DPRn 427S

On-line Measurement

Contents

Introduction
The Anton Paar Company

What Sensor Technology do we have

Combination of the Sensor Technology’s

Xdpix04S

Anton Paar GmbH, Austria

Foundation 1922
Ownership Santner Foundation

Employees > 730 in Austria

> More than 1000 worldwide
Turnover (2008) > 112.6 million EURO
> Growth rate: +6 %
Export share > 90 %
R&D expenditure approx. 20 % of turnover
Quality management ISO 9001:2000

1
 DPRn 427S

Guiding Principles

Customer orientation
We aim to pprovide optimal
p solutions which meet the
requirements of our customers and to work with them on
successful long-term projects.

The highest product quality

We are a world leader because the accuracy and working
life of our measuring and analysis instruments meet our
customers‘ highest expectations.

Service
We take care of our customers after the sale, quickly and
competently, throughout the working life of the instrument.

Anton Paar World Wide

Sales and service net > 100 partners worldwide
> 14 subsidiaries and participation in
sales and service companies
> Office in Buenos Aires, Prague and
Lj bljana
Ljubljana

Company headquarters Countries with individual Sales operated by sales Sales operated by Anton
Anton Paar GmbH subsidiary, sales office partners Paar GmbH
AUSTRIA or joint venture

2
 DPRn 427S

Anton Paar Product Range

ƒ Density and Concentration of Liquids and Gases

in the laboratory and process

ƒ Flow Behavior, Viscosity, Elasticity

or Visco-elasticity of Substances

ƒ Wet-chemical Decomposition and

Microwave-assisted Organic Synthesis

ƒ Structure and Character of Materials

ƒ Refractive Index determination and concentration

measurement

ƒ Development and Production of

high-precision mechanical components, devices and
prototypes and electromechanical assemblies

Anton Paar INLINE

Measurements

3
 DPRn 427S

Density
Transducers

DPRn 427

Xdpix50B

4
 DPRn 427S

Measuring
Principle Density

Density = Mass / Volume = A * P² - B

Low density Æ high Tone

P

c~A
t

High Density Æ low Tone

P
m, V

~B

Online Density Measuring

Principle

„ The resonant frequency of the oscillator tube depends on the

density of a sample which flows through.
„ An electronically circuit keeps the tube oscillating.
„ The temperature is measured with a Pt 1000 temperature
sensor.

10

5
 DPRn 427S

DPRn 427S
Accuracy class
4 DPRn 5*10-5 / DSRn 5*10-5 g/cm3

Oscillator material
2 Special materials: Hastelloy, Incolloy,
Tantalum, Glass

Inner diameter of the oscillating tube

7 6.6 or 7 mm

Special features
S Stainless steel housing

DPRn 4 2 7 S Density - Transducer

11

Specifications

Sensor DPRn 427 S DSRn 427S

Hastelloy C 276 W.Nr. 2.4819 , Incoloy 825, Tantalum,
Tube material Borosillicate Glass
Glass, SS 316Ti

tube length betw een connections ∼ 500 mm

Density and Sound Velocity

Measuring range 0 bis 3 g/cm3 0 bis 3 g/cm3 - 800 bis 3000 m/s

Repeatability 1x10-5 g/cm3 1x10-5 g/cm3 - 0.01 m/s

Accuracy w ithin the adjusted range 5x10-5 g/cm3 5x10-5 g/cm3 - 0.1 m/s

Temperature
Temperature range (sample) -25 ... +125°C

Ambient temperature -25 ...+ 70 oC

Accuracy w ithin the adjusted range < 0.1 K

Pressure 0 ... 200 bar

12

6
 DPRn 427S

Installation
Bypass over valve Bypass over narrowing

Flow Flow
adjustment adjustment
Sample outlet Sample outlet

Bypass over venturi tube

Flow
adjustment Sample outlet

13

Installation

In the mainline: Transducer

Inline Pump or Inline Adapter

14

7
 DPRn 427S

Inline pump

15

Installation

In the mainline:

„ Inline Adapter: Horizontal mounting

„ Inline Pump: Vertical and horizontal
mounting possible

16

8
 DPRn 427S

Installation in Pipes

Using Density Measurement

mPDS 1100

TEMP : +16.14 °C
PER-D: 2574.976 us L ESC
DENS: 1.33317 g/cm3 ENTER
Ai-curr: 0. 160 mA 06

