Recommended MCQs - 140 Questions - Structure of

Atom Contact Number: 9667591930 / 8527521718

Question 1. Question 4.
The atomic numbers of elements whose outermost The diameter of zinc atom is 2.6 Å, number of atoms
electrons are represented by 3s1 and 2p5 respectively present in a length of 1.6 cm, if the zinc atoms are
are: arranged side by side lengthwise, would be -

1. 9, 7 1. 5.153 x 107
2. 9, 11 2. 6.153 x 107
3. 11, 5
3. 4.153 x 109
4. 11, 9
4. 6.153 x 103

Question 5.
Question 2.
Yellow light emitted from a sodium lamp has a
Symbols 79
35
Br and 79Br can be written, wavelength (λ) of 580 nm.
whereas symbols 35
Br
79
and Br
35
are not acceptable The frequency (ν) and wave number of this yellow light
because - would be respectively -

1. The general convention of representing an element 1. 517 x 1014 s-1 , 172 x 106 m-1
along with its atomic number (A) and atomic mass (Z) is
A
X
2. 6.17 x 1014 s-1 , 1.72 x 106 m-1
Z

2. The general convention of representing an element 3. 4.17 x 1014 s-1 , 2.72 x 106 m-1
along with its atomic mass (A) and atomic number (Z) is
A 4. 5.17 x 1014 s-1 , 1.72 x 106 m-1
X
Z

3) The general convention of representing an element

along with its wavelength (A) and frequency (Z) is X A

Question 6.
Z

4) The general convention of representing an element The wave number of a light whose time period is 2.0 ×
along with its isotopes (A) and atomic number (Z) is X A

Z 10–10 s would be -

1. 16.66 m-1
Question 3. 2. 1. 66 m-1
A certain particle carries 2.5 × 10–16 C of static electric 3. 32.34 m-1
charge. The number of electrons present in it would be -
4. 12.34 m-1
1. 1460
2. 1350
3. 1560
4. 1660

Page: 1
 Recommended MCQs - 140 Questions - Structure of
Atom Contact Number: 9667591930 / 8527521718

Question 7. Question 11.

2 ×108 atoms of carbon are arranged side by side. The The number of electrons in the species H
+

2
, H2 , O
+

radius of carbon atom if the length of this arrangement is , are respectively -

2.4 cm would be -
1. 15, 2, 1
1. 7.0 x 10-11 m 2. 15, 1, 2
2. 5.0 x 10-11 m 3. 1, 2, 15

3. 8.0 x 10-11 m 4. 2, 1, 15

4. 6.0 x 10-11 m
Question 12.

Question 8. The complete symbol for the atom with the given atomic
number (Z) and atomic mass (A) would be respectively -
If the diameter of a carbon atom is 0.15 nm, number of
carbon atoms which can be placed side by side in a (i) Z = 17 , A = 35.
straight line across length of scale of length 20 cm long (ii) Z = 92 , A = 233.
will be -
(iii) Z = 4 , A = 9.
7
1. 1. 33 × 10

2. 5. 46 × 10
8 1. 9

4
Be
233
92
U
9

4
Be

9
3. 1. 33 × 10
2. 35

17
Cl
233
92
U
9

4
Be
8
4. 2. 36 × 10
3. 9
4
Be
35

17
Cl
233

92
U

4. 233
U
9
4
Be
35
17
Cl
Question 9.
92

The incorret statement regarding characterise X-rays is -

1. The radiation can ionise the gas Question 13.

2. It causes fluorescence effect on ZnS The maximum number of neutrons will be present in the
nuclei of-
3. Deflected by electric and magnetic fields
16
1. O
4. Have wavelength shorter than ultraviolet rays
8

24
2. Mg
12

56
3. Fe
26

Question 10. 4. Sr
88

38

If the thin foil of light atoms like aluminium etc. is used

in Rutherford’s experiment, the difference that would be
observed from the above results is - Question 14.
1. Same results will be observed Property which is same for the following species:
2. More deflection would be observed
N3–, O2–, F–, Na+, Mg2+ and Al3+
3. There will not be enough deflection
1. Ionic radii
4. None of the above
2. Number of electrons
3. Nuclear charge
4. None of the above

Page: 2
 Recommended MCQs - 140 Questions - Structure of
Atom Contact Number: 9667591930 / 8527521718

Question 15. Question 19.

The charge on the oil drop is –1.282 × 10–18C. The The number of electrons in 19 K have the following
number of electrons present on it would be - quantum numbers n=3; l=0 is-
1. 15 1. 1
2. 8 2. 2
3. 2 3. 4
4. 6 4. 3

Question 16. Question 20.

An atom of an element contains 29 electrons and 35 Species that has more number of electrons than the
neutrons. The number of protons in the element would number of neutrons is-
be-
1. Al3+
1. 29
2. 35 2. O2-

3. 6 3. F-

4. 64 4. C

Question 17. Question 21.

