12 PDF
12 PDF
12 PDF
Team:
Sonal Kumar
Sameer Maithel
Contents
1 Brick Firing Process in the Kilns ................................................................................................. 2
1.1 Steps in brick making ......................................................................................................... 2
1.2 Firing process in the kilns ................................................................................................... 2
1.2.1 Heating: ...................................................................................................................... 3
1.2.2 Soaking: ..................................................................................................................... 5
1.2.3 Cooling: ...................................................................................................................... 5
1.3 Quality of fired bricks .......................................................................................................... 6
2 Introduction to Brick Kilns ........................................................................................................... 7
2.1 Classification based on nature of production process .......................................................... 7
2.1.1 Intermittent kilns ......................................................................................................... 7
2.1.2 Continuous kilns ......................................................................................................... 8
2.2 Classification based on air flow......................................................................................... 10
3 Fuels ....................................................................................................................................... 12
3.1 Relevant fuel properties.................................................................................................... 12
4 Specific Energy Consumption .................................................................................................. 15
4.1 Definition .......................................................................................................................... 15
4.2 Measurement of energy input (external and internal fuel) .................................................. 15
4.3 Measurement of weight of fired bricks............................................................................... 16
4.4 Determination of SEC of intermittent/batch kilns ............................................................... 17
4.5 Determination of SEC of continuous kilns ......................................................................... 18
4.6 Precautions ...................................................................................................................... 19
4.7 Uncertainty analysis in the measurement of SEC.............................................................. 19
4.7.1 Uncertainties in Products and Quotients ................................................................... 19
4.7.2 Uncertainty in SEC ................................................................................................... 19
4.8 Significance of Specific energy consumption .................................................................... 20
5 Instruments for energy monitoring ............................................................................................ 21
5.1 Weighing balance ............................................................................................................. 21
5.2 Thermocouple .................................................................................................................. 21
5.3 Infrared thermometers ...................................................................................................... 21
5.4 Moisture meter ................................................................................................................. 22
5.5 Bomb calorimeter ............................................................................................................. 23
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1 Brick Firing Process in the Kilns
The typical steps involved in brick making process are – clay preparation, moulding, drying
of green bricks and then firing. Figure 1 below represents the process flow in the brick
making.
Firing is the last operation in brick making process. Green bricks are fired in the kilns to
convert a fairly loosely compacted blend of different minerals into a strong, hard, and stable
product i.e. fired brick. The firing process determines the properties of the fired brick —
strength, porosity, stability against moisture, hardness etc. Depending on nature of clay and
quality of fired brick requirement, bricks are fired in a temperature range of 800–1100oC.
The overall firing process can be categorized in three steps – heating, soaking and cooling.
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Figure 2: Steps in brick firing process
The important physical and chemical changes occurring in the brick during firing are briefly
explained in the subsequent sections. It is important to understand these changes as they
form the basis for proper operation of a brick kiln.
1.2.1 Heating:
Heating of clay leads to removal of moisture and carbonaceous material, chemical changes
and colour change in the final product. A detailed description of the various processes during
clay heating process is explained below.The chemical and physical changes occurring at
different temperatures during the clay heating process are represented in Figure 3 and are
explained below.
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Figure 3: Changes occurring in brick during heating of green bricks
1. Removal of mechanical moisture: About 25-30% of water is added to clay during the
hand-moulding or extrusion process. While most of the moisture is removed during
drying, generally 3-10% moisture still remains with bricks while loaded in the kiln due to
different climatic conditions. The first stage of heating involves removal of this moisture
(drying). Almost all the mechanically held water is evaporated when temperature of the
bricks reaches around 150 0C. However, the clay still retains its original characteristics.
4. Quartz inversion: Silica, a common constituent of brick making soils, has its crystal
structure in the form of –quartz (alpha–quartz) in nature. At 573oC, its crystal structure
changes into from –quartz (Beta quartz) and this transformation is accompanied by an
expansion of volume by around 2%. During cooling, – change occurs again at
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temperature 573 0C. The heating and cooling rates near quartz inversion temperature
have to be controlled to obtain near-uniform temperature throughout the brick and thus
avoiding excessive stresses which can lead to crack formation in bricks.
5. Carbonate and sulphide decomposition: Carbonates and sulphides present in the clay
decompose at 600 – 800 0C releasing CO 2 and SO2.
As temperature increases, more melting of clay mass occurs. In practice, the heating
must be restricted lest so much liquid forms that the whole brick starts to become
distorted under the weight of the higher layers of bricks. In extreme cases, the bricks
may get fused together in the kiln.
