UnitTest - D09 Mar 2024
UnitTest - D09 Mar 2024
UnitTest - D09 Mar 2024
1. Calculate the pOH of a solution at 25°C that contains 1 ´ 10–10 M of hydronium ions, i.e. H3O+.
(A) 4.000 (B) 9.0000 (C) 1.000 (D) 7.000
2. If the concentration of OH– ions in the reaction Fe(OH)3(s)
Fe3+(aq) + 3OH–(aq) is decreased by
1
e3+ will increase by :
times, then equilibrium concentration of Fe
4
(A) 8 times (B) 16 times (C) 64 times (D) 4 times
3. Equimolar solutions of the following were prepared in water separately. Which one of the solutions
will record the highest pH ?
(A) SrCl2 (B) BaCl2 (C) MgCl2 (D) CaCl2
4. Which of the following molecules acts as a Lewis acid ?
(A) (CH3)2O (B) (CH3)3P (C) (CH3)3N (D) (CH3)3B
5. The ionization constant of ammonium hydroxide is 1.77 ´ 10–5 at 298 K. Hydrolysis constant of
ammonium chloride is :
(A) 6.5 ´ 10–12 (B) 5.65 ´ 10–13 (C) 5.65 ´ 10–12 (D) 5.65 ´ 10–10
6. If pH of a saturated solution of Ba(OH)2 is 12, the value of its K(Sp) is :
(A) 4.0 ´ 10–6 M3 (B) 4.0 ´ 10–7 M3 (C) 5.0 ´ 10–6 M3 (D) 5.0 ´ 10–7 M3
7. In which of the following equilibrium Kc and Kp are not equal ?
(A) 2NO(g) N2(g) + O2(g)
(B) SO2(g) + NO2(g) SO3(g) + NO(g)
(C) H2(g) + I2(g) 2HI(g)
(D) 2C(s) + O2(g) 2CO2(g)
8. Which one of the following molecular hydrides acts as a Lewis acid ?
(A) NH3 (B) H2O (C) B2H6 (D) CH4
10. In qualitative analysis, the metals of Group-I can be separated from other ions by precipitating them
as chloride salts. A solution initially contains Ag+ and Pb2+ at a concentration of 0.10 M. Aqueous HCl
is added to this solution until the Cl– concentration is 0.10 M. What will the concentrations of Ag+ and
Pb2+ be at equilibrium ?
(Ksp for AgCl = 1.8 ´ 10–10,
Ksp for PbCl2 = 1.7 ´ 10–5)
(A) [Ag+] = 1.8 ´ 10–7 M; [Pb+2] = 1.7 ´ 10–6 M (B) [Ag+] = 1.8 ´ 10–11 M; [Pb+2] = 8.5 ´ 10–5 M
(C) [Ag+] = 1.8 ´ 10–9 M; [Pb+2] = 1.7 ´ 10–3 M (D) [Ag+] = 1.8 ´ 10–11 M; [Pb+2] = 8.5 ´ 10–4 M
11. The first and second dissociation constants of an acid H2A are 1.0 ´ 10–5 and 5.0 × 10–10 respectively.
The overall dissociation constant of the acid will be
(A) 0.2 ´ 105 (B) 5.0 ´ 10–5 (C) 5.0 ´ 1015 (D) 5.0 ´ 10–15
12. The pKa of a weak acid (HA) is 4.5. The pOH of an aqueous buffered solution of HA in which 50 % of the
acid is ionized is
(A) 7.0 (B) 4.5 (C) 2.5 (D) 9.5
23. If the value of an equilibrium constant for a particular reaction is 1.6 ´ 1012, then at equilibrium
the system will contain :
(A) all reactants. (B) mostly reactants.
(C) mostly products. (D) similar amounts of reactants and products.
Wish You - All The Best
If the value of an equilibrium constant for a particular reaction is 1.6 ´ 1012, then at equilibrium
the system will contain :
(A) all reactants. (B) mostly reactants.
(C) mostly products. (D) similar amounts of reactants and products.
24. Which of the following statements is correct for a reversible process in a state of equilibrium ?
(A) DG = –2.30 RT log K (B) DG = 2.30 RT log K
(C) DG° = –2.30 RT log K (D) DG° = 2.30 RT log K
25. If the equilibrium constant for N 2(g) + O 2(g) 2NO (g) is K, the equilibrium constant for
1 1
N 2( g ) + O2( g ) NO( g ) will be :
2 2
1
(A) K (B) K2 (C) K1/2 (D) K
2
26. Which one of the following pairs of solution is not an acidic buffer ?
(A) H2CO3 and Na2CO3 (B) H3PO4 and Na3PO4
(C) HClO4 and NaClO4 (D) CH3COOH and CH3COONa
27. Aqueous solution of which of the following compounds is the best conductor of electric current ?
(A) Ammonia, NH3 (B) Fructose, C6H12O6
(C) Acetic acid, C2H4O2 (D) Hydrochloric acid, HCl
28. What is the mole fraction of the solute in a 1.00m aqueous solution ?
(A) 0.0354 (B) 0.0177 (C) 0.177 (D) 1.770
29. What is the pH of the resulting solution when equal volumes of 0.1 M NaOH and 0.01 M HCl are
mixed ?