The number of protons, neutrons and electrons in 175

,
Lu
The mass and charge of one mole of electrons are
71

respectively, are: respectively -

1. 104, 71 and 71 1. 5.48 × 10 −7

kg, 9.65 C,

2. 71, 71 and 104 2. 5.48 × 10 −7

C, 1.098 x 1027
3. 175, 104 and 71 3. 5.48 × 10 −7
kg, 9.65 × 10 C
4

4. 71, 104 and 71 4. 9.65 × 10 C, 1.098 x 1027

4

Question 18. Question 22.

Isoelectronic among the following is - An atom forms an ion by the loss of three electrons. The
1. Na +
, K
+
, Ca
2+
, Mg
2+
ion has an electronic configuration [Ar]3d6. The symbol
of the ion is -
2. Ca 2+
, Mg
2+
, S
2−
, K
+

1. Fe3+
3. Ca 2+
, Ar, S
2−
, K
+

2. Ni3+
4. None of the above
3. Co3+

4. Mn+3

Page: 3
 Recommended MCQs - 140 Questions - Structure of
Atom Contact Number: 9667591930 / 8527521718

Question 23. Question 27.

An ion with mass number 56 contains 3 units of positive The total number of electrons present in one mole of
charge and 30.4% more neutrons than electrons. The methane are-
symbol of an ion is - 23
1. 6. 023 × 10
56 +3
24
1. Fe 2. 6. 023 × 10
26

57 +3 22
2. Fe 3. 6. 023 × 10
26
23
58 +3 4. 1. 619 × 10
3. Fe
27

56 +3
4. Fe
25

Question 28.
The unpaired electrons in Al and Si are present in the 3p
Question 24. orbital. The electrons that will experience a more
An element with mass number 81 contains 31.7% more effective nuclear charge from the nucleus is-
neutrons as compared to protons. The atomic symbol of 1. Electrons in the 3p orbital of silicon
an element would be-
81
2. Electrons in the 5d orbital of aluminium
1. Br
35

81
3. Electrons in the 3p orbital of aluminium
2. Br
36

79 4. Electrons in the 5p orbital of silicon

3. Br
35

79
4. Br
36

Question 29.
Assertion: Zn(ll) salts are diamagnetic.
Question 25.
The total number and mass of neutrons in 7 mg Reason: Zn2+ ion has one unpaired electron.
of 14C would be - 1. Both Assertion & Reason are true and the reason is the
correct explanation of the assertion.
(Assume that mass of a neutron = 1.675 × 10–27 kg)
2. Both Assertion & Reason are true but the reason is not
21 –6
1. 2. 41 × 10 , 4. 03 × 10 kg the correct explanation of the assertion.
23 −21
2. 6. 23 × 10 , 1. 67 × 10 kg
3. Assertion is a true statement but Reason is false.
22 6
3. 1. 22 × 10 , 4. 03 × 10 kg

21 −6
4. Both Assertion and Reason are false statements.
4. 2. 41 × 10 , 4. 03 × 10 g

Question 30.
Question 26.
Assertion: All isotopes of a given element show the
The electron of Br atom that experiences the lowest same type of chemical behaviour.
effective nuclear charge is -
Reason: The chemical properties of an atom are
1. 2p and 3p controlled by the number of electrons in the atom.
2. 4p 1. Both assertion and reason are true and the reason is
3. 2p the correct explanation of assertion.

4. 3p 2. Both assertion and reason are true and the reason is

not the correct explanation of assertion.
3. Assertion is true but the reason is false.
4. Assertion is false but the reason is true.

Page: 4
 Recommended MCQs - 140 Questions - Structure of
Atom Contact Number: 9667591930 / 8527521718

Question 31. Question 34.

4000 A photon is used to break the l molecules,the
o
2

The energy of the photon having frequency 3×1015 Hz percentage of energy converted to the KE of atoms is-
would be - (bond dissociation energy of the molecule is 246.5 kJ/mol)
1. 1.988 × 10 −18
J
1. 12%
2. 1.588 × 10 −18
J
2. 8%
3. 1.288 × 10 −18
J
3. 26%
4. 2.988 × 10 −18
J
4. 17%

Question 32.
Question 35.
The energies E1 and E2 of two radiations are 25 eV and
50 eV respectively. The relation Match the following:

between their wavelengths ( λ1 and λ2 ) will be -

Column I Column II
1. λ1 = 2λ2
A. X-rays 1. v = 10 0
− 10
4
Hz
2. λ1 = 4λ2

3. λ1 = 1
λ2 B. Ultraviolet wave (UV) 2. v = 10 10
Hz
2

4. λ1 = λ2 C. Long radio waves 3. v = 10 16

Hz

D. Microwave 4. v = 10 18
Hz
Question 33.
The correct arrangement of frequency in increasing order A B C D
is -
1. 4 1 3 2
1. Cosmic rays < Amber light < Radiation of FM radio <
2. 1 4 2 3
X-rays < Radiation from microwave ovens
3. 1 4 3 2
2. Radiation from FM radio < Radiation from
microwave oven < Amber light < X- rays < Cosmic rays 4. 4 3 1 2
3. Radiation from microwave ovens < Amber light <
Radiation of FM radio < X-rays < Cosmic rays
Question 36.
4. Cosmic rays < X-rays < Radiation from microwave
ovens < Amber light < Radiation of FM radio The wavelength of the light emitted when the electron
returns to the ground state in H atom, from n =5 to n =1
would be -

(The ground-state electron energy is –2.18 × 10-18 ergs)

1. E = 2.09 x 10-18 Kg, Wavelength = 9.498 x 10-8 km

2. E = 4.09 x 10-18 J, Wavelength = 12.498 x 10-8 m

3. E = 2.09 x 10-18 J, Wavelength = 9.498 x 10-8 m

4. E = 3.09 x 10-18 J, Wavelength = 9.498 x 10-8 m

Page: 5
 Recommended MCQs - 140 Questions - Structure of
Atom Contact Number: 9667591930 / 8527521718

Question 37. Question 41.

