AYJR 2023 January (Evening Shifsjsi
AYJR 2023 January (Evening Shifsjsi
AYJR 2023 January (Evening Shifsjsi
Questions with Answer Keys MathonGo
Q1
The efficiency of the Carnot engine is 50% and the temperature of the sink is 500 K. If temperature of the
source is kept constant and its efficiency is raised to 60%, then the required temperature of the sink will be
(1) 100 K
(2) 600 K
(3) 400 K
(4) 500 K
Q2
m(t) = 5 sin(1. 57 × 10 t)
8
and transmitted through an antenna.What will be the bandwidth of the modulated
signal ?
(1) 8 GHz
(2) 2. 01 GHz
Q3
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Q4
(1) 1
Y
=
3η
1
+
9B
1
(2) 9
Y
=
1
η
+
3
(3) 1
η
=
1
B
+
1
(4) 9
Y
=
3
η
+
1
Q5
A mass m moves in a circle on a smooth horizontal plane with velocity v at a radius R . The mass is attached
0 0
R0
The tension in the string is increased gradually and finally m moves in a circle of radius 2
. The final value of
the kinetic energy is:
(1) mv 2
0
(2)
1 2
mv
4 0
(3) 2 mv 2
0
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(4)
1 2
mv
2 0
Q6
Starting from rest, a particle is moving along x-axis. The variation of force with position is shown in figure.
Find the Kinetic energy (KE) of particle when it is at x = 3m.
(1) 3.3 J
(2) 4 J
(3) 5 J
(4) 4.2 J
Q7
A sound is produced between two vertical parallel walls. The echo from one wall is heard after 2 s while from
the other 2 s after the first echo. The speed of sound in air is 340 m s . Choose the correct options.
−1
Q8
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The two plates of a parallel plate capacitor are 4 mm apart. A slab of dielectric constant 3 and thickness 3 mm
is introduced between the plates with its faces parallel to them. The distance between the plates is so adjusted
that the capacitance of the capacitor becomes 2/3rd of its original value. What is the new distance between the
plates?
(1)
9 mm
(2)
21 mm
(3)
5 mm
(4)
8 mm
Q9
Two materials having coefficients of thermal conductivity 3K and K and thickness d and 3d respectively, are
joined to form a slab as shown in the figure. The temperatures of the outer surfaces are θ and θ respectively,
2 1
θ2 +θ1
(1) 2
θ1 5θ2
(2) 6
+
6
θ1 2θ2
(3) 3
+
3
θ1 9θ2
(4) 10
+
10
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Q10
A body is sliding down an inclined plane (angle of inclination 45°). If the coefficient of friction is 0. 5 and
g = 9. 8 m s
−2
. then the downward acceleration of the body in m s −2
is :-
(1)
4.9
√2
(2) 4. 9√2
(3) 19. 6√2
(4) 4. 9
Q11
A particle starts from origin O from rest and moves with a uniform acceleration along the positive X -axis.
Identify all figures that correctly represent the motion qualitatively.
(1) (A)
(2) (A), (B), (C)
Q12
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nuclear reaction 7
3
1
1
4
2
4
Li + H → H e + H e + Q
2
, the value of energy Q released is
(1) 19.6 MeV
(2) −2.4 MeV
(3) 8.4 MeV
(4) 17.3 MeV
Q13
The dimensional formula of the constant a in Vander Waal’s gas equation (P +
a
2
) (V − b) = RT is:
V
(1) [M L 4
T
−1
]
(2) [M L 2
T
−2
]
(3) [M L 5
T
−3
]
(4) [M L 5
T
−2
]
Q14
(1) zero
(2) 3 × 10 4
V m
−1
(3) 5.8 × 10 −4
T
(4) 3.0 × 10 −5
T
Q15
Find the time required for a 50 Hz alternating current to change its value from zero to the rms value.
(1) 10 ms
(2) 5 ms
(3) 15 ms
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(4) 2. 5 ms
Q16
Two identical conducting very large plates P and P having charges +4Q and +6 Q are placed very closed to
1 2
each other at separation d. The plate area of either face of the plate is A.
In the above question, if plates P and P are connected by a thin conducting wire, then the amount of heat
1 2
produced will be
2
Q
(1) Aε0
d
2
5Q
(2) Aε0
d
2
2Q
(3) Aε0
d
Q17
Magnetic field at the centre of a circular coil of radius R due to i flowing through it is B. The magnetic field at
a point along the axis at distance R from the centre is
(1) B
(2) B
(3) B
√8
(4) √8B
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Q18
Assertion: Electric appliances with metallic body, e.g., heaters, press etc, have three pin connections whereas
an electric bulb has a two pin connection.
Reason: Three pin connections reduce heating of connecting cables.
(1) If both Assertion and Reason are true and Reason is correct explanation of Assertion.
(2) If both Assertion and Reason are true but Reason is not the explanation of Assertion.
(3) If Assertion is true but the Reason is false.
Q19
Choose the correct statement for hydrogen and deuterium atoms (considering the motion of nucleus).
(1) The radius of first Bohr orbit of deuterium is less than that of hydrogen.
(2) The speed of electron in first Balmer line of deuterium is more than that of hydrogen.
(3) The wavelength of first Balmer line of deuterium is
more than that of hydrogen.
(4) The angular momentum of the electron in the first Bohr orbit of deuterium is more than that of hydrogen.
Q20
(1) AND
(2) OR
(3) NAND
(4) NOR
Q21
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Gas at pressure P is contained in a vessel. If the mass of all the molecules are halved and their speed is
0
doubled then the resulting pressure becomes nP . What is the value of ' n'.