1.2.2 Soaking:
The bricks are maintained at the finishing temperature for few hours in order to attain
uniform vitrification throughout the brick. This process is known as soaking.
1.2.3 Cooling:
During cooling the liquid solidifies to glass, bonding the whole mass together. The cooling
rate should be slow to avoid excessive thermal stresses in the bricks, particularly once the
quartz inversion temperature (573 0C) is reached, since shrinkage occurs at this point.
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1.3 Quality of fired bricks
The quality of the fired bricks is a function of several parameters. The important amongst
them are:
Many countries have notified standards in order to define the quality of clay fired bricks.
Usually the standards classify bricks on the basis of three properties — compressive
strength, water absorption and efflorescence.
In the same kiln or the same batch of fired bricks, the quality of fired bricks may vary due to
differences in the temperature profiles and the duration of the soaking period. A good brick
firing kiln should have as uniform temperature as possible throughout its cross-section so
that the quality of fired bricks are uniform and the percentage of good quality bricks are high.
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2 Introduction to Brick Kilns
A large variety of kilns are used for firing bricks. These can be classified in several ways,
e.g. on the basis of the production process (intermittent and continuous kilns); direction of air
flow (up-draught, down-draught and cross-draught kilns); or on the basis of the method of
production of draught (natural draught and induced/forced draught kilns).
Depending upon the nature of production process, brick kilns can be classified as
intermittent kilns and continuous kilns. The classification is represented in Figure 5 below:
Brick Kilns
Intermittent Continuous
Kilns kilns
Intermittent
Intermittent Moving fire Moving ware
kilns without
kilns with stack kilns kilns
stack
In intermittent kilns, bricks are fired in batches; fire is allowed to die out and the bricks are
allowed to cool after they have been fired. The kiln must be emptied, refilled and a new fire
has to be started for each load/batch of bricks. In intermittent kilns, most of the heat
contained in the hot flue gases, fired bricks and the kiln structure is thus lost. Intermittent
kilns are still widely used in several countries of Asia, Africa and South and Latin America.
Intermittent kilns can be further sub-divided into two categories:–
Intermittent kilns without stack: The kilns which do not have any stack/chimney to guide
the flue gases. In these kilns the flue gases can be seen coming out of the kiln from the
sides or from all over the top surface of the kiln. Clamps, scove and scotch kilns are the
examples of intermittent kilns without stack.
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Figure 6: Clamp (India) Figure 7: Scotch kiln (India)
Intermittent kilns with stack: As the name suggest, these kilns have a stack/chimney to
create draught for releasing the flue gases at a higher point in the atmosphere. Down-
draught kiln and climbing kilns are the example of intermittent kilns with stack.
In a continuous kiln fire is always burning and bricks are being warmed, fired and cooled
simultaneously in different parts of the kiln. Fired bricks are continuously removed and
replaced by green bricks in another part of the kiln which is then heated. Consequently, the
rate of output is approximately constant. Heat in the flue gas is utilised for heating and drying
of green bricks and the heat in the fired bricks is used for preheating air for combustion. Due
to incorporation of heat recovery features, continuous kilns are more energy efficient.
Continuous kilns can be further sub-divided into two categories: moving fire kilns and moving
ware kilns.
Moving fire kilns: In a moving-fire kiln, the fire progressively moves round a closed kiln
circuit while the bricks remain stationary (Figure 10). The kiln circuit can have oval,
rectangular or circular shapes. Figure 11 represents a part of the moving fire kiln showing
the typical air flow path through the bricks stacked in the kiln. The fire travel takes place in
the direction of airflow. Ambient air enters from the left and cools down the fired bricks in the
kiln. After combustion, the hot flue gases pass through the green bricks stacked ahead of the
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combustion zone resulting in preheating of the green bricks (and cooling of flue gases). A
chimney stack and/or a fan provide the necessary draught for airflow. Hoffman kilns, Fixed
Chimney Bull’s Trench kilns and zigzag kilns are the examples of moving fire kiln.
Figure 11: A part of moving fire kiln circuit showing fire travel
Moving ware kilns: In a moving ware kiln, fire remains stationary, while the bricks and air
move in counter-current paths. In tunnel kiln, which is a horizontal moving ware kiln, goods
to be fired are passed on cars through a long horizontal tunnel (see Figure 12). The firing
zone is located at the central part of its length. Cold air is drawn from the car exit end of the
kiln and it cools the fired bricks. The combustion gases travel towards the car entrance
losing a part of their heat to the entering green bricks. The cars can be pushed either
continuously or intermittently at fixed time intervals.
