24-07-2021 SR - Super60 (In Coming) Jee-Main WTM-37 Question Paper

Sri Chaitanya IIT Academy., India.
A.P, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI
A right Choice for the Real Aspirant

ICON Central Office – Madhapur – Hyderabad
Sec: Sr.Super-60(In Coming) Jee-Main Date: 24-07-2021
Time: 09.00Am to 12.00 WTM-37 Max.Marks:300
Sri Chaitanya IIT Academy 24-07-2021_Sr.Super60(In Coming)_Jee-Main_WTM-37_Q.P
24-07-2021_Sr.Super60(In Coming)_Jee-Main_WTM-37_Test Syllabus
PHYSICS : Particle nature of light : the photon, Wave nature of matter, Photo electric
effect, Radiation pressure, Matter waves, Davisson - Germer experiment, Heisenberg's
uncertainity principle (From NCERT Textbook)
CHEMISTRY : Aldehydehydes and Ketones, Carboxylic acids and its derivatives
MATHEMATICS : Conditional probability, Independent events, Multiplication theorem
Sec: Sr.Super60(In Coming) Space for Rough Work Page 2

PHYSICS Max Marks: 100
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. When green light is incident on the surface of metal, it emits photo-electrons but
there is no such emission with yellow colour light. Which one of the colours can
cause emission of photo-electrons?
1) Orange 2) Red 3) Indigo 4) None of the above
2. An electron is projected through a field. It is moving (i) opposite an electric field (ii)
perpendicular to a magnetic field as shown. For each situation the de-Broglie wave
length of electron
1) Increasing, increasing 2) Increasing, decreasing

3) Decreasing, same 4) Same, same
3. A beam of light of wavelength  is totally reflected at normal incidence by a plane
mirror. The intensity of the light is such that photons hit the mirror at a rate ‘n’.
Given that the Planck constant is h, the force exerted on the mirror by this beam is
1) nh 2) nh /  3) 2nh /  4) 2n / h
4. According to Einstein’s photoelectric equation, the plot of the kinetic energy of the
emitted photoelectron from a metal versus the frequency, of the incident radiation
give a straight line whose slope
1) Is the same for all metals and independent of the intensity of the radiation
2) Depends on the intensity of the radiation
3) Depends both on the intensity of the radiation and the metal used
4) Depends on the nature of the metals used
5. Two particles move at right angle to each other. Their de Broglie wavelengths are
1 and  2 respectively. The particles suffer perfectly inelastic collision. The de
Broglie wavelength  of the final particle is given by
1 1 1   2 2 1 1
1) 2  2  2 2)   1  2 3)   1 4)  
 1  2 2  1  2
6. If the momentum of an electron is changed by p , then the de-Broglie wavelength
associated with it changes by 0.50%. The initial momentum of the electron will be
p p
1) 2) 3) 199 p 4) 400 p
200 199
7. The correct graph between the maximum energy of a photoelectron emitted from a
metal surface and the inverse of wavelength of the incident radiation on the surface is
given by the curve
1) A 2) B 3) C 4) None of the above

8. 48W / m 2 energy density of sun light is normally incident on the surface of a solar
panel. Some part of incident energy (25%) is reflected from the surface and the rest is
absorbed by the surface. The force excerted on 1m 2 surface area will be close to
1) 20 108 N 2) 15108 N 3) 10 108 N 4) 35108 N
9. Ultraviolet light of wavelength 300 nm and intensity 1.0 watt/m2 falls normally on the
surface of a photosensitive material. If 1% of the incident photons produce
photoelectrons, then the number of photoelectrons emitted from an area of 1.0 cm2 of
the surface is nearly
1) 9.6 1014 per sec 2) 4.12 1013 per sec
3) 1.511012 per sec 4) 2.131011 per sec

10. The potential energy U of a moving particle of mass ‘m’ varies with ‘x’ as shown in
the figure. The de-Broglie wavelengths of the particle in the regions
0  x  1 and x  1 are 1 and  2 respectively. If the total energy of the particle is nE,
the ratio 1 /  2 is
n n n2 n2
1) 2) 3) 4)
n 1 n 1 n 2 1 n 2 1
11. An electron (mass m) and charge e with an initial velocity    0 î is projected in an
h
electric field E  E 0ˆj. If  0  , its de Broglie wavelength at time ‘t’ is given by:
mv0
e2 E 20 t 2
1)  0 2)  0 1 
m 2 v20
0 0
3) 4)
e2 E 20 t 2  e2 E 2 t 2 
1 1  0

