NAO Adv Paper-2 (Phase-4)
NAO Adv Paper-2 (Phase-4)
NAO Adv Paper-2 (Phase-4)
▪ Please read the instructions carefully. You are allotted 5 minutes specifically for
this purpose.
▪ You are not allowed to leave the Examination Hall before the end of the test.
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Sections.
3. Section-I is Physics, Section-II is Chemistry and Section-III is Mathematics.
4. Each Section is further divided into Two Parts: Part-A & C in the OMR.
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic
devices, in any form, are not allowed.
(ii) PART–A (05–10) contains Six (6) Multiple Choice Questions which have One or More Correct answer.
Full Marks: +4 If only the bubble(s) corresponding to all the correct options(s) is (are) darkened.
Partial Marks: +1 For darkening a bubble corresponding to each correct option, provided NO incorrect
option is darkened.
Zero Marks: 0 If none of the bubbles is darkened.
Negative Marks: −1 In all other cases.
For example, if (A), (C) and (D) are all the correct options for a question, darkening all these three will result
in +4 marks; darkening only (A) and (D) will result in +2 marks; and darkening (A) and (B) will result in −1
marks, as a wrong option is also darkened.
(iii) PART–C (01-08) contains (08) Numerical based questions with single digit integer as answer, ranging from
0 to 9 (both inclusive) and each question carries +3 marks for correct answer. There is no negative marking.
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1. n identical cells, each of emf and internal resistance r, are joined in series to form a closed circuit. The
potential difference across any one cell is
(A) zero (B)
n −1
(C) (D)
N n
3. A magnet is suspended in such a way that it oscillates in the horizontal plane. If it makes 20 oscillations
per minute at a place-1 where dip angle is 30 and 15 oscillations per minute at a
B
place-2 where dip angle is 60. The ratio of earth’s total magnetic field 1 at the two places is
B2
(A) 16 : 93 (B) 163 : 9
(C) 16 : 1 (D) 1 : 16
4. A neutral particle at rest at A decays into two charged particles of different mass. Magnetic field is inside
the paper. Which can be correct paths for two particles if we ignore any gravitational and electrostatic
force?
(A) (B)
collision
A A
(C) (D)
A A
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This section contains 06 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONE OR MORE may be correct.
5. The separation between the plates of charged parallel plate capacitor (not connected with battery) is
increased. Which of the following quantities will change?
(A) charge on the capacitor (B) potential difference across the capacitor
(C) energy of the capacitor (D) energy density between the plates
6. A conducting spheres of radius R carrying charge Q lies inside an uncharged conducting shell of radius
2R. if they are joined by a metal wire
(A) Q/3 amount of charge will flow form the sphere to the shell
(B) 2Q/3 amount of charge will flow from the sphere to the shell
(C) Q amount of charge will flow from the sphere to the shell.
(D) kQ2/4R amount of heat will be produced.
7. A conductor AB carries a current I in a magnetic field B . If AB = r and the force on the conductor is
F,
(A) F does not depend on the shape of AB (B) F = i(r B)
(C) F = i(B r ) (D) F = i(r B)
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8. A current passes through a wire of nonuniform cross-section. Which of the following quantities are
independent of the cross-section?
(A) the charge crossing in a given time interval
(B) drift speed
(C) current density
(D) free-electron density
10. A prism is made of wire mesh with each side having equal resistance E
R. A battery of 6 V and zero internal resistance is connected across
E and F as shown in the figure. The current in the branch AD, if R is F
equal to 5 , is A B
(A) 0.6 A (B) 0.8 A
(C) 0.4 A (D) 2 A
D C
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This section contains 08 questions. The answer to each question is a single-digit integer, ranging from 0 to
9. The correct digit below the question number in the ORS is to be bubbled.
I4
I1
2. An electric field is given by E = yiˆ + xjˆ volt/m. The work done in moving slowly a charge of 10 C from
a point r1 = 3iˆ + 4ˆj to another r2 = 2iˆ + 6ˆj is
2 4
2V
6
3V
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5. A long straight wire of circular cross-section is made of a non-magnetic material. The radius of cross-
section of the wire is a. The wire carries a current I which is uniformly distributed over its cross-section.
n0I2
The energy stored per unit length in the magnetic field contained with the wire is . Find the value
64
of n.