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Figure 12: Tunnel kiln (moving ware kiln)
Vertical shaft brick kiln is another example of moving ware kiln. In this kiln the movement of
bricks is in vertical downward direction and upward air movement is brought about by natural
convection (see Figure 13).
Based on the direction of air flow with respect to the brick setting in the kiln, brick kilns can
be classified as up draught kilns, down draught kilns and cross draught kilns. The
classification is represented in the figure below:
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Brick Kilns
Up-draught kilns: In an up-draught kiln, air enters the kiln from below, gets heated from the
fire and moves upward through the brick setting transferring the heat to the bricks. The
upward movement of heated air is a natural phenomenon and it does not require a stack or
fan to cause the air flow. Clamps and vertical shaft brick kiln (VSBK) are examples of up-
draught kilns.
Down-draught kilns: In a down-draught kiln, air is first heated up with the fire. The hot air is
then made to enter the kiln from top and is brought down through the brick setting with the
help of draught created by a stack. In this type of kilns, usually bricks are not in the direct
contact with fire. Down-draught kiln, as the name suggest, is an example of this category of
kilns.
Cross-draught kilns: In cross-draught kiln, air flows horizontally through the brick stacking.
The air movement is caused by either the draught created by the chimney (natural draught)
or the draught provided by a fan (forced draught). These are also called horizontal draught
kilns. Hoffman kilns, fixed chimney Bull’s trench kiln and tunnel kilns are example of cross-
draught kilns.
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3 Fuels
In brick kilns, generally solid fuels are used e.g. coal; wood; sawdust; agricultural residue like
mustard stalk, rice husk, coffee husk; industrial waste and bye-products like used rubber
tyres, pet-coke, etc. Apart from solid fuels, bricks are also fired from natural gas, diesel, bio-
gas, producer gas, etc.
The characteristics of fuel that should to be considered for assessing the suitability of a fuel
for combustion process are:
1. Calorific value
The calorific value is the measurement of heat or energy contained in the fuel. It is the
amount of heat/energy which is released or available for use after complete combustion
of a unit amount of fuel. Higher the calorific value, higher is its heat content. It is
measured either as Gross Calorific Value (GCV) or Net Calorific Value (NCV). The
difference being the latent heat of condensation of the water vapour produced during the
combustion process. Gross Calorific Value assumes that all the vapour produced during
the combustion process is fully condensed at the end of combustion and takes into
account the latent heat of condensation. Net Calorific Value assumes that the water
vapour leaves with the combustion products without being condensed.
2. Volatile matter:
Volatile matters are the methane, hydrocarbons, hydrogen and carbon monoxide, and
incombustible gases like carbon dioxide and nitrogen found in fuel. Thus the volatile
matter is an index of the gaseous fuels present. Volatile matter content proportionally
increases flame length and helps in easier ignition of fuel.
3. Fixed carbon:
Fixed carbon is the solid fuel left after the moisture and volatile matter are driven off. It
consists mostly of carbon but also contains some hydrogen, oxygen, nitrogen and sulphur
which are not driven off with the gases. The amount of fixed carbon and volatile
combustible matter directly contribute to the heating value of fuel. While volatile matter
helps in initiation of the burning, fixed carbon acts as the main heat generator during the
burning.
4. Ash content
Ash is an impurity that will not burn. Lower the ash content better is the fuel. Higher Ash
content reduces the burning capacity and also increases the handling costs. Ash can also
cause clinkering and slagging.
5. Sulphur Content:
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Sulphur content affects clinkering and slagging tendencies. It corrodes metal chimney and
other equipment such as induced draught fans etc. and limits the exit flue gas
temperature. SO2 produced due to the combustion of sulphur affects nearby vegetation.
