As NZS 3750-3-2008 Paints For Steel

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AS/NZS 3750.

3:2008
AS/NZS 3750.3:2008

Australian/New Zealand Standard™

Paints for steel structures

Part 3: Heat resisting—Exterior


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AS/NZS 3750.3:2008
This Joint Australian/New Zealand Standard was prepared by Joint Technical
Committee CH-003, Paints and Related Materials. It was approved on behalf of the
Council of Standards Australia on 19 March 2007 and on behalf of the Council of
Standards New Zealand on 3 March 2007.
This Standard was published on 19 May 2008.

The following are represented on Committee CH-003:

AUSTROADS
Australasian Corrosion Association
Australian Paint Approval Scheme
Australian Paint Manufacturers’ Federation
Australian Pipeline Industry Association
Business New Zealand
Engineers Australia
Institution of Professional Engineers New Zealand
Master Painters Australia
Master Painters New Zealand Association
National Association of Testing Authorities Australia
Water Corporation Western Australia

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This Standard was issued in draft form for comment as DR 04188.


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AS/NZS 3750.3:2008

Australian/New Zealand Standard™

Paints for steel structures

Part 3: Heat resisting—Exterior

Originated as AS/NZS 3750.3:1994.


Second edition 2008.

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COPYRIGHT
© Standards Australia/Standards New Zealand
All rights are reserved. No part of this work may be reproduced or copied in any form or by
any means, electronic or mechanical, including photocopying, without the written
permission of the publisher.
Jointly published by Standards Australia, GPO Box 476, Sydney, NSW 2001 and Standards
New Zealand, Private Bag 2439, Wellington 6020

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AS/NZS 3750.3:2008 2

PREFACE
This Standard was prepared by the Joint Standards Australia/Standards New Zealand
Committee CH-003, Paints and Related Materials to supersede AS/NZS 3750.3:1994. It
forms part of a series of product Standards for paints referred to in AS/NZS 2312, Guide to
the protection of structural steel against atmospheric corrosion by the use of protective
coatings.
See AS/NZS 3750.0 for other published Standards is this series.
The terms ‘normative’ and ‘informative’ have been used in this Standard to define the
application of the appendix to which they apply. A ‘normative’ appendix is an integral part
of a Standard, whereas an ‘informative’ appendix is only for information and guidance.

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3 AS/NZS 3750.3:2008

CONTENTS

Page

SECTION 1 SCOPE AND GENERAL


1.1 SCOPE ........................................................................................................................ 4
1.2 REFERENCED DOCUMENTS .................................................................................. 4
1.3 DEFINITIONS ............................................................................................................ 4
1.4 SAFETY REQUIREMENTS ....................................................................................... 5

SECTION 2 MATERIALS REQUIREMENTS


2.1 GENERAL .................................................................................................................. 6
2.2 CONDITIONS OF TEST............................................................................................. 6
2.3 LIQUID PAINT........................................................................................................... 6
2.4 APPLICATION PROPERTIES ................................................................................... 7
2.5 APPLIED FILM .......................................................................................................... 7

SECTION 3 PACKAGING AND LABELLING


3.1 PACKAGING............................................................................................................ 10
3.2 LABELLING............................................................................................................. 10

APPENDICES
A PURCHASING GUIDELINES.................................................................................. 11
B GUIDANCE ON THE USE AND APPLICATION OF HEAT RESISTING
PAINTS ..................................................................................................................... 12
C REFERENCED DOCUMENTS ................................................................................ 14
D PREPARATION OF TEST PANELS ........................................................................ 16

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STANDARDS AUSTRALIA/STANDARDS NEW ZEALAND

Australian/New Zealand Standard


Paints for steel structures

Part 3: Heat resisting—Exterior

SECT ION 1 SCOPE AND GENERA L

1.1 SCOPE
This Standard sets out requirements for single- and multi-component primers and finishing
coats for the protection of steel against atmospheric corrosion at elevated temperatures.
Paints specified in this Standard include those described as Paint References C27, C31
and C35 in AS/NZS 2312.
Temperature resistance, colour range, gloss level and drying times vary significantly
according to type. These products can normally be applied by brush, roller or spray
although airless spray application is not suitable for some types. Abrasive blast cleaning is
the preferred method of surface preparation, however hand or power tool cleaning may be
acceptable for some products that are exposed at lower temperatures. Some products require
the application of heat to achieve their full resistance properties.
NOTES:
1 These paints may be used for the appropriate systems detailed in AS/NZS 2312.
2 Appendix A provides recommendations on information which should be provided by the
purchaser at the time of enquiry or order.
3 Additional information on the use and application of heat resisting paints is contained in
Appendix B.
4 Some products covered by this Standard may be particularly prone to discolouration or
damage due to atmospheric contamination where there are acid or alkaline conditions, and the
manufacturer’s advice should be sought.