2 2 
m 2 v 02  m v0 
12. In an experiment on photoelectric effect, the emitter and the collector plates are
placed at a separation of 10 cm and are connected through an ideal ammeter without
any cell
A magnetic field B exists parallel to the plates. The work function of the emitter is
2.39 eV and the light incident on it has wavelengths between 400 nm to 600 nm. Find
the minimum value of B for which the current registered by the ammeter is zero.
Neglect any effect of space charge.
1) 1.58105 T 2) 3.85105 T
3) 4.58105 T 4) 2.85105 T

13. Davison and Germer’s experiment gives
1) Evidence of de Broglie’s waves associated with electrons
2) Evidence of particle nature of electrons
3) Evidence of –ve charge on electrons
4) Evidence of specific charge of electrons
14. A stationary shell of mass ‘5m’ explodes in to two parts and their masses are in the
ratio 2 : 3, then the ratio of their de-Broglie wavelengths associated with the above
two parts respectively is
1) 2 : 3 2) 3 : 2 3) 9 : 4 4) 1 : 1
15. The ratio of the de Broglie wavelength of proton, deuteron and alpha particle when
accelerated through the same potential difference 100V is
1) 2 : 2 : 1 2) 1 : 2 : 2 2 3) 2 : 1 : 2 4) 2 2 : 2 :1
16. A particle is projected horizontally with a velocity f 10 m/s. What will be the ratio of
de Broglie wavelength of particle when velocity vector makes an angle 450 and 600
with horizontal is
1) 1 : 1 2) 3 :1 3) 2 : 3 4) 2 :1
17. In a photo emissive cell the exciting wavelength  , the fastest electron has speed v. If
the exciting wavelength is changed to 3  / 4 , the speed of the fastest emitted electron
will be
1 1
 3 2  4 2
1) v   2) v  
 4   3 
1 1
 4 2  4 2
3) less than v   4) greater than v  
 3   3 
18. Which of the following graphs represents the variation of particle momentum and the
associated de-Broglie wavelength?
P P
1)  2) 

P P
3)  4) 
19. The radiation force experienced by a body exposed to radiation of intensity ‘I’
assuming surface of body to be perfectly absorbing is
R 2 I 2R 2I 4R 2 I
1) 2) 3) 4) None of these
c c c
20. Photoelectric effect is the phenomenon in which
1) Photons come out of a metal when it is hit by a beam of electrons
2) Photons come out of the nucleus of an atom under the action of an electric field
3) Electrons come out of a metal with a constant velocity which depends on the
frequency and intensity of incident radiation.
4) Electrons come out of a metal with different velocities not greater than a certain
value which depends only on the frequency of the incident light and not on its
intensity.
(NUMERICAL VALUE TYPE)

This section contains 10 questions. Each question is numerical value type. For each question, enter the correct numerical
value (in decimal notation, truncated/rounded-off to second decimal place. (e.g. 6.25, 7.00, 0.33, 30, 30.27, 127.30).
Attempt any five questions out of 10.
Marking scheme: +4 for correct answer, 0 if not attempted and 0 in all other cases.
21. The maximum value of stopping potential (in volts) in the following diagram is

22. The electric field associated with a light wave is given by
E  E 0 sin 1.57 107 m 1  x  ct  . Find the stopping potential (in volts) when this
 