0
Q22
3
m . It is kept in contact with a plane
mirror. Find magnitude of power of optical device formed if space between them is filled with water
Q23
In the circuit shown below, is working as a 8 V dc regulated voltage source. When 12 V is used as an input,
the power dissipated (in mW ) in each diode is (Considering both zener diodes are identical)
Q24
A light inextensible string that goes over a smooth fixed pulley as shown in the figure connects two blocks of
masses 0. 36 kg and 0. 72 kg. Taking g = 10 m s , find the work done (in joules) by the string on the block
−2
of mass 0. 36 kg during the first second after the system is released from rest.
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Q25
An inductor of 10 mH is connected to a 20 V battery through a resistor of 10 kΩ and a switch. After a long
time, when maximum current is set up in the circuit, the current is switched off. The current in the circuit after
1 μs is x
100
mA . Then x is equal to ______ . (Take e −1
= 0. 37 )
Q26
In YDSE if incident light consists of two wavelengths λ 1 =4000 Å and λ 2 =5600 Å and is parallel to line SO.
The minimum distance y upon screen, measured from point O, will be where the bright fringe due to two
Q27
respectively. The ratio of maximum speeds of the photoelectrons emitted in the two cases is 2. The work
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Q28
Two balls A and B are projected from the same height as shown in the figure. If the horizontal range of both
the balls remains the same, then the speed u of the second ball is … … m s −1
. take g = 9.8 m s −2
Q29
In a practical wheat stone bridge circuit as shown, when one more resistance of 100 Ω is connected in parallel
with unknown resistance X, then ratio l1
l2
becomes 2. l is balance length. AB is a uniform wire. Then the
1
Q30
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Q31
Choose the most appropriate answer from the options given below-
Q32
P and Q are -
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(1) P is NaBH 4
Q is
Q is
(3) P is LiAlH ,
4
Q is
Q is
Q33
Column I Column II
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Q34
(1) The difference in magnetic properties of gangue particles and ore particles.
(2) The difference in specific gravity of gangue particles and ore particles.
(4) preferential wetting properties with the frothing agent and water
Q35
(1) LiH
(2) CaH 2
(3) AlH 3
(4) SiH 4
Q36
Addition of sodium hydroxide solution to a weak acid (HA) results in a buffer of pH 6. If ionization constant
of HA is 10 , the ratio of salt to acid concentration in the buffer solution will be:
−5
(1) 10 : 1
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(2) 4 : 5
(3) 5 : 4
(4) 1 : 10
Q37
Q38
Among the following complexes the one which shows Zero crystal field stabilizations energy (CFSE)
3+
(1) [Ni(H 2 O)
6
]
3+
(2) [Fe(H 2 O)
6
]
2+
(3) [Co(H 2 O)
6
]
3+
(4) [Co(H 2 O)
6
]
Q39
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(1) 4-methoxy-2-nitrobenzaldehyde
(2) 4-formyl-3-nitro anisole
(3) 4-methoxy-6-nitrobenzaldehyde
Q40
Q41
Q42
2
Balmer gives an equation for wavelength of visible radiation of H-spectrum as λ = . The value of k in
kn
2
n −4
(1) R
(2) 4R
(3) R
(4) 4
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Q43
Statement II : Solubility of alkaline earth metal hydroxides in water increases down the group.
In the light of the above statements, choose the most appropriate answer from the options given below:
Q44
(2) Axial and equatorial bonds have the same bond length.
Q45
(1) analgesics
(2) tranquilizers
(3) antacids
(4) antiseptics
Q46
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If one strand of DNA has the sequence ATGCTTGA, the sequence in the complementary strand would be
(1) TACGAACT.
(2) TCCGAACT.
(3) TACGTACT.
(4) TACGTAGT.
Q47
Statement II : In aniline, the lone pair of electrons on nitrogen atom is delocalised over benzene ring due to
resonance and hence less available to a proton.
Q48
Here, P is;
(1)
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(2)
(3)
Q49
Assertion (A) : Ethene polymerized in the presence of Ziegler Natta Catalyst at high temperature and pressure
Reason (R) : High density polymers are closely packed and are chemically inert. Choose the correct answer
from the following:
(2) Both (A) and (R) are correct but (R) is not the correct explanation of (A).
(3) Both (A) and (R) are correct and (R) is the correct explanation of (A).
(4) (A) and (R) both are wrong.
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Q50
(1) 2-methyl-1-hexene
(2) 2,3-dimethyl-2-pentene
(3) 2-methyl-2-hexene
(4) 3-methyl-1-hexene
Q51
Q52
A + B ⇌ 2C
the value of equilibrium constant is 100 at 298 K. If the initial concentration of all the three species is 1 M
Q53
×10
−2
S m
−1
. (Round off to the Nearest Integer).
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Q54
For a certain quantity of reactants, if the volume of the reaction vessel is reduced by a factor of 3, the rate of
the reaction increases by a factor of _____ . (Round off to the Nearest Integer).
Q55
In neutral or faintly alkaline solution, 8 moles of permanganate anion quantitatively oxidize thiosulphate
Q56
How many ethers will be formed when a mixture of C 2 H5 OH and methyl alcohol are treated with
concentrated H 2 SO4 ?
Q57
+
ii. cis − [Co (en) 2
Br2 ]
+
iv. trans − [Co (NH 3)
4
Cl2 ]
3−
v. trans − [CoCl 2 (C2 O4 ) ]
2
Q58
The percentage of anhydrous salt is 56. 25 by weight. In the crystalline solid MSO 4. nH2 O of molar mass
288 g mol
−1
. The value of 'n' is:
Q59
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Cr2 O7
2−
. The molarity of the Fe 2+
solution is _______ ×10 −2
M (Round off to the Nearest Integer).
