1991 Bookmatter CitrusProcessing
1991 Bookmatter CitrusProcessing
1991 Bookmatter CitrusProcessing
412
ACID CORRECTIONS TO THE BRIX 413
C***************************************************************************************
C* RPG CALCULATIONS SUBROUTINE THAT CAN BE USED TO CALCULATE
C* THE LBS SOLIDS/GALLON FROM THE BRIX USING EQUATION 2-10
C***************************************************************************************
CSR SUBI BEGSR
CSR Z-ADDI COUNT 20 INITIALIZE
CSR Z-ADDl.OOOOOOO TAYLOR 157 VARIABLES
CSR BRIX ADD 330.872 FO 154
CSR Z-ADDl.OOOO Fl 158
CSR Z-ADD 1.0000 F2 154
CSR Z-ADDl.OOOO F3 154
CSR Fl MULTF Fl H CALCULATE
CSR F2 MULT 170435 F2 FACTORS
CSR Fl DIV F2 Fl H FOR
CSR Fl DIV F3 Fl H TAYLOR
CSR Fl MULT FO Fl H SERIES
CSR Z-ADDFI F4 158
CSR RET TAG
CSR SETOF 10 TAYLOR
CSR TAYLOR ADDF4 TAYLOR SERIES
CSR F4 MULT F3 F4 H SUMMATION
CSR F4 MULT Fl F4 H
CSR COUNT ADD 1 COUNT H
CSR F3 MULT COUNT F3 H
CSR F4 DIV F3 F4 H
CSR COUNT COMP20 10
CSR N10 GOTO RET
CSR SETOF 10
CSR TAYLOR MULT .0437691 TAYLOR H
CSR TAYLOR MULT BRIX SPG 43H FINAL SPG
CSR ENDSR VALUE
418
GWBASIC AND RPG PROGRAMS 419
10 'THIS PROGRAM CALCULATES THE UNCORRECTED BRIX NEEDED FROM THE EVAPORA-
TOR IN ORDER TO ACHIEVE A DESIRED GPL IN PROCESSING LEMON CONCENTRATE
20 INPUT "Uncorrected Brix of inbound lemon single strength juice"; UBJ
30 'IF REFRACT CORRECTS FOR TEMP, DISREGARD STEPS 40-60
40 INPUT "Temperature for Brix correction to lemon SSJ";T
50 BB=UBJ
60 GOSUB 340
70 INPUT "mls of NaOH titrated with SSJ";MLS
80 'IF NaOH NORMALITY IS ALWAYS 0.3125N THEN DISREGARD STEPS 90-110
90 INPUT "Normality of NaOH";N
100 IF N=O THEN N=.3125
110 MLS=MLS*N/.3125
422 APPENDIX B
10 'THIS PROGRAM CALCULATES THE BRIX, ACID, AND RATIO FROM LABORATORY DATA
20 INPUT "Uncorrected Brix";UB
30 'IF AN AUTO TEMP CORRECTING REFRACT IS USED, DISREGARD STEPS 40-80
AND ANY REFERENCES TO "TC"