light is used in an experiment on photoelectric effect with the emitter having work
function 1.9 eV.
23. The de –Broglie wavelength of a particle moving with a velocity 2.25108 m / s is
equal to the wavelength of photon. The ratio of energy of the photon to the kinetic
energy of the particle is (velocity of light is 3108 m / s )
24. A 100 W light bulb is placed at the centre of a spherical chamber of radius 20 cm.
Assume that 60% of the energy supplied to the bulb is converted into light and that
the surface of the chamber is perfectly absorbing. The pressure exerted by the light on
the surface of the chamber is …..107 Pa
25. Surface of certain metal is first illuminated with light of wavelength 350 nm and then,
by light of wavelength 540 nm. It is found that the maximum speed of photo electrons
in the two cases differ by factor of 2. The work function of the metal (in eV) is
26. Photons of energy 5 eV are incident on cathode as shown in the figure. Electrons
reaching the anode have kinetic energies varying from 5eV to 8eV. Find the work
function of the metal in eV.
27. When a metallic surface is illuminated with monochromatic light of wavelength  ,

the stopping potential is 5V0 . When the same surface is illuminated with light of
wavelength 3 , the stopping potential is V0 . If the work function of the metallic
hc
surface is find n :
n
28. A graph is drawn between stopping potential (along y-axis) and incident frequency
(along x-axis). The intercept OA on x-axis gives 0.51015 Hz . The K.E. (in eV) of
photo electron emitted from the metal when the energy of incident photon is 5eV is
29. If the velocity of the particle reduced to one third, then the percentage increase in its
de -Broglie wavelength is
30. If photons of ultraviolet light of energy 12 eV are incident on a metal surface of work
function of 4eV, then find the stopping potential (in eV)

CHEMISTRY Max Marks: 100
This section contains 20 multiple (1), (2), (3) and (4) for its
31. The correct sequence of reagents for the following conversion is
SOCl 2 Ag CH 2 N 2
1)        
H 2O
SOCl CH 2 N 2 Ag 2O
2) 2      
H 2O
CH 2 N 2 SOCl Ag 2O
3)   2    
H 2O
Ag 2O SOCl CH 2 N 2
4)   2    
H 2O
32.
RedP/ Br2
3 H2CH2COOH 
CHC  CHC
3 H2CH COOH
Br
This reaction is called the
1) Cannizaro reaction
2) Schrodinger reaction
3) Hell – Volhard – Zelinsky reaction
4) Reimer – Tiemann reaction

33.
Final product is
1) 2)
3) 4)
34. Which of the following observation does not establish the existence of keto-enol
tautomerism in acetone?
1) When treated with DCl in D 2O hexadeutertrated acetone is recovered.
2) When treated with dil. H 2SO 4 in H 2O18 CH3 2 C  O18 is obtained.
3) When treated with D 2O / NaOD , hexadeuterated acetone is recovered.
4) all of the above establishes keto enol tautomerism

35. An ester (1) with molecular formula C9 H10O 2 was treated with excess of CH3MgBr
and the complex so formed was treated with H 2SO 4 to give an olefin(II).Ozonolysis
of (II) gave a ketone with molecular formula C8H 8O which show positive iodoform
test. The structure of (I) is
1) C 6H 5COOC 2 H 5 2) C 6H 5COOC 6H 5
3) H 3COCH 2COC 6 H 5 4) p  CH 3O  C6 H 4  COCH 3
36. Carboxylic acids, RCOOH, furnish H  ions to water forming H 3O and
carboxyliate ions RCOO  . The major reason for this acidic behavior is that
1) The carboxylate ion is stabilised by salvation with H 2O
2) The carboxylic acid is stabilised by resonance
3) The carboxylate ion is stabilised by resonance
4) The carboxylate ion is more resonance stabilized than the unionized carboxylic
acid
37.
alc.KOH iO
  mixtureof alkenes 3 
HBr ii Zn/ H2O
(mixture of carbonyl compounds)

The incorrect statement is
1) Total five alkenes are obtained
2) Total six different carbonyl compounds are obtained on ozonolysis.
3) Only two carbonyl compound give positive iodoform test.
4) All carbonyl compounds can give aldol reaction when treated with dil.KOH

38.
The major product (y) in the above reaction:
1) 2)
3) 4)
39. Which of the following gives a cyclic anhydride on heating?
1) HOOC  CH 2  COOH 2)
3) 4)

40.
Product ( P ) of the reaction is :
1) 2)
3) 4)
18
41. Saponification ( basic hydrolysis ) of C6 H5 C OCH 3 will yield
||
O
O O
|| 18 18 || 18