Q60
Two moles of an ideal gas (monatomic) are taken through cycle ABCA. During process
AB, PT = constant T1 = 300 K . The work done in the process may be (150 R)x, the value of x is:
Q61
(1) 6
(2) 7
(3) 8
(4) 9
Q62
Coefficient of variation of two distributions are 60% and 75%, and their standard deviation are 18 and 15
respectively, then their arithmetic means respectively are
(1) 30, 30
(2) 30, 20
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(3) 20, 30
(4) 20, 20
Q63
π
3 tan(x− )
constant of integration.]
(1)
2
(2)
3
(3)
6
(4)
8
Q64
→
→ → → → → → → → →
Let a , b, c be three non-zero vectors satisfying a = b × c + 2b where | b | = | c | = 2 and |a | ≤ 4 .
→ → →
The sum of possible value(s) of |2 a + b + c | is:
(1)
8
(2)
12
(3)
20
(4)
32
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Q65
(3) (−2, 1)
(4) (0, 2)
Q66
x y −z
⎡ ⎤
(1) 28
(2) 42
(3) 20
(4) 36
Q67
n
n Ck
If the value of lim n→∞ ∑
k=0 k
n (k+3)
equals L. Then [L] is equal to:
[Note: Where [ k ] denotes greatest integer function less than or equal to k.]
(1)
0
(2)
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(3)
2
(4)
3
Q68
If the expression (p ⊕ q)∧(~p ⊙ q) is equivalent to p ∧ q, ( where ⊙, ⊕ ∈{∨, ∧}, ) then the ordered pair
(⊕, ⊙) is equivalent to :
Q69
(1)
0
(2)
1
(3)
2
(4)
more than 2
Q70
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Let a, b and c be non-negative real numbers satisfying a + b + c = 9. If the maximum value of the expression
2
a b c
3 4
can be expressed as 2 x
3
y
, where x and y are natural numbers, then the value of log 10
y
(x ) , is:
(1)
2
(2)
3
(3)
4
(4)
6
Q71
(1) 1
(2) 2
(3) 4
(4) 3
Q72
If S n =(1
2
− 1 + 1)(1!) +(2
2
− 2 + 1)(2!) + … +(n
2
− n +1)(n!) , then S is:
50
(1) 52!
(2) 1 + 49 × 51!
(3) 52! − 1
(4) 50 × 51! − 1
Q73
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(1)
5π
(2) π
(3) 3π
(4) π
Q74
x+59
The function f (x) satisfies the functional equation 3f (x) + 2f ( x−1
) = 10x + 30 for all real x ≠ 1. The
(1)
8
(2)
4
(3)
−8
(4)
11
Q75
y−1 z+1
The image of the line x
2
=
5
=
3
in the plane x + y + 2z = 3 meets the xz−plane at the point (a, b, c),
then the value of c is equal to
(1) 11
(2)
129
(3)
115
(4) 232
Q76
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S = {1, 2, 3}, f : S → S satisfies the property : ∀x ∈ S, f (f (x)) = f (x). How many different functions are
(1)
8
(2)
10
(3)
1
(4)
4
Q77
Q78
Let z 1, z2 and z are the points on the argand plane which lie on the circle with equation |z − z
3 0 |=
4
(where
√3
z0 is the centre of the circle). If z 1 = 0, z2 = −4 and z 3 = 4 + 3z0 , then |arg(z 0 )| is equal to (where
arg Z ∈(−π, π] )
(1)
π
5π
(2) 12
5π
(3) 6
(4)
2π
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Q79
(1)
9
(2) 2√2 + 3
(3) 3√2 + 2
(4)
3
+ 2 √2
2
Q80
(2j−1)+8n
The value of lim 1
n
∑
n
j=1 (2j−1)+4n
is equal to:
n→∞
3
(1) 5 + log e
(
2
)
(2) 2 − log e
(
2
3
)
(3) 3 + 2 log e
(
2
3
)
3
(4) 1 + 2 log e
(
2
)
Q81
⎧ x|x| for x ≤ −1
⎪
Given f (x)=⎨ [x + 1]+[1 − x] for −1 < x < 1 , where [.] denotes the greatest integer function. If
⎪
⎩
−x|x| for x ≥ 1
2
Q82
x x x
y
)dy = 0 is x + kye y
= C (where, C is
Q83
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Let a fair coin be tossed 6 times. A, B and C three events are defined as
B : 4
th
head obtained on 5 th
toss.
C : tail is obtained, on 2 or 4 nd th
toss
Q84
Suppose a function f : [0, 10] → R is continuous and differentiable everywhere in its domain. If f (10) = 19
and |f ′
(x) − 5| ≤ 4∀x in domain. Find maximum value of f (0).
Q85
Let f (x) = [x − 1
4
] + x[x] + |x(x − 4) sin x| + (2x − 1)
1/3
. Find the number of points in (0, 2π) where
f (x) is non-derivable.
Q86
The plane denoted by P 1 : 4x + 7y + 4z + 81 = 0 is rotated through a right angle about its line of intersection with
the plane P 2 : 5x + 3y + 10z = 25 . If the plane in its new position be denoted by P , and the distance of this plane
2
] (where [.] represents the greatest integer less than or equal to k) is
Q87
Q88
The number obtained after dividing the number formed by the last three digits of 17 256
by 3 is
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Q89
2
The area in sq. units inside the parabola 5x but outside the parabola 2x is A. Find .