1.2 REFERENCED DOCUMENTS


A list of the documents referred to in this Standard is contained in Appendix C.

1.3 DEFINITIONS
For the purpose of this Standard, the definitions given in AS/NZS 2310 and those below
apply.
1.3.1 Type 1 product
A single-component silicone acrylic paint, classed as Paint Reference C27 in AS/NZS 2312,
which is available in a limited colour range and intended as a finishing coat over inorganic
zinc silicate primer. It provides a decorative appearance with heat resistance to a continuous
temperature of 200°C and for limited periods at 230°C.
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1.3.2 Type 2 product


A single-component coumarone indene/oleoresinous aluminium paint, intended as a
finishing coat for application in two coats over oleoresinous zinc dust primer (see
Clause 1.3.4), providing weather resistance and heat resistance to 230°C.

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1.3.3 Type 3 product


A two-component oleoresinous zinc dust priming paint, generally of grey colour, for use
under aluminium paint (see Clause 1.3.2), providing corrosion resistance and heat
resistance to 230°C. It may also be used as a two-coat system without a topcoat.
NOTE: Under some circumstances it may be used over hand or power tool cleaned surfaces.
1.3.4 Type 4 product
A two-component oleoresinous zinc dust graphite paint, generally of grey colour for use as
a two- or three-coat self-finish system, providing both corrosion resistance and heat
resistance for operating temperatures up to 450°C. It may require heating to achieve full
cure.
NOTE: Suitable for application to power or hand tool cleaned substrates but not suitable for acid
or alkaline environments.
1.3.5 Type 5 product
A single-component silicone paint, classed as Paint Reference C31 in AS/NZS 2312,
available in a limited range of colours, usually aluminium or black, for application in one or
two coats over inorganic zinc silicate primer, providing heat resistance up to 480°C.
Following normal air drying for 6 h, it requires the initial application of heat to ensure
proper hardness and weather resistance, following which it is suitable for temperatures up
to 480°C.
NOTE: With the exception of aluminium, such paints have a good resistance to acid and alkaline
environments. They may also be applied over silicone-based primer.
1.3.6 Type 6 product
An aluminium pigmented butyl titanate paint classed as Paint Reference C35 in
AS/NZS 2312, for application in two coats over inorganic zinc silicate primer, providing
heat resistance to 480°C. It may also be applied over aluminium metal spray for heat
resistance up to 650°C.

1.4 SAFETY REQUIREMENTS


Health and safety aspects referenced in Section 13 of AS/NZS 2312 should be followed in
conjunction with the manufacturer’s safety data sheets (MSDSs).
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SECT I ON 2 MA T E R I A L S RE Q U I RE M E N T S

2.1 GENERAL
The paint shall comply with the requirements detailed in Clauses 2.2 to 2.5. These
properties and requirements are summarized in Table 1.

2.2 CONDITIONS OF TEST


Unless otherwise specified in this Standard, the following test conditions apply:
(a) The test panel material and its preparation shall be in accordance with Appendix D.
(b) The size of test panels shall be as specified in Table 1.
(c) Conditions for testing shall be in accordance with AS/NZS 1580.101.5.
(d) The spreading rate of paint shall be such that when applied by conventional spraying
it shall result in a dry film thickness specified on the manufacturer’s data sheet for
that product, as determined by either AS/NZS 1580.108.1 or AS 1580.108.2.
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(e) Conditions for air drying shall be in accordance with AS/NZS 1580.101.1.

