6092 Y24 Chem
6092 Y24 Chem
6092 Y24 Chem
Chemistry
(Syllabus 6092)
CONTENTS
Page
INTRODUCTION 3
AIMS 3
PRACTICES OF SCIENCE 4
DISCIPLINARY IDEAS OF CHEMISTRY 5
ASSESSMENT OBJECTIVES 5
SCHEME OF ASSESSMENT 7
CONTENT STRUCTURE 9
SUBJECT CONTENT 10
SUMMARY OF KEY QUANTITIES, SYMBOLS AND UNITS 25
PRACTICAL ASSESSMENT 26
NOTES FOR QUALITATIVE ANALYSIS 30
THE PERIODIC TABLE OF ELEMENTS 31
MATHEMATICAL REQUIREMENTS 32
GLOSSARY OF TERMS USED IN CHEMISTRY PAPERS 33
SPECIAL NOTE 34
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6092 CHEMISTRY GCE ORDINARY LEVEL SYLLABUS
INTRODUCTION
The Ordinary Level Chemistry Syllabus is designed to place less emphasis on factual materials while having a
greater emphasis on the understanding and application of scientific concepts and principles. This approach has
been adopted in recognition of the need for students to develop skills that will be of long-term value in an
increasingly complex and globalised world, rather than focusing on large quantities of factual material, which
may have only short-term relevance.
It is envisaged that teaching and learning programmes based on this syllabus will feature a wide variety of
learning experiences designed to promote acquisition of scientific expertise and understanding, and to develop
values and attitudes relevant to science. Teachers are encouraged to use a combination of appropriate
strategies including developing practical work for their students to facilitate a greater understanding of the
subject. It is expected that students will apply investigative and problem-solving skills and effectively
communicate the theoretical concepts covered in this course.
AIMS
The aims of a course based on this syllabus should be to:
1. provide a worthwhile educational experience for all students, whether or not they go on to study science
beyond this level.
2. develop in students the understanding and skills relevant to the practices of science, and enable them to
2.2 deepen their interest in Chemistry for future learning and work
2.3 become scientifically literate citizens who can innovate and seize opportunities in the 21st century
2.4 develop a way of thinking to approach, analyse and solve problems by explaining macroscopic
characteristics and changes in chemical systems through the use of sub-microscopic and symbolic
representations.
3. develop in students the values, ethics and attitudes relevant to science such as
3.1 curiosity – desiring to explore the environment and question what is found
3.3 integrity – handling and communicating data and information with complete honesty
3.4 objectivity – seeking data and information to validate observations and explanations without bias
3.5 open-mindedness – accepting all knowledge as tentative and suspending judgement, tolerance for
ambiguity, willingness to change views if the evidence is convincing
3.6 resilience – not giving up on the pursuit of answers/solutions, willingness to take risks and embrace
failure as part of the learning process
3.7 responsibility – showing care and concern for living things and awareness of our responsibility for the
quality of the environment
3.8 healthy scepticism – questioning the observations, methods, processes and data, as well as trying to
review one’s own ideas.
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6092 CHEMISTRY GCE ORDINARY LEVEL SYLLABUS
PRACTICES OF SCIENCE
The Practices of Science represent the set of established procedures and practices associated with scientific
inquiry, what scientific knowledge is and how it is generated and established, and how Science is applied in
society respectively. It consists of three components:
2.1 Science is an evidence-based, model-building enterprise concerned with understanding the natural
world
2.2 Science assumes there are natural causes for physical phenomena and an order and consistency in
natural systems
2.3 Scientific knowledge is generated using a set of established procedures and practices, and through a
process of critical debate within the scientific community
2.4 Scientific knowledge is reliable and durable, yet open to change in the light of new evidence
3.1 There are risks and benefits associated with the applications of science in society. Science and its
applications have the potential to bring about both benefits and harm to society
3.2 Applications of science often have ethical, social, economic and environmental implications
3.3 Applications of new scientific discoveries often inspire technological advancements while advances
in technology motivate scientists to ask new questions and/or empower scientists in their inquiry
(e.g. collecting more precise data or carrying out more complex data analysis)
The Practices of Science serve to highlight that the discipline of Science is more than the acquisition of a body
of knowledge (e.g. scientific facts, concepts, laws, and theories); it is also a way of thinking and doing. In
particular, it is important to appreciate that the cognitive, epistemic and social aspects of the Practices of
Science are intricately related. For example, observation of events can lead to the generation of scientific
knowledge which is, simultaneously, shaped by the beliefs of scientific knowledge. In addition, scientists
develop models to construct theories, based on the assumption that there is order and consistency in natural
systems. The practice of theory-making, in turn, reinforces the explanatory power of scientific knowledge. The
scientific endeavour is embedded in the wider ethical, social, economic and environmental contexts.
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6092 CHEMISTRY GCE ORDINARY LEVEL SYLLABUS
1. Matter is made up of a variety of chemical elements, each with characteristic properties, and the smallest
particle that characterises a chemical element is an atom.
2. The structure of matter and its chemical and physical properties are determined by the arrangement of
particles and electrostatic interactions between them.
3. Energy changes across and within systems usually occur during physical and chemical changes, when
there is rearrangement of particles.