2 2 A
− y = 0 − y + 9 = 0
12
Q90
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Answer Key
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Hints and Solutions MathonGo
Q1
T2
Efficiency (η) of a Carnot engine is given by η = 1 − T1
, where T is the temperature of the source and T is the
1 2
Here, T 2 = 500 K .
500
∴ 0 .5= 1 − ⇒ T1 = 1000 K
T1
′
T
′
T = 400 K
2
Q2
Band width = 2f m
8
ωm = 1. 57 × 10 = 2πfm
8
10
BW = 2fm = Hz = 50 MHz
2
Q3
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From the hysteresis curve of soft iron we know Soft iron has high retentivity and low coercive force therefore the
loop (i) is for soft iron and the loop (ii) is for steel.
Q4
Y
=
1
B
+
3
Q5
'
⇒ v = 2v0
Hence, final KE = 1
2
mv
'2
=
1
2
m(2v0 )
2
2
= 2mv
0
Q6
KE f = 5 J
Q7
2d1 = 340 × t1
2d2 = 340 × t2
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Next echo will be heard at 6 s not at 8 s. Because sound wave reflected from W will be reflected by W 2 1
in next 2 s.
Q8
Here, distance between parallel plates d = 4 mm = 0.004 m, K = 3, thickness t = 3 mm = 0.003 m and d =? 1
ε0 A ε0 A
∴ C =
d
and C 1 =
1
d1 −t(1− )
K
since C (given)
2
1 = C
3
ε0 A 2 ε0 A
∴ =
1 3 d
d1 −t(1− )
K
1 2
=
1 3d
d1 −t(1− )
K
1 2
=
1 3×0.004
d1 −0.003(1− )
3
1 1
2
=
0.006
d1 −0.003×
3
1 1
=
d1 −0.002 0.006
Q9
3 kA kA
(θ2 − T)= (T − θ1 )
d 3d
⇒ 9(θ2 − T)=(T − θ1 )
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⇒ 10T = 9θ2 + θ1
Q10
4.9 −2
= 9. 8[sin 45° − 0. 5 cos 45°]= m sec
√2
Q11
Since, the particle starts from rest, this means, initial velocity, u = 0
Also, it moves with uniform acceleration along positive X -axis. This means, its acceleration (a) is
constant.
∴ Given, a − t graph in (A) is correct. As we know, for velocity-time graph, slope = acceleration.
Since, the given v − t graph in (B) represents that its slope is constant and non-zero.
1 2 1 2
x = ut + at = 0 + at
2 2
2
⇒ x ∝ t
Q12
1
7 4
4
Li + 1
H → ( 2H e )
2
BE of products= ((5.6 MeV)×7) + 0
= 39.2 MeV
Ei = −39.2 MeV
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BE of reactant=(7.06)×4 × 2
= 56.48 MeV
Ef = −56.48 MeV
Q13
5 −2
∴ [a] = [M L T ]
Aliter:
a ab
PV + − Pb + = RT
V 2
V
As this equation is dimensionally correct, each term on either side will have same dimensions, i.e.,
a
[ ] = [P V ]
V
or [a] = [M L −1
T
−2 3 3
] [L ] [L ] = [M L T
5 −2
]
and [P × b] = (P V )
So that [μb] = [V ] i. e. ,
3
[b] = [L μ
−1
] with units m 3
/ mol
and [μ 2
a] = [P V
2
] i. e. , [a] = [M L T
5 −2
μ
−2
] with units J 3
m /mol
2
Q14
Given that,
B0 = 10
−4
T ,
the speed of the electromagnetic wave is
E0
c =
B0
(c = 3 × 10 8
m s
−1
)
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8 −4
E0 = 3 × 10 × 10
4 −1
E0 = 3 × 10 V m
Q15
I = I0 sin(wt)= I0 sin(2πf t)
I0
We know, rms current I rms =
√2
. if rms current is equal to the instantaneous current at time t, then
I0 1
I = = I0 sin(wt), sin(wt)=
√2 √2
π
⇒ wt = 2πf t =
4
π π 1
⇒ t = = =
4 ( 2πf ) 4 ( 2π×50 ) 400
⇒ t = 2. 5 ms
Q16
When we connected both the plates with the wires, the charges will start flowing from one plate to the
other and the final charges are as shown in the figure. Energy stored in the capacitor will be zero finally,
i.e., U f
= 0 , but initially, the energy will be stored in the electric field between the charges which can be
given by,
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2
1 1 Q
2
Ui = ε0 E × Ad = × ε0 × ( ) × Ad
2 2 Aε0
2
Q
ΔH = Ui − Uf = d
2Aε0
Q17
The magnetic field at a point along the axis at distance R from the centre of a circular coil of radius R carrying i is,
2
μ0 iR
B =
2 2
3/2
, by using formula magnetic field at axial point at a distance equal to the radius of coil.
2 ( R +R )
μ0 i μ0 i
B
= = [Bcentre = B = ]
2√8R √8 2R
Q18
The electrical appliances with metallic body like heater, press, etc, have three pin connections. Two pins are for
supply line and the third pin is for earth connection for safety purposes.
Q19
2 2
me M
m =
me +M
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where, m is the mass of the electron and M is the mass of the nucleus.
e
The mass of deuterium is more than that of hydrogen. So, the reduced mass of electron is more for
deuterium than that for hydrogen.
Hence, the radius of first Bohr orbit of deuterium is less than that of hydrogen.
