gives acetaldehyde. 17. Propanone is usually characterized by Iodoform test. (Oct -2008) 18. Compound which undergoes Iodoform test is e-pentanone. (June 09) 19. DiPhenyl Carbinol is known as Bezyhydrol.

Additional Questions: Total 20

Hint: Prepare one mark from these topics: Isomerism of Aldehydes, Ketones, Dry distillation, Rosemunds reduction, Stephens reaction, characteristics of Aldol condensation, Grignard addition, Addition of ammonia, LiAlH4, Clemmenson, Wolff-Krishner, Tollens and Fellings, Polymerization, Uses of Formaldehyde and acetaldehyde, Cannizaro reaction, Benzoin condensation, Perkins, Knoevenagal, Malachite green, Uses of benzaldegyde and Acetone, Mestiylene, Benzhydrol, uses of Acetophenone.

1.

Chloral belongs to a group of Aldehyde.

70

20. Acetone is used in the manufacture of cordite.

Chapter-19. CARBOXYLIC ACID

Number of one mark from this chapter 1. . In all the previous March question papers (March 06 to March 10), question was asked only from book back. Book back questions are also asked in a twisted manner, options might be interchanged, so be careful while answering. Refer Page No.: 271-272 in Vol.II. Q. No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 OPTIONS A D D A C C D B C B C C A D D B YEAR Mar 2009

17 18 19 20

C A D B

Mar 2006 June 2006, Model paper 2010. June 2008, June 2009

Additional Questions: Total 26

Hint: Prepare one mark from the topics: Source of acids, Decarboxylation, HVZ, Kolbes electrolysis, reducing property of Formic acid, Uses of Formic acid, chemical properties and uses of lactic acid, Physical properties of oxalic acid, uses of 1.)Oxalic acid, 2.) Benzoic acid, 3.)Salicylic acid, 4.) Acetyl Chloride, 5.) Acetic anhydride and 6.) Acetamide. 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. Pyruvic acid is the oxidation product of lactic acid. Urinary antiseptic is C6H5COOH. Methyl salicylate is present in Oil of Winter green. Aspirin is acetyl salicylic acid. The source of butyric acid is butter The source of HCOOH is red ant Ethane can be prepared from sodium acetate by electrolysis Brominating of salicylic acid gives white precipitate Acetyl chloride fumes in moist air forming HCl CH3COCl is used in the detection and estimation of alcoholic and

Mar 2008 June 2010, Model Paper 2009 Oct 2006, Mar 2010 Mar 2007, Oct 2008,09,10 Oct 2007

June 2007

amino groups 11. CH3CONH2 is used as soldering flux. 12. HCOOH is used in the coagulation of rubber latex 13. When acetic acid is passed over heated P 2O5 it forms acetic anhydride

71

14. Benzoic acid is used to disinfect the bronchial tube. 15. HCOOH is used as stimulant for the growth of yeast and in the treatment of gout. 16. Sodium benzoate an important food preservative. 17. Lactic acid is found in gastric juice, cucumber or opium. 18. In Glaciel acetic acid, percentage of acetic acid is 100%. 19. Salicylic acid is used as a medicine for Rheumatic pain. 20. An aqueous solution of Salicylic acid gives violet colour with neutral Ferric Chloride. 21. Oxalic acid is used for removing iron stains and ink stains. 22. Lactic acid is used in the treatment of digestive disorder in children . 23. Acetamide exists as a dimer due to Hydrogen bonding. 24. In HVZ reaction, carboxylic acid is treated with Halogen and Phosphorous Tri-Halides. 25. Lactic acid on treatment with dil.H 2SO4 gives HCOOH+CH3CHO. 26. Cyclic diester can be formed by Lactic acid.

Q. No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20

OPTIONS A C A C A B D D B C C C B B A B C D D C

YEAR Mar 2006, Oct 2010 Mar 2008, June 2009 Mar 2007 June 2007 June 2007, Oct 2009 June 2006 June 2010 June 2007, Mar 2010 Oct 2006 & 2007, Mar 2008 June 2008, Oct 2008, June 2010 Mar 2009 June 2008, Oct 2008 June-06, Oct 2009& 2010 Mar 2007 Mar 2009

Chapter-20. ORGANIC NITRO COMPOUNDS

Number of one mark from this chapter is 3. Normally one question is from book back. Book back questions are also asked with options being interchanged, so be careful while answering. Refer page No.: 310-312 in Vol.II.

Additional Questions: Total 36

Hint: Prepare one marks from the topics: Tautomerism, Nitro methane on reaction (With Cl2, Aldehyde and Ketone, Reduction with Sn/HCl), Uses of Nitro alkanes, Arrenium ion, physical properties of nitrobenzene, Chemical

72

properties of nitro benzene (Alkaline medium, Electrolytic reduction, nitration), uses of Nitro benzene, Hoffmanns bromide reaction, Gabriels pthalamide synthesis, physical properties of Amine, chemical properties of Methyl amine and Aniline, Chemical properties of benzene diazonium chloride. 1. 2. 3. 4. 5. 6. 7. 8. 9. Reaction of nitric methane with chlorine in presence of alkali produces trichloro nitro methane (or) Chloro Picrin. Electrolytic reduction of nitro benzene gives p-amino phenol. 1, 3, 5 tri nitro benzene is an explosive. Tertiary amine is less basic than secondary amine because of Steric effect Amine generally have fishy odour. Alkyl cyanide on reduction with LiAIH 4 / ether gives primary amine. Mustard oil reaction converts primary amine to Methyl isothio cyanate. Schotten Baumann reaction is formation of benzanilide Benzene diazonium chloride reacts with phenol to give p-Hydroxy azobenzene. 10. Test for aniline is Bromination test. 11. Gomberg reaction is used to prepare Biphenyl. 12. Reduction of nitro benzene using Sn/HCl gives aniline.

13. Azoxy benzene is obtained by the reduction of nitro benzene using glucose + NaOH. 14. Primary and secondary nitro compounds behave as an acid in the presence of strong alkali Sandmeyers reaction. amino benzene.
(Mar -06) (Mar -06) (Oct -06) (June -06)

15. Converting benzene diazonium chloride to chlorobenzene is called 16. Nitrogen compound used in the preparation of sulpha drugs is 17. Compound that does not show tautomerism is nitrobenzene. 18. Nitro group can be reduced to primary amino group by Sm / Conc. HCl.
(June-09) (Oct -06)

19. The tertiary nitro compound is 2-nitro 2 methyl propane 20. The intermediate formed in the nitration of Benzene is Arenium ion. reaction.(Oct -08) 22. Oil of mirbane is nitrobenzene
(June -08) (June-09)

21. Methanamide will not undergo Hoffmanns bromamide

23. A use of chloropicrin - soil sterilizing agent. (Oct-7,Mar08,Jun10) 24. The reaction between benzene diazonium chloride and benzene in the presence of NaOH is Homburg - Bachmann reaction.(Oct -07) 25. Nitroacintro tautomerism is exhibited by nitro methane. (Mar-07)

73

26. Nitration of nitro benzene resorts in m- di nitro benzene. 27. (CH3)2 -N-C2 H5 is a tertiary amine. (Mar 2009) 28. Basic strength of amine is in the order of Secondary amine> Primary amine> Ammonia. (Oct 2009) 29. C6H5N2Cl
CuCl2/HCl

37. Gabriel Phthalamide synthesis is used in the preparation of primary

aliphatic amines.

Chapter- 21. BIOMOLECULES

Number of one mark from this chapter is 2. In all the previous March question papers (March 06 to March 10), one question was asked from book back. Book back questions are also asked in a twisted manner, options might be interchanged, so be careful while answering. Refer page No.: 328-33- in Vol.II. Q. No 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 OPTIONS D D C B D C C A B D A A D A D June-06, Mar -07, Mar -09 June 07 Oct 08 June 08, June 09 Oct 2007& 2010 June 06, Mar 08, Oct 08 June 07 Mar 07 June 09, Oct 09& 10 YEAR

-> X, the compound X is C6H5Cl. (Mar 2010)

30. Aniline reacts with Benzoyl Chloride in the presence of sodium hydroxide and gives Benzanilide. This reaction is known as Schotten-Baumann reaction. 31. The product obtained when nitrobenzene is treated with

Zn/NaOH is hydrazobenzene. (Oct 2010) 32. Bromoethane reacts with silver nitrate to give C2H5ONO. 33. The product obtained by Carbyl Amine reaction is Isocyanide. 34. Benzene diazonium chloride reacts with Hypo Phosphorous acid in the
presence of cuprous salt, to give Benzene.

35. IUPAC name of CH3CN is Ethane Nitrile. 36. Aniline is used for the manufacture of anti-oxidant in rubber industry
and poly urethane plastic.

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16 17 18 19 20 21 22 23 24 25

C A C B A B C D C B

June 08, Oct 06 Mar-06

Oct 09, June 2010

Additional Questions: Total 36

Hint: Prepare one mark from the topics: Classification of carbohydrates, Structure of glucose and fructose, disaccharides, polysaccharides, amino acids and functions of lipids. 1. 2. 3. 4. 5. 6. 7. A mixture of D (+) glucose and D(-) fructose is known as invert sugar. (Mar 2006) Starch when treated with enzyme, diastase yields maltose. Precipitation of proteins is known as denaturation. (Oct 2007) Reverse of denaturation is known as denaturation. Protective agent on the surface of animals and plants is wax. Cephalins have been implicated in the process of blood coagulation. Glucose reduces Tollers reagent.

8. Zwitter ion in acidic solution in the form of Cation. 9. Sorbitol and mannitol are epimers (Mar 2008) 10. Nucleic acid is made up of organic base, a sugar unit, phosphoric acid (Oct 2006) 11. The number of asymmetric carbon in glucose is 4. 12. The hydrolysis of disaccharides involves a cleavage of Glycosidic linkage. 13. Cephalins are found in the brain. 14. pH at which amino acid shows no tendency to migrate when placed in an electric field is known as Iso electric point. 15. Starch when heated to 200-300oC gives Dextrin (Mar 2010) 16. Starch, Cellulose and Insulin is considered as a polysaccharide. 17. Raffinose is an example of trisaccharide. 18. General formula for polysaccharides is (C6H10 O5) n. 19. Lecithins are required for normal transport and utilization of other lipids, especially in the liver. 20. Galactolipids occur in considerable amount in the white matter of brain and all nervous systems. 21. Fruit sugar is fructose.

S. No 1 2 3 4

UNITS Atomic structure II Periodic classification II P-block D-block

MAX.Q 1 1 2 2

Q.No 31 32 33,34 35,36

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5 6 7 8 9 10 11 12 13 14 15 16 17 Total

Nuclear chemistry Solid state II Thermodynamics II Chemical Equilibrium Chemical kinetics Surface Chemistry Electro chemistry I Isomerism Hydroxy derivatives Carbonyl compounds Carboxylic acids Organic nitrogen Chemistry in action

1 1 1 1 2 1 1 1 2 1 1 1 2 21

37 38 39 40 41,42 43 44 45 46,47 48 49 50 51

March 10), question was asked from book back only. (Refer Page no 30 in Vol.I for Book back.) Q.No 1 2 3 4 QUESTION Explain the significance of negative electronic energy Distinguish between particle and wave What is bond order? And how is it useful in determining the stability of a molecule? Why He2 is not formed.
Page No. YEAR June 08, 09 &10 June 06 June 07, Mar 07 Mar 07 & Oct 08,10 Mar 06& 08, Oct 07 & 09 Oct 06 Mar 09

13 3 19 21

5 6 7 8 9

State Heisenbergs uncertainty principle What are the conditions for effective Hydrogen bonding ? Define hybridisation. What is meant by intra molecular Hbonding? What is a nodal plane? Give the type of hybridisation in Co 32- and NH4+ Give the type of hybridisation in NH3 and PCL5 What are the consequences of intra and inter molecular hydrogen bonding?

10

Answer any 15 from 21 Questions.

Question number 31-37: ---- Inorganic Question number 38-44: ---- Physical Question number 45-51: ----- Organic

27 23 28
16 25 & 26 24 & 25 29

For question number 31:

10 11

Hint: Problems based on the topics: De Broglie equation and Uncertainty principle are possible. In all the previous March question papers (March 06 to

12

76

13 14 15 16 17

What are bonding and anti-bonding molecular Orbitals? What are the significances of De-Broglie wave? Give any three importance of Hydrogen bonding Define molecular Orbitals Define an orbital De-Broglie equation based problems: Example problems: 1& 3, Problems for practice: 1, 2, 4. Uncertainty Principle Based problems: Problems for practice: 2 & 3.

17 6 29 15 15

Chlorine? 2 3 4 5 6 7 8 9 10 11 12 Why is the 1st I.E of Beryllium greater than Lithium (or) Boron? Compare I.E of Nitrogen and Oxygen. Define Electron Affinity (E.A) Mention disadvantage of Pauling and Mullikans scale Why IE2 always greater than IE 1 I.E of Neon greater then Fluorine. Give reason. Why is I E of Fluorine greater then Oxygen? I E of carbon greater then Boron Why Beryllium and Magnesium has almost zero EA? Compare I.E of Magnesium and Sodium. Compare I.E of Aluminum and Magnesium. Beryllium and Nitrogen has almost zero EA. Give reason.
38

09,Oct 10 June & Oct 06, June 08 Mar 07 Mar 08 Oct 08

32 43&44 40 39 38 42 39 39 40

18

6,9, 10
12

March 09, June 2010 Oct 09

19

For question number 32:

Hint: Prepare 3 marks from the topics: Comparing I.E, E.A between elements (Repeated). Problems based on Atomic Radii (or) Slaters rule. (I.I Ionization energy, E.A Electron affinity)

Q.No 1

QUESTION Why is EA of Fluorine less than

Page No. 42

YEAR Mar06,June

13

Mar 2010

77

14

If the d (C-C) is 1.76 and r (C) is 0.99. find the radius of Carbon atom Calculate the effective nuclear charge experienced by the 4s electron in Potassium atom ( S= 16.8)

33 36

June 2007

6 7

How will you prepare Phosphine in laboratory Prove that Phosphorous acid is a powerful reducing agent. Give the electron dot formula of PCL 5 and H3PO3 Uses of Neon (Any 3)

63 60 57& 61 76

15

Oct 07

June 06 Mar 08 & Oct 08 June 08& 10, Oct 10

8 9

For question number 33& 34:

Hint: Chances for book back questions are more. Prepare from the topics: Potash alum, Plumbo solvency, Compounds of phosphorous (P 2O3, H3PO4, H3PO3, PC l5, P2O5 etc...), Inter Halogen compounds, Uses of Neon and Helium. Refer page no.:78 for Book Back questions.
Q.No

10

How fluorine reacts with non-metals?

