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    Quiz - GRP A

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    SAURABH PANDEY
    The document is a quiz for an inorganic and physical chemistry course. It contains 10 multiple choice questions (1A-1J) worth 1.5 marks each, with a wrong answer carrying a -5 marks penalty. It also contains 5 additional short answer/calculation questions worth between 5-10 marks each on topics relating to quantum mechanics, wave-particle duality, black body radiation, de Broglie wavelength, particle behavior in one-dimensional boxes, and normalization of wavefunctions. The total marks for the quiz are 40.

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    © All Rights Reserved
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    Quiz - GRP A

    Uploaded by

    SAURABH PANDEY
    60 views2 pages
    The document is a quiz for an inorganic and physical chemistry course. It contains 10 multiple choice questions (1A-1J) worth 1.5 marks each, with a wrong answer carrying a -5 marks penalty. It also contains 5 additional short answer/calculation questions worth between 5-10 marks each on topics relating to quantum mechanics, wave-particle duality, black body radiation, de Broglie wavelength, particle behavior in one-dimensional boxes, and normalization of wavefunctions. The total marks for the quiz are 40.

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    Quiz_grp a

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    The document is a quiz for an inorganic and physical chemistry course. It contains 10 multiple choice questions (1A-1J) worth 1.5 marks each, with a wrong answer carrying a -5 marks penalty. It also contains 5 additional short answer/calculation questions worth between 5-10 marks each on topics relating to quantum mechanics, wave-particle duality, black body radiation, de Broglie wavelength, particle behavior in one-dimensional boxes, and normalization of wavefunctions. The total marks for the quiz are 40.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    60 views2 pages

    Quiz - GRP A

    Uploaded by

    SAURABH PANDEY
    The document is a quiz for an inorganic and physical chemistry course. It contains 10 multiple choice questions (1A-1J) worth 1.5 marks each, with a wrong answer carrying a -5 marks penalty. It also contains 5 additional short answer/calculation questions worth between 5-10 marks each on topics relating to quantum mechanics, wave-particle duality, black body radiation, de Broglie wavelength, particle behavior in one-dimensional boxes, and normalization of wavefunctions. The total marks for the quiz are 40.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 2

    Rajiv Gandhi Institute of Petroleum Technology

    Quiz-1
    Course Inorganic & Physical Chemistry
    Course Code CY111
    Full Marks 40
    Date & Time 10/Feb/2022, 9:15 AM- 10:00 AM

    1A- to- 1J : MCQ, each question carries 1.5 marks each, one wrong answer carries -5 marks.

    1A. The concept that all microscopic physical entities have both wave & particle properties is
    called wave-particle:

    (a) Singularity (b) Triality (c) Infinality (d) Duality (e) Intellectuality

    𝟏𝟓𝒉𝟐
    1B. The number energy states possible in the range 𝑬 < 𝟖𝒎𝒂𝟐 of a cubic box of side ‘a’ is

    (a) 03 (b) 6 (c) 12 (d) 12 (e) 15

    1C. The wave function for a quantum mechanical particle in a 1-D box of length “l” is given by  = A.
    Sin (x/L). The value of ‘A’ for a box of length 50 cm is

    (a) 0.1 (cm)-1/2 (b) 0.2 (cm)-1/2 (c) 5√2 (cm)-1/2 (d) √2/10 (cm)-1/2 (e) 0.00

    1D. In the probabilistic interpretation of wave function , the ||2 is:

    (a) probability (b) probability (c) negative (d) 1.00 (e) 0.00
    amplitude density probability

    1E. According to wave mechanics, a material particle is associated with :


    a) a single wave, b) a wave packet, c) progressive wave, d) light wave

    1F. When two particles are entangled and it is observed that one has its spin up, how long does it
    take for the other’s spin to be down?

    a) Instantaneously b) 1 microsecond c) 1 nanosecond, d) 1 femtosecond, e) Speed of light

    1G. The Dirac equation shows that every particle has

    (a) (b) (c) (d) (e)


    Wave function An Antiparticle A Matrix A duality Uncertainty
    1H. When one operates with d2/dx2 on the function 6 sin(4x), one finds that

    a) the function is an eigenfunction with eigenvalue -96.


    b) the function is an eigenfunction with eigenvalue 16.
    c) the function is an eigenfunction with eigenvalue -16.
    d) the function is not an eigenfunction.
    e) None of the above is a true statement.

    1I. Indicate which of the following functions are “acceptable.”

    a) ψ = x
    b) ψ = x2
    c) ψ = sin x
    d) ψ = exp(-x)
    e) ψ = exp(-x2)

    1J. The reason for normalizing a wavefunction ψ is

    a) to guarantee that ψ is square-integrable.


    b) to make ψ*ψ equal to the probability distribution function for the particle.
    c) to make ψ an eigenfunction for the Hamiltonian operator.
    d) to make ψ satisfy the boundary conditions for the problem.
    e) to make ψ display the proper symmetry characteristics.

    2 How does Planck’s Theory explain Black Body Radiation? 5


    3 Calculate the de Broglie wavelength in nanometers for each of the following:
    a) An electron that has been accelerated from rest through a potential change of 5
    500V.
    b) A bullet weighing 5 gm and traveling at 400 m s-1
    4 Consider an electron in a one-dimensional box of length 258 pm. 10
    a) What is the zero-point energy (ZPE) for this system? For a mole of such systems?
    b) What electronic speed classically corresponds to this ZPE? Compare to the speed of light.
    5 For a particle in the n=2 state in a one-dimensional box of length L, 10
    a) By sketching estimate the probability, ρ, for finding the particle between x =0 and x
    =0.20L.
    b) calculate the probability using wave functions.
    c) what probability for finding the particle between x =0 and x =0.20L is predicted
    by classical physics?

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