Q20
¯
¯
¯
¯¯
¯¯
¯
¯
¯¯
¯¯
¯¯
¯
¯
¯¯ ¯ = ¯
¯¯ ¯ = ¯¯¯¯¯¯¯¯¯¯
Y = A ⋅¯ B̄ A ⋅¯
B̄ A + B
Q21
So, P 0 =
1
3
mN
V
(vrms )
2
.
If the mass of all the molecules are halved and their speed is doubled,
( m/2 ) N
1 2
P = (2vrms )
3 V
1 mN 2
⇒ P = 2 [ (vrms ) ]
3 V
⇒ P = 2P0
Therefore, n = 2.
Q22
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f1 f2
effective lens (f eq )=
f1 +f2
=
−3R
−2
=
3R
2
= 1m
1 1 2 1 2
= − = −
f fM fl ∞ 1
1
f = − m
2
P =– 2D
Q23
( 12−8 )
4 −2
i = A = = 10 A
( 200+200 ) 400
Q24
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T − mg = ma . . .(1)
g ( M −m )
⇒ a =
( M +m )
g ( 0.72−0.36 ) g×0.36 g
a = = =
( 0.72+0.36 ) 1.08 3
g
T =(m × )+(m × g)
3
4mg
T =
3
2
at
2
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2
at
2
.
4mg 1 g
2
= × × × t
3 2 3
4×0.36×10 1 10
= × × × 1
3 2 3
W = 8 J
Q25
V 20 V
Imax = = = 2 mA
R 10 KΩ
−Rt/L
I = Imax e
3 −6
−10×10 ×1×10
10×10−3
I = 2 mA e
−1
I = 2 mA e
I = 2 × 0. 37 mA
74
I = mA
100
x = 74
Q26
¯
¯¯ = n X
n1 X ¯
¯¯
1 2 2
Dλ1 Dλ2
n1 = n2
d d
n 1 λ1 = n 1 λ2
λ1 n2 4000 40 5
= = = =
λ2 n1 5600 58 7
n2 5 X1 7
∴ = ⇒ =
n1 7 X2 5
7Dλ1
∴ ¯
¯¯ =
y = 7X 1
d
Q27
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Given,
The ratio of maximum speeds of the photoelectrons emitted in the two cases is
v1
= 2
v2
1 2
KEmax = mv = E − ϕ . . . (1)
2
1 2
mv = 4 − ϕ … (2)
2 1
1 2
mv = 2. 5 − ϕ . . . (3)
2 2
2
v1 4−ϕ 2
2
= = (2)
v2 2.5−ϕ
⇒ 3ϕ = 6
⇒ ϕ = 2 eV
Q28
The ball, B, follows horizontal and angular projectile and the ball A follows only horizontal projectile,
the height of the tower is, h = 490 m, and both the particle follows the same range,
2h 2×490
R = u√ = 10 × √ = 100 m
g 9.8
2
u sin θ
R = 100 m = ucosθ × t + ucosθ ×(490 + )
2g
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it means,
u2 sin2 θ
( 490+ )
2g
u sin θ √
R = ucosθ × + ucosθ ×
g g
2 2
u sin 30°
( 490+ )
2×9.8
u sin 30° √
⇒ R = 100 = u cos 30° × + u cos 30° ×
9.8 9.8
−1
⇒ u = 10. 9 m s
Q29
P R
=
Q S
100 x
( )
100 100+x
⇒ =
l1 l2
l1
So,
100
∵ = 2 = 2
l2 100x
( )
100+x
Q30
→
ˆ
r =(4 − 1) î +(3 − 2) ĵ +(−1 − 1)k
ˆ
= 3 î + ĵ − 2k
∣ î j k̂ ∣
→ → ∣ ∣
τ = r × F =∣ 3 1 −2 ∣
∣ ∣
∣1 2 3 ∣
ˆ ˆ
= î (7)− ĵ(11)+k(5)= 7 î − 11 ĵ + 5k
Q31
In manufacture of H 2 SO4 (contact process), V 2 O5 is used as a catalyst. Ni catalysts enables the hydrogenation of
fats. CuCl is used as catalyst in Deacon's process. ZSM − 5 used as catalyst in cracking of hydrocarbons.
2
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Q32
Q is
Q33
He ⇒ Inert gas
He has the electronic configuration of 1s . It is completely filled electronic configuration, due to this, it has the
2
Cl ⟶ Cl
−
gives the highest Δ eg H as Cl after getting one electron, it will achieve the stable electronic
–
configuration 18[Ar]. Due to this, large amount of energy is released during this process.
20 Ca −
−→ Ca
2+
−
−2e
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Alkaline earth metal and present in the fourth period, the outermost electron is far away from the nucleus. As a result,
less energy is required to remove the electron and easily donate the electron, hence, shows maximum metallic nature.
E
o
red
of Li is – 3. 07 V, a strong reducing agent.
It has very high hydration energy due to smaller in size. The hydration energy is directly proportional to the charge
Q34
On being preferrentially wetted by oil, the ore particles rise to the surface in the form of froth and from there we can
separate them.
Q35
It is generally formed by the group 13 element, and have lesser number of electrons than that required
for writing its Lewis structure. Being electron deficient, this hydride generally behaves as a Lewis acid,
which act as electron acceptor. This is a polynuclear hydride. According to the octet rule, each element
tends to completely fill it's outermost shell with 8e in it. The electronic configuration of aluminium is
−
2, 8, 3 , and it still needs 5 more electrons to complete its octet. Al has 3 valence electrons to complete its
octet, while each hydrogen has one valence electron.