(A) 7.0 (B) 1.04 (C) 12.65 (D) 2.0
30. The addition of a catalyst during a chemical reaction alters which of the following quantities ?
(A) Internal energy (B) Enthalpy (C) Activation energy (D) Entropy
31. MY and NY3 two nearly insoluble salts, have the same KSP values of 6.2 × 10–13 at room temperature.
Which statement would be true in regard to MY and NY3 ?
(A) The molar solubility of MY in water is less than that of NY3.
(B) The salts MY and NY3 are more soluble in 0.5 M KY than in pure water.
(C) The addition of the salt of KY to solution of MY and NY3 will have no effect on their solubilities.
(D) The molar solubilities of MY and NY3 in water are identical.
32. Consider the following liquid - vapour equilibrium. Liquid Vapour Which of the following relations
is correct ?
dlnP DH V dlnP DH V dlnP D H V d lnG DH V
(A) =– (B) 2
=- 2 (C) = (D) 2
=
dT RT dT T dT RT 2 dT RT 2
33. The percentage of pyridine (C5H5N) that forms pyridinium ion (C5H5N+H) in a 0.1 M aqueous pyridine
solution (Kb for C5H5N = 1.7 ´ 10–9) is
(A) 0.77% (B) 1.6% (C) 0.006% (D) 0.013%
34. The solubility of AgCl(s) with solubility product 1.6 ´ 10–10 in 0.1 M NaCl solution would be
(A) 1.6 ´ 10–11 M (B) Zero (C) 1.26 ´ 10–5 M (D) 1.6 ´ 10–9 M
35. Which of the following fluoro-compounds is most likely to behave as a Lewis base ?
(A) CF4 (B) SiF4 (C) BF3 (D) PF3
36. For the reaction N2(g) + 3H2(g) 2NH3(g), the standard equilibrium constant Kp is 5.8 × 105 at 298 K
temperature. If the concentration of gases indicate by mol L–1 then find the value of standard equilibrium
constant from the following.
(R = 0.08314 L bar K–1 mol–1)
(A) 3.5 × 106 (B) 3.8 × 107 (C) 3.56 × 10+8 (D) 3.99 × 109
Wish You - All The Best
constant from the following.
(R = 0.08314 L bar K–1 mol–1)
(A) 3.5 × 106 (B) 3.8 × 107 (C) 3.56 × 10+8 (D) 3.99 × 109
37. Take the following reaction in consederation. In which enthalpy change is positive. 2A(g) C(g) + D(g).
Which of the following will not affect on equilibrium ?
(A) Change in concentration of reactants (B) Change in pressure
(C) Change in temperature (D) Change in catalyst
Kp
38. The is equal to which of the following in given reaction ? CO(g) + Cl2(g) COCl2(g)
Kc
1
(A) (B) RT (C) RT (D) (RT)2
RT
39. The pKa and pKb of one weak acid (HA) and weak base (BOH) are 3.2 and 3.4 respectively. Find pH
of its salt AB.
(A) 7.2 (B) 6.9 (C) 7.9 (D) 1.0
40. Which of the following lines correctly show the temperature dependence of equilibrium constant, K, for
an exothermic reaction ?
(A) A and B ln K A
B
(B) B and C
(0, 0) 1
T(K)
(C) C and D
(D) A and D C
D
41. An aqueous solution contains 0.10 M H2S and 0.20 M HCl. If the equilibrium constants for the formation
of HS– from H2S is 1.0 ´ 10–7 and that of S2– from HS– ions is 1.2 ´ 10–13 then the concentration of S2– ions
in aqueous solution is :
(A) 5 ´ 10–8 (B) 3 ´ 10–20 (C) 6 ´ 10–21 (D) 5 ´ 10–19
42. An aqueous solution an unknown concen-tration of Ba2+. When 50 mL of a 1 M solution of Na2SO4
is added, BaSO4 just begins to precipitate. The final volume is 500 mL. The solubility product of
BaSO4 is 1 ´ 10–10. What is the original concentration of Ba2+.
(A) 5 ´ 10–9 M (B) 2 ´ 10–9 M (C) 1.1 ´ 10–9 M (D) 1.0 ´ 10–10 M
43. Which of the following are lewis acids ?
(A) PH3 and BCl3 (B) AlCl3 and SiCl4 (C) PH3 and SiCl4 (D) BCl3 and AlCl3
44. Which of the following salts is the most basic in aqueous solution ?
(A) Al(CN)3 (B) CH3COOK (C) FeCl3 (D) Pb(CH3COO)2
45. An alkali is titrated against an acid with methyl orange as indicator, which of the following is a correct
combination ?
