CHE502 Assignment 1 Mar-Aug 2023 (20232)
CHE502 Assignment 1 Mar-Aug 2023 (20232)
CHE502 Assignment 1 Mar-Aug 2023 (20232)
ASSIGNMENT 1
APRIL 2023
(PO1, PO2, CO1, CO2)
NAME
STUDENT ID
GROUP CEEH2204_
MARKS
Q1
Q2 PO1, CO1
Q3
Q4 PO2, CO2
In a 1 L batch reactor, 1 mol/L carbonic acid decomposes into carbon dioxide and
water at room temperature and atmospheric pressure. An online system of gas
chromatography has recorded the concentration of carbonic acid, C A, carbon
dioxide, CP and water, CS over a period of time.
t (s) 60 120 180 240 300 360 420 480 540 600 660 720
CA
0.74 0.548 0.406 0.306 0.223 0.162 0.122 0.090 0.067 0.05 0.035 0.025
(mol/L)
CP
0.172 0.300 0.395 0.465 0.517 0.556 0.585 0.606 0.621 0.633 0.648 0.65
(mol/L)
CS
0.026 0.150 0.197 0.232 0.258 0.278 0.292 0.303 0.301 0.316 0.324 0.32
(mol/L)
1. Write a possible chemical reaction equation and general rate law for this
reaction. State the classification of this reaction.
(4 marks)
2. The rate constant and reaction order of this decomposition reaction can be
evaluated using a differential graphical analysis method. State the overall order of
the reaction and rate constant for this reaction.
(9 marks)
3. Express the rate law based on concentration and conversion obtained from a
well organized stoichiometric table presented in your answer.
(8 marks)
4. A final year student was then instructed by his supervisor to elevate the
temperature of the decomposition reaction of carbonic acid to up to 60 oC and the
value of reaction speed was recorded according to temperature elevation. The
recorded data is as follow: