Acid Base Part II Test 1516 (Corrected)

Acid Base Part II Test
AP Chemistry 2015-16
Chemist: ______________________________________________ Date: ______________________
Multiple Choice
1. Correct procedures for a titration include which of the following?

I. Draining a pipet by touching the tip to the side of the container used for the titration
II. Rinsing the burette with distilled water just before filling it with the liquid to be titrated
III. Swirling the solution frequently during the titration
a. I Only b. II Only c. I and III Only d. II and III Only
2. Mixtures that would be considered buffers include which of the following?

I. 0.10 M HCl + 0.10 M NaCl
II. 0.10 M HF + 0.10 M NaF
III. 0.10 M HBr + 0.10 M NaBr
a. I Only b. II Only c. I and II Only d. II and III Only
3. Aqueous solutions of equal molar concentrations of these salts are listed in order of increasing pH.
NaBr < NaIO3 < NaF < NaC2H3O2 < Na2SO3
Which acid is the weakest?

a. HBr b. HIO3 c. HC2H3O2 d. H2SO3
4. The acid dissociation constants for the diprotic acid, malonic acid, H2C3H2O4, are Ka1 = 1.5 x 10-3 and
Ka2 = 2.0 x 10-6. Which of the following represents the Kb for HC3H2O41-?
a. Kw x Ka1 b. Kw x Ka2 c. Ka1 x Ka2 d. Kw / Ka1
5. Percentage ionization is defined as the number of moles of weak acid that ionizes expressed as a percentage of
the original concentration. Calculate the percentage ionization of a 0.10 M solution of hydroazoic acid, HN3,
Ka = 4.0 x 10-5.
a. 0.20 b. 0.40 c. 2.0 d. 4.0
6. Refer to the following:

I. Hydrazoic acid HN3 Ka = 1.9 x 10-5
II. Hydrofluoric acid HF Ka = 6.8 x 10-4
III. Phenol C6H5OH Ka = 1.3 x 10-10
IV. Hypobromous HBrO Ka = 2.0 x 10-9
Which compound is best when preparing a buffer of pH = 9.5?

a. I b. II c. III d. IV
For questions 7 – 11 refer to the following:
A total of 30.0 mL of a 0.10 M solution of a monoprotic acid (Ka = 1.0 x 10-5) is titrated with 0.20 M sodium hydroxide
solution.
7. Before the titration begins, the pH of the solution is about…
a. 3 b. 5 c. 9 d. 11
8. At the equivalence point, the pH of the solution is about…
a. 3 b. 5 c. 7 d. 9
9. The amount of NaOH required to reach the equivalence point is…
a. 15.0 mL b. 30.0 mL c. 45.0 mL d. 60.0 mL
10. The approximate pH of the solution when the weak acid is half neutralized is…
a. 3 b. 5 c. 7 d. 9
11. Which indicator is the most appropriate for signaling the endpoint of the titration? The approximate pH range for
the color change of each indicator is given.
a. Bromphenyl blue pH = 3-4.5

b. Bromthymol blue pH = 6-7
c. Phenolphthalein pH = 8-10
d. Alizarin yellow pH = 11-12
12. A solution contains sodium fluoride, which of the following can be added to make a buffer solution?
I. NaOH
II. HF
III. NaCl
a. I Only b. II Only c. I and II Only d. II and III Only
13. The pKb of the base ethylamine (C2H5NH2) is 3.25, if you wanted to prepare a buffer at pH 11.5 more ________
should be added to _______ the pH.
a. Acid, Decrease
b. Acid, Increase
c. Base, Decrease
d. Base, Increase
14. When 0.40 mol NH3 stoichiometrically react with 0.35 mol HI, which describes the solution that remains after
reaction?
a. It’s a buffer.
b. It’s a mixture of acids.
c. It’s a salt that contains only the conjugate acid.
d. A neutral solution will be produced.
For questions 15-18 refer to the following image:
15. What type of titration does the above curve represent?