40 INPUT "Temperature for Brix correction";T
50 A=UB'2*( .0001425-8.605E-06*T+7 .138E-08*T'2)
60 AA=UB*( -.02oo9+.001378*T-1.857E-05*T'2)
70 AAA=-.7788+.017*T+.00II*T'2)
80 TC=A+AA+AAA
90 INPUT "mls of NaOH titrated";MLS
100 'IF THE NORMALITY OF THE NaOH IS ALWAYS 0.1562, DISREGARD STEPS 110-130
110 INPUT "Normality of NaOH";N
120 IF N =0 THEN N = .1562
130 MLS=MLS*N/.1562
140 INPUT "Weight of juice sample (1O.5g = 10 mls SSJ)";W
150 ACID=MLS/W
160 AC=.014+.192*ACID-.00035*ACID'2
169 'THE FOLLOWING FIXES THE CORRECT DECIMAL PLACES
170 BRIX=CINT((UB+AC+TC)*lO)
180 BRIX=BRIX/lO
190 ACID=CINT(ACID*100)
200 ACID=ACID/loo
210 RATIO = CINT((BRIX/ACID)* 10)
220 RATIO=RATIO/I0
230 PRINT BRIX; "Brix"
240 PRINT ACID;"% acid"
250 PRINT RATIO;"B/ A ratio"
260 INPUT "Desired Brix";DB
270 INPUT "Volume of high Brix juice"; V
280 SPGI= .0437691 *BRIX*EXP((BRIX +330.872) '2/ 170435!)
290 SPGF= .0437691 *DB*EXP( (DB+330.872)'2/ 170435!)
300 WATER=CINT(V*(SPGI-SPGF)/SPGF)
GWBASIC AND RPG PROGRAMS 425
10 'THIS PROGRAM DETN'S THE AVG OIL AND OIL ADJUSTMENT OF A BLEND
20 DIM B(80)
25 DIM 0(80)
30 DIM V(80)
35 DIM SPG(80)
50 N=N+l
60 PRINT "Brix of component ";N;
70 INPUT B(N)
75 IF B(N) =0 THEN GOTO 130
76 PRINT "% oil of component ";N;
77 INPUT O(N)
78 O(N)=CINT( looo*O(N»/I000
80 PRINT "Volume of component ";N;
90 INPUT YeN)
95 SPG(N)=.0437691 *B(N)*EXP( (B(N)+330.872 )"2/ 170435!)
100 Z=Z+V(N)*SPG(N)
105 ZZ=ZZ+ V(N) *SPG(N) *O(N)
110 V=V+V(N)
120 GOTO 50
130 N=N-l
135 PRINT" #"," BRIX"," OIL", "VOL"
140 FOR 1=1 TO N
150 PRINT I,B(I),O(I),V(I)
160 NEXT
170 S=Z/V
1750=CINT(l000*ZZ/Z)/1OOO
180 BF=S*1O
190 B=BF
200 BF=S!( .0437691 *EXP( (B+330.872) "2/170435!»
210 IF ABS(BF-B)< .0001 THEN GOTO 230
220 GOTO 190
428 APPENDIX B
230 BF=CINT(BF*IO)/IO
250 PRINT "AVG BRIX = ";BF;SPC(3);"AVG OIL = ";0;SPC(3);"TOT VOL=";V
255 INPUT "Do you want to add oil (Y /N)";Q$
256 IF Q$ = "N" THEN END
260 INPUT "Desired final oillevel";OF
261 INPUT "Is volume in drums (52-gallon)(Y /N)";Q$
265 IF Q$="Y" THEN DD=52 ELSE DD=I
2700A=CINT«OF-0)*36.19*S*V*DD)
280 PRINT "Oil needed = ";OA
290 INPUT "mls oil enhancer needed per specification";OE
295 0I=OF-OE/(V*S*36.19*DD)