Base Acid End point
(A) Weak Strong Colourless to pink
(B) Strong Strong Pinkish red to yellow
(C) Weak Strong Yellow to pinkish red
(D) Strong Strong Pink to colourless
46. Following solutions were prepared by mixing different volumes of NaOH and HCl of different
concentrations :
M M
(a) 60 ml, HCl + 40 ml NaOH
10 10
(b) 55 ml,
M
HCl + 45 ml
M Wish You - All The Best
NaOH
10 10
M M
Following solutions were prepared by mixing different volumes of NaOH and HCl of different
concentrations :
M M
(a) 60 ml, HCl + 40 ml NaOH
10 10
M M
(b) 55 ml, HCl + 45 ml NaOH
10 10
M M
(c) 75 ml, HCl + 25 ml NaOH
5 5
M M
(d) 100 ml, HCl + 100 ml NaOH
5 10
pH of which one of them will be equal to 1 ?
(A) (c) (B) (b) (C) (d) (D) (a)
47. The solubility of BaSO4 in water is 2.42 ´ 10–3 gL–1 at 298 K. The value of its solubility product (KSP)
will be (Given molar mass of BaSO4 = 233 g mol–1)
(A) 1.08 ´ 10–8 mol2 L–2 (B) 1.08 ´ 10–10 mol2 L–2
(C) 1.08 ´ 10–14 mol2 L–2 (D) 1.08 ´ 10–12 mol2 L–2
48. Which one of the following conditions will favour maximum formation of the product in the reaction,
A2(g) + B2(g) X2(g), DrH = –X kJ
(A) High temperature and low pressure (B) Low temperature and high pressure
(C) High temperature and high pressure (D) Low temperature and low pressure
49. 501 gm NH4SH dissolve in 3 L at 327ºC temperature in evacuated vessel. 30% NH4SH decompose in
NH3 and H2S, find Kp at 327ºC. (Molecular of NH4SH = 51 gm/mol, R = 0.082 L atm./mol K)
(A) 0.242 ´ 10–4 atm.2 (B) 0.242 atm.2 (C) 1 ´ 10–4 atm.2 (D) 4.9 ´ 10–4 atm.2
50. Hydrolysis of sucrose is given by the following reaction.
Sucrose + H2O Glucose + Fructose
If the equilibrium constant (Kc) is 2 ´ 1013 at 300 K, the value of DrG at the same temperature will
be :
(A) 8.314 J mol–1 K–1 ´ 300 K ´ ln (3 ´ 1013) (B) –8.314 J mol–1 K–1 ´ 300 K ´ ln (4 ´ 1013)
(C) –8.314 J mol–1 K–1 ´ 300 K ´ ln (2 ´ 1013) (D) 8.314 J mol–1 K–1 ´ 300 K ´ ln (2 ´ 1013)
51. Find out the solubility of Ni(OH)2 in 0.1 M NaOH. Given that the ionic product of Ni(OH)2 is 2 ´ 10–15.
(A) 1 ´ 10–13 M (B) 1 ´ 103 M (C) 2 ´ 10–13 M (D) 2 ´ 10–8 M
52.
For the equilibrium A B, the variation of the rate of the forward ‘a’ and reverse ‘b’ reaction with
time is given by :
Rate of reaction
Rate of reaction
Equilibrium
Equilibrium
Rate of reaction
Rate of reaction
Equilibrium
Equilibrium
a a
a a
(A) (B) (C) (D)
b b b b
Time Time
Time Time
53. The pKb of dimethylamine and pKa of acetic acid are 3.27 and 4.77 respectively at T(K). The correct
option for the pH of dimethyl-ammonium acetate solution is :
(A) 7.75 (B) 6.25 (C) 8.50 (D) 5.50
54. For the reaction A(g) B(g) at 495 K, DrGo = –9.478 kJ mol–1. If we start the reaction in a closed container
at 495K with 22 millimoles of A, the amount of B is the equilibrium mixture is ...... millimoles. (Round off
to the Nearest Integer). [R = 8.314 J mol–1 K–1, ln 10 = 2.303]
55. Two salts A2X and MX have the same value of solubility product of 4.0 ´ 10–12. The ratio of their molar
S(A 2 X)
solubilities = ......
S(MX)
58. 0.01 moles of a weak acid HA (Ka = 2.0 ´ 10–6) is dissolved in 1.0 L of 0.1 M HCl solution. The degree
of dissociation of HA is ...... ´ 10–5 (Round off to the Nearest Integer).