a. Strong Acid with Strong Base
b. Strong Acid with Weak Base
c. Weak Acid with Strong Base
d. Impossible to Determine
16. At what point on the curve will OH1- first appear in solution?
a. B b. C c. D d. E
17. At what point can the Ka of the acid be determined?
a. A b. B c. C d. D
18. Based on the molecular picture shown below, what location on the titration curve is displayed?
a. B b. C d. D d. E
Acid Base Part II Test
AP Chemistry 2015-16
Chemist: ______________________________________________ Date: ______________________
Free Response
1. Codeine (C18H21NO3) is a pharmaceutical pain-reliever. When the drug is administered, it has an initial
concentration of 0.00500 M and a pH of 9.95 at equilibrium.
a. Determine the [OH1-] in solution at equilibrium.
b. Determine the ionization constant associated with codeine.
c. Calculate the mass of C18H22NO3Cl will be necessary when preparing a codeine buffer solution in order to
maintain a buffered pH at 8.65 in 50.0 mL solution.
2. Refer to the titration curve for the polyprotic acid H2A found below:
a. Which indicator would be better to use for determining the pH at which the first proton is released,
bromcresol green (Ka = 2.00 x 10-5) or thymolphthalein (Ka = 6.31 x 10-10)? Explain.
b. If the polyprotic acid H2A is found within the blood, where the average pH is 7.4, what substance(s)
would be observed at the molecular level between H2A, HA1-, and A2-?
Glutamine is an essential amino acid that is also polyprotic, its structure is shown below:
c. Proton A has a pKa of 2.17 and Proton B has a pKa of 9.13, in what order will the protons be dissociated
from the glutamine during a titration with a strong base? Explain.
3. Samples of biodiesel can be titrated to detect the presence of excess base with hydrochloric acid. During a
typical titration, 0.0100 M HCl is used to titrate an aliquot of biodiesel for the presence of KOH.
When a 60.0 mL sample is titrated, it is determined to be 0.0075 M KOH. Determine the following:
a. The initial pH.
b. The pH after 20.0 mL of acid have been added.
c. The pH at the equivalence point.
d. At the equivalence point, if the water evaporates, what mass of KCl would be present from the titration?
4. Hydrazine (N2H4, Kb = 1.7 x 10-6) is used to moderate pH levels in large industrial boilers. To ensure that hydrazine
is present in solution, a sample from the boiler can be titrated with a strong acid such as HNO3.
For a typical industrial boiler, the concentration of residual hydrazine should be 3.13 x 10-3 M. Determine the
following, when a 25.0 mL aliquot is titrated with 5.00 x 10-2 M HNO3.
a. The pH at the halfway point of the titration
b. The pH at the equivalence point of the titration.

Acid Base Part II Test 1516 (Corrected)

Uploaded by

Copyright:

Available Formats

Acid Base Part II Test 1516 (Corrected)

Uploaded by

Document Information

Original Title

Copyright

Available Formats

Share this document

Share or Embed Document

Sharing Options

Did you find this document useful?

Is this content inappropriate?

Copyright:

Available Formats

Acid Base Part II Test 1516 (Corrected)

Uploaded by

Copyright:

Available Formats

Acid Base Part II Test

Chemist: ______________________________________________ Date: ______________________

1. Correct procedures for a titration include which of the following?

a. I Only b. II Only c. I and III Only d. II and III Only

2. Mixtures that would be considered buffers include which of the following?

a. I Only b. II Only c. I and II Only d. II and III Only

Which acid is the weakest?

a. Kw x Ka1 b. Kw x Ka2 c. Ka1 x Ka2 d. Kw / Ka1

a. 0.20 b. 0.40 c. 2.0 d. 4.0

6. Refer to the following:

Which compound is best when preparing a buffer of pH = 9.5?

7. Before the titration begins, the pH of the solution is about…

8. At the equivalence point, the pH of the solution is about…

9. The amount of NaOH required to reach the equivalence point is…

a. 15.0 mL b. 30.0 mL c. 45.0 mL d. 60.0 mL

a. Bromphenyl blue pH = 3-4.5

a. I Only b. II Only c. I and II Only d. II and III Only

15. What type of titration does the above curve represent?

17. At what point can the Ka of the acid be determined?

Chemist: ______________________________________________ Date: ______________________

a. Determine the [OH1-] in solution at equilibrium.

b. Determine the ionization constant associated with codeine.

a. The initial pH.

b. The pH after 20.0 mL of acid have been added.

c. The pH at the equivalence point.

a. The pH at the halfway point of the titration

b. The pH at the equivalence point of the titration.

You might also like

Chemist: ________________________ Date:

Chemist: ________________________ Date: