Is 14946
Is 14946
Is 14946
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IS 14946:2001
(Reaffirmed - 2012)
(Reaffirmed 2017)
Indian Standard
ZINCETHYL SILICATEPRIMER,
TWO COMPONENTS — SPECIFICATION
..:
.-
0 BIS 2001
BUREAU OF INDIAN STANDARDS
MANAK BHAVAN, 9 BAHADUR SHAH ZAFAR MARG
NEW DELHI 110002
FOREWORD
This Indian Standard was adopted by the Bureau of Indian Standards, after the draft finalized by the Industrial
Paints Sectional Committee had been approved by the Chemical Division Council.
Zinc rich primers find a wide range of applications for corrosion protection of iron and steel. These can be used
alone but are usually employed as a primer coat as a part of the protective system for long term corrosion
- protection. Zinc pigmented primers are also used for fabrication primers ( shop primers ) for the protection of
abrasive blast cleaned steel plates and fabricated components of ships and other structures. Repair of damaged
galvanized and metallic zinc sprayed coatings is carried out by using metallic zinc rich primers.
The standard has been prepared with the aim to cater for the requirements of zinc rich paints for use as primers
and prefabrication paints having different degree of corrosion protection.
The satisfactory performance of zinc rich primers depends largely on their capacity to attain close electrical
contact between zinc particles and iron or steel surface to be protected. The close electrical contact permits in
achieving adequate galvanic protection of the steel substrate especially under marine conditions. To ensure such
electrical contact it becomes essential to remove all mill scale, rust and any other contamination from the steel
surface to be painted. The zinc rich primers, therefore, shall be applied only to very carefully prepared steel
preferably abrasive blast cleaned sutface conforming to Sa 2.5/Sa 3 quality to Swedish standard. It is important
to control the surface roughness. This is mainly achieved by the selection of correct size of grit or shot and
appropriate air pressure. The profile height obtained should lie between 50-75 microns.
While formulating this standard, considerable assistance have been obtained from SSPC - Paint 20, November
1982, Systems an-d Specification, Steel Structure Painting Manual, Part 2 of Steel Structure Painting Council,
Pittsburgh, PA ( USA ).
This standard also provides informative guidance for deciding a testing programme to help vendors
( see Annex G ).
The committee responsible for the formulation of this standard is given in Annex H.
..
For the purpose of deciding whether a particular requirement of this standard is complied with, the final value,
observed or calculated, expressing the result of a test or analysis, shall be rounded off in accordance with
IS 2: 1960 ‘Rules for rounding off numerical values ( revised )’. The number of significant places retained in
the rounded off value should be the same as that of specified value in this standard.
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IS 14946:2001
Indian Standard
ZINCETHYL SILICATEPRIMER,
TWO COMPONENTS — SPECIFICATION
1 SCOPE container at a temperature of 27 * 2°C [ see IS 101
( Part 6/see 2 ) ].
This standard prescribes requirements, sampling and
method of test for zinc eihyl silicate primer. This material 4.5 The material shall conform to the requirements
shall be used for the painting of steel paint equipments, given in Table 1.
by spraying, where corrosion” protection, chemical
5 TESTS
resistance under marine atmospheric condition, abrasion
and heat resistance are required. 5.1 Unless specified otherwise, tests shall be conducted
2 REFERENCES as prescribed in IS 101, preferably on the blasted panels.
Reference to the relevant sections of the standard are
The Indian Standards listed in Annex A contain given inCO16 of Table 1.
provisions which through reference in this text,
constitute provision of this standard. At the time of 5.2 The preparation of metal panels shall be according
publication, the editions indicated were valid. All to IS 101( Part l/See 3 ).
standards are subject to revision and parties to 5.3 Quality of Reagents
agreements based on this standard are encouraged
to investigate the possibility of applying the most Unless specified otherwise, pure chemicals and distilled
recent editions of the standards. water (see IS 1070) shall be employed.
4.1 Composition It shall ensure that the quality does not deteriorate
during storage and shall be as agreed to between
The material complying with this standard shall be puwhaser and supplier.
ethyl silicate pigmented with zinc metal see IS 14355.
