AITS 2223 PT I JEEA 20.11.22 Paper1

FIITJEE
ALL INDIA TEST SERIES

JEE (Advanced)-2023
PART TEST – I
PAPER –1
TEST DATE: 20-11-2022
Time Allotted: 3 Hours Maximum Marks: 180
General Instructions:
 The test consists of total 54 questions.

 Each subject (PCM) has 18 questions.
 This question paper contains Three Parts.
 Part-I is Physics, Part-II is Chemistry and Part-III is Mathematics.
 Each Part is further divided into Two Sections: Section-A & Section-B.
Section – A (01 –06, 19 – 24, 37 – 42): This section contains EIGHTEEN (18) questions. Each question has
FOUR options. ONE OR MORE THAN ONE of these four option(s) is(are) correct answer(s).
Section – A (07 – 10, 25 – 28, 43 – 46): This section contains TWELVE (12) Matching List Type Questions.
Each question has FOUR statements in List-I entries (I), (II), (III) and (IV) and FIVE statements in List-II
entries (P), (Q), (R), (S) and (T). The codes for lists have choices (A), (B), (C), (D) out of which, ONLY ONE of
these four options is correct answer.
Section – B (11 – 18, 29 – 36, 47 – 54): This section contains TWENTY FOUR (24) numerical based
questions. The answer to each question is a NUMERICAL VALUE. If the numerical value has more than
two decimal places, truncate/round-off the value to TWO decimal places.
MARKING SCHEME
Section – A (One or More than One Correct): Answer to each question will be evaluated according to the following
marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen;
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen;
Partial marks : +2 if three or more options are correct but ONLY two options are chosen and both
of which are correct;
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a
correct option;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –2 In all other cases.
Section – A (Single Correct): Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –1 In all other cases.
Section – B: Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct numerical value is entered at the designated place;
Zero Marks : 0 In all other cases.
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AITS-PT-I (Paper-1)-PCM-JEE(Advanced)/2023 2
Physics PART – I
Section – A (Maximum Marks: 24)

This section contains SIX (06) questions. Each question has FOUR options (A), (B), (C) and (D). ONE OR
MOER THAN ONE of these four option(s) is (are) correct answer(s).
1. Four dancers start their dance by forming a square with side

 = 9m. After that, they always move anticlockwise towards v
their neighbour with variable velocity v  k x where k = 0.1
m1/2sec1 and x is the distance of the closest neighbour in v
meter. Then choose the correct option(s).
v
(A) All the dancers will meet with each other at t = 60 sec after they start their dance.
(B) Angular velocity of the line joining the adjacent dancers increases with time.
(C) All the dancers will meet with each other at t = 63 sec after they start their dance.
(D) Magnitude of acceleration of each dancer is remains constant with time.
Ans. A, B, D
dx
Sol.   0.1 x
dt
0 
dx

9
x 
 0.1 dt   = 60 sec
0
0.1 x 0.1
  rad/s
x x
0.1
a = v = 0.1 x  0.01 m/s2
x
2. A point object of mass m = 2kg is connected to a cylinder of radius v0

R = 1m via a massless inextensible rope. At time t = 0 the object is
moving with an initial velocity v0 = 5 m/s perpendicular to the rope
as shown in the figure. The rope has initial length L0 = 10 m and
having non zero tension. Figure shows the top view and the motion
of the object is taking place on the horizontal smooth surface and
the cylinder is always fixed. The point object moves such that the
rope wraps up around the cylinder. The rope will break when the
tension in the rope exceeds 100 N. Then choose the correct
option(s).
(A) Kinetic energy of the object at the instant when the rope breaks is 25 J.
(B) Angular momentum of the object about the axis of the cylinder at the instant when the rope
breaks is less than 5 kg-m2/sec.
(C) Angular momentum of the object about the axis of the cylinder at the instant when the rope
breaks is equal to 5 kg-m2/sec.
(D) Angular momentum of the object about the axis of the cylinder at the instant when the rope
breaks is greater than to 5 kg-m2/sec.
3 AITS-PT-I (Paper-1)-PCM-JEE(Advanced)/2023
Ans. A, C
Sol. Speed of the object will remain constant because tension

is always perpendicular to the velocity. r
r (/2)  
So angular momentum about O = mv 0 sin   mv 0r  
sin 
mv 0mv 02 O v0
 5 kg-m2/sec
Tmax
3. Two discs are mounted on thin, lightweight rods oriented

through their centres and normal to the discs. These axles are
constrained to be vertical at all times, and the discs can pivot
frictionlessly on the rods. The discs have identical thickness
and are made up of the same material, but having different
radii r1 and r2. The discs are given angular velocities 1 and 2,
respectively, and L1 and L2 represents angular momentum of
the discs along their rotational axis respectively. Now they are r1 r2
brought into contact at the edges. After the discs interact via
friction it is found that both discs come exactly to a halt. Which
of the following(s) must hold? Ignore effects associated with
the vertical rods.
(A) 1r14  2r24 (B) 1r13  2r23
L1 r1 L1 1r12
(C)  (D) 
L2 r2 L2 2r22
Ans. B, C
Sol. 
For the bigger disc C1r14  fdtr1  0
For the smaller disc C2r24  fdtr2  0

L1 r1
So, 1r13  2r23 and 
L2 r2
4. A dumbbell is formed by connecting two identical particles A J A

m m
each of mass m with a massless rod. The system is placed on
a horizontal smooth surface and impulse J is applied in two J C C
ways as shown in the figure as situation-(i) and situation-(ii).
Then just after the application of impulse, choose the correct
option(s). m m
B B
Situation-(i) Situation-(ii)
(A) Velocity of centre of mass with respect to ground frame in situation-(i) and situation-(ii) are
same.
(B) Kinetic energy of the dumbbell with respect to centre of mass frame in situation-(i) and
situation-(ii) are same.
(C) Angular momentum of the dumbbell with respect to centre of mass frame in situation-(i) and
situation-(ii) are different.
(D) Velocity of particle A in situation-(ii) is double of velocity of particle A in situation-(i) just after
the application of impulse.
Ans. A, C, D
J
Sol. In both situations v C 
m
J
In situation-(ii),  
m
5. Three particles A, B and C are simultaneously thrown from a

cliff and their trajectories are shown in the given figure. Neglect
air resistance and take gravity to be uniform during the motion.
If u yA , uBy and uCy denotes the initial vertical components of
velocity of particles A, B and C respectively and the times tA, tB
and tC, they take to hit the ground respectively. Then B
A
C
(A) uBy  uCy  uyA (B) uBy  uyA  uCy