4. Energy plays a key role in influencing the rate and extent of physical and chemical changes.
5. Matter and energy are conserved in all physical and chemical changes.
ASSESSMENT OBJECTIVES
The Assessment Objectives listed below reflect those parts of the Aims and Practices of Science that will be
assessed.
2. scientific vocabulary, terminology and conventions (including symbols, quantities and units contained in
Signs, Symbols and Systematics 16–19, Association for Science Education, 2000)
3. scientific instruments and apparatus, including techniques of operation and aspects of safety
5. scientific and technological applications with their social, economic and environmental implications.
The syllabus content defines the factual knowledge that candidates may be required to recall and explain.
Questions testing these objectives will often begin with one of the following words: define, state, name,
describe, explain or outline (see the Glossary of Terms).
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6092 CHEMISTRY GCE ORDINARY LEVEL SYLLABUS
Candidates should be able (in words or by using symbolic, graphical and numerical forms of presentation) to:
7. solve problems.
These Assessment Objectives cannot be precisely specified in the syllabus content because questions testing
such skills may be based on information which is unfamiliar to the candidate. In answering such questions,
candidates are required to use principles and concepts that are within the syllabus and apply them in a logical,
reasoned or deductive manner to a novel situation. Questions testing these objectives will often begin with one
of the following words: predict, deduce, suggest, calculate or determine (see the Glossary of Terms).
A Knowledge with Understanding, approximately 45% of the marks with approximately 15% allocated to
recall.
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Paper 3 will assess appropriate aspects of assessment objectives C1 to C6 in the following skill areas:
• Planning (P)
The assessment of Planning (P) will have a weighting of 15%. The assessment of skill areas MMO, PDO and
ACE will have a weighting of 85%.
SCHEME OF ASSESSMENT
Candidates are required to enter for Papers 1, 2 and 3.
Theory Papers
Paper 1 (1 h, 40 marks)
A copy of the Periodic Table of Elements will be printed as part of this Paper.
Section A will carry 70 marks and will consist of a variable number of compulsory structured questions. The last
two questions will carry 20 marks, one of which is a data-based question requiring candidates to interpret, evaluate
or solve problems using a stem of information. The data-based question will carry 8–12 marks.
Section B will carry 10 marks and will consist of two questions. Candidates must answer only one out of these
two questions.
A copy of the Periodic Table of Elements will be printed as part of this Paper.
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6092 CHEMISTRY GCE ORDINARY LEVEL SYLLABUS
Practical Assessment
One, or more, of the questions may incorporate assessment of Planning (P) and require candidates to apply
and integrate knowledge and understanding from different sections of the syllabus. The assessment of PDO
and ACE may include questions on data-analysis which do not require practical equipment and apparatus.
Candidates are not allowed to refer to notebooks, textbooks or any other information during the assessment.
A copy of the Notes for Qualitative Analysis will be printed as part of this Paper.
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6092 CHEMISTRY GCE ORDINARY LEVEL SYLLABUS
CONTENT STRUCTURE
Sections Topics
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6092 CHEMISTRY GCE ORDINARY LEVEL SYLLABUS
SUBJECT CONTENT
SECTION I: MATTER – STRUCTURES AND PROPERTIES
Overview
Matter is understood in terms of particles, the way particles are arranged and the forces that hold them together.
Evidence of the particulate nature of matter come from daily observable phenomena such as diffusion and
crystal growth. The simplest particle is known as an atom, which consists of sub-atomic particles like protons,
neutrons and electrons. A myriad of molecules with different properties are formed from the atoms of hundreds
of elements discovered to date. The physical properties of a substance are determined by how its particles are
arranged (i.e. structure) and the strength of the electrostatic forces between them.
Chemistry is typically an experimental science and relies primarily on practical work. This section also examines
the appropriate use of simple apparatus and chemicals, and experimental techniques.
1. Experimental Chemistry
Content
Learning Outcomes
(a) name appropriate apparatus for the measurement of time, temperature, mass and volume; including
burettes, pipettes, measuring cylinders and gas syringes
(b) suggest suitable apparatus, given relevant information, for a variety of simple experiments, including
drying and collection of gases and measurement of rates of reaction
(drying agents will be limited to calcium oxide, concentrated sulfuric acid and fused calcium chloride).
(a) describe methods of separation and purification for the components of mixtures, to include:
(i) use of a suitable solvent, filtration and crystallisation or evaporation
(ii) sublimation
(iii) distillation and fractional distillation (see also 11.1(b))
(iv) use of a separating funnel
(v) paper chromatography
(b) suggest suitable separation and purification methods, given information about the substances involved
in the following types of mixtures:
(i) solid-solid
(ii) solid-liquid
(iii) liquid-liquid (miscible and immiscible)
(c) interpret paper chromatograms including comparison with ‘known’ samples and the use of Rf values
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6092 CHEMISTRY GCE ORDINARY LEVEL SYLLABUS
(d) explain the need to use locating agents in the chromatography of colourless compounds
(knowledge of specific locating agents is not required)
(e) deduce from given melting point and boiling point data the identities of substances and their purity
(f) explain the importance of measuring the purity in substances used in everyday life, e.g. foodstuffs and
drugs.