1 2 3
11 A D
8. The voltage across capacitor in steady state is Volts.
k
7 6
Find the value of k. 6V
B E
10C
3 12
F
C
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This section contains 04 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONLY ONE is correct.
i) Aceticanhydride/pyridine
ii)KBrO3/HBr
¾¾¾¾¾ ¾ ¾ ¾ ¾ ¾ ¾ ¾®
iii)H3O+ ,heat
iv) NaNO2 /HCl, 273- 278 K
v)Cu/HBr
Br
Br
(A) (B)
Br Br
Br
Br
Br Br Br Br
(C) (D)
Br
2. KI in acetone, undergoes SN2 reaction with each of P, Q, R and S. The rates of the reaction vary as
O
Cl
H3C-Cl Cl
Cl
P Q
R S
(A) P > Q > R > S (B) S > P > R > Q
(C) P > R > Q > S (D) R > P > S > Q
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3. Among cellulose, polyvinyl chloride, nylon and natural rubber, the polymer in which the intermolecular
force of attraction is weakest is
(A) Nylon (B) Polyvinyl chloride
(C) Cellulose (D) Natural Rubber
4. OH O O
−
OH /
H3C CH CH2 C H ⎯⎯⎯ ⎯→ H3C CH CH C H
Expected mechanism is
(A) E1 (B) E1cb
(C) E2 (D) none
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5. KMnO4 / H+ ,
Y
OH
⎯⎯⎯⎯⎯
30% H2SO4
→W + X
(major ) (minor )
OH KMnO4 / H+ ,
Z
Of the 4 compounds listed above, more than one will:
(A) exhibit resonance due to conjugation in their structure
(B) show NaHCO3 test
(C) have a cyclic structure
(D) show 2,4-DNPH precipitation
, CHO
H2CO and
O COOH
CH3 CH CH COCH
2 2 3
Which of the following structure(s) can not be of agathene dicarboxylic
(A) H C COOH (B) H C COOH
3 3
CH2 CH2
CH3 CH3
COOH COOH
(C) COOH (D) COOH
H3C H3C
CH2 CH2
COOH COOH
CH3 CH3
CH3 C2H5
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H O/
HNO ⎯⎯⎯⎯
2
→Q
OH ⎯⎯⎯⎯
2
→P Cl
NH2
(C) O (D) O
+
HO
H3C C OC2H5 ⎯⎯⎯→
3
R
SeO
⎯⎯⎯
2
⎯
→S
8.
Cl
⎯⎯⎯⎯⎯
KCN(1 eq.)
→(A) ⎯⎯⎯→
H2 /Pt
B
Cl
Correct statement for product B is
(A) It is gives positive carbyl amine test
(B) It gives coupting reaction with diazonum salt
(C) It gives alcohol on treatment with nitrous acid
(D) It forms dibromo derivative with bromine water
9. CH3
Br CH Ph
(1) Mg, ether
⎯⎯⎯⎯⎯
( 2) Ph − CHO →
( 3 ) H3 O+
N N
H H
The given product cannot be obtained in the above reaction. Identify the correct product obtained.
(A) (B)
N CH Ph N
H HC Ph
OH
OH
(C) OH (D) O
CH C
Ph Ph
N N
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10. NH2
O
+ →P (Product ) . P can not be
⎯⎯
O
H2C
CH3
(A) O O (B) O
HN C CH2 C CH3 HN C CH3
CH3
CH3
(C) NH2 O O (D) NH2 O
C CH2 C CH3
CH3 CH3 O
This section contains 08 questions. The answer to each question is a single-digit integer, ranging from 0 to
9. The correct digit below the question number in the ORS is to be bubbled.
P + Br2
1. CH3 CH2 COOH ⎯⎯⎯ → A ⎯⎯⎯
NH3
→ B
( C3H5BrO2 ) C3H8NO2
If dl ( ) mixing of (B) heated then the possible. Number of stereo isomer formed are……….
2. O
C OCH3
HO
⎯⎯⎯⎯⎯
HO
dry HCl( g )
→ ( X )(Major product )
CHO
Degree of unsaturation of ‘X’ is……………..
