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Guided Revision Plan 1
PHYSICAL CHEMISTRY
GUIDED REVISION PLAN-SCORE ADVANCED
Topic : Atomic Structure (Question Bank # 12)
MM : 81 Time : 45 Min.
SECTION–I : (i) Only One option correct Type
This section contains 9 multiple choice questions. Each question has four choices (A), (B), (C) and
(D) out of which ONLY ONE is correct. 3(–1)
1. The wavelength of K-characteristic X-rays produced is , when cathode rays strike a metal of atomic
number Z. What should be the atomic number of metal such that it can produce the K-characteristic
X-rays of wavelength 4?

Z Z
(A) (B)
16 2

Z 1
(C) (D) 2Z – 1
2
2. According to Maxwell's theory of electrodynamics, an electron going in a circle should emit radiation
of frequency equal to its frequency of revolution. What should be the wavelength of the radiation
emitted by a hydrogen atom in the ground state if this rule is followed?
(A) 4500 nm (B) 450 nm
(C) 45 nm (D) 4.5 nm
3. An electron revolving around H-nucleus in ground state absorbs 10.2 eV energy. Its angular momentum
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increases by

h h
(A) (B)
2 
2h h
(C) (D)
 4
4. In a hydrogen like species , an electron jumps from an orbital having two radial and two angular nodes
to the orbital having same sign of wave function in all direction, at any distance. If the energy of emitted
photon is 326.4 eV, the atom or ion is
(A) H (B) Li2+
(C) He+ (D) B4+
5. O2 undergoes photochemical dissociation into one normal oxygen atom and one oxygen atom, 1.2
eV more energetic than normal. The dissociation of O2 into two normal atoms of oxygen requires
482.5 kJ/mol. The maximum wavelength effective for photochemical dissociation of O2 is
(1 eV = 96.5 kJ/mol)
(A) 248 nm (B) 1033.3 nm (C) 1236.2 nm (D) 200 nm

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2 JEE-Chemistry
6. The given diagram shows points P1, P2 P3 & P4 in 1s orbital.

The correct order of radial probability density at these point are

(A) P1 = P2 = P4 > P3
(B) P1 = P3 < P2 = P4
(C) P1 = P3 > P2 = P4
(D)P1 = P2 = P4 < P3
7. Which electronic level would allow the hydrogen atom to absorb a photon but not to emit a photon
(A) 3s (B) 2p
(C) 2s (D) 1s
8. Assuming Heisenberg Uncertainity Principle to be true what could be the minimum uncertainty in
de-broglie wavelength of a moving electron accelerated by Potential Difference of 6 V whose

7
uncertainty in position is n.m.
22

(A) 6.25 Å (B) 6 Å

(C) 0.625 Å (D) 0.3125 Å
9. A light source of wavelength  illuminates a metal and ejects photo-electrons with (KE)max = 1 eV.

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
Another light source of wavelength, , ejects photo-electrons from same metal with (KE)max = 4
3
eV. Find the value of work function ?
(A) 1 eV (B) 2 eV
(C) 0.5 eV (D) None of these

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Guided Revision Plan 3
(ii) One or more options correct Type
This section contains 5 multiple choice questions. Each question has four choices (A), (B), (C) and
(D) out of which ONE or MORE are correct. 4(–1)
h
10. The orbital angular momentum of an electron in a single electron system is 3 . Which of the

following angular momentum value (s) are not possible for this electron in Bohr orbit.
3h h
(A) (B)
2 
3h 2h
(C) (D)
 
11 For He+ ion, select incorrect option(s) :
(A) Difference between radius of II & III Bohr's orbit is greater than that of III & IV Bohr orbit.
(B) Ratio of velocity of electron in III & IV Bohr's orbit is less then one.
(C) Energy difference between consecutive energy levels decreases continuously.
(D) Ratio of wavelength of least energetic and most energetic photon of lyman series is (3/4).
12. Which of the following orbitals has (have) two spherical nodes?
(A) 2s (B) 4p
(C) 3d (D) 6 f
13. Orbitals in which the numbers of radial and angular nodes are equals?
(A) 3p (B) 4d
(C) 5d (D) 6f
14. When photons of energy 4.25 eV strike the surface of a metal 'A', the ejected photo electrons
if maximum kinetic energy have wavelength  A . The maximum kinetic energy of
photoelectrons liberated from another metal 'B' by photons of energy 4.7 eV is 1.5 eV
less than that of photo electrons of metal A. If wavelength of photo electrons of metal
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B is twice than that of photoelectron of 'A' then -

(A) Work function of A = 2.25 eV
(B) Work function of B = 4.2 eV
(C) Maximum (K.E.) of photoelectrons of 'A' = 2 eV
(D) Maximum (K.E.) of photoelectrons of 'B' = 2.75 eV

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4 JEE-Chemistry
(iii) Paragraph Type
This section contains 2 paragraphs , describing theory, experiment, data etc. 6 questions relate
to 2 paragraphs with 3 questions. Each question of a paragraph has only one correct answer among
the four choices (A), (B), (C) and (D). 3(0)
Paragraph for questions 15 to 17
The hydrogen-like species Li2+ is in a spherically symmetric state S1 with one radial node. Upon
absorbing light the ion undergoes transition to a state S2. The state S2 has one radial node and its
energy is equal to the ground state energy of the hydrogen atom.
15. The state S1 is :-
(A) 1s (B) 2s (C) 2p (D) 3s
16. Energy of the state S1 in units of the hydrogen atom ground state energy is :-
(A) 0.75 (B) 1.50 (C) 2.25 (D) 4.50
17. The orbital angular momentum quantum number of the state S2 is :-
(A) 0 (B) 1 (C) 2 (D) 3
Paragraph for question nos. 18 to 20
The location of electron inside the atom can be predicted by wave mechanical model which gives
wavefunction of orbitals represented as n,,m where n,, m represents quantum numbers
sometimes,  can be analysed as two separate components , radial and angular, represented as (r)
and () respectively for H, the following expressions of n,,m are known
2r
[Where a0 is constant and  is na ]
0