300 IF OA> =OE THEN PRINT "mls oil enhancer needed = ";OA: END
310 INPUT "Can the total volume of the blend change (Y /N)";Q$
330 INPUT "Number of blend component you wish to exchange";NN
340 FOR J = I TO N
350 ZZZ = ZZZ + SPG(J)*V(J)*(OI -0(1))
360 NEXT
370 ZZZ=ZZZ-SPG(NN)*V(NN)*(OI-O(NN»
375 01 =CINT«OI + ZZZ/(SPG(NN)*V(NN»)*lOoo) / 1000
380 IF Q$="N" THEN PRINT "% oil needed in component";NN;" =";01
390 V I = CINT(ZZZ / (O(NN)*SPG(NN)*( 1 - 01 /O(NN))))
400 IF Q$="Y" THEN PRINT "Volume needed in component";NN;" = ";VI
410 ZZZ=O
420 GOTO 310
10 'THIS PROGRAM DETN'S THE AVG PULP AND PULP ADJUSTMENT OF A BLEND
20 DIM B(80)
25 DIM P(80)
30 DIM V(80)
35 DIM SPG(80)
50 N=N+l
60 PRINT "Brix of component ";N;
70 INPUT B(N)
75 IF B(N)=O THEN GOTO 130
76 PRINT" % pulp of component ";N;
77 INPUT peN)
7 8 peN) = CINT( 1000*0(N» / 1000
80 PRINT "Volume of component ";N;
90 INPUT YeN)
95 SPG(N)= .0437691 *B(N)*EXP«B(N) +330.872 (2/ 170435!)
100 Z2 = Z2 + V (N)*SPG(N)
105 ZI =Zl + V(N)*SPG(N)*P(N)
120 GOTO 50
130 N=N-I
135 PRINT " #"," BRIX"," PULP", "VOL"
140 FOR 1=1 TO N
150 PRINT I,B(I),P(I),V(I)
160 NEXT
170 PAVG=ZI/Z2
250 PRINT "AVG PULP=";PAVG;SPC(3);"TOT VOL=";V
310 INPUT "Can the total volume of the blend change (Y /N)";Q$
GWBASIC AND RPG PROGRAMS 429
HP-41 C Programs
The following HP-41C or HP-41CV programs can best be used by assigning the pro-
grams to convenient keys using the ASN function. Then the program will activate when
the calculator is in the USER mode. The programs are designed for the calculator to be
alloted 53 storage registers using the SIZE function (SIZE 053). Included with each
program is a brief explanation of how to use the program. It is assumed that the user is
familer with the HP-41C program language. Most programs are self-explanatory. You
enter the data when prompted. Consult the text and relevant flow charts for program
logic and the objectives of the programs.
This program will calculate the parameters needed to adjust a full tank of juice to the
proper Brix by adding either water or higher Brix concentrate. If no entry is made for
the needed Brix, the program defaults to 11.8 °Brix. If the prompt does not apply, enter
nothing.
430
HP-41 C PROGRAM 431
This program will calculate the Brix, % acid, and B / A ratio from laboratory results. No
entry when you are prompted for the temperature causes the program to default to 20°C
or to apply no temperature correction to the Brix. If nothing is entered for the normality,
the default is 0.1562N. This can be changed in the program to 0.3125N if desired. If no
entry is made when you are prompted for the sample weight, a weight of 10.5 g (10 ml
of SSJ) will be assumed.
Each program below should be assigned a USER key. The BLD G?D program sets the
volume mode of the blend. Gallons mode assumes all volumes are in gallons. Gal/drums
mode assumes that all volumes less than 52 represent the number of 52-gallon drums,
and all volumes 52 or over are gallons. For example, an entry of 45 would mean 45
drums of concentrate, whereas 58 would be taken as 58 gallons of concentrate. This
allows the blending from bulk tanks and drums simultaneously without conversion of
one quantity to the volume units of the other. Each component is numbered and appears
in the prompts and displays. In the view program, if you enter nothing when prompted
for the number of the blend component desired, the default is the first component. The
calculator then will automatically step through the entered blend components for com-
parison to a blend manifest. You can add, delete, correct, or view blend components at
any time by using the separate assigned USER keys. The blend calculation takes a few
minutes. The calculation program also will prompt for the desired Brix and will calculate
the water needed in the blend, as well as the resulting final volume of the blend.
This program can be used to calculate fruit sample data for oranges, tangerines, grape-
fruit, or other citrus fruit except lemons and limes. The default temperature for the
temperature correction to the Brix is, again, 20 C or no temperature correction. The
D
default normality is 0.1562, and the default sample weight is 10.5 g (10 ml SSJ).
This program will calculate the average % oil or % pulp in a blend, as the two calcu-
lations are similar. The difference between oil and pulp is determined by the magnitude
of their values. The Brix of each component must be entered, as well as the % oil or
pulp. The volume prompt assumes that all units are the same (all drums or all gallons).
When all the components have been entered, enter nothing, press R/S, and the weighted
average % oil or pulp will appear.
This program calculates the fruit sample information for lemons and limes. The default
for temperature is, again, 20°C; the default for the NaOH normality is 0.1562; and the
default for the sample weight is 10.5 g.
This program will calculate the uncorrected Brix needed by evaporator operators in order
to concentrate lemon or lime juices to a desired GPL level. The temperature, normality,
and sample weight defaults are as before-20°C, 0.1562N, and 10.5 g, respectively.
The default for the desired GPL is 400,GPL. If you want to subtract an acid correction
from the Brix observed by the evaporator operator, then enter the temperature of the
concentrate observed by the refractometer.
This program calculates the GPL from Brix and acid measurements. The temperature,
normality, sample weight, and desired GPL defaults are 20°C, 0.3125N, 10.5 g, and
400 GPL, respectively. Any volumes can be used, but you must use the same units
throughout the calculation. The program also calculates the water needed to adjust high
GPL concentrates or juices.