A 25-watt bulb emits monochromatic yellow light of The radiation source has a duration of 2 ns and the
wave length of 0.57µm. The rate of emission of quanta number of photons emitted is 2.5 × 1015, the energy of
per second would be - the source is -
−10
1. 8. 28 × 10 J
−19 −1
1. 7. 17 × 10 s 10
2. 8. 24 × 10 J
16 −1
2. 4. 13 × 10 s −11
3. 7. 12 × 10 J
19 −1
3. 7. 17 × 10 s 10
4. 2. 12 × 10 J
20 −1
4. 1. 26 × 10 s

Question 42.
Question 38.
Electromagnetic radiation of wavelength 242 nm is just
Nitrogen laser produces radiation at a wavelength of sufficient to ionise the sodium atom. The ionisation
337.1 nm. If the number of photons emitted is 5.6 × 1024, energy of sodium in kJ mol-1 is -
The power of the laser is -
1. 494
7
1. 4. 56 × 10 J
6 2. 4.94
2. 3. 33 × 10 J

3. 1. 29 × 10
6
J 3. 516
5
4. 9. 17 × 10 J
4. 0.50

Question 39.
Question 43.
If the photon detector receives a total of 3.15×10 J
−18

The number of photons of light with a wavelength of

from the radiations of 600 nm,the number of photons 4000 pm that provides 1J of energy would be -
received by the detector would be -
16
1. 2. 01 × 10
2
1. 10 19
2. 2. 01 × 10
2. 10
23
3. 4. 14 × 10
3. 50
21
4. 2. 14 × 10
4. 20

Question 40. Question 44.

The neon gas emits radiation of 616 nm. The number of Assertion: A black body is an ideal body that emits and
quanta is present in 2 J of energy is- absorbs radiations of all frequencies.

1. 6. 2 × 10
−18 Reason: The frequency of radiation emitted by a body
17 goes from a lower frequency to a higher frequency with
2. 5. 6 × 10
18
an increase in temperature.
3. 6. 2 × 10

4. 32. 2 × 10
−20 1. Both assertion and reason are true and the reason is
the correct explanation of assertion.
2. Both assertion and reason are true and the reason is
not the correct explanation of assertion.
3. Assertion is true but the reason is false.
4. Assertion is false but the reason is true.

Page: 6
 Recommended MCQs - 140 Questions - Structure of
Atom Contact Number: 9667591930 / 8527521718

Question 45. Question 49.

In photoelectric effect, the kinetic energy of A photon with an initial frequency 10 Hz scatters off an
11

photoelectrons increases linearly with the- electron at rest. Its final frequency is 0. 9 × 10 Hz.
11

The speed of scattered electron is close to -

1. Wavelength of incident light
2 −1
1. 3 × 10 ms
2. Frequency of incident light
3 −1
2. 3. 8 × 10 ms
3. Velocity of incident light 3. 2 × 10
6
ms
−1

4. Atomic mass of an element 4. 30 ms

−1

Question 46.
Question 50.
Electrons are emitted with zero velocity from a metal
surface when it is exposed to radiation of wavelength The ejection of the photoelectron from the silver metal
6800 Å. The work function (W0 ) of the metal is - can be stopped by applying the voltage of 0.35 V when
the radiation having wavelength 256.7 nm is used. The
1. 3.109 x 10-20 J work function for silver metal is -
1. 3.40 eV
2. 2.922 x 10-19 J
2. 5.18 eV
3. 4.031 x 1019 J
3. 4.48 eV
4. 2.319 x 10-18 J
4. -4.40 eV

Question 47.

A photon of wavelength 4 × 10–7 m strikes on metal Question 51.

surface, the work function of the metal being 2.13
eV. The kinetic energy of emission would be - If the photon of the wavelength 150 pm strikes an atom
and one of its inner bound electrons are ejected out with a
1. 0.97 eV
velocity of 1.5 × 107 m s–1, the energy with which it is
2. 97 eV bound to the nucleus would be -
3. 4.97 × 10 −19
eV 1. 32.22 × 10–16 J
4. 5.84 × 105 eV 2. 12.22 × 10–16 J

3. 22.27 × 10–16 J
Question 48. 4. 31.22 × 10–16 J
The photoelectric emission from a surface starts only
when the light incident upon the surface has certain
minimum: Question 52.
1. Intensity The work function for the Cesium atom is 1.9 eV. The
2. Wavelength threshold frequency of the radiation is-

3. Frequency 1. 4.59 × 1014 s −1

4. Velocity 2. 8.59 × 1014 s −1

3. 5.59 × 10-14 s −1

4. 65.9 × 1014 s −1

Page: 7
 Recommended MCQs - 140 Questions - Structure of
Atom Contact Number: 9667591930 / 8527521718

Question 53. Question 57.

