PYROVATEX CP - Change of Shade

Ciba® PYROVATEX® CP FINISH – CHANGE OF SHADE
Ciba® PYROVATEX® CP
– Durable flame retardant finish –
Change of shade
Textile Effects
Possible reasons for change shade and alteration of color:
• pH–value of the PYROVATEX CP bath: 3.1–3.5
• Alkaline wash-off process
• High curing temperatures
Textile Effects
Dyestuff recommendation and selection:
• Direct and sulfur dyestuffs showed very strong

shade changes
• Naphthol dyestuffs normally do not have

problems
• Vat, reactive and pigment dyestuffs are

recommended, see attached trials
Textile Effects
Change of shade and alteration of color
Recipe 1 (standard) Recipe 2 (CIBACRON C range only)
400 g/l PYROVATEX CP NEW 400 g/l PYROVATEX CP–LF

60 g/l LYOFIX CHN 60 g/l LYOFIX MLF NEW
40 g/l ULTRAREX FSA NEW 40 g/l ULTRAREX FSA NEW
22 g/l phosphoric acid 80% 22 g/l phosphoric acid 80%
5 g/l INVADINE PBN 5 g/l INVADINE PBN
curing: 4 min at 150°C curing: 4 min at 150°C

Wash-off: alkaline wash-off Wash-off: alkaline wash-off
Textile Effects
Reactive dyes – CIBACRON® C
Xenon light
CIBACRON Change of shade with
without CP-LF with CP-LF
PYROVATEX CP-LF finish (1/1 SD) (1/1 SD)
Yellow C-5G 4–5 5 4–5
Yellow C-R-01 4–5 6 6–7
Yellow C-RG 4–5 5–6 6
Yellow C -2R 4 5–6 4–5
Orange C-3R 2 4 5
Orange C-RN 4–5 4 3–4
Scarlet C-6G 4–5 4 3–4
Red C-2G 3–4 BW 4–5 4
Red C-GR 3B 4 3–4
Red C-R 4 BW 4–5 4
Red C-B 4–5 5 4
Y = yellower, greener R = redder B = bluer

Textile Effects
W = weaker De = deeper Du = duller Br = brighter
Reactive dyes – CIBACRON® C
Xenon light
without CP-LF with CP-LF
PYROVATEX CP-LF finish (1/1 SD) (1/1 SD)
Red C-2BL 1 5–6 6

Blue C-R 4 YW 7 6–7
Navy C-B 2R 4 3–4
Navy C-R 2–3 RW 4–5 3–4
Black C-NN hc. 3 5 (2/1) 5 (2/1)
Black C-2R 3–4 B 5 (2/1) 5 (2/1)
Orange BR 3–4 W 6 5
Blue 4R 3–4 R 6 6–7
Turquoise GN 4–5 5–6 4

Textile Effects
Reactive dyes – CIBACRON® FN / F / W
Xenon light
PYROVATEX CP NEW finish without CP with CP
(1/1 SD) (1/1 SD)
Yellow FN-2R 4 5–6 4–5

Orange FN-R 4–5 4 3–4
Red FN-3G 3–4 B 4 3
Red FN-R 4 BW 4–5 4
Red FN-2BL 1 5–6 6
Blue FN-R 4 YW 7 6–7
Brill. Blue FN-G 3–4 R 6–7 6–7
Navy FN-B 2R 4 3–4
Navy FN-GN 3 RW 4 (2/1) 4 (2/1)
Yellow NP 4 6–7 6

Textile Effects
Xenon light
without CP with CP
PYROVATEX CP NEW finish (1/1 SD) (1/1 SD)
Yellow F-3R 3–4 6 6–7

Yellow F-4G 4 5 4
Orange F-BR 3–4 6 5
Orange F-R 4–5 3–4 3–4
Scarlet F-3G 4 4 3–4
Red F-B 4 4–5 4
Blue F-R 3 6–7 6–7
Blue F-GFN 4 6 5–6
Navy F-G 1 4 3–4
Black F-2B 2 3–4 (2/1) 3–4 (2/1)

Textile Effects
Xenon light
without CP with CP
Yellow W-RN 200% 4–5 4–5 4–5

Orange W-3R 2 4 5
Red W-B 150% 3B 4 3–4
Dark Blue W-R 2–3 RW 5 3–4
Navy W-B 2–3 RW 4 3–4 R
Black W-NN hc. 3 4–5 (2/1) 3–4 (2/1)
Black W-HF 2–3 RW 4 (2/1) 3–4 (2/1)
Super Black G 3 4 (2/1) 3

Textile Effects
Reactive dyes – CIBACRON® LS
CIBACRON Change of shade with Xenon light

(1/1 SD) (1/1 SD)
Yellow LS-R 4–5 6 5–6
Yellow LS-4G 4–5 4–5 4
Orange LS-BR 4–5 6 5–6
Scarlet LS-2G 3–4 YW 3–4 2–3
Red LS-B 4–5 4–5 3–4
Red LS-6G 4 4–5 3–4
Red LS-BL 2–3 B 4–5 3–4

Textile Effects
Reactive dyes – CIBACRON® LS
Xenon light
(1/1 SD) (1/1 SD)
Brill. Blue LS-G 4 6 5
Blue LS-3R 4 6–7 6
Navy LS-G 1–2 R 4 3
Green LS-3B 3–4 R 4 3
Black LS-N 3 4 (2/1) 3–4 (2/1)
Black LS-N-01 3 4 (2/1) 3–4 (2/1)