Content
Learning Outcomes
(a) describe the solid, liquid and gaseous states of matter and explain their interconversion in terms of the
kinetic particle theory and of the energy changes involved
(b) describe and explain evidence for the movement of particles in liquids and gases
(the treatment of Brownian motion is not required)
(c) explain everyday effects of diffusion in terms of particles, e.g. the spread of perfumes and cooking
aromas; tea and coffee grains in water
(d) state qualitatively the effect of molecular mass on the rate of diffusion and explain the dependence of
rate of diffusion on temperature.
(a) state the relative charges and approximate relative masses of a proton, a neutron and an electron
(b) describe, with the aid of diagrams, the structure of an atom as consisting of protons and neutrons
(nucleons) in the nucleus and electrons arranged in shells (energy levels)
(knowledge of s, p, d and f classification is not required; a copy of the Periodic Table will be available
in Papers 1 and 2)
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(d) interpret and use nuclide notations such as 6 C
(f) deduce the numbers of protons, neutrons and electrons in atoms and ions given proton and nucleon
numbers.
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6092 CHEMISTRY GCE ORDINARY LEVEL SYLLABUS
Content
Learning Outcomes
(a) describe the formation of ions by electron loss/gain and that these ions usually have the electronic
configuration of a noble gas
(b) describe, including the use of ‘dot-and-cross’ diagrams, the formation of ionic bonds between
metals and non-metals, e.g. NaCl ; MgCl 2
(c) state that ionic materials contain a giant lattice in which the ions are held by electrostatic attraction,
e.g. NaCl
(candidates will not be required to draw diagrams of ionic lattices)
(d) relate the physical properties (including electrical property) of ionic compounds to their lattice structure
(see also 3.4(g)).
(a) describe the formation of a covalent bond by the sharing of a pair of electrons and that the atoms in
the molecules usually have the electronic configuration of a noble gas
(b) describe, using ‘dot-and-cross’ diagrams, the formation of covalent bonds between non-metallic
elements, e.g. H2; O2; H2O; CH4; CO2
(d) relate the physical properties (including electrical property) of covalent substances to their structure
and bonding (see also 3.4(g)).
(b) describe the general physical properties of metals as solids having high melting and boiling points,
malleable, good conductors of heat and electricity in terms of their structure (see also 3.4(g)).
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6092 CHEMISTRY GCE ORDINARY LEVEL SYLLABUS
(b) describe an alloy as a mixture of a metal with another element, e.g. brass; stainless steel
(d) explain why alloys have different physical properties to their constituent elements
(e) compare the structures of the following substances in order to deduce their properties:
(i) simple molecular substances, e.g. methane, iodine
(ii) macromolecules, e.g. poly(ethene)
(iii) giant covalent substances, e.g. sand (silicon dioxide), diamond, graphite
(see also 3.4(g))
(f) compare the bonding and structures of diamond and graphite in order to deduce their properties such
as electrical conductivity, lubricating or cutting action
(candidates will not be required to draw the structures)
(g) deduce the physical and chemical properties of substances from their structures and bonding and vice
versa (see also 3.1(d), 3.2(d), 3.3(b) and 3.4(e)).
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6092 CHEMISTRY GCE ORDINARY LEVEL SYLLABUS
Overview
This section provides an understanding of the changes at the sub-microscopic level during chemical reactions.
Different types of chemical reactions (acid-base, precipitation and redox reactions) are delved into and lay the
foundation for understanding what happens to energy and rate of reactions during a chemical change. The
study of reactions also reveals patterns in the chemical properties of substances, leading to the organisation of
elements in the Periodic Table.
In all chemical reactions, matter is conserved and this is illustrated by balanced chemical equations. Chemists
use symbols and formulae to construct these chemical equations, from which the molar ratios are used to
quantify the amount of reactants and products in a reaction.
4. Chemical Calculations
Content
Learning Outcomes
(a) state the symbols of the elements and formulae of the compounds mentioned in the syllabus
(b) deduce the formulae of simple compounds from the relative numbers of atoms present and vice versa
(c) deduce the formulae of ionic compounds from the charges on the ions present and vice versa
(e) construct chemical equations, with state symbols, including ionic equations.
(b) define relative molecular mass, Mr, and calculate relative molecular mass (and relative formula mass)
as the sum of relative atomic masses
(d) calculate the percentage mass of an element in a compound when given appropriate information
(f) calculate stoichiometric reacting masses and volumes of gases (one mole of gas occupies 24 dm3 at
room temperature and pressure); calculations involving the idea of limiting reactants may be set
(knowledge of the gas laws and the calculations of gaseous volumes at different temperatures and
pressures are not required)
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6092 CHEMISTRY GCE ORDINARY LEVEL SYLLABUS
(g) apply the concept of solution concentration (in mol/dm3 or g/dm3) to process the results of volumetric
experiments (e.g. titration) and to solve simple problems
(appropriate guidance will be provided where unfamiliar reactions are involved)
5. Acid-Base Chemistry
Content
5.2 Salts
5.3 Ammonia
Learning Outcomes
(a) describe the meanings of the terms acid and alkali in terms of the ions they produce in aqueous
solution and their effects on Universal Indicator
(c) describe qualitatively the difference between strong and weak acids in terms of the extent of ionisation
(d) describe the characteristic properties of acids as in reactions with metals, bases and carbonates to
form salts
(e) describe the reaction between hydrogen ions and hydroxide ions to produce water,
H+ + OH– → H2O, as neutralisation
(f) describe the importance of controlling the pH in soils and how excess acidity can be treated using
calcium hydroxide
(g) describe the characteristic properties of bases in reactions with acids and with ammonium salts
(h) classify oxides as acidic, basic, amphoteric or neutral based on metallic/non-metallic character.