The ratio of slopes of K max vs. v and V0 vs. v curves The number of spectral lines obtained when an electron
in the photoelectric effect gives - jumps from n=5 to n=1 hydrogen atom is -
(v=frequency, K =maximum kinetic energy,
max V0 1. 3
stopping potential):
2. 4
1. Charge of electron
3. 6
2. Planck's constant
4. 10
3. Work function
4. The ratio of Planck's constant of electronic charge
Question 58.
The energy associated with the fifth orbit of hydrogen is -
Question 54. −18
1. − 2. 18 × 10 J
The ratio of the wavelengths of the last lines of the 2. − 8. 72 × 10
−20
J
Balmer to Lyman series is- −21
3. − 3. 88 × 10 J

1. 4:1 4. − 8. 72 × 10
−19
J

2. 27:5
3. 3:1
Question 59.
4. 9:4
The wavelength of light emitted when the electron in a H
atom undergoes the transition from an energy level
with n = 4 to an energy level with n = 2, is -
Question 55.
1. 586 mm
The maximum number of emission lines obtained when
the excited electron of the H atom jumps from n = 6 to 2. 486 nm
the ground state is - 3. 523 nm
1. 30 4. 416 pm
2. 21
3. 15
Question 60.
4. 28
The wave number for the longest wavelength transition
in the Balmer series of atomic hydrogen would be -
6 −1

Question 56. 1. 1. 52 × 10 m
6 −1
2. 3. 14 × 10 cm
The wavelength of the radiations emitted when in a H 6 −1
3. 15. 2 × 10 m
atom, the electron falls from infinity to stationary state 1, 6 −1
is: 4. 1. 52 × 10 cm

1. 15 nm
2. 192 nm
3. 406 nm
4. 91 nm

Page: 8
 Recommended MCQs - 140 Questions - Structure of
Atom Contact Number: 9667591930 / 8527521718

Question 61. Question 65.

Electronic transitition in the hydrogen atom that emits The ionization energy for H atom in the ground state
maximum energy is : is 2.18 x 10-18 J. The energy required for the process
1. 2 → 1 will be -
+ 2+ −
2. 1 → 4 He (g) → He (g) + e

−18
3. 4 → 3 1. 8. 72 × 10 J

4. 3 → 2 2. 7. 54 × 10
−19
J

−17
3. 5. 67 × 10 J

−17
Question 62. 4. 2. 18 × 10 J

Emission transitions in the Paschen series end at orbit n =

3 and start from orbit n and can be represented as v =
Question 66.
3.29 × 1015 (Hz)(
1 1

2
− 2
n
) . The value of n if the
3

transition is observed at 1285 nm is - The wavelength of the spectral line obtained in spectrum
of Li when the transition takes place between levels
+2

1. 6
whose sum is 4 and difference is 2 will be-
2. 5

3. 8
1. 11.4 x 10 −6
cm
4. 9
2. 1.14 x 10 cm−6

3. 0.114 x 10 −6
cm
Question 63. 4. 1.14 x 10 −8
cm
The maximum wavelength in the Lyman series of He+
ion is-
Question 67.
1. 3R
The masses of photons corresponding to the first lines of
2. 1/3R
the Lymann and the Balmer series of the atomic spectrum
3. 1/R of hydrogen are in the ratio of-
4. 2R 1. 5:27
2. 1:4
3. 27:5
Question 64.
4. 4:1
The energy of an electron in H - atom is given by En =
−18
(–2.18 × 10 )

n
2
J. The shortest wavelength of light that
can be used to remove an electron completely from n = 2
orbit is-
°
1. 3647 A

°
2. 5132 A

°
3. 3017 A

4. None of these

Page: 9
 Recommended MCQs - 140 Questions - Structure of
Atom Contact Number: 9667591930 / 8527521718

Question 68. Question 71.

The transition in He+ ion in balmer series that would A dye absorbs a photon of wavelength λ and re-emits the
have the same wave number as the first Lyman line in the same energy into two photons of wavelengths λ and λ
1 2

hydrogen spectrum is- respectively. The wavelength λ is related with λ and λ

1 2

as-
1. 2 →1
1.
λ1 +λ2
λ =
2. 5 →3 λ1 λ2

3. 4 →2 2.
λ1 λ2
λ =
λ1 +λ2

4. 6 →4 2
λ +λ
2

3. λ =
1

λ1 +λ2
2

4.
λ1 λ2
λ = 2
( λ1 +λ2 )

Question 69.
The transition in the hydrogen spectrum that would have Question 72.
the same wavelength as the Balmer transition n = 4 to n =
2 of He+ spectrum is - The energy of an electron in the first Bohr's orbit of H-
atom is -13.6 eV. The possible energy value (s) of the
1. n = 3 to n = 4
1 2 excited state (s) for electrons in Bohr's orbits of hydrogen
is (are):
2. n = 3 to n1 = 2
2