The manufacturer shall specify the principal type of 6.2 Marking
binder,used in the pigmented curing agent. The total
6.2.1 Each container shall be marked with the following
metallic zinc content in non-volatile portion of the
information:
shop coat primer shall be 65 percent A4in and for the
main coat primer 75 percent Min when tested as per a) Indication of the source of manufacture,
Annex B.
b) Batch No. or Lot No. and month and year of
4.2 Weight per 10 litre of the mixed paint shall be manufacture,
13 kg, Min for shop coat and 20 kg, Min for main
coat and shall be determined in accordance with c) Date ofexpiry,
IS 101 ( Part l/See 7 ). Variation shall be within d) Mass of the material,
+ 3 percent.
e) Name of the material ( both the component
4.3 Solids percent by weigh{ of the mixed paint shall to be mentioned including type and pack),
be 50 Min for shop coat and 68 Min for main coat and
and shall be determined in accordance with
IS 101 ( Part 2/See 2 ). Variation shall be within f) The caution label ‘FLAMMABLE’ together
+ 2 units. with the corresponding symbol for Iabelling
dangerous goods as given in Fig. 5 of
4.4 Keeping Properties IS 1260(Part 1 ).
The liquid portion of the multi-cotiponent paint shall
6.2.2 BIS Cert@cation Marking
not show thickening, curdling, gelling or hard caking
after being stored unmixed for six months from the The product may also be marked with the Standard
date of delivery in a tightly covered unopened Mark.
1
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IS 14946:2001
( Clause 4.5)
A Wet Paint
iii) Flash Point Not below 13°C Not Below 15°C Part l/See 6
NOTE — Tests from S1 No. (ii) to (vii) are for mixed paint.
B Dry Coat
(To be conducted atter
72 h of curing)
2
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IS 14946:2001
Table 1 ( Concluded)
NOTES
1 Inorganic zinc rich.primers should not be applied at relative humidities below 50 percent, without specific instructions
from paint manufacturer.
2 Multiple component zinc rich paints should be applied within 4 h atter mixing and should be continuously agitated
during application.
622.1 The use of the Standard Mark is governed by from the Bureau of Indian Standards.
the provisions of the Bureau of lndiau Standiwdk
Act, 1986 and the Rules and Regulations made 7 SAMPLING
thereunder. The details of the conditions under which
the Iicence fbr use of the Standard Mark maybe granted Representative samples of the material shall be drawn
to the mamtfhcturers or the producers may be obtained according to 6 of IS 101 (Part l/See 1 ).
3
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IS 14946:2001
ANNEX A
( Clause 2.1 )
LIST OF REFFERED INDIAN STANDARDS
101 Methods of sampling and test for ( Part 3/Sec4 ): Tests on paint film formation,
paints, varnishes and related 1987 Section 4 Finish ( third revision)
products :
( Part 4/See 2 ): Optical tests on paint films,
(Part l/See 1): Test on liquid paints ( general and 1988 Section 2 Colour ( third revision )
1986 physical ), Section l.Sampling ( third
(Part 6/See 1): Durability tests, Section 1 Resistance
revision )
1988 to humidity under conditions of
( Part l/Sec3 ): Test on liquid paints (general and condensation ( third revision )
1986 physical ), Section 3 Preparation (Part 6/See 2): Durability tests, Section 2 Keeping
of panels ( third revision ) 1989 properties ( third revision)
(Part l/See 5): Test on liquid paints ( general and (Part 7/See 3): Environmental tests on paint films,
1989 physical ), Section 5 Consistency 1990 Section 3 Resistance to heat ( third
(third revision) revision )
(Part l/Sec6): Test on liquid paints (general and ( Part 8/See 6 ): Tests for pigments and other solids,
1987 physical ), Section 6 Flash Point 1993 Section 6 Volume solids
( third revision)
266:1993 ● Sulphuric acid ( third revision)
(Part l/See 7): Test on liquid paints (general 1070:1992 Reagent grade water ( thirdrevision)
1987. and physical ), Section 7 Mass
per 10 Iitres ( third revision ) 1260 (Partl ) : Pictorial marking for handling and
;., . 1973 Iabdling of goods : Part 1 Dangerous
(Part 2/See 2): Test on liquid paints (Chemical goods (first revision )
1986 examination ), Section 2 Volatile
matter ( third revision) 1303:1983 Glossary of terms relating to paints
( second revision)
(Part 3/See 1): Tests on paint film formation,
1499:1977 Method for charpy impact test for
1986 Section 1 Drying time ( third
metals (first revision )
revision )
1608:1995 Mechanical testing of metals —
(Part 3/See 2): Tests on paint film formation,
Tensile testing ( second revision)
1989 Section 2 Film thickness ( third
revision ) 14355:1996 Zinc dust pigment for paints
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IS 14946:2001
ANNEX B
( Clause 4.1 )
DETERMINATION OFTOTALZINC
Two methods are prescribed. In Method 1 total zinc Weighabout 2.5 g of the material accurately into a beaker,
content in the sample is determined volumetrically using moisten with alcohol and dissolve in 40 ml of dilute
potassium ferrocyanide solution. Method 2 is the hydrochloric acid by heating. Cool, filter, if necessary,
alternate method and uses EDTA method. and make up to 500 ml.