69 54,55
Oct-06& 10, June 06, 07& 09, Mar10. Oct 06 &
Mar07

11
Page No. 60 59 67 Mar 07 YEAR June 09

What is Plumbo Solvency?

QUESTION What is the action of heat of phosphoric acid Action of P2O3 with cold and hot water Why is HF not stored in silica (or glass bottle)? Give equation. Write note on potash alum. H3PO4 is Tri basic nature or Triprotic?

1 2 3

12 13 14 15

Prove that P2O5 a powerful dehydrating agent. Uses of Helium (Any 3) How H3PO4 prepared in the Laboratory? What is a inter halogen compound? Give any one preparation. Illustrate the oxidizing power of fluorine What is inert pair affect?

60

76 61 70 66 49

Oct 07, June 08 Oct-08 June 07 Mar 09

4 5

50 61

Mar 08 Mar 06

16 17

78

18 19 20 21 22 23 24

H3PO3 is diprotic. Why? Write the uses of Phosphine (or) Phosphoric acid. Draw the structures of ortho and pyro phosphoric acid. Write a note on etching on glass. Show that phosphine is a powerful reducing agent. Write any 3 uses of Silicones (or) Lead Write a note on Holmess signal.

60

Oct 09, Mar 10

1 2 3 4 5 6

What is the action of heat on copper sulphate? Give equation. Write a note on Chromyl chloride test Write note on Chrome plating Why are transition metal ions coloured? Splitting of silver and how is it prevented Purple of cassius. How is it prepared? Bordeaux mixture Action of heat on AgNO3 and how is it prepared. Why do d-block elements possess Catalytic activity How gold dissolves in aquaregia What is Philosophers wool? How is it formed? Evidences for oxidizing nature of potassium dichromate (Any 2) Explain electrolytic refining of copper What is the reaction of CuSO4 with KCN? (or) KI (or) Ammonia?

101 100 92

Mar 08, Oct 10 Mar 09 Oct 06, Mar 08& 10 Oct 09 Oct 07 & 08, June 2010

64& 62 62& 63 67 63 52& 55 64 Oct 07& 09

82 96

104 102 108 83 98 94 100 87 101 July 06 June 07 June 08, Oct 09 Mar 07

7 8 9

For question number 35& 36:

Hint: Chances for book back questions to be asked in Board exams is more. Refer page No.: 106-107. Prepare 3 marks from the topics: Formation of coloured ions, Variable oxidation sta te, complex formation of d-block elements, chrome plating, spitting of silver, chromyl chloride test, and action of heat of copper sulphate.

10 11 12 13

Q.No

QUESTION

Page No.

YEAR

14

79

15 16 17

What is the action of Zinc on hot NaOH solution? Explain why Mn3+? Mn 2+ is more stable than

94 83 85

Oct-08

Hint: Problems based on the topics: Half Life period Mass defect, average
Mar 06

life, Carbon dating is possible. Refer textbook examples in page no.:144148 and book back problems in page no.:149& 150.Prepare for questions, from the topics: half Life period, mass defect, difference between chemical and nuclear reaction, Q-Value, types of nuclear reaction, Hydrogen bomb, Carbon dating and its uses, Nuclear reaction taking plate in sun, study of a reaction (Mechanisms).
Q.No

A substance is found to have a magnetic moment of 3.9 BM. How many unpaired electrons does it contain?

Mar 06
June 06, 08, 09& 10, Oct 07& 10, Mar 10

18

Why do transition elements form complexes? Why do d-block elements have variable oxidation state? Why Zn 2+ salts are colour less while Ni 2+ salts are coloured? Write a note on alumino thermic process. How is silver extracted from silver coins? Write two alloys of copper and their uses. How does copper reacts with concentrated acids? How is copper sulphate prepared?

85

84

19

Mar 07, 09, June 07 & Oct 06

1 2 3 4 5

20 21 22 23 24 25

83 90,91 96

June 09

QUESTION Principle behind the hydrogen bomb Q value of a nuclear reaction Difference between chemical and nuclear reaction* (any 3) What is radio carbon dating? In the following radioactive decay: 92X232 89Y220 , How many and particles are ejected? Answer: =3, =3. What is binding energy of nucleus? Uses of radioactive isotope to study the mechanism of photo synthesis. Write a note on nuclear power generator.

Page No. 141 138,139 137 141

YEAR Mar 06,10 June 06 Oct 06

Oct 07 137 142 140

89 88 100,101

6 7 8

For question number 37:

80

Example Problems: Page No.:144-148: Example 1,2 (June 07-09), 6 (Mar 08), 7(Mar 07), 8,9 (June 10) and 11 (Oct 09) Practice Problems : Q.No 14, Pg. No.: 149-150, Q.No: 20,26 (Mar 09), 27(Oct 2010), 29, 30, 32 (June 08), 33, 34 and 35 (Oct 08) Explain the nuclear reactions taking place in sun. What is spallation reaction?
142

06,09, Oct 08

4 5 6 7
139

What are point defects ? What is a vitreous state? Write a note on molecular crystal. Write a note on Frenkels defect. Write a note on metallic crystal. Significations of Braggs equation. How glass formed Sketch the following lattices a. Simple cubic b. FCC, c. BCC State Braggs law Write a note about metal excess defect. Any three characteristics of Ionic crystals Write the structure of Rutile (TiO 2) What do you mean by imperfection in solids? Example Problems: 1, 2, 3& 4 Problems for Practice: 1(Repeated), 2, 3.

160 162 158 160 158 156 162 154 156 161 158 159 159 162-163 164 Oct 09 Mar 09 Oct-06 & 07 Mar 08 June 08

10

11

8 9 10 11

12

For question number 38:

Hint: Problems based on the topics: Cubic systems and Braggs law. Prepare 3 marks from the topics: Types of cubic system, Braggs equation and its significance, Types of crystals, types of ionic crystals, Point defects, Super conductors and its applications and Glasses.
Q.No

12 13 14 15 16 17 18

QUESTION What is meant by super conducting transition temperature Application of Super conductors What are super conductors?

Page No. 162 162 161

YEAR June 07 Oct 10, June 10, Mar 06, June

1 2 3

81

For question number 39:

Hint: Problems based on the topics: 1.) Efficiency of a engine, Trautons rule, Change in entropy, standard entropy, standard free energy and enthalpy. Prepare 3 marks from the topics: Various sta tements of second law of thermodynamics, Trautons rule and characteristics of 1.)Entropy, 2.) Gibbs free energy. Q.No 1 2 3 4 5 6 7 8 QUESTION Clausius statement, Kelvin-plank, Entropy statement of second law of thermodynamics Troutons rule or types of liquids or substances derivatives from Troutons rule What is entropy? What are the units of entropy? What is Gibbs free energy? Mention the essential condition for spontaneity in a chemical reaction. Define the standard entropy change of formation. How is G related to H and S? What is the meaning of G=0 Example problems: 1(Mar 08), 2)(Mar 09), 3(Mar 10), 7,8,9& 10(June 08& 10), Page No.
167,168

11& 12. Exercises problems: Q.No 19 (Oct 07, 09), 20, 21& 30.

180-181

For question number 40:

Hint: Problems based on the topics: ng, Formation of HI etc. Prepare 3 marks from the topics: Dynamic equilibrium, Equilibrium constant, reaction quotient, Le-chateliers principle, Habers process and contact process. Q.No 1 2 3 4 5 6 7 QUESTION What is reaction quotient(Q), How is it related to equilibrium constant ? Dissociation of PCl5 decreases in presence of increase in Cl2.why? State Le-chateliers principle What is relationship between formation equilibrium constant and dissociation constant? What is equilibrium constant? Where are the favorable conditions for the maximum yield of ammonia by Hebers process? Why is equilibrium reaction referred to as dynamic equilibrium? Example Problems: from Formation of HI, in page no.: 187 (Repeated), Page No.: 188(Repeated). Answer in one or two sentences: Page Page No.
188

Year
Mar & July 07, Oct 08 Oct 06, June 09 Mar 06 June 06

Year
Oct 07, June 10, 08

Mar 09 190,191 186 Mar07,10 Mar 08

170

168,172 175 176 174 176 170-178

184 192,193

Oct 09

183

Oct 10

Oct 10

8 9

82

10

No.:194, Q.No:9 (Oct 06), 13(June 09), 14(Repeated). Problems For Practice: Page No.:195196, Q.No.: 18(Mar 06), 19(June 06), 26(June 09), 27, 28(Oct 08)

6 7

Write the Arrhenius equation and explain the terms. What are parallel reactions? Give an example Define order of reaction. Compare simple and complex reactions. Define activation energy.

14 19

Mar 07 & Mar 09 Mar 07, 10 June 07, 08,Mar 09, Oct 10 Oct 07 Oct 07 & 08, Mar 08,10 June 08 Oct 08

2 17,18 15

For question number 41& 42:

9 10

11 Hint: Problems based on 1.) First order reaction (Finding K, Half life etc.) 2.) Activation energy. Prepare 3 marks from characteristics of order of a reaction and first order reaction, Examples of first order reactions, half life period, Pseudo order, Arrhenius equation, activation energy, and threshold energy; compare simple and complex reactions, repeated questions from types of complex reaction in board papers. Q.No QUESTION 1 Define Pseudo first order reaction. Give an example. 2 3 4 5 What are the characteristics of 1st order Zero order reaction. Give an example Give 3 examples for opposing reactions What are consecutive reactions? Give an example Page No.
10

12 13 14 15 16 17

Year
Mar 08, June 09& 10 , Oct 09

4 20 18 Mar 06, June 09 June 06, Oct 06, Oct 09

18 19 20

Derive an equation for the halflife period of first order reaction. What are complex reactions? Give an example. Define halflife period. What is meant by Threshold energy? Any three example for first order reaction Define rate of reaction. 75% of reaction of the first order was completed in 48 minutes. When was it half complete? Answer: K=0.0288 min -1.t1/2 =24.06 min What are opposing reactions ? Give an example . Draw the potential energy diagram for activation energy Example Problems: From First order

4 17,18

7 15 4,5 3

20 15

June 09

83

21

reaction: in page no.:8,9 and 10. All examples are repeated in board papers. Example problem in page no.:10 was asked in October 2010. Problems for Practice: Q.No:2,5 (Repeated), 6, 8(repeated).

6 7 22 8 9 10

What is meant by electro osmosis ? What is auto catalyst? Give an example What is heterogeneous catalysis ? Give an example. What is tanning? What is electrophoresis? What are emulsions? Why colloidal system of gas in gas does not exist? What is electro dialysis? Write about Helmholtz double layer. Why colloids are purified? What is Brownian movement? (or) What is the Kinetic property of colloids? Give reason. Give any 3 difference between physical and chemical adsorption. What are general characteristics of a catalytic reaction? What is meant by Tyndall effect?

40 28
27 42 39 42 33 36 38,39 36 38 25 26 38 Oct 2010 June 09

Oct 06
Mar 08 Oct 07 Mar 06 , June 10 June 06 Mar 07 Oct 08

For question number 43:

Hint: Prepare 3 mark from the topics: Difference between Physical and chemical adsorption, Characteristics of catalytic reactions, Types of catalytic reactions and catalysts, promoters, Catalytic poisons and active centres, 1.) Preparation 2.) Purification 3.) Properties and 4.) Applications of colloids. Q.No 1 2 3 4 5 QUESTION What are promoters? Give an example What is catalytic poison? Give an example. What is peptisation? Give an example. Why does the sky appear blue? How is the stability of the sol maintained? Page No. 29 29 35 40 38 Year June 08, Mar 10 June 07, Mar 10 Mar 09

11 12 13 14 15 16

17 18 19

Oct 09

84

20 21 22 23 24 25 26

What is ultra filtration ? What are Lyophobic and Lyophobic colloids? What is induced catalyst? Give an example. What are active centres ? What are dispersed phase and dispersed medium? Any 3 medical applications of colloids? How is colloidal solution prepared by double decomposition method?

37 33

Q.No 1 2

QUESTION Faradays first and second law State Kohlrauschs law.

Page No.
53 61

Year
Mar 06 June 06, Oct 08 & 09 Oct 06,07 July 07, Mar 08, 10 June 08 Mar 09 June 09

28

3
29 32 42 35

What is mean by common ion effect? Define equivalent conductance. Give equation. State Ostwald dilution law. Define electrochemical equivalent. What is its unit? Define Molar conductance. What are indicators? What are insulators? Give 2 examples. Write Debye Huckel Onsager equation for a univalent strong electrolyte. Write a note on Ionic product of water. What do you understand by buffer solution? Give an example. How will you determine of acetic acid ? What is buffer action? Give an example What is Henderson equation? What are Intrinsic and extrinsic semi conductors ?

