GeneralChemistry1 Q1 Mod6 GasesII Version1
GeneralChemistry1 Q1 Mod6 GasesII Version1
GeneralChemistry1 Q1 Mod6 GasesII Version1
NOT
General Chemistry 1
Quarter 1 - Module 6
Gases II
Pmixture = P1 + P2 + P3
𝑃1 𝑃2
=
𝑇1 𝑇2
𝑃1 𝑉1 = 𝑃2 𝑉2
𝑉1 𝑉2
=
𝑇1 𝑇2
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i
Senior
Senior High
High School
School
General
Chemistry 1
Quarter 1 - Module 6
Gases II
ii
Table of Contents
What I Know………………………………………………………………………………………….vi
Summary……………………………………………………………………………………………..11
Assessment: (Post-Test)…………………………………………………………………………...12
Key to Answers……………………………………………………………………………………...13
References…………………………………………………………………………………………..15
iii
Module 6
Gases II
What This Module is About
This module demonstrates your understanding of the mathematical relationship
between the pressure, volume, and temperature of a gas. It also tackles the partial pressures
of a gas and its quantitative relationships of the reactants and products in a gaseous reaction
and behaviour and properties of gases at the molecular level
iv
How to Learn from this Module
To achieve the objectives cited above, you are to do the following:
• Take your time reading the lessons carefully.
• Follow the directions and/or instructions in the activities and exercises diligently.
• Answer all the given tests and exercises.
v
What I Know
MULTIPLE CHOICE.
Directions: Read and understand each item and choose the letter of the best answer. Write
your answers on the space provide before the number.
__1. Balance the gaseous chemical equation: __C3H8 + __O2 __CO2 + __H2O
a. 1, 5, 3, 4
b. 2, 3, 4, 1
c. 2, 10, 6, 8
d. 4, 6, 8, 2
__2. Which of the following is NOT a gas mixture?
a. Air b. Smelly Farts
c. Chimney Fumes d. Butane
__3. In which of the following gas mixtures of N 2 and He is the partial pressure of He the
greatest?
a. 2 moles N2, 3 moles He
b. 3 moles N2, 1 moles He
c. 4 moles N2, 2 moles He
d. 5 moles N2, 5 moles He
__4. Which of the following systems will have the greatest volume at STP?
a. 1.00 g N2 (MM = 28 g/mol)
b. 1.00 g NH3 (MM = 17 g/mol)
c. 1.00 g He (MM = 4 g/mol)
d. 1.00 g CO2 (MM = 44 g/mol)
__5. Which of the following will contain the greatest number of molecules at 300K and 1 atm
pressure?
a. 0.01 L
b. 0.10 L
c. 1.00 L
d. 10.0 L
__6. How much carbon dioxide is there in a 3.4 L balloon at SATP?
a. 0.13 g
b. 6.1 g
c. 0.15 mol
d. 6.6 g
__7. In the reaction 2H2 (g) + O2 (g) H2O(l), how many liters of oxygen gas at STP will be
needed to react with 10 L of hydrogen gas at STP?
a. 20.0 c. 5.00 L
b. 10.0 L d. 100 L
__8. Which of the following postulates of the Kinetic Molecular Theory for gases explains
why gases exhibit pressure?
a. The molecules are in constant random motion
b. The distance between the molecules is great
c. The molecules collide with the walls of the vessel
d. The molecular kinetic energy depends on the temperature.
__9. How will a velocity of a gas molecule vary if its molecular weight is increased from 32
g/mol to 64 g/mol?
a. It will increase. c. It will double.
b. It will decrease. d. Nothing happens.
__10. Which of the following gases is the fastest: He, O 2, CO2, NH3?
a. O2 c. He
b. CO2 d. NH3
vi
Lesson Gas Stoichiometry
1
What I Need to Know
Gases are everywhere. We interact with gases in our day to day life. The air we
breathe, the fire that cooks our food, the formation of our ozone layer, and even the
engines that powers our cars deal with gaseous reactions.
In this lesson, you will learn the quantitative relationships of the reactants and
products in a gaseous reaction. We will also be tackling how gases interact to form
products and its impact on its pressure and volume. You will also learn how to
determine the amount of gaseous reactants or products using the principles of
stoichiometry.