2.3 LIQUID PAINT


2.3.1 Condition in container
When examined in accordance with AS/NZS 1580.103.1 at the time of delivery from the
manufacturer or supplier, the liquid components of these paints shall be free from gel,
coarse particles, skin and foreign matter. They shall readily yield a product of uniform
consistency when manually incorporated in accordance with AS/NZS 1580.211.2.
2.3.2 Density
When determined in accordance with AS/NZS 1580.202.1, the density of the paint shall be
within 5 percent of the value of the manufacturer’s specification.
2.3.3 Consistency
When determined in accordance with the appropriate method chosen from
AS/NZS 1580.214.1, AS/NZS 1580.214.2, AS 1580.214.3, AS/NZS 1580.214.4 or
AS/NZS 1580.214.5, the consistency shall be within 5 percent of the manufacturer’s
specification.
2.3.4 Storage properties
2.3.4.1 Degree of settling
When stored under cover in the original unopened containers for 12 months from the date of
manufacture, at a temperature of 23 ±3°C, the rating for settling of the liquid components,
when determined in accordance with AS/NZS 1580.211.1, shall be not less than 6.
2.3.4.2 Re-incorporation after storage
When stored under cover in original unopened containers for 12 months from the date of
manufacture, at a temperature of 23 ±3°C, and tested in accordance with
AS/NZS 1580.211.2, the liquid components shall be readily re-incorporated, produce a
paint of uniform consistency and be free from lumps, gel and other defects.

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2.4 APPLICATION PROPERTIES


2.4.1 General
The applied film shall be free from defects when applied in accordance with the
manufacturer’s recommended methods of application. (See Clauses 2.4.2 to 2.4.4.)
2.4.2 Brushing
When applied to a vertical test panel in accordance with AS/NZS 1580.205.1, the test paint
shall exhibit satisfactory brushing properties and be free from visible defects.
2.4.3 Rolling
When applied to a vertical test panel in accordance with AS/NZS 1580.205.3, the test paint
shall exhibit satisfactory rolling properties and be free from visible defects.
2.4.4 Spraying
When thinned in accordance with the manufacturer’s instructions and applied to a vertical
test panel in accordance with AS/NZS 1580.205.2, the test paint shall exhibit good spraying
properties and be free from visible defects.

2.5 APPLIED FILM


2.5.1 Surface dry time
When the paint has been applied to a steel test panel at the appropriate dry film thickness
and tested in accordance with AS/NZS 1580.401.1, it shall have a surface dry time
appropriate for the product type (refer to Appendix B).
2.5.2 Hard dry time
When the paint has been applied to a steel test panel at the appropriate dry film thickness,
and tested in accordance with AS 1580.401.5, it shall have a hard dry time appropriate for
the product type (refer to Appendix B).
2.5.3 Heat resistance—Slow cooling
When the paint or paint system is applied to a steel test panel at the appropriate dry film
thickness modified as stated below, at the maximum recommended temperature for that
product type, there shall be no cracking, peeling, flaking or other defect upon cooling. For
the purpose of this Clause, the oven heating period shall be increased from 4 h to 24 h, and
the bend test from AS 1580.402.1 is not required.
NOTE: Due to the characteristics of some of the paints included in heat resisting paint systems,
the bend test requirement of this test is not appropriate to most of the paint systems involved in
this Standard.
When the treated test panel is tested in accordance with AS 1580.408.2, a rating not greater
than 1 shall be achieved.
NOTE: A rating of 0 implies no loss of adhesion.
When tested in accordance with AS/NZS 1580.601.1 after completion of the heating period,
the test panel shall exhibit an approximate match to an unheated coated reference panel.
2.5.4 Heat resistance—Thermal shock
When the paint or paint system is applied to a steel test panel at the appropriate dry film
thickness at the maximum recommended temperature for that product type, there shall be no
cracking or other defect upon cooling. For the purposes of this Clause, the bend test from
AS 1580.402.1 is not required.
NOTE: Due to the characteristics of some of the paints included in heat resisting paint systems,
the bend test requirement of this test is not appropriate to most of the paint systems involved in
this Standard.