63

4 5 6

57 52 53 58 73 47 59 64 69 61,62 69 71,72 48

For question number 44:

Hint: Problem based on the topics: Electro chemical equivalent and pH of a solution. Prepare other questions from the topics: Semiconductors, Ostwald dilution law, Faradays first and second law, electrochemical equivalent, Kohlrauschs law, common ion effect, ionic product of water, buffer solution and action, Henderson equation and its significance, pH indicators and its selection for acid-base titra tion, suitable indicator (Phenol pthalein and methyl orange) in the ti tra tion.

8 9 10 11 12 13 14 15

June 10, Oct 10

85

16 17

Example Problems: From pH of a solution, Example problem 3, 4 and 5. Problems for Practice: Q.No.: 1& 2

68

6
80

Meso tartaric acid is optically inactive: explain. Compare diastereomer from enantiomer. Distinguish between racemic and meso forms. What is racemic mixture? Give example. What are optical isomers? Give example. Justify that boat form is less stable than chair form of cyclohexane. Which Isomerism is possible Disubstituted benzene? Give example. in

113 114 113

Mar 10, Oct 06 June 06 Mar 07, June 10, Oct 10 Mar 08 June 09 & Oct 09 June 08

7 8

For question number 45:

Hint: Prepare 3 mark from the topics: Geometrical Isomerism, Mentioning Cis-Trans (or) E, Nomenclature for given alkenes, 1,3 butadiene, cyclohexane, optical isomerism and rotation, condition for optical activity, Isomerism in Tartaric acid, compare 1.)Racemic and Mesoform 2.) Enantiomers and Diastereomer, Racemic mixture and Disubstituted benzene. Q.No 1 2 3 4 5 QUESTION Inter conversion between Cis and trans isomerism Condition for optical isomerism Draw the confirmations of cyclopropane, cyclobutane and cyclopentane. Write a note on Isomerism in1,3 Butadiene What is Geometrical isomerism (or) CisTrans isomerism ? Give examples Page No. 104
110 106,107 Oct 07,Mar09

9 10 11 12

112,112

111 108 116

Year

13

Self Evaluation: Geometrical Isomerism, Q.No:2 (Sep 08), 3(Repeated), 7(Repeated), 9(June 07).

118-120

For question number 46& 47:

106 103

Hint: Prepare 3 marks from the topics: 1.) Ethyl Alcohol Preparation (Ethers, Grignard), chemical properties (Lucas, oxidation, Haloform, Victor Meyer Test) and uses. 2.) Glycol Preparation (Bouveault- Blanc

86

reduction), Physical properties, chemical properties (Terylene, acetaldehyde, dioxan) and uses. 3.) Glycerol Preparation (Saponification, propylene), properties (Acrolein, oxalic acid) and uses. 4.) Benzyl alcohol- Preparation (Grignard, Cannizaro) and uses. 5.) PhenolsPreparation (Dows, Cumene), Physical and chemical properties(Dye test, Bromine water, Kolbes, Riemer-Tiemann, Phenolphthalein, LedererManasse reaction) and uses. Q.No QUESTION 1 Breath Analysis test 2 3 4 5 6 7 8 9 10 11 12 13 Phenol is insoluble in NaHCO 3 solution but acetic acid is soluble. give reason Reaction of glycerol with KHSO4 Explain Dows process How will you Convert Phenol to Phenol Phenolphthalein? Why is glycol more viscous than ethanol? Give a brief account on coupling reaction of Phenol with benzene diazonium chloride. Give ant three uses of benzyl alcohol. Convert ethyl alcohol to diethyl ether. Write the dye test for phenol. How is Allyl alcohol obtained from glycerol? Alcohols cannot be used as a solvent for Grignard reagents. Why? How is ethylene glycol converted into Page No.
134 159 149 157 166 141 165

14 15 16 17 18 19 20 21 22 23

dioxan? Write a note on Kolbes reaction. How is glycerol synthesized from propylene? Give a chemical test to distinguish between ethanol and methanol. How Terylene prepared from glycol? How is phenol identified? How will you convert 2-methyl-2-propanol into 2-methyl propene? What happens when ethylene reacts with cold dilute alkaline KMn O4? Write a note one Haloform reaction. Phenols are soluble in alcohols, Why ? Starting from Phenol, how would you obtain picric acid?

165 147 135 142 163,164 136 139 135 158 164

Oct 08 June 08 June 08 Oct 08 Mar 09 Mar 09 June 09 Oct 09

Year
Mar 06 Mar 07 Mar 07 June 07 Mar & June 06, June 09 June 06 Oct 06

June 10 Oct 10

For question number 48:

Hint: Prepare from these topics: 1.) Acetaldehyde: Preparation (Rosemunds, Stephens), Chemical properties(Addition reaction, Ammonia, Aldol, Clemmenson, Wolff Krishner, Oxidation, Polymerization and uses. 2.) Acetone: Preparation ,Chemical properties (Grignard addition, Ammonia, Reduction, Popots rule, Haloform reaction, Pherone, Mestiylene) and uses. 3.)Benzaldehyde: Chemical Properties (Reduction, Benzoin, Perkins, Knoevenagal, Malachite green) and uses. 4.) Acetophenone: Preparation, properties and uses. 5.)Benzophenone: Preparation (Friedel crafts), properties (Benzhydrol) .

155 132 165 150 130 144

Oct 06 June 07 Oct 07 Oct 07 Mar 08 Mar &

87

Q.No 1

QUESTION How does formaldehyde react ammonia? And mention uses. with

Page No.
211 229 217 201,202 216 226 222 223 230 221 201 198,199

Year
June 06,09, Mar 08, 10, Oct 09,06,10 Mar 07 & Mar 09 June 07 Oct 07 June 08 Oct 08

17 18 19

with conc.H2SO4? How malachite is green obtained from Benzaldehyde? What is Popots rule? Write a note on Wolff-Krishner reaction

223 215,216 215

2 3 4 5 6 7 8 9 10 11 12 13 14 15 16

How acetophenone prepared by Friedelcrafts method? What is formalin? Write its uses. What is Rosemunds reduction? What is the Purpose of adding BaSO4 in it? Write two tests to identify aldehydes. Explain Halo form reaction with example. Naming reaction, Perkins, Knoevenagal. How will you distinguish between formaldehyde and acetaldehyde? How is benzophenone prepared by Friedel-crafts method? Write Benzoin condensation reaction. How is acetaldehyde obtained from calcium salts of fatty acids? Give IUPAC names for i)Crotonaldehyde ii)Methyl-n-propylketone , iii)Phenyl acetaldehyde Write briefly on clemmensens reduction How is Paraldehyde obtained ? Formaldehyde and Benzaldehyde gives cannizaros reaction, but acetaldehyde does not - Explain. How do acetaldehyde and acetone react

For question number 49:

Hint: Prepare 3 marks from source and trivial name. 1.)Acetic acid preparation, chemical properties (Esterification, HVZ, Kolbes electrolysis, 2.) Reducing property and Uses of formic acid test for carboxylic acid, 3.)Lactic acid: preparation (acetylene, propene), properties (Pyruvic acid, dil.H2SO4, Haloform reaction, lactide, PCl5) and uses, 4.)Oxalic acid: preparation, physical properties, chemical properties (NaOH, PCl5, Action of heat) and uses. 5.)Bemoic acid: properties and uses, 6.) Salicylic acid properties(Kolbes), test for salicylic acid, properties (Aspirin, oil of winter green) and uses. 7.)Methyl acetate - properties (Trans-esterification, claisen ester condensation), 8.)Acetamide Preparation, physical properties, chemical properties (dehydration and Hoffmanns) and uses. Q.No 1 2 3 4 5 6 QUESTION Write a note on HVZ reaction Trans-esterification, Claisen ester Mention the uses of oxalic acid. Formic acid reduces Tollers but acetic acid does not. Give reason. How methyl salicylate is prepared? Reaction of lactic acid with dilute sulphuric acid. Page No.
249 268 257 251 264 253

Year
Oct 06 Mar & July 06 Mar 07 & 09 Oct 07, 08 & 09 June 08 Mar 08

Mar 06

214 217 224 217,227

June 10

88

7 8 9 10 11 12 13 14 15

Uses of formic acid, salicylic acid, Succinic acid and lactic acid. What is meant by esterification? Write the equation. Convert phenol into salicylic acid. How you will distinguish formic acid acetic acid. Two test to identify carboxylic acid. Give the source and trivial name of a) HCOOH b)C3H7COOH c)C11H23COOH Account the reducing nature of Formic acid, with suitable example. Give tests for Salicylic acid. Mention the uses of Benzoic acid.

251,264, 257,254 246 262 250 251 241 250 263 262

Q.No
June 06

QUESTION Convert acetamide to methyl amine What is Gabriel pthalamide synthesis

Page No.
290 291

Year
Mar 06 Oct 06,08, Mar07,sep 07,June10 June 07 & 09

1 2

June 09 June 07 Oct 08

3 4 5 6

What is diazotization? Give an example. Write a note on Gattermann reaction Uses of aniline acid. What happens when aniline is treated with phosgene (or) carbon di sulphide Basic nature of aniline What is mustard oil reaction?

308 307

307,309 301 299 294

For question number 50:

7 8

Hint: Chances are more for Organic problems (Identifying A,B,C: Refer Q.N: 50 in Mar 2008,09 and 10, June 2006, 08 & Oct 2009& 10) Prepare 3 marks from 1.)Nitro methane: Tautomerism, properties (Chloropicrin, with Aldehyde and Ketone, reduction) and uses. 2.) Nitro Benzene: properties (Acidic, neutral, alkaline medium, catalytic and electrolytic reduction) and uses. 3.) Methylamine preparation (cyanide, NH3, Gabriel), basic nature, chemical properties (HNO2, carbylamines, mustard oil, Schiffs base) and uses. 4.)Aniline : Preparation (Hoffmanns) properties (HNO2, carbylamines, mustard oil, Schiffs base) and uses. 5.) Benzene Diazonium Chloride: Preparation, properties (Sandmeyer, Gattermann, Gomberg, diazonium coupling) and uses.

For question number 51:

Hint: Prepare 3 marks from the topics: Anaesthetis, antipyretics, antiseptics, antiprotozoals, Antibiotics, antacids, antispasmodics, and characteristics of dye, chromophore and auxochrome, chemical in food, artificial sweetening agents and anti oxidants. Rocket propellants (Use and examples), Buna rubbers (Buna N & S), Nylon 66 (Preparation and uses), Formaldehyde Resins.

89

Q.No QUESTION 1 Write a note on Buna S and its uses 2 3 4 5 6 7 8 9 10 11 12 13 14 Write a note on Antiseptic What are chromophores? Give two examples. What are anesthetics? Give one example. Why are Iodoform and phenolic solutions called antiseptic? Give the preparation of Buna-N rubber. How is nylon -66 (or) Polyamide prepared? Give its use. Give a note on Antibiotics In what way antacids are important How is Dacron prepared? Give any two uses. ( Hint: Refer Hydroxy Deri vati ves for ans.) What are artificial sweetening agents? Give two examples Write a note on chemicals in food. Give the characteristic of dye What are antispasmodics and antipyretics?

Page No.
339 334 336 333 334 339 340 334 334,335 142 & 339 337 336,337

Year
June 06 Oct 06 Mar 07,10 & June 09 July 07 & 08 Mar 08 Oct 08 Mar 09 June 10 Sep 07 Mar 06 Oct 09

SECTION A (Inorganic Chemistry)

S. No 1 2 3 4 UNITS Atomic structure II D-block F-block Co-ordination compounds MAX.QUS 1 1 1 1 Normally. Q.No 52 53 54 55

SECTION B (Physical chemistry) 5 6 7 8 Thermodynamics Chemical equilibrium Chemical kinetics Electro chemistry II 1 1 1 1 56 57 58 59

SECTION C (Organic chemistry) 9 10 11 12 Ethers Carbonyl compounds Carboxylic acids Chemistry in action Total 1 1 1 1 12 60 61 62 63

335 335,333

Note: There are no three marks Question from the following chapters: F-block Co-ordination compounds Electro chemistry II Ethers Biomolecules

90

Answer any 7 questions choosing at least 2 from each section. SECTION A INORGANIC CHEMISTRY

9. 10. 11. 12.

Explain the types of Hydrogen Bonding. Page No.27,28 Whats Hybridisation? State its salient features. Page. No 22,23 Explain the verification of particle character. Page. No 5. Write a note on importance of hydrogen bonding. Page. No 29.

For Question Number 53:

For Question Number 52:

Note: Till now (from March 06 to Oct 10) Extraction of copper is not given in board Question papers. Questions based on chemical properties of copper, Zn, Ag, CuSO4, Cr.
1.

Note: Problem chance based on De-Broglie equation and Uncertainty. 1. Derive de-Broglie wave equation and mention its significance.
Page No.5, 6 (Oct 06, June 07)

2. 3. 4. 5. 6. 7.

Explain inter & intra molecular hydrogen bonding. Discuss Davisson & Germers experiment. (Mar 07) Page No. 3, 4 Give any five postulates of molecular orbital theory. (Mar08) Discuss the shape of s, p, and d, orbital. (still this book back question is not given in board exam) Page No.17 Explain the formation of O 2 molecule by molecular orbital theory.
Page No.22, 23 (Mar 10,06 , June 06, Oct 07)

Extraction of silver from its chief ore? Page no: 75

08, Oct 07)

(June 06 &

2. 3. 4. 5. 6.

Extraction of zinc from its chief ore? Page no:93 (June09,Oct10,Mar

06)

Extraction of gold from its chief ore? Page no:97 (June 10,Oct
06,09, June 07, Mar 08)

Explain the formation of N 2 molecule by MOT. (June 08,10 Oct08,10) Page No.22

Extraction of copper from its chief ore? Page no: 86,87 (chance) Explain the preparation of K 2Cr2O7 and its oxidizing property.
Page no:99, 100

8.