(C) t A  t C  tB (D) t C  t A  tB
Ans. B, D
Sol. Hmax
B  Hmax
A  Hmax
C (as shown clearly)
So, uBy  uyA  uCy
Vertical component of initial velocity of each particle will decide the time taken.
So, t C  t A  tB
6. A thin rod has an unknown non-uniform density. It is mounted CM

on an axle passing perpendicular to it, through its centre of
mass as shown and is then rotated about the axle. The axle
divides the rod into two parts, one on each side of it. Which of 
the following must be true, no matter how the mass in the rod is
distributed?
(A) The two part must have the same mass.
(B) The magnitudes of the linear momentum of the two parts must be equal.
(C) The magnitudes of the angular momentum of the two parts about the centre of mass must be
equal.
(D) The kinetic energies of two parts must be equal.
Ans. B
Sol. For COM position, m1x1 = m2x2

Where m1 and m2 are masses of left and right part of the rod and x1, x2 are their respective
position of centre of mass.
Simultaneously, m1x1 = m2x2
and I1  I2 
1 2 1 2
and I1  I2 
2 2

This section contains FOUR (04) Matching List Type Questions. Each question has FOUR statements in
List-I entries (I), (II), (III) and (IV) and FIVE statements in List-II entries (P), (Q), (R), (S) and (T). The
codes for lists have choices (A), (B), (C), (D) out of which ONLY ONE of these four options is correct
answer.
7. List –I describes for systems and List-II gives possible value of work done in Joules.
List –I List -II
(I) A plank of mass 100 kg is placed on a smooth horizontal (P) +100J
surface at rest along with a man. Now man starts moving on
the plank with relative velocity of 3 m/s with respect to plank.
The work done by man is
50 kg
urel = 3 m/s
100 kg
(II) A block of mass 2 kg is placed on a smooth track and imparted (Q) 100J
a velocity of 10 m/s to the left and observed by an observer
moving with 5 m/s as shown in the figure. Work done by the
normal force applied by the track on the block upto the instant
when the block reaches the highest point on the track in the
frame of observer. Assume that block never loose contact with
the track. (take g = 10 m/s2)
10 m/s w.r.t 5 m/s w.r.t

ground ground
2 kg
(III) A particle of mass 1 kg is projected from an unstable (R) +150J

equilibrium point N towards a stable equilibrium point S with
negligible velocity in a conservative force field having potential
energy function
 1  2 2
U   J / m4   x  10   x  30  , where x is in meters.
 100 
Then work done by conservative force during the displacement
from N to S is
(IV) A solid hemisphere of mass 4 kg and radius 10 m is slowly (S) 150J
turned as shown in the figure. Then work done by external
force in turning is (Take g = 10 m/s2)
(T) Zero
Which one of the following options is correct ?
(A) I  R, II  T, III  P, IV  P
(B) I  S, II  T, III  Q, IV  P
(C) I  R, II  Q, III  P, IV  P
(D) I  T, II  Q, III  Q, IV  P
Ans. C
Sol. (I) 0 = 100v + 50(v + 3) (COLM) 3 m/s

v = 1 m/s
1 1
So, work done by man = (100)(1)2  (50)(2)2  150 J v
2 2
(II) WN + Wmg =  K.E. (WET)
1 1
WN  (2)(10)2  (2) (5)2  (15)2 
2 2  
WN =  100 J
(III) Unstable equilibrium points are x = 10 m, 30 m
Stable equilibrium point is x = 20 m
1
So, Ui = 0, and Uf =  (10)4  100 J
100
Wconservative force = Ui  Uf = 100 J
 5R 3R  mgR
(IV) Wext = Uf  Ui = mg     100 J
 8 8  4
8. A disc placed on a frictionless horizontal plank is rotating with a y


constant angualr velocity  about its vertical axis. Now the plank is

made to move with a constant acceleration a on a straight path.
Initially the centre of the disc is at the origin of xyz space which is
fixed with the plank and xy plane is on the plank. List-I gives some x
 
possible a ,  and List-II gives trajectories of instantaneous centre
of rotation of the disc.
List –I List -II

 
(I) a  2ˆj m/s2,   4kˆ rad/s (P) y=4
 
(II) a  2ˆj m/s2,   4kˆ rad/s (Q) y = 4x2 (x  0)
 
(III) a  2iˆ m/s2,   4kˆ rad/s (R) y = 4x2 (x  0)
 
(IV) a  2iˆ m/s2,   4kˆ rad/s (S) x = 4y2 (y  0)
(T) x = 4y2 (y  0)
(A) I  P, II  Q, III  T, IV  S
(B) I  Q, II  R, III  S, IV  T
(C) I  Q, II  S, III  T, IV  R
(D) I  R, II  Q, III  S, IV  T
Ans. B
Sol. In case-(I)
at  x
1
y  at 2
2
1 2 x 2
y a 2
2 a
2 x 2
y
2a
9. Figure shows a system of multiple blocks  = 0.1 D

1kg A
placed over each other and connected  = 0.4
 = 0.2 1kg B 3kg
through an inextensible string. All the 1kg C  = 0.5
pulleys are ideal and frictionless. List-I S1 S2
shows the surfaces between which the
friction is asked and List-II gives the value
of friction acting between the surfaces.
(Take g = 10 m/s2)
E 2kg
List –I List –II

(I) Between A and B (P) 15 N
(II) Between B and C (Q) 9.4 N
(III) Between C and S1 (R) 7.2 N
(IV) Between D and S2 (S) 6N
(T) 1N
(A) I  T, II  R, III  S, IV  Q
(B) I  T, II  R, III  S, IV  P
(C) I  T, II  S, III  R, IV  Q
(D) I  T, II  Q, III  R, IV  P
Ans. A
Sol. 3 kg block will be at rest. (so friction between S2 and D = tension in the string connect to block D)
Considering A + B + C in a system
T  6 = 3a, 20  2T = 2a1 and a = 2a1
8
So, a  m/s2
7
So, there will be slipping between blocks A and B.
Now consider (B + C) in a system
T  6  1 = 2a
20  2T = 2a2 and a = 2a2
So, T  7 = 4a2
20  2T = 2a2
So, a = 1.2 m/s2
10. A disc of mass m is placed over a horizontal smooth surface (xy plane) z
such that the centre of the disc is at the origin of the xyz space, as y
shown in the figure. Radius of the disc is R = 1m and is rotating with an

angular velocity 0  6kˆ rad/s and having zero velocity of centre of 0

mass. A particle of same mass m hits the disc with a speed v = 8 m/s x
in each case of list-I. List-I gives the trajectory and velocity direction of
the particle before hitting the disc and the coefficient of restitutions (e)
of the collision. List-II gives the angular velocity of the disc just after the
collision (in rad/s)
List –I List -II
(I) x = 0, y = R and v̂  kˆ , e = 0 (P) 3
(II) x 3 ˆ 1ˆ (Q) 5
y , z = 0 and v̂  i j, e= 1
3 2 2
(III) y = R, z = 0 and v̂  ˆi , e = 0 (R) 6
(IV) R (S) 7
y  , z = 0 and v̂  ˆi , e = 0
2
(T) 8
(A) I  P, II  Q, III  R, IV  T
(B) I  S, II  Q, III  P, IV  R
(C) I  P, II  R, III  S, IV  Q
(D) I  S, II  P, III  Q, IV  T
Ans. C
mR2  mR2 mR2 mR2 