B-2 METHOD 1 B-2.3.1 Pipette 20 ml of the made up solution into a
250-ml beaker, dilute to 50 ml and pass hydrogen
B-2.1 Outline of the Method
sulphide for about 5 min. Keep for 10 min. Heat to
Total zinc content in the sample is determined 80°C. Filter and collect the filtrate in a 500-ml conical
volumetrically using potassium ferrocyanide solution. flask. Boil the filtrate till free from hydrogen sulphide.
Just neutralize with ammonium hydroxide, make acidic
B-2.2 Reagents
with dilute hydrochloric acid, warm to 60”C and titrate
B-2.2.1 Concentrated Sulphuric Acid— See IS 266. against the standard potassium ferrocyanide soloution
exactly as was done for the standardization of the
B-2.2.2 Ammonium Hydroxide — 20 percent ( m/v). ferrocyanide scdution.
B-2.2.3 Dilute Hydrochloric Acid— Approximately
B-2.4 Calculation
6 N.
B-2.2.4 Diphenylamine Indicator Total zinc (as Zn), = -
Dissolve 1 g of diphenylamine in 100 ml of concentrated percent by mass
sulphuric acid. It shall be freshly prepared.
where
B-2.2.5 Standard Potassium Ferrocyanide Solution v. volume in ml of standard potassium
B-2.2.5.1 Dissolve 21.12 g of potassium ferrocyanide ferrocyanide solution used in the titration,
and 0.3 g of potassium ferricyanide in one Iitre of water F= mass in g of the zinc equivalent to one ml of
and standardize as described in B-2.2.5.2.
standard potassium ferrocyanide solution,
B-2.2.5.2 Standardization ofpotassium ferrocyanide and
solution
M= mass in g of the material taken for the test.
Weigh accurately 4 to 5 g of pure zinc in a beaker, add
60 ml of dilute hydrochloric acid and heat carefully till B-3 METHOD 2
it dissolves completely. To facilitate dissolution about B-3. 1 Reagents
0.02 g of iron filling free from zinc may also be added.
After all the zinc has dissolved, cool, dilute and make B-3.1.1 Concentrated Hydrochloric Acid— Density
up to one litre. Pipette out 20 ml of made up zinc solution 1.18g/ml.
into a 500 ml conical flask, dilute to 100 ml with water
B-3.1.2 Dilute Hydrochloric Acid— Dilute 200 ml of
and neutralize with ammonium hydroxide, added
the hydrochloric acid (see B-3.1.1) to 1 Iitre, with water.
carefully till a white precipitate appears. Add dilute
hydrochloric acid drop by drop till the precipitate just B-3.1.3 Sulpuric Acid— Density 1.84 g/ml.
dissolves and add 5 ml dilute acid in excess. Warm to
60”C, add 3 drops of diphenylamine indicator and titrate B-3.1.4 Nitric,4cid— Density 1.42 g/ml.
against potassium ferrocyanide solution, a precipitate B-3.1.5 Ammonia Solution — Density 0.880 g/ml,
is formed with deepening in colour as the end point
approaches, the end point being the sudden colour B-3.1.6 Buffer Solution — Dissolve 200 g
change with the addition of one drop from blue voilet of hydroxylammonium chloride ( NH, OH. HCI )
to a pale green colour persisting even after thorough in approximately 300 ml of water. Dissolve 28 g of
shaking. Repeat the titration to obtain constant values. sodium hydroxide in approximately 300 ml of water.
