ARIF RAZA GROUP COACHING

0334 36 53 937
𝑵𝑨𝑴𝑬: −
Date:- 12th July, 2021,
Monday
GRAND TEST 𝑻𝒊𝒎𝒆: − 𝟎𝟒: 𝟎𝟎 𝑷𝑴 − 𝟔: 𝟎𝟎 𝑷𝑴

𝑴𝒂𝒙. 𝑴𝒂𝒓𝒌𝒔: − 𝟖𝟓 Chemistry XI 𝑴𝒂𝒓𝒌𝒔 𝑶𝒃𝒕𝒂𝒊𝒏𝒆𝒅: −

𝐴𝑅𝐼𝐹 𝑅𝐴𝑍𝐴 𝐺𝑅𝑂𝑈𝑃 𝐶𝑂𝐴𝐶𝐻𝐼𝑁𝐺, 0334 − 36 53 937 𝑷𝒓𝒆𝒑𝒂𝒓𝒆𝒅 𝑩𝒚: − 𝑨𝒓𝒊𝒇 𝑹𝒂𝒛𝒂
SECTION “A”
(MULTIPLE CHOICE QUESTIONS)
1. Choose the correct answer for each from the given options:- (𝟒𝟑)
(i) Rain drops have spherical shape because a sphere has the least ___.
* Area * Volume * Length * Surface to volume ratio
(ii) The quantities relationship between the substances according to balance equation describes
___.
* Reversible reaction * Stoichiometry
* Limiting reactant * Percentage compound
(iii) 3. 870.0 have ___ significant figures.
* 2 * 3 * 4 * 5
(iv) The number of orbitals in a shell can be determined by the formula ___.
* 2𝑙 + 1 * 2(2𝑙 + 1) * 𝑛2 * 2𝑛2
(v) 𝑆 −2 is isoelectronic with ___.
+1 +1 +3
* 𝑁𝑎11 * 𝐹9−1 * 𝐾19 * 𝐴𝑙13
(vi) The most of the radiations coming out from pitch blend were ___.
* Electron * Proton * X−rays * Neutron
(vii) The bonds present in ethene (𝐶2 𝐻4 ) are ___.
* 5𝜎&1𝜋 * 2𝜎&2𝜋 * 3𝜎&2𝜋 * 𝐴𝑙𝑙 𝜎
(viii) ___ molecule has linear structure.
* 𝐶𝐻4 * 𝑁𝐻3 * 𝐵𝐹3 * 𝐶2 𝐻2
(ix) Ice floats on top of water because its density is ___.
* Lesser than density of water * Greater than density of water
* Equal to density of water * All of them
(x) Heat absorbed by a system when its volume does not change is equal to ___.
* Internal energy * Work done by system
* Increase internal energy * Change in enthalpy of system
(xi) ___ is the intensive property of system.
* Density * Energy * Volume * Entropy
(xii) The product of pressure and volume, 𝑃𝑉 has the dimensions of ___.
* Pressure * Volume * Energy * Temperature
(xiii) For the reaction 2𝑁𝐻3 → 𝑁2 + 3𝐻2 the relationship between 𝐾𝑐 and 𝐾𝑝 is ___.
𝐾𝑐
* 𝐾𝑐 > 𝐾𝑝 * 𝐾𝑐 < 𝐾𝑝 * 𝐾𝑐 = 𝐾𝑝 * 𝐾𝑝 = 2