Q36
(∵ [Salt]=[Anion])
Salt
pH = pka + log [ ]
Acid
Salt
⇒ 6 = 5 + log
Acid
Salt
⇒ 1 = log
Acid
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Salt 10
=
acid 1
Q37
Q38
3+
[Fe(H2 O) ]
6
1,1,1 1,1
+2 5
Fe = 3d (t eg )
2g
Q39
The -CHO functional group is the highest priority functional group. The carbons of the benzene ring are numbered
accordingly.
Q40
Non – stoichiometric Schottky defect is a type of point defect. This defect is forms when oppositely charged ion
leave their lattice site creating vacancies, thus lowers the density of crystal.
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Q41
Mercury poisoning often produces a crippling and fatal disease called Minamata disease.
Q42
(Rydberg equation)
1 2 1 1
= RZ ( − )
λ 2 2
n n
1 2
For H-atom, Z = 1
2
R ( n −4 )
1 1 1
∴ = R( − )=
λ 2 2 2
2 n 4n
2 2
Or λ = 4n
2
R ( n −4 )
=
kn
2
n −4
4
∴ k =
R
Q43
Statement-I is incorrect
Be (OH)
2
dissolve in alkali due to it's amphoteric nature.
Statement-II is correct
Solubility of alkaline earth metal hydroxide in water increases down the group due to rapid decreases in lattice
Q44
This statement is true, as PCl carries five sigma bonds and all these sigma bonds are used for
5
hybridisation according to the valence shell electron pair repulsion theory. Structure of PCl is shown 5
below:
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And we can see here, that axial bonds and equatorial bonds, both are not of the same length.
Q45
A substance which is used for the purpose of diagnosis, prevention, cure or relief of a disease is called
drug. Drugs are the chemicals of low molecular masses, these interact with macromolecular targets and
produce a response. When the biological response is therapeutic and useful, these chemicals are called
medicines and are used in diagnosis, prevention and treatment of diseases.
Analgesics are the drugs used to reduce or abolish pain without causing impairment of
consciousness, mental confusion or paralysis or some other nervous system disturbances.
Q46
We can say that if the sequence of bases in one strand of DNA is I, then, the sequence in the second
strand should be II. The base pairs on one of the strands of DNA bind with the base pairs of the other
strand very specifically. Adenine always pairs with thymine with two hydrogen bonds and
Q47
Explanation :- aniline is more basic than acetamide because in acetamide, lone pair of nitrogen is delocalised to more
Q48
In the first step of the reaction, NaOH is given which is a strong base, abstracts the hydrogen and phenoxide ion is
formed, which is more reactive than phenol. It further undergoes electrophilic substitution reaction with CO to form
2
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salicylic acid. But further reaction with D abstracts the hydrogen of acid to form deuterated acid. It follows the
+
Q49
High density polythene: It is formed when addition polymerisation of ethene takes place in a hydrocarbon solvent in
the presence of a catalyst such as triethylaluminium and titanium tetrachloride (Ziegler-Natta catalyst) at a
temperature of 333 K to 343 K and under a pressure of 6-7 atmospheres. High density polythene (HDP) thus
produced, consists of linear molecules and has a high density due to close packing. It is also chemically inert and
more tougher and harder. It is used for manufacturing buckets, dustbins, bottles, pipes, etc.
Q50
Q51
RH MH.C
2
= √ = 3√3
RH.C 2
MH.C = 54 g/mol
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n = 4
Q52
2 2
[C] ( 1+2x )
eq
K = =
[A] [B] ( 1−x ) ( 1−x )
eq eq
2
1+2x
100 = ( )
1−x
1+2x
( )= 10
1−x
3
x =
4
[C]eq. = 1 + 2x
3
= 1 + 2( )
4
= 2. 5 M
−1
= 25 × 10 M
Q53
1 ∗
κ = ⋅ G
R
∴ 0. 14 × 4. 19 = κ × 1. 03
0.14×4.19
or, = 1.03
−1
= 0. 5695 Sm
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Q54
Reaction : 2 A + B 2 ⟶ 2 AB
2
r = K. [A] [ B2 ]
on reducing the volume by a factor of 3, the concentrations of A and B will become 3 times and hence, the rate
2
becomes 3 2
× 3 = 27 times of initial rate.
Q55
− 2− 2− ⊖
8MnO + 3S2 O + H2 O → 8MnO2 + 6SO + 2OH
4 3 4
Q56
When alcohol is treated with concentrated H 2 SO4 , ethers are formed by dehydration of alcohols.
Mechanism:
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Q57
Complexes (i), (iii),(iv) and (v) are optically inactive due to the presence of plane of symmetry.
Q58
Considering 100gof solid, mass of anhydrous slat = 56. 25 g and mass of water = 100 − 56. 25
43. 75 g
Moles of H 2O in 288 g of solid = 43.75
100
× 288
= 126 g
∴ Moles of H 2O =
126
18
= 7 mol
∴ n = 7
Q59
2+ 2−
neq Fe = neq Cr2 O
7
15×M 2+
or ( 1000
Fe
)×1 =(
20×0.03
1000
)×6
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Q60
PdT + TdP = 0
P
dP = − dT
T
Substitute in (i)
P
PdV + V(− dT)= nRdT
T
PV
PdV = nRdT + dT = 2nRdT
T
V2 T1
∴ x = 8
Q61
⇒
n
C
3
+
n
C
4
+ 35 = 0 (not possible)
or n
C3 =
n
C4 = 35 ⇒ n = 7
Q62
− −
Let x1 and x2 be the means of 1 and 2 st nd
distribution respectively.
