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    Lab Report Upsi SKT1013 Diploma Science Experiment 3

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    Nur Wanyz Syazwanie
    This laboratory report summarizes an experiment on the oxidation states of manganese. Different oxidation states of manganese complexes result in different colors - purple for +7, green for +6, dark red for +4, and light red for +2. The experiment involved mixing potassium permanganate (KMnO4) with other compounds and observing the color changes, which indicated reductions in the manganese oxidation state. For example, adding sodium bisulfide reduced KMnO4 from +7 to either +6 or +4 depending on other reactants. Sodium bisulfate did not cause any color change. The conclusions relate the oxidation states and observed colors of the manganese complexes.

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    Lab Report Upsi SKT1013 Diploma Science Experiment 3

    Uploaded by

    Nur Wanyz Syazwanie
    299 views5 pages
    This laboratory report summarizes an experiment on the oxidation states of manganese. Different oxidation states of manganese complexes result in different colors - purple for +7, green for +6, dark red for +4, and light red for +2. The experiment involved mixing potassium permanganate (KMnO4) with other compounds and observing the color changes, which indicated reductions in the manganese oxidation state. For example, adding sodium bisulfide reduced KMnO4 from +7 to either +6 or +4 depending on other reactants. Sodium bisulfate did not cause any color change. The conclusions relate the oxidation states and observed colors of the manganese complexes.

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    LAB REPORT UPSI SKT1013 DIPLOMA SCIENCE EXPERIMENT 3

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    This laboratory report summarizes an experiment on the oxidation states of manganese. Different oxidation states of manganese complexes result in different colors - purple for +7, green for +6, dark red for +4, and light red for +2. The experiment involved mixing potassium permanganate (KMnO4) with other compounds and observing the color changes, which indicated reductions in the manganese oxidation state. For example, adding sodium bisulfide reduced KMnO4 from +7 to either +6 or +4 depending on other reactants. Sodium bisulfate did not cause any color change. The conclusions relate the oxidation states and observed colors of the manganese complexes.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    299 views5 pages

    Lab Report Upsi SKT1013 Diploma Science Experiment 3

    Uploaded by

    Nur Wanyz Syazwanie
    This laboratory report summarizes an experiment on the oxidation states of manganese. Different oxidation states of manganese complexes result in different colors - purple for +7, green for +6, dark red for +4, and light red for +2. The experiment involved mixing potassium permanganate (KMnO4) with other compounds and observing the color changes, which indicated reductions in the manganese oxidation state. For example, adding sodium bisulfide reduced KMnO4 from +7 to either +6 or +4 depending on other reactants. Sodium bisulfate did not cause any color change. The conclusions relate the oxidation states and observed colors of the manganese complexes.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    of 5

    DEPARTMENT OF CHEMISTRY

    FACULTY OF SCIENCE AND MATHEMATICS


    UNIVERSITI PENDIDIKAN SULTAN IDRIS

    LABORATORY REPORT

    SKT 1013 INTRODUCTION TO INORGANIC CHEMISTRY


    SEMESTER 02 SESSION 2019/2020

    ID NUMBER 1. E20181019624
    2. E20181019660
    NAME 1. NUR AIMAN SYAZWANI BINTI ZULKEFLE
    2. NUR AYUNI ADIBAH BINTI MOHD ASRI
    GROUP I
    LECTURER DR. NOORSHIDA BINTI MOHD ALI
    EXPERIMENT NO. 3
    TITLE OXIDATION STATES OF MANGANESE
    DATE 19TH NOVEMBER 2019

    CHECK LIST (Please tick) Marks


    Spelling, punctuation and grammar 10
    Format and style 10
    Introduction 10
    Materials 10
    Methodology and jotter 10
    Results 10
    Discussions 10
    Conclusions 10
    References (minimum 2) 10
    Conceptual understanding 10
    TOTAL MARKS 100
    EXPERIMENT 3: OXIDATION STATES OF MANGANESE

    OBJECTIVES

    Upon completion of this experiment, we are able to observe the colour of manganese complexes
    with different oxidation state

    INTRODUCTION

    Manganese element is one of transition metal that shows different colour depending on oxidation
    state from +2 to +7. This is because the variable oxidation states give different partially filled d
    sublevel electrons for its central metal ion. For manganese element, different oxidation states has
    different colour. At the end, in this experiment, we aim to identify and predict the number of
    oxidation states by observing the colour of manganese compound after mixing the potassium
    permanganate (KMnO4) with several other compounds.