DPRn
mPDS 1100

Volume
Counter
To kettle

17

Installation in Tank

Using Density Measurement

mPDS 1100
DPRn
TEMP : +16.14 °C
PER-D: 25 74.976 us L ESC
DENS: 1.33317 g/cm3 ENTER
Ai-curr: 0.160 mA 06

mPDS 1100

Hot water

18

9
 DPRn 427S

Example

NaOH (Caustic Soda) Monitor

using
DPRn 427 Incoloy + mPDS 1100
or
DTR 427 Incoloy
I l

19

Sound velocity
Transducers

10
 DPRn 427S

Measuring Principle
Sound Velocity

Lenght L
Sound Velocity Vs = -----------
t Time t

Ultrasonic
Transmitter Receiver

21

Sound Velocity Sensor

The sound velocity is determined using the time an

ultrasonic pulse needs to travel through the liquid

22

11
 DPRn 427S

Installation directly in Pipe

Using Sound Velocity
Measurement

SPRn

TEMP : +16.14 °C
PER-D: 25 74.976 us
DENS: 1.33317 g/cm3
L ESC

ENTER
mPDS 1100
Ai-curr: 0.160 mA 06

mPDS 1100

23

Installation in Tank

Using Sound Velocity Measurement

mPDS 1100

TEMP : +16.14 °C
PER-D: 2574.976 us L ESC
DENS: 1.33317 g/cm3 ENTER
Ai-curr: 0. 160 mA 06

mPDS 1100
SPRn

24

12
 DPRn 427S

A li ti
Application
for

Rolling Oil
p
Phase Separation and Product Detection
Oil Concentration in Refrigerants

25

Viscosity
Transducers

13
 DPRn 427S

Content
Inline Viscometer L-Vis 510

Æ Measuring Principle

27

The Fluid Dynamic

Principle
Inline Viscometer L-Vis 510

28

14
 DPRn 427S

The Sensor Head

Inline Viscometer L-Vis 510

Deflection sensor Flange incl.

Temperature sensor sealing

Fixation

Measuring bob

Springlike
tube
29

The Measuring Gap

Inline Viscometer L-Vis 510

Springlike tube

Æ deflected by the
li id gap pressure
liquids

Flat projection of the measuring gap

parallel gap
deflection
25 mm

5 mm
0.75 – 1.2

0.25 – 0,75

sample

wedge shaped gap

- several bob types available Æ gap dimension

30

15
 DPRn 427S

This makes L-Vis Unique!

Inline Viscometer L-Vis 510

+ Temperature and viscosity measured inline

+ In position for a 24-hour production

+ New measuring principle “fluid dynamic viscometer”

+ Absolutely robust measurement

+ Non-sensitive against pressure drops and flow rate

+ Bringing together lab and process

+ Flexibility at installation (pipe, tank or bypass)

+ Inline installation

31

Installation
Inline Viscometer L-Vis 510

also see L-Vis 510 manual

several flange types available

- Anton Paar flange
- DIN or ANSI flange
- Varivent

Inline or bypass installation

32

16
 DPRn 427S

MAIN ADVANTAGES OF THESE 3

TECNIQUES

- Robust techniques
- Easyy Techniques
q
- Virtually maintenance free
- Very Accurate

33

Combining Tecniques

17
 DPRn 427S

Combining Techniques

„ How?
„ Why?
„ Examples.

35

mPDS 5 Evaluation Unit

How:

36

18
 DPRn 427S

New control unit: mPDS5

USB

PLC/Profibus
Ethernet
(Davis 5)
Relays
analogue and
digital I/O DC 24 V
Power Supply

1-2 DPRn/SPRn/DSRn
Carbo 2100/Inline viscometer/
flow stop signal

37

mPDS 5
Components/Interfaces
ƒ Full flexibility on sensor connection and prepared for
the future by (Standard configuration):
• Up to 2 AP-transducer (DSRn
(DSRn, DPRn
DPRn, SPRn)
• Up to 10 CAN sensors (Carbo 510, Inline Pump 5, L-Vis 510, etc.)
• Up to 5 Analog Inputs (scalable on the mPDS 5)
• Up to 4 Analog Outputs (scalable on the mPDS 5)
• Up to 24 Digital I/O‘s,
• Up to 2 Relays

ƒ Prepared for the future by various field buses such as:

• PROFIBUS, PROFINET, DeviceNet, EtherNet/IP, Modbus TCP

ƒ Davis 5 connected through standard Ethernet

38

19
 DPRn 427S

mPDS 5 Features I

The next step into evolution:

ƒ Large 8.4 " touch screen

ƒ Graphical trend

ƒ All results can be monitored

independently

ƒ Two line operation simultaneously

ƒ Alarms visible directly on the main

screen

ƒ Easy adjustment with reference values

(Laboratory adjustment)
39

mPDS 5 Features II

The next step into evolution:

ƒ Manual adjustment with offset and
gain
i factor
f t

ƒ 999 different products with

alphanumeric names

ƒ Communication with Davis 5

ƒ There
Th are functions
f ti for
f user
authorization, trouble shooting,
diagnosis, backup of instrument
settings, audit trail, data export, etc.

