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    0062 J5tfc5kub

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    This safety data sheet provides information on SAF ACID, which is used for industrial metal cleaning. It lists sulphamic acid and magnesium oxide as main ingredients. The preparation is classified as irritating to eyes and skin, and harmful to aquatic organisms. It can cause irritation when inhaled, ingested, or in contact with skin or eyes. Proper personal protective equipment should be worn when handling, and the product stored in a cool, well-ventilated area.

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    0062 J5tfc5kub

    Uploaded by

    Nandar Min Htet
    4 views5 pages
    This safety data sheet provides information on SAF ACID, which is used for industrial metal cleaning. It lists sulphamic acid and magnesium oxide as main ingredients. The preparation is classified as irritating to eyes and skin, and harmful to aquatic organisms. It can cause irritation when inhaled, ingested, or in contact with skin or eyes. Proper personal protective equipment should be worn when handling, and the product stored in a cool, well-ventilated area.

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    0062.j5tfc5kub

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    This safety data sheet provides information on SAF ACID, which is used for industrial metal cleaning. It lists sulphamic acid and magnesium oxide as main ingredients. The preparation is classified as irritating to eyes and skin, and harmful to aquatic organisms. It can cause irritation when inhaled, ingested, or in contact with skin or eyes. Proper personal protective equipment should be worn when handling, and the product stored in a cool, well-ventilated area.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    4 views5 pages

    0062 J5tfc5kub

    Uploaded by

    Nandar Min Htet
    This safety data sheet provides information on SAF ACID, which is used for industrial metal cleaning. It lists sulphamic acid and magnesium oxide as main ingredients. The preparation is classified as irritating to eyes and skin, and harmful to aquatic organisms. It can cause irritation when inhaled, ingested, or in contact with skin or eyes. Proper personal protective equipment should be worn when handling, and the product stored in a cool, well-ventilated area.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 5

    Conforms to 91/155/EEC - 2001/58/EC - United Kingdom (UK)

    SAFETY DATA SHEET


    SAF ACID
    1. Identification of the substance/preparation and of the company/undertaking
    Product name : SAF ACID
    Material Uses : Industrial applications: Metal cleaning. Cleaning mineral deposits from boilers,
    piping, heat exchangers, etc.

    Manufacturer / Supplier :
    Drew Marine Drew Marine
    Ashland Specialty Chemical Company Ashland Specialty Chemical Company
    Malledijk 20 One Drew Plaza
    3208 LA Spijkenisse Boonton, NJ 07005
    Netherlands United States
    Tel. No.: Tel. No.:
    +31 181 457 070 +1 (973) 263 7600
    Fax: Fax:
    +31 181 625 792 +1 (973) 263 4491
    Emergency telephone number
    (Germany) : +49 621 60-43333
    Fax:
    (Germany) : +49 621 60-92664

    2. Composition/information on ingredients
    Substance/Preparation : Preparation

    Chemical name* CAS No. % EC Number Classification


    Sulphamic acid 5329-14-6 90-100 226-218-8 Xi; R36/38
    R52/53
    Magnesium oxide 1309-48-4 0.5-1 215-171-9
    See Section 16 for the full text of the R Phrases declared above

    * Occupational Exposure Limit(s), if available, are listed in Section 8

    3. Hazards identification
    The preparation is classified as dangerous according to Directive 1999/45/EC and its amendments.
    Classification : Irritant
    R36/38- Irritating to eyes and skin.
    R52/53- Harmful to aquatic organisms, may cause long-term adverse effects
    in the aquatic environment.
    Effects and symptoms
    Inhalation : Inhalation of dust will produce irritation to gastrointestinal or respiratory tract,
    characterized by burning, sneezing and coughing. Overexposure by inhalation
    may cause respiratory irritation.
    Ingestion : Ingestion may cause gastrointestinal irritation and diarrhoea.
    Skin contact : Hazardous in case of skin contact (irritant). Skin inflammation is
    characterized by itching, scaling, reddening, or, occasionally, blistering.
    Eye Contact : Hazardous in case of eye contact (irritant).
    Target Organs : Causes damage to the following organs: skin, eyes.
    Contains material which causes damage to the following organs: lungs, upper
    respiratory tract, eye, lens or cornea.