This program is convenient when dilution to a desired Brix is all that is wanted. The
default desired Brix is 11.8°Brix. Any units of volume can be used as long as they are
consistent.
This program will generate data to construct a volume table for a particular bulk tank.
After entering the needed tank dimensions (see text for greater details), you enter the
distances from the hatch to the juice level, and the equivalent volume of the tank will
appear. The hatch depth is the distance from the lower lip of the hatch to the edge of
the tank.
Chapter 2
Questions
3. No.
5. Temperature, acid level, lab technician or techniques, refractometer calibration,
wavelength or color of light source, sample concentration.
Problems
Chapter 3
Questions
Problems
4. 4.82% acid
7. 60.6°Brix
10. 245 gallons of the 398 GPL concentrate, 3146 total gallons.
444
ANSWERS TO SELECT QUESTIONS AND PROBLEMS 445
Chapter 4
Questions
Problems
Chapter 5
Questions
4. Because the smaller and irregular size of the lemon fruit causes more fruit to be
lost during conveyance, and the nonspherical shape results in less efficient juice
extraction.
Problems
Chapter 6
Questions
Problems
Chapter 7
Questions
2. Increased.
3. The yield would be low, also.
9. Pulp wash may be used in drinks or beverages, or in other food products.
Problems
4. 4.7% pulp.
5. 1.8% pulp.
Chapter 8
Questions
Problems
Chapter 9
Questions
2. California orange juice is usually deeper in color than Florida orange juice be-
cause of California's drier climate.
Chapter 10
Questions
4. USDA: no standards. Florida: Grade A, 600 ppm naringin and 5.0 ppm limonin;
Grade B, 750 ppm naringin and 7.0 ppm limonin.
7. Test the juice for limonin, heat, and retest until the heating no longer increases
the limonin level.
ANSWERS TO SELECT QUESTIONS AND PROBLEMS 447
Problems
Chapter 11
Questions
Problems
Chapter 12
4. Extractors.
5. 58 sec-I.
448 APPENDIX D
Chapter 13
Questions
Chapter 14
Questions
Chapter 15
Questions
9. This minimum plate count is unknown, perhaps in the tens of thousands or higher.
12. By a pure random correlation; or, it does not correlate.
14. Several months.
Problems
1. Too many to count (TMTC) or too numerous to count (TNTC) , as over 300
colonies appeared on the plate.
4. 3.2 ppm.
Chapter 16
Questions
Chapter 17
Questions
Chapter 18
Questions
Problems
1. 2.35 - 2.27 meq/IOO ml = 0.08, less than the 0.10 that produces off flavors.
Therefore, the shelf life has not expired, but it is about to do so shortly.
3. Ksp (O°C) = 0.014 M2
Chapter 19
Questions
Problems
4. No. Early-season juice is authentic and may contain this much acid.
450 APPENDIX 0
Chapter 20
Questions
Problems
3. 688 pounds of citric acid, 13,134 gallons of water, 13,838 pounds of sugar, and
5797 gallons of juice.
5. 0 pounds of citric acid, 5,645 gallons of water, and 5,492 pounds of sugar.
Chapter 21
Questions
Problems
1. 25.0.
5. 6.3% alcohol; no.
Chapter 22
Questions
Problems
Chapter 23
Questions
3. Significant figures determine the number of decimal places that legitimately can
be used but do not indicate the actual error range. Error analysis does not indicate
the precision of measurement, only the range of error.
4. By specification.
9. Least squares analysis is a form of regression analysis that uses calculus to math-
ematically determine the best fit of a particular curve to particular data.