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2.5.5 Resistance to weathering


The paint shall have a satisfactory resistance to weathering. This shall be clearly and
adequately demonstrated, by at least two documented case histories that confirm
satisfactory performance for a minimum of four years in a moderate or more severe
environment. One of these case histories shall demonstrate satisfactory performance at
continuously elevated temperatures at or near the recommended maximum. The other shall
demonstrate satisfactory performance in temperatures cycling between near ambient and the
maximum recommended temperature.
A satisfactory performance is one where the paint (system) has not allowed any integrity
failure, i.e., no cracking, flaking, blistering or rusting and in a visual assessment of erosion,
there shall not be any grinning through.
NOTE: Because of the specialized performance characteristics of these paints, weathering tests in
accordance with AS/NZS 1580.457.1 are not considered appropriate due to their inability to
simulate the high temperatures involved.
2.5.6 Finish
When a steel test panel prepared in accordance with Clause 2.4.4 is allowed to air-dry for
7 d and is examined in accordance with AS 1580.603.1, the film shall be of uniform colour
and appearance and be free of film defects.

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TABLE 1
SUMMARY OF RECOMMENDATIONS FOR HEAT RESISTING PAINTS
Typical test panel
Clause Minimum
Property assessed Acceptable performance Test method
number Material dimensions
(mm)
2.3.1 Condition in container Free of gel, coarse particles, skin AS/NZS 1580.103.1
and foreign matter
Uniform consistency after N/A* —
manual reincorporation AS/NZS 1580.211.2
2.3.2 Density Within 5 percent of AS/NZS 1580.202.1 N/A* —
manufacturer’s specification
2.3.3 Consistency Within 5 percent of AS/NZS 1580.214.1 N/A* —
manufacturer’s specification AS/NZS 1580.214.2
AS 1580.214.3
AS/NZS 1580.214.4
AS/NZS 1580.214.5
2.3.4 Storage properties Settlement ≥6 AS/NZS 1580.211.1 N/A* —
(12 months) Uniform consistency free of
lumps, gel and other defects AS/NZS 1580.211.2
2.4 Application properties No run, sag, streak, excessive AS/NZS 1580.205.1 Steel 500 × 500
roughness, or grittiness AS/NZS 1580.205.2
AS/NZS 1580.205.3
2.5.1 Surface dry Refer Appendix B AS/NZS 1580.401.1 Steel 150 × 100
2.5.2 Hard dry time Refer Appendix B AS 1580.401.5 Steel 150 × 100
2.5.3 Heat resistance No cracking, flaking, peeling or Steel 100 × 50
—slow cooling other defect
Adhesion ≤1 AS 1580.408.2
Colour Approximate match AS/NZS 1580.601.1
2.5.4 Heat resistance No cracking, flaking, peeling or Visual inspection Steel 100 × 50
—thermal shock other defect
2.5.6 Finish Uniform colour and appearance, AS 1580.603.1 Steel 500 × 500
free of film defects
* N/A = Not applicable

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SECT ION 3 PACKAG I NG AND L A B E L L I N G

3.1 PACKAGING
Paints should be packaged in clean and dry containers constructed of materials which are
inert to the contents and sufficiently robust to withstand normal conditions of handling and
storage without rupture or leakage. The containers should be capable of being readily
resealed so as to be gastight.
Containers are to comply with statutory requirements relevant to the transport and storage
of flammable liquids, as specified in the current edition of the ADG Code.
NOTES:
1 AS 2854 and AS 2905 specify suitable containers for paints and related materials.
2 The ADG Code does not apply in New Zealand. In New Zealand, refer to NZS 5433.

3.2 LABELLING
The following information shall be legibly and durably marked on each container, or on a
label permanently attached to each container:
(a) The name or registered mark of the manufacturer.
(b) The words ‘Heat Resisting Paint for Steel’ or equivalent wording.
(c) The type of heat resisting paint and the manufacturer’s specified maximum
temperature resistance.
(d) The contents of the container by volume, in litres.
(e) Where appropriate, a statement that the paint is a two-component material.
(f) The production or batch number of the contents that can be traced back to the date of
manufacture.
(g) Information required by relevant regulatory authorities.
(h) Guidance on the use of the paint.
NOTE: Manufacturers making a statement of compliance with this Australian/New Zealand
Standard on a product, packaging, or promotional material related to that product are advised to
ensure that such compliance is capable of being verified.