    Date of issue : 10/16/2002. Page: 1/5


    SAF ACID

    4. First-aid measures
    First-Aid measures
    Inhalation : If inhaled, remove to fresh air. If not breathing, give artificial respiration. If
    breathing is difficult, give oxygen. Obtain medical attention.
    Ingestion : Do NOT induce vomiting unless directed to do so by medical personnel.
    Never give anything by mouth to an unconscious person. Loosen tight clothing
    such as a collar, tie, belt or waistband. Get medical attention if symptoms
    appear.
    Skin contact : In case of contact, immediately flush skin with plenty of water. Cover the
    irritated skin with an emollient. Remove contaminated clothing and shoes.
    Cold water may be used. Wash clothing before reuse. Clean shoes
    thoroughly before reuse. Obtain medical attention.
    Eye Contact : Check for and remove any contact lenses. In case of contact, immediately
    flush eyes with a copious amount of water for at least 15 minutes. Cold water
    may be used. Obtain medical attention.

    5. Fire-fighting measures
    Extinguishing Media
    Suitable : Not applicable.
    Hazardous thermal (de)composition : These products are nitrogen oxides (NO, NO2...), sulphur oxides (SO2, SO3,
    products etc.), phosphates. Some metallic oxides.
    Protection of fire-fighters : Fire fighters should wear self-contained positive pressure breathing apparatus
    (SCBA) and full turnout gear.

    6. Accidental release measures


    Personal Precautions : Splash goggles. Dust respirator. Boots. Gloves.
    Environmental precautions and : Stop leak if without risk. Use water spray to reduce vapours. Prevent entry
    cleanup methods into sewers, basements or confined areas; dike if needed. Call for assistance
    on disposal.
    Note: See section 8 for personal protective equipment and section 13 for waste disposal.

    7. Handling and storage


    Handling : Keep container dry. Do not breathe dust. Wear suitable protective clothing. If
    ingested, seek medical advice immediately and show the container or the
    label. Keep away from incompatibles such as oxidizing agents, alkalis.
    Storage : Keep container tightly closed. Keep container in a cool, well-ventilated area.
    Packaging materials
    Recommended use : Use original container.

    8. Exposure controls/personal protection


    Engineering measures : Use process enclosures, local exhaust ventilation, or other engineering
    controls to keep airborne levels below recommended exposure limits. If user
    operations generate dust, fume or mist, use ventilation to keep exposure to
    airborne contaminants below the exposure limit.
    Hygiene measures : Wash hands after handling compounds and before eating, smoking, using
    lavatory, and at the end of day.
    Occupational Exposure Limits

    Date of issue : 10/16/2002. Page: 2/5


    SAF ACID

    Ingredient Name Occupational Exposure Limits


    Magnesium oxide EH40-OES (United Kingdom (UK), 2001). Notes: OES
    STEL: 10 mg/m3 Form: Dust and fumes
    TWA: 10 mg/m3 Form: Dust
    TWA: 4 mg/m3 Form: Dust and fumes

    Respiratory system : Wear appropriate respirator when ventilation is inadequate. Dust respirator.

    Skin and body : Synthetic apron.


    Hands : Impervious gloves.
    Eyes : Splash goggles.

    9. Physical and chemical properties


    Physical state : Solid. (Crystalline granules solid.)
    Colour : Green.
    Odour : Odourless.
    Melting point : Decomposition Temperature: 180 to 220°C (356 to 428°F)
    Density : 0.9 to 1.34 g/cm3 (20°C / 68°F)
    Vapour pressure : <0.0013 kPa (<0.01 mmHg) (at 20°C)
    Solubility : Soluble in cold water.
    pH : 1 to 2 [Acidic.]
    Flash point : Not applicable.