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3. How many of the following acids are relatively more acidic than acetic acid?
COOH COOH COOH
CH3 OCH3
(A) (B) (C)
Cl
COOH OH
O 2N NO 2
(D) (E) (F) H2CO3
NO 2 NO 2
COOH
OH
I
(G) HCOOH (H) (I)
4. O
C H () i OH−
⎯⎯⎯⎯
(ii) H+ /
→ ' X'
C CH3
O
Find degree of unsaturation of ‘X’.
Ph O O CH3
| || || |
5. When H − C − C− NH2 , CH3 − C− NH2 and H − C − CONH2 are mixed and reacted with Br2/KOH than
| |
D D
how many 1 amines are obtained.
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6.
N I ⎯⎯⎯
AgOH
→ (A) + tertiary amine
Major hydrocarbon
H+ / H2 O
(D ) + ( C ) ⎯⎯⎯
I /NaOH
2
⎯ (B )
M3 +
, , , ,
OH O
OH NO2
8. How many of the following compounds give white precipitate when treated with HIO4 followed by AgNO3
CH2OH H C O H C O H C O CH2OH
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This section contains 04 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONLY ONE is correct.
x3 + x − 2 x2 + x + 2
1. If f(x) = and g(x) = then (Df represents domain and Rf represents range of f(x))
x3 − 1 x2 + x + 1
7 4 7
(A) Df = R – { 1 } Rf = 1, − (B) Df = R – {1} Rf = 1,
3 3 3
7 7
Dg = R Rg = 1, Dg = R Rg = 1,
3 3
7 7
(C) Df = R – {1} Rf = 1, (D) Df = R – {1} Rf = 1,
3 3
7 7
Dg = R Rg = 1, Dg = R Rg = 1,
3 3
4. A survey shows that 63% of the Americans like cheese whereas 76% like apples. If x % of the
Americans like both cheese and apples, then
(A) x = 39 (B) x = 63
(C) 39 x 63 (D) none of these
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This section contains 06 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out
of which ONE OR MORE may be correct.
5. Let f be a polynomial function satisfying f(x2) – xf(x) = x4(x2 – 1) = 0 x R+. Then, which of the following
is correct
(A) f is an even function
(B) f is an odd function
f (x)
(C) lim 3 = 1
x → x
f (x)
(D) lim 2 − x exists and is equal to a non-zero quantity
x →
x
n2 1! 2! ..... n!
6. If lim = , where is a non-zero real number, then
n→ n
3 1
(A) = (B) =
4 2
(C) = e−3/4 (D) = e−1/2
7. If f(x) is a non-increasing function such that f ( x ) + f '' ( x ) 0 x R & f ( 0 ) = f ' ( 0 ) = 0 then f(x) is not
strictly decreasing in
(A) −4, −2 (B) −2,2
(C) 3,4 (D) 2,4
8. Let f(x) = 5x tan x + 8 sin(tan x) + 5 ln(cos x), then in the interval − , 0
4
(A) f(x) is increasing (B) f(x) has a point of local maxima
(C) f(x) has a root (D) f(x) is always negative
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3n −1 3n
r
rn rn
9. Tn = , Sn = , then n {1, 2, 3, …}
r = 2n
2
+n 2
r = 2n +1 r
2
+ n2
1 1
(A) Tn > ln2 (B) Sn < ln2
2 2
1 1
(C) Tn < ln2 (D) Sn > ln2
2 2
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1. Let A and B have 3 and 6 elements respectively. What can be the minimum number of elements in
A B?