3/2
2 1  1
1,0,0 
a 3/0 2
e  / 2
3,0,0 
9 3  a 0 
 6  6    e2  / 2

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3/ 2 3/2
1 1 1 1
 2,0,0   2   e  / 2
3,1,0   4    e  / 2
2 2  a 0  9 3  a 0 
18. For 1 s orbital H-atom, the radial probability will be maximum at what radial distance from nucleus:
(A) r = 0 (at the nucleus) (B) r = 
(C) r = a0 (D) r = 2a0
19. At what radial distance will there be a spherical node for 3py orbital of hydrogen?
(A) r = 6a0 (B) r = 2a0 (C) r = 0 (D) data is insufficient.
20. Which of the following statements are incorrect w.r.t. (r) v/s r graph for H-atom
(A) For 1s orbital the graph will not intersect x - axis at finite distance.
(B) For 2s orbital, the graph will have one 'local minima' only.
(C) For 3s orbital, the graph will intersect x - axis at two distinct points.
(D) For 3p orbital, the graph will intersect x-axis at two non-zero distinct points.

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Guided Revision Plan 5
SECTION-II: (Integer Second Decimal)
 This section contains 3 questions.
 The answer to each question is a NUMERICAL VALUE.
 For each question, enter the correct numerical value (If the numerical value has more
than two decimal places, truncate/round-off the value to TWO decimal places; e.g. 6.25,
7.00, –0.33, –.30, 30.27, –127.30, if answer is 11.36777..... then both 11.36 and 11.37 will
be correct) by darken the corresponding bubbles in the ORS.
For Example : If answer is –77.25, 5.2 then fill the bubbles as follows.
+ – + –
0 0 0 0 • 0 0 0 0 0 0 • 0 0
1 1 1 1 • 1 1 1 1 1 1 • 1 1
2 2 2 2 • 2 2 2 2 2 2 • 2 2
3 3 3 3 • 3 3 3 3 3 3 • 3 3
4 4 4 4 • 4 4 4 4 4 4 • 4 4
5 5 5 5 • 5 5 5 5 5 5 • 5 5
6 6 6 6 • 6 6 6 6 6 6 • 6 6
7 7 7 7 • 7 7 7 7 7 7 • 7 7
8 8 8 8 • 8 8 8 8 8 8 • 8 8
9 9 9 9 • 9 9 9 9 9 9 • 9 9

 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If ONLY the correct numerical value is entered as answer.
Zero Marks : 0 In all other cases.
1. How many non-spherical orbitals are possible that have atleast two maxima if a curve is plotted
between radial probability distribution function versus radial distance for which principal quantum number:
n  4?
2. If 4 times the most probable distance of electron of a 1s orbital in a unielectronic atom /ion is given
by 0.529 Å then the atomic number of the unielectronic species will be.
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 Z 3   Zr / a0
[Given : Wave function of 1s orbital,    a 3  e where a0 = radius of first Bohr's orbital in
0

H  atom   52.9pm  and Z is atomic number of unielectrnic species ]

3. Find the number of spectral lines in Paschen series emitted by atomic H, when electron is excited
from ground state to 7th energy level returns back.

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6 JEE-Chemistry
SECTION-IV : (Matrix Type)
This Section contains 1 question. Question has four statements (A, B, C and D) given in Column I
and five statements (P, Q, R, S and T) in Column II. Any given statement in Column I can have correct
matching with ONE or MORE statement(s) given in Column II. For example, if for a given question,
statement B matches with the statements given in Q and R, then for the particular question, against
statement B, darken the bubbles corresponding to Q and R in the ORS. 8(0)
1. Match the column -

Column-I Column-II

(A) l (P) Indicates the distance from nucleus

(B) s (Q) It can have only two possible values.

(C) m (R) Possible values are 0 to (n – 1)

(D) n (S) Indicates the possible orientations in space.

(T) Possible values are +l to –l including ‘Zero’

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Guided Revision Plan 7

ANSWER KEY
SECTION–I : (i) Only One option correct Type 3(–1)
1. Ans.(C) 2. Ans.(C) 3. Ans.(A) 4. Ans.(D)

5. Ans.(D) 6. Ans.(C) 7. Ans.(D) 8. Ans.(C)

9. Ans.(C)
(ii) One or more options correct Type 4(–1)
10. Ans.(A,B) 11. Ans.(A,B,D) 12. Ans.(B,D) 13. Ans.(A,C)
14. Ans.(A,B,C)
(iii) Paragraph Type 3(0)
15. Ans.(B) 16. Ans.(C) 17. Ans.(B) 18. Ans.(C)
19. Ans.(C) 20. Ans.(D)
SECTION-II: (Integer Second Decimal)
1. Ans.(11.00) 2. Ans.(4.00) 3. Ans.(4.00)
SECTION-IV : (Matrix Type)
1. Ans(A) - R ; (B) - Q ; (C) - S, T ; (D) - P
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