12th Chemistry - 1st Revision Test 2022 - English Medium PDF Download

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EDUCATION DEPARTMENT- CHENGELPATTU

SECOND ASSESSMENT TEST - JANUARY - 2022

DURATION: 2.30 HRS STD XII MAX MARKS: 70

CHEMISTRY

PART A

CHOOSE THE BEST ANSWER. 15 X 1=15

1. The gas evolved during the formation of blister copper is


a) CO2 b) SO2 c) SnO2 d) NH3

2. Which one of the following is used as an anode during the electrolytic refining of silver

a) Impure silver b) Pure silver c) Acidified silver nitrate solution d) silver chloride

3. Assertion : Zone refining process is carried out in an inter gas atmosphere

Reason: In order to prevent the oxidation of metal

A) Both Assertion and Reason are true

B) Both Assertion and Reason are false


C) Assertion is true and Reason is false
D)

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Assertion is false and Reason is true

4. The14th group element silicon shown diagonal relationship with one of the following element

a) Boron b) Silicon

5. Boric acid is an acid because its molecule


c) Germanium d) Lead

a) contains replaceable H+ ion b) gives up a proton

c) combine with proton to form water molecule d) accepts OH- from water, releasing proton.

6. The stability of Thalium (I) Chloride is best explained by a

a) Oxidation state b) inert pair effect c) Ionisation energy d) Small size.

7. Which one of the following polar molecular crystal has dipole-dipole interaction

a) solid CO2 b) H2O ( ice) c) Glucose d) urea

8. Co-ordination number of Simple cubic crystal lattice is

a) 6 b) 8 c) 1 d) 2

9. Number of Bravis lattice is a) 7 b) 14 c) 3 d) 2

10. Molecularity of the following reaction is 2H2O2(aq) ------ 2 H2O (l) + O2(g)

a) 1 b) 2 c)0 d)3

11. An example of Zero order reaction is

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a) Dissociation of nitrogen pentoxide b) Dissociation of H2O2

c) Dissociation of N2O on surface of platinum d) Dissociation of sulphuryl chloride

12. The rate constant value of a reaction is 5.8 X10-2 S-1 . The order of the reaction is

a) First order b) Zero order c) Second order d) Third order

13. Which one the following is an example for simple ether

a) 4-Chloro -1-methoxy benzene b) 3-methyl -1- ethoxy benzene

c) phenymethoxy benzene d) Ethooxy butane

14. Which one of the following alcohol produce blue coloration in victor mayor’s test

a) Ehanol b) propane-2-ol c) 2- methyl propane-2-ol d) propanol

15. The relativereactivities of alcohols in the dehydration reaction is

a) Primary <Secondary < Tertiary b) Primary > Secondary < Tertiary

c) Primary <Secondary > Tertiary d) Primary > Secondary>Tertiary

PART B

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II. ANSWER THE FOLLWING ( ANY SIX)

16. What is inert pair effect?

17. What is the action of heat on Borax?


6 X 2= 12

18. Define half life period of a reaction

19. What are covalent crystal? Give example

20.What is an elementary reaction?

21. What is meant by point defects?

22. What is anode mud?

23. CH3-CH2-CH2-OH − − − −→ ?

24. What is TNG? How is it prepared

PART C

III. ANSWER THE FOLLWING ( ANY SIX) 6 X 3 = 18

25. Mention the uses Boron

26. Write note on Cyanide leaching process

-3
27. The rate of the reaction x+2y -- product is4 X 10 mol L-1S-1 if [x]=[y]= 0.2 M,

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and the rate constant at 400 K is 2 x 10-2 S-1

28.Differentiate order and molecularity

29.Write note on Coupling reaction

30. How will you calculate packing efficiency for simple cubic crystal?

31. Identify the major product formed when 1- methoxy propane is heated with excessHI.

32. Explain Pseudo first order reaction with an example

33. Define a) Point defects b) F- center

PART- D

IV . ANSWER THE FOLLOWING 5 X 5 =25

34 a) Explain with an example the principle involved in Electrolytic refining process?

OR

b) Draw the structure of Boric acid and mention its uses

35 a) Differentiate crystalline solids from amorphous solid

OR

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b) Derive integrated rate law for zero order reaction?

36 a) Draw the structures of Simple cubic crystal lattice also calculate the number of atoms in it.

OR

b) A--- product . Derive integrated rate law for first order reaction

37 a) Write note on Schotky defect and Frenkel defect

OR

b) How would you prepare the following from etheleneglycol

a) 1,2- Epoxy ethane b) 1,4 di oxan c) Formaldehyde

38. a) Explain Lucas test to distinguish primary, secondary and tertiary alcohol

OR

b) Write note on a) Williomson ether synthesis b) Kolbesreaction

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