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    Representing Enthalpy Changes Other

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    Jennifer Loh
    This document discusses four ways to represent enthalpy changes in chemical reactions: 1) Enthalpy diagrams visualize the relative enthalpies of reactants and products to show if a reaction is exothermic or endothermic. 2) Thermochemical equations list the enthalpy change within or beside the equation, with negative values for exothermic reactions releasing energy. 3) Separate expressions state the molar enthalpy of a specific reaction. 4) Enthalpy changes are associated with phase changes such as vaporization, melting, and formation. An example combustion reaction of sulfur dioxide is provided.

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    Representing Enthalpy Changes Other

    Uploaded by

    Jennifer Loh
    25 views4 pages
    This document discusses four ways to represent enthalpy changes in chemical reactions: 1) Enthalpy diagrams visualize the relative enthalpies of reactants and products to show if a reaction is exothermic or endothermic. 2) Thermochemical equations list the enthalpy change within or beside the equation, with negative values for exothermic reactions releasing energy. 3) Separate expressions state the molar enthalpy of a specific reaction. 4) Enthalpy changes are associated with phase changes such as vaporization, melting, and formation. An example combustion reaction of sulfur dioxide is provided.

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    CIMP chemistry

    Original Title

    Representing Enthalpy Changes other

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    This document discusses four ways to represent enthalpy changes in chemical reactions: 1) Enthalpy diagrams visualize the relative enthalpies of reactants and products to show if a reaction is exothermic or endothermic. 2) Thermochemical equations list the enthalpy change within or beside the equation, with negative values for exothermic reactions releasing energy. 3) Separate expressions state the molar enthalpy of a specific reaction. 4) Enthalpy changes are associated with phase changes such as vaporization, melting, and formation. An example combustion reaction of sulfur dioxide is provided.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    25 views4 pages

    Representing Enthalpy Changes Other

    Uploaded by

    Jennifer Loh
    This document discusses four ways to represent enthalpy changes in chemical reactions: 1) Enthalpy diagrams visualize the relative enthalpies of reactants and products to show if a reaction is exothermic or endothermic. 2) Thermochemical equations list the enthalpy change within or beside the equation, with negative values for exothermic reactions releasing energy. 3) Separate expressions state the molar enthalpy of a specific reaction. 4) Enthalpy changes are associated with phase changes such as vaporization, melting, and formation. An example combustion reaction of sulfur dioxide is provided.

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    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 4

    Enthalpy Changes

    Enthalpy Change - H
    Bonds Broken Bonds Made
    Energy absorbed Energy released

    4 Ways to Represent Enthalpy of a Reaction:

    For EXOTHERMIC reactions: (negative enthalpy change)

    1) Enthalpy Diagrams:
    -great to help you visualize the relative enthalpies of reactants and products and see
    whether the reaction is endothermic or exothermic.
    -y-axis (enthalpy axis) has no zero point …. This is because only changes in enthalpy are
    measured
    -no x-axis (really) as the enthalpy change of a system depends on the initial and final
    states of the system and is not affected by the process….however we do represent this as
    “reaction progression” though…

    -reactants have a larger enthalpy than products and therefore drawn above the products.
    -arrow representing enthalpy change points downward.

    2) Thermochemical Equations with energy terms (enthalpy withing the eqn'):


    -energy is released as the reaction proceeds and is listed with the products
    3) Thermochemical Equations with H values (enthalpy beside the eqn'):
    note: H is -

    4) As an Statement of the Molar Enthalpy of a Specific Reaction (separate expression):

    Now, for ENDOTHERMIC reactions: (positive enthalpy change)

    1) Enthalpy Diagrams:
    -great to help you visualize the relative enthalpies of reactants and products and see
    whether the reaction is endothermic or exothermic.
    -y-axis represents potential energy of the system.
    no x axis is called the reaction progress or reaction coordinate

    --the products have a larger potential energy than the reactants and therefore drawn above
    the reactants and the arrow representing enthalpy change points upwards.
    2) Thermochemical Equations with energy terms (enthalpy withing the eqn'):
    -reaction requires a certain quantity of energy to be supplied to the reactants

    3) Thermochemical Equations with H values (enthalpy beside the eqn'):


    note: H is +

    4) As an Statement of the Molar Enthalpy of a Specific Reaction (separate expression):


    As a Separate Expression:
    Enthalpy change is associated with phase changes:
    Hvap (vaporization) Hcomb (combustion)
    Hmelt ( melting) Hf (formation)
    Hsol (solution) Hneut*moles of base consumed
    Hfr (freezing) Hneut *moles of acid consumed

    Example:

    The molar enthalpy of combustion of sulphur dioxide is – 98.9 kJ/mol of SO2. What is
    the enthalpy change for this reaction: *please represent this in each of the for ways of
    representing changes in enthalpy.

    2 SO2 (g) + O2(g) 2 SO3(g)

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