Problems: Examples volume I Page No. 6-10(De-Broglie) Example 1, 2, 3(repeated), 4(repeated), 5(repeated) Problem for practice ( Page no 10) Question no 4 (repeated), 5 (Oct 09), 7, 8 and 9. Problems: Examples volume I Page no 11 and 12 (Uncertainty) Example 1 Page No 11. Problem for practice 1 and 2(repeated), 5 (Mar 09) Page no: 12.

Explain how potassium dichromate is extracted from chromium ore. Page no:99 (Mar 07,10) 7. Explain alumino thermic process involved in the extraction of chromium. Page no:90, 91 (Mar 09, Oct 08) 8. Explain salient features of oxidation states of transition elements.
Page no:84

For Question Number 54:

91

1. Note: Normally indirect (or) twisted Questions chance, so read full unit properly. 1. Explain the extraction of lanthanides from monazite sand. Page
no: 111(Oct 06,10,Mar 10 June 07)

In the compounds K4Fe (CN)6 , [Cu(NH3)4] SO4 , Mention a) IUPAC name b) Central metal ion c) ligand d) Co-ordination number Page no:124 (Oct 06, Mar & Oct 07, Oct 09) Explain the postulates of Werners theory? Page no:126 (Mar 06) [Ni (CN) 4]2- is diamagnetic, whereas [Ni (NH 3)4]2+ is paramagnetic, Explain. Page no: 128 (June 10, Oct 10) In what way does [FeF6]4- differ from [Fe (CN)6]4-? Page no: 129
(Mar 09)

2.

What is lanthanide contraction? Discuss any three consequences & causes of lanthanides extraction. Page no: 109,110(June 06, Oct
07 & Mar 09,07)

2. 3. 4. 5. 6. 7. 8.

3. 4. 5. 6. 7. 8.

Uses of lanthanides & actinides. Page no:112,113(June 09, Oct 09) List the similarities & difference between lanthanides & actinides.
Page no: 112, 113 (Mar 06, June 10)

Mention oxidation state and any 3 uses of lanthanides. Page no:

109,112(Oct 08)

Mention oxidation state and uses of actinides. Page no:110,113 Discuss the position of lanthanides in the periodic table. Page no:
108,109(Mar 08)

Compare the properties of lanthanides and actinides. Page no:112

(June 08)

9. What is actinide contraction? Write its causes. Page no:110,111 10. i) +3 oxidation states of lanthanides is the most sable. ii) Why f-block elements are called inner translation elements?
Page no:109

9.

Explain co-ordination isomerism (or) ionisation isomerism with example. Page no: 121 (June 0708, Mar & Oct 08. June 09 as 65a) Apply VB theory for [Ni (CN)4] & [FeF6] & explain the shape & magnetic properties. Page no: 128, 129 Write a note on stereoisomerism (or) cis-trans isomerism and Optical isomerism. Page no: 123-125 K3[Cr(C2O4)3].3H2O Mention Page no:120 a) IUPAC Name b) central metal ion c) ligand d) coordination number How chlorophyll important. Mention its function. Page no:
131,132(Mar-08)

For Question Number 55:

Note: Very important chapter useful for writing Q. No 55 as well as 65(a). So read properly. Questions may inter change.

10. In co-ordination complex [Co(NH3)6]Cl3. Mention the following a) IUPAC name b) ligand c) Central metal ion d) Co-ordination number e) nature of complex (June 09) 11. Mention the type of hybridization and magnetic property of the following complexes using VB theory: Page no:129 i) [FeF6]4ii) [Fe(CN)6]4-

92

12. Mention the function of haemoglobin in natural process. Page

no:131 (Mar 10)

7.

13. Explain the IUPAC rules of nomenclature. Page no: 119-120. 14. Mention any 5 uses of coordination compounds. Page no: 130.

8.

i) How is efficiency of machine determined? Page no: 168 ii) How is G is related to H and S? What do you mean by G=0? Problems: Examples volume I Page no 180 and 181. 19 (model papers), 22, 23 and 29 (repeated)

SECTION-B
PHYSICAL CHEMISTRY.

For Question Number 57:

For Question Number 56:

Note: Problem also possible. Only in Oct 2006 problem is given from this chapter. 1. Apply Le Chatliers principle; explain the condition to yield maximum ammonia (or) Habers process. Page no:192,193
(June 06, Mar 08, June 10 )

Note: Till now problems is not given in Board Question papers. 1. 2. 3. 4. Various statement of second law? Page no:167,168 (Mar, June &
Oct 06,10, Mar 08, Oct 09,10)

2. 3. 4. 5.

Characteristics of entropy (spontaneous reaction)

no: 171(June 08, Oct 08 & Mar 09)

Page

Explain about the application of Le Chatliers principle to contact process. Page no: 193 (Oct 07,June 08 Mar 09, ) Derive an expression for K C and KP for the formation of HI. Page no: 187 (Oct 09)
Derive the expression for Kc and K P for decomposition of PCL5. Page no: 189, 190 (Mar-07)

Characteristic of Gibbs free energy or free energy.

Page no: 176-177 (Mar, June & Oct 07, June 09)

What is spontaneous reaction? What are the conditions for spontaneity of a process? Page no: 175-176(Chance for this March
2010)

Derive relation between KP=KC (RT)n(g) for a general chemical equilibrium reaction. Page no: 184,185 (Mar 06, June 07, Oct 08,
Mar 10, Oct 10)

5. 6.

State 1st Law and mention limitation of 1st law of Thermodynamics. Page no: 167 State Troutons rule, mention its applications and give examples of substance that deviates from Troutons rule. Page no: 170

6.

State Le Chatliers principle. Discuss the effect of pressure, concentration and temperature on the following reaction. N2(g) + O 2(g) 2NO(g) (or) N2O4(g) 2NO2(g) Page no: 191,192 (June 09)

93

7.

Problems: Problem for practice (volume I) Page no 195 and 196. Q. no 26 (dissociation of HI) (Oct 06), 29 (model papers)

For Question Number 58:

10. Problems: Solved problems in text book (volume II) Page no 5 Example (N2O5 decomposition) Page no 6 Example (H2O2 decomposition) Page no 8 Compound A problem (Mar 09), Thermal decomposition of N2O Page no 9 99.9% problem, page no: 13(Methyl acetate problem) 11. Solve the problems Page no 22, 23. Q. No 5, 6 and 8. (all the above
mentioned problems are given in model question papers)

Note: Problem also possible. Only in Mar and Oct 2009 problem is given from this chapter. 1. 2. 3. 4. 5. 6. 7. 8. 9. Derive the equation for rate constant for a first reaction. Page no:3 and 4 (June 09) Decomposition of H2O2 in aqueous solution. Page no: 6 (Oct 07, June 06) Difference between simple and complex reaction. Page no:18
(June 07, Oct 10)

For Question Number 59:

Note: Problem based on Nernst equation more chance. 1. 2. 3. 4. 5. Derive Nernst equation. * Page no:92 to 94 ( Oct 06, Mar 09) How is e.m.f of a half cell determined? Page no: 86,87 How SHE constructed? Which is the e.m.f of it? What is the use of it? Page no:87 and 88 (Oct 09) Write an account on cell Terminology Page no:84 (June 09) Calculate the e.m.f of the cell Zn, 2n2+ 2Ag+, Ag E cell = 1.56 at 273K. Concentration 2n2+ is 0.1M and Ag + = 10M. Page no:96 and 97 (Mar 06, June 06, 07 & 08, Oct 08, Mar10,
Oct 10)

Give

characteristics

of

order

of

reaction?

Page

no:2

(Mar 06, Oct 08,Mar 10,June 10)

Explain the experimental determination of rate constant of acid hydrolysis of methyl acetate. Page no:11 to 13 (Mar 07) Discuss the characteristics of a first order reaction. Page no:4 (Oct-06) Write an account of the Arrhenius equation for rates of chemical reactions. Page no:14 Write notes on i) consecutive reaction ii) Parallel iii) opposing. Page no:18 to 20 (Mar & June-08) A first order reaction is 75% complete in 100 minutes. What are the rate constant and half life period of the reaction? (Oct 09)

6.

7.

The e.m.f of the half cell Cu2+(aq)/Cu (s) containing 0.01 M Cu2+ solution is +0.301 V. Calculate the standard e.m.f of the half cell Page no:101 (Mar 07, June 10) Determine standard e.m.f of a cell and standard free energy change of the cell reaction Zn, Zn 2+, Ni2+, Ni. The standard

94

reduction potentials (E) of Zinc -0.76 V and nickel -0.25 V. Page no:92 (Oct 07, Mar 08) 8.
Calculate the e.m.f of Zn Ag cell. Zn 0.001M, Ag 0.1M. The standard potential of Ag Half cell +0.80V, Zn Half cell -0.76V. Page no:95,96

5. What are ethers? How are they classified? Give examples. Page no:182 6. Any three methods of preparing diethyl ether. Page no:184,185
(June 07, Mar 08,Mar 10)

9.

How will you predict the feasibility of a reaction with the help of electro chemical series? 10. Calculate the e.m.f of a cell Cd | Cd2+ Cu | Cu2+ and determine the cell reaction. The standard reaction potentials of copper and cadmium are 0.34V and -0.40V. predict feasibility of the cell reaction. Page no:91 (model papers)

SECTION-C For Question Number 60:

7. How Ethers do reacts with HI? Give the significance of the reaction.* Page no:189 and 191 (Mar-06) 8. Explain the reaction of diethyl ether: (i) as Lewis acid. (ii) Reaction involving C-O bond. (iii) Grignard reagent Page no:187,188 9. Illustrate electrophilic substitution reactions of anisole. Page no: 191,192 10. How does diethyl ether reacts with PCl 5 one mole of HI and excess of HI. Page no: 189 (Oct 10)

For Question Number 61:

Note: Normally twisted type question chance. So read properly. 1. Action of anisole with a) HI, b) Nitrating Mixture, c) Br2/FeBr3. Give any 2 preparation of anisole. Page no: 191.192 (June 08,
Mar 09)

2. Distinguish between aliphatic and aromatic ethers? Page no:192

(Oct 06 & 08, June 09, Oct 09, June 10) 3. Discuss the isomerism in ethers. Page no:183 (June 06, Oct 07)

4. What happens when diethyl ether treated with a) O2/long contact b) dil. H2SO4 c) Conc. H2SO4 d) Cl2/dark
Page no: 186 to 188 (Mar 07)

Note: Mechanism (or) Naming reaction (or) Distinguish between chemical properties 1) acetaldehyde 2) acetone 3) benzaldehyde chance 1. Mechanism of aldol condensation of acetaldehyde. Page no: 207 (Oct 06 & 08, Mar & June 07) 2. Mechanism of aldol condensation of acetone. Page no:207, 208 (Oct 08) 3. Mechanism of crossed aldol condensation. Pageno:208
(June 06, June 10)

4.

Mechanism of Cannizaro reaction. (Mar 06, June 08, June 09, Mar 10)

Page

no:220

95

5. 6. 7.

Mechanism of Claisen (or) Claisen-Schmidt reaction. Page no:221

(Sep -07, Oct 10)

4. 5.

Distinguish between Acetaldehyde and acetone. Pageno:228

(Mar-08)

Explain Popotts rule with an example. Page no:215, 216 (Mar 09) 8. Write a note on (i) Stephens reaction Page no: 204 (ii) Perkins reactions. Page no:222 (Oct 09) 9. How you convert acetone into (a) mesitylene (b) Mesityl oxide (c) phorone (d) isopropyl alcohol. Page no:226 and 227 10. What happens when the following compounds reacts with ammonia (a) HCHO (b) CH3CHO (c) C6H5CHO. Page no:211 11. Compare acetaldehyde and Benzaldehyde. Page no:224

6. 7. 8. 9.

How oxalic acid manufactured from sodium for mate. Page no:254, 255 (Oct 07) Convert the following (i) Lactic acid to Lactide Page no:253 (ii) Succinic acid to succinimide Page no:256 (iii) Salicylic acid to aspirin Page no:263 (iv) methyl salicylate Page no:264 (v) Benzonic acid to benzyl alcohol. Page no:261 (June 07, Oct 08,) Distinguish between formic acid and acetic acid. Page no:250
(Mar 07)

For Question Number 62:

Explain the mechanism of esterification involving carboxylic acid and alcohol Page no:246,247 (Mar 08,Oct 09) How lactic acid manufactured? How it convert into cyclic diester? Page no:251, 252,253 (Mar 06) What happens when (i) oxalic acid treated with Ammonia. Page no:256 (ii) Benzonic acid treated with PC5 Page no:260
(June 08)

Note: useful for writing Q. No 62 and 68 (b) questions may interchange mechanism (or) convert the following chance from chemical properties 1) oxalic acid 2) benzoic acid 3) lactic acid 4)acetamide 1. 2. 3. Mechanism of bromination of salicylic acid. Page no: 263 Account for the reducing property of formic acid. Page no: 250
(June 06, June 09 as 68.b, Mar 10)

10. Explain the mechanism of Kolbes reaction. Page no:262 (Mar 09) 11. What happens when lactic acid is (a) treated with dil. H 2SO4, (b) with PC5 (c) oxidized with acidified KMnO 4 (d) tenfons
reagent.(June 09,June 10)

12. Explain the reaction of CH3CONH2 with i)P2O5 ii)Br2/NaOH hydrolysis by an acid. Page no:270 (Oct 10)

iii)

For Question Number 63:

How benzoic acid obtained from; b) Phenyl cyanide

a) Ethyl benzene c)CO2

Note: Twisted questions (or) two 3 marks combine as 5 marks question. Chance

(Oct 06, Oct 09 as 68.b) Page no:259, 260

96

1. 2. 3. 4. 5. 6. 7.