    10. Stability and reactivity


    Stability : The product is stable.
    Conditions to Avoid : Absorbs moisture on long-term storage under high humidity conditions.
    Materials to avoid : Reactive with oxidizing agents, alkalis.
    Incompatible with amines. Incompatible with halogens and aluminium.

    Hazardous decomposition products : These products are nitrogen oxides (NO, NO2...), sulphur oxides (SO2, SO3,
    etc.), phosphates. Some metallic oxides.

    11. Toxicological information


    Acute toxicity
    Ingredient Name Test Result Route Species
    Sulphamic acid LD50 3160 mg/kg Oral Rat
    LD50 1312 mg/kg Oral Mouse
    LD50 1050 mg/kg Oral Guinea pig

    Chronic toxicity : Repeated exposure of the eyes to a low level of dust can produce eye
    irritation. Repeated skin exposure can produce local skin destruction or
    dermatitis. Repeated inhalation of dust can produce varying degrees of
    respiratory irritation or lung damage.
    Skin irritation : Hazardous in case of skin contact (irritant).
    Eye irritation : Hazardous in case of eye contact (irritant).
    Carcinogenic effects : Not available.

    Mutagenic Effects : Not available.


    Reproduction toxicity : Not available.

    Date of issue : 10/16/2002. Page: 3/5


    SAF ACID

    12. Ecological information

    Persistence/degradability : Ecological testing has not been conducted on this product.

    13. Disposal considerations


    Methods of disposal ; Waste of : Waste must be disposed of in accordance with federal, state and local
    residues ; Contaminated packaging environmental control regulations.

    European Waste Catalogue (EWC) : 16 05 02


    Hazardous Waste : The classification of the product may meet the criteria for a hazardous waste.
    Additional Information : 16 05 02 other waste containing inorganic chemicals, e.g. lab chemicals not
    otherwise specified, fire extinguishing powders

    14. Transport information


    International transport regulations
    Land - Road/Railway
    UN number : 2967
    Proper shipping name : Sulphamic acid mixture
    ADR/RID Class : 8
    Packing group : III
    ADR/RID label :

    Other information : -
    Sea
    UN number : 2967
    Proper shipping name : Sulphamic acid mixture
    IMDG Class : 8
    Packing group : III
    IMDG label :

    Other information : Emergency Schedules (EmS)


    8-08

    15. Regulatory information


    EU Regulations
    Hazard symbol(s) :

    Irritant
    Risk Phrases : R36/38- Irritating to eyes and skin.
    R52/53- Harmful to aquatic organisms, may cause long-term adverse effects
    in the aquatic environment.

    Date of issue : 10/16/2002. Page: 4/5


    SAF ACID

    Safety Phrases : S37/39- Wear suitable gloves and eye/face protection.


    S56- Dispose of this material and its container at hazardous or special waste
    collection point.
    Product Use : Classification and labelling have been performed according to EU directives
    67/548/EEC, 88/379/EEC, including amendments and the intended use.
    - Industrial applications.

    16. Other information


    Full text of R-Phrases with no. : R36/38- Irritating to eyes and skin.
    appearing in Section 2 - United R52/53- Harmful to aquatic organisms, may cause long-term adverse effects
    Kingdom (UK) in the aquatic environment.
    Text of classifications appearing in : Xi - Irritant
    Section 2 - United Kingdom (UK)
    HISTORY
    Date of printing : 10/17/2002.
    Date of issue : 10/16/2002.
    Version : 3
    SAF-ACID™ is a trademark of Ashland Inc.
    Notice to Reader
    To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor
    any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained
    herein.
    Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown
    hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these
    are the only hazards that exist.
    Date of issue Version
    10/16/2002. 3 Page: 5/5

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