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APPENDIX A
PURCHASING GUIDELINES
(Informative)

A1 GENERAL
Australian Standards are intended to include the technical requirements for relevant
product(s) referred to in a particular Standard but do not purport to comprise all the
necessary provisions of a contract. This Appendix contains advice and recommendations on
information to be supplied by the purchaser at the time of enquiry or order.

A2 INFORMATION TO BE SUPPLIED WITH THE ENQUIRY OR ORDER


At the time of enquiry or order, the following information should be supplied by the
purchaser:
(a) Reference number and title of the Standard, i.e., AS/NZS 3750.3, Paints for steel
structures—Heat resisting—Exterior.
(b) The type of paint required (i.e., Type 1–6), the temperature resistance required and

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the probable environmental conditions.
(c) Colour of the dry film, preferably in terms of an established colour Standard such as
AS 2700S or NZ/BS 4800.
(d) Quantity to be delivered.
(e) Pack size, in litres.
(f) Any special packaging and marking requirements.
(g) Delivery information.
(h) Whether a certificate of compliance is required.

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APPENDIX B
GUIDANCE ON THE USE AND APPLICATION OF HEAT RESISTING PAINTS
(Informative)

B1 SCOPE
This Appendix provides guidance on the use and application of heat resisting paints.

B2 MANUFACTURER’S TECHNICAL DATA


Before opening the containers for use, the manufacturer’s technical data sheets and label
instructions should be studied.

B3 SAFETY PRECAUTIONS
The manufacturer’s material safety data sheets (MSDS) for the product should be consulted
and followed. These paints or their components require adequate care when being handled.
Some individuals may show some allergic reaction to them and should not continue to
handle such products. The majority of people are unaffected by contact with these
materials.
All personnel should be protected during mixing and application from skin contact, spray
dust and eye splashing by use of protective equipment and clothing. Any accidental spillage
on the skin should be removed with soap and water or an industrial skin cleaner. Solvent
should not be used as this promotes penetration into the pores of the skin.
As these paints contain flammable solvents, they should not be applied near naked flames.
Attention is drawn to the need to observe the relevant statutory regulations where they
apply.

B4 TYPICAL USES
The main purpose of the paint systems covered by this Standard is to provide a decorative
appearance and impart corrosion protection to steelwork which is subjected to high
temperatures. These paints are intended for use on such structures as chimney stacks, heat
exchangers, hot process lines, kilns, incinerators, exhaust systems and steam pipes. Some
paint types may not be suitable for use in severe chemical environments.

B5 MIXING
Where the paint is a two-pack product, the two components should be mixed in the
manufacturer’s specified ratios and thoroughly blended before application. Only the
recommended thinners should be added to suit application requirements.
Heat resisting paints are special paints that are usually needed above 100°C. At elevated
temperatures, they are more resistant to expansion and contraction due to fluctuating
temperatures, the destructive attack of oxygen and shock from rain. Inorganic polymers
based on silicone or butyl titanate show the best resistance.
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B6 CURING
Most of these paints will cure satisfactorily at normal ambient temperature. However,
Type 5 (silicone aluminium) products require the application of heat at a specified rate to
achieve full curing. Failure to apply the required degree of heat within the specified time
may result in the paint not achieving its full corrosion resistance and decorative appearance.

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B7 POT-LIFE
Of the six paint types covered by this Standard, only Types 3 and 4 are two-pack materials.
For these two paints the pot-life is normally in the region of 24 to 48 h. The manufacturer
should be consulted for details and the paint not used after the recommended pot-life has
expired, as an unsatisfactory coating may result even though the paint appears usable. Thus,
freshly mixed paint should not be added to paint that is nearing the end of its pot-life as this
may deleteriously affect the properties of the paint.

B8 TYPICAL FILM THICKNESS


Dry film thickness will vary according to product type and manufacturer but the following
are indicative of the available products:
Type 1: 35 to 50 µm
Type 2: 25 to 35 µm
Type 3: 35 to 50 µm
Type 4: 35 to 50 µm

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Type 5: 25 to 35 µm
Type 6: 25 to 35 µm
Higher thicknesses should be avoided to prevent cracking at the operating temperatures.