Calorific value
4,000-7,000 3,500-4,500 4,300-4,500 3,500-4,500
kcal/kg
Ignition Point
0
Fuel Ignition Temperature C
Proximate and Ultimate analysis are the common standard tests for determining physical
and chemical properties of solid fuels. Proximate analysis indicates the percentage by
weight of the Fixed Carbon, Volatiles, Ash and Moisture content in the fuel. A typical
proximate analysis of various fuels on wet basis is provided in the table below:
Fire wood
Parameter (%) Bituminous coal Saw dust Coffee husk
(Eucalyptus)
Moisture 5.98 7.3 14.24 9.87
Ash 38.63 4.68 6.02 2.75
Volatile matter 20.70 68.42 76.82 69.2
Fixed carbon 34.69 19.59 2.92 18.18
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The Ultimate analysis determines the mass percentage of the various elemental chemical
constituents such as carbon, hydrogen, oxygen, nitrogen, sulphur, etc. as well as moisture
and ash present in the fuel. It is useful in determining the quantity of air required for
combustion and the volume and composition of combustion gases. Typical ultimate analysis
of various fuels on wet basis is given in the table below:
Fire wood
Parameter (%) Indian coal Saw dust Coffee husk
(Eucalyptus)
Moisture 5.98 7.3 14.24 9.87
Ash content 38.63 4.36 6.02 2.48
Carbon 41.11 42.27 40.30 42.71
Hydrogen 2.76 5.75 4.60 5.78
Nitrogen 1.22 0.37 1.27 0.71
Sulphur 0.41 0.46 0.15 0.14
Oxygen 9.89 39.58 33.42 38.31
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4 Specific Energy Consumption
4.1 Definition
Specific Energy Consumption (SEC) is defined as the energy in MJ consumed for producing
1 kg of fired brick. SEC is usually used as a parameter to compare energy performance of
brick kilns.
H in
SEC =
M fbr
Where,
= Average mass of fired brick x number of bricks fired in one firing cycle/batch
Hin = Total energy input to the kiln for the duration of one firing cycle/batch
= (Energy input from external fuels fed in the kiln) + (Energy input from internal fuels
added during moulding in the bricks) + (Energy input from the organic matter present in the
brick soil).
n1 n2
W
i 1
f ext ,i GCV f ext ,i W
i 1
f int, i GCV f int, i
Where, n1 and n2 are the types/ lots of external and internal fuel used.
Notes:
1. The average mass of fired brick is determined by randomly selecting 24 fired bricks,
weighing them and calculating a simple average in case of small kilns. In case of
large kilns at least one brick per thousand bricks fired in the kiln should be weighed.
2. It is to be noted that while calculating SEC, the quality of fired brick is not taken into
account; all the bricks that has undergone firing during the duration of the experiment
are taken while calculating Mfbr
3. GCV is the gross calorific value of the fuel.
4. The energy from carbonaceous content in green bricks is often small and difficult to
measure and is neglected in these calculations.
In order to accurately identify energy inputs, a material balance chart should be prepared for
the kiln. A general material balance for an intermittent kiln is provided below
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Figure 15: Material balance of brick kiln
The energy for firing of bricks is being supplied through addition of fuel and carbonaceous
material present in the green bricks.
Fuel can be added in two ways – 1) externally and 2) mixed internally in the soil while green
brick preparation. Both internal and external fuel needs to be accounted for calculating the
heat input in the kiln.
External Fuel
1. Weights of each of the external fuels added in one batch/cycle of green bricks (W f-ext)
2. Type and Gross Calorific Values (GCV) of each of the external fuels (GCVf-ext)
Internal fuel
1. Weight of each of the internal fuels added in one batch/cycle of green bricks (W f-int)
2. Type and Gross Calorific Values (GCV) of each of the internal fuels (GCV f-int)
The energy from carbonaceous content in green bricks is often small and difficult to measure
and is neglected in these calculations.
The total weight of fired batch/cycle is obtained by determining the average weight of the
fired brick and then multiplying it by number of bricks fired in the batch/cycle.
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The average mass of fired brick is determined by randomly selecting 24 fired bricks,
weighing them and calculating a simple average in case of small kilns. In case of large kilns
at least one brick per thousand bricks fired in the kiln should be weighed.
Weight of fired batch = average weight of fired brick x number of bricks in batch
The specific energy consumption can be computed through the equation given below
!"
# $ $
Please note that the specific energy consumption should also mention the firing temperature
of the bricks.
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4.5 Determination of SEC of continuous kilns
In the case of continuous kilns, the unit basis for calculations is time, usually the duration of
monitoring is for minimum of one day (24 hours). The rest of the concept and the parameters
to be measured remain same as that of intermittent kiln. The equations used for calculating
SEC of continuous kiln are given below
Where;
W f-ext =Weight of the external fuel added during the monitoring duration
W f-int = Weight of the internal fuel added to the green bricks which are fired during the
duration of the monitoring
Total weight of fired brick = average weight of fired brick x number of bricks fired
during the duration of the monitoring
The specific energy consumption can be computed through the equation given below
Please note that the specific energy consumption should also mention the firing temperature
of the bricks.
Example 2: Calculation of SEC of a Bull’s trench kiln in India (24 hour duration)
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Example 3: Calculation of SEC of a VSBK in India (48 hour duration) (multiple fuel)
4.6 Precautions
Moisture present in the fuel must be accounted, while calculating the energy input to
the kiln.