Sol. Case –I : 0      
2  2 4 4
 
0
 3 rad/s
2
Case –II:   0  6 rad/s
mR2 R
Case –III: 0  mv  (mR2 )
2 2
8
So, 3     7 rad/s
2
mR2 R 1
Case –IV: 0  mv    mR2 
2 22
8
3    5 rad/s
4
Section – B (Maximum Marks: 24)

This section contains EIGHT (08) numerical based questions. The answer to each question is a
NUMERICAL VALUE. If the numerical value has more than two decimal places, truncate/round-off the
value to TWO decimal places.
11. Two massless rods are attached to F 0.5m 2m

frictionless pivots, with their ends
touching. The distances between
the pivot points and the endpoints
of the rods are shown in the figure.
2m 1m F1
Neglect friction force between the
rods, if a force F = 9N is applied at
the left end of the left rod, what
force F1 (in newton) must be
applied at the right end of the right
rod to keep the system in
equilibrium.
Ans. 4.50 (range 4.40 to 4.60)
Sol. (F) (2) = (N) (1)  N = 2F (N is normal between rods)

 1
and (N)    (F1 )(2)
2
F
So, F1 
2
12. A small sphere slides with a speed v = 60 m/s on

a frictionless horizontal surface between two
parallel massive walls. One of which is fixed and
the other can be moved. Initial distance between
walls is L. The sphere bounces between the walls
perfectly elastically. Now the right wall is moved
towards the left walls by a distance 0.01 L with
speed 0.0001v. Then what is the final speed of v
the sphere after the said movement of the wall in Movable
m/s. Fixed wall L
wall
Ans. 60.60 (range 60.00 to 61.00)
0.01L 100L
Sol. Total time taken = 
0.0001v v
100L
Total number of collision with moving wall in the said movement   50
 2L 
v 
 v 
In each collision with the movable wall speed of the sphere increases by 0.0002 v.
So, final speed of sphere = v + 50  0.0002v = 1.01 v = 60.60 m/s
13. Figure shows a laptop made of two identical uniform plates,

each of mass m = 1 kg connected by a hinge and placed on a
rough horizontal surface as shown. The hinge is locked when
the screen makes an angle of 120 from the keypad of the
laptop. Assume that the laptop does not slide on the horizontal 120
surface, then what is the minimum force (in newton) that can
be applied on the top of the laptop, in the plane of the page to
cause the bottom of the laptop to lift off the ground? (Take g =
10 m/s2)
Ans. 2.50 (range 2.40 to 2.60)
Sol. from torque equilibrium about O F

1 
F  mg  mg
22 2
mg
F N
4 30
mg
O

mg
14. A block of mass m = 1 kg is dropped vertically onto a fixed ramp from a height of h = 2.5 m with
angle  = 37 with horizontal and having coefficient of static friction and kinetic friction = 0.5. The
block is dropped in such a way that it does not rotate after colliding with the ramp. Through this
problem assume that the time of the collision is negligible. The block slides down the ramp
immediately after impact. What it the speed (in m/s) of the block right after the collision? (Take g
= 10 m/s2)
Ans. 1.41 (range 1.35 to 1.45)
Sol.  Ndt  mv cos  (v  2gh )
mv sin   mv cos  3 1 4 50

So, v f   2gh     2 m/s
m 5 2 5 5
15. One end of the non stretchable rope is uA

tied to a fixed knob O, while other end
B of the rope is moving horizontally
with a constant velocity uB = 1 m/s.  B uB
A
That rope goes through a small ring A,
which can move freely along a
horizontal straight rod as shown in the
figure. Determine velocity uA of the ring
(in m/s), when inclined section of the
rope makes an angle  = 30 with the O
rod.
Ans. 7.46 (range 7.40 to 7.50)
Sol. xB  x A  x 2A  h2  L xB
dxB dx A xA dx A uA
  0 xA
dt dt x 2A  h2 dt
uB 1 2  uB
So, u A    A B
1  cos  3 2 3
1
2 h
 uA = 7.46 m/s
16. Two small bodies with masses m and 2m are attached to a spring of 2m
v0
negligible mass. Initially the compressed spring form a straight vertical
line, when both objects are launched with same velocities v0 = 1 m/s in k
2h
the horizontal direction as shown in the figure. Initial height of the lower
g
body is h = 1 m from the ground, while distance of heavier body is 2h = m
2m. After t = 0.1 sec from the launch, lower body hits the ground. v0
Determine height H (in m) of the upper body from the ground at that h
moment of time. (assume no air drag and g = 10 m/s 2)
Ans. 2.43 (range 2.35 to 2.55)
2
1  1 
Sol. yCM  (10)    0.05 m
2  10 
2
So, hCM  1   0.05  1.62 m
3
1.62  3
So, y 2m   2.43 m
2
17. A right triangular wooden block of mass M = 4 kg is at rest on a m m

smooth table as shown in the figure. Two smaller wooden cubes M
both of mass m = 2 kg, initially at rest on the two sides of the 37 53
larger block start sliding down. What is the normal force (in
newton) applied by the system on the table? (take g = 9.8 m/s 2)
Ans. 58.80 (range 57.00 to 59.00)
Sol. Assume the bloc M at rest, we see that both smaller cubes are applying net zero resultant
horizontal force on the larger block.
So, N = Mg + mg (cos2 37 + cos2 53) = Mg + mg
18. The ‘wall of death’ ride consists of a drum with d

diameter d = 10m which rotates at an angular velocity  d
 as shown in the figure-(a). Passengers stand

against the inside vertical rough wall and as the ride
speeds up to angular velocity , they are held against
the wall and can not slide down due to friction with
the wall. The rotating drum is now tilted so that its  = 37
axis of rotation is  = 37 above the horizontal as
Figure-(a) Figure-(b)
shown in the figure-(b). If the coefficient of friction
between the wall and the passenger is  = 0.5, then
find the minimum angular velocity 0 (in rad/s) of the
drum so that passengers are held against the wall at
the highest point. (Take g = 10 m/s2)
Ans. 2.00 (range 1.95 to 2.05)
Sol. mg cos 53 = 0.5 N

mg sin 53 + N = m2r
mg(0.6)
So, mg(0.8)   m 2r
0.5
 8 6
So, g     2r
 10 5 
So, 10  2 = 2r
20
So,    2.00 rad/s
5
Chemistry PART – II