What’s New
1
What Is It
In every chemical reaction, there is a certain ratio of the components that must
be available in order for the reaction to proceed. This ratio is called the stoichiometric
ratio. The stoichiometric ratio dictate how much reactants are needed in order to
create the desired products. We can see this as a ‘recipe’ for the reaction except that
the ‘recipe’ come in an equation with coefficients telling us how much of each
component is needed rather than having cups and teaspoons and a whole bunch of
instructions in it.
Similarly, gases that participate in a gaseous reaction follow the same principle.
However, quantifying the exact amount of product that a gaseous reaction produce is
not as easy as reactions that yield solid or liquid products which are simpler to
measure and contain. Gases, as defined, is a state of matter with no definite shape
and volume, so how can people tell how much product is formed?
𝑃𝑉
𝑛=
𝑅𝑇
Substituting the STP values in the equation, we can infer that the amount of
gaseous products is equal to:
…where VSTP is the volume of the gases involved measured at STP in litres (L).
The expansion of the airbag can then be measured which can be used to
determine the amount of gaseous products formed. Let’s say that our airbag has an
average volume of 60 litres and the volume occupied by the solid sodium is negligible.
Assuming that the airbag’s volume was measured at STP, we can determine the
amount of nitrogen gas produced by the reaction.
2
Substituting that into the equation:
𝑉𝑆𝑇𝑃 60 𝐿
𝑛= = = 2.68 𝑚𝑜𝑙 𝑁2
22.4 22.4
This means that for every 60 litres of airbag that is inflated, there are 2.68 mol
of nitrogen gas produced by the reaction.
This equation can be used when determining the amount of gaseous products
in moles measured at SATP.
What’s More
Directions: Put a star on the letter that corresponds to the best answer.
(For #1-3) Mr Wangxian installed a pneumatic piston near his door that is triggered
to lock the door in case of an attack and placed 13.0 grams of NaN 3 in the empty
piston. It is powered by the reaction below:
2 NaN3 (s) 2 Na (s) + 3 N2 (g)
1. How many moles of NaN3 was available for the reaction? (Molar mass of NaN3
is 65 g/mol)
A. 0.2 mol C. 0.1 mol
B. 0.3 mol D. 0.4 mol
2. Assuming that all of the NaN3 reacted, how many moles of nitrogen gas was
formed?
A. 0.2 mol C. 0.1 mol
B. 0.3 mol D. 0.4 mol
3. Assuming that all of the NaN3 reacted and the volume occupied by the solid
sodium is negligible, what is the final volume of the piston?
A. 6.27 L C. 6.72 L
B. 7.26 L D. 2.76 L
3
4. 22.4 L of compound A was measured at STP after a gaseous reaction, how
many moles of A was in the sample?
A. 0.1 mol C. 10 mol
B. 0.01 mol D. 1.0 mol
(For #5-7) Acetylene (C2H2) is formed by the reaction of water with calcium carbide,
according to the following equation:
7. How many grams of CaC2 must Ms Xiyao prepare? (Molar mass of CaC2 is 64
g/mol)
A. 68.2 g C. 28.6 g
B. 62.8 g D. 26.8 g
9. Assuming that all of the acetylene reacted, how many moles of CO 2 was
formed?
A. 6.64 mol C. 6.44 mol
B. 6.46 mol D. 4.46 mol
4
What I Have Learned
Directions: Look up some cases where gas stoichiometry can be used in our modern
day. In your own words, write about what you discovered and how it is related to the
topic.
What I Can Do
Enrichment Activity:
5
Lesson Kinetic Molecular Theory of
2 Gases
What’s In
In the previous lesson, you have learned about how gaseous products are
measured with the use of stoichiometry and the ideal gas law.
In this lesson, we will be learning how gases move around and how they interact
with the space around it.
Gases around us behave differently from the other states of matter since they
are very flexible. Understanding how these work around our surroundings is one way
of appreciating our environment.
In this lesson, you will learn about the kinetic molecular theory of gases and
relate the rates of gas effusion with molar mass.
What’s New
Differentiate. Describe and differentiate the illustrations in the columns from one
another. You may also guess what state of matter it represents.
6
What Is It
Solids, liquids, and gases differ from one another in many ways. One distinction
that is being observed between the three states of matter is how closely packed their
atoms are. Solids are the most rigid among the three with each atom bundled up
almost side to side with no room for movement except for tiny vibrations which we
usually feel as heat. Liquids, on the other hand, are more flexible than solids with its
particles freely sliding on each other. This allows liquids to take the shape of their
containers while keeping its volume constant. Meanwhile, gases are the most flexible
and freely moving with its atoms observing very good social distancing and can be
compressed. This is the reason why gases cannot have a definite volume and can
occupy the shape of its container.