Textile Effects
Reactive dyes – CIBACRON® H

without CP with CP
Yellow H-2G
Br. Yellow H-4GN 4–5 4–5 4
Yellow H-RN 200% 4–5 4–5 4–5
Yellow H-G 4–5 7 7
Orange H-R 3–4 4 3–4
Orange H-BR 4 6 5–6
Red H-B 150% 3B 4 3–4

Textile Effects
Reactive dyes – CIBACRON® H

without CP with CP
Red H-D 200% 4 4 3–4
Red H-BL 2–3 B 4–5 3–4
Blue H-RN-01 4–5 7 7
Br. Blue H-GR 4 6 5
Blue H-GN 4–5 5 5
Navy H-2G 2–3 RW 4 4
Turquoise H-GN 4–5 5–6 4

Textile Effects
Vat dyes – CIBANON®
Xenon light
CIBANON Change of shade with
without CP with CP
Yellow G md. 3–4 W 5–6 7
Yellow 3R md. 2–3 W 7 7–8
Golden Yellow RK md. 3–4 6–7 7
Orange 3G md. 3–4 W
Orange 3R md. 3–4 YW 6 6
Brown BR md. 3–4 W 7 7–8
Brown 2BR md. 4W 7–8 7–8
Red 2B md. 4W 7 7
Red 6B md. 4 6–7 6–7
Blue RSJ md. 3–4 R 7–8 7–8

Textile Effects
Xenon light
without CP with CP
Blue GFJ md. 4R 7–8 7–8
Blue BOA–01 md./liq. 2–3 RW 7–8 7–8
Navy DB–01 md. 2 RW 7 7–8
Green BF md. 4W 7 7–8
Olive B–01 md. 3W 8 7–8
Olive S md. 3–4 YW 8 7–8
Olive 2R–01 md. 2 YW 7 7
Gray CBK liq. 40% 3–4 Y 8 7–8
Gray P2R md. 2–3 RW 7–8 7–8

Textile Effects
Xenon light
without CP with CP
Black B-01 md. 4 7–8 (2/1) 7–8 (2/1)

Black R-01 md. 3–4 RW 8 (2/1) 7–8 (2/1)
Black 2BX-01 liq. 10%
Golden Yellow RK 3–4 6–7 7
Orange 3R 3–4 YW 6 6
Brown 2R 3–4 7 7
Gray SG-01
Black TS

Textile Effects
Copyright © 2003 Ciba Specialty Chemicals Inc. All rights reserved.

All trademarks mentioned are either property of or licensed to Ciba Specialty Chemicals and registered in relevant countries.
IMPORTANT: The following supersedes Buyer’s documents. SELLER MAKES NO REPRESENTATION OR WARRANTY, EXPRESS OR IMPLIED, INCLUDING OF
MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE. No statements herein are to be construed as inducements to infringe any relevant patent. Under no
circumstances shall Seller be liable for incidental, consequential or indirect damages for alleged negligence, breach of warranty, strict liability, tort or contract arising in
connection with the product(s). Buyer’s sole remedy and Seller’s sole liability for any claims shall be Buyer’s purchase price. Data and results are based on controlled or
lab work and must be confirmed by Buyer by testing for the intended conditions of use. The product(s) has (have) not been tested for, and is (are) therefore not
recommended for, uses for which prolonged contact with mucous membranes, abraded skin, or blood is intended; or for uses for which implantation within the
human body is intended.
Please note that products may differ from country to country. If you have any queries, kindly contact your local Ciba Specialty Chemicals representative. Further
information at website: http://www.cibasc.com
Ciba Specialty Chemicals is a member of:
(Ecological and Toxicological Association of Dyes and Organic Pigments Manufacturers)
9110008e — September, 2003, Printed in Switzerland.
Textile Effects

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Ciba® PYROVATEX® CP FINISH – CHANGE OF SHADE

• pH–value of the PYROVATEX CP bath: 3.1–3.5

• Alkaline wash-off process

• High curing temperatures

• Direct and sulfur dyestuffs showed very strong

• Naphthol dyestuffs normally do not have

• Vat, reactive and pigment dyestuffs are

Recipe 1 (standard) Recipe 2 (CIBACRON C range only)

400 g/l PYROVATEX CP NEW 400 g/l PYROVATEX CP–LF

curing: 4 min at 150°C curing: 4 min at 150°C

Y = yellower, greener R = redder B = bluer

Red C-2BL 1 5–6 6

Y = yellower, greener R = redder B = bluer

Yellow FN-2R 4 5–6 4–5

Y = yellower, greener R = redder B = bluer

Yellow F-3R 3–4 6 6–7

Y = yellower, greener R = redder B = bluer

Yellow W-RN 200% 4–5 4–5 4–5

Y = yellower, greener R = redder B = bluer

CIBACRON Change of shade with Xenon light

Y = yellower, greener R = redder B = bluer

Y = yellower, greener R = redder B = bluer

CIBACRON Change of shade with Xenon light

Y = yellower, greener R = redder B = bluer

CIBACRON Change of shade with Xenon light

Y = yellower, greener R = redder B = bluer

Y = yellower, greener R = redder B = bluer

Y = yellower, greener R = redder B = bluer

Black B-01 md. 4 7–8 (2/1) 7–8 (2/1)

Y = yellower, greener R = redder B = bluer

Copyright © 2003 Ciba Specialty Chemicals Inc. All rights reserved.

(Ecological and Toxicological Association of Dyes and Organic Pigments Manufacturers)

9110008e — September, 2003, Printed in Switzerland.

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