19. Which of the following species are polar as well as non-planar?

(A) XeF4
(B) H2 O 2
(C) XeF5
(D) XeF5
Ans. B, D
Sol. XeF4  sp3 d2  Square planar and nonplanar

H2 O2  sp3  open book structure. Nonplanar and polar
XeF5  Pentagonal planar and non  polar
XeF5  Square pyramidal non  planar polar
20. All bonds are equivalent in

(A) Cr2 O72
(B) HCO3
(C) XeO64 
(D) SF6
Ans. C, D
Sol. O O O
O
Cr Cr C
O O
O O
H
O O
All Cr - O bonds are not equivalent All C - O bonds are not equivalent
O
O F
O
F F
Xe
S
O O
O F F
F
All Xe - O bonds are equivalent due to resonance sp3d2 hybridisation
1  6r r 2  r /3ao
21. The radial part R  r    o  2  e represent for an orbital. (ao is Bohr’s radius of H-
9 a3/2
o a ao 
atom)
Choose the correct statement about the orbital
(A) this orbital may have one nodal plane in yz plane
(B) it is 3p orbital
(C) one node will be found at the r  6ao distance from nucleus
(D) this orbital can accommodate maximum 6 electrons
Ans. A, B, C
Sol. r = 0, R(r) = 0 so its true for p-orbital, Azimuthal quantum number is 1.

6r r 2
R  r   0, o  2  0
a ao
One radial node is observed at r  6ao distance.
So, its true for 3p-orbital.
In Px orbital nodal plane is in yz plane and p-orbital accommodate only 2-electron.
22. Which of the following geometry is most likely form from sp3 d  hybridisation ?
(A) Linear
(B) Tetrahedral
(C) Bent T-shaped
(D) See-Saw
Ans. A, C, D
Sol. Tetrahedral will be formed by sp3-hybridisation. Other three can be formed by distorted sp3d
hybridisation. i.e.
XeF2 andI3  are sp3d but linear shape.
BrF3 is sp3d but bent T-shaped.
SF4 is sp3d but see-saw shaped.
23. Find the incorrect statement

(A) Iodine exists as I28  ion in Cs2I8
(B) Oxidation state of Cr in CrO5 and CrO38  is +6
(C) FeCl2 is more ionic than FeCl3
(D) LiO2 and NaO2 are yellow coloured compound but KO2 is colourless
Ans. A, C
Sol. In CrO38  Cr has +5 oxidation state.

KO2 is also colorful.
24. Consider the following options and choose the correct one
(A) In the given equilibrium 2SO2  O2  2SO3
If O2 is added and the volume of the reaction vessel is reduced the equilibrium is shift in
product side.
(B) If we add CrO24 ion in saturated solution of Ag2 CrO4 it will decreases  Ag  .
(C) Three sparingly soluble salt A 2 B, AB and AB3 are given. If all the three having same value of
solubility product (KSP). In the saturated solution the correct order of their solubilities is
AB  A 2 B  AB3 .
(D) If in option (A) inert gas is added at constant pressure and temperature. Partial pressure of
SO3 will be remain same.
Ans. A, B, C
Sol. In option (D) if we add inert gas at constant pressure and temperature. Equilibrium will get
disturbed and more in backward direction.

answer.
25. If tx represents time required for a fraction x of a reactant to be reacted during a reaction involving
only one reactant. Then match List – I with List – II.
List – I List – II
(I) Zero order reaction (P) t 3/ 4
3
t1/2
(II) First order reaction (Q) t1/ 4
2
t1/8
(III) Second order reaction (R) t 7/8 3

t 3/ 4 2
(IV) Order of reaction  1 (S)

  1  e kt 
(T) t100%
2
t 50%
(   degree of dissociation, k  rate constant)
(A) I→Q, T; II→R, S; III→P; IV→P, R, S
(B) I→Q; II→R, T; III→P; IV→P, R
(C) I→ T; II→P; III→R, S; IV→Q, T
(D) I→R, T; II→Q; III→ P; IV→P, Q
Ans. A
Sol. For reaction A  Product

Using the given formula we can solve all the options
 A o   A t
For zero order reaction t 
k
1  A o
For first order reaction t  n
k  A t
1 1 1 
For second order reaction t    
k   A t  A o 
26. List – I contains properties and List – II contains moles or ions

(I) 2 lone pair on central atom (P) XeF
5
(II) Zero dipole moment (Q) NF3
(III) Planar (R) ICl3
(IV) All adjacent bond angle are equal (S) XeF4
(T) PCl3F2
(A) I→P, R, S; II→S, T; III→P, Q,R, S; IV→P, Q, R, S, T
(B) I→P, R, S; II→P, S, T; III→P, R, S; IV→P, Q,R, S
(C) I→P, R, T; II→R, S, T; III→R, S; IV→S, T
(D) I→P,S, T; II→P, R, S; III→P, Q,R, S, T; IV→P, R, S
Ans. B
Sol. Correct answer is I→P, R, S; II→P, S, T; III→P, R, S; IV→P, Q,R, S
27. List – I contains compounds with bond parameter and List – II contains bond parameter
decreasing order (x1, x2, x3 are bond length while , ,  are bond angle)
1  x3  x 2
(I) OH NH2 (P) x
F
B B B
x1 x2 x3
  