x2
(sin t ) dt
2. Lim
x →0 x3
is equal to k, then the value of 3k is _____
0
x3 + 1 x5 − x3
1
3. I1 = 5 dx and I2 = 5 dx , then I1 + 2I2 is equal to ____________
− x + 1 −1 x + 1
1 1 1
4. If f(x) = 3x2 sin − xcos , x 0, f(0) = 0 then the value of f is _____
x x
f (101) k
6. If f(x) = (x – 1)100 (x – 2)2(99) (x – 3)3(98) … (x – n)100, let k = , then − 97 is ____________
(
f 101 ) 50
2 2
7. If k = lim sec −1 − exist, then the minimum value of [||] is ____________ (where [.] denotes
x →1 ln x x − 1
the greatest integer function)
8. Let f: A → B be an onto function where A = {1, 2, 3, 4}, B = {x, y, z} also f(1) = x. Let M be total such
M
functions then the value of is ____
2
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FIITJEE INTERNAL
TEST
PHYSICS, CHEMISTRY & MATHEMATICS
CPT–1 QP CODE: PAPER–2
ANSWERS
PHYSICS (SECTION –I)
PART – A
1. A 2. C 3. A 4. A
5. B, C 6. C, D 7. A, B 8. A, D
9. A, C, D 10. C
PART – C
1. 2 2. 0 3. 9 4. 5
5. 4 6. 0 7. 3 8. 5
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SOLUTION
PHYSICS
PART – A
1. A
n
i= =
nr r
Voltage across one cell = −ir
= − r = 0
r
2. C
q q 3 q
− =
0 4 0 4 0
3. A
60 60
T1 = , T2 =
20 15
I
T = 2 , = dip angle
MBcos
60 I
= 2 …(i)
20 MB1 cos30
60 I
= 2 …(ii)
15 MB2 cos 60
From (i) and (ii)
B1 16
=
B2 9 3
4. A
Momentum of both particles are same and in opposite direction as well as they have equal and
opposite charges
mv P
r= =
qB qB
So, r is same for both particles also force on moving charge particle = q(V B)
5. B, C
0 A
C=
d
If d, C and V
1 Q2
Energy = , so energy
2 C
2
1 1 Q
Energy density = 0E 2 = 0 = constant
2 2 A 0
6. C, D
If inner sphere and outer sphere are connected charge flows to outermost surface of outer sphere.
1 Q2 1 Q2 KQ2
Loss = Ui − Uf = − =
2 40R 2 40 (2R) 4R
7. A, B
F = i(r B) independent of shape of AB if B field is uniform
8. A, D
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i
Current density (J) =
A
eE
and drift speed
m
Also J = E
If A, J and hence E
So, drift speed
9. A, C, D
W.D. = P.E. due to field
= − 0 ( ) = − 0 2
20 2 4 0
A, C are wrong
VB − VA = −
A 0
D is wrong
10. C
The voltage at D and C are equal also voltage at A C B
and B are equal
Current in D A
6 2
AD = = = = 0.4A F E
3R 3 5 5
PART – C
1. 2
B d = (8 − 4 − 6)0 = −20
2. 0
2,6
3. 9
1
U= 2 32 = 9 J
2
4. 5
2Q1 Q2 Q3 Q1 −Q1 Q1 −Q1 Q2 −Q2 Q3 −Q3
+ + =0
C C C
Q2 − Q1 = 4Q and Q3 – Q2 = 2Q
5Q
Solving Q1 = −
2
5Q
VA − VB = .
2C
5. 4
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u 0I2
=
16
6. 0
charge distribution on 3 plates
u2 = 0
(since E is zero between 2nd and 3rd plate) 3Q −2Q 0 3Q
2Q 0
1 2 3
7. 3
= − qE
qE
= −
I
qE
=
I
1 3qE
f= =
2 2 2m
2 2
2 2m 2
Here I = 2m + m =
3 3 3
Dipole rotates about its center of mass
8. 5
Figure shows potential distribution in steady state A D
VA − VB = 4.2V
6R
VD − VE = 2V 6V (7×6)/10 7R 6×6/18
From the above equation we get –+
VE − VB = 2.2V B
10C
(3×6)/10 3 12
6×12/18
F
C
CHEMISTRY
PART – A
1. O O
NH2 HN C CH3 HN C CH3 NH2 N2 Cl Br
( CH − CO ) O +
⎯⎯⎯ →
⎯⎯⎯⎯⎯ → ⎯⎯⎯⎯ →
Cu
⎯⎯⎯⎯⎯ → ⎯⎯⎯ →
3 2
KBrO3 /HBr H3 O NaNO2
C5H5N HCl HBr
Br Br Br Br
S P R Q
More steric hindrance
Less hindrance
O
Due to − I of H5C6 C group
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5. O
O O
C O
H3C CH3
W O
X Y
O O
Z
7. O
P=
Q=
O
−
R= CH3 COOH + C2H5 OH ; C2H5 OH ⎯⎯⎯⎯⎯⎯⎯
Oxidation by XO
→ CH3CHO
O
O
S=
8.