(1) -3.4 eV
3. n = 3 to n1 = 1
2

(2) -4.2 eV
4. n = 2 to n1 = 1
2
(3) -6.8 eV
(4) +6.8 eV
Question 70.
An absorption line of lowest frequency in transition of Question 73.
hydrogen spectra is-
For any H like system, the ratio of velocities of I, II & III
1. n=1 to n=2 orbit i.e., V : V : V will be-
1 2 3

2. n=3 to n=8 1. 1 : 2 : 3
3. n=2 to n=1 2. 1 : 1/2 : 1/3
4. n=8 to n=3 3. 3 : 2 : 1
4. 1 : 1 : 1

Question 74.
The concept that contradicts the Bohr Model of an atom
is -
1. Rutherford Model
2. Heisenberg's Uncertainty Principle
3. J.J. Thomson Model
4. Photoelectric Effect

Page: 10
 Recommended MCQs - 140 Questions - Structure of
Atom Contact Number: 9667591930 / 8527521718

Question 75. Question 79.

An ion among the following that has the same radius as Be ion and a proton are accelerated by the same
3+

for hydrogen atom having n=1 , is - potential,their de-Broglie wavelengths have the ratio-
1. He +
, n = 2 (assume mass of proton = mass of neutron)
2. Li 2+
,n = 2 1. 1:2

3. Be 3+
, n = 2 2. 1:4

4. Li 2+
,n = 3
3. 1:1
4. 1:3√3

Question 76.
The wavelength of a certain line in Balmer series is Question 80.
observed to be 4341 A for hydrogen atom. The
o

The charge on the electron and proton are reduced to rd

2

electronic transition may be - 3

of their original values. Let the present value of the

1. 3 → 2
Rydberg constant of H-atom be R. The new value of the
2. 4 → 1 Rydberg constant will be -
3. 5 → 2
2R

4. 5 → 3 1.
3

4R
2.
9

8R

Question 77. 3.
27

16R

If the size of the first orbit of the hydrogen atom is 5.29 4.

81

nm, the size of the second orbit of He+ is-

1. 2.65 nm
Question 81.
2. 21.16 nm
Assertion: Bohr’s orbits are also called stationary states.
3. 10.58 nm
Reason: Electrons are stationary in an orbit.
4. 5.29 nm
1. Both Assertion & Reason are true and the reason is the
correct explanation of the assertion.

Question 78. 2. Both Assertion & Reason are true but the reason is not
the correct explanation of the assertion.
In the transition of an electron in an atom, its kinetic
y
energy changes from y to . The change in potential 3. Assertion is a true statement but Reason is false.
4

energy will be - 4. Both Assertion and Reason are false statements.

−3
1. y
8

3
2. y
2

3
3. y
4

−3
4. y
4

Page: 11
 Recommended MCQs - 140 Questions - Structure of
Atom Contact Number: 9667591930 / 8527521718

Question 82. Question 85.

Assertion: The radius of the second orbit of He* is equal The measurement of the electron position is associated
to that of the first orbit of hydrogen. with an uncertainty in momentum, equal to 1x10-18 g cm
Reason: The radius of an orbit in hydrogen-like species is s-1. The uncertainty in velocity of the electron is-
directly proportional to n and inversely proportional to Z.
(mass of an electron is 9 x 10-28 g)
1. Both Assertion & Reason are true and the reason is the
correct explanation of the assertion. 1. 1 x 109 cm s-1
2. Both Assertion & Reason are true but the reason is not 2. 1 x 106 cm s-1
the correct explanation of the assertion.
3. 1 x 105 cm s-1
3. Assertion is a true statement but Reason is false.
4. Both Assertion and Reason are false statements. 4. 1 x 1011 cm s-1

Question 83. Question 86.

Assertion: Angular momentum of an electron in an atom If the position of the electron is measured within an
is quantized. accuracy of +0.002 nm, the uncertainty in the momentum
of the electron would be -
Reason: In an atom only those orbits are permitted in
which angular momentum of the electron is a natural 1. 5.637 × 10–23 kg m s–1
number multiple of . h

2π
2. 4.637 × 10–23 kg m s–1
1. Both Assertion & Reason are true and the reason is the
correct explanation of the assertion. 3. 2.637 × 10–23 kg m s–1

2. Both Assertion & Reason are true but the reason is not 4. 3.637 × 10–23 kg m s–1
the correct explanation of the assertion.
3. Assertion is true statement but Reason is false.
4. Both Assertion and Reason are false statements.
Question 87.
Assertion: It is impossible to determine the exact
Question 84. position and exact momentum of an electron
simultaneously.
If uncertainty in position and momentum are equal, then
uncertainty in velocity is - Reason: The path of an electron in an atom is clearly
defined.
1. 1

2m
√
h

π 1. Both assertion and reason are true and the reason is

the correct explanation of assertion.
2. √ h

2π
2. Both assertion and reason are true and the reason is
not the correct explanation of assertion.
3. 1

m
√
h

π
3. Assertion is true but the reason is false.
4. h

π 4. Assertion is false but the reason is true.