F F F F F F
(II) (Q) 
N
N N
 F
  Cl F F
H Cl Cl
H H
(III) (R) 
O O O
x1 x2 x3
  
H H F F Cl Cl
(IV) S8 S2 F2 S2 Cl2 (S) x3  x 2  x1
 S  S bond length x1 x2 x3
(T) 
(A) I→S,T; II→R; III→Q,S; IV→S
(B) I→R, S; II→Q; III→S, T; IV→P
(C) I→R,S; II→R; III→Q, S; IV→P
(D) I→R,S; II→T; III→S,T; IV→S
Ans. C
Sol. Correct order is I→R,S; II→R; III→Q, S; IV→P
28. List – I contains elements and compounds in respective properties and List – II contains
decreasing order of properties.
(I) B Al Ga In (P) 4 > 3 > 2 > 1
1 2 3 4  Atomic size 
(II) NaOH KOH RbOH CsOH (Q) 4>2>3>1
1 2 3 4  Thermal stability 
(III) SiO2 CO2 CaO Cs2 O (R) 1>2>3>4
1 2 3 4 Basic strength 
(IV) BeF2 BaF2 CaF2 MgF2 (S) 4>3>1>2
1 2 3 4  Water so lub ility 
(T) 2>3>4>1
(A) I→Q; II→S; III→P; IV→T
(B) I→Q; II→P; III→S; IV→T
(C) I→P; II→Q; III→S; IV→R
(D) I→Q; II→P; III→S; IV→R
Ans. D
Sol. Correct answer is I→Q; II→P; III→S; IV→R

29. Fauzosite, a zeolite has formula

Na x  AlO2  y  SiO2 136  .250H2 O
 
x
The value of is.....
y
Ans. 1.00
Sol. SiO2 is neutral and Na has unit +ve charge AlO2 should have unit – ve charge to balance the
charge of molecule.
x(1) + y(– 1) + 136(0) + 250(0) = 0
x=y
x
 1.00
y
30. Calculate the pH at equilibrium point when a solution of 0.6 M CH3COOH is titrated with a
solution of 0.20 M NaOH (Ka of CH3COOH 10-5 at 25oC (log2 = 0.30, log3 = 0.48)
Ans. 9.09
Sol. CH3 COOH  NaOH  CH3 COONa  H2 O

0.60 V 0.20  3V 0.60V
0.60V 3
CH3 COONa   M
4V 20
pH at 25oC for salt of WA + SB is
1
pH  7   pK a  log  salt  
2
1 3 
pH  7   5  log 
2 20 
1
 7   5  0.82 
2
1
 7   4.18 
2
 7  2.09
= 9.09
31. In cyanuric triazide C3 N3 N3 3  . The number of sp2 hybridised centre atoms is/are ‘x’ and
x
number of  bond that can lies in same plane is/are ‘y’. Calculate the value of ...?
y
Ans. 1.50
Sol. N
N sp
N sp2
C sp2
sp2
sp2 N N
sp2
C C
N N
N N N
N sp2
2 2
N sp sp
2 sp
sp sp
Maximum 6 bond can lies in same plane and sp2 centre are 9.
x  9, y  6
x 9
   1.50
y 6
32. For reaction I  ClO3  H2 SO4  Cl  HSO 4  I2


If stoichiometric coefficient of HSO4 is ‘x’ and total number of electron gain in the balance
xz
reduction half reaction is ‘y’. Calculate the value of ......?
y
(z – Stoichiometric coefficient of I 2).
Ans. 1.50
Sol. Balance reaction is

ClO3  6I  6H2 SO4  3I2  Cl  6HSO 4  3H2 O
x = 6, y = 6, z = 3
33. 2 mole of NH4HS(s) is taken in close container of volume 2 litre. If 1 mole NH4HS (s) taken part in
reaction to attain the equilibrium state and at equilibrium moles of H2(g) is 0.75.
NH4 HS  s   NH3  g   H2 S  g K C1  x
1 3
NH3  g   N2  g   H2  g K C2  y
2 2
At equilibrium [NH3] = a M
y1
[N2] = b M calculate the value of is... ?
x1  a  b 
Ans. 6.93
Sol. NH4 HS  s   NH3  g  H2 S  g 

2x xy x
1 3
NH3  g   N2  g  H2  g 
2 2
y 3y
xy
2 2
Given,
3y
2–x=1  0.75
2
 1
x=1 y 
2
 1  1  1
x1  K C1   .     
2 4 8
3 1
 3 2  1 2
8 8 3 3 
   
y1  K C2  
 1  16 
 
4
 
1
a  NH3   M
4
1
H2 S  M
2
1
b  N2   M
8
3
H2   M
8
y1 3 3 8 8
   4 3
x1  a  b  16 1 3
 4  1.732
= 6.928
= 6.93
34. The mechanism of the reaction

K,Ea,A
X  2Y   P is
Fast 
K ,Ea ,A
Step 1. X  Y   1 1 1 I
K 2 ,Ea2 ,A 2
Step 2. I  Y 
K 3 ,Ea3 ,A 3
P  Slow 
If the value of K1,K 2 ,K 3 ,Ea1 ,Ea2 ,Ea3 , A1, A 2 and A 3 are given below
K1 K2 K3 A1 A2 A3 Ea1 Ea 2 Ea3
10 3
10 4
10 5
2  10 8
2  10 9
2  10 6 20 40 35
1
Rate constant unit and pre-exponential factors for the reaction is in sec and activation energy is
KA
in kJ. Calculate the value of is.....?
Ea
Ans. 1.33
K1K 3
Sol. K  overall    104 sec 1
K2
A1 A 3
A  overall    2  105 sec 1
A2
Ea  overall  Ea1  Ea3  Ea2  15 kJ
K.A 2  10 4  105
  1.33
Ea 15
35.
0.30 L
0.70 L
0.2 M
0.2 M
MgCl2 solution
NH3 solution
Mix
What mass (in g) of (NH4)2SO4 should be added to the above mixture cause the Mg(OH)2 to re-

dissolve? K SP for Mg  OH2  6.0  10 12 and K b for NH3  2  105 
Ans. 18.48
Sol. MgCl2  2NH3  2H2 O  Mg  OH2  s   2NH4 Cl

Mg  OH2  s   Mg2  2OH
NH4 2 SO4 is acidic so it will dissolved Mg  OH2 solid which is formed in mix. When all
Mg  OH2 will re-dissolve the conc. of Mg2+ ions in the final solution will become equal to its initial
conc.
0.70  0.2
NH3  in mix initially   0.14 M
1.0
0.30  0.2
Mg2   in mix initially   0.06 M
  1.0
When Mg2    0.06
K SP 6  1012
OH     105 M
  Mg2   0.06
 