σ1 −
Then, CV
18×100
1
= × 100 ⇒ x 1 = = 30
− 60
x1
σ2 − 15×100
CV2 = × 100 ⇒ x 2 = = 20
− 75
x2
− −
Hence, x 1 = 30 and x 2 = 20
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Q63
2
3(tan x − 1) sec x (t − 1)
I = ∫ dx = 3 ∫ dt
3 2 3 2
(tan x + 1)√tan x + tan x + tan x (t + 1)√t + t + t
1
(1 − )
t
2
1 1
2
= 3∫ dt Let t + + 1 = z ⇒ (1 − ) dt = 2zdz
1 1 t t2
(t + + 2) √t + + 1
t t
dz −1
1
= 6∫ = 6 tan √1 + + t + C
2
(z + 1) t
Q64
→ → → →
a = b × c + 2b
→
Taking dot product with b
→ → → → →
→
a ⋅ b = 2| b |
2
⇒ | a || b | cos θ = 2| b |
2
4 → ∘
⇒ cos θ = ⇒ | a | = 4 ⇒ θ = 0
→
| a |
→ →
⇒ a = 2b
→ → → → → →
Now, b × c = 0 ⇒ b = c or b = − c
∴ Required sum = 12 + 8 = 20
Q65
Given g(x)= cos −1
[x + 1]+ sin
−1
[x]
For domain
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⇒ x ∈[−1, 1)
π π
− ; −1 ≤ x < 0
Now g(x)={ 2 2
0 + 0 ; 0 ≤ x < 1
g(x)= 0; x ∈[−1, 1)
Now f (x)+g(x)= 4
⇒ sin
−1
(sin x)+0 = 4 ,
⇒ sin
−1
(sin x)= 4 , which is not possible. Hence no solution.
Q66
4
( 3−1 )
det.(adj(adj(adj(adjA))))= |A|
16 8 16
= |A| = 4 .5
⇒|A|= ±10
∣x y −z ∣
∣ ∣
|A|=∣ 1 2 3 ∣= x + y + z = ±10
∣ ∣
∣1 1 2 ∣
= 36
Q67
n n 1 1 n 1
k n
Ck k+2 n
x 2
x 2
lim ∑ ∫ x dx = ∫ [ lim ∑ Ck ( ) x ] dx = ∫ [ lim (1 + ) x ] dx
n→∞
nk 0 0
n→∞ n 0
n→∞ n
k=0 k=0
1 1 1 1
x 2 x 2 x x
= ∫ e x dx = ∫ e (x + 2x) dx − 2 ∫ e (x + 1)dx + 2 ∫ e dx
0 0 0 0
1
x 2
= e (x − 2x + 2)] = e − 2
0
Q68
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1) (p ∨ q) ∧ (~p ∧ q)
≡ [q ∧ ~p] ∧ q
≡ ~p ∧ q
2) = (p ∧ q) ∧ (~p ∧ q)
≡ (p ∧ ~p) ∧ q
≡ F ∧ q ≡ F
3) (p ∨ q) ∧ (~p ∨ q)
≡(p ∧ ~p)∨q
⇒ F ∨ q ≡ q
4) (p ∧ q) ∧ (~p ∨ q)
≡ (q ∧ p) ∧ (~p ∨ q)
≡ q ∧ (p ∧ q)
≡ p ∧ q
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Q69
1
=
2k−6
2k−2
=
7−3k
3k−5
⇒ no value of k
Case-II : Equation x 2
+ (2k − 6)x + 7 − 3k = 0 has equal roots and equation x 2
+ (2k − 2)x + (3k − 5) = 0 has
equal roots
2 2 2
∴ (2k − 6) − 4(7 − 3k) = 0 ⇒ 4k − 12k + 8 = 0 ⇒ k − 3k + 2 = 0 ⇒ k = 1, 2
2 2
(2k − 2) − 4(3k − 5) = 0 ⇒ 4k − 20k + 24 = 0 ⇒ (k − 2)(k − 3) = 0 ⇒ k = 2
∴ k = 2
Q70
Consider the numbers a/2, a/2, b/3, b/3, b/3, c/4, c/4, c/4, c/4 using A.M. ≥ G.M. we get
1/9
2 3 4
a+b+c a b c
≥ ( 10 3
)
9
2 3
⇒ maximum value of a 2 3
b c
4
is 2 10
× 3
3
Hence x = 10 and y = 3
y 3
∴ log10 (x ) = log10 (10 ) = 3
Q71
x+2
y(4)= 8( )⇒ y = x + 2
2
(x − 2)
2
+ (y − 4)
2
+ λ(x − y + 2)= 0 which passes through (0, 4)
⇒ 4 + 0 + λ(0 − 4 + 2)⇒ λ = 2
⇒ Required circle is x 2
+ y
2
− 2x − 10y + 24 = 0
2 2
⇒ (x − 1) + (y − 5) = 2
2 2
(x − 1) = 1 = (y − 5)
⇒ x = 0, 2 and y = 4, 6
⇒ 4 integral points lie on the circle
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Q72
Given,
2 2 2
Sn = (1 − 1 + 1) (1!) + (2 − 2 + 1) (2!) + ⋯ + (n − n + 1) (n!)
2
(r − r + 1)r!
2
tr = [(r − 1) − (r − 2)] (r!)
tr = (r − 1) (r + 1)! − (r − 2)(r)!
n
Sn = ∑ tr
r=1
S50 = 1 + 49(51)! .