5.2 Salts
(a) describe the techniques used in the preparation, separation and purification of salts as examples of
some of the techniques specified in Section 1.2(a) (methods for preparation should include
precipitation and titration together with reactions of acids with metals, insoluble bases and insoluble
carbonates)
(b) describe the general rules of solubility for common salts to include nitrates, chlorides (including those
of silver and lead), sulfates (including those of barium, calcium and lead), carbonates, hydroxides,
salts of Group 1 cations and ammonium salts
(c) suggest a method of preparing a given salt from suitable starting materials, given appropriate
information.
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6092 CHEMISTRY GCE ORDINARY LEVEL SYLLABUS
5.3 Ammonia
(a) describe the use of nitrogen, from air, and hydrogen, from the cracking of crude oil, in the manufacture
of ammonia
(b) state that some chemical reactions are reversible, e.g. manufacture of ammonia
(c) interpret data relating to the conditions used in industry for processes involving reversible reactions,
e.g. manufacture of ammonia by the Haber Process
(knowledge of Le Chatelier’s Principle is not required).
6. Qualitative Analysis
Learning Outcomes
(a) describe the use of aqueous sodium hydroxide and/or aqueous ammonia to identify the following aqueous
cations through the formation of precipitates (if any) and their subsequent solubility: aluminium, ammonium
(together with evolution of ammonia gas upon warming), calcium, copper(II), iron(II), iron(III) and zinc
(formulae of complex ions are not required)
(b) describe tests to identify the following anions: carbonate (by the addition of dilute acid and subsequent use
of limewater); chloride (by reaction of an aqueous solution with nitric acid and aqueous silver nitrate);
iodide (by reaction of an aqueous solution with nitric acid and aqueous silver nitrate); nitrate (by reduction
with aluminium in aqueous sodium hydroxide to ammonia and subsequent use of damp red litmus paper)
and sulfate (by reaction of an aqueous solution with nitric acid and aqueous barium nitrate)
(c) describe tests to identify the following gases: ammonia (using damp red litmus paper); carbon dioxide
(using limewater); chlorine (using damp litmus paper); hydrogen (using a burning splint); oxygen (using a
glowing splint) and sulfur dioxide (using acidified potassium manganate(VII)).
7. Redox Chemistry
Content
7.2 Electrochemistry
Learning Outcomes
(b) define redox in terms of electron transfer and changes in oxidation state
(c) identify redox reactions in terms of oxygen/hydrogen gain/loss, electron gain/loss and changes in
oxidation state
(d) describe the use of aqueous potassium iodide and acidified potassium manganate(VII) in testing for
oxidising and reducing agents from the resulting colour changes.
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7.2 Electrochemistry
(a) describe electrolysis as the conduction of electricity through an ionic compound (an electrolyte), when
molten or dissolved in water, leading to chemical changes (including decomposition) at the electrodes
(b) describe electrolysis as evidence for the existence of ions which are held in a lattice when solid but
which are free to move when molten or in solution
(c) describe, in terms of the mobility of ions present and the electrode products, the electrolysis of molten
sodium chloride, using inert electrodes
(d) predict the likely products of the electrolysis of a molten binary ionic compound using inert electrodes
(f) predict the likely products of the electrolysis of an aqueous electrolyte, given relevant information
(g) construct ionic equations for the reactions occurring at the electrodes during the electrolysis, given
relevant information
(h) describe the electrolysis of aqueous copper(II) sulfate with copper electrodes as a means of purifying
copper
(no technical details are required)
(i) describe the electroplating of metals, e.g. copper plating, and state one use of electroplating
(j) describe the production of electrical energy from simple cells (i.e. two electrodes in an electrolyte)
linked to the reactivity series (see also 8.4) and redox reactions (in terms of electron transfer)
(k) describe hydrogen, derived from water or hydrocarbons, as a potential fuel, reacting with oxygen to
generate electricity directly in a hydrogen fuel cell
(details of the construction and operation of a fuel cell are not required).
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6092 CHEMISTRY GCE ORDINARY LEVEL SYLLABUS
Content
Learning Outcomes
(a) describe the Periodic Table as an arrangement of the elements in the order of increasing proton
(atomic) number
(b) describe how the position of an element in the Periodic Table is related to proton number and
electronic configuration
(c) describe the relationship between number of outer (valence) electrons and the ionic charge of an ion
for the first twenty elements
(d) explain the similarities between the elements in the same group of the Periodic Table in terms of their
electronic configuration
(e) describe the change from metallic to non-metallic character from left to right across a period of the
Periodic Table
(f) describe the relationship between number of outer (valence) electrons and metallic/non-metallic
character
(g) predict the properties of elements in Group 1 and Group 17 using the Periodic Table.