NH4  OH 
   K b NH3 
For NH3 K b   NH4  
NH3  OH 
 
2  10 5  0.14
NH4    0.28 M
  10 5
Mole of NH4   0.28
0.28
Mole of NH4 2 SO4 needed   0.14
2
Mass of NH4 2 SO4  132  0.14
= 18.48 g.
36. In a elementary chemical reaction A  aq  

t1/ 2 10 min
 2B  aq  C  aq 
Reaction mixture react with another reactant T and n-factor of A, B and C react with T in the ratio
2 : 1 : 2 respectively.
If volume of ‘T’ used at 10 min is 40 ml. Calculated volume of T used at t = 0 is x ml, at t = 20 min,
is y ml at t   is z ml.
yz
Find out the value of is.......?
x
Ans. 37.50
Sol. A  aq  2B  aq  C  aq 

t0 a 0 0
a a
t  10 min a a
2 2
3a 3a 3a
t  20 min a
4 2 4
t 0 2a a
Let the normality of ‘T’ is N and initial volume of ‘T’ is used x ml
At t = 0 Meq. of A = Meq. of T
a  2n  N  x … (1)
At t = 10 min Meq. of (A + B + C) = Meq. of T

a a
 2n  a  n   2n  40  N … (2)
2 2
At t = 20 min Meq. of (A + B + C) = Meq. of T
a 3a 3a
 2n  n  2n  N  y … (3)
4 2 4
At t =  min Meq. of (B + C) = Meq. of T
2a  n  a  2n  N  z … (4)
80 140 160
Solving these equilibrium x  ml, y  ml, z  ml
3 3 3
yz
Value of  37.5 .
x
Mathematics PART – III

3 2x 2  x 3
37. If maximum value of f  x   (where x > 0) is , then  may lie in
2x  x  2 sin 
2 2
2
     
(A)   ,  (B)   , 
 6 6  4 4
  
(C)   ,  (D) (–, )
 3 3
Ans. B, C, D
3
Sol. f x 
 2sin2  
2x 2  x   
 2x  x 
2
Using AM  GM
2sin2 
2x 2  x  1 1
 2x 2  x   2sin2   2  3  2 2 sin     3
f x  3 cosec 
2 2f  x 
22
3 1
 f x   |cosec | = 2  |sin | =
2 2
x 1
 f  t  dt  e  ae  f  t  e dt , then
x 2x t
38. If
0 0
1
(A) a  (B) f  x   e x  2e2x
3  2e
1
(C) a  (D) f  x   e x  e  x
e
Ans. A, B
1
1
 f t e
t
Sol. Put x = 0  dt 
0
a
x
1
  f  t  dt  e  ae2x   e x  22x , differentiating we get, f  x   e x  2e2x
x
0
a
39. If a function satisfies (x – y) f(x + y) – (x + y) f(x – y) = 2(x2y – y3)  x, y  R and f(1) = 2, then
(A) |f(x)| is non differentiable at two points (B) |f(x)| is continuous everywhere
(C) f(–4) = 12 (D) f(4) = 18
Ans. A, B, C
Sol. (x – y) f(x + y) – (x + y) f(x – y)= 2y(x – y)(x + y)

f v f u
Let x – y = u, x + y = v  uf(v) – v(f(u) = (v – u)uv  v  u  k
v u
 f(x) = kx + x2  f(1) = 2  k = 1  f(x) = x2 + x
40. The value(s) ‘a’ for which the area of the triangle included between the axes and any tangent to
the curve xay = a is constant is/are
1
(A)  (B) –1
2
1
(C) (D) 1
2
Ans. D
dy dy ay
Sol. x a y   a , on differentiating ax a 1y  x a
0  
dx dx x
ay
Tangent at point (x1, y1) is y  y1   1  x  x1 
x1
1 a  a  1
2
 x1 
1 a
Area =    area is constant if a = 1
2 a
x
41. Let f(x) be non-positive continuous function and F(x) =  f  t  dt
0
 x  0 and f(x)  c F(x) where c >
dg x
0 and let g : [0, )  R be a function such that  g  x   x > 0 and g(0) = 0, then
dx
(A) the total number of roots of the equation f(x) = g(x) is 1
(B) the total number of roots of the equation f(x) = g(x) is 0
(C) the number of solution of equation |x2 + x – 6| = f(x) + g(x) is 1
(D) the number of solution of equation |x2 + x – 6| = f(x) + g(x) is 0
Ans. A, D
Sol. f(x)  0, F(x) = f(x) as f(x)  c F(x)  F(x) – c F(x)  0

d  cx
 e  cx  F  x   c  e cxF  x   0  e  F  x  0
dx
 e  cx  F  x  is an increasing function
 e  cx  F  x   e  c 0  f  0   F(x)  0  f(x)  0  f(x) = 0
 
d x
Also,  e g  x    0  e x g  x  is a decreasing function
dx
 e–xg(x) < e–(0)g(0)  g(x) < 0 (as g(0) = 0)
Thus, f(x) = g(x) has one solution x = 0 also, |x2 + x – 6| = f(x) + g(x) = g(x)  no solution

 sin x  2y   sin x 1  2cos x  and  , 0  is a point on the curve,
dy
42. If y(sin 2x + y cos x) + sin x
dx 2 
then which of the following is a point on the curve also
 3   3 
(A)  ,  1 (B)  , 0 
 2   2 
 
(C)  ,  1 (D) none of these
2 
Ans. B, C
Sol. Solution of differential equation is  sin2 x  y   sin x  y 2   cos x  cos2 x   0

answer.
43. Match the following List-I with List-II

List-I List-II
1
If function f satisfies f
4
 x   8x 2 f 2  x   dx  16  0 , then the value of
(I) 0
5 (P) 0
f2(1) is
x
(II)
If the point of inflection for the curve y  
0
1  t 4 dt is (, ), then  +  is
(Q) 1
equal to
x
 x

Let f be continuous and function g is defined as g  x     t 2   f  u  du  dt
0 1 
(III) f  1 (R) 2
also f(1) = 3, and g(1) + g(1) is equal to n1  (where n1, n2  N),
n2
then n1 – n2 is
1 1
ex x2 I1
(IV) Let I1  0 1  x dx and I2  0 e x3  2  x3  dx , then eI2 is (S) 3
(T) 4
The correct option is:
(A) (I)  (T); (II)  (P); (III)  (R); (IV)  (S)
(B) (I)  (T); (II)  (P); (III)  (Q); (IV)  (R)
(C) (I)  (P); (II)  (Q); (III)  (R); (IV)  (S)
(D) (I)  (T); (II)  (P); (III)  (T); (IV)  (S)
Ans. D
1 1
  f  x   8x  f  x   16x  dx    f  x   4x 
2
Sol. (I) 4 2 2 4 2 2
 0  f2(x) = 4x2
0 0
4x 3
(II) f   x     f(x) = 0 at x = 0 and f(x) changes sign around it
2 1  x4
x  x  f  1
(III) g  x   x 2   f u  du   f  x     t 2 dt  and g(1) = 1  g 1  6 
1  0  3
1 0 t 1
1 dt 1 e 1
(IV) I2     t   dt  I1 (Let –x3 = t)
3 0 e 2t  3 1 1 t 3e

List-I List-II
 2x 
Number of points of discontinuity of f  x      sin x in x  [0, ] is/are
(I)  (P) 0
(where [.] and {.} represents greatest integer function and fractional part
function)
If the area included between the curve y2 = x3, tangent to it at point (1, 1)
(II) (Q) 1
and x-axis is A, then [A + 1] (where [.] represents greatest integer function)
If the area bounded by f : [1, )  [1, ) given by f(x) = x2 – 2x + 2 and its
(III) (R) 2
inverse is A, then 3A is equal to
1
In
(IV) Let In   xn 1  x 2 dx , then lim is equal to (S) 3
0
n  In  2
(T) 4
(A) (I)  (R); (II)  (Q); (III)  (S); (IV)  (T)
(B) (I)  (T); (II)  (P); (III)  (Q); (IV)  (R)
(C) (I)  (R); (II)  (Q); (III)  (Q); (IV)  (Q)
(D) (I)  (T); (II)  (P); (III)  (S); (IV)  (R)
Ans. C

Sol. (I) f(x) is discontinuous at x  ,
2
1
  3x  1   3
(II) A    x 3/2    dx 
0
 2  20
2 2
1
(III) Required area = 2  xdx    x 2  2x  2  dx 
1 1 3
1 1 1
n  1 n 2 
In   xn 1  x 2 dx =  x  x 1  x dx = 0  1  x 2  1  x 2 dx
3 0
n 1 2
(IV) x
0 0
n 1 n 1 I n 1
= In 2  In  n 
3 3 In 2 n  2

List-I List-II
3/ 4
3 1
(I) Let f  x   x 3  x 2  x  , then the value of
2 4  f  f  x   dx
1/ 4
is (P) 5
Let f : R  R, f(x) = 2x – x2 and g : R  R, g(x) = xn, n  N. If area

11
(II) 1 (Q)
between f(x) and g(x) in first quadrant is , then n is 2
2
1
If f  x   and S = f(5) + f(4) + f(3) + ..... + f(–3) + f(–4) + f(–5), 13
(III) 1  ex (R)
2
then the value of S is
1
 1 7 1
(IV) If f  x    4cos 4 x  2cos 2x  cos 4x  x 7  , then f(f(4)) (S)
 2  4
(T) 4
(A) (I)  (T); (II)  (P); (III)  (R); (IV)  (S)
(B) (I)  (S); (II)  (P); (III)  (Q); (IV)  (T)
(C) (I)  (S); (II)  (P); (III)  (T); (IV)  (Q)
(D) (I)  (T); (II)  (P); (III)  (S); (IV)  (S)
Ans. B
3 2 1
Sol. (I) For f  x   x 3  x  x   f(x) + f(1 – x) = 1  f(f(x)) + f(1 – f(x)) = 1
2 4
3/ 4
 I  f  f  x   dx
1/ 4
..... (1)
3/ 4
I  f  f 1  x   dx
1/ 4
..... (2)
3/ 4
1 1
Adding equation (1) and (2), we get 2I   f  f  x    f 1  f  x    2
1/ 4
 I
4
1
1
(II) Area  A     2x  x 2  xn  dx   n = 5
0
2
11
(III) f(x) + f(–x) = 1  S 
2
1/7
3 
(IV) f  x     x7  and f(f(x)) = x
2 

List-I List-II
(I) If f : R  R be differentiable function such that f(x + 2y) = f(x) + f(2y) + 4xy (P) 1
 x, y  R, then f(1) – f(0) is equal to
 3f  x   1 
If lim f  x  exist and is finite and non-zero and lim  f  x   2   3,
(II) x  x 
 f x  (Q) 2
then value of lim f  x  is
x 
Let f(x) = 1 + 2 cos x + 3 sin x. If real number a, b, c are such that

(III) bcosc (R) 3
af(x) + bf(x + c) = 1 holds for any x  R, then is
a
Define f : R  R, such that f(x + y) = 3y f(x) + 2xf(y)  x, y  R and f(1) = 1,
(IV) (S) 4
then f(2) is
(T) 5
(A) (I)  (Q); (II)  (P); (III)  (T); (IV)  (P)
(B) (I)  (T); (II)  (P); (III)  (Q); (IV)  (R)
(C) (I)  (P); (II)  (Q); (III)  (R); (IV)  (S)
(D) (I)  (Q); (II)  (P); (III)  (P); (IV)  (T)
Ans. D
Sol. (I) Put 2y = y  f(x + y) = f(x) + f(y) + 2xy partially differentiate with respect to x
f(x + y) = f(x) + 2y put x = 1, y = –1  f(1) – f(0) = 2
3  1
(II) Let lim f  x    , then   3 =1
x  2
1 1
(III) f(x) + f(x + ) = 2  f  x   f  x     1 also af(x) + bf(x + c) = 1
2 2
1
On comparing a = b = , c = 
2
(IV) f(x + y) = 3yf(x) + 2xf(y) ..... (1)
Put x = 1 in equation (1) f(1 + y) = 3yf(1) + 2f(y)
y  x  f(1 + x) = 3xf(1) + 2f(x) ..... (2)
Now, put y = 1 in equation (1)
f(1 + x) = 3f(x) + 2xf(1) ..... (3)
From equation (2) and (3), we get f(x) = 3x – 2x

x
47. Function f : R+  R is differentiable and satisfies the condition f(x) – f(y)  ln    x  y , for all x,
y
 1 
y  R+. If g denote the derivative of f, then the value of the g  
 2022 
Ans. 2023.00
Sol. f(x) – f(y)  ln x – ln y + x – y ..... (1)

x  y and y  x
f(y) – f(x)  ln y – ln x + y – x
 f(x) – f(y)  ln x – ln y + x – y ..... (2)
From equation (1) and (2), f(x) – f(y) = (ln x + x) – (ln y + y)
1  1 
 f(x) = ln x + x  g  x   1   g    2023
x  2022 
  2x  
 1  2cos  r  