1) C6 H5  C O  H OCH 3 2) C6H 5  C O  HOCH3
18
3) C6 H5 CO  HOCH3 4) C6 H5 CO HOCH3
|| ||
O O
42. Which of the following reactions is/not correctly represented
1)
2)

3)
4)
43. Reactivity order of acid derivatives towards nucleophilic acyl substilition
1) RCO2 O  RCOOR  R.CO.Cl  R.CO.NH 2
2) R.CO.Cl   RCO 2 O  R.CO.NH 2  RCOOR
3) R.COOR  R.CO.Cl  R.CO 2 O  R.CO.NH 2
4) R.CO.Cl   R.CO 2 O  RCOOR  R.CO.NH 2
44.
End product (C) in above reaction is :
1) 2)
3) 4)

45. Which of the following does not form a stable hydrate on addition of H 2O ?
1) PhCO – CO – COPh 2)
3) CCl3CHO 4)
46. In which of the following reactions of carboxylic acid (or) salt of carboxylic acid
alkane is the product?
NaOH  CaO Re d ' P '  HI
1) RCOONa  
2) RCOOH  
electrolysis
3) RCOONa aq    4) All
I2
  B CHI3;

NaOH
47.
Product (B) in this reaction is :
1) 2) 3) 4)
48. A substance C 4 H10O yields on oxidation a compound C 4 H8O which gives an oxime
and a positive iodoform test. The original substance on treatment with conc. H 2SO 4
gives C 4 H 8 . The structure of the compound is :
1) CH 3CH 2CH 2CH 2OH 2) CH3CH OH CH 2CH 3
3) CH3 3 COH 4) CH 3CH 2  O  CH 2CH 3
49.
What is (X)?
1) 2)
3) 4)
50.   chlorobutyric acid is named in IUPAC as
1) 2-chlorobutanoic acid 2) 2-chlorobuteric acid
3) 3-chlorobutanoic acid 4) 3-chlorobuteric acid

51. Number of non-bonded electron pairs present in a molecule of bulky organic product
(unprotonated form) of the following acid catalysed hydrolysis?

HO , H2O
3
 
?
52. The following molecule is prepared from formaldehyde and propanedial by a suitable
process. What is the sum of change of oxidation state of carbon atoms of two
reactants in the formation of one molecule given below ?

53. The number of isomeric carboxylic acids possible for the formula C4 H 8O2 are
54.
1mole CH 3  Mg  X
     X
H 2 O
The numbers of stereoisomers of ‘X’ is :
55. How many of the following are more reactive than acetaldehyde towards nucleophilic
addition?
C6H5 – CHO, CH3CH2CHO, FCH2CHO, O2N – CH2CHO, CH3COCH3
CH3CH2COCH2CH3
O O O
|| || ||
H  C H CCl3  C  H CF3  C  CF3
56. HCHO  NH 3  P is used for urinary infections. In ‘P’ difference in number of
carbons and nitrogen’s is
i)CH MgBr CaOH , I2 
3 A 2  B C
ii)H2O/ H yellowppt
57.
Number of sp2 carbons in the molecule ‘C’
58. Number of isomers exists with molecular formula C 9 H10O .
If ‘n’ is the number of isomers which satisfy following conditions, value of ‘n’
is___________
1) They can be prepared by Rosenmund’s reduction
2) on oxidation with KMnO 4 gives benzoic acid

59. The number of compounds which liberates CO2 from NaHCO3in the following is
60. Find the no. of reactions in which carboxylic acid is obtained as a final product.
H 3O 
I) R  C  O  R ' 
 i LiAlH 4 
 II) R  C  O  C  R ' 
|| || ||  ii H 2O
O O O
H 3O  
  H 3O 
III) R  C  N    IV) R  N  C   
O O
||
 i NaOI
V) R  C  CH 3   VI) R 
||
C  H 
R ' CO3H