Write a note on Buna rubbers? Mention its uses? Page no:338,339 (Mar 07 & 08) Explain the characteristics of rocket propellant? Page no:337,338 (Mar 06, June 06, 07 & 08, Oct 07, Mar 09) Explain briefly on colour and structure of dyes. Page no:335,336
(Oct 08 & 09&10)

chance) 6 Organic nitrogen compounds And Biomolecules Hydroxy, carbonyl, carboxylic(inter related) And D-block 1 69a & 69b

70a & 70b

Give the characteristic of a dye. Page no:335 (June 09) Write the preparation of Buna - S and nylon66. Page no: 339,340. (Mar 08) Write the preparation of any three condensation polymers. Page no: 339.340. Write a note on Anesthetics. Page no:333 (Oct 06, Mar10)

8. EITHER-OR Carbonyl ,carboxylic ,organic nitrogen(inter related)& 1 Electro chemistry I

70c & 70d

For Question Number 64 (a) & (b):

S. No 1 2 3 4

UNITS Atomic structure II And P-block Co-ordination compounds And Nuclear chemistry Solid state II And Surface chemistry Electro chemistry And Electro chemistry II Isomerism in organic chemistry And Carboxylic acids Or Hydroxy derivative (less

MAX QUS. 1 1 1 1

Normally. Q.No 64a & 64b 65a & 65b 66a & 66b 67a & 67b Hint: one question direct another indirect (or) twisted (or) two 3 marks combine as 5 marks. So writing both 64(a) and 64(b) is difficult so prepare well. 1. Write a note on Pauling and Milliken's scale of electro negativity. Page no: 43,44

68a & 68b

97

2. 3. 4. 5. 6.

How is fluorine isolated from their fluorides by Dennis method? Page no:68 (Mar 06, Oct 09) What are the factors affecting ionisation energy?(ANY 3) Page no:38, 39 (June 08) Explain the various factors affecting electron affinity. Page no:41, 42 (June 06 & 07, Mar 07 & 09, Oct 06) How are noble gases isolated from air (Ramsay and Dewars method)Page no:74, 75 (Oct 06, June 06 & June 09,Mar 10) Illustrate: i) tribasic nature of orthophosphoric acid Page no:61 ii) Reducing property of phosphorous acid Pageno:60
(June 07)

15. Explain how electro negativity values help to find out the percentage of ionic character in Polar covalent bond. Page no:45
(Oct 08)

16. Explain the following i) dehydrating property of P2O5 Page no:60 ii) oxidizing power of fluorine. Page no:66 17. Discuss the property of interhalogen compound of AX3 and AX5 type Page no:71, 72 18. Write a note on halogen hydrides. Page no:66, 67

7. 8. 9. 10. 11. 12. 13.

Explain Pauling method to determine ionic radii? Page no:34, 35

(Mar 06, Oct 09,Mar 10, June 10, Oct 10)

Discuss the structure of interhalogen compounds of AX and Ax5 type. Page no:71 and 72 (Oct 07) How electro negativity values help to find out the nature of bonding between atoms? Page no:45 (Oct 07, June 09) What are silicones? How are they prepared? Mention its uses. Page no:51, 52 (Mar 07) Extraction of lead from galena. Explain. Pageno:53, 54 (June 08) How are atomic radii calculated from covalent bond length? Page no: 32, 33 Explain the Pauling scale for the determination of electro negativity. Give the disadvantage of Pauling scale. Page no:43
(Mar 08)

For Question Number 65 (a) & (b):

Hint: one question direct another indirect (or) twisted (or) two 3 marks combine (as 5 mark). Problem from Nuclear chemistry as 65 (b) is chance. Writing both (a) and (b) are difficult. So prepare well. 1. 2. Differentiate nuclear reactions & chemical (2) Chelates reactions.

Page no:137 (Mar 09) Explain the terms (1) Neutral ligand (3) Co-ordination sphere (4) Central metal atom (5) Co-ordination number Page no:117, 118(Oct 08) 3. Mention the uses of radio isotopes in study of hydrolysis of ester and in mechanism of photosynthesis. Page no:142, 143 (Oct 08)

14. Write any five points about the anomalous nature of fluorine. Page no:67 (Mar 08 & 09, June 10, Oct 10)

98

4. 5. 6. 7. 8. 9.

Explain

nuclear

fission

reaction

with

example.

16. Difference between nuclear fusion and fission reactions (Oct 09) 17. Solved problems: Example 3 Cobalt 60. 5.26 yrs (refer text book vol. I Page no 144) Example 4 (refer text book vol. I Page no 145, 146) 18. In what way complex salt differ from double salt?

Page no:139 (June 08) Explain the geometrical Isomerism in co-ordination compound. Page no:123 to 125 Explain the nuclear reaction that take place in sun. Page no:142
(June 07)

Page no:115, 116 19. Define (i) Target nuclear (ii) Recoiled nuclear (iii) Ejected particle with example. Page no:138 of valence bond theory. 20. Mention the type of hybridization and magnetic property of the following complexes using VB theory: Page no:129 i) [FeF6]4ii) [Fe(CN)6]4- (Mar 06) 21. Apply VB of find out the geometry of [Ni(NH3)4]2+ and calculate its magnetic moment. Page no: 128 (Oct 06). 22. Explain hydrate and linkage isomerism with suitable example. Page no: 122 (Mar 10) 23. Explain coordination and ionization isomerism with suitable example Page no: 121,122 (Oct 10)

Explain the principle underlying the function of hydrogen bomb. Page no:141 (Mar 07) Explain the postulates Page no:127 (Mar 09) Explain radio carbon dating. Mention the uses. Page no:141,142
(Mar 08, Oct 06 & 07, June 06, Mar 10, June 10, Oct 10)

10. Give

the

postulates the function

of of

Werner's

theory in

of

co-ordination process?

compounds. Page no: 126 11. Mention Page no:131

(June 06, 07 & 08, Oct 07 & 09)

hemoglobin

nature

12. Explain the uses of radioactive isotopes with specified examples. Page no:143 13. What is controlled and uncontrolled Page no: 139, 140 14. [Ni (CN)4]2- is diamagnetic whereas [Ni (NH 3)4]2+ is paramagnetic. Explain. Page no:128 explain.
(Mar 07, June 10) (Mar 06, June 09)

fission

reaction?

For Question Number 66 (a) & (b):

Hint: Normally March question papers book back questions from both units chance. So read all book back questions properly.

15. [Cu (NH3)4]2+ is square planar, where as [Ni Cl 4]2- Is tetrahedral

99

Even book back question in SURFACE CHEMISTRY twisted (more chance)

1. 2. 3. 4.

Explain Bragg's spectrometer method. Page no:157

(Mar 08, June -06 & 09, Oct 06, 07 & 09, Mar 10)

Write a note on electro-osmosis. Volume II Pageno:40

(June 08, Oct 07)

13. Write a note on; (a) Auto catalyst (b) Promoters Page no:28,29 Volume II (Oct 09) 14. Discuss factors affecting adsorption. Page no:25, 26 Volume II 15. Write a note on emulsion. Page no:42 Volume II 16. Explain Brownian movement and Tyndall effect. Page no:38 Volume II. 17. write a note on a)electro dialysis b)ultra filtration Page no:36,38 (Volume II)

Write briefly about the preparation of colloids by dispersion method. Page no:34, 35 Volume II (Mar 08, June 06) Explain the chemical methods of preparing colloids (or) condensation method. Page no:35,36 Volume II
(June 07, Oct 06,June 10,Oct 10)

For Question Number 67 (a) & (b):

5. 6. 7. 8.

Explain the nature of glass. Page no: 162 (Mar 07) What do you mean by ionic crystal? Write the properties of ionic crystal. Page no: 158 (June 07)
Explain Schottky and Frenkels defects in crystals. Page no:160 (Mar 06 & 09 Oct 08,June 10, Oct 10)

Hint: Normally one question standard and another twisted (chance) Problem also possible from electro chemistry II (Nernst based problem) 1. 2. 3. 4. 5. Describe Daniel cell. Page no:83 (June 07, Oct 09) Derive Nernst equation Page no:92 to 94
(June & Oct 08, June 06, June 10, Oct 10)

What are super conductors? Write their uses. Page no:161,162

(June 08)

9. Explain AB & AB2 type of ionic crystal with example. Page no:159 10. Write briefly on adsorption Theory of catalysis. Volume II Page no:30, 31 (Mar 06 & 09) 11. Write briefly on intermediate compound functions theory with an example. Page no: 30(Volume II) (Mar 07 & Oct 08) 12. Give any five differences between physical adsorption and chemical adsorption. Page no:25 Volume II (June 09)

How is e.m.f of a half cell determined? Page no:86, 87 (Mar 08) Describe Henderson equation for an acidic buffer solution? Page no:70,71,72 (Mar 08, June 07, Oct 06) Explain Oswald dilution law? Page no:52, 53
(Mar 06,Mar 07 , Oct 08)

100

6. 7. 8. 9. 10. 11. 12. 13. 14. 15. 16. 17. 18.

Establish a relationship between free energy& e.m.f. Page no:91, 92 (Oct 06 & 07, June 09) Write the IUPAC convention of repetition of cell. Page no:84 to 86 (Mar 06, 07 & 09, Mar 10) Describe the construction and function of standard hydrogen electrode. Page no:87, 88 Explain buffer action of acidic buffer with example. What is buffer solution? Page no:69 and 70 (Oct 09) Explain Quinonoid Theory of indicators. Page no:76, 77 (Oct 07, June 08,Mar 09, Oct 10) Explain Ostwald Theory of indicator. Page no75, 76(June 10) Write the postulates of Arrhenius Theory of electrolytic dissociation. Page no:49 to 51 (June 09,June 10) How would you predict the displacement of one metal by another metal? Page no: 90 State and explain Kohlraushs Law. Page no:61 Write any three applications of Nernst equation. Page no:94,95,96 What is common ion effect? Give three examples. Page no:63 Give the evidence for Arrhenius Theory. Page no:51 and 52 (Mar 10) How will you choose indicators for various types of titrations? Explain with titration curve. Page no:74, 75

Hint: Normally one question standard and another twisted type. Writing both the question is difficult. Convert the following more chance from carboxylic acid

1. Convert;

(1) Salicylic acid methyl salicylate Page no:264 (2) Lactic acid pyruvic acid Page no: 253 (3) Methyl cyanide Acetamide page no :269 (4)Methyl acetate Ethyl acetate. Page no:268 (Mar 08) What happens when Lactic acid is; Page no:253 (i) treated with dil. H2SO4 (ii) heated alone (iii) oxidised with alkaline KMnO4? (Mar 07) Describe the conformations of cyclohexanol. Comment their stability. Page no: 108 (Mar 07,Mar 10,Oct 10) Discuss the optical isomerism in tartaric acid.Page no:112,113
(June 06 & 08, Oct 08, Mar 09,June 10)

2.

3. 4. 5. 6. 7.

For Question Number 68 (a) & (b):

Distinguish between enantiomers from diastereomers. Give an example each. Page no:114 (Mar 06 & 08) Distinguish meso from with racemic form with suitable example. Page no:113 (Oct 06) Explain internal and external compensation with suitable example. Page no:112, 113 (June 07)

101

8.

Convert the following: Salicylic acid aspirin page no:263 Salicylic acid 2, 4, 6, tribromophenol Page no:264 Salicylic acid methyl salicylate.Page no: 264 Lactic acid Lachide Page no:253 (June 06,June 10) 9. Write the mechanism involved in the esterification of carboxylic acid with alcohol. Page no:246,247 (Mar 06,June 07, Mar 08) 10. Mechanism: Bromination of salicylic acid. Page no:263
(Oct 07 & 08)

1. 2. 3. 4.

How is the structure of glucose determined? Page no:320 to 322

(June 06, Mar 09, June 10)

Discuss the structure of fructose in detail . Pageno:320to322

(Mar 06 & 07, Oct 07 & 08, June 09, Oct 09,Oct 10)

11. Discuss the isomerism exhibited by carboxylic acid. Page no: 242
(Oct 06)

5.

12. Write a note on Cis-trans Isomerism. Page no:103,104

(Oct 07 & 09, June 09)

13. Explain the Isomerism exhibited by di substituted benzene. Page no:116 to 118 14. Explain i) Kolbes electrolytic reaction Page no: 249 and ii) Trans estertification reaction. Page no:268 (Mar 10) 15. How is Oxalic acid manufactured from Sodium Formate. Page no:254, 255 (Oct 10)

Out line the classification of carbohydrates giving an example for each. Page no:318to320 (Mar 08, June 07 & 08,Mar 10) What is peptide bond? Illustrate the formation of peptide bond in glycylalanine. Draw the structure of glucose and fructose. Page no:327 (Oct 06) Convert the following: a) Nitro benzene phenol hydroxylamine Pageno:284 b) Aniline phenyl isocyanides Pageno: 301 c) Benzene diazonium chloride biphenyl Pageno:308 d) Nitro methane methyl amine. Pageno:280 e) Methyl amine methyl isocyanides pageno:294
(June 07, Oct 06)

6. 7. 8. 9. 10. 11.

Distinguish

between

primary,

secondary&

tertiary

amine.

Pageno:295 (Mar 06 & 09, June 06 & 09, Oct 07 & 09,Mar 10,Oct 10)

For Question Number 69 (a) & (b):

Hint: One question standard and another twisted, more chance for convert the following from organic nitrogen compounds.

12. 13.

Explain the Gabriels phthalimide synthesis Pageno:291 and mustard oil reaction. Page no:294 (Mar 09) Mechanism of nitration of benzene. Page no 282 t0 283 Mechanism of Hoffmans bromamide reaction. Page no:290 How phenol, chlorobenzene, biphenyl prepared by using benzene diazonium chloride. Page no:306,307,308 (Mar 08) Write a note on the reduction nitrobenzene under different conditions. Page no:284, 285 (Mar 07,June 10) Biological importance of lipids. Page no:328 (chance) How does Nitric acid react with Primary, secondary and tertiary Amine. Page no:294 (June 08)

102

14. Explain the following reaction aniline: i) Coupling reaction Page no: 308 ii) Schotten-Baumaan reaction Page no: 300 iii) Carbylamine reaction Page no: 294 15. Write a note on amino acids Page no: 326,327 16. Write a short note on i) starch ii) cellulose Page no: 325,326 17. Write a note on Iso-electric point and di-peptide. Page No. 327.