40

20
 DPRn 427S

mPDS 5 Screenshots

41

Combining Techniques

„ Why?
ƒBecause one technique is not sufficient
(eg Sulfuric acid)
ƒBecause we have more than a 2 component
mixture
ƒTo calculate new parameters out measured date

42

21
 DPRn 427S

Sulfuric Acid and Oleum

Sound Sound
Density Velocity Density Velocity
1600

2 00
2.00

1500
1.75

Sound velocity [m/s]

Density [g/cm3]

1400

1.50

1300
1.25

1.00 1200
0 90 100 114 % H2SO4
0 65 % Oleum
Concentration [%]

Density and sound velocity vs. concentration of Sulfuric Acid and Oleum at 40°C.
43

Acids
Online Measurement Using Density

DPRn 427 Tantalum/borosillicate glass

mPDS 5

Bypass installation
of the DPRn DPRn 427 Tantalum

Tantalum U-Tube
Bypass

Concentration range see graphs Temperature range 0 – 100 °C

44

22
 DPRn 427S

Sulfuric Acid and Oleum

Inline Measurement Using Sound
Velocity

Inline installation of
the SPRn
(gold-coated)

mPDS 5
SPRn 4115 L Gold
SPRn 4115 L Gold

Concentration range 90 – 100 % H2SO4 Temperature range 20 – 90 °C

45 – 65 % Oleum

45

Specifications (1)

Measuring Range

Density: 0 – 3 g/cm3

Velocity of sound: 1000 – 2000 m/s

Temperature: -25° – 125 °C (32 – 158 °F)

Sulfuric acid: 0 – 100 % H2SO4

Oleum: 0 – 65 % free SO3

Other Concentrations: application dependent

46

23
 DPRn 427S

Specifications (2)

Accuracy
0 – 100 % H2SO4: 0 02 % H2SO4
0.02
0 – 28 % free SO3: 0.04 % free SO3
28 – 65 % free SO3: 0.1 % free SO3
Other concentrations: application dependent,
typically 0.01 – 0.1 %
Repeatability, s.d.
D i :
Density 0.00005 g/cm3
Velocity of sound: 0.1 m/s
Temperature: 0.001 °C

47

Sulfuric Acid and Oleum

Benefits

ƒ Accurate determination over wide

concentration ranges:
• Accuracy: ± 0.05 % H2SO4

ƒ Continuous monitoring of the dilution process

ƒ Simple and robust method

ƒ Automatic temperature compensation

48

24
 DPRn 427S

Combining Techniques

„ Why?
ƒBecause one technique is not suficient
(eg Sulfuric acid)
ƒBecause we have more than a “2 component
mixture”
ƒTo calculate new parameters out measured date

49

Beer: Alcohol and Extract

Determination
Density number

Beverage density and sound number

CO2 influence

Water

Sound number

50

25
 DPRn 427S

Combining Techniques

„ Why?
ƒBecause one technique is not suficient
(eg Sulfuric acid)
ƒBecause we have more than a 2 component
mixture
ƒTo calculate new parameters out measured date

51

From Density/Sound Velocity/Conductivity

to Concentration
Laboratory experiment:
Determination of COD “chemical oxygen demand” in waste water
using density, sound velocity and conductivity.
Sound velocity

1525

1520

1515
Sound velocity [m/s]

1510

1505

1500 Density
~6,5 %
1,012
1495

1,010
1490
0 2 4 6 8 10 12 Conductivity
1,008
Concentration [%]
1,80
1,006
cm3]
Density [g/c

1,60
1,004
1,40
1,002
1,20
Conductivity [mS]

1,000 ~6,5 %
1,00
0,998
0,80

0,996
0,60
0 2 4 6 8 10 12
Concentration [%] 0,40 ~7 %
0,20

0,00
0 2 4 6 8 10 12
Concentration [%]

52

26
 DPRn 427S

COD Measurement
1,08

Density
1,06

1,04

1,02

Sound velocity
1

1.600,00
0,98 39,999

30,003
1.500,00
0,96 20,004

Dichte Dichte Dichte Dichte Dichte Dichte 10,005

bei 10 % bei 20 % bei 30 % Dichte Dichte
bei 40 % bei 50 % bei 60 % Dichte Dichte
1.400,00 bei 70 % bei 80 % bei 90 %
bei 100
%

1.300,00

1.200,00

1.100,00 39,999

30,003

1.000,00 20,004

US bei 10 US bei 20
US bei US bei 40 10,005
% US bei 50 US bei 60 US bei 70
% 30% US bei 80 US bei 90
% % US bei
% % % % 100 %

53

Example 2: Kinematic viscosity

27
 DPRn 427S

Kinematic viscosity

Definition
This is the dynamic viscosity divided by the
d it (typical
density it cm2/s,
(t i l units / Stokes,
St k St).
St)

Calculated values
We measure the Dynamic viscosity and
the density and calculate in the mPDS5
the kinematic viscosity

55

Are there any QUESTIONS??

56

28