 ii H 
O
O HIO4
PCC  
RC 
VII) H VIII) O

MATHS Max Marks: 100
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its
61. A = {1, 2, 3, 4} and B = {0, 1, 2, …….., 6}. A mapping f : A  B is chosen at
random from set of all mappings from A to B. If ‘f’ is one-one, then the probability
that the maximum element in the range of ‘f’ is 4 is
5 3 4 2
1) 2) 3) 4)
21 14 35 7
62. A fifteen digit number is formed at random by using all the digits 1, 1, 1, 1, 2, 2, 3, 3,
3, 4, 4, 4, 4, 4, 4. If the number so formed is a palindrome, then the probability that it
contains no two 4’s adjacent is :
5 3 4 2
1) 2) 3) 4)
21 14 35 7
63. The letters of the word EQUILIBRIUM are arranged in a row at random. If it is
known that no two vowels are together, then the probability that no two consonants
are together is ……
3 5
1) 0 2) 1 3) 4)
53 53
64. A wooden cube whose faces are painted same colour red and with volume 64 cubic
units is divided into 64 unit cubes by cutting the cube along planes parallel to its
faces. Out of 64 units cubes obtained one is chosen at random and one of its faces is
found painted red then the probability that none of the remaining faces of it, is
painted is ……..
2 1 3 4
1) 2) 3) 4)
7 4 7 7
65. A fair coin is tossed repeatedly until two consecutive heads are obtained. The
probability that two consecutive heads occur on the seventh and eighth flips is equal
to:
11 15 13 17
1) 2) 3) 4)
256 256 256 256
66. 10 different books and 2 different pens are given away to 3 boys. Given that all get
equal number of things, the chance that the same boy will not receive both pens is
…….
1 3 5 8
1) 2) 3) 4)
11 11 11 11

67. Four standard, six faced dice are rolled. If the product of their values turns out to be
an even number then the probability that their sum is odd, is :
1 3 8 4
1) 2) 3) 4)
2 4 15 15
E  1
If E1 , E 2 are two events such that P E1   , P E 2 / E1   and P  1   then
1 1
68.
4 2  E 2  4
which of the following is not true?
1) E1 and E 2 are independent
2) E1 and E 2 are exhaustive
3) E 2 is twice as likely to occur as E1
4) Probabilities of the events E1  E 2 ,E1 , E 2 are in G.P
69. When a missile is fired from a ship, the probability that it is intercepted is 1/3. The
probability that the missile hits the target, given that it is not intercepted is 3/4.If three
missiles are fired independently from the ship, then the probability that all the three
hits the target, is
1) 1/12 2) 1/8 3) 3/8 4) 3/4
70. A box contains 100 tickets numbered 1 to 100. Two tickets are chosen at random .It is
given that the maximum number on them is not more than 10, then the minimum is 5
with probability
1) 4/45 2) 1/9 3) 8/45 4)1/18
71. Two cubes have each of their faces painted either red or blue. The first cube has five
red faces and one blue face. When the two cubes are rolled simultaneously, the
probability that the two top faces show the same colour is (1/2). Number of red faces
on the second cube, is
1) 1 2) 2 3) 3 4) 4
72. For any two elements E and F in a sample space and if P (A denote probability of
event
A, then
E E 1 E E
1) P    P    2) P   P    1
 F   F  2  F  F
E E E E
3) P    P    1 4) P    P    1
 F   F   F   F 

73. One ticket is selected at random from 50 tickets numbered 00, 01, 02,…….,49. Then
the probability that the sum of the digits on the selected ticket is 4, given that product
of digits is zero, equals
1 1 1 5
1) 2) 3) 4)
50 7 4 14
74. For two events A and B if P A   0.4, P B / A  0.9, PB / A  0.6 then PA / B 
1) 0.6 2) 0.1 3) 0.64 4) 0.4
75. Three numbers are selected at random without replacement from the set of numbers
1, 2, 3....n. The probability that the third number falls between the first two
numbers; if the first number is known to be smaller than the second is
1 1 2 1
1) 2) 3) 4)
2 3 3 4
76. A 4-digit number is chosen at random. If it is known that its digits (from 1000’s place
to unit place) are in strictly decreasing order then the probability that the number is
divisible by 4 is
3 2 5 1
1) 2) 3) 4)
7 7 7 2
77. A bag contains 4 black, 5 white and 6 red balls. If 4 balls are drawn one by one with
replacement the probability that none is red is
81 27 81 27
1) 2) 3) 4)
625 125 125 625
78. Two dice are thrown at a time and the sum of the numbers is 6. The probability of
getting a number 4 on any one of die is
1 2 1 2
1) 2) 3) 4)
5 3 3 5
79. From the set of all positive integral divisors of 2 .3 .5 .7  one number ‘x’ is selected
3 4 2 1
at random. If ‘x’ is even, then the probability that it is a multiple of 10 is