7. In Lucas test

Tertiary alcohol give turbidity immediately Secondary alcohol give turbidity slow.

Primary alcohol give no turbidity

8. For a compound to give Iodoform test it should have either CH3 CH group (or) CH3 C group. | OH O 9. Decarboxylation is done by heating the compounds with soda lime 10. Organic acid effervescence with sodium bicarbonate. (June-

To solve 70.A and 70.C Organic problems from i) Hydroxy Derivatives ii) Carbonyl Compounds iii) carboxylic acid iv) organic nitrogen compounds(interrelated between all these four chapters) Points to remember to solve70 A (or) 70 C. (Total - 28 points) 1. Alcohols when treated with sodium. Liberate hydrogen. 2. 3. Secondary alcohol gives ketone

2007)

4. Phenols give violet colour with neutral Fecl 3 5. Phenols give a white precipitate when treated with bromine water (test for phenols). Brown colour of bromine water disappears. 6. In Victors Meyers test Primary alcohol gives red colour. Secondary alcohol gives blue colour. Tertiary alcohol gives no colour.

11. Acetaldehyde, acetone, ethyl alcohol and acetophenone give yellow precipitate with I2 and alkali 12. Benzaldehyde, formaldehyde, acetaldehyde and acetone give addition compounds with sodium bisulphite 13. Amide or alkyl cyanide-give ammonia on hydrolysis 14. Aromatic fuming compound is benzoyl chloride and aliphatic fuming compounds is acetyl chloride 15. Primary alcohols on oxidation give Aldehyde and Aldehyde on oxidation give acids. 16. Secondary alcohols on oxidation give ketones and ketones on oxidation give acids of lesser no. Of carbon atom. 17. Aldehydes on reduction primary alcohols ketones on reduction secondary alcohols. 18. Acetaldehyde contains alpha hydrogen so it under go aldol cond.

103

19. C6H5CHO, HCHO, CCl3 CHO have no alpha hydrogen so it under go Cannizaro condensation. 20. A compound to undergo Iodoform reaction it should have either CH3CH OH (or) CH3CO group (this point is important) 21. Benzaldehyde (a) it does not reduce Fehlings solution. (b) Used to prepare M alachite green dye. 22. Acetophenone (a) Used as hypnotic and perfumery. 23. In presence of dry HCl gas two molecules of acetone condense to give phorone. 24. With conc. H2SO4 three molecules of acetone gives mesitylene. (Oct 2009) 25. Benzophenone does not give bisulphate addition product with NaHSO3. 26. Nitro benzene bitter almonds smell and called as oil of mirbane. 27. Benzaldehyde bitter almonds smell but m.f.C 7H6O. (Mar
2009)

2 3 4 5 6 7 8 9

Page No: 134-135

Ethyl alcohol reaction with acidified KMnO4 Iodoform test. (June 06, 07, Mar 09) Synthesis of Glycerol.
(general board exam paper Mar 07)

Page No: 136-137 Victor Meyers test. (Mar 07) Page No: 147 Page No: 152-153 Page No: 154 Page No: 157

Preparation of benzyl alcohol. Properties of benzyl alcohol. Benzyl alcohol oxidation reactions. Preparation of phenol.
Phenol on reaction with benzene diazonium chloride, Kolbe Schmidt (or) Kolbes reaction, Riemer-Tiemann reaction. (Oct 07)

Page No: 152-153 Phenol reaction with NaOH and Na. Page No: 165 (Very important)

28. Refer all naming reactions given in page no. 240 (Vol-2). And Kolbes mechanism (June 06, Mar 07). Claisen ester cond. Dry distillation preparation of acetophenone and Benzophenone (Mar- 08) Fentons reagent (June 08). Baeyers reagent (June 09). Refer HYDROXY Derivatives to solve 70. A or70.C problems 1 Page No: 130-131 Ethyl alcohol reaction with sodium, Lucas test, copper (June 06, 07 & 09, Mar 09)

Refer carbonyl compounds to solve 70 (a) or (c) Problems Oxidation of alcohols acetaldehyde (or) 1 Page No: 200 acetone Reaction with ammonia 2 Page No: 211 a)acetaldehyde b)formaldehyde c)acetone Acetaldehyde (or) acetone reaction with Page No: 214-215 3 NaBH4 Clementon, Wolff Kishner, Tollens, (very important) Fehlings solution reaction 4 5 6 Page No:216-217 (very important) Page No: 219 Page No: 221
Acetaldehyde answer with Tollens and Fehlings test, formaldehyde and acetaldehyde polymerisation reaction (June- 2006,Mar-2009) Chemical properties of Benzaldehyde. (Mar 08)

Benzaldehyde reaction with aniline,

104

(very important) Page No: 222 (very important) Page No: 226-227 (Very important) Page No: 229

Cannizaro reaction, Claisen, Benzoin condensation. (Mar 06,Oct 06, June 08) Perkins reaction, Knoevenagal reaction and Benzaldehyde electrophilic substitution reaction. (Mar-2006,Oct-2008)
Acetone on reaction with oxidizing agents, LAH, Clementon, Halo form reaction, Ammonia, chloroform, preparation of Mesityl oxide, phorone and with conc.H2SO4.

Page No: 259 to 261

Preparation, chemical properties till electrophilic substitution of Benzoic acid.

(Mar 08)

Page No: 262 very important Page No: 263 to 264 very important Page No: 269 to 270

Kolbes mechanism (Oct 06, Mar 07) Chemical properties of salicylic acid.
(Oct 06, Mar 07)

7 8

9 10

Preparation of acetophenone, Clementon, Wolff Kishner Preparation of benzophenone and its Page No: 230-231 properties

Preparation and chemical properties of acetamide.

Refer Carboxylic acid to solve 70.A (or) 70.C problem 1

Page No: 243 to 245

Refer Organic Nitrogen Compounds to solve 70.A (or) 70.C problem 1

Page No: 284 to 286 Page No: 289 to 291 Page No: 293 to 295 Page No: 297 to 298 Page No: 298 to 302 Page No: 304 Page No: 306 to 308 Chemical properties of nitro benzene till electrophilic substitution reaction. (important)

Preparation of acetic acid, Formic acid. Chemical properties of acetic acid and Formic acid, reducing properties of Formic acid. Preparation and chemical properties of lactic acid. (Oct 08) Preparation and chemical properties of oxalic and Succinic acid.

2 3 4 5 6 7

Preparation of amines. (repeated) Chemical properties of methylamine

(repeated)

Page No: 247 to 250

Chemical properties of benzyl amine. Preparation, chemical properties of aniline.

(repeated)

Page No: 252 to 253

Chemical properties of methyl cyanide

(repeated)

Page No: 255 to 256

Chemical properties of Benzene diazonium chloride. (chance)

105

test and also forms a chloride C with SOCl2. The chloride on 1. An organic compound (A) of molecular formula C7H6O is not reduced by Fehlings solution but will undergo Cannizzaro reaction. Compound (A) also reacts with Aniline to give compound (B). Compound (A) also react with Cl 2 in the presence of catalyst to give compound (C). Identify (A),(B),(C) and explain the reaction. (M ar 06) treatment with alcoholic KOH gives D. identify A,B,C and D and explain the reactions. (M ar 07). ANSWER: (A) Acetone (B) Isopropyl alcohol (C) Isopropyl chloride (D)Propylene 5. An organic compound (A) C3H8O answer Lucas test with in 5-10 minutes and on oxidation forms B (C 3H6O). This on further oxidation forms C (C2H4O2) which gives effervescence NaHCO 3 . B also undergoes iodoform reaction. Identify A,B and C. Explain the coversion of A to B and C. (June 07). ANSWER: (A) Iso-propyl alcohol (B) Acetone (C) Acetic acid 6. An organic compound (A) of molecular formula C 6H6O gives violet colour with neutral FeCl 3. (A) gives maximum of two isomers (B) and (C) when an alkaline solution of (A) is refluxed with CCl 4. (A) also react with C6H5N2Cl to give the compound (D) which is red orange dye. Identify (A),(B),(C) and (D). Explain with suitable chemical reactions.(Oct 07) ANSWER: (A) Phenol (B) O-Salicyclic acid (C) p-Salicyclic acid Hydroxy azo benzene 7. Compound A with molecular formula C3H6 is obtained from Petroleum. When A is treated with chlorine at 773 K compound B of molecular formula C3H5Cl is obtained. When B is treated with (D)p-

ANSWER: (A) Benzaldehyde (B) Benzanilide (C)m-Chlorobenzaldehyde

2. An organic compound (A) C2H6O liberates hydrogen on treatment with metallic sodium. (A) on mild oxidation gives (B) C 2H4O which answer iodoform test. (B) when treated with conc.H 2SO4 undergo polymerization to give (C), a cyclic compound. Indentify (A),(B),(C) and explain the reactions.(June 06) ANSWER: (A) Ethyl alcohol (B) Acetaldehyde (C)Paraldehyde 3. An organic compound A(C7H6O) reduces Tollens reagent. On treating with an alkali compound A form B and C. B on treating with sodalime forms benzene and C(C 7H8O) is an antiseptic. Identify compounds A,B and C. Explain the reactions.(Oct 06). ANSWER: (A) Benzaldehyde (B) Benzoic acid (C)Benzyl alcohol 4. An organic compound A of molecular formula C 3H6O on reduction with LiAlH4 gives B. Compound B gives blue colour in Victor meyers

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Na2CO3 solution at 773/12 atm. It gives the compound C with molecular formula C3H6O, Con treatment with HOCl followed by hydrolysis with NaOH give D having molecular formula C 3H8O. compound C on treatment with 50% caustic soda gives compound B and also D. Find A,B,C and D. Explain the reaction.(M ar 08) ANSWER: (A) Propyl (B) Allyl chloride (C)Allyl alcohol (D) Glycerol 8. Compound A of molecular formula C 7H8 is treated with chlorine and then with NaOH to get compound B of molecular formula C 7H8O. B on oxidation by acidified K2Cr2O7 gives compound C of molecular formula C7H6O. Compound C on treatment with 50% caustic soda gives the compound B and also D. Find A,B,C and D. Explain the reaction.(June 08) ANSWER: (A) toluene (B) Benzyl alcohol (D) Sodium Benzoate 9. An organic compound (A) C7H8O liberates hydrogen with metal sodium. (A) on treatment with acidic potassium dichromate give (B) (C7H6O). Compound (B) when treated with conc.N 2H4 & NaOH /KOH gives (A). (B) with acetic anhydride in the presence of Sodium acetate gives (C) of molecular formula (C9H8O2). Identify (A),(B) and (C). Explain the reaction revolved. (Oct 08) ANSWER: (A)Benzyl alcohol (B)Benz aldehyde (C)Cinnamic acid (C) Benzaldehyde

10. Two isomers (A) and (B) have the same molecular formula C 4H10O. (A) when heated with copper at 573K gives alkene (C) of molecular formula C4H8.(B) on heating with copper at 573K gives (D) of molecular formula C4H8O which does not reduces Tollens reagent but answer iodoform test. Identify (A),(B),(C) and (D) and explain the reactions.(M ar 09) ANSWER: (A)Tertiary butyl alcohol (B)Secondary butyl alcohol (C)Isobutylene (D) Ethyl methyl ketone. 11.An organic compound (A) C 3H8O answer Lucas test within 5-10 min On oxidation form (B) C3H6O. (B) on further oxidation forms (C) C2H4O2 which gives effervescence with NaHCO3.(B) also undergoes Iodoform reaction. Identify A,B,C. Explain the reaction involved. (June 09) ANSWER: (A) Iso-propyl alcohol (B) Acetone (C) Acetic acid 12. Compound (A) of molecular formula C 3H8O liberates hydrogen With sodium metal.(A) with P/I2 gives (B). Compound (B) on Treatment with silver nitrate gives (C) which gives blue color with Nitrous acid. Identify (A),(B),(C) and explain the reaction.(Oct 09) ANSWER: (A)2-propanol (B)2-iodopropane (C)2-nitro propane. 13. Compound (A) with molecular formula C 6H6O gives violet colour With neutral FeCl3. Reacts with CHCl3 and NaOH and gives two Isomers (B) and (C) with molecular formula C 7H6O2. Compound (A) reacts with ammoniaat 473 K in the presence of ZnCl2and gives compound (D) with molecular formula C 7H7N.

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Compound (D) with molecular formula C 7H7N. compound (D) Undergoes carbylamines test. Identify (A),(B),(C) and (D) and Explain the reactions.(M ar 10) ANSWER: (A)phenol (B)O-hydroxy benzaldehyde (C)phydroybemaldehyde (D) Aniline. 14. An organic compound C6H6O (A) reacts with Al2O3 at 620K and Gives (B) of molecular formula C 2H4. (B) reacts with cold alkaline KMnO4(Baeyers reagent) to give (C) of molecular formula C2H6O2. Identify (A),(B) and (C) and explain the reaction.(June 10) ANSWER: (A) Ethyl alcohol (B) ethylene (C)Glycol 15. An organic compound (A) (C 6H6O) gives maximum of two isomers (B) and (C) when an alkaline solution of (A) is refluxed with Chloroform. (B) on oxidation gives acid (D). The acid (D) is also Obtained by treating sodium salt of (A) with CO 2 under pressure Followed by hydrolysis. Identify the compound (A),(B),(C) and (D) And explain proper chemical reactions.(Oct 10) ANSWER: (A)phenol (B)O-hydroxybenzaldehyde (C)p-hydroxybenzaldehyde (D) salicylic acid.

