Unit 3 Optoelectronic Properties of Semiconductors
Unit 3 Optoelectronic Properties of Semiconductors
Unit 3 Optoelectronic Properties of Semiconductors
Computational Methods
(21PYB102J)
Module III
2
For the optical properties of semiconductors, the photons should interact with
charge carriers.
In the process of interaction three process occurs
Absorption
Recombination
Emission
i.e the photons are absorbed and emitted , these processes are important
in photonic devices using semiconductors
There are several type of transition possibilities to occur
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In semiconductors, electrons can make transitions between two energy states and create or
destroy photons in the process.
1. Band to band transition (Inter band transition)
An absorbed photon can result in an electron in the valence band making an upward
transition to conduction band. This results electron-hole pair generation, followed by this
electron-hole recombination takes place by the emission of Photon
Eg: Band to Band transition in GaAs can results absorption and emission of photons
with wavelength of 0.087 µm or (Eg = 1.42 eV)
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2. Impurity level to band transition:
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Optical absorption process :
hν ≥ E2-E1
This process is called spontaneous emission
An incident photon causes an upper level atom to decay, emitting a “stimulated”
photon whose properties are identical to those of the incident photon.
The term “stimulated” underlines the fact that this kind of radiation only occurs if an
incident photon is present
1
1
Stimulated emission:
Nst = B21 Q N2
Nst number of atoms undergoing stimulated process
N2 number of atoms in E2
Q energy density of incident radiation
B21 proportionality constant
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2
1
3
Overall picture of Absorption and emission processes
1
4
Recombination process:
1
6
When a semiconductor is under equilibrium without any incident photon (or) injection of
electron the carrier density can be calculated from an equilibrium Fermi level using Fermi
Dirac statistics
But when light is illuminated non-equilibrium carrier concentration is created and above
relation is not valid, hence Fermi Dirac distribution for electrons and holes in non-equilibrium
condition are
1
7
The excess carriers generated in semiconductor at non equilibrium condition
must eventually recombine
Generation rate (G) = recombination rate (R)
The generation and recombination processes involve transition of charge
carriers across the energy bandgap and is different for direct & indirect bandgap
semiconductor materials.
1
8
1
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DEPARTMENT OF PHYSICS AND NANOTECHNOLOGY
SRM INSTITUTE OF SCIENCE AND TECHNOLOGY
21PYB102J
SEMICONDUCTOR PHYSICS AND COMPUTATIONAL
METHODS
Session – 7
MODULE-III
20
Optical Joint density of states
Introduction:
We have density of states for electrons in the conduction band (CB) and density of
states for holes in the valence band (VB).
Whole concentration depends on the density of the states in the valence band but
in photon interactions, you have one state in the VB and one in the CB and
therefore, we define an optical joint density of states
Optical processes, such as emission and absorption involve the energy states in
the valence band and the energy states in the conduction band.
Therefore, it is important to know how many states are available for a photon of
energy (hν) to interact with.
Optical joint density of states simultaneously takes care of number of states
in both valence band and conduction band for a given energy (hν) of photon.
Optical joint density of states tells us the number of states available for
photons to interact simultaneously in the valence band and the conduction
band.
In all optical processes, it is the joint density of states which is important. 21
Optical Joint density of states
Derivation:
We know that density of states defines the number of allowed energy states per
unit volume.
To know or find the number of transitions or emissions (because that gives the no.
of photons emitted) we need to know the emissions per unit volume. This can also
give an idea of the power emitted.
The number of emissions per unit volume can be found by multiplying density of
states and probability of occupations.
Concentration of electrons in conduction band is given by:
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Optical Joint density of states
Derivation:
Suppose a radiation of energy hν is incident on an electron sitting at certain level
in valence band (E1), it makes a transition to a vacant state in conduction band
(E2).
This means that absorption involves a certain energy level in valence and a
corresponding vacant level in conduction band.
Similarly, if there is an electron at certain energy level (E2′) in conduction band
and it makes a transition at a vacant level (E1′) in valance band, a photon with
energy hν′ is emitted.
We can thus say that absorption and emission involve a state in valance band and
conduction band.
For a fixed incident energy hν, if E2 is fixed then E1 will also be fixed.
For a given energy hν there are several pairs of E2 – E1 and so there are number
of pairs of states available for a photon of energy hν to interact and this is given
by density of states.
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Optical Joint density of states
Derivation:
Since the absorption or emission takes place from the top of valence band and
bottom of conduction band respectively, we can have a parabolic approximation
for any level in conduction and valance band respectively.
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Optical Joint density of states
Derivation:
Where, Z(v)dv is the number of states per unit volume available for photons of
energy between hv and h(v+dv) to interact (either absorb or emit).
Once we find out Z(v)dv, i.e. density of states available for interaction and
multiply it by probability of emission or absorption, we can obtain total number of
emission or absorption per unit volume.
