Scribd Logo
Upload

Welcome to Scribd!

  • 104 views

    GR 12.volumetry, Practicals.

    Uploaded by

    jeevan
    This document describes two volumetric experiments to determine the concentration of a potassium manganate (VII) solution (KMnO4). In the first experiment, KMnO4 is titrated against a standard solution of ferrous ammonium sulfate. In the second experiment, KMnO4 is titrated against a standard solution of oxalic acid. Both experiments involve recording burette readings and using mole ratios from balanced chemical equations to calculate the molarity and strength of the KMnO4 solution. The results are reported as the determined molarity and calculated strength in grams per liter.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd

    GR 12.volumetry, Practicals.

    Uploaded by

    jeevan
    104 views4 pages
    This document describes two volumetric experiments to determine the concentration of a potassium manganate (VII) solution (KMnO4). In the first experiment, KMnO4 is titrated against a standard solution of ferrous ammonium sulfate. In the second experiment, KMnO4 is titrated against a standard solution of oxalic acid. Both experiments involve recording burette readings and using mole ratios from balanced chemical equations to calculate the molarity and strength of the KMnO4 solution. The results are reported as the determined molarity and calculated strength in grams per liter.

    Original Title

    Gr 12.Volumetry,Practicals.

    Copyright

    © © All Rights Reserved

    Available Formats

    PDF, TXT or read online from Scribd

    Did you find this document useful?

    Is this content inappropriate?

    This document describes two volumetric experiments to determine the concentration of a potassium manganate (VII) solution (KMnO4). In the first experiment, KMnO4 is titrated against a standard solution of ferrous ammonium sulfate. In the second experiment, KMnO4 is titrated against a standard solution of oxalic acid. Both experiments involve recording burette readings and using mole ratios from balanced chemical equations to calculate the molarity and strength of the KMnO4 solution. The results are reported as the determined molarity and calculated strength in grams per liter.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    104 views4 pages

    GR 12.volumetry, Practicals.

    Uploaded by

    jeevan
    This document describes two volumetric experiments to determine the concentration of a potassium manganate (VII) solution (KMnO4). In the first experiment, KMnO4 is titrated against a standard solution of ferrous ammonium sulfate. In the second experiment, KMnO4 is titrated against a standard solution of oxalic acid. Both experiments involve recording burette readings and using mole ratios from balanced chemical equations to calculate the molarity and strength of the KMnO4 solution. The results are reported as the determined molarity and calculated strength in grams per liter.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 4

    1

    JAI GURU DEV.

    MVM. Senior Secondary School. Class: XI. Chemistry .

    Volumetric Practicals. WS-1 By : Sunny. M.G

    Experiment No:1.

    Aim:-Determination of concentration/molarity of KMnO4 solution by titrating it against a standard


    solution of ferrous ammonium sulphate(0.05m)

    Molecular Equations:-

    2KMnO4+3H2SO4 K2SO4+2MnSO4+3H2O+5(O)

    (2FeSO4(NH4)2SO4 .6H2O +H2SO4+(O) Fe2(SO4)3 +2(NH4)2SO4 +13H2O)X5

    2KMnO4+8H2SO4 +10FeSO4(NH4)2SO4.6H2O
    K2SO4+2MnSO4+5Fe2(SO4)3+10(NH4)2SO4 +68H2O

    Ionic Equations:-

    MnO4- +8H+ + 5e- Mn+2+4H2O

    ( Fe+2 Fe+3+e-)x5

    MnO4-+8H+ + 5Fe+2 5Fe+3+Mn+2+4H2O

    Indicator:-KMnO4 is a self indicator.

    End Point:-Colourless to pale permanent pink colour.

    Procedure:-

    Weigh 4.9g of Mohr’s salt ,transfer it in to 250ml standard flask, add water and make up to 250 level.

    Rinse this solution with pipette and take 20ml of this solution in to a titration flask ,add 20ml of
    dilute H2SO4 .Rinse the burette with the given KMnO4 solution and fill it in the burette. Noted the
    initial reading on the burette. Transfer the burette solution in to the Mohr’s salt slowly with constant
    stirring ,until a pale permanent pink colour appears. Repeat the expt to get concordant values.

    Results:-

     Molarity of the given KMnO4 solution= ………….M


     Strength of the given KMnO4 solution= molarity x molar mass
     = …………x 158= ……..g/l.
    2

    Calculations:-

    Weight of mohrs salt taken=4.9g

    Volume of Mohrs salt solution prepared=250ml

    Molarity of mohrs salt solution =0.05M Mohrs salt X KMnO4

    S.No Vol.Of Volume Of KMnO4


    Mohrs salt used.
    Burette Readings
    taken.
    Initial Reading Final Reading.

    1. ………..ml

    2. ………….ml

    3. ………..ml

    End point : Pale permanent Pink colour.

    From the overall balanced equations, it is clear that 2moles of KMnO4 reacts with 10moles of Mohrs
    salt.( 2:10 ratio)

    ( MKMnO4 X V KMnO4) / ( M Mohrs salt X V Mohrs salt)=2/10

    By substituting the values ,we get molarity of KMnO4 = ……………M

    Strength of KMnO4 = Molarity x Molar mass = …………. X 158= ……..g/L.


    3

    Experiment No;2.

    Aim:-Determine the molarity and strength of the given KMnO4 solution using a standard solution of
    Oxalic acid (M/40Oxalic acid)

    Molecular Equations:-

    2KMnO4 + 3H2SO4 K2SO4+2MnSO4+ 3H2O+5(O)

    (H2C2O4+ 2H2SO4+ (O) ( 60-70) 2CO2+3H2O)X 5

    2KMnO4+ 2H2SO4+5 C2H2O4.2H2O K2SO4+2MnSO4 +18H2O+10CO2

    Ionic Equations:-

    ( MnO4- +8H+ +5e- Mn+2+4H2O )x 2

    (C2O4-2 2CO2 + 2e-)X5

    2MnO4- + 16H++ 5C2O4-2 2Mn+2+8H2O + 10CO2

    Indicator:-KMnO4 is a self indicator.

    End point:-Colourless to pale permanent pink colour.

    Procedure:-

    Weigh about one gram of oxalic acid and dissolve in 250ml of standard flask and make up to 250ml.

    Pipetted out 20 ml of oxalic acid in to a titration flask ,add20ml of dilute H2SO4 and heated to 60-70
    degree . Fill the burette with the given KMnO4 solution ,after rinsing it .Add KMnO4 solution from
    the burette until the solution in the flask get a pale permanent pink colour. Repeat the expt to get
    concordant values.

    Results:-

    Molarity of the given KMnO4 solution= …….M

    Strength of the given KMnO4 solution= molarity X molar mass

    ; ……………x 158= ………..g/L


    4

    Calculations:-

    Mass of oxalic acid taken=1g

    Volume of oxalic acid prepared =250ml

    So the molarity of oxalic acid =M/40. Oxalic Acid X KMnO4

    S.No Vol.Of Volume Of KMnO4


    Oxalic acid used.
    Burette Readings
    taken.
    Initial Reading Final Reading.

    1. ………..ml

    2. ………….ml

    3. ………..ml

    End point : Pale permanent Pink colour.

    From the balanced chemical equation ,it is clear that 2moles of KMnO4 reacts with 5 moles of Oxalic
    acid.( 2;5 ratio)

    ( M KMnO4 X VKMnO4) /(MOxalic Acid X V Oxalic Acid)=2/5

    By substitution we get molarity of KMnO4 =………………M

    Strength of KMnO4 = molarity X molar mass

    ……………..x 158= …………………g/L

    You might also like