Cl ⎯⎯⎯
KCN
→ Cl ⎯⎯⎯
H2Pt
→ Cl
Cl CN NH2
9. Br MgBr
⎯⎯⎯⎯⎯→
Mg/ dry ether
()1 Ph − CHO
⎯⎯
→ ⎯⎯⎯⎯⎯
( 2 ) H O+
→
3
N N N N
H H HC Ph
OH
10. O OH
HN C CH2 C CH2
O
H3C NH2
O
H2C Tautomerise
CH3
O O
HN C CH2 C CH3
CH3
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PART – C
1. CH3
CH3 CH2 COOH ⎯⎯⎯
→ H3C CH HVZ
COOH HC COOH
Br NH2
O H
N
H3C CH3
N
OH
3 isomer possible
2. O O
C O CH3 C OH
⎯⎯⎯
HCl
→ O CH2
O CH2
HC HC
O CH2 O CH2
(X), degree of unsaturation = 6
3. Except (F) and (I) all are relatively more acidic than acetic acid.
4. O O
C CH3 C CH3
O O
OH
C H CH H − OH +
⎯⎯⎯
OH−
→ ⎯⎯⎯ → H /
⎯⎯⎯ →
C CH3 C CH3
O O
H
5. It is Hofmann’s Bromamide reaction and in this reaction cross over products are not obtained.
6. OH
CH3 CH = CH2 H3C CH CH3 CH3 COO− CHI3
(A)
(B ) (C) (D )
→ Fe ( CH3 COO )3
3CH3 COO ⎯⎯⎯ − Fe3+
7. OH O OH COOH
NO2
,
and
OH O
NO2
8. HC O HC O CH2OH
CH2OH , C O , CHOH
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MATHEMATICS
Part − A
1. D
x3 + x − 2 x − 1 x + x + 2 x + x + 2
2 2
f(x) = f (x) = = , when x 1
x3 − 1 x − 1 x 2 + x + 1 x 2 + x + 1
7
Hence range is 1, .
3
2. A
1/ h2
tan−1 h
lim x 2
ln ( x cot −1 x )
= lim ln
x → h →0 h
h3 h5
h − + − ..... − h
1 tan h −1
− 1 = lim
3 5 1
= lim 2 =−
h →0 h h h →0 h3 3
3. C
1
x2
y = f (x) = 2−t +c y = x
2
ln2 + c .
0
4. C
Let A denotes the set of Americans who like cheese and B denote who like apples. Let the population
of Americans is 100. Then,
n(A) = 63 and n(B) = 76.
Now, n(A B) = n(A) + n(B) − n(A B)
n(A B) = 139 − n(A B).
But n(A B) 100, so that n(A B) 39.
Further, A B A and A B B imply that n (A B) n(A) and n(A B) n(B) that is
n(A B) 63 and n(A B) 76]
Hence, 39 n(A B) 63 39 x 63.
5. B, C
( ) ( )
f x 2 − xf ( x ) = x 4 x 2 − 1
xf ( x ) − x f ( x ) = x x ( x ) − x
2
2 2 2 2 2
f (x ) f (x)
2
= (x ) − x
2
2
− 2 2
x x
f (x )
2
f (x) f (x ) 4
− (x ) = − (x )
2 2
2
2
−x = 2
4
4
.....