From equation (6),
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Optical Joint density of states
Derivation:
From equations (1) & (3),
21PYB102J
SEMICONDUCTOR PHYSICS AND COMPUTATIONAL
METHODS
Session – 7
MODULE-III
27
Density of States for Photons
Introduction:
Quanta of the electromagnetic radiation are called photons
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Density of States for Photons
Derivation::
Density of states
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Density of States for Photons
Derivation:
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DEPARTMENT OF PHYSICS AND NANOTECHNOLOGY
SRM INSTITUTE OF SCIENCE AND TECHNOLOGY
21PYB102J
SEMICONDUCTOR PHYSICS AND COMPUTATIONAL
METHODS
Session – 8
MODULE-III
32
Fermi’s Golden Rule
Introduction:
It is also referred to as the “Golden Rule of time-dependent
perturbation theory”.
Fermi’s golden rule is a simple expression for the transition
probabilities between states of a quantum system, which are
subjected to a perturbation.
Fermi’s Golden Rule provides the rate at which atomic or electronic
transitions take place between two states.
The rates are calculated from probabilities determined by transition
matrix elements in quantum mechanical, first-order perturbation
theory.
It applies to a wide range of optical and electronic processes for
which the initial and final states can be described by wave functions.
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Fermi’s Golden Rule
The transition probability is of the general form:
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Downward transition (Emission) Rate
37
DEPARTMENT OF PHYSICS AND NANOTECHNOLOGY
SRM INSTITUTE OF SCIENCE AND TECHNOLOGY
21PYB102J
SEMICONDUCTOR PHYSICS AND COMPUTATIONAL
METHODS
Session – 8
MODULE-III
38
Optical Gain and Optical Loss
Optical Gain:
Optical Gain in semiconductor defines the stimulated emission
associated with light emission created by recombination of
electrons and holes.
Optical Loss:
Optical Loss in semiconductor defines the stimulated absorption
associated with light absorption created by generation of electrons
and holes. 39
Optical Gain in Semiconductors
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Optical Loss in Semiconductors
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Optical Gain and Loss in Semiconductors
From the above figure, given a value for the Fermi level splitting, optical
frequencies for which Eg< ħω< Efe-Efh experience optical gain.
The condition Eg< ħω< Efe-Efh is the condition for population inversion.
From the above figure, given a value for the Fermi level splitting, optical
frequencies for which Eg> ħω, Efe-Efh experience optical loss. 42
Optical Gain and Loss from Fermi’s Golden Rule:
In a semiconductor crystal, consider an electron initially occupies a
single state (b) and makes a transition to one of a large number of
final states (a) due to photon interaction.
The electron-photon interactions in the crystal is characterized by
Fermi’s Golden Rule and gives the transition rate for a single pair of
conduction and valence band states.
Each downward transition generates one photon and upward
transition absorbs one photon.
According to Fermi’s Golden Rule:
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Where ‘Φ’ is the photon flux (the number of photons per cross section
area in unit time)
‘z’ is the direction of the electromagnetic propagation
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DEPARTMENT OF PHYSICS AND NANOTECHNOLOGY
SRM INSTITUTE OF SCIENCE AND TECHNOLOGY
Photovoltaic Effect
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Photovoltaic effect: It is a process that generates voltage or
electric current in semiconductor device when it is exposed to
light.
Over 99% of the energy flux from the sun is in the spectral
region of 0.15 – 4μm, with approximately 50% in the visible
light region of 0.4 – 0.7μm.
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Photovoltaic in Semiconductor
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When photons strike a photovoltaic cell made by
semiconductor PN junction, they may be reflected, absorbed
or transmitted.
The carrier that are generated in the space charge region will
be immediately swept away due to the electric field (electron
towards N-region and holes towards P-region).
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Ln and Lp - Diffusion length of electron and hole in Quasi neutral region, W –
Width of depletion region or Space charge region, Ev – Energy of valence band
and Ei – Fermi energy 53
Due to the electric field, chances of recombination of these
electron pairs are quite less
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Minority electrons from P-side will come to N-side leaving
behind their positive charge called hole.
observed 57
The large negative current in illuminated PN junction is due to
voltage which is generated due to light biases the PN Junction in
a forward bias mode, the diffusion current flows opposite to the
direction of light generated current
Itotal = I0 (e qV / kT – 1) - IL
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DEPARTMENT OF PHYSICS AND NANOTECHNOLOGY
SRM INSTITUTE OF SCIENCE AND TECHNOLOGY
Solar Cell
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Solar Cell
The net current is zero and the voltage produced is the open-circuit
voltage Voc. The photocurrent is just balanced by the forward-biased
junction current, so we have
where Vt = nkT/q
Solar Cell
We may find the current and voltage which will deliver the maximum
power to the load by setting the derivative equal to zero, or dP/dV = 0.
Fill Factor FF
Fill Factor FF, is a measure of the realizable power from a
solar cell. Typically, the fill factor is between 0.7 and 0.8. The FF is
defined as the ratio of the maximum power from the solar cell to the
product of Voc and Isc so that
Solar Cell
Conversion Efficiency
A photon with energy greater than Eg will contribute to the solar cell
output power, but the fraction of photon energy that is greater than Eg
will eventually only be dissipated as heat.
We can see that the conversion efficiency increases only slightly with
optical concentration through Fig. 4. The primary advantage of using
concentration techniques is to reduce the overall system cost since an
optical lens is less expensive than an equivalent area of solar cells.
Solar Cell