Page: 12
 Recommended MCQs - 140 Questions - Structure of
Atom Contact Number: 9667591930 / 8527521718

Question 88. Question 92.

The circumference of the Bohr orbit for the H atom is The graphs that represents the variation of momentum of
related to the de Broglie wavelength associated with the particle with de-Broglie wavelength is -
electron revolving around the orbit by which of the
following relation?
1. 2πr = nλ

2. πr = 2nλ

3. mvr = nλ

4. vr = 2nλ

1.
Question 89.
The largest de Broglie wavelength among the following
(all have equal velocity) is -
1. CO2 molecule
2. NH3 molecule
3. Electron
4. Proton
2.

Question 90.
The wavelength of an electron moving with a velocity of
2.05 × 107 m s-1 would be -
−12
1. 4. 65 × 10 m
−11
2. 3. 55 × 10 m
11
3. 2. 34 × 10 m
−11
3.
4. 6. 43 × 10 m

Question 91.

If the velocity of the electron is 1.6 × 106 ms . The de

−1

Broglie wavelength is associated with this electron is -

1. 590 pm

2. 455 pm

3. 512 pm
4.
4. 401 pm

Page: 13
 Recommended MCQs - 140 Questions - Structure of
Atom Contact Number: 9667591930 / 8527521718

Question 93. Question 97.

Among the following statements the wrong statement is- The incorrect set of quantum number among the
following is -
1. The uncertainty principle is Δx ⋅ Δp ≥ h

4π
1. n= 4, l= 0, m= 0, s= -1/2
2. Half-filled and fully filled orbitals have greater
stability due to greater exchange energy, 2. n= 5, l= 3, m= 0, s= +1/2

greater symmetry and a more balanced arrangement. 3. n= 3, l= 2, m= -3, s= -1/2

3. The energy of 2s orbital is less than the energy of 2p 4. n= 3, l= 2, m= 2, s= -1/2

orbital in the case of hydrogen-like atoms.

4. De-Broglie's wavelength is given by λ = , where

h

mv
Question 98.
m= mass of the particle , v = group velocity of the
particle. Sets of quantum numbers that are possible-
1. n = 0, l = 0, ml = 0, ms = + ½

2. n = 1, l = 0, ml = 0, ms = – ½

Question 94. 3. n = 1, l = 1, ml = 0, ms = + ½
The velocity associated with a proton moving in a 4. n = 3, l = 3, ml = –3, ms = + ½
potential difference of 1000 V is 4.37 × 105 ms–1. If the
hockey ball of mass 0.1 kg is moving with this velocity
then the wavelength associated with this velocity would
be-
−38
1. 1. 52 × 10 m
−32
2. 2. 54 × 10 m
−36
3. 1. 52 × 10 m
−34
Question 99.
4. 3. 19 × 10 m
Consider the following sets of quantum numbers:
n l m s
Question 95.
(i) 3 0 0 +1/2
The kinetic energy of an electron is 3.0 × 10–25 J, it's (ii) 2 2 1 +1/2
wave length would be -
−7
(iii) 4 3 -2 -1/2
1. 8. 96 × 10 m

2. 4. 37 × 10
−6
m
(iv) 1 0 -1 -1/2
3. 1. 32 × 10
−7
m (v) 3 2 3 +1/2
−4
4. 2. 89 × 10 m
Which of the following sets of quantum numbers is not
possible?
1. ii, iii and iv
Question 96.
2. i, ii, iii and iv
The characteristic velocity associated with the neutron if
the wavelength is 800 pm - 3. ii, iv and v
1. 494 m s
−1
4. i and iii
−1
2. 567 m s
−1
3. 494 cm s
−1
4. 501 m s

Page: 14
 Recommended MCQs - 140 Questions - Structure of
Atom Contact Number: 9667591930 / 8527521718

Question 100. Question 104.

The correct set of four quantum numbers for the valence An excited state of H atom emits a photon of wavelength
electron of rubidium atom (Z =37) is - λ and returns in the ground state, the principal quantum

number of excited state is given by:

1. 5, 1, 1, + 1

1. √λR(λR − 1)

2. 6, 0, 0, +
1

2. √
λR

3. 5, 0, 0, +
1 ( λR−1 )

3. √λR(λR + 1)
4. 5, 1, 0, + 1

( λR−1 )
4. √
λR

Question 101.
The quantum number not obtained from the Question 105.
Schrodinger’s wave equation is -
Wave mechanical model of the atom depends upon-
1. n
1. De-Broglie concept of dual nature of electron
2. l
2. Heisenberg uncertainty principle
3. m
3. Schrodinger principle
4. s
4. All

Question 102.
Question 106.
Total number of electrons in an atom with the following
quantum numbers would be respectively - The number of orbitals are possible in L-energy level is-

(a) n = 4, ms = – ½ (b) n = 3, l = 0 1. 2
2. 4
1. 16, 2
3. 6
2. 11, 8
4. 1
3. 16, 8
4. 12, 7
Question 107.
The quantum numbers of the most energetic electron in
Question 103.
Ne atom in first excited state is-
The angular momentum of electrons in d orbital is equal to -
1. 2, 1, 0, +1/2
1. √6 h
2. 3, 1, 1, +1/2
2. √2 h 3. 3, 0, 0, +1/2
4. 3, 1, 0, +1/2
3. 2√3 h

4. 0 h

Page: 15
 Recommended MCQs - 140 Questions - Structure of
Atom Contact Number: 9667591930 / 8527521718

Question 108. Question 111.