Calculate the mass of zinc equivalent to 1ml of potassium Combine the two solutions, cool and dilute 1 litre with
ferrocyanide solution. water.
5
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IS 14946:2001 4
B-3.1.7 Ethylene diamine tetraacetic acid(EDTA), filtration in a 500 ml one mark volumetric flask. Make
disodium salt, dihydrate, solution, zinc factor T, in g the solution up to the mark and mix thoroughly.
Zn/ml (that is 1 ml of disodium EDTA solution will
B-3.2.3 By means of a pipette, transfer 50 ml of the
form a complex with T g of zinc).
solution to a 500-ml conical flask; add 200 ml of water
Dissolve about 20 g of disodium EDTA, dihydrate, in and 3 drops of the bromothymol blue indicator
water and make up to 1 Iitre with water. Store in a ( see B-3.1.9 ), then add ammonia solution ( see
polyethylene bottle. B-3.1.5 ) drop by drop, until the colour turns blue.
Then add the hydrochloric acid ( see B-3.1.2) until
Standardize against a 0.05 M zinc sulphate solution. the red colour changes to pale yellow. After that add
B-3. 1.8 Xylenol Orange — 0,1 g indicator ( sodium 20 ml of the buffer solution ( see B-3.1.6 ) and 3 drops
xylenol orange indicator ( see B-3.1.8) and titrate with
salt ) in 100 ml of water.
the disodium EDTA solution ( see B-3.1.7) until the
B-3.1.9 Bromothymo/ Blue — 0.1 g in 100 ml of red colour changes to pale yellow.
96 percent ethanol ( v/v ).
B-3.3 Calculation
B-3.2 Procedure
B-3.2.1 Weigh to the nearest 0.001 g about 1.5 g of Total zinc content (as Zn ), = -
the sample into a 250-ml beaker. Dissolve the sample percent by mass
in 20 ml of the hydrochloric acid ( see B-3.1.1 ) and
add 1 or 2 ml of the nitric acid ( see B-3.1.4) to ensure where
that any lead present is dissolved. Add 5 ml of the
m = mass, in grams of the test portion;
sulphuric acid ( see B-3.1.3) and evaporate strongly,
until fuming. Cool then add 100 ml of water, boil for T = zinc factor in grams per millilitre, of the
a short time and allow to stand until the following day. disodium EDTA solution ; and
B-3.2.2 Filter the solution through a sintered glass V =volume, in millilitres, of the disodium EDTA
or silica crucible; wash the crucible, collecting the solution used.
6
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IS 14946:2001
ANNEX C
[ Table 1, S/ No. 1 (A), iv (b) and C ]
DETERMINATION OF HARD DRY AND TIME TO TOP COAT
C-1 PURPOSE C-3.4 Testing should be done within an area, any
point of which is not less than% inch ( 15 mm ) from
To determine hard dry and time to top coat of zinc
the film edge.
silicate coatings , with desired dry film thickness
( DFT ) and under standard atmospheric conditions C-3.5 Testing should be done at temperature
of27 * 2° C and 65 ● 5 percent relative humidity. 27+ 2°C and at relative humidity of 65 * 5 percent.
C-2 SCOPE C-4 PROCEDURE
This test method is applicable for checking hard dry
C-4.1 Hard Dry Time
time and time to top coat.