B9 TYPICAL DRYING TIME


Drying time will vary considerably according to the product type and the manufacturer;
however, the following are indicative drying times:

Surface dry time Hard dry time Minimum


Type recoat time
h h h
1 1 16 2 (spray)
16 (brush)
2 2 8 16
3 1 16 24
4 12 Upon heating 24
5 2 Upon heating —
6 1 — 16

B10 STORAGE CONDITIONS


When stored under cover in unopened containers in industrial situations, the paints or
components should have a storage life of at least 12 months from date of manufacture.
Containers should preferably be stored out of direct sunlight away from heat and water.
Because the paints contain flammable solvents, they should not be stored near naked flame.

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APPENDIX C
REFERENCED DOCUMENTS
(Normative)
AS
1580 Paints and related materials
1580.108.2 Method 108.2: Dry film thickness—Paint inspection gauge
1580.214.3 Method 214.3: Viscosity—Cone-and-plate
1580.401.5 Method 401.5: Hard dry condition—Sanding test
1580.402.1 Method 402.1: Bend test
1580.408.2 Method 408.2: Adhesion—Knife test
1580.481.1 Method 481.1: Coatings
1580.603.1 Method 603.1: Finish—General appearance
1627 Metal finishing—Preparation and pretreatment of surfaces
1627.4 Part 4: Abrasive blast cleaning of steel
2700S Colour Standards for general purposes—Swatches
2854 Tinplate cans for general use
2905 Steel drums
AS/NZS
1580.101.1 Method 101.1: Conditions of test—Temperature, humidity and airflow
control
1580.101.5 Method 101.5: Conditions of test—Temperature and humidity control
1580.103.1 Method 103.1: Examination and preparation of samples for testing
1580.104.1 Method 104.1: Recommended materials for test panels
1580.108.1 Method 108.1: Determination of dry film thickness on metallic
substrates—Non-destructive methods
1580.202.1 Method 202.1: Density
1580.205.1 Method 205.1: Application properties—Brushing
1580.205.2 Method 205.2: Application properties—Conventional spraying
1580.205.3 Method 205.3: Application properties—Roller coating
1580.211.1 Method 211.1: Degree of settling
1580.211.2 Method 211.2: Ease of manual re-incorporation
1580.214.1 Method 214.1: Consistency—Stormer viscometer
1580.214.2 Method 214.2: Consistency—Flow cup
1580.214.4 Method 214.4: Consistency—Rotothinner
1580.214.5 Method 214.5: Consistency—Rotational viscometer
1580.401.1 Method 401.1: Surface dry condition
1580.457.1 Method 457.1: Resistance to natural weathering
1580.601.1 Method 601.1: Colour—Visual comparison
2310 Glossary of paint and painting terms
2312 Guide to the protection of structural steel against atmospheric corrosion by
the use of protective coatings
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ACTDG Advisory Committee for the Transport of Dangerous Goods


ADG Code Australian code for the transport of dangerous goods by road and rail
NZS
5433 Transport of dangerous goods on land

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15 AS/NZS 3750.3:2008

NZ/BS
4800 Schedule of paint colours for building purposes

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AS/NZS 3750.3:2008 16

APPENDIX D
PREPARATION OF TEST PANELS
(Normative)

D1 SCOPE
This Appendix sets out specifications and procedures for the coating of panels to assess the
properties of heat resisting paint.

D2 TEST PANEL MATERIAL


Test panels shall be of low carbon steel complying with AS/NZS 1580.104.1.

D3 COATING OF PANELS
The procedure shall be as follows:
(a) Blast clean the test panels to AS 1627.4, Class Sa 3 ‘white metal’ blast cleaning
requirements using fresh garnet abrasive blast material.
(b) If applicable, apply an appropriate primer by conventional spray.
NOTE: Type 1, 5 and 6 products are designed to be used over an inorganic zinc silicate, while
Type 2 products are designed for application over an oleoresinous zinc primer.
(c) Allow to air-dry in accordance with AS/NZS 1580.101.1 for 24 h.
(d) Apply the test paint by conventional spray, to the dry film thickness nominated on the
manufacturer’s data sheet for the product.
Any necessary thinning to achieve satisfactory application properties shall be strictly
in accordance with that specified on the manufacturer’s data sheet for that particular
product.
(e) Allow the panels to air-dry in accordance with AS/NZS 1580.101.1 for 7 days.
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Standards Australia
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Standards New Zealand


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