From what we know of the kinetic energy, it is defined as the energy possessed
by the object in motion. When things are in motion, they have velocity. Gases in
particular are very mobile particles and since these particles move independently from
one another and move randomly, it is hard to pinpoint the velocity at which each
molecule moves. In order to determine its kinetic energy, the root-mean-square
velocity of the gas is used and is defined by the equation:
3𝑅𝑇
𝑣𝑟𝑚𝑠 = √
𝑀
…where vrms is the root-mean-square velocity of the gas, R is the ideal gas
constant, T is the absolute temperature in K, and M is the molar mass of the gas in
g/mol.
7
As you can observe in the previous equation, the velocity is directly dependent
on its absolute temperature. This means that the hotter the gas, the more mobile the
gas molecules are.
3𝑅𝑇 𝑇 𝑇
𝑣𝑟𝑚𝑠 = √ = (√3𝑅) × √ = 𝑘 × √
𝑀 𝑀 𝑀
Just like the gas laws, we can make use of this proportionality to compare the
velocities of two different gases of different molar masses at the same absolute
temperature. Let’s take compound 1 and 2 as an example with molar masses M 1 and
M2, respectively.
𝑇 𝑇
𝑣𝑟𝑚𝑠,1 = 𝑘 × √ 𝑣𝑟𝑚𝑠,2 = 𝑘 × √
𝑀1 𝑀2
Since both are of the same temperature, we can factor out the square root of
the temperature. This will yield this expression:
1 1
𝑣𝑟𝑚𝑠,1 = 𝑘√𝑇 × 𝑣𝑟𝑚𝑠,2 = 𝑘√𝑇 ×
√𝑀1 √𝑀2
Since both expressions are equal to k multiplied to the square root of T, we can
equate both equations and rearrange them again to get this expression:
𝑣𝑟𝑚𝑠,1 √𝑀2
=
𝑣𝑟𝑚𝑠,2 √𝑀1
Let’s take the diffusion of helium gas (He, molar mass = 4 g/mol) and oxygen
gas (O2, molar mass = 16 g/mol). How much faster would helium gas diffuse than
oxygen gas? Let us use the Graham’s Law of Diffusion to determine this.
8
According to our calculations, the ratio of the diffusion rates of helium to oxygen
gas is 4:2, which means that helium diffuses two times faster than oxygen at the same
temperature.
What’s More
Directions: Put a star on the letter that corresponds to the best answer.
1. Two bottles at the same temperature containing hydrogen sulphide (H 2S) and
ammonia (NH3) are placed at equal lengths from you and are opened at the
same time. Which gas would you smell first?
A. Both C. None
B. Hydrogen sulphide D. Ammonia
2. Which of the following gases diffuses the fastest? Oxygen (O2), Hydrogen (H2),
Sulphur dioxide (SO2), or Carbon dioxide (CO2)?
A. Oxygen C. Hydrogen
B. Sulphur dioxide D. Carbon dioxide
3. Which of the following gases diffuses the slowest? Oxygen (O 2), Hydrogen (H2),
Sulphur dioxide (SO2), or Carbon dioxide (CO2)?
A. Oxygen C. Hydrogen
B. Sulphur dioxide D. Carbon dioxide
4. Which of the following gases diffuses the fastest? Helium (He), Ammonia (NH 3),
Hydrogen sulphide (H2S), or Carbon dioxide (CO2)?
A. Helium C. Ammonia
B. Hydrogen sulphide D. Carbon dioxide
5. Which of the following gases diffuses the slowest? Helium (He), Ammonia
(NH3), Hydrogen sulphide (H2S), or Carbon dioxide (CO2)?
A. Helium C. Ammonia
B. Hydrogen sulphide D. Carbon dioxide
6. Which of the following gases diffuses the fastest? Helium (He), Hydrogen (H2),
Sulphur dioxide (SO2), or Carbon dioxide (CO2)?
A. Helium C. Hydrogen
B. Sulphur dioxide D. Carbon dioxide
7. How much faster does helium gas diffuse than sulphur dioxide?
A. 2x C. 4x
B. 0.5x D. 0.25x
8. How much faster does hydrogen gas diffuse than sulphur dioxide?
A. 5.65x C. 4x
B. 0.18x D. 0.25x
9
9. How will a gas velocity vary if its molecular weight was decreased from 144
g/mol to 64 g/mol?