C-3 PREPARATION OF TEST SPECIMENS AND Place the test panel in a horizontal position at a height
TEST CONDITIONS such that when the thumb is placed on the film, the
arm of the operator is in a vertical line from the wrist
C-3.1 Conduct test in a well ventilated room or chamber, to the shoulder. Bear down on the film with the thumb,
free from dust, products of combustion, laboratory exerting the maximum pressure of the arm, at the same
fumes and under diffused light. time turning the thumb through an angle of 90° in plane
C-3.2 Apply the paint on M.S. panel, blast cleaned of the film. The film is considered ‘hard dry’ when
to Sa 21/2 with a surfaceprofile25-40 microns by spray there is no loosening, detachment, wrinkling or other
application at a recommended DFT. evidence of distortion of the film.
C-3.3 Allow the coated panel to dry in a horizontal C-4.2 A quick and easy method to assess adequacy
or slanting position shielded from direct air current of cure for topcoating is to rub the primer with the
and in absence of direct sunlight. edge of a coin. If the film burnishes, it is acceptable.
ANNEX D
IS 14946:2001
ANNEX E
ANNEX F
IS 14946:2001
ANNEX G
( F’cweword )
GENERAL PROVISIONS
G-1 SUPPLY testingprogrammeinrelationto vendor’scetiification.
Unless otherwise agreed by the purchaser, the zinc- G-4.4 It may also provide a useful basis on which to
ethyl silicateprimer supplied shall not differ significar@y establish a testing programrne when a testing authority,
from the requirements of the specification in either acting on behalf of a purchaser, is required to examine
composition or performance. a series of batches for compliance with this standard.
The purchaser may require a test certificate that primer Tests to be made on first batch and on every subsequent
complies with this specification. batch:
G-3 The following information shall be given on the — Mass in kg per 10 Iitre
certificate:
— Solids in percent by weight
a) Description of primer,
— Consistency
b) The vendor’s product reference,
— Drying time
c) Batch identification,
— Pot life
d) Quantity in batch, and
— Colour
e) Date of manufacture.
— Finish
A certificate may relate to more than one batch.
— Total metallic zinc content
G-4 TESTS
— Flash point
G-4.1 The arrangement to establish compliance of the
primer with this specification and the frequency of the G-4.4.2 GROUP 2
tests to be carried out for testing the bulk supply shall
Tests to be made on first batch and subsequently as
be as agreed between the purchaser and the supplier.
and when agreed:
G-4.2 When a purchaser orders supply of primer to — Percent volume solids
this standard in lots to be delivered over a period, it
is not contemplated that all of the tests specified must — Protection against corrosion under condition
necessarily be made on samples representative of every of condensation
batch or consignment. The extent and frequency of
— Salt spray test
the testing will depend on many factors and a definite
schedule cannot be laid down. — Heat resistance test in case of main coat primer
G-4.3 The following classification oftests is, however, — Effect of welding on shop coat primer
submitted for the guidance of purchasers in establishing
in consultation with manufacturers, an appropriate
.. . — Keeping qualities
,,, .
9
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IS 14946:2001
ANNEX H
(Foreword )
~MM1’lTEE~
Members
10
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IS 14946:2001
( Continnedjiim page 10 )
Members Representing
DrrP. KUMAR Ott and Natural Gtrs Corporation Ltd, New Mumbai
SNRISHAISHKuwia Departmentof Industrial Development, New Delhi
SHRIB. B. SHAR~A( Alternate )
SHRILAII~DERSINGH, Director General, BIS ( Ex-officio Member)
Director ( Chem )
Member-Secretary
Du D. K. CHAUDHURY
Director ( Chem ), INS
11
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Copyright
BIS has the copyright of all its publications. No part ofthesepublications maybe reproduced in any form without
the prior permission in writing of BIS. This does not preclude the free use, in the course of implementing the
standard, of necessary details, such as symbols and sizes, type or grade designations. Enquiries relating to
copyright be addressed to the Director (Publications), BIS.
Amendments are issued to standards as the need arises onthebasis of comments, standards are aiso reviewed
periodically; a standard along with amendments is reafilrrned when such review indicates that no changes are
needed; if the review indicates that changes are needed, it is taken up for revision. Users of Indian Standards
should ascertain that they are in possession of the latest amendments or edition by referring to the latest issue
of ‘BIS Catalogue’ and ‘Standards: Monthly Additions’.
This Indian Standard has been developed from Doc : No. CHD 31 ( 430 ).