Pge 2017 Presentation Hydrogen Co Firing Larfeldt Siemens

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Hydrogen Co-Firing in

Siemens Low NOX


Industrial Gas Turbines
Adj Professor Jenny Larfeldt
Senior Combustor Expert

© Siemens AG 2017 All rights reserved. siemens.com/power-gas


Table of content

• Fundamentals on H2 co-firing
• From fundamentals to real engines
• Atmospheric combustion rig test
• Pressurized single burner test
• Pressurized single can test
• Next steps

© Siemens AG 2017 All rights reserved.


Page 2 June 2017 J. Larfeldt / Siemens AG AL: N ECCN: N
Fundamentals on H2 co-firing 1(2)

100
1. 100 % H2
90 Heavy hydrocarbons 2. 75/25 H2/N2
80 3. 50/50 H2/N2
Wobbe Index [MJ/Nm3]

70

60

50 Standard range NG WI: 42 to 53 MJ/nm3


1
40 120
30
High H2
20
2
10
3
0
0 10 20 30 40 50 60 70 80 90
Lower Heating Value [MJ/kg]
© Siemens AG 2017 All rights reserved.
Page 3 June 2017 J. Larfeldt / Siemens AG AL: N ECCN: N
Fundamentals on H2 co-firing 2(2)

H2 has ten times higher flame speed compared to natural gas.


CH4-air

Co-firing H2 and CH4/C2H6/C3H8


− H2 < 60 vol-%: slight increase in burning velocity
and chemistry hydrocarbon dominated
− 60 < H2 < 90 vol-% intermediate regime
− H2 > 90 vol-% dramatic increase in laminar
burning velocity and chemistry is hydrogen
dominated. CH4(75%)-H2(25%)-air

Φ=1.0 and p=3 atm.

© Siemens AG 2017 All rights reserved.


Page 4 June 2017 J. Larfeldt / Siemens AG AL: N ECCN: N
From fundamentals to real engines
SGT-800 / 53MW

− 30 DLE burners of so called 3rd generation in an annular combustor


− Air entering combustor with about 20 bar and 700 K

https://www.youtube.com/watch?v=uY-iQYpO_a8

© Siemens AG 2017 All rights reserved.


Page 5 June 2017 J. Larfeldt / Siemens AG AL: N ECCN: N
From fundamentals to real engines
Step 1. Atmospheric combustion rig test

© Siemens AG 2017 All rights reserved.


Page 6 June 2017 J. Larfeldt / Siemens AG AL: N ECCN: N
From fundamentals to real engines
Step 2a. Pressurized single burner test 1(2)
Engine stack
Emissions probe

Engines 16
circumferential
T7 probes
Engine Dynamics probes
-Outer
-Inner

36MW generator

EBIT experimental burner:

Single burner feed in engine Separate fuel feed EBIT Boroscope probe
EBIT
Extra instrumentation including Emissions probe 0% H2 12%
dynamics measurement
H2

20% 32% H2
H2

© Siemens AG 2017 All rights reserved.


Page 7 June 2017 J. Larfeldt / Siemens AG AL: N ECCN: N
From fundamentals to real engines
Step 2. Pressurized single burner test 2(2)

− Customer had a constant flow of hydrogen


corresponding to approximately 0.5 ton/h.
− For a SGT-700 this resulted in hydrogen content in
the fuel varying between 50-75 % for loads
between 27 and 10 MW.
− A small increase of NOX was seen as hydrogen
content increases, but the increase is only significant
above 45 % hydrogen.
− The 2014 tests confirmed the possibility to run the
SGT-700 on high hydrogen fuels with results indicating
that 40-50 % H2 is possible at high loads.
− At 10 MW load, 100 % H2 was tested and it was fully
possible to run, but the hydrogen flow had to be
doubled and NOX emissions were about 60 % higher
than the high load emissions.
2nd Oct 2014

© Siemens AG 2017 All rights reserved.


Page 8 June 2017 J. Larfeldt / Siemens AG AL: N ECCN: N
Additive manufacturing of SGT-600/700/800 standard burner
Rapid prototyping speeds up development

Traditionally manufactured burner front SLM adapted burner front

− 13 machined parts, joined by 18 welds. − One single part


− External pilot gas feed − Pilot gas feed integrated in structure
− Weight: 4.5 kg − Lead time reduction of >75%
− Weight: 3.6 kg

© Siemens AG 2017 All rights reserved.


Page 9 June 2017 J. Larfeldt / Siemens AG AL: N ECCN: N
From fundamentals to real engine SGT-750
Step 2b. Pressurized single can test

© Siemens AG 2017 All rights reserved.


Page 10 June 2017 J. Larfeldt / Siemens AG AL: N ECCN: N
Conclusions

Next steps:
− SGT-800 string test with 50 vol% H2 co-firing (Aug 2017)
− Co-firing with 15 vol% H2 in SGT-800 at Industriepark Höchst,
Frankfurt (Dec 2017).
− Burner design for 100% H2 to be tested at pressure in
Siemens combustion test facility in Berlin (ongoing R&D).
− SGT-750 scaled burner tests for NH3/N2/H2 mixtures
together with universities.

Gas Fuel Constituents SGT-800 SGT-750 SGT-700 SGT-600


mole % mole % mole % mole %
Methane, CH4 100 100 100 100
Ethane, C2H6 100 35 100 100
Propane, C3H8 100 30 100 100
Butanes and heavier alkanes, C4+ 15 15 15 15
Hydrogen, H2 30 15 40 40
Carbon monoxide, CO 40 40 40 40
Inerts, N2/CO2 50/40 50/40 50/40 50/40

© Siemens AG 2017 All rights reserved.


Page 11 June 2017 J. Larfeldt / Siemens AG AL: N ECCN: N
Thank you for your attention

Ajdunct professor Jenny Larfeldt


Senior Combustor Expert
PG DG GPS CTV
Slottsvagen 3
612 38 Finspång
Phone: +46 122 82 789
Mobile: +46 70 180 14 147
E-mail:
[email protected]

siemens.com

© Siemens AG 2017 All rights reserved.


Page 12 June 2017 J. Larfeldt / Siemens AG AL: N ECCN: N
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