Weight of the fuel that is added needs to be accurately estimated.
In case of continuous kiln, measurement of bricks fired per day needs to be
estimated accurately.
Specific energy consumption has to be reported along with the firing temperature;
hence the firing temperature also has to be measured.
Let quantities x, …..., w are measured with uncertainties x, ........., w, and the measured
values are used to compute
x ...... z
q
u ....... w
If the uncertainties in x, ...,w are independent and random, then the fractional uncertainties in
q is the sum in quadrature of the original fractional uncertainties
2 2 2 2
q x z u w
.......... .......
q x z u w
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Hence the uncertainty in calculation of SEC can be given by,
2 2 2 2
SEC M f GCV f w fbr n fbr
SEC Mf GCV f w fbr n fbr
Now let us estimate the uncertainty in the calculation of SEC for the case presented in
Example-2 in Section 4.5:
Least count of weighing balance for weighing coal = 0.1 ton and typical weight of a coal lot =
12 ton. Therefore,
M f
1.0%.
Mf
w fbr = 2.91 kg
w fbr
1.7 %
w fbr
n fbr
= 2%
n fbr
SEC
= 12 1.7 2 2 2 = 2.81%
SEC
Specific energy consumption is a measure of energy used for firing one kg of green brick to
fired brick in given conditions using specific type of kiln. The energy required depends
heavily of type of clay and the efficiency of the kiln. Hence, the specific energy consumption
cannot be used as a single parameter to compare the kiln technologies across geographies.
One should take extra care while commenting upon the technology performance using
specific energy consumption data.
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5 Instruments for energy monitoring
Some of the important instruments required for the energy monitoring of brick kilns are
described below:
Weighing balance is a measuring instrument for determining the weight or mass of an object.
These are used in the monitoring of brick kilns for measuring weights of green bricks, fired
bricks and the fuel. For measuring weight of bricks, smaller weighing balances with capacity
in the order of 20-25 kg and least count of 10 g are suitable. However, for measuring the
weight of fuel, a larger capacity balance would be required which can measure weights of
the order of 50-100 kg.
5.2 Thermocouple
K type (Ni-Cr/Ni-Al) thermocouples are commonly used for measuring temperatures in brick
kilns. It is inexpensive and can measure temperatures in the range −200 °C to +1350 °C
which is suitable for brick kiln applications. These are called contact type thermometers as
they measure temperatures by coming in actual contact with the object.
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temperature from a distance. By knowing the amount of infrared energy emitted by the
object and its emissivity, the object's temperature can be determined. In the basic infrared
thermometers, a constant emissivity value is preloaded for temperature measurements.
However, in the advanced meters there is an option to select the emissivity value depending
on the material of the surface of which temperature is being measured.
Moisture meters are used to measure the percentage of water in a given substance. It works
on the principle that conductivity of materials vary with its moisture content. It measures the
conductivity of the material and with the help of conductivity characteristics curves pre-
loaded in it for various materials; it determines the moisture content in the material. It can be
used for determining moisture content in fire-wood fuels. The limitation with these meters is
that these can measure moisture content correctly for those materials only whose
characteristics curve has been preloaded. Most of the commonly found moisture meters can
measure moisture content in fuel wood, however, it should be checked with the supplier
whether it can measure moisture content of green bricks and other loose biomass fuels or
not.
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5.5 Bomb calorimeter
A weighed mass of the fuel sample (typically 1-1.5 g) along with some fixed amount of water
is kept in the bomb. Water is added to saturate the internal atmosphere, thus ensuring that
all water produced during burning is liquid. The bomb is pressurised with excess pure
oxygen (typically at 30 atm.) and submerged under a known volume of water (typically 2000
ml). The charge is then electrically ignited. The bomb, with the known mass of the sample
and oxygen, form a closed system - no gases escape during the reaction. Energy released
by the combustion raises the temperature of the metal bomb, its contents, and the
surrounding water jacket. The temperature change in the water is then accurately measured
with a thermometer. This reading, along with a bomb factor (which is dependent on the heat
capacity of the metal bomb parts), is used to calculate the energy given out by the sample
burn.
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References
1. Report on ‘Small-scale brick making’ published by International Labour Office, Switzerland, 1984.
http://www.pssurvival.com/ps/bricks/Small-Scale_Brickmaking_1984.pdf
4. ‘Energy Efficiency in Thermal Utilities – Guidebook for National Certification Examination for
Energy Managers and Energy Auditors’, Published by Bureau of Energy Efficiency, Govt. of
India.
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