The number of electrons can be fit in the orbital for Orbital that does not exist:
which n = 3 and l = 1, is -
1. 6p
1. 2
2. 2s
2. 6
3. 3f
3. 10
4. 2p
4. 14

Question 112.
Question 109.
The possible values of n, l, and m for the electron present
Match the quantum numbers with the information in 3d would be respectively -
provided by these.
1. n = 3, l = 1, m = – 2, – 1, 3, 1, 2

Quantum number Information provided 2. n = 3, l = 3, m = – 2, – 1, 0, 1, 2

3. n = 3, l = 2, m = – 2, – 1, 0, 1, 2
A. Principal quantum 1. Orientation of the
number orbital 4. n = 5, l = 2, m = – 2, – 1, 0, 1, 2

B. Azimuthal quantum 2. Energy and size of

number orbital Question 113.
A pairs of d-orbitals having electron density along the
C. Magnetic quantum axes is-
3. Spin of electron
number
1. d z
2 , dxz

D. Spin quantum number 4. Shape of the orbital 2. d xz , dzy

3. d z
2 , dx2 −y 2

A B C D
4. d xy , dx2 −y 2
1. 2 4 1 3
2. 1 2 3 5
3. 5 4 3 2 Question 114.

4. 4 5 3 2 Maximum number of electrons in a subshell with l = 3

and n = 4 is-
1. 14
Question 110. 2. 16
Set of quantum numbers which represent 3p is - 3. 10
1. n =1, l =0; 4. 12
2, n = 3; l=1
3. n = 4; l =2;
4. n = 4; l = 3

Page: 16
 Recommended MCQs - 140 Questions - Structure of
Atom Contact Number: 9667591930 / 8527521718

Question 115. Question 119.

The lowest value of n for 'g' orbitals is - Assertion: In the third energy level there is no f subshell.
1. 4 Reason: For n = 3, the possible values of l are 0, 1, 2 and
for f subshell / = 3.
2. 5
1. Both Assertion & Reason are true and the reason is the
3. 3 correct explanation of the assertion.
4. 1 2. Both Assertion & Reason are true but the reason is not
the correct explanation of the assertion.
3. Assertion is a true statement but Reason is false.
Question 116.
4. Both Assertion and Reason are false statements.
The rule used to determined the maximum number of
electrons in a subshell of an atom is-
1. 4l+2 Question 120.
2. 2l+1 A: All d orbitals are tetra-lobed structure having two
3. 4l- 2 nodal planes.

4. 2n2 R: Out of five only four d-orbitals are degenerate

orbitals.
1. Both Assertion & Reason are true and the reason is the
Question 117. correct explanation of the assertion

The number of electrons with the azimuthal quantum 2. Both Assertion & Reason are true but the reason is not
number l = 1 and 2 for Cr in ground state are- the correct explanation of the assertion.
24

1. 16 and 5 3. Assertion is a true statement but Reason is false.

2. 12 and 5 4. Both Assertion and Reason are false statements.

3. 16 and 4
4. 12 and 4 Question 121.
The correct order of total number of node of atomic
orbitals is-
Question 118.
1. 4f > 6s > 5d
The number of electrons that will be present in the
subshells having ms value of –1/2 for n = 4 are: 2. 6s > 5d > 4f
3. 4f > 5d > 6s
1. 36
4. 5d > 4f > 6s
2. 4
3. 16
4. 2

Page: 17
 Recommended MCQs - 140 Questions - Structure of
Atom Contact Number: 9667591930 / 8527521718

Question 122. Question 126.

The incorrect statement about the nodal plane among the Assertion: The number of radial nodes in 3d , is zero.
z
2

following is -
Reason: The number of angular nodes of atomic orbitals
1. A plane on which there is zero probability of finding is equal to the value of /.
an electron
1. Both Assertion & Reason are true and the reason is the
2. A plane on which there is maximum probability that correct explanation of the assertion.
the electron will be found
2. Both Assertion & Reason are true but the reason is not
3. ψ is zero at nodal plane
2
the correct explanation of the assertion.
4. None of the above 3. Assertion is a true statement but Reason is false.
4. Both Assertion and Reason are false statements.

Question 123.
The correct statement among the following is - Question 127.
1. Number of angular nodes = n-l-1 The correct order of increasing energy of atomic orbital
is
2. Number of radial nodes = l
1. 3s, 3p, 4s, 3d, 4p
3. Total number of nodes = n-1
2. 3s, 3p, 3d, 4s, 4p
4. All of the above
3. 3s, 3p, 4s, 4p, 3d
4. 3s, 3p, 3d, 4p, 4s
Question 124.
Orbitals having two spherical nodes is -
Question 128.
1. 2s Among the following statements, the wrong statement is-
2. 4s 1. Total orbital angular momentum of an electron in 's'
3. 3d orbital is equal to zero.