(a) describe lithium, sodium and potassium in Group 1 (the alkali metals) as a collection of relatively soft,
low density metals showing a trend in melting point and in their reaction with water
(b) describe chlorine, bromine and iodine in Group 17 (the halogens) as a collection of diatomic non-
metals showing a trend in colour, state and their displacement reactions with solutions of other halide
ions
(c) describe the elements in Group 18 (the noble gases) as a collection of monoatomic elements that are
chemically unreactive and hence important in providing an inert environment, e.g. argon and neon in
light bulbs; helium in balloons; argon in the manufacture of steel
(d) describe the lack of reactivity of the noble gases in terms of their electronic configurations.
(a) describe typical transition elements as metals having high melting point, high density, variable
oxidation state and forming coloured compounds
(b) state that the elements and/or their compounds are often able to act as catalysts (see also 10(d)).
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6092 CHEMISTRY GCE ORDINARY LEVEL SYLLABUS
(a) place in order of reactivity calcium, copper, (hydrogen), iron, lead, magnesium, potassium, silver,
sodium and zinc by reference to
(i) the reactions, if any, of the metals with water, steam and dilute hydrochloric acid
(ii) the reduction, if any, of their oxides by carbon and/or by hydrogen
(b) describe the reactivity series as related to the tendency of a metal to form its positive ion, illustrated by
its reaction with
(i) the aqueous ions of the other listed metals
(ii) the oxides of the other listed metals
(c) deduce the order of reactivity from a given set of experimental results
(d) describe the action of heat on the carbonates of the listed metals and relate thermal stability to the
reactivity series
(e) describe the ease of obtaining metals from their ores by relating the elements to their positions in the
reactivity series
(f) describe the essential conditions for the corrosion (rusting) of iron as the presence of oxygen and
water; prevention of rusting can be achieved by placing a barrier around the metal, e.g. painting;
greasing; plastic coating; galvanising
(g) describe the sacrificial protection of iron by a more reactive metal in terms of the reactivity series
where the more reactive metal corrodes preferentially, e.g. underwater pipes have a piece of
magnesium attached to them.
9. Chemical Energetics
Learning Outcomes
(a) describe the meaning of enthalpy change in terms of exothermic (ΔH negative) and endothermic
(ΔH positive) reactions
(b) represent energy changes by energy profile diagrams, including reaction enthalpy changes and activation
energies (see also 10(c), 10(d))
(c) describe bond breaking as an endothermic process and bond making as an exothermic process
(d) explain qualitatively overall enthalpy changes in terms of the energy changes associated with the breaking
and making of covalent bonds.
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6092 CHEMISTRY GCE ORDINARY LEVEL SYLLABUS
Learning Outcomes
(a) describe the effect of concentration, pressure, particle size and temperature on the rates of reactions and
explain these effects in terms of collisions between reacting particles
(b) define the term catalyst and describe the effect of catalysts (including enzymes) on the rates of reactions
(c) explain how pathways with lower activation energies account for the increase in rates of reactions (see also
9(b))
(d) state that some compounds act as catalysts in a range of industrial processes and that enzymes are
biological catalysts (see also 8.3(b), 9(b), 10(c) and 12(d))
(e) suggest a suitable method for investigating the effect of a given variable on the rate of a reaction
(f) interpret data obtained from experiments concerned with rate of reaction.
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6092 CHEMISTRY GCE ORDINARY LEVEL SYLLABUS
Overview
Ubiquitous in modern life, organic compounds range from the fuels we burn, the materials we use such as
plastics to the food we eat. Urbanisation, industrialisation, increasing population and economic development
especially in developing countries also create a huge demand for consumption of material goods and energy,
accelerating the rate of waste output and emissions of pollutants. The excessive use of crude oil and its
products results in detrimental effects on the environment and sustainability. Chemists have made significant
contributions towards reducing these effects and improving sustainability through innovative use of chemical
knowledge.
In this section, knowledge and concepts from other topics within the syllabus are applied to assess the impacts
of the consumption of organic compounds like fuels and plastics, the environmental issues related to their use
and the solutions afforded by chemistry.
Content
11.2 Hydrocarbons
11.4 Polymers
In describing reactions, candidates will be expected to quote the reagents, e.g. aqueous bromine, and
the essential conditions, e.g. high temperature and pressure. Detailed conditions involving specific
temperature and pressure values are not required.
Learning Outcomes
(a) name natural gas, mainly methane, and crude oil as non-renewable sources of energy
(b) describe crude oil as a mixture of hydrocarbons and its separation by fractional distillation to yield
fractions which have competing uses as fuels and as a source of chemicals (see also 1.2(a))
(c) describe biofuel (exemplified by bioethanol from sugarcane) as a renewable alternative to natural
gas and crude oil
(d) describe how biofuel, when compared to fossil fuels, can be more environmentally sustainable in
terms of carbon dioxide emission (see also 12(g)).