Q73
We have,
arg zw = π
Now,
¯
¯
z̄ + iw¯ = 0 ⇒ z̄ = −iw
¯
¯¯
∴ z = iw
π
⇒ arg z = + arg w
2
⇒ arg z =
π
2
+ π − arg z [from (1)]
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Q74
x+59
∵ 3f (x) + 2f (
x−1
) = 10x + 30 ...(1)
x+59
Replace x by x−1
, we get
x+59 x+59
3f (
x−1
) + 2f (x) = 10 (
x−1
) + 30 ...(2)
Q75
4
13λ = 4 ⇒ λ =
13
−1
So, coordinates of the point are (
8 33
, , )
13 13 13
Image of point (0,1, −1) also lies on the image of the line
x−0 y−1 z+1 ( −4 )
= = = −2
1 1 2 6
4 7 5
x = ,y = ,z =
3 3 3
Point is ( 4
3
,
7
3
,
5
3
)
4 7 5
x− y− z−
4 5
x− z−
3 7 3
= =
28 24 68
129
⇒ z =
6
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Q76
3
∴ C2 × 2 = 6
Q77
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f (0)= 0
f (1)= a
3
+
b
2
+ c
= 2a+3b+6c
6
= 0
Where f ′
(x)= ax
2
+ bx + c
⇒ ax
2
+ bx + c has at least one root in (0, 1).
Q78
z1 +z2 +z3
Here 3
= z0 ⇒ z3 = 4 + 3z0
∴ z0 can be = −2 + 2
i, −2 −
2
i
√3 √3
5π
⇒ arg(z0 )=
6
Q79
−2+1 1
C 1 M =∣
∣
∣=
∣
2 2
9 1
PM = √ − = √2
4 4
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= 3 + 2 √2 units
Q80
2j 1
( − +8 )
n n
1 n
lim ∑
n j=1 2j 1
n→∞
( − +4 )
n n
1 2x+8 1 1 4
∫ dx = ∫ dx + ∫ dx
0 2x+4 0 0 2x+4
1 1
= 1 + 4 (ln∣ ∣ ∣
∣2x + 4∣)∣
2 0
3
= 1 + 2ℓn( )
2
Q81
2
f (x)= −x for x ≤ −1,
f (x)= 2 for x = 0,
2
f (x)= −x for x ≥ 1
⇒ f (x) is even
2 1 2 1 2
−8
2
∴ I = 2 ∫ f (x) dx = 2 ∫ f (x) dx + 2 ∫ f (x) dx = 2 ∫ (1) dx + 2 ∫ −x dx =
3
0 0 1 0 1
∴ |3I | = | − 8| = 8
Q82
x x
x
y y
e (dx − dy)+e dy + dx = 0
y
x x
or e y
yd(
x
y
)+e y
dy + dx = 0
y
⇒ d(e y)+dx = 0
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On integrating, we get,
y
e y + x = C
⇒ k = 1
Q83
P(A∩B∩C)
B
P( )=
A∩C P(A∩C)
T
A ∩ C :(− − −−) (− − −T − −) − (−T − T − −)
−
¯
¯¯ ¯
¯¯ ¯
¯¯
5 5 6
5 1 1 5 1 1 1
P(A ∩ C) = C ⋅ ( ) ⋅ + C ⋅ ( ) ⋅ − ( )
4 2 2 4 2 2 2
9
= 6
2
A ∩ B ∩ C : (H T H H H T )
¯
¯¯ ¯¯
¯ ¯ ¯
¯¯¯
¯¯¯
¯¯¯
¯
or (H , H H T H T )
¯
¯¯ ¯
¯¯ ¯
¯¯¯
¯¯¯
¯¯¯
¯¯
2
P(A ∩ B ∩ C) = 6
2
Required probability= 26
9
=
2
9
=
m
n
6
2
∴ n − m = 7
Q84
y = f (x) in [0, 10]
Use L.M.V.T.
f (10) − f (0) 19 − f (0)
′
f (x) = =
10 10
19 − f (0)
−4 ≤ − 5 ≤ 4
10
19 − f (0)
1 ≤ ≤ 9
10
10 ≤ 19 − f (0) ≤ 90
−71 ≤ f (0) ≤ 9
∴ f (0)| = 9
max.
Q85
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[x] → {1, 2, 3, 4, 5, 6}
1/3 1
(2x − 1) → { }
2
sin x → π
⇒ Total 15 points
Q86
4x + 7y + 4z + 81 = 0 . . . . (i)
or
∴ λ =– 1
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Therefore,
k 2√53
[ ]=[ ]=[√53]= 7
2 2
k
⇒[ ]= 7
2
Q87
T T T
A = −A1 , A = −A2 , … . . , A = −A20
1 2 20
20 2r+1
B = ∑ 2r(Ar )
r=1
T
20 2r+1
T
B = (∑ 2r(Ar ) )
r=1
20 2r+1
T
= ∑ 2r(Ar )
r=1
20 2r+1
= ∑ 2r(−Ar )
r=1
20 2r+1
= −∑ 2r(Ar )
r=1
= −B
⇒ B is skew-symmetric
Q88
= 1000I +
128
C2 (290)
2
−
128
C1 (290) + 1 , where I is an integer
= 1000I + 128(290)(18415 − 1) + 1
= 1000m + 681
Q89
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Solving y = 5x and y = 2x 2 2
+ 9 we get x = ±√3
√3
Area, A = ∫ 0
((2x
2
+ 9)−5x )dx
2
√3
2
= 2∫ (9 − 3x )dx
0
√3
3
= 2[9x − x ]
0
(12√3)
2
A
⇒ = = 36
12 12
Q90
2
f (x) = x (2x + ax + b)
D > 0
2
a − 8b > 0
2
a > 8b
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