(xiv) Given the equilibrium the 𝑃𝐶𝑙5 → 𝑃𝐶𝑙3 + 𝐶𝑙2 ∆𝐻 = +𝑣𝑒 concentration of 𝐶𝑙2 at equilibrium
will be increased by ___.
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* Lowering of temperature * Adding 𝑃𝐶𝑙3 to the mixture
* Adding 𝑃𝐶𝑙5 to the mixture * Increasing pressure
(xv) Solution of ___ is basic.
* 𝑁𝐻4 𝐶𝑙 * 𝑁𝑎𝐶𝑙 * 𝑁𝑎2 𝐶𝑂3 * 𝐾𝐶𝑙
(xvi) The oxidation number of 𝐶𝑟 in 𝐶𝑟2 𝑂7−2 is ___.
* +3 * +6 * +12 * −2
(xvii) The properties of solution which depends upon the number of particles of solute is called ___
properties.
* Colligative * Intensive * Qualitative * Physical
(xviii) If the rate of reaction is independent of concentration of the reactant the reaction is of ___
order.
* 𝑍𝑒𝑟𝑜 * 𝐹𝑖𝑟𝑠𝑡 * 𝑆𝑒𝑐𝑜𝑛𝑑 * 𝑇ℎ𝑖𝑟𝑑
(xix) A catalyst is a substance which increase the rate of reaction of chemical reaction, because ___.
* It increases the temperature * It increases the pressure
* It changes the rate constant * It lowers the activation energy
(xx) The branch of chemistry which deals with the study of reaction rates is known as ___.
* Photochemistry * Chemical kinetics
* Thermodynamics * Electrochemistry
(xxi) The penetration power of 𝛽 − 𝑝𝑎𝑟𝑡𝑖𝑐𝑙𝑒 in air as compare to 𝛼 − 𝑝𝑎𝑟𝑡𝑖𝑐𝑙𝑒 is ___ times.
* 100 * 2 * 1000 * 200
(xxii) A gas at 𝑧𝑒𝑟𝑜 𝑘𝑒𝑙𝑣𝑖𝑛 ___.
* Is super cooled * Freezes
* Liquefies * Has zero volume
(xxiii) The molecular formula of 𝑣𝑖𝑡𝑎𝑚𝑖𝑛 𝐶 is 𝐶6 𝐻8 𝑂6. Its Empirical formula is ___.
* 𝐶2 𝐻3 𝑂2 * 𝐶3 𝐻4 𝑂3 * 𝐶𝐻2 𝑂 * 𝐶𝐻𝑂2
(xxiv) 𝐸 + 𝑃𝑉 is called ___.
* Entropy * Enthalpy * Free energy * Internal energy
(xxv) The quantum number values for 3𝑝 orbitals are ___.
* 𝑛 = 2, 𝑙 = 1 * 𝑛 = 3, 𝑙 = 0 * 𝑛 = 2, 𝑙 = 2 * 𝑛 = 3, 𝑙 = 1
(xxvi) Orbitals having same energy are called ___ orbitals.
* Hybrid * Degenerated * Valence * Bonding
(xxvii) The net enthalpy change in a chemical reaction is same, whether it is brought about in two or
more different ways in one or several steps. It is known as ___.
* Henry’s law * Hess’s law
* Joule’s principle * Law of energy conservation
(xxviii) __ compound does not contain hydrogen bonding.
* 𝐶𝐻4 * 𝐻2 𝑂 * 𝑁𝐻3 * 𝐻𝐹
(xxix) In a chemical reaction, equilibrium is said to have established when ___.
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* Concentration of reactants and products are equal
* Opposing reaction rates cease * Rate of opposing reactions becomes equal
* Rate of forward reaction is twice as compared to reverse reaction
(xxx) ___ molecule has the largest bond angle.
* 𝐶𝐻4 * 𝐻2 𝑂 * 𝑁𝐻3 * 𝐵𝑒𝐶𝑙2
(xxxi) The value of 𝑅 (𝑔𝑒𝑛𝑒𝑟𝑎𝑙 𝑔𝑎𝑠 𝑐𝑜𝑛𝑠𝑡𝑎𝑛𝑡) in 𝑆. 𝐼 𝑈𝑛𝑖𝑡 is ___.
* 8.3143 𝑁. 𝑚/𝐾. 𝑚𝑜𝑙 * 8.3143 𝑁. 𝑚/°𝐶. 𝑚𝑜𝑙
* 0.0821 𝑁. 𝑚/°𝐶. 𝑚𝑜𝑙 * 0.0821 𝑁. 𝑚/𝐾. 𝑚𝑜𝑙
(xxxii) Bohr’s Atomic model is contradicted by ___.
* Planks quantum theory * Chadwick experiment
* Heisenberg uncertainty principle * Faraday’s experiment
𝑒
(xxxiii) The 𝑚 value of electron is ___ 𝐶/𝑔.