48. Consider a function f  x      3   . Then two number of points where |x f(x)| + ||x – 2|
r 1  3 
– 1| is non differentiable on interval (0, 3)
Ans. 5.00
x 2x 
Sol. sin 3 = 3 sin  – 4 sin3  = sin (1 + 2 cos 2)  sin x  sin  1  2cos 
3 3 
x  x  2x 
sin  sin  2  1  2cos 2  and so on multiplying all
3  3  3 
 x   2x 
sin  n  n  1  2cos r 
 x  n  2x  sin x  3   3   f(x) = sin x
sin x  sin  n    1  2cos r    lim 
 3  r 1  3  x n   x  r 1 3 x
 n
3 
Thus |x f(x)| + ||x – 2| – 1| = |sin x| + ||x – 2| – 1| is not differentiable at 5 points in (0, 3)
2
49. If the value of definite integral I    3x 2  3x  1 cos  x 3  3x 2  4x  2  dx can be expressed in the
0
 2  2  1
form of (sin ), where ,   N, then the value of
2
Ans. 4.50
2 2
Sol. I    3x 2  6x  4  cos  x3  3x 2  4x  2  dx    3x  3  cos  x 3  3x 2  4x  2  dx
0 0
Let I = I1 + I2
2
I1    cos t  dt = 2 sin 2 (where t = x3 – 3x2 + 4x – 2)
2
1
I2  3  ucos  u3  u  du = 0 (where u = x – 1)
1
502
 305r  S
50. If S     , then 10,000 is (where [.] represents greatest integer function)
r 1  503
Ans. 7.63
Sol. If each of two positive real number x, y is not integer but x + y is an integer,
then [x] + [y] = x + y – 1
 x  y  1
305k 305  503  k 

Since,   305 for 1  k  502
503 503
 305   305  2   305  502 
 S     .....   = 304.251 = 76304
 503   503   503 
1
22022  x1010 1  x 
1010
dx
51. The value of I  1
0
is
 x 1  x 
1010 2022 1010
dx
0
Ans. 4044.00
1
I2   x1010 1  x 2022 
1010
Sol. dx let x1011  t
0
1 1 1
1  1
1  t2  1  1  t 2   dt = 1  t1010  2  t 1010 dt
1010 1010
 I2 
1011 0  dt = 
1011 0 1011 0
Put t = 2y
1/ 2 1 1/ 2
22021
    0 x 1  x  dx
1010
1011 0 0
1010 1010
I2  y 1010
1  y dy and I1  x1010
1  x dx = 2 1010
I1
 I  22022  4044
I2
x  y 1
52. Let f be a differentiable function satisfying the functional equation f(xy) = f  x   f  y  
xy
 x, y > 0 and f(1) = 2, then the value of f  e200  is equal to (where [.] represents greatest
integer function)
Ans. 199.00
1 1
Sol. f  x   ln x   f  e200   200  200
x e
53. Consider the following area:

A1 = Area of region common to y  f(x) and y  g(x)
A2 = Area of region common to y  f(x) and y  g(x)
A = Area of region bounded by y = f(x), y = g(x) and x = 
where f(x) = |cos |x||, g(x) = |sin |x|| for x  [–, ]. Then the value of  2  1  A1  A 2  A 3  is
Ans. 16.00
/ 4
A
Sol. A1  4   cos x  sin x  dx  4  2  1 also A1  A 2 
0
2
/ 2
54. If I   sin x log e
 sin x  dx and A is area of the region bounded by the set
0
  1 
 x, y  : 0  y  min 3  x, x   , then the value of A – I is
  x 
Ans. 4.75
 /2
1
I  sin x ln  sin x   dx , put cos x = t
2
Sol.
2 0
1  2  t 2    t 2 3 
1 1 2
1   1 1 1 1 
I   ln 1  t dt =  t 
2
   .....  dt =      .....
20 2 0 2 3  2  3 10 21 
1 1 1   1 1   1 1  
=     .....           ..... = loge 2  1
 6 20 42   2 3   4 5  
15
and A   ln2
4

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FIITJEE

ALL INDIA TEST SERIES

 The test consists of total 54 questions.

Section – A (Maximum Marks: 24)

1. Four dancers start their dance by forming a square with side

2. A point object of mass m = 2kg is connected to a cylinder of radius v0

Sol. Speed of the object will remain constant because tension

3. Two discs are mounted on thin, lightweight rods oriented

For the smaller disc C2r24  fdtr2  0

4. A dumbbell is formed by connecting two identical particles A J A

5. Three particles A, B and C are simultaneously thrown from a

(A) uBy  uCy  uyA (B) uBy  uyA  uCy

6. A thin rod has an unknown non-uniform density. It is mounted CM

Sol. For COM position, m1x1 = m2x2

Section – A (Maximum Marks: 12)

10 m/s w.r.t 5 m/s w.r.t

(III) A particle of mass 1 kg is projected from an unstable (R) +150J

Sol. (I) 0 = 100v + 50(v + 3) (COLM) 3 m/s

8. A disc placed on a frictionless horizontal plank is rotating with a y

List –I List -II

9. Figure shows a system of multiple blocks  = 0.1 D

List –I List –II

mR2  mR2 mR2 mR2 

Section – B (Maximum Marks: 24)

11. Two massless rods are attached to F 0.5m 2m

Ans. 4.50 (range 4.40 to 4.60)

Sol. (F) (2) = (N) (1)  N = 2F (N is normal between rods)

12. A small sphere slides with a speed v = 60 m/s on

Ans. 60.60 (range 60.00 to 61.00)

13. Figure shows a laptop made of two identical uniform plates,

Ans. 2.50 (range 2.40 to 2.60)

Sol. from torque equilibrium about O F

Ans. 1.41 (range 1.35 to 1.45)

Sol.  Ndt  mv cos  (v  2gh )

mv sin   mv cos  3 1 4 50

15. One end of the non stretchable rope is uA

Ans. 7.46 (range 7.40 to 7.50)

Ans. 2.43 (range 2.35 to 2.55)

17. A right triangular wooden block of mass M = 4 kg is at rest on a m m

Ans. 58.80 (range 57.00 to 59.00)

18. The ‘wall of death’ ride consists of a drum with d

Ans. 2.00 (range 1.95 to 2.05)

Sol. mg cos 53 = 0.5 N

Section – A (Maximum Marks: 24)

19. Which of the following species are polar as well as non-planar?

Sol. XeF4  sp3 d2  Square planar and nonplanar

20. All bonds are equivalent in

All Xe - O bonds are equivalent due to resonance sp3d2 hybridisation

Sol. r = 0, R(r) = 0 so its true for p-orbital, Azimuthal quantum number is 1.

23. Find the incorrect statement

Sol. In CrO38  Cr has +5 oxidation state.

Section – A (Maximum Marks: 12)

Sol. For reaction A  Product

26. List – I contains properties and List – II contains moles or ions

Sol. Correct answer is I→P, R, S; II→P, S, T; III→P, R, S; IV→P, Q,R, S

Sol. Correct order is I→R,S; II→R; III→Q, S; IV→P

Sol. Correct answer is I→Q; II→P; III→S; IV→R

Section – B (Maximum Marks: 24)

29. Fauzosite, a zeolite has formula