ANSWER: (A)isopropyl alcohol (B)Acetone (C)trichloroacetone 2. An organic compound (A) of molecular formula C 2H6O on Treatment with PCl5 give compound (B). compound (B) reacts With KCN to gives a compound (C) of molecular formula C 3H5N Which undergoes acid hydrolysis to give compound (D) which on Treatment with sodalime gives a hydrocarbon. Identify (A),(B),(C) And (D) and explain the reaction.(June 06). ANSWER: (A)ethyl alcohol (B) ethyl chloride (C) ethyl cyanide (D) propanoic acid (hydrocarbon is ethane obtained from
(D) propanoic acid)

1. An organic (A) of molecular formula C 3H8O gives turbidity within 5-10 min on reaction with anhydrous ZnCl2/HCl. Compound (A) On treatment with sodium hypochlorite gives a carbonyl Compound (B) which on further chlorination gives compound (C) Of molecular formula C3H3OCl3. Identify (A),(B),(C). explain the Reaction. (M ar 06).

3. An organic compound (A) of molecular formula C6H6O gives violet colouration with neutral FeCl 3. Compound A on treatment with metallic Na gives compound B. Compound B on treatment with CO2 at 400K under pressure gives C. This product on acidifcication gives compound D(C7H6O3) which is used in medicine. Identify A,B,C and D and explain the reactions. (Oct 2006) ANSWER: A:Phenol, B:Sodium Phenoxide C:Sodium Salicylate D:Salicyclic acid 4. An Organic compound A(C6H60) gives maximum of two isomers B and C when an alkaline soultion of A is refluxed with chloroform at 330K. B on Oxidation gives an acid D. The acid D is also obtained by treating sodium salt of A with CO 2 under pressure. Identify A,B,C and D and explain the reactions.(M ar 2007) ANSWER: (A) Phenol, (B) o-Hydroxybenzaldehyde (C) pHydroxybenzaldehyde (D) Salicylic acid. 5. An organic compound A(C7H60) forms a bisulphate. A when treated with alcoholic KCN forms B(C 14H12O2) and A on refluxing with sodium acetate and acetic anhydride forms an acid C(C 9H8O2).

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6.

7.

8.

9.

Identify A,B and C. Explain the conversion of A to B to C.(June 2007) ANSWER: A: Benzaldehyde B:Benzoin C:Cinnamic Acid An organic compound aldehyde (A) of molecular formula C 7H6O which has the smell of bitter almonds on treatment woth (CH3CO)2O and CH3COONa to give compound (B) which is an aromatic unsaturated acid. (A) also reacts with (A) in the presence of alcoholic KCN to give dimmer (C). Identify (A), (B) and (C). Explain the conversion of A to B to C. (Oct 2007. ANSWER: A:Benzaldehyde B:Cinnamic Acid C:Benzoin Compound A with molecular formula C7H6O reduces Tollens reagent and also give Cannizzaro reaction. A on oxidation gives the compound B with molecular formula C 7H6O. Calcium salt of B on dry distillation gives the compound C with molecular formula C13H10O. Find A,B and C. Explain the reaction. (M ar 2008) ANSWER: A:Benzaldehyde B:Benzoic Acid C:Benzophenone. Compound A having the molecular formula C 2H4O reduces Tollens reagent. A on treatment with HCN followed by hydrolysis gives the compound B with molecular formula C 3H6O3. Compound B on oxidation by Fentons reagent gives the compound C with molecular formula C3H4O3. Find A,B and C. Explain the reactions (June 2008 and Oct 2008) ANSWER: A:Acetaldehyde B:Lactic Acid C:Pyruvic Acid. An organic compound (A) with molecular formula C7H6O has the smell of bitter almonds. (A) reacts with Cl2 in the absence of a catalyst to give (B) and in the presence of catalyst compound (a) reacts with Chlorine to give (C). Identify (A), (B) and (C). Explain the reactions. (M ar 2009)

ANSWER: A:Benzaldehyde B:Bencoyl Chloride C:m-Chloro Benzaldehyde. 10. An Aromatic compound (A) with molecular formula C 2H6O liberates hydrogen with metallic sodium. Compound (A) on heating with excess of conc.H2SO4 at 440K gives an alkene (B). Compound (B) when oxidized by Baeyers reagent gives compound (C). Identify A,B,C and explain the above reactions.(June 2009) ANSWER: A:Ethyl Alcohol B:Ethylene C:Ethyl Glycol. 11.An organic compound (A) C 2H3OCl on treatment with Pd and BaSO4 gives (B) C2H4O which answers iodoform test. (B) when treated with conc. H2SO4 undergoes polymerization to give (C) a cyclic compound. Identify (A), (B) and (C) and explain the reaction.(Oct 2009) ANSWER: A:AcetylChloride B:Acetaldehyde C:Paraldehyde 12.Compound (A) with molecular formula C2H4O reduces Tollens reagent (A) on treatment with HCN gives compound (B). Compound (B) on hydrolysis with an acid gives compound (C) with molecular formula C3H6O3. Compound (C) is optically active. Compound (C) on treatment with Fentons reagent gives compound (D) with molecular formula C3H4O3. Compounds (C) and (D) give effervescence with NaHCO3 solution. Identify the compounds (A), (B), (C) and (D) and explain the reaction.(M ar 2010)

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ANSWER: A:Acetaldehyde B:Acetalcyanohydrin C:Lactic Acid (Optically active) 13.Compound (A) of molecular formula C 7H8 when treated with air in presence of V205 at 773K gives a compound (B) of molecular formula C7H6O , which has the smell of bitter almonds. Alkaline KMnO4 oxidizes compound (B) to (C) of molecular formula C7H6O2.Compound (B) on treatment with N2H4 and KOH gives back compound (A). Identify (A), (B) and (C) and explain the reaction.(June 2010). ANSWER: A:Toluene B:Benzaldehyde C:Benzoic Acid 14.An Organic Compound (A) with molecular formula C 3H6O undergoes iodoform reaction. Two molecules of compound (A) react with dry HCl to give compound (B) (C6H10O). Compound (B) reacts with one more molecule of compound (A) to give compound (C) (C 9H14O). Identify (A), (B) and (C). Explain the reaction. (Oct 2010) ANSWER: A:Acetone B:Mesityloxide C:Phorone.

2. 3. 4. 5. 6.

Chromium period no-4 group no-6 a silvery white metal Page No:91 properties of Chromium with air, water, acids .(June 07) Zinc period no-4 group no-12 a bluish white metal Page No: 94 properties of zinc with air, dil.HNO3, NaOH . (Oct 06, 08, 09, June 08) Silver period no-5 group no-11 a white lustrous metal Page No: 96 properties of silver with acids. (Mar-2008) Gold period no-6 group no-11 a lustrous yellow metal Potassium dichromate-action industry Page No: 99-100 of heat, action with NaOH, oxidizing properties, red orange in colour and used in leather

7.

Blue vitriol (very important) action of heat, action with NaOH, H2S with ammonia, KI, KCN pg. no 101-102. (Mar 07, June 09)
(refer book back problem)

8.

Silver nitrate action of heat (repeated), action with organic compounds used in marking inks and hair dyes Page No: 102103
(Mar-2008, 2009, June-2006)

Refer D-block (or) P-block to solve 70 (b) Problem

From D-block Refer page No. from (Vol-1) reprint edition 2009 1. Copper period no-4 group no-11 a reddish brown metal Page No: 88 properties of Copper with air, action of heat, action with dil. Or Conc.HNO3.
(Mar-2006,2007;Oct-2007)

9.

Zinc carbonate- preparation, action of heat (repeated) used in making ointment for curing skin diseases Page No: 103. (Oct 06)

70 (b) Problem from P-block (less chance) 1. 2. Lead action with water, acid, chloro plumbic acid, tetra-ethyl lead Page No: 55 Compounds of phosphorus chemical properties of PCl3 or PCl5 Page No: 57-58

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3.

Fluorine action with water and hydrogen. Page No: 73

1. An element (A) belongs to group number 11 and period number 4. (A) is a reddish metal. (A) reacts with HCl in the presence of air and gives compound (B). (A) also reacts with conc.HNO 3 to give compound (C) with the liberation of NO 2. Identify (A), (B) and (C). Explain the reactions. (M ar 2006) ANSWER: A:Copper B:Copper Chloride C:Copper Nitrate. 2. Silver reacts with dil.HNO 3 to give compound (A) which on heating at 723K gives (B). (B) on further heating gives (C). Further compound (A) reacts with KBr and gives (D) which is highly useful in photography. Identify (A), (B), (C) and (D) and write the reactions (June 2006) ANSWER: A:Silver Nitrate B:Silver Nitrile C:Silver and NO2 D:Silver Bromide. 3. The Sulphide ore of an element of group 12 when roasted gave compound (A) which on reduction with carbon gave the element (B). The carbonate (C) of this element is used for skin diseases. Identify (A), (B) and (C) and write the required reaction. (Oct 2006) ANSWER: A:Zinc Oxide B:Zinc C:Zinc Carbonate. 4. An element A occupies group number 11 and period number 5. This metal is extracted from its mixed sulphide ore B. A reacts with dil.H2SO4 in presence of air and forms C which is colourless. With water C gives a blue compound D. Identify A,B and C. and Explain the reactions.(M ar 2007)

ANSWER: A:Copper B:Copper Pyrites C:Copper Suphate D:Copper Sulphate Pentahydrate. 5. An element (A) belonging to group 6 and period 4 is silvery white in colour. Red hot, A decomposes steam liberating hydrogen and forming B. A also reacts with conc.Suphuric acids forming C with evolution of SO2. Identify A, B and C. Explain the two reactions. (June 2007) ANSWER: A:Chromium B:Chromic Oxide C:Chromic Sulphate. 6. An element (A) belonging to group No.11 and period No.4 is extracted from pyrite ore. (A) reacts with oxygen at two different temperatures forming compounds (B) and (C). (A) also reacts with conc.HNO3 to give (D) with the evolution of NO2. Find out (A), (B), (C) and (D). Explain the reactions. (Oct 2007) ANSWER: A:Copper B:Cupric Oxide C:Cuprous Oxide D:Cupric Nitrate. 7. The metal B is extracted from the ore A. On treatment with dil.Nitric acid, metal B gives a compound C, which is also known as Lunar Caustics. The compound C on treatment with KI gives a yellow precipitate D. Find A, B, C and D. Explain the reactions of formation of C and D.(M ar 2008) ANSWER: A:Silver Glance B:Argentite B:Slver C:Silver Nitra te (or) Lunar Caustic. D:Silver Iodide. 8. A bluish white metal A present in 4 th period and 12th group on heating in air gives a white cloud B. Metal A on treatment with conc. H2SO4 gives the compound C and SO2 gas. Find A, B and C. Explain the reactions. (June 2008) ANSWER: A:Zinz B:Zinc Oxide C:Zinc Sulphate. 9. An element belonging to Group 12 and Period 4 is bluish white in colour. (A) reacts with hot conc. H 2SO4 forming (B) with

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liberation of SO2. (A) also reacts with dil HNO 3 forming (C) with liberation of N2O. Identify (A), (B) and (C). Explain the reaction involved. (Oct 2008) ANSWER: A:Zinc B:Zinc Sulphate C:Zinc Nitra te. 10. Silver Reacts with dil. HNO 3 to give compound (A), which on heating at 723 K gives compound (B). (B) on heating gives compound (C). Compound (A) reacts with KBr and gives (D) which is highly useful in photography. Identify (A), (B), (C) and (D). Explain the reactions. (M ar 2009) ANSWER: A:Silver Nitrate B:Silver Nitrile C:Silver and NO 2 D:Silver Bromide. 11. Compound A is a sulphate compound of group II element. This compound is also called as a blue Vitriol. The compound undergoes Decomposition at various temperatures. (June 2009) A ------ B ------ C ------ D
100C 230C 720C

conc.HNO3 to give (D) with the evolution of NO2. Find out (A), (B), (C) and (D). Explain the reactions. (M ar 2010) ANSWER: A:Copper B:Cupric Oxide C:Cuprous Oxide D:Cupric Nitrate. 14. An element A occupies group number 11 and period number 5. This metal is extracted from its mixed sulphide ore B. A reacts with dil.H2SO4 in presence of air and forms C which is colourless. With water C gives a blue compound D. Identify A,B and C. and Explain the reactions.(June 2010) ANSWER: A:Copper B:Copper Pyrites C:Copper Suphate D:Copper Sulphate Pentahydrate. 15.An element (A) Belongs to group 11 and period number 5 and is a lustrous white metal. (A) reacts with dil.HNO 3 to give (B), (B) with KI gives (C) which is a bright yellow coloured precipitate. Identify (A0, (B) and (C). Explain the reactions. (Oct 2010) ANSWER: A:Silver B:Silver Nitrate (Lunar Caustics) C:Silver Iodide.