    MATERIALS

    Chemicals : Sulphuric acid, H2SO4 (3.0M), sodium hydroxide, NaOH (2.0M), potassium
    permanganate, (KMnO4) (0.01M), sodium bisulphide, NaHSO3 (0.02M) and
    sodium bisulphate, NaHSO4 (0.02M).
    Apparatus : Test tube, graduated cylinder and test tube rack

    METHODOLOGY (refer to jotter)

    RESULTS (refer to 1.5 worksheet)

    Test Tube Observations


    1. KMnO4
    2. KMnO4 + NaOH + NaHSO3

    3. KMnO4 + H2SO4 + NaHSO3

    4. KMnO4 + NaHSO3

    5. KMnO4 + NaOH + NaHSO4

    6. KMnO4 + H2SO4 + NaHSO4

    7. KMnO4 + NaHSO4
    DISCUSSION

    Potassium permanganate, KMnO4


    Permanganate (+7 oxidation state) compounds are purple and can give glass a violet color
    Permanganate (+7 oxidation state) compounds are purple and can give glass a violet color Mn in
    MnO4- is in +7 state with d0configuration. The deep purple colour of KMnO 4 is not due to d-d
    transition but due to charge transfer from (O to Mn) reducing the oxidation state of Mn from +7
    to +6 momentarily.

    Reaction of KMnO4 + NaOH + NaHSO3

    This reaction between potassium permanganate with sodium hydroxide and sodium bisulphide
    has reduced the +7 oxidation number of manganese to +6 oxidation number. As the result of this
    redox reaction,the initial purple solution turned to green solution showing that the manganate
    (VII) ion reduced to manganate (VI) ion, MnO42-
    Below is the equations that described the redox chemistry observed.
    2 MnO4- + 3 OH- + HSO3- → 2 MnO42- + SO42- + 2 H2O

    Reaction of KMnO4 + H2SO4 + NaHSO3


    The reaction of potassium permanganate with sulphuric acid and sodium bisulphide has reduced
    from +7 oxidation number to +2 oxidation number of manganese. As the result from this
    reaction, the purple solution has changed to light red solution that merely colourless.

    Below is the equation that described the redox chemistry observed.


    2 MnO4- + H+ + 5 HSO3- → 2 Mn2+ + 5 SO42- + 3 H2O

    Reaction of KMnO4 + NaHSO3


    The reaction between potassium permanganate with sodium bisulphide has reduced the +7
    oxidation number of manganate to +4 oxidation number as the initial purple coloured solution
    had changed to dark red coloured solution after mixing the two solutions together.

    Below is the equation that described the redox chemistry observed.


    2 MnO4- + 3 HSO3- → 2 MnO2 + 3 SO42- + 3 H2O

    Reaction of KMnO4 + NaOH + NaHSO4 , KMnO4 + H2SO4 + NaHSO4 & KMnO4 + NaHSO4
    For all these, there is no reaction occur between the reagent as the colour of potassium
    permanganate remains purple till end of experiment indicating that the oxidation number of
    KMnO4 has not been reduced or oxidized. Therefore, the solution remain the same as the initial
    solution colour which purple because of potassium permanganate(VII) has +7 oxidation number.
    CONCLUSIONS

    Different manganese complexes oxidation number shows different coloured solution such as +7
    oxidation number shows purple solution, +6 oxidation number shows turquoise solution, +4
    oxidation number shows dark red solution and +2 oxidation number of manganese complex
    appeared in light red solution.

    REFERENCES

    1. Weller, M. T., Overton, T., Rourke, J., & Armstrong, F. (2018). Inorganic chemistry.
    Oxford: Oxford University Press.
    2. U.S. National Library Of Medicine. (T.T). Compound Summary Ethylenediamine, Retrieved
    from https://pubchem.ncbi.nlm.nih.gov/compound/Ethylenediamine
    3. U.S. National Library Of Medicine. (T.T). Compound Summary EDTA, Retrieved from
    https://pubchem.ncbi.nlm.nih.gov/compound/EDTA

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