* 1.758 × 108 * 0.000550 * 1.008 * 9.11 × 10−28

(xxxiv) The reaction which involves both oxidation and reduction is called ___ reaction.
* Addition * Redox * Elimination * Substitution
(xxxv) The rate of reaction ___.
* Increases as the reaction proceeds * Increases as the reaction proceeds
* Remains the same as the reaction proceeds
* May increase or decrease as the reaction proceeds
(xxxvi) For gaseous system, the value of 𝐾𝑝 and 𝐾𝑐 are same when ___.
* Reaction occurs at S.T.P. * Reaction is exothermic
* Reaction is endothermic
* Number of moles of products are equal to number of moles of reactants
(xxxvii) Heat absorbed or released during a chemical process at constant pressure is equal to ___.
* ∆𝐸 * ∆𝐻 * 𝑞 * 𝑊
(xxxviii) ___ molecule has two 𝜋 bonds.
* 𝐶𝐻4 * 𝐶2 𝐻4 * 𝑁2 * 𝑂2
(xxxix) No two electrons in an atom can have a same set of four quantum number is called ___.
* Newton’s first law * Pauli’s exclusion principle
* Hund’s rule * Aufbau principle
(xl) Alpha rays are ___.
* Neutron * Electron * Proton * Helium nuclei
(xli) The surface tension of liquid is independent of ___.
* Temperature * Intermolecular forces
* Nature of liquid * Amount of liquid
(xlii) The tendency of liquid to cling together is called ___.
* Surface tension * Cohesion * Adhesion * Viscosity
(xliii) The number of waves travel in 𝑜𝑛𝑒 𝑐𝑒𝑛𝑡𝑖𝑚𝑒𝑡𝑒𝑟 distance is called ___.
* Wavelength * Wave number * Wave function * Frequency
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SECTION “B” (Short−Answer Questions)
Note:- Attempt any FIVE questions from this section. All questions carry equal marks.
𝑨𝒕𝒐𝒎𝒊𝒄 𝒎𝒂𝒔𝒔𝒆𝒔: = − 𝑯 = 𝟏, 𝑪 = 𝟏𝟐, 𝑵 = 𝟏𝟒, 𝑶 = 𝟏𝟔, 𝑪𝒍 = 𝟑𝟓. 𝟓, 𝒁𝒏 = 𝟔𝟓, 𝑨𝒈 = 𝟏𝟎𝟕. 𝟖 (𝟐𝟓)

2. (i) 1.367 𝑔 of an organic compound containing 𝐶, 𝐻 and 𝑂 was combusted in a stream of air yield
3.002 𝑔 𝐶𝑂2 and 1.64 𝑔 𝐻2 𝑂. What is the empirical formula of the compound.
(ii) Define the following:-
* Significant figures * System
* Viscosity * Gay−Lussac Law
(iii) State Boyle’s Law, Charles’s law and prove them in term of Kinetic Molecular Theory.
(iv) Write down the electronic configuration for ground sates of each of the following:-
* 𝐶𝑙 (𝑍 = 17) * 𝐶𝑎+2 (𝑍 = 20) * 𝐹𝑒 (𝑍 = 26) * 𝑁 −3 (𝑍 = 7)
(v) Differentiate between the following (write only two differences for each).
* Sigma and Pi bond * Hydration and Hydrolysis
(vi) The ratio of rates of diffusion of two gasses 𝐴 and 𝐵 is 1.5: 1. If the relative molecular mass of
gas 𝐴 is 16, find out the relative molecular mass of gas 𝐵.
(vii) State First Law of Thermodynamic. In a certain process, 500 𝐽 of work is done on a system
which gives off 200 𝐽 of heat. What is the value of change in Internal energy for the process?
(viii) Explain the effects of surface area and concentration of reactant on the rate of reaction.
(ix) Define Dipole moment. Why dipole moment of 𝐶𝑂2 and 𝐶𝐶𝑙4 is zero.
(x) Predict the effect of increase in temperature and pressure on the following system at
equilibrium state (only predict the direction).
* 𝑁2 + 3𝐻2 → 2𝑁𝐻3 + 𝐻𝑒𝑎𝑡 * 𝑁2 + 𝑂2 + 𝐻𝑒𝑎𝑡 → 2𝑁𝑂
SECTION “C” (Detailed−Answer Questions)
Note:- Attempt any ONE question from this section. (𝟏𝟕)
3. (a) Write the postulates of Bohr’s atomic theory. Derive the formula for the radius of 𝑛𝑡ℎ 𝑜𝑟𝑏𝑖𝑡 of
hydrogen atom by using Bohr’s atomic model. (𝟎𝟗)
(b) Write the postulates of electron pair repulsion theory. Explain the shape of the 𝐻2 𝑂and 𝑁𝐻3 on
the basis of electron pair repulsion theory. (𝟎𝟖)
4. (a) Define oxidation and reduction. Define orbital hybridization. Explain the following with
examples. (a) 𝒔𝒑𝟑 hybridization (b) 𝒔𝒑 hybridization (𝟎𝟗)
(b) Explain Arrhenius theory of ionization in detail. State and explain the Equilibrium Law. (𝟎𝟖)
5. (a) What are cathode rays? Give the properties of cathode rays and conclusion drawn about the
structure of the atom from this experiment. Also define the construction of discharge tube.
(𝟎𝟗)
(b) How 𝐾𝑐 is used to predict the extent of a reversible reaction? Calculate the number of moles of
𝐶𝑙2 produced at equilibrium when 𝑜𝑛𝑒 𝑚𝑜𝑙𝑒 of 𝑃𝐶𝑙5 is heated at 250 °𝐶 in vessel having a
capacity of 10𝑑𝑚3 (𝐾𝑐 = 0.041) 𝑷𝑪𝒍𝟓 → 𝑷𝑪𝒍𝟑 + 𝑪𝒍𝟐 (𝟎𝟖)