1 1 2 1
1) 2) 3) 4)
3 2 3 4
80. Two persons A, B and 8 others are arranged in a row at random. In the arrangement if
A is not at the starting place or the ending place, then the probability that A, B are
adjacent to each other is …..
2 1 4 1
1) 2) 3) 4)
9 5 5 9

81. A four digited number is formed at random by using the digits 1, 2, 3, 4, 5, 6 with no
digit repeated. If the number so formed is divisible by 4, then the probability that the
1
number is divisible by 9 is   where ‘p’ equals to
 p 
82. From a box containing 3 red ball, 4 white ball and 5 blue balls, 3 balls are drawn
together at random. Out of the 3 balls drawn, it is found that one is blue. Then the
probability that all the 3 balls drawn are of different colours is equal to ‘p’ then
1 
18 1 
 p 
83. The faces of a perfect cubical die are marked 1, 2, 2, 3, 3, 3. The die is rolled two
times. If the sum of the numbers obtained is even, then the probability that their
product is also even is equal to 1/p where p = ………
84. A = {1, 2, 3, 4, 5, 6}. Two subsets P, Q are chosen from the power set of A, one by
 n P  Q  1 
one with replacement. Then the value of the conditional probability P  
 n P  Q  4 
 
is   where  ,   N are coprime. Then the sum of all positive integral divisors of
  
  is……
85. One matrix ‘M’ is chosen at random from set of all 3 3 matrices all of whose
elements belongs to 3,  2, 1, 0, 1, 2, 3 If M is a symmetric matrix, then the
probability that ‘M’ is either skew-symmetric or a scalar matrix is equal to ‘P’ where
2
the value of    …….
 7P 
 1 
A1 , A 2 ,......, A10 are independent events where P A i     1  i  10, i  N. If the
1  i 
86.
1
probability that none of A 1 , A 2 ,......., A10 occurs, except A 5 is equal to  , then p =
 p 
….
87. A man ‘A’ speaks truth in 80% cases. Another man ‘B’ speaks truth in 88% cases. If
they speaks about same incidents independently, then they contradict each other in
x% cases where x = …..
88. Let A, B are two independent events of a trial. Let the probability of occurrence of
both A and B is 1/6 and then probability of occurrence of none of A, B is 1/3. If
P(A) < P(B) then the value of 2022 P  A / B  ....
89. Two cards are drawn together at random from a normal pack of 52 playing cards. If
one of the cards is found to be heart, then the probability that the other card is also a
heart is equal to reciprocal of ‘p’ where p  …….
90. A fair die is rolled 3 times. If the numbers obtained in order be x, y, z and x, y, z
forms A.P, then the probability that the common difference of the A.P is 2 is (1/p).
Then the least positive integer having exactly ‘p’ positive integral divisors is equal to
…..

24-07-2021 SR - Super60 (In Coming) Jee-Main WTM-37 Question Paper

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Sri Chaitanya IIT Academy., India.

A.P, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI

A right Choice for the Real Aspirant

24-07-2021_Sr.Super60(In Coming)_Jee-Main_WTM-37_Test Syllabus

CHEMISTRY : Aldehydehydes and Ketones, Carboxylic acids and its derivatives

MATHEMATICS : Conditional probability, Independent events, Multiplication theorem

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1) Increasing, increasing 2) Increasing, decreasing

1) A 2) B 3) C 4) None of the above

3) 1.511012 per sec 4) 2.131011 per sec

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(NUMERICAL VALUE TYPE)

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27. When a metallic surface is illuminated with monochromatic light of wavelength  ,

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(mixture of carbonyl compounds)

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The major product (y) in the above reaction:

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Product ( P ) of the reaction is :

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End product (C) in above reaction is :

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(NUMERICAL VALUE TYPE)

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at random. If ‘x’ is even, then the probability that it is a multiple of 10 is

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