Problems
Chapter 24
Questions
Chapter 25
Questions
Problems
453
454 INDEX
Deaeration of juice for Brix measurement, 9, concentrated juice addition to, 328
10, 12 core wash use in, 115
Debittering (see also Limonin) 2, 156-158, flavors in, 323, 324
280 flow chart to formulate a drink base,
adsorption resins use in, 157, 158 333
auxin sprays use in, 157 foaming agents in, 326
immobilized bacteria use in, 157 juices used in, 321, 322
insect antifeedant use of wastes from, 2 low pulp juices in, 107
neodiosmin use in, 157 nutrients in, 325
of core wash, 115 preservatives in, 325, 326
supercritical carbon dioxide use in, 157 sample base formulation, 334
Decolorization of grapefruit, 134 sugar addition to, 327-329, 333
Defoaming agents in juice drinks, 326 sugar correction in, 331, 332, 334
Density (see also Specific gravity), 21,94 sulfites in, 325
of juices, 7-9,13,14,31,40,47,48,50, sweeteners used in, 322
52, 68, 70, 148, 150, 154, 166, 324- texturizers in, 324
328,331,383,393,408 vitamin C addition to, 325
of pellets, 341 vitamin C as an antioxidant in, 326
of oils, 87, 94, 95 water addition to, 328-330
of water, 94, 95, 403 water quality used to make, 334, 335
optical, 94, 143 Drosophila fruit fly, 246, 247
radioactive, 178 light effects on, 248
tables of, 8 Dutch standards, 292, 295
temperature corrections to juice, 31
a-terpineol, 264
Deoiling of single strength juice, 83 Employee discipline, 392, 393
Diacetyl Employee evaluations, 391
determination of, 232-234 Employee training, 391
non-random effects of, levels, 377 Enzymes
statistical analysis of, 371 aconitase, in citrus acid cycle, 35
Dried juice sacs, 110-112 deactivation of pectinase, 83, 119, 120,
color of, 112 177,239,281
composition of, (table), 112 deactivation of pectinase in juice sac
Dried peel, 339-341 production, 110
dust from, 339 effect of. on pressed peel due to liming,
heat production from, 339, 340 342
moisture addition to, by oil recovery immobilized, used in debittering, 157
systems, 340 immunoassay limonin determination, 142-
moisture content of, 339, 340 144
moisture test, 340 lemon juice clarification using, 124
nutrients in, (table), 341 melanin formation via, 271
Drinks, 303, 320-335 oxidation via, 260
acid addition to, 327-331, 333 PEV measurement of, activity, 121-123
acid correction, 331, 332, 334 protein as, 164
acids used in, 322 Steven's cloud test, 120
anti foaming agents in, 326 thiamine as coenzyme, 171
base formulation, 320, 326-331, 333 use of, as drink preservative, 326
calcium addition to, 325 in first stage of pulp wash, 124
~-carotene, 323 in Florida not allowed, 124
clouding agents in, 324 in oil production, 85
colors in, 322, 323 in pectin extraction, 304, 305
computer applications, 333, 334 in production of cold pressed oil, 87
458 INDEX
potassium citrate in, juice, 273, 274 deoiling of single strength juice, 83, 88, 89
use of, juice in drinks, 321 effect on alcoholic fermentation of
Neodiosmin, 157 molasses, 345
Nomilin, precurser to limonin, 140 essence oils, 88
Nootkatone evaporative residue, 97, 98
from valencene in excessively heated FCC specifications for, 89-91
essence oils, 88 flavor enhancer use of, 73
unique component in grapefruit oil, 74 flavor source for juice drinks, 323
Nutrients, 162-172 folded oils, 88
calcium, 172,321,322,325 freshly extracted juice levels, 83
calories, 164 grapefruit oils, 86
carbohydrates, 165, 166 in citric molasses fermentation, 347
drink base components, 325, 326, 334 in sample drink base formulation, 334
fat, 166 insect barrier of, to fruit, 245
flavonoids, 172 juice oils, 88
labeling, 162-167 levels in press liquor, 342
labeling example, 163 moisture addition to peel from, recovery,
macronutrients, 164 340
micronutrients, 166, 167 non-food product use, 73
minerals, 166, 167, 172 optical rotation of, 89, 92, 93
pectin, 172 production of, 83-99
potassium, 166 refractive index of, 93, 94
protein, 164, 165 removal during debittering, 157
sample plan for determination of nutrional Scott method of determination of, 74-79