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11.2 Hydrocarbons
(a) describe a homologous series as a group of compounds with a general formula, similar chemical
properties and showing a gradation in physical properties as a result of increase in the size and
mass of the molecules, e.g. melting and boiling points; viscosity
(b) describe the alkanes as a homologous series of saturated hydrocarbons with the general formula
CnH2n+2
(c) draw the structures of branched and unbranched alkanes, C1 to C4, and name the unbranched
alkanes methane to butane
(e) describe alkanes (exemplified by methane) as being generally unreactive except in terms of
combustion and substitution by chlorine
(f) describe the alkenes as a homologous series of unsaturated hydrocarbons with the general formula
CnH2n
(g) draw the structures of branched and unbranched alkenes, C2 to C4, and name the unbranched
alkenes ethene to butene
(h) describe the manufacture of alkenes and hydrogen by cracking hydrocarbons and recognise that
cracking is essential to match the demand for fractions containing smaller molecules from the
refinery process
(i) describe the difference between saturated and unsaturated hydrocarbons from their molecular
structures and by using aqueous bromine
(j) describe the reactions of alkenes (exemplified by ethene) in terms of combustion, polymerisation
(see also 11.4(b)), and the addition with bromine, steam and hydrogen
(l) describe the manufacture of margarine by the addition of hydrogen to unsaturated vegetable oils to
form a solid product.
(a) describe the alcohols as a homologous series containing the –OH group
(b) draw the structures of branched and unbranched alcohols, C1 to C4, and name the unbranched
alcohols methanol to butanol
(c) describe the reactions of alcohols in terms of combustion and oxidation to carboxylic acids
(d) describe the formation of ethanol by the catalysed addition of steam to ethene and by fermentation of
glucose
(e) describe the carboxylic acids as a homologous series containing the –CO2H group
(f) draw the structures of carboxylic acids, C1 to C4, and name the unbranched acids methanoic acid to
butanoic acid
(g) describe the carboxylic acids as weak acids, reacting with carbonates, bases and some metals
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(h) describe the formation of ethanoic acid by the oxidation of ethanol by atmospheric oxygen or
acidified potassium manganate(VII)
(i) describe the reaction of a carboxylic acid with an alcohol to form an ester, e.g. ethyl ethanoate
(j) deduce the name and formula of an ester from the unbranched carboxylic acid, C1 to C4, and
alcohol, C1 to C4, and vice versa.
11.4 Polymers
(a) describe polymers as large molecules built up from small units (monomers), different polymers
having different units and/or different linkages
(b) describe the formation of poly(ethene) as an example of addition polymerisation of ethene as the
monomer (see also 11.2(j))
(c) state some uses of poly(ethene) as a typical plastic, e.g. plastic bags; clingfilm
(d) deduce the structure of the polymer product from a given monomer and vice versa
(e) describe nylon, a polyamide, and Terylene, a polyester, as condensation polymers, the partial
structure of nylon being represented as
(f) state some typical uses of man-made fibres such as nylon and Terylene, e.g. clothing; curtain
materials; fishing line; parachutes; sleeping bags
(g) describe the pollution problems caused by the disposal of non-biodegradable plastics
(i) describe depolymerisation as a process in which polymers are broken down into their monomers,
exemplified by hydrolysis of polyesters using acid as a catalyst
(j) discuss the social, economic and environmental issues of recycling plastics.
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6092 CHEMISTRY GCE ORDINARY LEVEL SYLLABUS
Learning Outcomes
(a) describe the volume composition of gases present in dry air as being approximately 78% nitrogen, 21%
oxygen and the remainder being noble gases (with argon as the main constituent) and carbon dioxide
(b) name some common atmospheric pollutants, e.g. carbon monoxide; methane; nitrogen oxides (NO and
NO2); ozone; sulfur dioxide; unburned hydrocarbons
(d) describe the reactions used in possible solutions to the problems arising from some of the pollutants
named in (b)
(i) the redox reactions in catalytic converters to remove combustion pollutants (see also 10(d))
(ii) the use of calcium carbonate to reduce the effect of ‘acid rain’ and in flue gas desulfurisation
(e) discuss some of the effects of these pollutants on health and on the environment
(i) the toxic nature of carbon monoxide
(ii) the role of nitrogen dioxide and sulfur dioxide in the formation of ‘acid rain’ and its effects on
respiration and buildings
(f) discuss the importance of the ozone layer and the problems involved with the depletion of ozone by
reaction with chlorine-containing compounds, chlorofluorocarbons (CFCs)
(h) state that carbon dioxide and methane are greenhouse gases and may contribute to global warming; give
the sources of these gases and describe the potential effects of increased levels of these greenhouse
gases, including more extreme weather events and melting of polar ice.
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6092 CHEMISTRY GCE ORDINARY LEVEL SYLLABUS
Base quantities
mass m g, kg, tonne
length l cm, m
time t s, min
amount of substance n mol
Other quantities
temperature θ, t °C
volume V cm3, m3, dm3
density ρ g / cm3, kg / m3
atomic mass ma g
atomic
relative
{ isotopic } mass Ar –
molecular mass m g
relative molecular mass Mr –
molar mass M g / mol
nucleon number A –
proton number Z –
neutron number N –
enthalpy change of reaction ΔH J, kJ, J / mol, kJ / mol
bond energy – kJ / mol
concentration c mol / dm3, g / dm3
pH pH –
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6092 CHEMISTRY GCE ORDINARY LEVEL SYLLABUS
PRACTICAL ASSESSMENT
Scientific subjects are, by their nature, experimental. It is therefore important that an assessment of a
candidate’s knowledge and understanding of science should include a component relating to practical work and
experimental skills.