x x x
f (x)
− x 2 = k (has infinite solutions)
x
f(x) – x3 – kx = 0 has infinite roots
f(x) = x3 + kx
f (x) f (x) k
Hence f is odd, lim 3 = 1 , lim 2 − x = lim x + − x = 0
x → x x → x x → x
6. B, C
1
ln = lim [ln 1 + (ln 1 + ln 2) + (ln 1 + ln 2 + ln 3) + .....] – ln n
n → n2
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1 2 n n ( n + 1)
nln + ( n − 1) ln + ..... + ln + lnn
n + 1 − 2n 1 n n + 1− r r
= lim
n→
n n
n2
n 2 − lnn = lim
n→ 2n
lnn +
n r =1 n
ln
n
1
1 3
=
2
and ln = (1 − x ) ln x dx = − 4
0
7. B, C, D
f '(x) 0
f ( x ) f ' ( x ) + f ' ( x ) f '' ( x ) 0
d
dx
( (
f ( x )) + ( f ' ( x )) 0
2 2
)
( )
f 2 ( x ) + ( f ' ( x ) ) f 2 ( 0 ) + ( f ( 0 ) ) x 0
2 2
f ( x ) = 0 x 0
8. A, D
f(x) = 5x tan x + 8 sin(tan x) + 5 ln (cos x), x − , 0 f(x) = sec2 x·(5x + 8 cos (tan x))
4
Now let g(x) = 5x + 8 cos(tan x). So, g(x) = 5 – 8 sin(tan x) sec2 x > 0 in − , 0
4
5 5 1 16 − 5
So, g(x) is increasing. So, for x > − , g(x) > g − = − + 8cos1 − + 8 = 0
4 4 4 4 2 4
So, f(x) > 0. So, f(x) is increasing in − , 0 . Also at x = 0, LHL = 0. So, f(x) < 0 x − , 0 .
4 4
9. A, B
3
x
Sn < 1+ x
2
2
dx Tn n N.
10. B, C
tan 2 2 tan2 2 sec 2
I= sec 3 2d = sec 2 2 sec 2 d =
2
sec 2 − 2
d
tan 2 1
2I = sec 2 + ln sec 2 + tan 2 + c
2 2
tan 2 1
I= sec 2 + ln sec 2 + tan 2 + c
4 4
Part − C
1. 6
A B will contain minimum number of elements if A B and in this case n(A B) = n(B) = 6.
2. 2
d
x
We know f(t) dt = f(x)
dx 0
x2
(sin t ) dt
Hence Lim . Let t = u then dt = 2u du
x →0
0 x3
2x sin x 2 sin x 2
Lim = Lim =
x →0 3x 2 3 x →0 x 3
3. 4
1
(x 5
) (
+ 1 − x3 + 1 ) dx 1 1
x3 + 1
I2 = x +1 5
= dx − x5 + 1 dx
−1 −1 −1
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−1
x3 + 1 x3 + 1 x3 + 1
1
Again I1 = 5 dx + 5 dx + x5 + 1 dx
− x + 1 −1 x + 1 1
x3 + 1
1
1
Putting x = in first and third part in I1, we get I1 = 2 5 dx
−1 x + 1
t
I1
I2 = 2 −
2
I1 + 2I2 = 4
4. 0
1 1
f(x) = 3x2 sin − x cos
x x
1 1
f(x) = (3x2 sin − xcos ) dx
x x
1 3 1 1 3 1
f(x) = sin .x − cos − 2 x dx − x cos dx
x x x x
1
f(x) = x3 sin + c
x
f(0) = 0 + c = 0 c = 0
1
f(1/) = 3 . sin + 0 = 0.
5. 1
2f ( x ) f ( x )
− 2x 0
d
( )
sin−1 ( f ( x ) ) − x 2 0
2
1− ( f ( x ))
4 dx
Let g(x) = sin–1((f(x))2) – x2 is a non-decreasing function.
lim + g ( x ) lim − g ( x )
x → x1 x → x2
− x12 − x 22
2 6
x12 − x 22 x12 − x 22 1.
3
6. 4
100
( x − i)
i(101−i )
f(x) =
i=1
100
ln(f(x)) = i (101 − i) ln ( x − i)
i=1
i (101 − i )
100
1
f(x) =
(
f x) i=1
( x − i)
f (101)
100
101 − i
k=
f (101)
= i 101 − i = 5050
i=1
k
− 97 = 4.
50
7. 1
2 2
lim sec −1 −
x →1 ln x x − 1
let x – 1 = t x = t + 1 as x → 1, t → 0
2 2 −1
2
t
lim sec −1 − = lim sec − 1
t →0 ln ( t + 1) t t →0 t ln ( t + 1)
2
= lim sec −1
t →0 2
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2
1 | | 2
2
Hence minimum value of [||] = 1.
8. 6
M
M = 3C1 2! + 3C2 2 = 12 = 6.
2
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