Identify the compounds A, B, C and D and give equations. ANSWER: A: Copper Sulphate Pentahydrate B:Copper Sulphate Monohydrate C:Copper Sulphate D:Cupric Oxide. 12.A bluish white metal when treated with dilute nitric acid gives (A) along with zinc nitrate and water. With very dilute nitric acid it gives (B) along with zinc nitrate and water. The metal when heated with air gives (C). What are (A), (B) and (C)? Explain the reactions. (Oct 2009) ANSWER: A: Nitrous Acid B:Ammonium Nitrate C:Zinc Oxide. 13. An element (A) belonging to group No.11 and period No.4 is extracted from pyrite ore. (A) reacts with oxygen at two different temperatures forming compounds (B) and (C). (A) also reacts with

1. What is the pH of a solution containing 0.5 M propionic acid and 0.5 M sodium propionate? The K a of propionic acid is 1.34x10-5. (M ar 2006) ANSWER: Refer Textbook Vol.II Page No.: 73 (Example 2) 2. Find the pH of a buffer solution containing 0.20 moles per liter sodium acetate and 0.15 mole per litre, K a for acetic acid is 1.8 x 10-5. (June 2006) ANSWER: Refer Textbook Vol.II Page No. 72 and 73 (Example 1)

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3. Find the pH of a buffer solution containing 0.20 mole per litre sodium acetate and 0.15 mole per litre acetic acid. K a for acetic acid is 1.8 x 10-5. (Oct 2006) ANSWER: Refer Textbook Vol.II Page No.: 73 (Example 2) 4. Calculate the pH of a buffer solution containing 0.04M NH 4Cl and 0.02 M NH4OH. For NH4OH Kb is 1.8 x 10-5. (M ar 2007) ANSWER: pK b = 4.7445, pOH-5.0456, pH=8.9544. 5. Equivalent conductivity of acetic acid at infinite dilution is 390.7. For 0.1M acetic acid, the equivalent conductance is 5.2 mho cm2 gm equiv-1. Calculate the degree of dissociation and hydrogen ion (H+) concentration. (June 2007) ANSWER: Refer Textbook Page No.: 61 in Vol.I (Example 3) 6. Calculate the pH of a buffer solution containing 0.2 mole per litre CH3COONa and 0.15 mole per liter CH3COOH. Ka For acetic acid is 1.8 x 10-5. (Oct 2007) ANSWER: Refer Textbook Vol.II Page No. 72 and 73 (Example 1) 7. An electric current is passed through three cells in series containing respectively the solutions of copper sulphate, silver nitrate and potassium iodide. What weights of silver and iodine will be liberated while 1.25gm of copper is being deposited? (Mar 2008) ANSWER: Refer Textbook Vol.II Page No.:56 (Example 4). 8. The equivalent conductance of HCl, CH3COONa and NaCl at infinite dilution are 426.16, 91.0 and 126.45 ohm-1 cm2 (gram equivalent)-1 respectively. Calculate the equivalent conductance of acetic acid. (June 2008) ANSWER: Refer Textbook Problem in Vol.II Page 81, Problem No. 10.

9. Find the pH of a buffer solution containing 0.30 mole per litre of CH3COONa and 0.15 mole per litre of CH3COOH. K for acetic acid is 1.8 x 10-5. (Oct 2008) ANSWER: pKa = 4.7447, pH=5.0457. 10. 0.1978g of copper is deposited by a current of 0.2 ampere in 50 minutes. What is the electrochemical equivalent of copper? (Mar 2009). ANSWER: Refer Textbook Vol.II Page no: 55 (Example 2). 11. Calculate the pH of 0.1M CH 3COOH solution. Dissociation constant of acetic acid is 1.8 x 10-5. (June 2009) ANSWER: Refer Textbook Vol.II Page No.: 68 (Example 5) 12. 0.04N solution of a weak acid has a specific conductance of 4x10-4 mho cm-1. The degree of dissociation of the acid at this dilution is 0.05. Calculate the equivalent conductance of the weak acid at infinite dilution. (Oct 2009) ANSWER: c = 10 mho cm2 equiv-1, = 200 mho cm2 g equiv-1. 13. Ionic conductances at infinite dilution of Al3+ and SO42- are 189 ohm-1 cm2 gm equiv-1. Calculate equivalent and molar conductance of the electrolyte at infinite dilution. (M ar 2010) ANSWER: Refer Textbook Vol.II Page No.: 62 (Example 4) 14. What is the pH of a solution containing 0.5 M propionic acid and 0.5 M sodium propionate? The K a of propionic acid is 1.34x10-5. (June 2010) ANSWER: Refer Textbook Vol.II Page No.: 73 (Example 2) ___________________________________________________________________

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Example to draw compulsory problems 70(a) or (c)

S. No. Compound Given formula Identified(or) structural formula Name

Note: write correct balanced equations and explain briefly, (which is A, B, etc..,) later draw above mentioned table

Total Question paper 43 marks problems out of 233 marks.

Note for One mark Question No: 1 to 30 Out of 30 questions, problem types questions are 4. Distribution of questions: Inorganic Organic Physical (Chances for problem). Organic: Organic nitrogen compounds (chances for problem) Physical: Thermodynamics, Chemical equilibrium, E.C 1, Chemical kinetics (chances for problem). Note for Three mark Question No: 31 to 51 Out of 21 questions, problem types questions are 3. 15 have to be answered 7 inorganic & 7physical & 7 organic Problems: - 10 - 10 - 10

1 2 3

A B C

Note: Write correct naming reactions and explain briefly, (which is A, B, etc..,) later draw the above mentioned table.

Inorganic: Atomic structure, nuclear chemistry periodic classification.

Example to draw compulsory problem 70(b)

S. No. 1 2 3 Element(or) compound A B C Symbol (or)molecular formula Name

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Inorganic Chance from Atomic structure, Periodic Classification and Nuclear Chemistry. Organic Physical Chance from Organic nitrogen compounds. Chance from Solid state, Thermodynamics, Chemical equilibrium, Chemical kinetics and E.C 1 Note for five mark Question No: 52 to 63 (2 problems) Section A Inorganic 4Q (52 - 55) chance for one problem type or twisted type question from Atomic structure or coordination compounds Chance for Extraction (or) chemical properties of elements (or) compounds from D block. Section B Physical 4Q (56 - 59) chance for problem from E.C 2, Chemical equilibrium (or) Chemical Kinetics. Section C Organic 4Q (60 - 63) one mechanism from Carbonyl or Carboxylic acid. Note: For ten marks to write any three from 64 to 69 both sub division (a&b) finds some time difficult to write. Dont skip any questions given from Q. no 64 to 69 from the material its must. ______________________________________________________________________
5. 4. 3. 2. 1.

Jai Guru Dev

SGK MODEL QUESTION PAPER (For Practice)

[TIME ALLOWED: 3 HOURS] PART-I NOTE: (i) Answer all the questions (ii) Choose and write the correct answer If the energy of an electron in the second Bohr orbit of H-atom is E, what is the energy of the electron in the Bohrs first orbit? a) 2E b)-4E c)-2E d) 4E [MAXIMUM MARKS= 150]

The particle character of an electron is explained by a) Interference c) G.P.Thomsons experiment b) Diffraction d) J.J.Thomsons experiment

Across the period, electron affinity a) Decreases b) increases

c) Decreases and then increases d) increases and then decreases Lead is mainly extracted from a) PbO b) PbCO3 c) PbSO4 d) PbS

Silver salt is used in photography is a) AgCl b) AgNO3 c) AgF d) AgBr

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6.

The alloy used in surgical instruments is a) German Silver b) Invar c) Stellite d) Stainless steel

15.

In Habers process ammonia formed is removed by a) High amount of H2 and N2 b)Fe/Mo c)H2O d)steam

7.

Lanthanides are separated by a) Fractional distillation b) steam distillation d) sublimation

16.

Extra plotting the upper arm of the plot of log vs. I/T gives a) A b) In A c) log A d) log A

c) Fractional crystallization 8.

17. d) mish metals

Oil of mirbane is A) Nitrobenzene B) Benzaldehyde C) Methyl Salycilate D) Aspirin

___________ is used in tracer bullets. a) Ceria b) Thoria c) Pyrophoric alloy 18.

Fog is the dispersion of a) Solid in gas b) liquid in gas c) gas in liquid d) gas in solid

9.

In photosynthesis, chlorophyll act as a) An oxidising agent c) An electron carrier b) a light sensitizer d) a colouring matter 20. d) Positron decay 19.

Colloidal antimony is used in curing a) Malaria b) Jaundice c) Kalazar d) Headache

10.

The reaction 5B8------------>4Be8 takes place due to a) alpha-decay b) beta-decay c) gamma-emission

11.

An example for Frenkel defeat is a) NaCl b) AgCl c) CsCl d) FeS

The specific conductance of a 0.01 M solution of KCl is 0.0014 ohm-1 cm-1 at 25C. Its Equivalent Conductance is a) 14 ohm-1 cm2 eq-1 b.)140 ohm-1 cm2 eq-1 c.) 1.4 ohm-1 cm2 eq-1 d.)0.14 ohm

12.

In an adiabatic process which of the following is true? a) q=w b) q=0 c) E=q d) pv=0

21.

The alcohol obtained by the hydrolysis of oils and fats is a) Pentanol b) Propanol c) glycerol d) glycol

13.

Which one is state function? a) H b) S c) q d) both a and b

22.

Intermolecular hydrogen bonds are not present in a) CH3 COOH b) C2 H5 O C2 H5 c) CH3CH2OH d) C 2 H5 NH2

14.

State of chemical equilibrium is a) Dynamic b) Decreases c) Increases d) Becomes Zero

23.

Phenetole is

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a) Aromatic mixed ether d) aromatic simple ether 24.

b) aliphatic mixed ether c) aliphatic simple ether

Formaldehyde polymerises to give a) Paraldehyde b) paraformaldehyde c) formalin d) formic acid

25.

Which of the following are compounds will react with NaHCO3 solution to give sodium salt and CO2? a) Acetic acid b) n-hexanol c) phenol d) both (a) and (c)

26.

Bromo ethane reacts with silver nitrite to give a) C2 H5 NO2 b) C2 H5 -O-NO c) C2 H5Ag + NaBr d) C 2 H5 NC

27.

Which one of the following is a secondary amine? a) Aniline b) diphenyl amine c) sec.butyl amine d) tert.butyl amine

28.

Mustard oil reaction converts primary amine to a) Isocyanate b) isothiocynate c) Schiffs base d) alcohol

29.

Proteins are not sensitive to a) Acids b) bases c) elevated temperature d) water

31. 32. 33. 34. 35. 36. 37. 38. 39. 40. 41. 42. 43. 44. 45. 46. 47. 48. 49. 50.

30.

Which contains a long chain ester a) Wax b) cooking oil c) turpentine oil d) cellulose

State Heisenbergs uncertainty principle. Why be and Mg has almost zero B A? Why H2 O is a liquid while H2 S is a gas? What is the action of heat on Phosphine? Why Zn2+ salts are white while Ni2+ salts are coloured? What is aquaregia? Give the reaction of Au with aqua regia. What is spallation reaction? Write the significance of Braggs equation. Give the Kelvin-Planclc statement of second law of thermodynamics. Dissociation of PCl5 decreases in presence of increase in Cl2 why? What are parallel reactions? Give an example. The rate constant of a reaction is 1.54 X 10 -3 sec. Calculate t . What is Helmholtz double layer? What is Kohlranschs law? Distinguish between racemic and mesoform. Why Glycol is hygroscopic in nature? How is glycerol synthesized from propylene? How will you prepare Malachite green from Benzaldehyde? What are the uses of benzoic acid? Compound A is yellow coloured liquid and it is called oil of mirbane A. On reduction with Sn/HCl gives B. B answers to carbonyl amine test? What are A and B? 51. What are antispasmodics? PART III Note: i) Answer any seven questions choosing at least two questions from each Section. Section A 52. Discuss shapes of p and d orbitals.

PART II
Note: i) Answer any fifteen questions. ii) Each answer should be in one or two sentences. 15x3=45

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53. How is silver extracted from its chief ore? 54. Mention the oxidation state and any three uses of Lanthanides. 55. [Ni (CN) 6]2- is square planar whereas [Ni (NH3)4]2+ is tetrahedral. Explain. Section B 56. What are characteristics of entropy? 57. Derive the expression for kc and kp for the decomposition of PCl5. 58. Explain the experimental determination of rate constant for decomposition of H2O2 in aqueous solution. 59. What is the potential of a half-cell consisting ZnC electrode in 0.01M ZnSO4, solution at 25`C and B`C= 0.7862 K. Section C 60. Discuss the isomerism exhibited by ethers. 61. Distinguish between Acetaldehyde and acetone. 62. Discuss the mechanism of Bromination of salicyclic acid. 63. How are Buna S and Nylon 66 prepared?

b) Discuss the structure of inter halogen compounds of AX 3 and AX5 type. 65. a) State the postulates of Werners theory. b) How are radioactive isotopes useful in medicine? 66. a) Write the properties of ionic crystals. b) Write briefly about the adsorption theory of catalysis. 67. a) Derive Henderson equation. b) Establish a relationship between free energy and emf. 68. a) Write a short account on cis-trans isomerism. b) Account for the reducing properties of formic acid. 69. a) How are the following conversions carried out? i) Nitro methane to methyl amine ii) Methyl amine to methyl isocyanide iii) Benzene Diazonium chloride to biphenyl. b) Outline the classification of carbohydrates giving example for each. 70. a) An organic compound A of molecular formula C3 H6O on reduction with LiAlH4 gives B. Compound B gives blue colour in Victor Meyers test and also forms a chloride C with SOCl 2 . The chloride on treatment with alcoholic KOH gives D. Identify A, B, C and D and explain the reactions. b) An element A is obtained from argentite ore. A reacts with conc.H2 SO4 to give compound B. A also reacts with Cl 2 to give compound C. Find

PART-IV Note: i) Answer four questions in all. ii) Question No.70 is compulsory and answer any three from the remaining.

64. a) Explain various factors that affect electron affinity.

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out A,B and C. Explain the reactions involved. Write any two uses of element A. (Or) c) An organic compound A (C7 H6 O) has a bitter alcoholic almond shell. With ammonia A gives B (C21 H18 N2 ) with aqueous alcoholic KCN A gives C (C14 H12O2 ) with aromatic tertiary amine A gives (C23 H26 N2 ). What are A, B, C and D and explain the reactions. d) The resistance of a 0.01 N solution of an electrolyte was formed to 210 ohm at 25`C using a conductance cell with a cell constant 0.88 cm-1. Calculate the specific conductance and equivalent conductance of the solution.

Prepared By, S.Karthikeyan, M.Sc, B.Ed, Maharishi Vidya Mandir, Cell: 9842029967 HOSUR 635 109 (Krishnagiri Dist.)

All the Best!