This assessment is provided in Paper 3 as a formal practical test and is outlined in the Scheme of Assessment.
Paper 3 Practical
This paper is designed to assess a candidate's competence in those practical skills which can realistically be
assessed within the context of a formal practical assessment.
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6092 CHEMISTRY GCE ORDINARY LEVEL SYLLABUS
One, or more, of the questions may incorporate some assessment of skill area P, set in the context of the
syllabus content, requiring candidates to apply and integrate knowledge and understanding from different
sections of the syllabus. It may also require the treatment of given experimental data in drawing relevant
conclusion and analysis of proposed plan.
The assessment of skills MMO, PDO and ACE will be set mainly in the context of the syllabus content. The
assessment of PDO and ACE may also include questions on data-analysis which do not require practical
equipment and apparatus.
Within the Scheme of Assessment, the practical paper constitutes 20% of the O-Level Chemistry examination.
It is therefore recommended that the schemes of work include learning opportunities that apportion a
commensurate amount of time for the development and acquisition of practical skills.
Candidates should be able to use appropriate apparatus/equipment to record a range of measurements such as
mass, length, time, volume and temperature. In addition, candidates are expected to have been exposed to a
range of experimental techniques in the following areas:
1. Titration, e.g. acid-base titration (with suitable indicators such as methyl orange, screened methyl orange, and
thymolphthalein). Other types of titrations may also be required, and where appropriate, sufficient working
details will be given.
2. Speeds of reaction that may involve measuring of quantities, e.g. temperature, volume, length, mass or time
measurements
3. Experiments involving separation techniques such as paper chromatography, filtration and distillation
4. Salt preparation
5. Gas collection
Candidates would not be required to carry out drying of gases during practical examination.
Candidates would not be required to carry out tests involving sulfur dioxide gas.
Reactions involving ions not included in the Notes for Qualitative Analysis may be tested: in such cases,
candidates will not be expected to identify the ions but only to draw conclusions of a general nature.
Candidates should not attempt tests, other than those specified, on substances, except when it is
appropriate to test for a gas.
7. Qualitative organic analysis requiring a knowledge of simple organic reactions as outlined in Topic 11
Organic Chemistry, e.g. test-tube reactions indicating the presence of unsaturation (C=C) may be set, but
this would be for the testing of observation skills and drawing general conclusions only.
This is not intended to be an exhaustive list. Candidates are expected to be familiar with the use of data-
loggers. Assessment of Skill P may include the appropriate use of data-loggers.
Candidates are not allowed to refer to notebooks, textbooks or any other information in the practical
examination. Notes for Qualitative Analysis will be included in the question paper for the use of candidates in the
examination. Candidates may be required to carry out simple calculations.
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6092 CHEMISTRY GCE ORDINARY LEVEL SYLLABUS
Practical Techniques
The following notes are intended to give schools and candidates an indication of the accuracy that is expected
in titration and general instructions for qualitative analysis.
(a) Candidates should normally record burette readings to the nearest 0.05 cm3 and they should ensure that
they have carried out a sufficient number of titrations, e.g. in an experiment with a good end-point, two titres
within 0.20 cm3.
(b) In qualitative analysis, candidates should use approximately 1 cm depth of a solution (1–2 cm3) for each
test and add reagents slowly, ensuring good mixing, until no further change is seen. Candidates should
indicate at what stage a change occurs. Answers should include details of colour changes and precipitates
formed, and the name and test for any gases evolved.
Apparatus List
This list given below has been drawn up in order to give guidance to Centres concerning the apparatus that is
expected to be generally available for examination purposes. The list is not intended to be exhaustive, in
particular, items (such as Bunsen burners, tripods, test-tube holders) that are commonly regarded as standard
equipment in a chemical laboratory are not included.
The apparatus and material requirements for Paper 3 will vary year on year. Centres will be notified in advance
of the details of the apparatus and materials required for each practical examination.
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6092 CHEMISTRY GCE ORDINARY LEVEL SYLLABUS
Reagents
This list given below has been drawn up in order to give guidance to Centres concerning the standard reagents
that are expected to be generally available for examination purposes. The list is not intended to be exhaustive
and Centres will be notified in advance of the full list of all reagents that are required for each practical
examination.
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6092 CHEMISTRY GCE ORDINARY LEVEL SYLLABUS
chloride (Cl –) acidify with dilute nitric acid, then add white ppt.
[in solution] aqueous silver nitrate
iodide (I–) acidify with dilute nitric acid, then add yellow ppt.
[in solution] aqueous silver nitrate
sulfate (SO42–) acidify with dilute nitric acid, then add white ppt.