[Neglect volume change on adding HA. Assume degree of dissociation <<1]
59. Consider the reaction N2O4(g) 2NO2(g). The temperature at which KC = 20.4 and KP = 600.1, is ......
K. (Round off to the Nearest Integer). [Assume all gases are ideal and R = 0.0831 L bar K–1 mol–1]
60. In order to prepare a buffer solution of pH 5.74, sodium acetate is added to acetic acid. If the
concentration of acetic acid in the buffer is 1.0 M, the concentration of sodium acetate in the buffer
is ...... M. (Round off to the Nearest Integer). [Given : pKa (acetic acid) = 4.74]
61. The solubility of CdSO4 in water is 8.0 × 10–4 mol L–1. Its solubility in 0.01 M H2SO4 solution is ......
´ 10–6 mol L–1. (Round off to the Nearest integer) (Assume that solubility is much less than 0.01 M)
62. 10.0 mL of Na2CO3 solution is titrated against 0.2 M HCl solution. The following titre values were
obtained in 5 readings. 4.8 mL, 4.9 mL, 5.0 mL, 5.0 ml and 5.0 mL Based on these readings and
convention of titrimetric estimation of concentration of Na2CO3 solution is ...... mM.
63. The pH of the solution containing 50 mL each of 0.10 M sodium acetate and 0.01 M acetic acid is
[Given CH3COOH of pKa = 4.57]
(A) 4.57 (B) 2.57 (C) 5.57 (D) 3.57
64. 3 O2(g) 2 O3(g)
for the above reaction at 298 K, KC is found to be 3.0 × 10–59. If the concentration of O2 at
equilibrium is 0.040 M then concentration of O3 in M is
(A) 2.4 × 1031 (B) 1.2 × 1021 (C) 4.38 × 10–32 (D) 1.9 × 10–63
65. For a reaction at equilibrium
1
A (g) B(g) + C(g)
2
the relation between dissociation constant (K), degree of dissociation (a) and equilibrium pressure
(p) is given by :
1 3 3 1
a 2 p2 a 2p2
(A) K = 1
(B) K = 1
æ 3 ö2 (2 + a )2 (1 – a )
1 + a ÷ (1 – a )
èç 2 ø
3 3
( a p)2 (a p)2
(C) K = 1
(D) K = 1
æ 3 ö2 (1 + a )(1 – a )2
çè1 + a ø÷ (1 – a )
2
66. Ka , Ka and Ka are the respective ionization constants for the following reactions (a), (b) and (c)
1 2 3
(a) H2C2O4 H+ + HC2O–4
(b) HC2O–4 H+ + HC2O–42
(c) H2C2O4 2H+ + C2O24–
The relationship between Ka , Ka and Ka isgiven as .......
1 2 3
(A) Ka = Ka + Ka (B) Ka = Ka – Ka (C) Ka = Ka / Ka (D) Ka = Ka ´ Ka
3 1 2 3 1 2 3 1 2 3 1 2
67. In base vs. Acid titration, at the end point methyl orange is present as .........
(A) quinonoid form (B) heterocyclic form (C) phenolic form (D) benzenoid form
Wish You - All The Best
In base vs. Acid titration, at the end point methyl orange is present as .........
(A) quinonoid form (B) heterocyclic form (C) phenolic form (D) benzenoid form
68. 25 mL buffer solution is prepared by mixing CH3COOH of concentration 0.1 M and CH3COONa of
concentration 0.01 M. If the pH of the solution is 5, then calculate the pKa of CH3COOH.
Student Name : _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
Roll Number : 0 1 2 0 1 2 3 4 5 6 7 8 9 0 1 2 3 4 5 6 7 8 9
A B C D A B C D A B C D
1. 21. 41.
2. 22. 42.
3. 23. 43.
4. 24. 44.
5. 25. 45.
6. 26. 46.
7. 27. 47.
8. 28. 48.
9. 29. 49.
19. 39.
20. 40.
Namra
Chapter : Equilibrium Std 11 : Chemistry Date : 09/03/24
Total Marks : 58 Unit Test Time : 01 Hour
Marks Identifier :
A B C D A B C D A B C D
1. 21. 41.
2. 22. 42.
3. 23. 43.
4. 24. 44.
5. 25. 45.
6. 26. 46.
7. 27. 47.
8. 28. 48.
9. 29. 49.
19. 39.
20. 40.
Namra
Chapter : Equilibrium Std 11 : Chemistry Date : 09/03/24
Unit Test
Section A
//X
• Write the answer of the following questions. [Each carries 1 Mark] [69]
1.
2.
3.
4.
5.
7.
8.
9.
10.
12.
13.
15.
16.
18.
19.
21.
22.
24.
25.
26.
27.
29.
30.
31.
32.
33.
35.
36.
38.
39.
40.
42.
44.
45.
47.
49.
50.
51.
53.
54.
56.
57.
59.
60.
62.
64.
66.
68.
69.