4. 6f
2. An orbital is designated by three quantum numbers
while an electron in an atom is designated by four
quantum numbers.
Question 125.
In a subshell, the number of radial nodes is two times of 3. The electronic configuration of N atom is
the number of angular nodes then minimum possible
value of the principal quantum number (n) is -
[angular nodes are non-zero)
1. 1
2. 2 4. The value of m for dz2 is zero.
3. 3
4. 4

Page: 18
 Recommended MCQs - 140 Questions - Structure of
Atom Contact Number: 9667591930 / 8527521718

Question 129. Question 133.

The group number and electronic configuration of The electronic configurations of Eu (Atomic no. 63), Gd
element Z =114 is - (Atomic no. 64) and Tb (Tb Atomic no. 65) are

1. Halogen family, [Rn]5f146d107s27p5 1. [Xe]4f65d16s2, [Xe]4f75d16s2 and [Xe]4f96s2

2. Carbon family, [Rn]5f146d107s27p2 2. [Xe]4f65d16s2, [Xe]4f75d16s2 and [Xe]4f85d16s2

3. Oxygen family, [Rn]5f146d107s27p4 3. [Xe]4f76s2, [Xe]4f75d16s2 and [Xe]4f96s2

4. Nitrogen family, [Rn]5f146d107s27p6 4. [Xe]4f76s2, [Xe]4f86s2 and [Xe]4f85d16s2

Question 130. Question 134.

If n=6, the correct sequence for filling of electrons will Number of unparired electrons in 1s2 2s2 2p3 is -
be-
1. 2
1. ns → (n − 1) d → (n − 2) f → np
2. 0
2. ns − (n − 2) f → np → (n − 1) d 3. 3

3. ns − np → (n − 1)d → (n − 2) f
4. 1

4. ns → (n − 2) f → (n − 1) d → np

Question 135.
An electronic configuration represent an atom in the
Question 131. excited state is-
The number of d-electrons in Fe2+ (z = 26) is not equal to 2 2 1
the number of electrons among the given option is - 1. 1s , 2s 2p

2 2 2
2. 1s , 2s 2p

1. s-electrons in Mg (Z = 12) 2 2
3. 1s , 2s 2p , 3s
2 1

2 2 5
4. 1s , 2s 2p
2. p-electrons in Cl (Z = 17)

3. d-electrons in Fe (Z = 26)
Question 136.
4. p-electrons in Ne (Z = 10)
If the electronic structure of oxygen atom is written as

2
1s , 2s
2
it would violate
Question 132. 1. Hund's rule
Magnetic moment 2.84 BM can be shown by - 2. Paulis exclusion principle
(At. no. Ni = 28, Ti = 22, Cr = 24, Co = 27) 3. Both Hund's and Pauli's principles

1. Ni2+ 4. None of these

2. Ti3+

3. Cr3+

4. Co2+

Page: 19
 Recommended MCQs - 140 Questions - Structure of
Atom Contact Number: 9667591930 / 8527521718

Question 137. Question 139.

The orbital diagram in which both the Pauli's exclusion Match the following species with their corresponding
principle and Hund's rule are violated is- ground state electronic configuration.

Atom/Ion Electronic configuration

1.
A. Cu 1. 1s 2 2 6 2 6
2s 2p 3s 3p 3d
10

2.
B. Cu2+ 2. 1s 2 2 6 2 6 10 2
2s 2p 3s 3p 3d 4s

3. C. Zn2+ 3. 1s 2 2 6 2 6
2s 2p 3s 3p 3d
10
4s
1

D. Cr3+ 4. 1s 2 2 6 2 6 9
2s 2p 3s 3p 3d
4.

5. 1s 2 2 6 2 6
2s 2p 3s 3p 3d
3

Question 138.
1. A- 4, B-2, C-5, D-1
Among the given options the element having the highest
number of unpaired electrons in the ground state is - 2. A-3, B-4, C-1, D-5

1. P 3. A-3, B-2, C-1, D-4

2. Fe 4. A-4, B-2, C-1, D-3

3. Kr
4. Cr

Page: 20
 Recommended MCQs - 140 Questions - Structure of
Atom Contact Number: 9667591930 / 8527521718

Question 140.
Match the following rules with their statements.

Rules Statements

1. No two electrons in an atom

A. Hund’s Rule can have the same set of four
quantum numbers.

B. Aufbau 2. Half-filled and completely

Principle filled orbitals have extra stability.

3. Pairing of electrons in the

C. Pauli Exclusion orbitals belonging to the same
Principle subshell does not take place until
each orbital is singly occupied.

4. It is impossible to determine
D. Heisenberg’s
the exact position and exact
Uncertainty
momentum of a subatomic
Principle
particle simultaneously.

5. In the ground state of atoms,

orbitals are filled in the order of
their increasing energies.

A B C D
1. 3 5 1 2
2. 1 2 3 4
3. 3 5 1 4
4. 4 5 3 2

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