[in solution] aqueous barium nitrate
aluminium (Al 3+) white ppt., soluble in excess giving a white ppt., insoluble in excess
colourless solution
copper(II) (Cu2+) light blue ppt., insoluble in excess light blue ppt., soluble in excess giving a
dark blue solution
iron(II) (Fe2+) green ppt., insoluble in excess green ppt., insoluble in excess
iron(III) (Fe3+) red-brown ppt., insoluble in excess red-brown ppt., insoluble in excess
zinc (Zn2+) white ppt., soluble in excess giving a white ppt., soluble in excess giving a
colourless solution colourless solution
sulfur dioxide (SO2) turns aqueous acidified potassium manganate(VII) from purple to colourless
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6092 CHEMISTRY GCE ORDINARY LEVEL SYLLABUS
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6092 CHEMISTRY GCE ORDINARY LEVEL SYLLABUS
MATHEMATICAL REQUIREMENTS
Candidates should be able to:
10. recognise and use the relationship between length, surface area and volume, and their units on metric
scales
12. solve equations of the form x = yz for any one term when the other two are known
14. comprehend how to handle numerical work so that significant figures are neither lost unnecessarily nor
used beyond what is justified.
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6092 CHEMISTRY GCE ORDINARY LEVEL SYLLABUS
1. Calculate is used when a numerical answer is required. In general, working should be shown, especially
where two or more steps are involved.
3. Comment is intended as an open-ended instruction, inviting candidates to recall or infer points of interest
relevant to the context of the question, taking account of the number of marks available.
4. Compare requires candidates to provide both similarities and differences between things or concepts.
5. Construct is often used in relation to chemical equations where a candidate is expected to write a balanced
equation, not by factual recall but by analogy or by using information in the question.
6. Define (the term(s)…) is intended literally. Only a formal statement or equivalent paraphrase being
required.
7. Describe requires candidates to state in words (using diagrams where appropriate) the main points of the
topic. It is often used with reference either to particular phenomena or to particular experiments. In the
former instance, the term usually implies that the answer should include reference to (visual) observations
associated with the phenomena. In the latter instance, the answer may often follow a standard pattern,
e.g. Apparatus, Method, Measurement, Results and Precautions.
In other contexts, describe and give an account of should be interpreted more generally, i.e. the candidate
has greater discretion about the nature and the organisation of the material to be included in the answer.
Describe and explain may be coupled in a similar way to state and explain.
8. Determine often implies that the quantity concerned cannot be measured directly but is obtained by
calculation, substituting measured or known values of other quantities into a standard formula.
9. Discuss requires candidates to give a critical account of the points involved in the topic.
10. Estimate implies a reasoned order of magnitude statement or calculation of the quantity concerned, making
such simplifying assumptions as may be necessary about the points of principle and about values of
quantities not otherwise included in the question.
11. Explain may imply reasoning or some reference to theory, depending on the context.
12. Find is a general term that may be variously interpreted as calculate, measure, determine, etc.
13. List requires a number of points, generally each of one word, with no elaboration. Where a given number of
points is specified, this should not be exceeded.
14. Measure implies that the quantity concerned can be directly obtained from a suitable measuring
instrument, e.g. length, using a rule, or angle, using a protractor.
15. Outline implies brevity, i.e. restricting the answer to giving essentials.
16. Predict or deduce implies that the candidate is not expected to produce the required answer by recall but
by making a logical connection between other pieces of information. Such information may be wholly given
in the question or may depend on answers extracted from an earlier part of the question. Predict also
implies a concise answer with no supporting statement required.
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6092 CHEMISTRY GCE ORDINARY LEVEL SYLLABUS
17. Sketch, when applied to graph work, implies that the shape and/or position of the curve need only be
qualitatively correct, but candidates should be aware that, depending on the context, some quantitative
aspects may be looked for, e.g. passing through the origin, having the intercept, asymptote or discontinuity
at a particular value.
In diagrams, sketch implies that a simple, freehand drawing is acceptable; nevertheless, care should be
taken over proportions and the clear exposition of important details.
18. State implies a concise answer with little or no supporting argument, e.g. a numerical answer that can be
obtained ‘by inspection’.
19. Suggest is used in two main contexts, i.e. either to imply that there is no unique answer, or to imply that
candidates are expected to apply their general knowledge to a ‘novel’ situation, one that may be formally
‘not in the syllabus’.
20. What do you understand by/What is meant by (the term(s)...) normally implies that a definition should be
given, together with some relevant comment on the significance or context of the term(s) concerned,
especially where two or more terms are included in the question.
The amount of supplementary comment intended should be interpreted in light of the indicated mark value.
SPECIAL NOTE
Nomenclature
Candidates will be expected to be familiar with the nomenclature used in the syllabus. The proposals in ‘Signs,
Symbols and Systematics’ (The Association for Science Education Companion to 16–19 Science, 2000) will
generally be adopted although the traditional names sulfate, sulfite, nitrate, nitrite, sulfurous and nitrous acids
will be used in question papers. Sulfur (and all compounds of sulfur) will be spelt with f (not with ph) in question
papers, however candidates can use either spelling in their answers.
It is intended that, in order to avoid difficulties arising out of the use of l as the symbol for litre, use of dm3 in
place of l or litre will be made.
In chemistry, full structural formulae (displayed formulae) in answers should show in detail both the relative
placing of atoms and the number of bonds between the atoms. Hence, –CONH2 and –CO2H are not satisfactory
as full structural formulae, although either of the usual symbols for the benzene ring is acceptable.
Candidates should be aware that misuse of units and/or significant figures, i.e. failure to quote units where
necessary, the inclusion of units in quantities defined as ratios or quoting answers to an inappropriate number of
significant figures, is liable to be penalised.
Calculators
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