A. It will be faster by 200% C. It will be halved.
B. It will remain the same. D. It will be faster by 150%
10. How will a gas velocity vary if its molecular weight was increased from 32 g/mol
to 128 g/mol?
A. It will be faster by 200% C. It will be halved.
B. It will remain the same. D. It will be faster by 150%
Directions: Write an essay about how gas diffusion affects your day to day life. If
possible, cite examples and explain its connection to your day to day life.
10
Summary
With the integration of the ideal gas law, we can then determine the amount of
gas molecules occupied in a volume. At STP, the amount of gaseous molecules are
determined with the use of the expression:
𝑉𝑆𝑇𝑃
𝑛=
22.4
And at SATP, the amount of gaseous molecules can be determined using the
expression:
𝑉𝑆𝐴𝑇𝑃
𝑛=
24.5
Gases behave differently compared to solids and liquids due to its kinetic
molecular theory which states that gases are (1) made up of very small molecules that
are (2) separated by very great distances that (3) causes the force of attraction
between two molecules to be negligible, hence their motion is independent from one
another and since they have so much space between them, (4) the molecules are in
constant motion and move randomly in all directions which (5) eventually causes them
to collide (6) in a perfectly elastic collision which means that no momentum is lost
between two particles and due to their constant state of motion, (6) the average kinetic
energy of the molecules can only be determined by its absolute temperature.
The kinetic energy of the gas can also be determined using the root-mean-
square velocity of the gas which is expressed in this equation:
3𝑅𝑇
𝑣𝑟𝑚𝑠 = √
𝑀
This can also be used to compare the diffusion rates between two gases at the
same temperature using the Graham’s Law of Diffusion, as shown by the expression
below:
𝑣𝑟𝑚𝑠,1 √𝑀2
=
𝑣𝑟𝑚𝑠,2 √𝑀1
11
Assessment: (Post-Test)
MULTIPLE CHOICE.
Directions: Read and understand each item and choose the letter of the best answer. Write
your answers on the space provide before the number.
__1. Balance the gaseous chemical equation: __C3H8 + __O2 __CO2 + __H2O
e. 1, 5, 3, 4
f. 2, 3, 4, 1
g. 2, 10, 6, 8
h. 4, 6, 8, 2
__2. Which of the following is NOT a gas mixture?
c. Air b. Smelly Farts
d. Chimney Fumes d. Butane
__3. In which of the following gas mixtures of N 2 and He is the partial pressure of He the
greatest?
e. 2 moles N2, 3 moles He
f. 3 moles N2, 1 moles He
g. 4 moles N2, 2 moles He
h. 5 moles N2, 5 moles He
__4. Which of the following systems will have the greatest volume at STP?
e. 1.00 g N2 (MM = 28 g/mol)
f. 1.00 g NH3 (MM = 17 g/mol)
g. 1.00 g He (MM = 4 g/mol)
h. 1.00 g CO2 (MM = 44 g/mol)
__5. Which of the following will contain the greatest number of molecules at 300K and 1 atm
pressure?
e. 0.01 L
f. 0.10 L
g. 1.00 L
h. 10.0 L
__6. How much carbon dioxide is there in a 3.4 L balloon at SATP?
e. 0.13 g
f. 6.1 g
g. 0.15 mol
h. 6.6 g
__7. In the reaction 2H2 (g) + O2 (g) H2O(l), how many liters of oxygen gas at STP will be
needed to react with 10 L of hydrogen gas at STP?
b. 20.0 c. 5.00 L
d. 10.0 L d. 100 L
__8. Which of the following postulates of the Kinetic Molecular Theory for gases explains
why gases exhibit pressure?
e. The molecules are in constant random motion
f. The distance between the molecules is great
g. The molecules collide with the walls of the vessel
h. The molecular kinetic energy depends on the temperature.
__9. How will a velocity of a gas molecule vary if its molecular weight is increased from 32
g/mol to 64 g/mol?
c. It will increase. c. It will double.
d. It will decrease. d. Nothing happens.
__10. Which of the following gases is the fastest: He, O 2, CO2, NH3?
c. O2 c. He
d. CO2 d. NH3
12
Key to Answers
Pretest
Lesson 1
Lesson 2
What’s New
What’s More
13
Post-test
14
References
15
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16