label compliance, 398 significant figures of, levels, 373
sodium, 166 specific gravity of, 94, 95
thiamine, 171, 172,334 standards of identity allowance, 281
vitamin C, I, 166-172, 188,202,325 steam distilled, 87
vitamins, 166, 167,334 storage of, 85
taste threshold of, 79
Occupational Safety and Health Administra- USDA grades of, in juices, 80, 83
tion (OSHA), 394, 395 USP specifications for, 89-91
Oils, 2, 73-99, 303 use of, in juice drink flavor emulsions, 326
a-pinene in, 74 in juice drinks, 323, 324
a-terpineol oxidative by-product, 264 uv absorption of, 98, 99
addition of, to juice products, 80-82 winterizing of, 85
air pollution from d-limonene burning in yield change of, with maturity of fruit, 86
feedmill, 354 Oriental fruit fly, 246
aldehyde determination in, 95-97 Oxidation, 97, 260-272
blending of, levels in juices, 79-83, 427, acid contributions to, 264
428, 436, 437 amino acid contribution to, 261
centrifuge use in production of, 86 cyclotene formation due to, 262
Clevenger method determination of, 74, 75 detection of, 265
cold pressed, production, 85-87 2,5-dimethyl-4-hydroxy-3(2H)-furanone
composition of, 74 formation due to, 264, 270
computer applications, 83, 84, 427, 428, N-ethylpyrrole-2-carboxaldehyde formation
436,437 due to, 264
d-limonene effects in aerobic wastewater l-ethyl-2-formylpyrrole formation due to,
treatment, 359, 365 261,270
d-limonene effects on aerobic wastewater formol test, 267
treatment, 360, 366 furaneol formation due to, 263
d-limonene in, 74 furfural, 267, 270
464 INDEX
Citrus limetta Risso (Lemon-like), 201 tangerine juice addition and, 195, 281
Citrus limettoides Tan. (Sweet Lime), 203, varietal blending and, 291
204 vitamin C addition and, 188
Citrus limon (L.) Burm. f. (Lemon), 181, Statistics, 371-386
201 actual range, 374
Citrus maxima (Burm.) (Pummelo), 181, analysis of variance, 378-383
183 average deviation, 374
Citrus nobilis Loureiro (King Tangerine), control charts, 376, 377
181,200 error analysis, 374-376
Citrus paradisi Macfadyen (Grapefruit), F-distribution, 380
181, 192 least squares analysis, 383-386
Citrus reticulata Blanco (Common pulp level control applications, 104
Tangerine), 181, 195, 196 regression, 383-386
Citrus sinensis (L.) Osbeck (Sweet Orange), root mean square deviation. 374, 375
181-185, 187, 189, 190 runs, 376, 377
Citrus sudachi Hort. Shirai (Tangerine significant figures, 371-373
Hybrid), 201 standard deviation, 375
Citrus unshiu Marc. (Satsuma Tangerine), Steven's cloud test, 120
181 Sulfites
Specifications, 3, 234 as antioxidants, 272, 325, 326
black flake, 260 as preservative, 325, 326
Brix,28 in juice drinks. 325, 326
color, 130 Sucrose (see also Brix)
FCC, for oils, 89-91 adulteration detection of, 285
for pectin, 305 as Brix, 8
inbound and outbound, 389 as soluble solids. 7
microbial, 235 in nutritional labeling, 164-166
oil, 79 potassium citrate solubility in, solutions,
pulp, 107, 109 273
use of, to prevent adulteration, 297, 298 refractometer calibration using, solutions.
with control charts, 376 15
USP, for oils, 89-91 regression analysis of, tables, 21. 383
SPG (pounds soluble solids per gallon, see slime molds metabolized from. 228
Brix) structure of. 8
Standard deviation, 375, 376 viscosity contributions of, 177
Standards of identity, 280-284, 293. 389, 397 use of, density tables, 21. 47.154,383
antioxidants and. 272 in juice drinks. 322
calcium addition and, 172 solutions to increase limonin solubility,
cleaning agents and, 256 141
dried juice sacs and, 110 yeast fermentation of, 230, 231
food additives and, 256 Supercritical extraction, 2, 157
fruit sections, 319 Sweet orange (Citrus sinensis L. Osbeck).
grapefruit juices, 282 181, 182
imported juice, 220
jellies, 314, 315
labeling requirements, 400 Tangeretin, unique component in tangerine
lemon juices, 47, 282, 283, 400 oils, 74
oils and, 73, 281 Tangerines or mandarins, 181, 194-197
orange juices, 52, 53, 280-282 acid determination of, juice, 46
pulp and, 281 blending of, juice in orange juices, 126,
pulpwash and, 105, 114 281,291
468 INDEX